[ { "Publication Type": "J", "Authors": "Yang, WS; Noh, JH; Jeon, NJ; Kim, YC; Ryu, S; Seo, J; Seok, SI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Woon Seok; Noh, Jun Hong; Jeon, Nam Joong; Kim, Young Chan; Ryu, Seungchan; Seo, Jangwon; Seok, Sang Il", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-performance photovoltaic perovskite layers fabricated through intramolecular exchange", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The band gap of formamidinium lead iodide (FAPbI(3)) perovskites allows broader absorption of the solar spectrum relative to conventional methylammonium lead iodide (MAPbI(3)). Because the optoelectronic properties of perovskite films are closely related to film quality, deposition of dense and uniform films is crucial for fabricating high-performance perovskite solar cells (PSCs). We report an approach for depositing high-quality FAPbI(3) films, involving FAPbI(3) crystallization by the direct intramolecular exchange of dimethylsulfoxide (DMSO) molecules intercalated in PbI2 with formamidinium iodide. This process produces FAPbI(3) films with (111)-preferred crystallographic orientation, large-grained dense microstructures, and flat surfaces without residual PbI2. Using films prepared by this technique, we fabricated FAPbI(3)-based PSCs with maximum power conversion efficiency greater than 20%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 5584, "Times Cited, All Databases": 5939, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 12", "Publication Year": 2015, "Volume": 348, "Issue": 6240, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1234, "End Page": 1237, "Article Number": null, "DOI": "10.1126/science.aaa9272", "DOI Link": "http://dx.doi.org/10.1126/science.aaa9272", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356011500049", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Protesescu, L; Yakunin, S; Bodnarchuk, MI; Krieg, F; Caputo, R; Hendon, CH; Yang, RX; Walsh, A; Kovalenko, MV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Protesescu, Loredana; Yakunin, Sergii; Bodnarchuk, Maryna I.; Krieg, Franziska; Caputo, Riccarda; Hendon, Christopher H.; Yang, Ruo Xi; Walsh, Aron; Kovalenko, Maksym V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullocrystals of Cesium Lead Halide Perovskites (CsPbX3, X = Cl, Br, and I): Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal halides perovskites, such as hybrid organic-inorganic CH3NH3PbI3, are newcomer optoelectronic materials that have attracted enormous attention as solution-deposited absorbing layers in solar cells with power conversion efficiencies reaching 20%. Herein we demonstrate a new avenue for halide perovskites by designing highly luminescent perovskite-based colloidal quantum dot materials. We have synthesized monodisperse colloidal nullocubes (4-15 nm edge lengths) of fully inorganic cesium lead halide perovskites (CsPbX3, X = Cl, Br, and I or mixed halide systems Cl/Br and Br/I) using inexpensive commercial precursors. Through compositional modulations and quantum size-effects, the bandgap energies and emission spectra are readily tunable over the entire visible spectral region of 410-700 nm. The photoluminescence of CsPbX3 nullocrystals is characterized by narrow emission line-widths of 12-42 nm, wide color gamut covering up to 140% of the NTSC color standard, high quantum yields of up to 90%, and radiative lifetimes in the range of 1-29 ns. The compelling combination of enhanced optical properties and chemical robustness makes CsPbX3 nullocrystals appealing for optoelectronic applications, particularly for blue and green spectral regions (410-530 nm), where typical metal chalcogenide-based quantum dots suffer from photodegradation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 7392, "Times Cited, All Databases": 7899, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 15, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3692, "End Page": 3696, "Article Number": null, "DOI": "10.1021/nl5048779", "DOI Link": "http://dx.doi.org/10.1021/nl5048779", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356316900006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Togo, A; Tanaka, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Togo, Atsushi; Tanaka, Isao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "First principles phonon calculations in materials science", "Source Title": "SCRIPTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phonon plays essential roles in dynamical behaviors and thermal properties, which are central topics in fundamental issues of materials science. The importance of first principles phonon calculations cannot be overly emphasized. Phonopy is an open source code for such calculations launched by the present authors, which has been world-widely used. Here we demonstrate phonon properties with fundamental equations and show examples how the phonon calculations are applied in materials science. (C) 2015 Acta Materialia Inc. Published by Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons.orgilicenses/by/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 8499, "Times Cited, All Databases": 8915, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2015, "Volume": 108, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1, "End Page": 5, "Article Number": null, "DOI": "10.1016/j.scriptamat.2015.07.021", "DOI Link": "http://dx.doi.org/10.1016/j.scriptamat.2015.07.021", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000360250700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mannix, AJ; Zhou, XF; Kiraly, B; Wood, JD; Alducin, D; Myers, BD; Liu, XL; Fisher, BL; Santiago, U; Guest, JR; Yacaman, MJ; Ponce, A; Oganov, AR; Hersam, MC; Guisinger, NP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mannix, Andrew J.; Zhou, Xiang-Feng; Kiraly, Brian; Wood, Joshua D.; Alducin, Diego; Myers, Benjamin D.; Liu, Xiaolong; Fisher, Brandon L.; Santiago, Ulises; Guest, Jeffrey R.; Yacaman, Miguel Jose; Ponce, Arturo; Oganov, Artem R.; Hersam, Mark C.; Guisinger, Nathan P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis of borophenes: Anisotropic, two-dimensional boron polymorphs", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "At the atomic-cluster scale, pure boron is markedly similar to carbon, forming simple planar molecules and cage-like fullerenes. Theoretical studies predict that two-dimensional (2D) boron sheets will adopt an atomic configuration similar to that of boron atomic clusters. We synthesized atomically thin, crystalline 2D boron sheets (i.e., borophene) on silver surfaces under ultrahigh-vacuum conditions. Atomic-scale characterization, supported by theoretical calculations, revealed structures reminiscent of fused boron clusters with multiple scales of anisotropic, out-of-plane buckling. Unlike bulk boron allotropes, borophene shows metallic characteristics that are consistent with predictions of a highly anisotropic, 2D metal.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2187, "Times Cited, All Databases": 2304, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 18", "Publication Year": 2015, "Volume": 350, "Issue": 6267, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1513, "End Page": 1516, "Article Number": null, "DOI": "10.1126/science.aad1080", "DOI Link": "http://dx.doi.org/10.1126/science.aad1080", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000366591100055", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, SY; Belopolski, I; Alidoust, N; Neupane, M; Bian, G; Zhang, CL; Sankar, R; Chang, GQ; Yuan, ZJ; Lee, CC; Huang, SM; Zheng, H; Ma, J; Sanchez, DS; Wang, BK; Bansil, A; Chou, FC; Shibayev, PP; Lin, H; Jia, S; Hasan, MZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Su-Yang; Belopolski, Ilya; Alidoust, Nasser; Neupane, Madhab; Bian, Guang; Zhang, Chenglong; Sankar, Raman; Chang, Guoqing; Yuan, Zhujun; Lee, Chi-Cheng; Huang, Shin-Ming; Zheng, Hao; Ma, Jie; Sanchez, Daniel S.; Wang, BaoKai; Bansil, Arun; Chou, Fangcheng; Shibayev, Pavel P.; Lin, Hsin; Jia, Shuang; Hasan, M. Zahid", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Discovery of a Weyl fermion semimetal and topological Fermi arcs", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A Weyl semimetal is a new state of matter that hosts Weyl fermions as emergent quasiparticles and admits a topological classification that protects Fermi arc surface states on the boundary of a bulk sample. This unusual electronic structure has deep analogies with particle physics and leads to unique topological properties. We report the experimental discovery of a Weyl semimetal, tantalum arsenide (TaAs). Using photoemission spectroscopy, we directly observe Fermi arcs on the surface, as well as the Weyl fermion cones and Weyl nodes in the bulk of TaAs single crystals. We find that Fermi arcs terminate on the Weyl fermion nodes, consistent with their topological character. Our work opens the field for the experimental study of Weyl fermions in physics and materials science.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2782, "Times Cited, All Databases": 2968, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 7", "Publication Year": 2015, "Volume": 349, "Issue": 6248, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 613, "End Page": 617, "Article Number": null, "DOI": "10.1126/science.aaa9297", "DOI Link": "http://dx.doi.org/10.1126/science.aaa9297", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000359092900034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nedelcu, G; Protesescu, L; Yakunin, S; Bodnarchuk, MI; Grotevent, MJ; Kovalenko, MV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nedelcu, Georgian; Protesescu, Loredana; Yakunin, Sergii; Bodnarchuk, Maryna I.; Grotevent, Matthias J.; Kovalenko, Maksym V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fast Anion-Exchange in Highly Luminescent nullocrystals of Cesium Lead Halide Perovskites (CsPbX3, X = Cl, Br, I)", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Postsynthetic chemical transformations of colloidal nullocrystals, such as ion-exchange reactions, provide an avenue to compositional fine-tuning or to otherwise inaccessible materials and morphologies. While cation-exchange is facile and commonplace, anion-exchange reactions have not received substantial deployment. Here we report fast, low-temperature, deliberately partial, or complete anionexchange in highly luminescent semiconductor nullocrystals of cesium lead halide perovskites (CsPbX3, X = Cl, Br, I). By adjusting the halide ratios in the colloidal nullocrystal solution, the bright photoluminescence can be tuned over the entire visible spectral region (410-700 nm) while maintaining high quantum yields of 20 80% and narrow emission line widths of 10-40 nm (from blue to red). Furthermore, fast internullocrystal anion-exchange is demonstrated, leading to uniform CsPb(Cl/Br)(3) or CsPb(Br/I)(3) compositions simply by mixing CsPbCl3, CsPbBr3, and CsPbI3 nullo crystals in appropriate ratios.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2047, "Times Cited, All Databases": 2199, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2015, "Volume": 15, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5635, "End Page": 5640, "Article Number": null, "DOI": "10.1021/acs.nullolett.5b02404", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.5b02404", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000359613700119", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rost, CM; Sachet, E; Borman, T; Moballegh, A; Dickey, EC; Hou, D; Jones, JL; Curtarolo, S; Maria, JP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rost, Christina M.; Sachet, Edward; Borman, Trent; Moballegh, Ali; Dickey, Elizabeth C.; Hou, Dong; Jones, Jacob L.; Curtarolo, Stefano; Maria, Jon-Paul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Entropy-stabilized oxides", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Configurational disorder can be compositionally engineered into mixed oxide by populating a single sublattice with many distinct cations. The formulations promote novel and entropy-stabilized forms of crystalline matter where metal cations are incorporated in new ways. Here, through rigorous experiments, a simple thermodynamic model, and a five-component oxide formulation, we demonstrate beyond reasonable doubt that entropy predominates the thermodynamic landscape, and drives a reversible solid-state transformation between a multiphase and single-phase state. In the latter, cation distributions are proven to be random and homogeneous. The findings validate the hypothesis that deliberate configurational disorder provides an orthogonal strategy to imagine and discover new phases of crystalline matter and untapped opportunities for property engineering.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2203, "Times Cited, All Databases": 2351, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8485, "DOI": "10.1038/ncomms9485", "DOI Link": "http://dx.doi.org/10.1038/ncomms9485", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363146400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nie, WY; Tsai, HH; Asadpour, R; Blancon, JC; Neukirch, AJ; Gupta, G; Crochet, JJ; Chhowalla, M; Tretiak, S; Alam, MA; Wang, HL; Mohite, AD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nie, Wanyi; Tsai, Hsinhan; Asadpour, Reza; Blancon, Jean-Christophe; Neukirch, Amanda J.; Gupta, Gautam; Crochet, Jared J.; Chhowalla, Manish; Tretiak, Sergei; Alam, Muhammad A.; Wang, Hsing-Lin; Mohite, Aditya D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-efficiency solution-processed perovskite solar cells with millimeter-scale grains", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "State-of-the-art photovoltaics use high-purity, large-area, wafer-scale single-crystalline semiconductors grown by sophisticated, high-temperature crystal growth processes. We demonstrate a solution-based hot-casting technique to grow continuous, pinhole-free thin films of organometallic perovskites with millimeter-scale crystalline grains. We fabricated planar solar cells with efficiencies approaching 18%, with little cell-to-cell variability. The devices show hysteresis-free photovoltaic response, which had been a fundamental bottleneck for the stable operation of perovskite devices. Characterization and modeling attribute the improved performance to reduced bulk defects and improved charge carrier mobility in large-grain devices. We anticipate that this technique will lead the field toward synthesis of wafer-scale crystalline perovskites, necessary for the fabrication of high-efficiency solar cells, and will be applicable to several other material systems plagued by polydispersity, defects, and grain boundary recombination in solution-processed thin films.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2941, "Times Cited, All Databases": 3159, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 30", "Publication Year": 2015, "Volume": 347, "Issue": 6221, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 522, "End Page": 525, "Article Number": null, "DOI": "10.1126/science.aaa0472", "DOI Link": "http://dx.doi.org/10.1126/science.aaa0472", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348639300046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Friebel, D; Louie, MW; Bajdich, M; Sanwald, KE; Cai, Y; Wise, AM; Cheng, MJ; Sokaras, D; Weng, TC; Alonso-Mori, R; Davis, RC; Bargar, JR; Norskov, JK; Nilsson, A; Bell, AT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Friebel, Daniel; Louie, Mary W.; Bajdich, Michal; Sanwald, Kai E.; Cai, Yun; Wise, Anna M.; Cheng, Mu-Jeng; Sokaras, Dimosthenis; Weng, Tsu-Chien; Alonso-Mori, Roberto; Davis, Ryan C.; Bargar, John R.; Norskov, Jens K.; Nilsson, Anders; Bell, Alexis T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identification of Highly Active Fe Sites in (Ni,Fe)OOH for Electrocatalytic Water Splitting", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Highly active catalysts for the oxygen evolution reaction (OER) are required for the development of photoelectrochemical devices that generate hydrogen efficiently from water using solar energy. Here, we identify the origin of a 500-fold OER activity enhancement that can be achieved with mixed (Ni,Fe)oxyhydroxides (Ni1-xFexOOH) over their pure Ni and Fe parent compounds, resulting in one of the most active currently known OER catalysts in alkaline electrolyte. Operando X-ray absorption spectroscopy (XAS) using high energy resolution fluorescence detection (HERFD) reveals that Fe3+ in Ni1-xFexOOH occupies octahedral sites with unusually short Fe-O bond distances, induced by edge-sharing with surrounding [NiO6] octahedra. Using computational methods, we establish that this structural motif results in near optimal adsorption energies of OER intermediates and low overpotentials at Fe sites. By contrast, Ni sites in Ni1-xFexOOH are not active sites for the oxidation of water.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2153, "Times Cited, All Databases": 2270, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 28", "Publication Year": 2015, "Volume": 137, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1305, "End Page": 1313, "Article Number": null, "DOI": "10.1021/ja511559d", "DOI Link": "http://dx.doi.org/10.1021/ja511559d", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000348690100042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rodenas, T; Luz, I; Prieto, G; Seoane, B; Miro, H; Corma, A; Kapteijn, F; Xamena, FXLI; Gascon, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rodenas, Tania; Luz, Ignacio; Prieto, Gonzalo; Seoane, Beatriz; Miro, Hozanna; Corma, Avelino; Kapteijn, Freek; Llabres i Xamena, Francesc X.; Gascon, Jorge", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal-organic framework nullosheets in polymer composite materials for gas separation", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Composites incorporating two-dimensional nullostructures within polymeric matrices have potential as functional components for several technologies, including gas separation. Prospectively, employing metal-organic frameworks (MOFs) as versatile nullofillers would notably broaden the scope of functionalities. However, synthesizing MOFs in the form of freestanding nullosheets has proved challenging. We present a bottom-up synthesis strategy for dispersible copper 1,4-benzenedicarboxylate MOF lamellae of micrometre lateral dimensions and nullometre thickness. Incorporating MOF nullosheets into polymer matrices endows the resultant composites with outstanding CO2 separation performance from CO2/CH4 gas mixtures, together with an unusual and highly desired increase in the separation selectivity with pressure. As revealed by tomographic focused ion beam scanning electron microscopy, the unique separation behaviour stems from a superior occupation of the membrane cross-section by the MOF nullosheets as compared with isotropic crystals, which improves the efficiency of molecular discrimination and eliminates unselective permeation pathways. This approach opens the door to ultrathin MOF-polymer composites for various applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1787, "Times Cited, All Databases": 1899, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2015, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 48, "End Page": 55, "Article Number": null, "DOI": "10.1038/NMAT4113", "DOI Link": "http://dx.doi.org/10.1038/NMAT4113", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000346430100013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cho, HC; Jeong, SH; Park, MH; Kim, YH; Wolf, C; Lee, CL; Heo, JH; Sadhanala, A; Myoung, N; Yoo, S; Im, SH; Friend, RH; Lee, TW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cho, Himchan; Jeong, Su-Hun; Park, Min-Ho; Kim, Young-Hoon; Wolf, Christoph; Lee, Chang-Lyoul; Heo, Jin Hyuck; Sadhanala, Aditya; Myoung, NoSoung; Yoo, Seunghyup; Im, Sang Hyuk; Friend, Richard H.; Lee, Tae-Woo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Overcoming the electroluminescence efficiency limitations of perovskite light-emitting diodes", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic-inorganic hybrid perovskites are emerging low-cost emitters with very high color purity, but their low luminescent efficiency is a critical drawback. We boosted the current efficiency (CE) of perovskite light-emitting diodes with a simple bilayer structure to 42.9 candela per ampere, similar to the CE of phosphorescent organic light-emitting diodes, with two modifications: We prevented the formation of metallic lead (Pb) atoms that cause strong exciton quenching through a small increase in methylammonium bromide (MABr) molar proportion, and we spatially confined the exciton in uniform MAPbBr3 nullograins (average diameter = 99.7 nullometers) formed by a nullocrystal pinning process and concomitant reduction of exciton diffusion length to 67 nullometers. These changes caused substantial increases in steady-state photoluminescence intensity and efficiency of MAPbBr(3) nullograin layers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2512, "Times Cited, All Databases": 2659, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 4", "Publication Year": 2015, "Volume": 350, "Issue": 6265, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1222, "End Page": 1225, "Article Number": null, "DOI": "10.1126/science.aad1818", "DOI Link": "http://dx.doi.org/10.1126/science.aad1818", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000365700500069", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Weng, HM; Fang, C; Fang, Z; Bernevig, BA; Dai, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Weng, Hongming; Fang, Chen; Fang, Zhong; Bernevig, B. Andrei; Dai, Xi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Weyl Semimetal Phase in Noncentrosymmetric Transition-Metal Monophosphides", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Based on first-principle calculations, we show that a family of nonmagnetic materials including TaAs, TaP, NbAs, and NbP are Weyl semimetals (WSM) without inversion centers. We find twelve pairs of Weyl points in the whole Brillouin zone (BZ) for each of them. In the absence of spin-orbit coupling (SOC), band inversions in mirror-invariant planes lead to gapless nodal rings in the energy-momentum dispersion. The strong SOC in these materials then opens full gaps in the mirror planes, generating nonzero mirror Chern numbers and Weyl points off the mirror planes. The resulting surface-state Fermi arc structures on both (001) and (100) surfaces are also obtained, and they show interesting shapes, pointing to fascinating playgrounds for future experimental studies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1901, "Times Cited, All Databases": 2042, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 17", "Publication Year": 2015, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11029, "DOI": "10.1103/PhysRevX.5.011029", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.5.011029", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000351507700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Drozdov, AP; Eremets, MI; Troyan, IA; Ksenofontov, V; Shylin, SI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Drozdov, A. P.; Eremets, M. I.; Troyan, I. A.; Ksenofontov, V.; Shylin, S. I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Conventional superconductivity at 203 kelvin at high pressures in the sulfur hydride system", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A superconductor is a material that can conduct electricity without resistance below a superconducting transition temperature, T-c. The highest T-c that has been achieved to date is in the copper oxide system(1): 133 kelvin at ambient pressure(2) and 164 kelvin at high pressures(3). As the nature of superconductivity in these materials is still not fully understood (they are not conventional superconductors), the prospects for achieving still higher transition temperatures by this route are not clear. In contrast, the Bardeen-Cooper-Schrieffer theory of conventional superconductivity gives a guide for achieving high T-c with no theoretical upper bound-all that is needed is a favourable combination of high-frequency phonons, strong electron-phonon coupling, and a high density of states(4). These conditions can in principle be fulfilled for metallic hydrogen and covalent compounds dominated by hydrogen(5,6), as hydrogen atoms provide the necessary high-frequency phonon modes as well as the strong electron-phonon coupling. Numerous calculations support this idea and have predicted transition temperatures in the range 50-235 kelvin for many hydrides(7), but only a moderate T-c of 17 kelvin has been observed experimentally(8). Here we investigate sulfur hydride(9), where a T-c of 80 kelvin has been predicted(10). We find that this system transforms to a metal at a pressure of approximately 90 gigapascals. On cooling, we see signatures of superconductivity: a sharp drop of the resistivity to zero and a decrease of the transition temperature with magnetic field, with magnetic susceptibility measurements confirming a T-c of 203 kelvin. Moreover, a pronounced isotope shift of T-c in sulfur deuteride is suggestive of an electron-phonon mechanism of superconductivity that is consistent with the Bardeen-Cooper-Schrieffer scenario. We argue that the phase responsible for high-T-c superconductivity in this system is likely to be H3S, formed from H2S by decomposition under pressure. These findings raise hope for the prospects for achieving room-temperature superconductivity in other hydrogen-based materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1830, "Times Cited, All Databases": 1999, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 3", "Publication Year": 2015, "Volume": 525, "Issue": 7567, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 73, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature14964", "DOI Link": "http://dx.doi.org/10.1038/nature14964", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000360594100027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lv, BQ; Weng, HM; Fu, BB; Wang, XP; Miao, H; Ma, J; Richard, P; Huang, XC; Zhao, LX; Chen, GF; Fang, Z; Dai, X; Qian, T; Ding, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lv, B. Q.; Weng, H. M.; Fu, B. B.; Wang, X. P.; Miao, H.; Ma, J.; Richard, P.; Huang, X. C.; Zhao, L. X.; Chen, G. F.; Fang, Z.; Dai, X.; Qian, T.; Ding, H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Experimental Discovery of Weyl Semimetal TaAs", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Weyl semimetals are a class of materials that can be regarded as three-dimensional analogs of graphene upon breaking time-reversal or inversion symmetry. Electrons in a Weyl semimetal behave as Weyl fermions, which have many exotic properties, such as chiral anomaly and magnetic monopoles in the crystal momentum space. The surface state of a Weyl semimetal displays pairs of entangled Fermi arcs at two opposite surfaces. However, the existence of Weyl semimetals has not yet been proved experimentally. Here, we report the experimental realization of a Weyl semimetal in TaAs by observing Fermi arcs formed by its surface states using angle-resolved photoemission spectroscopy. Our first-principles calculations, which match remarkably well with the experimental results, further confirm that TaAs is a Weyl semimetal.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2287, "Times Cited, All Databases": 2423, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 31", "Publication Year": 2015, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 31013, "DOI": "10.1103/PhysRevX.5.031013", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.5.031013", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358858300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, W; Wu, YZ; Yue, YF; Liu, J; Zhang, WJ; Yang, XD; Chen, H; Bi, EB; Ashraful, I; Grätzel, M; Han, LY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Wei; Wu, Yongzhen; Yue, Youfeng; Liu, Jian; Zhang, Wenjun; Yang, Xudong; Chen, Han; Bi, Enbing; Ashraful, Islam; Graetzel, Michael; Han, Liyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient and stable large-area perovskite solar cells with inorganic charge extraction layers", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The recent dramatic rise in power conversion efficiencies (PCEs) of perovskite solar cells (PSCs) has triggered intense research worldwide. However, high PCE values have often been reached with poor stability at an illuminated area of typically less than 0.1 square centimeter. We used heavily doped inorganic charge extraction layers in planar PSCs to achieve very rapid carrier extraction, even with 10- to 20-nullometer-thick layers, avoiding pinholes and eliminating local structural defects over large areas. The robust inorganic nature of the layers allowed for the fabrication of PSCs with an aperture area >1 square centimeter that have a PCE >15%, as certified by an accredited photovoltaic calibration laboratory. Hysteresis in the current-voltage characteristics was eliminated; the PSCs were stable, with >90% of the initial PCE remaining after 1000 hours of light soaking.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2031, "Times Cited, All Databases": 2126, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 20", "Publication Year": 2015, "Volume": 350, "Issue": 6263, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 944, "End Page": 948, "Article Number": null, "DOI": "10.1126/science.aad1015", "DOI Link": "http://dx.doi.org/10.1126/science.aad1015", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364955200041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hoke, ET; Slotcavage, DJ; Dohner, ER; Bowring, AR; Karunadasa, HI; McGehee, MD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hoke, Eric T.; Slotcavage, Daniel J.; Dohner, Emma R.; Bowring, Andrea R.; Karunadasa, Hemamala I.; McGehee, Michael D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reversible photo-induced trap formation in mixed-halide hybrid perovskites for photovoltaics", "Source Title": "CHEMICAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report on reversible, light-induced transformations in (CH3NH3) Pb(BrxI1-x) 3. Photoluminescence (PL) spectra of these perovskites develop a new, red-shifted peak at 1.68 eV that grows in intensity under constant, 1-sun illumination in less than a minute. This is accompanied by an increase in sub-bandgap absorption at similar to 1.7 eV, indicating the formation of luminescent trap states. Light soaking causes a splitting of X-ray diffraction (XRD) peaks, suggesting segregation into two crystalline phases. Surprisingly, these photo-induced changes are fully reversible; the XRD patterns and the PL and absorption spectra revert to their initial states after the materials are left for a few minutes in the dark. We speculate that photoexcitation may cause halide segregation into iodide-rich minority and bromide-enriched majority domains, the former acting as a recombination center trap. This instability may limit achievable voltages from some mixed-halide perovskite solar cells and could have implications for the photostability of halide perovskites used in optoelectronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1783, "Times Cited, All Databases": 1947, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 6, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 613, "End Page": 617, "Article Number": null, "DOI": "10.1039/c4sc03141e", "DOI Link": "http://dx.doi.org/10.1039/c4sc03141e", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345901600072", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, WY; Yao, HB; Yan, K; Zheng, GY; Liang, Z; Chiang, YM; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Weiyang; Yao, Hongbin; Yan, Kai; Zheng, Guangyuan; Liang, Zheng; Chiang, Yet-Ming; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The synergetic effect of lithium polysulfide and lithium nitrate to prevent lithium dendrite growth", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium metal has shown great promise as an anode material for high-energy storage systems, owing to its high theoretical specific capacity and low negative electrochemical potential. Unfortunately, uncontrolled dendritic and mossy lithium growth, as well as electrolyte decomposition inherent in lithium metal-based batteries, cause safety issues and low Coulombic efficiency. Here we demonstrate that the growth of lithium dendrites can be suppressed by exploiting the reaction between lithium and lithium polysulfide, which has long been considered as a critical flaw in lithium-sulfur batteries. We show that a stable and uniform solid electrolyte interphase layer is formed due to a synergetic effect of both lithium polysulfide and lithium nitrate as additives in ether-based electrolyte, preventing dendrite growth and minimizing electrolyte decomposition. Our findings allow for re-evaluation of the reactions regarding lithium polysulfide, lithium nitrate and lithium metal, and provide insights into solving the problems associated with lithium metal anodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1668, "Times Cited, All Databases": 1813, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7436, "DOI": "10.1038/ncomms8436", "DOI Link": "http://dx.doi.org/10.1038/ncomms8436", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357176700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, SI; Lee, KH; Mun, HA; Kim, HS; Hwang, SW; Roh, JW; Yang, DJ; Shin, WH; Li, XS; Lee, YH; Snyder, GJ; Kim, SW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Sang Il; Lee, Kyu Hyoung; Mun, Hyeon A.; Kim, Hyun Sik; Hwang, Sung Woo; Roh, Jong Wook; Yang, Dae Jin; Shin, Weon Ho; Li, Xiang Shu; Lee, Young Hee; Snyder, G. Jeffrey; Kim, Sung Wng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dense dislocation arrays embedded in grain boundaries for high-performance bulk thermoelectrics", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The widespread use of thermoelectric technology is constrained by a relatively low conversion efficiency of the bulk alloys, which is evaluated in terms of a dimensionless figure of merit (zT). The zT of bulk alloys can be improved by reducing lattice thermal conductivity through grain boundary and point-defect scattering, which target low-and high-frequency phonons. Dense dislocation arrays formed at low-energy grain boundaries by liquid-phase compaction in Bi0.5Sb1.5Te3 (bismuth antimony telluride) effectively scatter midfrequency phonons, leading to a substantially lower lattice thermal conductivity. Full-spectrum phonon scattering with minimal charge-carrier scattering dramatically improved the zT to 1.86 +/- 0.15 at 320 kelvin (K). Further, a thermoelectric cooler confirmed the performance with a maximum temperature difference of 81 K, which is much higher than current commercial Peltier cooling devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1702, "Times Cited, All Databases": 1788, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 3", "Publication Year": 2015, "Volume": 348, "Issue": 6230, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 109, "End Page": 114, "Article Number": null, "DOI": "10.1126/science.aaa4166", "DOI Link": "http://dx.doi.org/10.1126/science.aaa4166", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352079500037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, TQ; Chen, IW; Liu, FX; Yang, CY; Bi, H; Xu, FF; Huang, FQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Tianquan; Chen, I-Wei; Liu, Fengxin; Yang, Chongyin; Bi, Hui; Xu, Fangfang; Huang, Fuqiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nitrogen-doped mesoporous carbon of extraordinary capacitance for electrochemical energy storage", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon-based supercapacitors can provide high electrical power, but they do not have sufficient energy density to directly compete with batteries. We found that a nitrogen-doped ordered mesoporous few-layer carbon has a capacitance of 855 farads per gram in aqueous electrolytes and can be bipolarly charged or discharged at a fast, carbon-like speed. The improvement mostly stems from robust redox reactions at nitrogen-associated defects that transform inert graphene-like layered carbon into an electrochemically active substance without affecting its electric conductivity. These bipolar aqueous-electrolyte electrochemical cells offer power densities and lifetimes similar to those of carbon-based supercapacitors and can store a specific energy of 41 watt-hours per kilogram (19.5 watt-hours per liter).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1835, "Times Cited, All Databases": 1899, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 18", "Publication Year": 2015, "Volume": 350, "Issue": 6267, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1508, "End Page": 1513, "Article Number": null, "DOI": "10.1126/science.aab3798", "DOI Link": "http://dx.doi.org/10.1126/science.aab3798", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000366591100054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, XQ; Zhao, ZP; Cao, L; Chen, Y; Zhu, EB; Lin, ZY; Li, MF; Yan, AM; Zettl, A; Wang, YM; Duan, XF; Mueller, T; Huang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Xiaoqing; Zhao, Zipeng; Cao, Liang; Chen, Yu; Zhu, Enbo; Lin, Zhaoyang; Li, Mufan; Yan, Aiming; Zettl, Alex; Wang, Y. Morris; Duan, Xiangfeng; Mueller, Tim; Huang, Yu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-performance transition metal-doped Pt3Ni octahedra for oxygen reduction reaction", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bimetallic platinum-nickel (Pt-Ni) nullostructures represent an emerging class of electrocatalysts for oxygen reduction reaction (ORR) in fuel cells, but practical applications have been limited by catalytic activity and durability. We surface-doped Pt3Ni octahedra supported on carbon with transition metals, termed M-Pt3Ni/C, where M is vanadium, chromium, manganese, iron, cobalt, molybdenum (Mo), tungsten, or rhenium. The Mo-Pt3Ni/C showed the best ORR performance, with a specific activity of 10.3 mA/cm(2) and mass activity of 6.98 A/mg(Pt), which are 81- and 73-fold enhancements compared with the commercial Pt/C catalyst (0.127 mA/cm(2) and 0.096 A/mg(Pt)). Theoretical calculations suggest that Mo prefers subsurface positions near the particle edges in vacuum and surface vertex/edge sites in oxidizing conditions, where it enhances both the performance and the stability of the Pt3Ni catalyst.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1665, "Times Cited, All Databases": 1783, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 12", "Publication Year": 2015, "Volume": 348, "Issue": 6240, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1230, "End Page": 1234, "Article Number": null, "DOI": "10.1126/science.aaa8765", "DOI Link": "http://dx.doi.org/10.1126/science.aaa8765", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000356011500048", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Burke, MS; Kast, MG; Trotochaud, L; Smith, AM; Boettcher, SW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Burke, Michaela S.; Kast, Matthew G.; Trotochaud, Lena; Smith, Adam M.; Boettcher, Shannon W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cobalt-Iron (Oxy)hydroxide Oxygen Evolution Electrocatalysts: The Role of Structure and Composition on Activity, Stability, and Mechanism", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cobalt oxides and (oxy)hydroxides have been widely studied as electrocatalysts for the oxygen evolution reaction (OER). For related Ni-based materials, the addition of Fe dramatically enhances OER activity. The role of Fe in Co-based materials is not well-documented. We show that the intrinsic OER activity of Co1-xFex(OOH) is similar to 100-fold higher for x approximate to 0.6-0.7 than for x = 0 on a per-metal turnover frequency basis. Fe-free CoOOH absorbs Fe from electrolyte impurities if the electrolyte is not rigorously purified. Fe incorporation and increased activity correlate with an anodic shift in the nominally Co2+/3+ redox wave, indicating strong electronic interactions between the two elements and likely substitutional doping of Fe for Co. In situ electrical measurements show that Co1-xFex(OOH) is conductive under OER conditions (similar to 0.7-4 mS cm(-1) at similar to 300 mV overpotential), but that FeOOH is an insulator with measurable conductivity (2.2 x 10(-2) mS cm(-1)) only at high overpotentials >400 mV. The apparent OER activity of FeOOH is thus limited by low conductivity. Microbalance measurements show that films with x >= 0.54 (i.e., Fe-rich) dissolve in 1 M KOH electrolyte under OER conditions. For x < 0.54, the films appear chemically stable, but the OER activity decreases by 16-62% over 2 h, likely due to conversion into denser, oxide-like phases. We thus hypothesize that Fe is the most-active site in the catalyst, while CoOOH primarily provides a conductive, high-surface area, chemically stabilizing host. These results are important as Fe-containing Co- and Ni-(oxy)hydroxides are the fastest OER catalysts known.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1655, "Times Cited, All Databases": 1743, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 18", "Publication Year": 2015, "Volume": 137, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3638, "End Page": 3648, "Article Number": null, "DOI": "10.1021/jacs.5b00281", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b00281", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000351420800034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Anasori, B; Xie, Y; Beidaghi, M; Lu, J; Hosler, BC; Hultman, L; Kent, PRC; Gogotsi, Y; Barsoum, MW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Anasori, Babak; Xie, Yu; Beidaghi, Majid; Lu, Jun; Hosler, Brian C.; Hultman, Lars; Kent, Paul R. C.; Gogotsi, Yury; Barsoum, Michel W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-Dimensional, Ordered, Double Transition Metals Carbides (MXenes)", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The higher the chemical diversity and structural complexity of two-dimensional (2D) materials, the higher the likelihood they possess unique and useful properties. Herein, density functional theory (DFT) is used to predict the existence of two new families of 2D ordered, carbides (MXenes), M'M-2 '' C-2 and M'M-2 '' C-2(3), where M' and M '' are two different early transition metals. In these solids, M' layers sandwich M carbide layers. By synthesizing Mo2TiC2Tx, Mo2Ti2C3Tx, and Cr2TiC2Tx (where T is a surface termination), we validated the DFT predictions. Since the Mo and Cr atoms are on the outside, they control the 2D flakes' chemical and electrochemical properties. The latter was proven by showing quite different electrochemical behavior of Mo2TiC2Tx and Ti3C2Tx. This work further expands the family of 2D materials, offering additional choices of structures, chemistries, and ultimately useful properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1476, "Times Cited, All Databases": 1593, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 9, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9507, "End Page": 9516, "Article Number": null, "DOI": "10.1021/acsnullo.5b03591", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.5b03591", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363915300009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Withers, F; Del Pozo-Zamudio, O; Mishchenko, A; Rooney, AP; Gholinia, A; Watanabe, K; Taniguchi, T; Haigh, SJ; Geim, AK; Tartakovskii, AI; Novoselov, KS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Withers, F.; Del Pozo-Zamudio, O.; Mishchenko, A.; Rooney, A. P.; Gholinia, A.; Watanabe, K.; Taniguchi, T.; Haigh, S. J.; Geim, A. K.; Tartakovskii, A. I.; Novoselov, K. S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Light-emitting diodes by band-structure engineering in van der Waals heterostructures", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The advent of graphene and related 2D materials1,2 has recently led to a new technology: heterostructures based on these atomically thin crystals(3). The paradigm proved itself extremely versatile and led to rapid demonstration of tunnelling diodes with negative differential resistance(4), tunnelling transistors(5), photovoltaic devices(6,7) and so on. Here, we take the complexity and functionality of such van der Waals heterostructures to the next level by introducing quantum wells (QWs) engineered with one atomic plane precision. We describe light-emitting diodes (LEDs) made by stacking metallic graphene, insulating hexagonal boron nitride and various semiconducting monolayers into complex but carefully designed sequences. Our first devices already exhibit an extrinsic quantum efficiency of nearly 10% and the emission can be tuned over a wide range of frequencies by appropriately choosing and combining 2D semiconductors (monolayers of transition metal dichalcogenides). By preparing the heterostructures on elastic and transparent substrates, we show that they can also provide the basis for flexible and semi-transparent electronics. The range of functionalities for the demonstrated heterostructures is expected to grow further on increasing the number of available 2D crystals and improving their electronic quality.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1407, "Times Cited, All Databases": 1559, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2015, "Volume": 14, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 301, "End Page": 306, "Article Number": null, "DOI": "10.1038/nmat4205", "DOI Link": "http://dx.doi.org/10.1038/nmat4205", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000350136400017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Eperon, GE; Paternò, GM; Sutton, RJ; Zampetti, A; Haghighirad, AA; Cacialli, F; Snaith, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Eperon, Giles E.; Paterno, Giuseppe M.; Sutton, Rebecca J.; Zampetti, Andrea; Haghighirad, Amir Abbas; Cacialli, Franco; Snaith, Henry J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Inorganic caesium lead iodide perovskite solar cells", "Source Title": "JOURNAL OF MATERIALS CHEMISTRY A", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The vast majority of perovskite solar cell research has focused on organic-inorganic lead trihalide perovskites. Herein, we present working inorganic CsPbI3 perovskite solar cells for the first time. CsPbI3 normally resides in a yellow non-perovskite phase at room temperature, but by careful processing control and development of a low-temperature phase transition route we have stabilised the material in the black perovskite phase at room temperature. As such, we have fabricated solar cell devices in a variety of architectures, with current-voltage curve measured efficiency up to 2.9% for a planar heterojunction architecture, and stabilised power conversion efficiency of 1.7%. The well-functioning planar junction devices demonstrate long-range electron and hole transport in this material. Importantly, this work identifies that the organic cation is not essential, but simply a convenience for forming lead triiodide perovskites with good photovoltaic properties. We additionally observe significant rate-dependent current-voltage hysteresis in CsPbI3 devices, despite the absence of the organic polar molecule previously thought to be a candidate for inducing hysteresis via ferroelectric polarisation. Due to its space group, CsPbI3 cannot be a ferroelectric material, and thus we can conclude that ferroelectricity is not required to explain current-voltage hysteresis in perovskite solar cells. Our report of working inorganic perovskite solar cells paves the way for further developments likely to lead to much more thermally stable perovskite solar cells and other optoelectronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1534, "Times Cited, All Databases": 1626, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 3, "Issue": 39, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 19688, "End Page": 19695, "Article Number": null, "DOI": "10.1039/c5ta06398a", "DOI Link": "http://dx.doi.org/10.1039/c5ta06398a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000362041300009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fei, HL; Dong, JC; Arellano-Jiménez, MJ; Ye, GL; Kim, ND; Samuel, ELG; Peng, ZW; Zhu, Z; Qin, F; Bao, JM; Yacaman, MJ; Ajayan, PM; Chen, DL; Tour, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fei, Huilong; Dong, Juncai; Arellano-Jimenez, M. Josefina; Ye, Gonglan; Kim, Nam Dong; Samuel, Errol L. G.; Peng, Zhiwei; Zhu, Zhuan; Qin, Fan; Bao, Jiming; Yacaman, Miguel Jose; Ajayan, Pulickel M.; Chen, Dongliang; Tour, James M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomic cobalt on nitrogen-doped graphene for hydrogen generation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Reduction of water to hydrogen through electrocatalysis holds great promise for clean energy, but its large-scale application relies on the development of inexpensive and efficient catalysts to replace precious platinum catalysts. Here we report an electrocatalyst for hydrogen generation based on very small amounts of cobalt dispersed as individual atoms on nitrogen-doped graphene. This catalyst is robust and highly active in aqueous media with very low overpotentials (30 mV). A variety of analytical techniques and electrochemical measurements suggest that the catalytically active sites are associated with the metal centres coordinated to nitrogen. This unusual atomic constitution of supported metals is suggestive of a new approach to preparing extremely efficient single-atom catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1468, "Times Cited, All Databases": 1527, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8668, "DOI": "10.1038/ncomms9668", "DOI Link": "http://dx.doi.org/10.1038/ncomms9668", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364936200011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Vance, ME; Kuiken, T; Vejerano, EP; McGinnis, SP; Hochella, MF; Rejeski, D; Hull, MS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Vance, Marina E.; Kuiken, Todd; Vejerano, Eric P.; McGinnis, Sean P.; Hochella, Michael F., Jr.; Rejeski, David; Hull, Matthew S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullotechnology in the real world: Redeveloping the nullomaterial consumer products inventory", "Source Title": "BEILSTEIN JOURNAL OF nullOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To document the marketing and distribution of nullo-enabled products into the commercial marketplace, the Woodrow Wilson International Center for Scholars and the Project on Emerging nullotechnologies created the nullotechnology Consumer Products Inventory (CPI) in 2005. The objective of this present work is to redevelop the CPI by leading a research effort to increase the usefulness and reliability of this inventory. We created eight new descriptors for consumer products, including information pertaining to the nullomaterials contained in each product. The project was motivated by the recognition that a diverse group of stakeholders from academia, industry, and state/ federal government had become highly dependent on the inventory as an important resource and bellweather of the pervasiveness of nullotechnology in society. We interviewed 68 nullotechnology experts to assess key information needs. Their answers guided inventory modifications by providing a clear conceptual framework best suited for user expectations. The revised inventory was released in October 2013. It currently lists 1814 consumer products from 622 companies in 32 countries. The Health and Fitness category contains the most products (762, or 42% of the total). Silver is the most frequently used nullomaterial (435 products, or 24%); however, 49% of the products (889) included in the CPI do not provide the composition of the nullomaterial used in them. About 29% of the CPI (528 products) contain nullomaterials suspended in a variety of liquid media and dermal contact is the most likely exposure scenario from their use. The majority (1288 products, or 71%) of the products do not present enough supporting information to corroborate the claim that nullomaterials are used. The modified CPI has enabled crowdsourcing capabilities, which allow users to suggest edits to any entry and permits researchers to upload new findings ranging from human and environmental exposure data to complete life cycle assessments. There are inherent limitations to this type of database, but these modifications to the inventory addressed the majority of criticisms raised in published literature and in surveys of nullotechnology stakeholders and experts. The development of standardized methods and metrics for nullomaterial characterization and labelling in consumer products can lead to greater understanding between the key stakeholders in nullotechnology, especially consumers, researchers, regulators, and industry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1345, "Times Cited, All Databases": 1533, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 21", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1769, "End Page": 1780, "Article Number": null, "DOI": "10.3762/bjnullo.6.181", "DOI Link": "http://dx.doi.org/10.3762/bjnullo.6.181", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000359834400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, XC; Zhao, LX; Long, YJ; Wang, PP; Chen, D; Yang, ZH; Liang, H; Xue, MQ; Weng, HM; Fang, Z; Dai, X; Chen, GF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Xiaochun; Zhao, Lingxiao; Long, Yujia; Wang, Peipei; Chen, Dong; Yang, Zhanhai; Liang, Hui; Xue, Mianqi; Weng, Hongming; Fang, Zhong; Dai, Xi; Chen, Genfu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of the Chiral-Anomaly-Induced Negative Magnetoresistance in 3D Weyl Semimetal TaAs", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Weyl semimetal is the three-dimensional analog of graphene. According to quantum field theory, the appearance of Weyl points near the Fermi level will cause novel transport phenomena related to chiral anomaly. In the present paper, we report the experimental evidence for the long-anticipated negative magnetoresistance generated by the chiral anomaly in a newly predicted time-reversal-invariant Weyl semimetal material TaAs. Clear Shubnikov de Haas (SdH) oscillations have been detected starting from a very weak magnetic field. Analysis of the SdH peaks gives the Berry phase accumulated along the cyclotron orbits as pi, indicating the existence of Weyl points.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1465, "Times Cited, All Databases": 1568, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 24", "Publication Year": 2015, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 31023, "DOI": "10.1103/PhysRevX.5.031023", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.5.031023", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000359947000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, XL; Yang, MX; Yuan, FP; Wu, GL; Wei, YJ; Huang, XX; Zhu, YT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Xiaolei; Yang, Muxin; Yuan, Fuping; Wu, Guilin; Wei, Yujie; Huang, Xiaoxu; Zhu, Yuntian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Heterogeneous lamella structure unites ultrafine-grain strength with coarse-grain ductility", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Grain refinement can make conventional metals several times stronger, but this comes at dramatic loss of ductility. Here we report a heterogeneous lamella structure in Ti produced by asymmetric rolling and partial recrystallization that can produce an unprecedented property combination: as strong as ultrafine-grained metal and at the same time as ductile as conventional coarse-grained metal. It also has higher strain hardening than coarse-grained Ti, which was hitherto believed impossible. The heterogeneous lamella structure is characterized with soft micrograined lamellae embedded in hard ultrafine-grained lamella matrix. The unusual high strength is obtained with the assistance of high back stress developed from heterogeneous yielding, whereas the high ductility is attributed to back-stress hardening and dislocation hardening. The process discovered here is amenable to large-scale industrial production at low cost, and might be applicable to other metal systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1471, "Times Cited, All Databases": 1557, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 24", "Publication Year": 2015, "Volume": 112, "Issue": 47, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14501, "End Page": 14505, "Article Number": null, "DOI": "10.1073/pnas.1517193112", "DOI Link": "http://dx.doi.org/10.1073/pnas.1517193112", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000365173100046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Saidaminov, MI; Abdelhady, AL; Murali, B; Alarousu, E; Burlakov, VM; Peng, W; Dursun, I; Wang, LF; He, Y; Maculan, G; Goriely, A; Wu, T; Mohammed, OF; Bakr, OM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Saidaminov, Makhsud I.; Abdelhady, Ahmed L.; Murali, Banavoth; Alarousu, Erkki; Burlakov, Victor M.; Peng, Wei; Dursun, Ibrahim; Wang, Lingfei; He, Yao; Maculan, Giacomo; Goriely, Alain; Wu, Tom; Mohammed, Omar F.; Bakr, Osman M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-quality bulk hybrid perovskite single crystals within minutes by inverse temperature crystallization", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single crystals of methylammonium lead trihalide perovskites (MAPbX(3); MA = CH3NH3+, X = Br- or I-) have shown remarkably low trap density and charge transport properties; however, growth of such high-quality semiconductors is a time-consuming process. Here we present a rapid crystal growth process to obtain MAPbX(3) single crystals, an order of magnitude faster than previous reports. The process is based on our observation of the substantial decrease of MAPbX(3) solubility, in certain solvents, at elevated temperatures. The crystals can be both size- and shape-controlled by manipulating the different crystallization parameters. Despite the rapidity of the method, the grown crystals exhibit transport properties and trap densities comparable to the highest quality MAPbX(3) reported to date. The phenomenon of inverse or retrograde solubility and its correlated inverse temperature crystallization strategy present a major step forward for advancing the field on perovskite crystallization.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1605, "Times Cited, All Databases": 1720, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7586, "DOI": "10.1038/ncomms8586", "DOI Link": "http://dx.doi.org/10.1038/ncomms8586", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358855800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, YZ; He, XF; Mo, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Yizhou; He, Xingfeng; Mo, Yifei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Origin of Outstanding Stability in the Lithium Solid Electrolyte Materials: Insights from Thermodynamic Analyses Based on First-Principles Calculations", "Source Title": "ACS APPLIED MATERIALS & INTERFACES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "First-principles calculations were performed to investigate the electrochemical stability of lithium solid electrolyte materials in all-solid-state Li-ion batteries. The common solid electrolytes were found to have a limited electrochemical window. Our results suggest that the outstanding stability of the solid electrolyte materials is not thermodynamically intrinsic but is originated from kinetic stabilizations. The sluggish kinetics of the decomposition reactions cause a high overpotential leading to a nominally wide electrochemical window observed in many experiments. The decomposition products, similar to the solid-electrolyte-interphases, mitigate the extreme chemical potential from the electrodes and protect the solid electrolyte from further decompositions. With the aid of the first-principles calculations, we revealed the passivation mechanism of these decomposition interphases and quantified the extensions of the electrochemical window from the interphases. We also found that the artificial coating layers applied at the solid electrolyte and electrode interfaces have a similar effect of passivating the solid electrolyte. Our newly gained understanding provided general principles for developing solid electrolyte materials with enhanced stability and for engineering interfaces in all-solid-state Li-ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1461, "Times Cited, All Databases": 1607, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 28", "Publication Year": 2015, "Volume": 7, "Issue": 42, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 23685, "End Page": 23693, "Article Number": null, "DOI": "10.1021/acsami.5b07517", "DOI Link": "http://dx.doi.org/10.1021/acsami.5b07517", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363994700039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, HS; Gibbs, ZM; Tang, YL; Wang, H; Snyder, GJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Hyun-Sik; Gibbs, Zachary M.; Tang, Yinglu; Wang, Heng; Snyder, G. Jeffrey", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Characterization of Lorenz number with Seebeck coefficient measurement", "Source Title": "APL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In analyzing zT improvements due to lattice thermal conductivity (kappa(L)) reduction, electrical conductivity (sigma) and total thermal conductivity (kappa(Total)) are often used to estimate the electronic component of the thermal conductivity (kappa(E)) and in turn kappa(L) from kappa(L) = similar to kappa(Total) - L sigma T. TheWiedemann-Franz law, kappa(E) = L sigma T, where L is Lorenz number, is widely used to estimate kappa(E) from sigma measurements. It is a common practice to treat L as a universal factor with 2.44 x 10(-8) W Omega K-2 (degenerate limit). However, significant deviations from the degenerate limit (approximately 40% or more for Kane bands) are known to occur for non-degenerate semiconductors where L converges to 1.5 x 10(-8) W Omega K-2 for acoustic phonon scattering. The decrease in L is correlated with an increase in thermopower (absolute value of Seebeck coefficient (S)). Thus, a first order correction to the degenerate limit of L can be based on the measured thermopower, vertical bar S vertical bar, independent of temperature or doping. We propose the equation: L = 1.5 + exp [ -vertical bar S vertical bar/116] (where L is in 10(-8) W Omega K-2 and S in mu V/K) as a satisfactory approximation for L. This equation is accurate within 5% for single parabolic band/acoustic phonon scattering assumption and within 20% for PbSe, PbS, PbTe, Si0.8Ge0.2 where more complexity is introduced, such as non-parabolic Kane bands, multiple bands, and/or alternate scattering mechanisms. The use of this equation for L rather than a constant value (when detailed band structure and scattering mechanism is not known) will significantly improve the estimation of lattice thermal conductivity. (C) 2015 Author(s).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1564, "Times Cited, All Databases": 1632, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2015, "Volume": 3, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 41506, "DOI": "10.1063/1.4908244", "DOI Link": "http://dx.doi.org/10.1063/1.4908244", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353828400013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yakunin, S; Protesescu, L; Krieg, F; Bodnarchuk, MI; Nedelcu, G; Humer, M; De Luca, G; Fiebig, M; Heiss, W; Kovalenko, MV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yakunin, Sergii; Protesescu, Loredana; Krieg, Franziska; Bodnarchuk, Maryna I.; Nedelcu, Georgian; Humer, Markus; De Luca, Gabriele; Fiebig, Manfred; Heiss, Wolfgang; Kovalenko, Maksym V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Low-threshold amplified spontaneous emission and lasing from colloidal nullocrystals of caesium lead halide perovskites", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal halide semiconductors with perovskite crystal structures have recently emerged as highly promising optoelectronic materials. Despite the recent surge of reports on microcrystalline, thin-film and bulk single-crystalline metal halides, very little is known about the photophysics of metal halides in the form of uniform, size-tunable nullocrystals. Here we report low-threshold amplified spontaneous emission and lasing from similar to 10nm monodisperse colloidal nullocrystals of caesium lead halide perovskites CsPbX3 (X = Cl, Br or I, or mixed Cl/Br and Br/I systems). We find that room-temperature optical amplification can be obtained in the entire visible spectral range (440-700 nm) with low pump thresholds down to 5 +/- 1 mu J cm(-2) and high values of modal net gain of at least 450 +/- 30 cm(-1). Two kinds of lasing modes are successfully observed: whispering-gallery-mode lasing using silica microspheres as high-finesse resonators, conformally coated with CsPbX3 nullocrystals and random lasing in films of CsPbX3 nullocrystals.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1310, "Times Cited, All Databases": 1406, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8056, "DOI": "10.1038/ncomms9056", "DOI Link": "http://dx.doi.org/10.1038/ncomms9056", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000360352600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hong, JH; Hu, ZX; Probert, M; Li, K; Lv, DH; Yang, XN; Gu, L; Mao, NN; Feng, QL; Xie, LM; Zhang, J; Wu, DZ; Zhang, ZY; Jin, CH; Ji, W; Zhang, XX; Yuan, J; Zhang, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hong, Jinhua; Hu, Zhixin; Probert, Matt; Li, Kun; Lv, Danhui; Yang, Xinull; Gu, Lin; Mao, nullnull; Feng, Qingliang; Xie, Liming; Zhang, Jin; Wu, Dianzhong; Zhang, Zhiyong; Jin, Chuanhong; Ji, Wei; Zhang, Xixiang; Yuan, Jun; Zhang, Ze", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exploring atomic defects in molybdenum disulphide monolayers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Defects usually play an important role in tailoring various properties of two-dimensional materials. Defects in two-dimensional monolayer molybdenum disulphide may be responsible for large variation of electric and optical properties. Here we present a comprehensive joint experiment-theory investigation of point defects in monolayer molybdenum disulphide prepared by mechanical exfoliation, physical and chemical vapour deposition. Defect species are systematically identified and their concentrations determined by aberration-corrected scanning transmission electron microscopy, and also studied by ab-initio calculation. Defect density up to 3.5 x 10(13) cm(-2) is found and the dominullt category of defects changes from sulphur vacancy in mechanical exfoliation and chemical vapour deposition samples to molybdenum antisite in physical vapour deposition samples. Influence of defects on electronic structure and charge-carrier mobility are predicted by calculation and observed by electric transport measurement. In light of these results, the growth of ultra-high-quality monolayer molybdenum disulphide appears a primary task for the community pursuing high-performance electronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1249, "Times Cited, All Databases": 1361, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6293, "DOI": "10.1038/ncomms7293", "DOI Link": "http://dx.doi.org/10.1038/ncomms7293", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000350289800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hinton, TJ; Jallerat, Q; Palchesko, RN; Park, JH; Grodzicki, MS; Shue, HJ; Ramadan, MH; Hudson, AR; Feinberg, AW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hinton, Thomas J.; Jallerat, Quentin; Palchesko, Rachelle N.; Park, Joon Hyung; Grodzicki, Martin S.; Shue, Hao-Jan; Ramadan, Mohamed H.; Hudson, Andrew R.; Feinberg, Adam W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Three-dimensional printing of complex biological structures by freeform reversible embedding of suspended hydrogels", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We demonstrate the additive manufacturing of complex three-dimensional (3D) biological structures using soft protein and polysaccharide hydrogels that are challenging or impossible to create using traditional fabrication approaches. These structures are built by embedding the printed hydrogel within a secondary hydrogel that serves as a temporary, thermoreversible, and biocompatible support. This process, termed freeform reversible embedding of suspended hydrogels, enables 3D printing of hydrated materials with an elastic modulus <500 kPa including alginate, collagen, and fibrin. Computer-aided design models of 3D optical, computed tomography, and magnetic resonullce imaging data were 3D printed at a resolution of similar to 200 mm and at low cost by leveraging open-source hardware and software tools. Proof-of-concept structures based on femurs, branched coronary arteries, trabeculated embryonic hearts, and human brains were mechanically robust and recreated complex 3D internal and external anatomical architectures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1275, "Times Cited, All Databases": 1521, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 1, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1126/sciadv.1500758", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1500758", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000216598200039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bi, C; Wang, Q; Shao, YC; Yuan, YB; Xiao, ZG; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bi, Cheng; Wang, Qi; Shao, Yuchuan; Yuan, Yongbo; Xiao, Zhengguo; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Non-wetting surface-driven high-aspect-ratio crystalline grain growth for efficient hybrid perovskite solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Large-aspect-ratio grains are needed in polycrystalline thin-film solar cells for reduced charge recombination at grain boundaries; however, the grain size in organolead trihalide perovskite (OTP) films is generally limited by the film thickness. Here we report the growth of OTP grains with high average aspect ratio of 2.3-7.9 on a wide range of non-wetting hole transport layers (HTLs), which increase nucleus spacing by suppressing heterogeneous nucleation and facilitate grain boundary migration in grain growth by imposing less drag force. The reduced grain boundary area and improved crystallinity dramatically reduce the charge recombination in OTP thin films to the level in OTP single crystals. Combining the high work function of several HTLs, a high stabilized device efficiency of 18.3% in low-temperature-processed planar-heterojunction OTP devices under 1 sun illumination is achieved. This simple method in enhancing OTP morphology paves the way for its application in other optoelectronic devices for enhanced performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1462, "Times Cited, All Databases": 1526, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7747, "DOI": "10.1038/ncomms8747", "DOI Link": "http://dx.doi.org/10.1038/ncomms8747", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358858500053", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rivera, P; Schaibley, JR; Jones, AM; Ross, JS; Wu, SF; Aivazian, G; Klement, P; Seyler, K; Clark, G; Ghimire, NJ; Yan, JQ; Mandrus, DG; Yao, W; Xu, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rivera, Pasqual; Schaibley, John R.; Jones, Aaron M.; Ross, Jason S.; Wu, Sanfeng; Aivazian, Grant; Klement, Philip; Seyler, Kyle; Clark, Genevieve; Ghimire, Nirmal J.; Yan, Jiaqiang; Mandrus, D. G.; Yao, Wang; Xu, Xiaodong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of long-lived interlayer excitons in monolayer MoSe2-WSe2 heterostructures", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Van der Waals bound heterostructures constructed with two-dimensional materials, such as graphene, boron nitride and transition metal dichalcogenides, have sparked wide interest in device physics and technologies at the two-dimensional limit. One highly coveted heterostructure is that of differing monolayer transition metal dichalcogenides with type-II band alignment, with bound electrons and holes localized in individual monolayers, that is, interlayer excitons. Here, we report the observation of interlayer excitons in monolayer MoSe2-WSe2 heterostructures by photoluminescence and photoluminescence excitation spectroscopy. We find that their energy and luminescence intensity are highly tunable by an applied vertical gate voltage. Moreover, we measure an interlayer exciton lifetime of similar to 1.8 ns, an order of magnitude longer than intralayer excitons in monolayers. Our work demonstrates optical pumping of interlayer electric polarization, which may provoke further exploration of interlayer exciton condensation, as well as new applications in two-dimensional lasers, light-emitting diodes and photovoltaic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1304, "Times Cited, All Databases": 1433, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6242, "DOI": "10.1038/ncomms7242", "DOI Link": "http://dx.doi.org/10.1038/ncomms7242", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000350202400006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, LH; Hu, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Long-Hua; Hu, Xiao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Scheme for Achieving a Topological Photonic Crystal by Using Dielectric Material", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We derive in the present work topological photonic states purely based on conventional dielectric material by deforming a honeycomb lattice of cylinders into a triangular lattice of cylinder hexagons. The photonic topology is associated with a pseudo-time-reversal (TR) symmetry constituted by the TR symmetry supported in general by Maxwell equations and the C-6 crystal symmetry upon design, which renders the Kramers doubling in the present photonic system. It is shown explicitly for the transverse magnetic mode that the role of pseudospin is played by the angular momentum of the wave function of the out-of-plane electric field. We solve Maxwell equations and demonstrate the new photonic topology by revealing pseudospin-resolved Berry curvatures of photonic bands and helical edge states characterized by Poynting vectors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1271, "Times Cited, All Databases": 1355, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 3", "Publication Year": 2015, "Volume": 114, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 223901, "DOI": "10.1103/PhysRevLett.114.223901", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.114.223901", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000355563000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, CMJ; Fang, RH; Wang, KC; Luk, BT; Thamphiwatana, S; Dehaini, D; Nguyen, P; Angsantikul, P; Wen, CH; Kroll, AV; Carpenter, C; Ramesh, M; Qu, V; Patel, SH; Zhu, J; Shi, W; Hofman, FM; Chen, TC; Gao, WW; Zhang, K; Chien, S; Zhang, LF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Che-Ming J.; Fang, Ronnie H.; Wang, Kuei-Chun; Luk, Brian T.; Thamphiwatana, Soracha; Dehaini, Diana; Phu Nguyen; Angsantikul, Pavimol; Wen, Cindy H.; Kroll, Ashley V.; Carpenter, Cody; Ramesh, Manikantan; Qu, Vivian; Patel, Sherrina H.; Zhu, Jie; Shi, William; Hofman, Florence M.; Chen, Thomas C.; Gao, Weiwei; Zhang, Kang; Chien, Shu; Zhang, Liangfang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nulloparticle biointerfacing by platelet membrane cloaking", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Development of functional nulloparticles can be encumbered by unullticipated material properties and biological events, which can affect nulloparticle effectiveness in complex, physiologically relevant systems(1-3). Despite the advances in bottom-up nulloengineering and surface chemistry, reductionist functionalization approaches remain inadequate in replicating the complex interfaces present in nature and cannot avoid exposure of foreign materials. Here we report on the preparation of polymeric nulloparticles enclosed in the plasma membrane of human platelets, which are a unique population of cellular fragments that adhere to a variety of disease-relevant substrates(4-7). The resulting nulloparticles possess a right-side-out unilamellar membrane coating functionalized with immunomodulatory and adhesion antigens associated with platelets. Compared to uncoated particles, the platelet membrane-cloaked nulloparticles have reduced cellular uptake by macrophage-like cells and lack particle-induced complement activation in autologous human plasma. The cloaked nulloparticles also display platelet-mimicking properties such as selective adhesion to damaged human and rodent vasculatures as well as enhanced binding to platelet-adhering pathogens. In an experimental rat model of coronary restenosis and a mouse model of systemic bacterial infection, docetaxel and vancomycin, respectively, show enhanced therapeutic efficacy when delivered by the platelet-mimetic nulloparticles. The multifaceted biointerfacing enabled by the platelet membrane cloaking method provides a new approach in developing functional nulloparticles for disease-targeted delivery.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1388, "Times Cited, All Databases": 1500, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 1", "Publication Year": 2015, "Volume": 526, "Issue": 7571, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 118, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature15373", "DOI Link": "http://dx.doi.org/10.1038/nature15373", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000362095100045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, JW; Kim, DH; Kim, HS; Seo, SW; Cho, SM; Park, NG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Jin-Wook; Kim, Deok-Hwan; Kim, Hui-Seon; Seo, Seung-Woo; Cho, Sung Min; Park, Nam-Gyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Formamidinium and Cesium Hybridization for Photo- and Moisture-Stable Perovskite Solar Cell", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although power conversion efficiency (PCE) of state-of-the-art perovskite solar cells has already exceeded 20%, photo- and/or moisture instability of organolead halide perovskite have prevented further commercialization. In particular, the underlying weak interaction of organic cations with surrounding iodides due to eight equivalent orientations of the organic cation along the body diagonals in unit cell and chemically non-inertness of organic cation result in photo- and moisture instability of organometal halide perovskite. Here, a perovskite light absorber incorporating organic-inorganic hybrid cation in the A-site of 3D APbI(3) structure with enhanced photo- and moisture stability is reported. A partial substitution of Cs+ for HC(NH2)(2)(+) in HC(NH2)(2)PbI3 perovskite is found to substantially improve photo- and moisture stability along with photovoltaic performance. When 10% of HC(NH2)(2)(+) is replaced by Cs+, photo- and moisture stability of perovskite film are significantly improved, which is attributed to the enhanced interaction between HC(NH2)(2)(+) and iodide due to contraction of cubo-octahedral volume. Moreover, trap density is reduced by one order of magnitude upon incorporation of Cs+, which is responsible for the increased open-circuit voltage and fill factor, eventually leading to enhancement of average PCE from 14.9% to 16.5%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1326, "Times Cited, All Databases": 1357, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 21", "Publication Year": 2015, "Volume": 5, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1501310, "DOI": "10.1002/aenm.201501310", "DOI Link": "http://dx.doi.org/10.1002/aenm.201501310", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363459400010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, HB; Xia, BY; Yu, L; Yu, XY; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Hao Bin; Xia, Bao Yu; Yu, Le; Yu, Xin-Yao; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Porous molybdenum carbide nullo-octahedrons synthesized via confined carburization in metal-organic frameworks for efficient hydrogen production", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical water splitting has been considered as a promising approach to produce clean and sustainable hydrogen fuel. However, the lack of high-performance and low-cost electrocatalysts for hydrogen evolution reaction hinders the large-scale application. As a new class of porous materials with tunable structure and composition, metal-organic frameworks have been considered as promising candidates to synthesize various functional materials. Here we demonstrate a metal-organic frameworks-assisted strategy for synthesizing nullo-structured transition metal carbides based on the confined carburization in metal-organic frameworks matrix. Starting from a compound consisting of copper-based metal-organic frameworks host and molybdenum-based polyoxometalates guest, mesoporous molybdenum carbide nullo-octahedrons composed of ultrafine nullocrystallites are successfully prepared as a proof of concept, which exhibit remarkable electrocatalytic performance for hydrogen production from both acidic and basic solutions. The present study provides some guidelines for the design and synthesis of nullostructured electrocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1227, "Times Cited, All Databases": 1270, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6512, "DOI": "10.1038/ncomms7512", "DOI Link": "http://dx.doi.org/10.1038/ncomms7512", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352720000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, WJ; Upadhyaya, P; Zhang, W; Yu, GQ; Jungfleisch, MB; Fradin, FY; Pearson, JE; Tserkovnyak, Y; Wang, KL; Heinonen, O; te Velthuis, SGE; Hoffmann, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Wanjun; Upadhyaya, Pramey; Zhang, Wei; Yu, Guoqiang; Jungfleisch, M. Benjamin; Fradin, Frank Y.; Pearson, John E.; Tserkovnyak, Yaroslav; Wang, Kang L.; Heinonen, Olle; te Velthuis, Suzanne G. E.; Hoffmann, Axel", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Blowing magnetic skyrmion bubbles", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The formation of soap bubbles from thin films is accompanied by topological transitions. Here we show how a magnetic topological structure, a skyrmion bubble, can be generated in a solid-state system in a similar manner. Using an inhomogeneous in-plane current in a system with broken inversion symmetry, we experimentally blow magnetic skyrmion bubbles from a geometrical constriction. The presence of a spatially divergent spin-orbit torque gives rise to instabilities of the magnetic domain structures that are reminiscent of Rayleigh-Plateau instabilities in fluid flows. We determine a phase diagram for skyrmion formation and reveal the efficient manipulation of these dynamically created skyrmions, including depinning and motion. The demonstrated current-driven transformation from stripe domains to magnetic skyrmion bubbles could lead to progress in skyrmion-based spintronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1212, "Times Cited, All Databases": 1288, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 17", "Publication Year": 2015, "Volume": 349, "Issue": 6245, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 283, "End Page": 286, "Article Number": null, "DOI": "10.1126/science.aaa1442", "DOI Link": "http://dx.doi.org/10.1126/science.aaa1442", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358218600045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dou, LT; Wong, AB; Yu, Y; Lai, ML; Kornienko, N; Eaton, SW; Fu, A; Bischak, CG; Ma, J; Ding, TN; Ginsberg, NS; Wang, LW; Alivisatos, AP; Yang, PD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dou, Letian; Wong, Andrew B.; Yu, Yi; Lai, Minliang; Kornienko, Nikolay; Eaton, Samuel W.; Fu, Anthony; Bischak, Connor G.; Ma, Jie; Ding, Tina; Ginsberg, Naomi S.; Wang, Lin-Wang; Alivisatos, A. Paul; Yang, Peidong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomically thin two-dimensional organic-inorganic hybrid perovskites", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic-inorganic hybrid perovskites, which have proved to be promising semiconductor materials for photovoltaic applications, have been made into atomically thin two-dimensional (2D) sheets. We report the solution-phase growth of single-and few-unit-cell-thick single-crystalline 2D hybrid perovskites of (C4H9NH3)(2)PbBr4 with well-defined square shape and large size. In contrast to other 2D materials, the hybrid perovskite sheets exhibit an unusual structural relaxation, and this structural change leads to a band gap shift as compared to the bulk crystal. The high-quality 2D crystals exhibit efficient photoluminescence, and color tuning could be achieved by changing sheet thickness as well as composition via the synthesis of related materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1166, "Times Cited, All Databases": 1277, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 25", "Publication Year": 2015, "Volume": 349, "Issue": 6255, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1518, "End Page": 1521, "Article Number": null, "DOI": "10.1126/science.aac7660", "DOI Link": "http://dx.doi.org/10.1126/science.aac7660", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000361707000042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, SM; Xu, SY; Belopolski, I; Lee, CC; Chang, GQ; Wang, BK; Alidoust, N; Bian, G; Neupane, M; Zhang, CL; Jia, S; Bansil, A; Lin, H; Hasan, MZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Shin-Ming; Xu, Su-Yang; Belopolski, Ilya; Lee, Chi-Cheng; Chang, Guoqing; Wang, BaoKai; Alidoust, Nasser; Bian, Guang; Neupane, Madhab; Zhang, Chenglong; Jia, Shuang; Bansil, Arun; Lin, Hsin; Hasan, M. Zahid", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Weyl Fermion semimetal with surface Fermi arcs in the transition metal monopnictide TaAs class", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Weyl fermions are massless chiral fermions that play an important role in quantum field theory but have never been observed as fundamental particles. A Weyl semimetal is an unusual crystal that hosts Weyl fermions as quasiparticle excitations and features Fermi arcs on its surface. Such a semimetal not only provides a condensed matter realization of the anomalies in quantum field theories but also demonstrates the topological classification beyond the gapped topological insulators. Here, we identify a topological Weyl semimetal state in the transition metal monopnictide materials class. Our first-principles calculations on TaAs reveal its bulk Weyl fermion cones and surface Fermi arcs. Our results show that in the TaAs-type materials the Weyl semimetal state does not depend on fine-tuning of chemical composition or magnetic order, which opens the door for the experimental realization of Weyl semimetals and Fermi arc surface states in real materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1327, "Times Cited, All Databases": 1432, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7373, "DOI": "10.1038/ncomms8373", "DOI Link": "http://dx.doi.org/10.1038/ncomms8373", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357175300006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, MQ; Ren, CE; Ling, Z; Lukatskaya, MR; Zhang, CF; Van Aken, KL; Barsoum, MW; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Meng-Qiang; Ren, Chang E.; Ling, Zheng; Lukatskaya, Maria R.; Zhang, Chuanfang; Van Aken, Katherine L.; Barsoum, Michel W.; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flexible MXene/Carbon nullotube Composite Paper with High Volumetric Capacitance", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Free-standing and flexible sandwich-like MXene/carbon nullotube (CNT) paper, composed of alternating MXene and CNT layers, is fabricated using a simple filtration method. These sandwich-like papers exhibit high volumetric capacitances, good rate performances, and excellent cycling stability when employed as electrodes in supercapacitors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1194, "Times Cited, All Databases": 1263, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 14", "Publication Year": 2015, "Volume": 27, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 339, "End Page": 345, "Article Number": null, "DOI": "10.1002/adma.201404140", "DOI Link": "http://dx.doi.org/10.1002/adma.201404140", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000347698300024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schuh, B; Mendez-Martin, F; Völker, B; George, EP; Clemens, H; Pippan, R; Hohenwarter, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schuh, B.; Mendez-Martin, F.; Voelker, B.; George, E. P.; Clemens, H.; Pippan, R.; Hohenwarter, A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mechanical properties, microstructure and thermal stability of a nullocrystalline CoCrFeMnNi high-entropy alloy after severe plastic deformation", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An equiatomic CoCrFeMnNi high-entropy alloy (HEA), produced by arc melting and drop casting, was subjected to severe plastic deformation (SPD) using high-pressure torsion. This process induced substantial grain refinement in the coarse-grained casting leading to a grain size of approximately 50 nm. As a result, strength increased significantly to 1950 MPa, and hardness to similar to 520 MV. Analyses using transmission electron microscopy (TEM) and 3-dimensional atom probe tomography (3D-APT) showed that, after SPD, the alloy remained a true single-phase solid solution down to the atomic scale. Subsequent investigations characterized the evolution of mechanical properties and microstructure of this nullocrystalline HEA upon annealing. Isochronal (for 1 h) and isothermal heat treatments were performed followed by microhardness and tensile tests. The isochronal anneals led to a marked hardness increase with a maximum hardness of similar to 630 HV at about 450 degrees C before softening set in at higher temperatures. The isothermal anneals, performed at this peak hardness temperature, revealed an additional hardness rise to a maximum of about 910 MV after 100 h. To clarify this unexpected annealing response, comprehensive microstructural analyses were performed using TEM and 3D-APT. New nullo-scale phases were observed to form in the originally single-phase HEA. After times as short as 5 min at 450 degrees C, a NiMn phase and Cr-rich phase formed. With increasing annealing time, their volume fractions increased and a third phase, FeCo, also formed. It appears that the surfeit of grain boundaries in the nullocrystalline HEA offer many fast diffusion pathways and nucleation sites to facilitate this phase decomposition. The hardness increase, especially for the longer annealing times, can be attributed to these nullo-scaled phases embedded in the HEA matrix. The present results give new valuable insights into the phase stability of single-phase high-entropy alloys as well as the mechanisms controlling the mechanical properties of nullostructured multiphase composites. (C) 2015 Acta Materialia Inc. Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1065, "Times Cited, All Databases": 1124, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2015, "Volume": 96, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 258, "End Page": 268, "Article Number": null, "DOI": "10.1016/j.actamat.2015.06.025", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2015.06.025", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358459900024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, SH; Zhou, J; Wang, Q; Chen, XS; Kawazoe, Y; Jena, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Shunhong; Zhou, Jian; Wang, Qian; Chen, Xiaoshuang; Kawazoe, Yoshiyuki; Jena, Puru", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Penta-graphene: A new carbon allotrope", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A 2D metastable carbon allotrope, penta-graphene, composed entirely of carbon pentagons and resembling the Cairo pentagonal tiling, is proposed. State-of-the-art theoretical calculations confirm that the new carbon polymorph is not only dynamically and mechanically stable, but also can withstand temperatures as high as 1000 K. Due to its unique atomic configuration, penta-graphene has an unusual negative Poisson's ratio and ultrahigh ideal strength that can even outperform graphene. Furthermore, unlike graphene that needs to be functionalized for opening a band gap, penta-graphene possesses an intrinsic quasi-direct band gap as large as 3.25 eV, close to that of ZnO and GaN. Equally important, penta-graphene can be exfoliated from T12-carbon. When rolled up, it can form pentagon-based nullotubes which are semiconducting, regardless of their chirality. When stacked in different patterns, stable 3D twin structures of T12-carbon are generated with band gaps even larger than that of T12-carbon. The versatility of penta-graphene and its derivatives are expected to have broad applications in nulloelectronics and nullomechanics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1253, "Times Cited, All Databases": 1284, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 24", "Publication Year": 2015, "Volume": 112, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2372, "End Page": 2377, "Article Number": null, "DOI": "10.1073/pnas.1416591112", "DOI Link": "http://dx.doi.org/10.1073/pnas.1416591112", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000349911700035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Baena, JPC; Steier, L; Tress, W; Saliba, M; Neutzner, S; Matsui, T; Giordano, F; Jacobsson, TJ; Kandada, ARS; Zakeeruddin, SM; Petrozza, A; Abate, A; Nazeeruddin, MK; Grätzel, M; Hagfeldt, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Baena, Juan Pablo Correa; Steier, Ludmilla; Tress, Wolfgang; Saliba, Michael; Neutzner, Stefanie; Matsui, Taisuke; Giordano, Fabrizio; Jacobsson, T. Jesper; Kandada, Ajay Ram Srimath; Zakeeruddin, Shaik M.; Petrozza, Annamaria; Abate, Antonio; Nazeeruddin, Mohammad Khaja; Graetzel, Michael; Hagfeldt, Anders", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly efficient planar perovskite solar cells through band alignment engineering", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The simplification of perovskite solar cells (PSCs), by replacing the mesoporous electron selective layer (ESL) with a planar one, is advantageous for large-scale manufacturing. PSCs with a planar TiO2 ESL have been demonstrated, but these exhibit unstabilized power conversion efficiencies (PCEs). Herein we show that planar PSCs using TiO2 are inherently limited due to conduction band misalignment and demonstrate, with a variety of characterization techniques, for the first time that SnO2 achieves a barrier-free energetic configuration, obtaining almost hysteresis-free PCEs of over 18% with record high voltages of up to 1.19 V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1064, "Times Cited, All Databases": 1117, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2015, "Volume": 8, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2928, "End Page": 2934, "Article Number": null, "DOI": "10.1039/c5ee02608c", "DOI Link": "http://dx.doi.org/10.1039/c5ee02608c", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000362351700011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Amani, M; Lien, DH; Kiriya, D; Xiao, J; Azcatl, A; Noh, J; Madhvapathy, SR; Addou, R; Santosh, KC; Dubey, M; Cho, K; Wallace, RM; Lee, SC; He, JH; Ager, JW; Zhang, X; Yablonovitch, E; Javey, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Amani, Matin; Lien, Der-Hsien; Kiriya, Daisuke; Xiao, Jun; Azcatl, Angelica; Noh, Jiyoung; Madhvapathy, Surabhi R.; Addou, Rafik; Santosh, K. C.; Dubey, Madan; Cho, Kyeongjae; Wallace, Robert M.; Lee, Si-Chen; He, Jr-Hau; Ager, Joel W., III; Zhang, Xiang; Yablonovitch, Eli; Javey, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Near-unity photoluminescence quantum yield in MoS2", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) transition metal dichalcogenides have emerged as a promising material system for optoelectronic applications, but their primary figure of merit, the room-temperature photoluminescence quantum yield (QY), is extremely low. The prototypical 2D material molybdenum disulfide (MoS2) is reported to have a maximum QY of 0.6%, which indicates a considerable defect density. Herewe report on an air-stable, solution-based chemical treatment by an organic superacid, which uniformly enhances the photoluminescence and minority carrier lifetime of MoS2 monolayers by more than two orders of magnitude. The treatment eliminates defect-mediated nonradiative recombination, thus resulting in a final QY of more than 95%, with a longest-observed lifetime of 10.8 0.6 nulloseconds. Our ability to obtain optoelectronic monolayers with near-perfect properties opens the door for the development of highly efficient light-emitting diodes, lasers, and solar cells based on 2D materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1042, "Times Cited, All Databases": 1188, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 27", "Publication Year": 2015, "Volume": 350, "Issue": 6264, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1065, "End Page": 1068, "Article Number": null, "DOI": "10.1126/science.aad2114", "DOI Link": "http://dx.doi.org/10.1126/science.aad2114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000366422600037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, K; Ricco, R; Doherty, CM; Styles, MJ; Bell, S; Kirby, N; Mudie, S; Haylock, D; Hill, AJ; Doonull, CJ; Falcaro, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Kang; Ricco, Raffaele; Doherty, Cara M.; Styles, Mark J.; Bell, Stephen; Kirby, Nigel; Mudie, Stephen; Haylock, David; Hill, Anita J.; Doonull, Christian J.; Falcaro, Paolo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biomimetic mineralization of metal-organic frameworks as protective coatings for biomacromolecules", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Enhancing the robustness of functional biomacromolecules is a critical challenge in biotechnology, which if addressed would enhance their use in pharmaceuticals, chemical processing and biostorage. Here we report a novel method, inspired by natural biomineralization processes, which provides unprecedented protection of biomacromolecules by encapsulating them within a class of porous materials termed metal-organic frameworks. We show that proteins, enzymes and DNA rapidly induce the formation of protective metal-organic framework coatings under physiological conditions by concentrating the framework building blocks and facilitating crystallization around the biomacromolecules. The resulting biocomposite is stable under conditions that would normally decompose many biological macromolecules. For example, urease and horseradish peroxidase protected within a metal-organic framework shell are found to retain bioactivity after being treated at 80 degrees C and boiled in dimethylformamide (153 degrees C), respectively. This rapid, low-cost biomimetic mineralization process gives rise to new possibilities for the exploitation of biomacromolecules.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1177, "Times Cited, All Databases": 1249, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7240, "DOI": "10.1038/ncomms8240", "DOI Link": "http://dx.doi.org/10.1038/ncomms8240", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357169000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, J; Buin, A; Ip, AH; Li, W; Voznyy, O; Comin, R; Yuan, MJ; Jeon, S; Ning, ZJ; McDowell, JJ; Kanjanaboos, P; Sun, JP; Lan, XZ; Quan, LN; Kim, DH; Hill, IG; Maksymovych, P; Sargent, EH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Jixian; Buin, Andrei; Ip, Alexander H.; Li, Wei; Voznyy, Oleksandr; Comin, Riccardo; Yuan, Mingjian; Jeon, Seokmin; Ning, Zhijun; McDowell, Jeffrey J.; Kanjanaboos, Pongsakorn; Sun, Jon-Paul; Lan, Xinzheng; Quan, Li Na; Kim, Dong Ha; Hill, Ian G.; Maksymovych, Peter; Sargent, Edward H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Perovskite-fullerene hybrid materials suppress hysteresis in planar diodese", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solution-processed planar perovskite devices are highly desirable in a wide variety of optoelectronic applications; however, they are prone to hysteresis and current instabilities. Here we report the first perovskite-PCBM hybrid solid with significantly reduced hysteresis and recombination loss achieved in a single step. This new material displays an efficient electrically coupled microstructure: PCBM is homogeneously distributed throughout the film at perovskite grain boundaries. The PCBM passivates the key PbI3- antisite defects during the perovskite self-assembly, as revealed by theory and experiment. Photoluminescence transient spectroscopy proves that the PCBM phase promotes electron extraction. We showcase this mixed material in planar solar cells that feature low hysteresis and enhanced photovoltage. Using conductive AFM studies, we reveal the memristive properties of perovskite films. We close by positing that PCBM, by tying up both halide-rich antisites and unincorporated halides, reduces electric field-induced anion migration that may give rise to hysteresis and unstable diode behaviour.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1015, "Times Cited, All Databases": 1090, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7081, "DOI": "10.1038/ncomms8081", "DOI Link": "http://dx.doi.org/10.1038/ncomms8081", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000355531400007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, CP; Yin, YX; Zhang, SF; Li, NW; Guo, YG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Chun-Peng; Yin, Ya-Xia; Zhang, Shuai-Feng; Li, Nian-Wu; Guo, Yu-Guo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Accommodating lithium into 3D current collectors with a submicron skeleton towards long-life lithium metal anodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium metal is one of the most attractive anode materials for electrochemical energy storage. However, the growth of Li dendrites during electrochemical deposition, which leads to a low Coulombic efficiency and safety concerns, has long hindered the application of rechargeable Li-metal batteries. Here we show that a 3D current collector with a submicron skeleton and high electroactive surface area can significantly improve the electrochemical deposition behaviour of Li. Li anode is accommodated in the 3D structure without uncontrollable Li dendrites. With the growth of Li dendrites being effectively suppressed, the Li anode in the 3D current collector can run for 600 h without short circuit and exhibits low voltage hysteresis. The exceptional electrochemical performance of the Li-metal anode in the 3D current collector highlights the importance of rational design of current collectors and reveals a new avenue for developing Li anodes with a long lifespan.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1180, "Times Cited, All Databases": 1209, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8058, "DOI": "10.1038/ncomms9058", "DOI Link": "http://dx.doi.org/10.1038/ncomms9058", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000360352600005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, MJ; Guo, X; Ma, W; Ade, H; Hou, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Maojie; Guo, Xia; Ma, Wei; Ade, Harald; Hou, Jianhui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Large-Bandgap Conjugated Polymer for Versatile Photovoltaic Applications with High Performance", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": null, "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1015, "Times Cited, All Databases": 1045, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 19", "Publication Year": 2015, "Volume": 27, "Issue": 31, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4655, "End Page": 4660, "Article Number": null, "DOI": "10.1002/adma.201502110", "DOI Link": "http://dx.doi.org/10.1002/adma.201502110", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000359911500023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deng, J; Ren, PJ; Deng, DH; Bao, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deng, Jiao; Ren, Pengju; Deng, Dehui; Bao, Xinhe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced Electron Penetration through an Ultrathin Graphene Layer for Highly Efficient Catalysis of the Hydrogen Evolution Reaction", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Major challenges encountered when trying to replace precious-metal-based electrocatalysts of the hydrogen evolution reaction (HER) in acidic media are related to the low efficiency and stability of non-precious-metal compounds. Therefore, new concepts and strategies have to be devised to develop electrocatalysts that are based on earth-abundant materials. Herein, we report a hierarchical architecture that consists of ultrathin graphene shells (only 1-3 layers) that encapsulate a uniform CoNi nulloalloy to enhance its HER performance in acidic media. The optimized catalyst exhibits high stability and activity with an onset overpotential of almost zero versus the reversible hydrogen electrode (RHE) and an overpotential of only 142 mV at 10 mAcm(-2), which is quite close to that of commercial 40% Pt/C catalysts. Density functional theory (DFT) calculations indicate that the ultrathin graphene shells strongly promote electron penetration from the CoNi nulloalloy to the graphene surface. With nitrogen dopants, they synergistically increase the electron density on the graphene surface, which results in superior HER activity on the graphene shells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1160, "Times Cited, All Databases": 1202, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 9", "Publication Year": 2015, "Volume": 54, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2100, "End Page": 2104, "Article Number": null, "DOI": "10.1002/anie.201409524", "DOI Link": "http://dx.doi.org/10.1002/anie.201409524", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000349391000013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shen, LF; Yu, L; Wu, HB; Yu, XY; Zhang, XG; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shen, Laifa; Yu, Le; Wu, Hao Bin; Yu, Xin-Yao; Zhang, Xiaogang; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Formation of nickel cobalt sulfide ball-in-ball hollow spheres with enhanced electrochemical pseudocapacitive properties", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While the synthesis of hollow structures of transition metal oxides is well established, it is extremely challenging to fabricate complex hollow structures for mixed transition metal sulfides. Here we report an anion exchange method to synthesize a complex ternary metal sulfides hollow structure, namely nickel cobalt sulfide ball-in-ball hollow spheres. Uniform nickel cobalt glycerate solid spheres are first synthesized as the precursor and subsequently chemically transformed into nickel cobalt sulfide ball-in-ball hollow spheres. When used as electrode materials for electrochemical capacitors, these nickel cobalt sulfide hollow spheres deliver a specific capacitance of 1,036 F g(-1) at a current density of 1.0 A g(-1). An asymmetric supercapacitor based on these ball-in-ball structures shows long-term cycling performance with a high energy density of 42.3 Wh kg(-1) at a power density of 476 W kg(-1), suggesting their potential application in high-performance electrochemical capacitors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1214, "Times Cited, All Databases": 1232, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6694, "DOI": "10.1038/ncomms7694", "DOI Link": "http://dx.doi.org/10.1038/ncomms7694", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353043600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, CG; Bai, SQ; Liu, YT; Tang, YS; Chen, LD; Zhao, XB; Zhu, TJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Chenguang; Bai, Shengqiang; Liu, Yintu; Tang, Yunshan; Chen, Lidong; Zhao, Xinbing; Zhu, Tiejun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Realizing high figure of merit in heavy-band p-type half-Heusler thermoelectric materials", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solid-state thermoelectric technology offers a promising solution for converting waste heat to useful electrical power. Both high operating temperature and high figure of merit zT are desirable for high-efficiency thermoelectric power generation. Here we report a high zT of similar to 1.5 at 1,200 K for the p-type FeNbSb heavy-band half-Heusler alloys. High content of heavier Hf dopant simultaneously optimizes the electrical power factor and suppresses thermal conductivity. Both the enhanced point-defect and electron-phonon scatterings contribute to a significant reduction in the lattice thermal conductivity. An eight couple prototype thermoelectric module exhibits a high conversion efficiency of 6.2% and a high power density of 2.2 Wcm(-2) at a temperature difference of 655 K. These findings highlight the optimization strategy for heavy-band thermoelectric materials and demonstrate a realistic prospect of high-temperature thermoelectric modules based on half-Heusler alloys with low cost, excellent mechanical robustness and stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 992, "Times Cited, All Databases": 1041, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8144, "DOI": "10.1038/ncomms9144", "DOI Link": "http://dx.doi.org/10.1038/ncomms9144", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363015800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, CJ; Wen, YW; Hu, XL; Ji, XL; Yan, MY; Mai, LQ; Hu, P; Shan, B; Huang, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Chaoji; Wen, Yanwei; Hu, Xianluo; Ji, Xiulei; Yan, Mengyu; Mai, Liqiang; Hu, Pei; Shan, Bin; Huang, Yunhui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Na+ intercalation pseudocapacitance in graphene-coupled titanium oxide enabling ultra-fast sodium storage and long-term cycling", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sodium-ion batteries are emerging as a highly promising technology for large-scale energy storage applications. However, it remains a significant challenge to develop an anode with superior long-term cycling stability and high-rate capability. Here we demonstrate that the Na+ intercalation pseudocapacitance in TiO2/graphene nullocomposites enables high-rate capability and long cycle life in a sodium-ion battery. This hybrid electrode exhibits a specific capacity of above 90mAh g(-1) at 12,000mAg(-1) (similar to 36 C). The capacity is highly reversible for more than 4,000 cycles, the longest demonstrated cyclability to date. First-principle calculations demonstrate that the intimate integration of graphene with TiO2 reduces the diffusion energy barrier, thus enhancing the Na+ intercalation pseudocapacitive process. The Na-ion intercalation pseudocapacitance enabled by tailor-deigned nullostructures represents a promising strategy for developing electrode materials with high power density and long cycle life.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1061, "Times Cited, All Databases": 1081, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6929, "DOI": "10.1038/ncomms7929", "DOI Link": "http://dx.doi.org/10.1038/ncomms7929", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353704100037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bekenstein, Y; Koscher, BA; Eaton, SW; Yang, PD; Alivisatos, AP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bekenstein, Yehonadav; Koscher, Brent A.; Eaton, Samuel W.; Yang, Peidong; Alivisatos, A. Paul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Luminescent Colloidal nulloplates of Perovskite Cesium Lead Halide and Their Oriented Assemblies", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Anisotropic colloidal quasi-two-dimensional nulloplates (NPLs) hold great promise as functional materials due to their combination of low dimensional optoelectronic properties and versatility through colloidal synthesis. Recently, lead-halide perovskites have emerged as important optoelectronic materials with excellent efficiencies in photovoltaic and light-emitting applications. Here we report the synthesis of quantum confined all inorganic cesium lead halide nulloplates in the perovskite crystal structure that are also highly luminescent (PLQY 84%). The controllable self-assembly of nulloplates either into stacked columnar phases or crystallographic-oriented thin-sheet structures is demonstrated. The broad accessible emission range, high native quantum yields, and ease of self-assembly make perovskite NPLs an ideal platform for fundamental optoelectronic studies and the investigation of future devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1009, "Times Cited, All Databases": 1105, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 30", "Publication Year": 2015, "Volume": 137, "Issue": 51, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 16008, "End Page": 16011, "Article Number": null, "DOI": "10.1021/jacs.5b11199", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b11199", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367636600008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Vyas, VS; Haase, F; Stegbauer, L; Savasci, G; Podjaski, F; Ochsenfeld, C; Lotsch, BV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Vyas, Vijay S.; Haase, Frederik; Stegbauer, Linus; Savasci, Goekcen; Podjaski, Filip; Ochsenfeld, Christian; Lotsch, Bettina V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A tunable azine covalent organic framework platform for visible light-induced hydrogen generation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen evolution from photocatalytic reduction of water holds promise as a sustainable source of carbon-free energy. Covalent organic frameworks (COFs) present an interesting new class of photoactive materials, which combine three key features relevant to the photocatalytic process, namely crystallinity, porosity and tunability. Here we synthesize a series of water-and photostable 2D azine-linked COFs from hydrazine and triphenylarene aldehydes with varying number of nitrogen atoms. The electronic and steric variations in the precursors are transferred to the resulting frameworks, thus leading to a progressively enhanced light-induced hydrogen evolution with increasing nitrogen content in the frameworks. Our results demonstrate that by the rational design of COFs on a molecular level, it is possible to precisely adjust their structural and optoelectronic properties, thus resulting in enhanced photocatalytic activities. This is expected to spur further interest in these photofunctional frameworks where rational supramolecular engineering may lead to new material applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 988, "Times Cited, All Databases": 1034, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8508, "DOI": "10.1038/ncomms9508", "DOI Link": "http://dx.doi.org/10.1038/ncomms9508", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000363149200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Arbabi, A; Horie, Y; Ball, AJ; Bagheri, M; Faraon, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Arbabi, Amir; Horie, Yu; Ball, Alexander J.; Bagheri, Mahmood; Faraon, Andrei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Subwavelength-thick lenses with high numerical apertures and large efficiency based on high-contrast transmitarrays", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Flat optical devices thinner than a wavelength promise to replace conventional free-space components for wavefront and polarization control. Transmissive flat lenses are particularly interesting for applications in imaging and on-chip optoelectronic integration. Several designs based on plasmonic metasurfaces, high-contrast transmitarrays and gratings have been recently implemented but have not provided a performance comparable to conventional curved lenses. Here we report polarization-insensitive, micron-thick, high-contrast transmitarray micro-lenses with focal spots as small as 0.57 lambda. The measured focusing efficiency is up to 82%. A rigorous method for ultrathin lens design, and the trade-off between high efficiency and small spot size (or large numerical aperture) are discussed. The micro-lenses, composed of silicon nullo-posts on glass, are fabricated in one lithographic step that could be performed with high-throughput photo or nulloimprint lithography, thus enabling widespread adoption.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 927, "Times Cited, All Databases": 1091, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7069, "DOI": "10.1038/ncomms8069", "DOI Link": "http://dx.doi.org/10.1038/ncomms8069", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000355531100005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kornienko, N; Zhao, YB; Kiley, CS; Zhu, CH; Kim, D; Lin, S; Chang, CJ; Yaghi, OM; Yang, PD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kornienko, Nikolay; Zhao, Yingbo; Kiley, Christopher S.; Zhu, Chenhui; Kim, Dohyung; Lin, Song; Chang, Christopher J.; Yaghi, Omar M.; Yang, Peidong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal-Organic Frameworks for Electrocatalytic Reduction of Carbon Dioxide", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A key challenge in the field of electrochemical carbon dioxide reduction is the design of catalytic materials featuring high product selectivity, stability, and a composition of earth-abundant elements. In this work, we introduce thin films of nullosized metal organic frameworks (MOFs) as atomically defined and nulloscopic materials that function as catalysts for the efficient and selective reduction of carbon dioxide to carbon monoxide in aqueous electrolytes. Detailed examination of a cobalt porphyrin MOF, Al-2(OH)(2)TCPP-Co (TCPP-H-2 = 4,4',4 '',4 '''-(porphyrin-5,10,15,20-tetrayl)tetrabenzoate) revealed a selectivity for CO production in excess of 76% and stability over 7 h with a per-site turnover number (TON) of 1400. In situ spectroelectrochemical measurements provided insights into the cobalt oxidation state during the course of reaction and showed that the majority of catalytic centers in this MOF are redox-accessible where Co(II) is reduced to Co(I) during catalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 959, "Times Cited, All Databases": 1033, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 11", "Publication Year": 2015, "Volume": 137, "Issue": 44, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14129, "End Page": 14135, "Article Number": null, "DOI": "10.1021/jacs.5b08212", "DOI Link": "http://dx.doi.org/10.1021/jacs.5b08212", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364727600025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kulbak, M; Cahen, D; Hodes, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kulbak, Michael; Cahen, David; Hodes, Gary", "Book Author Full Names": null, "Group Authors": null, "Article Title": "How Important Is the Organic Part of Lead Halide Perovskite Photovoltaic Cells? Efficient CsPbBr3 Cells", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hybrid organic-inorganic lead halide perovskite photovoltaic cells have already surpassed 20% conversion efficiency in the few years that they have been seriously studied. However, many fundamental questions still remain unullswered as to why they are so good. One of these is Is the organic cation really necessary to obtain high quality cells? In this study, we show that an all-inorganic version of the lead bromide perovslcite material works equally well as the organic one, in particular generating the high open circuit voltages that are an important feature of these cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 984, "Times Cited, All Databases": 1063, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 2", "Publication Year": 2015, "Volume": 6, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2452, "End Page": 2456, "Article Number": null, "DOI": "10.1021/acs.jpclett.5b00968", "DOI Link": "http://dx.doi.org/10.1021/acs.jpclett.5b00968", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357626700009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shekhar, C; Nayak, AK; Sun, Y; Schmidt, M; Nicklas, M; Leermakers, I; Zeitler, U; Skourski, Y; Wosnitza, J; Liu, ZK; Chen, YL; Schnelle, W; Borrmann, H; Grin, Y; Felser, C; Yan, BH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shekhar, Chandra; Nayak, Ajaya K.; Sun, Yan; Schmidt, Marcus; Nicklas, Michael; Leermakers, Inge; Zeitler, Uli; Skourski, Yurii; Wosnitza, Jochen; Liu, Zhongkai; Chen, Yulin; Schnelle, Walter; Borrmann, Horst; Grin, Yuri; Felser, Claudia; Yan, Binghai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Extremely large magnetoresistance and ultrahigh mobility in the topological Weyl semimetal candidate NbP", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent experiments have revealed spectacular transport properties in semimetals, such as the large, non-saturating magnetoresistance exhibited by WTe2 (ref.1). Topological semimetals with massless relativistic electrons have also been predicted(2) as three-dimensional analogues of graphene(3). These systems are known as Weyl semimetals, and are predicted to have a range of exotic transport properties and surface states(4-7), distinct from those of topological insulators(8,9). Here we examine the magneto-transport properties of NbP, a material the band structure of which has been predicted to combine the hallmarks of a Weyl semimetal(10,11) with those of a normal semimetal. We observe an extremely large magnetoresistance of 850,000% at 1.85 K (250% at room temperature) in a magnetic field of up to 9 T, without any signs of saturation, and an ultra-high carrier mobility of 5 x 10(6) cm(2) V-1 s(-1) that accompanied by strong Shubnikov-de Haas (SdH) oscillations. NbP therefore presents a unique example of a material combining topological and conventional electronic phases, with intriguing physical properties resulting from their interplay.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 958, "Times Cited, All Databases": 1020, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2015, "Volume": 11, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 645, "End Page": "+", "Article Number": null, "DOI": "10.1038/NPHYS3372", "DOI Link": "http://dx.doi.org/10.1038/NPHYS3372", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358851900016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, C; Han, TYJ; Duoss, EB; Golobic, AM; Kuntz, JD; Spadaccini, CM; Worsley, MA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Cheng; Han, T. Yong-Jin; Duoss, Eric B.; Golobic, Alexandra M.; Kuntz, Joshua D.; Spadaccini, Christopher M.; Worsley, Marcus A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly compressible 3D periodic graphene aerogel microlattices", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graphene is a two-dimensional material that offers a unique combination of low density, exceptional mechanical properties, large surface area and excellent electrical conductivity. Recent progress has produced bulk 3D assemblies of graphene, such as graphene aerogels, but they possess purely stochastic porous networks, which limit their performance compared with the potential of an engineered architecture. Here we report the fabrication of periodic graphene aerogel microlattices, possessing an engineered architecture via a 3D printing technique known as direct ink writing. The 3D printed graphene aerogels are lightweight, highly conductive and exhibit supercompressibility (up to 90% compressive strain). Moreover, the Young's moduli of the 3D printed graphene aerogels show an order of magnitude improvement over bulk graphene materials with comparable geometric density and possess large surface areas. Adapting the 3D printing technique to graphene aerogels realizes the possibility of fabricating a myriad of complex aerogel architectures for a broad range of applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 940, "Times Cited, All Databases": 1021, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6962, "DOI": "10.1038/ncomms7962", "DOI Link": "http://dx.doi.org/10.1038/ncomms7962", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000353704700014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hanlon, D; Backes, C; Doherty, E; Cucinotta, CS; Berner, NC; Boland, C; Lee, K; Harvey, A; Lynch, P; Gholamvand, Z; Zhang, SF; Wang, KP; Moynihan, G; Pokle, A; Ramasse, QM; McEvoy, N; Blau, WJ; Wang, J; Abellan, G; Hauke, F; Hirsch, A; Sanvito, S; O'Regan, DD; Duesberg, GS; Nicolosi, V; Coleman, JN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hanlon, Damien; Backes, Claudia; Doherty, Evie; Cucinotta, Clotilde S.; Berner, Nina C.; Boland, Conor; Lee, Kangho; Harvey, Andrew; Lynch, Peter; Gholamvand, Zahra; Zhang, Saifeng; Wang, Kangpeng; Moynihan, Glenn; Pokle, Anuj; Ramasse, Quentin M.; McEvoy, Niall; Blau, Werner J.; Wang, Jun; Abellan, Gonzalo; Hauke, Frank; Hirsch, Andreas; Sanvito, Stefano; O'Regan, David D.; Duesberg, Georg S.; Nicolosi, Valeria; Coleman, Jonathan N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Liquid exfoliation of solvent-stabilized few-layer black phosphorus for applications beyond electronics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Few-layer black phosphorus (BP) is a new two-dimensional material which is of great interest for applications, mainly in electronics. However, its lack of environmental stability severely limits its synthesis and processing. Here we demonstrate that high-quality, few-layer BP nullosheets, with controllable size and observable photoluminescence, can be produced in large quantities by liquid phase exfoliation under ambient conditions in solvents such as N-cyclohexyl-2-pyrrolidone (CHP). nullosheets are surprisingly stable in CHP, probably due to the solvation shell protecting the nullosheets from reacting with water or oxygen. Experiments, supported by simulations, show reactions to occur only at the nullosheet edge, with the rate and extent of the reaction dependent on the water/oxygen content. We demonstrate that liquid-exfoliated BP nullosheets are potentially useful in a range of applications from ultrafast saturable absorbers to gas sensors to fillers for composite reinforcement.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 954, "Times Cited, All Databases": 1016, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 8563, "DOI": "10.1038/ncomms9563", "DOI Link": "http://dx.doi.org/10.1038/ncomms9563", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000364932600010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yakunin, S; Sytnyk, M; Kriegner, D; Shrestha, S; Richter, M; Matt, GJ; Azimi, H; Brabec, CJ; Stangl, J; Kovalenko, MV; Heiss, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yakunin, Sergii; Sytnyk, Mykhailo; Kriegner, Dominik; Shrestha, Shreetu; Richter, Moses; Matt, Gebhard J.; Azimi, Hamed; Brabec, Christoph J.; Stangl, Julian; Kovalenko, Maksym V.; Heiss, Wolfgang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Detection of X-ray photons by solution-processed lead halide perovskites", "Source Title": "NATURE PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The evolution of real-time medical diagnostic tools such as angiography and computer tomography from radiography based on photographic plates was enabled by the development of integrated solid-state X-ray photon detectors made from conventional solid-state semiconductors. Recently, for optoelectronic devices operating in the visible and near-infrared spectral regions, solution-processed organic and inorganic semiconductors have also attracted a great deal of attention. Here, we demonstrate a possibility to use such inexpensive semiconductors for the sensitive detection of X-ray photons by direct photon-to-current conversion. In particular, methylammonium lead iodide perovskite (CH3NH3PbI3) offers a compelling combination of fast photoresponse and a high absorption cross-section for X-rays, owing to the heavy Pb and I atoms. Solution-processed photodiodes as well as photoconductors are presented, exhibiting high values of X-ray sensitivity (up to 25 mu C mGy(air)(-1) cm(-3)) and responsivity (1.9 x 10(4) carriers/photon), which are commensurate with those obtained by the current solid-state technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 938, "Times Cited, All Databases": 1014, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2015, "Volume": 9, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 444, "End Page": "+", "Article Number": null, "DOI": "10.1038/NPHOTON.2015.82", "DOI Link": "http://dx.doi.org/10.1038/NPHOTON.2015.82", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000357406300009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Saliba, M; Matsui, T; Domanski, K; Seo, JY; Ummadisingu, A; Zakeeruddin, SM; Correa-Baena, JP; Tress, WR; Abate, A; Hagfeldt, A; Grätzel, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Saliba, Michael; Matsui, Taisuke; Domanski, Konrad; Seo, Ji-Youn; Ummadisingu, Amita; Zakeeruddin, Shaik M.; Correa-Baena, Juan-Pablo; Tress, Wolfgang R.; Abate, Antonio; Hagfeldt, Anders; Gratzel, Michael", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Incorporation of rubidium cations into perovskite solar cells improves photovoltaic performance", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All of the cations currently used in perovskite solar cells abide by the tolerance factor for incorporation into the lattice. We show that the small and oxidation-stable rubidium cation (Rb+) can be embedded into a cation cascade to create perovskite materials with excellent material properties. We achieved stabilized efficiencies of up to 21.6% (average value, 20.2%) on small areas (and a stabilized 19.0% on a cell 0.5 square centimeters in area) as well as an electroluminescence of 3.8%. The open-circuit voltage of 1.24 volts at a band gap of 1.63 electron volts leads to a loss in potential of 0.39 volts, versus 0.4 volts for commercial silicon cells. Polymer-coated cells maintained 95% of their initial performance at 85 degrees C for 500 hours under full illumination and maximum power point tracking.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 3166, "Times Cited, All Databases": 3333, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 14", "Publication Year": 2016, "Volume": 354, "Issue": 6309, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 206, "End Page": 209, "Article Number": null, "DOI": "10.1126/science.aah5557", "DOI Link": "http://dx.doi.org/10.1126/science.aah5557", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000387816500039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Read, N; Wang, W; Essa, K; Attallah, MM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Read, Noriko; Wang, Wei; Essa, Khamis; Attallah, Moataz M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Selective laser melting of AlSi10Mg alloy: Process optimisation and mechanical properties development", "Source Title": "MATERIALS & DESIGN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The influence of selective laser melting (SLM) process parameters (laser power, scan speed, scan spacing, and island size using a Concept Laser M2 system) on the porosity development in AlSi10Mg alloy builds has been investigated, using statistical design of experimental approach, correlated with the energy density model. A two-factor interaction model showed that the laser power, scan speed, and the interaction between the scan speed and scan spacing have the major influence on the porosity development in the builds. By driving the statistical method to minimise the porosity fraction, optimum process parameters were obtained. The optimum build parameters were validated, and subsequently used to build rodshaped samples to assess the room temperature and high temperature (creep) mechanical properties. The samples produced using SLM showed better strength and elongation properties, compared to die cast Al-alloys of similar composition. Creep results showed better rupture life than cast alloy, with a good agreement with the Larson-Miller literature data for this alloy composition. (C) 2014 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 932, "Times Cited, All Databases": 1016, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2015, "Volume": 65, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 417, "End Page": 424, "Article Number": null, "DOI": "10.1016/j.matdes.2014.09.044", "DOI Link": "http://dx.doi.org/10.1016/j.matdes.2014.09.044", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000345520000051", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "McMeekin, DP; Sadoughi, G; Rehman, W; Eperon, GE; Saliba, M; Hörantner, MT; Haghighirad, A; Sakai, N; Korte, L; Rech, B; Johnston, MB; Herz, LM; Snaith, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "McMeekin, David P.; Sadoughi, Golnaz; Rehman, Waqaas; Eperon, Giles E.; Saliba, Michael; Hoerantner, Maximilian T.; Haghighirad, Amir; Sakai, Nobuya; Korte, Lars; Rech, Bernd; Johnston, Michael B.; Herz, Laura M.; Snaith, Henry J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A mixed-cation lead mixed-halide perovskite absorber for tandem solar cells", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal halide perovskite photovoltaic cells could potentially boost the efficiency of commercial silicon photovoltaic modules from similar to 20 toward 30% when used in tandem architectures. An optimum perovskite cell optical band gap of similar to 1.75 electron volts (eV) can be achieved by varying halide composition, but to date, such materials have had poor photostability and thermal stability. Here we present a highly crystalline and compositionally photostable material, [HC(NH2)(2)](0.83)Cs0.17Pb(I0.6Br0.4)(3), with an optical band gap of similar to 1.74 eV, and we fabricated perovskite cells that reached open-circuit voltages of 1.2 volts and power conversion efficiency of over 17% on small areas and 14.7% on 0.715 cm(2) cells. By combining these perovskite cells with a 19%-efficient silicon cell, we demonstrated the feasibility of achieving >25%-efficient four-terminal tandem cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2577, "Times Cited, All Databases": 2797, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 8", "Publication Year": 2016, "Volume": 351, "Issue": 6269, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 151, "End Page": 155, "Article Number": null, "DOI": "10.1126/science.aad5845", "DOI Link": "http://dx.doi.org/10.1126/science.aad5845", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367806500036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Saliba, M; Matsui, T; Seo, JY; Domanski, K; Correa-Baena, JP; Nazeeruddin, MK; Zakeeruddin, SM; Tress, W; Abate, A; Hagfeldt, A; Grätzel, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Saliba, Michael; Matsui, Taisuke; Seo, Ji-Youn; Domanski, Konrad; Correa-Baena, Juan-Pablo; Nazeeruddin, Mohammad Khaja; Zakeeruddin, Shaik M.; Tress, Wolfgang; Abate, Antonio; Hagfeldt, Anders; Gratzel, Michael", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Today's best perovskite solar cells use a mixture of formamidinium and methylammonium as the monovalent cations. With the addition of inorganic cesium, the resulting triple cation perovskite compositions are thermally more stable, contain less phase impurities and are less sensitive to processing conditions. This enables more reproducible device performances to reach a stabilized power output of 21.1% and similar to 18% after 250 hours under operational conditions. These properties are key for the industrialization of perovskite photovoltaics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 4453, "Times Cited, All Databases": 4732, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 9, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1989, "End Page": 1997, "Article Number": null, "DOI": "10.1039/c5ee03874j", "DOI Link": "http://dx.doi.org/10.1039/c5ee03874j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378244200005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, B; Zheng, XL; Voznyy, O; Comin, R; Bajdich, M; García-Melchor, M; Han, LL; Xu, JX; Liu, M; Zheng, LR; de Arquer, FPG; Dinh, CT; Fan, FJ; Yuan, MJ; Yassitepe, E; Chen, N; Regier, T; Liu, PF; Li, YH; De Luna, P; Janmohamed, A; Xin, HLL; Yang, HG; Vojvodic, A; Sargent, EH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Bo; Zheng, Xueli; Voznyy, Oleksandr; Comin, Riccardo; Bajdich, Michal; Garcia-Melchor, Max; Han, Lili; Xu, Jixian; Liu, Min; Zheng, Lirong; de Arquer, F. Pelayo Garcia; Dinh, Cao Thang; Fan, Fengjia; Yuan, Mingjian; Yassitepe, Emre; Chen, Ning; Regier, Tom; Liu, Pengfei; Li, Yuhang; De Luna, Phil; Janmohamed, Alyf; Xin, Huolin L.; Yang, Huagui; Vojvodic, Aleksandra; Sargent, Edward H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Homogeneously dispersed multimetal oxygen-evolving catalysts", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Earth-abundant first-row (3d) transition metal-based catalysts have been developed for the oxygen-evolution reaction (OER); however, they operate at overpotentials substantially above thermodynamic requirements. Density functional theory suggested that non-3d high-valency metals such as tungsten can modulate 3d metal oxides, providing nearoptimal adsorption energies for OER intermediates. We developed a room-temperature synthesis to produce gelled oxyhydroxides materials with an atomically homogeneous metal distribution. These gelled FeCoW oxyhydroxides exhibit the lowest overpotential (191 millivolts) reported at 10 milliamperes per square centimeter in alkaline electrolyte. The catalyst shows no evidence of degradation after more than 500 hours of operation. X-ray absorption and computational studies reveal a synergistic interplay between tungsten, iron, and cobalt in producing a favorable local coordination environment and electronic structure that enhance the energetics for OER.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2118, "Times Cited, All Databases": 2222, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 15", "Publication Year": 2016, "Volume": 352, "Issue": 6283, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 333, "End Page": 337, "Article Number": null, "DOI": "10.1126/science.aaf1525", "DOI Link": "http://dx.doi.org/10.1126/science.aaf1525", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373990100038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, W; Emaminejad, S; Nyein, HYY; Challa, S; Chen, KV; Peck, A; Fahad, HM; Ota, H; Shiraki, H; Kiriya, D; Lien, DH; Brooks, GA; Davis, RW; Javey, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Wei; Emaminejad, Sam; Nyein, Hnin Yin Yin; Challa, Samyuktha; Chen, Kevin; Peck, Austin; Fahad, Hossain M.; Ota, Hiroki; Shiraki, Hiroshi; Kiriya, Daisuke; Lien, Der-Hsien; Brooks, George A.; Davis, Ronald W.; Javey, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fully integrated wearable sensor arrays for multiplexed in situ perspiration analysis", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wearable sensor technologies are essential to the realization of personalized medicine through continuously monitoring an individual's state of health(1-12). Sampling human sweat, which is rich in physiological information(13), could enable non-invasive monitoring. Previously reported sweat-based and other non-invasive biosensors either can only monitor a single analyte at a time or lack on-site signal processing circuitry and sensor calibration mechanisms for accurate analysis of the physiological state(14-18). Given the complexity of sweat secretion, simultaneous and multiplexed screening of target biomarkers is critical and requires full system integration to ensure the accuracy of measurements. Here we present a mechanically flexible and fully integrated (that is, no external analysis is needed) sensor array for multiplexed in situ perspiration analysis, which simultaneously and selectively measures sweat metabolites (such as glucose and lactate) and electrolytes (such as sodium and potassium ions), as well as the skin temperature (to calibrate the response of the sensors). Our work bridges the technological gap between signal transduction, conditioning (amplification and filtering), processing and wireless transmission in wearable biosensors by merging plastic-based sensors that interface with the skin with silicon integrated circuits consolidated on a flexible circuit board for complex signal processing. This application could not have been realized using either of these technologies alone owing to their respective inherent limitations. The wearable system is used to measure the detailed sweat profile of human subjects engaged in prolonged indoor and outdoor physical activities, and to make a real-time assessment of the physiological state of the subjects. This platform enables a wide range of personalized diagnostic and physiological monitoring applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 3671, "Times Cited, All Databases": 4013, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 28", "Publication Year": 2016, "Volume": 529, "Issue": 7587, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 509, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature16521", "DOI Link": "http://dx.doi.org/10.1038/nature16521", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000368673800033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mahmood, J; Lee, EK; Jung, M; Shin, D; Jeon, IY; Jung, SM; Choi, HJ; Seo, JM; Bae, SY; Sohn, SD; Park, N; Oh, JH; Shin, HJ; Baek, JB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mahmood, Javeed; Lee, Eun Kwang; Jung, Minbok; Shin, Dongbin; Jeon, In-Yup; Jung, Sun-Min; Choi, Hyun-Jung; Seo, Jeong-Min; Bae, Seo-Yoon; Sohn, So-Dam; Park, Noejung; Oh, Joon Hak; Shin, Hyung-Joon; Baek, Jong-Beom", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nitrogenated holey two-dimensional structures", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent graphene research has triggered enormous interest in new two-dimensional ordered crystals constructed by the inclusion of elements other than carbon for bandgap opening. The design of new multifunctional two-dimensional materials with proper bandgap has become an important challenge. Here we report a layered two-dimensional network structure that possesses evenly distributed holes and nitrogen atoms and a C2N stoichiometry in its basal plane. The two-dimensional structure can be efficiently synthesized via a simple wet-chemical reaction and confirmed with various characterization techniques, including scanning tunnelling microscopy. Furthermore, a field-effect transistor device fabricated using the material exhibits an on/off ratio of 10(7), with calculated and experimental bandgaps of approximately 1.70 and 1.96 eV, respectively. In view of the simplicity of the production method and the advantages of the solution processability, the C2N-h2D crystal has potential for use in practical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 969, "Times Cited, All Databases": 997, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6486, "DOI": "10.1038/ncomms7486", "DOI Link": "http://dx.doi.org/10.1038/ncomms7486", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000352635600005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schlipf, M; Gygi, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schlipf, Martin; Gygi, Francois", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Optimization algorithm for the generation of ONCV pseudopotentials", "Source Title": "COMPUTER PHYSICS COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present an optimization algorithm to construct pseudopotentials and use it to generate a set of Optimized Norm-Conserving Vanderbilt (ONCV) pseudopotentials for elements up to Z = 83 (Bi) (excluding Lanthanides). We introduce a quality function that assesses the agreement of a pseudopotential calculation with all-electron FLAPW results, and the necessary plane-wave energy cutoff. This quality function allows us to use a Nelder-Mead optimization algorithm on a training set of materials to optimize the input parameters of the pseudopotential construction for most of the periodic table. We control the accuracy of the resulting pseudopotentials on a test set of materials independent of the training set. We find that the automatically constructed pseudopotentials (http://www.quantum-simulation.org) provide a good agreement with the all-electron results obtained using the FLEUR code with a plane-wave energy cutoff of approximately 60 Ry. (C) 2015 The Authors. Published by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 897, "Times Cited, All Databases": 993, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2015, "Volume": 196, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 36, "End Page": 44, "Article Number": null, "DOI": "10.1016/j.cpc.2015.05.011", "DOI Link": "http://dx.doi.org/10.1016/j.cpc.2015.05.011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000362602900005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chaudhuri, O; Gu, L; Klumpers, D; Darnell, M; Bencherif, SA; Weaver, JC; Huebsch, N; Lee, HP; Lippens, E; Duda, GN; Mooney, DJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chaudhuri, Ovijit; Gu, Luo; Klumpers, Darinka; Darnell, Max; Bencherif, Sidi A.; Weaver, James C.; Huebsch, Nathaniel; Lee, Hong-pyo; Lippens, Evi; Duda, Georg N.; Mooney, David J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrogels with tunable stress relaxation regulate stem cell fate and activity", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Natural extracellular matrices (ECMs) are viscoelastic and exhibit stress relaxation. However, hydrogels used as synthetic ECMs for three-dimensional (3D) culture are typically elastic. Here, we report a materials approach to tune the rate of stress relaxation of hydrogels for 3D culture, independently of the hydrogel's initial elastic modulus, degradation, and cell-adhesion-ligand density. We find that cell spreading, proliferation, and osteogenic differentiation of mesenchymal stem cells (MSCs) are all enhanced in cells cultured in gels with faster relaxation. Strikingly, MSCs form a mineralized, collagen-1-rich matrix similar to bone in rapidly relaxing hydrogels with an initial elastic modulus of 17 kPa. We also show that the effects of stress relaxation are mediated by adhesion-ligand binding, actomyosin contractility and mechanical clustering of adhesion ligands. Our findings highlight stress relaxation as a key characteristic of cell-ECM interactions and as an important design parameter of biomaterials for cell culture.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1758, "Times Cited, All Databases": 1971, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 15, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 326, "End Page": "+", "Article Number": null, "DOI": "10.1038/NMAT4489", "DOI Link": "http://dx.doi.org/10.1038/NMAT4489", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000370967400019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Maintz, S; Deringer, VL; Tchougréeff, AL; Dronskowski, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Maintz, Stefan; Deringer, Volker L.; Tchougreeff, Andrei L.; Dronskowski, Richard", "Book Author Full Names": null, "Group Authors": null, "Article Title": "LOBSTER: A Tool to Extract Chemical Bonding from Plane-Wave Based DFT", "Source Title": "JOURNAL OF COMPUTATIONAL CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The computer program LOBSTER (Local Orbital Basis Suite Towards Electronic-Structure Reconstruction) enables chemical-bonding analysis based on periodic plane-wave (PAW) density-functional theory (DFT) output and is applicable to a wide range of first-principles simulations in solid-state and materials chemistry. LOBSTER incorporates analytic projection routines described previously in this very journal [J. Comput. Chem. 2013, 34, 2557] and offers improved functionality. It calculates, among others, atom-projected densities of states (pDOS), projected crystal orbital Hamilton population (pCOHP) curves, and the recently introduced bond-weighted distribution function (BWDF). The software is offered free-of-charge for noncommercial research. (C) 2016 The Authors. Journal of Computational Chemistry Published by Wiley Periodicals, Inc.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2363, "Times Cited, All Databases": 2467, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 30", "Publication Year": 2016, "Volume": 37, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1030, "End Page": 1035, "Article Number": null, "DOI": "10.1002/jcc.24300", "DOI Link": "http://dx.doi.org/10.1002/jcc.24300", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000374023100008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Stoumpos, CC; Cao, DH; Clark, DJ; Young, J; Rondinelli, JM; Jang, JI; Hupp, JT; Kanatzidis, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Stoumpos, Constantinos C.; Cao, Duyen H.; Clark, Daniel J.; Young, Joshua; Rondinelli, James M.; Jang, Joon I.; Hupp, Joseph T.; Kanatzidis, Mercouri G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ruddlesden-Popper Hybrid Lead Iodide Perovskite 2D Homologous Semiconductors", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The hybrid two-dimensional (2D) halide perovskites have recently drawn significant interest because they can serve as excellent photoabsorbers in perovskite solar cells. Here we present the large scale synthesis, crystal structure, and optical characterization of the 2D (CH3(CH2)(3)NH3)(2)(CH3NR3)(n-1)PbnI3n+1 (n = 1, 2, 3, 4, infinity) perovskites, a family of layered compounds with tunable semiconductor characteristics. These materials consist of well-defined inorganic perovskite layers intercalated with bulky butylammonium cations that act as spacers between these fragments, adopting the crystal structure of the Ruddlesden-Popper type. We find that the perovskite thickness (n) can be synthetically controlled by adjusting the ratio between the spacer cation and the small organic cation, thus allowing the isolation of compounds in pure form and large scale. The orthorhombic crystal structures of (CH3(CH2)(3)NH3)(2)(CH3NH3)-Pb2I7 (n = 2, Cc2m; a = 8.9470(4), b = 39.347(2) angstrom, c = 8.8589(6)), (CH3(CH2)(3)NH3)(2)(CH3NH3)(2)Pb3I10 (n = 3, C2cb; a = 8.9275(6), b = 51.959(4) angstrom, c = 8.8777(6)), and (CH3(CH2)(3)NH3)(2)(CH3NH3)(3)Pb4I13 (n = 4, Cc2m; a = 8.9274(4), b = 64.383(4) angstrom, c = 8.8816(4)) have been solved by single-crystal X-ray diffraction and are reported here for the first time. The compounds are noncentrosymmetric, as supported by measurements of the nonlinear optical properties of the compounds and density functional theory (DFT) calculations. The band gaps of the series change progressively between 2.43 eV for the n = 1 member to 1.50 eV for the n = infinity adopting intermediate values of 2.17 eV (n = 2), 2.03 eV (n = 3), and 1.91 eV (n = 4) for those between the two compositional extrema. DFT calculations confirm this experimental trend and predict a direct band gap for all the members of the Ruddlesden Popper series. The estimated effective masses have values of m(h) = 0.14 m(0) and m(e) = 0.08 m(0) for holes and electrons, respectively, and are found to be nearly composition independent. The band gaps of higher n members indicate that these compounds can be used as efficient light absorbers in solar cells, which offer better solution processability and good environmental stability. The compounds exhibit intense room-temperature photoluminescence with emission wavelengths consistent with their energy gaps, 2.35 eV (n = 1), 2.12 eV (n = 2), 2.01 eV (n = 3), and 1.90 eV (n = 4) and point to their potential use in light-emitting diodes. In addition, owing to the low dimensionality and the difference in dielectric properties between the organic spacers and the inorganic perovskite layers, these compounds are naturally occurring multiple quantum well structures, which give rise to stable excitons at room temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1704, "Times Cited, All Databases": 1861, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 26", "Publication Year": 2016, "Volume": 28, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2852, "End Page": 2867, "Article Number": null, "DOI": "10.1021/acs.chemmater.6b00847", "DOI Link": "http://dx.doi.org/10.1021/acs.chemmater.6b00847", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000375244500043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, NC; Stambula, S; Wang, D; Banis, MN; Liu, J; Riese, A; Xiao, BW; Li, RY; Sham, TK; Liu, LM; Botton, GA; Sun, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Niancai; Stambula, Samantha; Wang, Da; Banis, Mohammad Norouzi; Liu, Jian; Riese, Adam; Xiao, Biwei; Li, Ruying; Sham, Tsun-Kong; Liu, Li-Min; Botton, Gianluigi A.; Sun, Xueliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Platinum single-atom and cluster catalysis of the hydrogen evolution reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Platinum-based catalysts have been considered the most effective electrocatalysts for the hydrogen evolution reaction in water splitting. However, platinum utilization in these electrocatalysts is extremely low, as the active sites are only located on the surface of the catalyst particles. Downsizing catalyst nulloparticles to single atoms is highly desirable to maximize their efficiency by utilizing nearly all platinum atoms. Here we report on a practical synthesis method to produce isolated single platinum atoms and clusters using the atomic layer deposition technique. The single platinum atom catalysts are investigated for the hydrogen evolution reaction, where they exhibit significantly enhanced catalytic activity (up to 37 times) and high stability in comparison with the state-of-the-art commercial platinum/carbon catalysts. The X-ray absorption fine structure and density functional theory analyses indicate that the partially unoccupied density of states of the platinum atoms' 5d orbitals on the nitrogen-doped graphene are responsible for the excellent performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1711, "Times Cited, All Databases": 1810, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 30", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13638, "DOI": "10.1038/ncomms13638", "DOI Link": "http://dx.doi.org/10.1038/ncomms13638", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000388872900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, JY; Wang, H; Huang, HL; Xu, XD; Chen, MW; Wu, Y; Liu, XJ; Nieh, TG; An, K; Lu, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, J. Y.; Wang, H.; Huang, H. L.; Xu, X. D.; Chen, M. W.; Wu, Y.; Liu, X. J.; Nieh, T. G.; An, K.; Lu, Z. P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A precipitation-hardened high-entropy alloy with outstanding tensile properties", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent studies indicated that high-entropy alloys (HEAs) possess unusual structural and thermal features, which could greatly affect dislocation motion and contribute to the mechanical performance, however, a HEA matrix alone is insufficiently strong for engineering applications and other strengthening mechanisms are urgently needed to be incorporated. In this work, we demonstrate the possibility to precipitate nullosized coherent reinforcing phase, i.e., L1(2)-Ni-3(TLA1), in a fcc-FeCoNiCr HEA matrix using minor additions of Ti and Al. Through thermomechanical processing and microstructure controlling, extraordinary balanced tensile properties at room temperature were achieved, which is due to a well combination of various hardening mechanisms, particularly precipitation hardening. The applicability and validity of the conventional strengthening theories are also discussed. The current work is a successful demonstration of using integrated strengthening approaches to manipulate the properties of fcc-HEA systems, and the resulting findings are important not only for understanding the strengthening mechanisms of metallic materials in general, but also for the future development of high-performance HEAs for industrial applications. (C) 2015 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1963, "Times Cited, All Databases": 2061, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2016, "Volume": 102, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 187, "End Page": 196, "Article Number": null, "DOI": "10.1016/j.actamat.2015.08.076", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2015.08.076", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000365368800020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Halim, J; Cook, KM; Naguib, M; Eklund, P; Gogotsi, Y; Rosen, J; Barsoum, MW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Halim, Joseph; Cook, Kevin M.; Naguib, Michael; Eklund, Per; Gogotsi, Yury; Rosen, Johanna; Barsoum, Michel W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "X-ray photoelectron spectroscopy of select multi-layered transition metal carbides (MXenes)", "Source Title": "APPLIED SURFACE SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, a detailed high resolution X-ray photoelectron spectroscopy (XPS) analysis is presented for select MXenes a recently discovered family of two-dimensional (2D) carbides and carbonitrides. Given their 2D nature, understanding their surface chemistry is paramount. Herein we identify and quantify the surface groups present before, and after, sputter-cleaning as well as freshly prepared vs. aged multi layered cold pressed discs. The nominal compositions of the MXenes studied here are Ti-3 C2Tx,Ti3CNTx, Nb2CTx and Nb4C3Tx where T represents surface groups that this work attempts to quantify. In all the cases, the presence of three surface terminations, O, OH and F, in addition to OH-terminations relatively strongly bonded to H2O molecules, was confirmed. From XPS peak fits, it was possible to establish the average sum of the negative charges of the terminations for the aforementioned MXenes. Based on this work, it is now possible to quantify the nature of the surface terminations. This information can, in turn, be used to better design and tailor these novel 2D materials for various applications. Published by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1559, "Times Cited, All Databases": 1628, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 30", "Publication Year": 2016, "Volume": 362, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 406, "End Page": 417, "Article Number": null, "DOI": "10.1016/j.apsusc.2015.11.089", "DOI Link": "http://dx.doi.org/10.1016/j.apsusc.2015.11.089", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000368657900056", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, BJ; Zhang, J; Zhong, Q; Li, WB; Li, S; Li, H; Cheng, P; Meng, S; Chen, L; Wu, KH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Baojie; Zhang, Jin; Zhong, Qing; Li, Wenbin; Li, Shuai; Li, Hui; Cheng, Peng; Meng, Sheng; Chen, Lan; Wu, Kehui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Experimental realization of two-dimensional boron sheets", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A variety of two-dimensional materials have been reported in recent years, yet single-element systems such as graphene and black phosphorus have remained rare. Boron analogues have been predicted, as boron atoms possess a short covalent radius and the flexibility to adopt sp(2) hybridization, features that favour the formation of two-dimensional allotropes, and one example of such a borophene material has been reported recently. Here, we present a parallel experimental work showing that two-dimensional boron sheets can be grown epitaxially on a Ag(111) substrate. Two types of boron sheet, a beta(12) sheet and a chi(3) sheet, both exhibiting a triangular lattice but with different arrangements of periodic holes, are observed by scanning tunnelling microscopy. Density functional theory simulations agree well with experiments, and indicate that both sheets are planar without obvious vertical undulations. The boron sheets are quite inert to oxidization and interact only weakly with their substrate. We envisage that such boron sheets may find applications in electronic devices in the future.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1511, "Times Cited, All Databases": 1584, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 8, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 564, "End Page": 569, "Article Number": null, "DOI": "10.1038/NCHEM.2491", "DOI Link": "http://dx.doi.org/10.1038/NCHEM.2491", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000376529000012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dubbeldam, D; Calero, S; Ellis, DE; Snurr, RQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dubbeldam, David; Calero, Sofia; Ellis, Donald E.; Snurr, Randall Q.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "RASPA: molecular simulation software for adsorption and diffusion in flexible nulloporous materials", "Source Title": "MOLECULAR SIMULATION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A new software package, RASPA, for simulating adsorption and diffusion of molecules in flexible nulloporous materials is presented. The code implements the latest state-of-the-art algorithms for molecular dynamics and Monte Carlo (MC) in various ensembles including symplectic/measure-preserving integrators, Ewald summation, configurational-bias MC, continuous fractional component MC, reactive MC and Baker's minimisation. We show example applications of RASPA in computing coexistence properties, adsorption isotherms for single and multiple components, self- and collective diffusivities, reaction systems and visualisation. The software is released under the GNU General Public License.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1435, "Times Cited, All Databases": 1532, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 22", "Publication Year": 2016, "Volume": 42, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 81, "End Page": 101, "Article Number": null, "DOI": "10.1080/08927022.2015.1010082", "DOI Link": "http://dx.doi.org/10.1080/08927022.2015.1010082", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000362190200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bi, DQ; Tress, W; Dar, MI; Gao, P; Luo, JS; Renevier, C; Schenk, K; Abate, A; Giordano, F; Baena, JPC; Decoppet, JD; Zakeeruddin, SM; Nazeeruddin, MK; Grätzel, M; Hagfeldt, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bi, Dongqin; Tress, Wolfgang; Dar, M. Ibrahim; Gao, Peng; Luo, Jingshan; Renevier, Clementine; Schenk, Kurt; Abate, Antonio; Giordano, Fabrizio; Baena, Juan-Pablo Correa; Decoppet, Jean-David; Zakeeruddin, Shaik Mohammed; Nazeeruddin, Mohammad Khaja; Gratzel, Michael; Hagfeldt, Anders", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient luminescent solar cells based on tailored mixed-cation perovskites", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report on a new metal halide perovskite photovoltaic cell that exhibits both very high solar-to-electric power-conversion efficiency and intense electroluminescence. We produce the perovskite films in a single step from a solution containing a mixture of FAI, PbI2, MABr, and PbBr2 (where FA stands for formamidinium cations andMA stands for methylammonium cations). Using mesoporous TiO2 and Spiro-OMeTAD as electron-and hole-specific contacts, respectively, we fabricate perovskite solar cells that achieve a maximum power-conversion efficiency of 20.8% for a PbI2/FAImolar ratio of 1.05 in the precursor solution. Rietveld analysis of x-ray diffraction data reveals that the excess PbI2 content incorporated into such a film is about 3 wt %. Time-resolved photoluminescence decay measurements show that the small excess of PbI2 suppresses nonradiative charge carrier recombination. This in turn augments the external electroluminescence quantum efficiency to values of about 0.5%, a record for perovskite photovoltaics approaching that of the best silicon solar cells. Correspondingly, the open-circuit photovoltage reaches 1.18 V under AM 1.5 sunlight.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1672, "Times Cited, All Databases": 1748, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2016, "Volume": 2, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1501170", "DOI": "10.1126/sciadv.1501170", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1501170", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000376972900023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dris, R; Gasperi, J; Saad, M; Mirande, C; Tassin, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dris, Rachid; Gasperi, Johnny; Saad, Mohamed; Mirande, Cecile; Tassin, Bruno", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthetic fibers in atmospheric fallout: A source of microplastics in the environment?", "Source Title": "MARINE POLLUTION BULLETIN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sources, pathways and reservoirs of microplastics, plastic particles smaller than 5 mm, remain poorly documented in an urban context. While some studies pointed out wastewater treatment plants as a potential pathway of microplastics, none have focused on the atmospheric compartment. In this work, the atmospheric fallout of microplastics was investigated in two different urban and sub-urban sites. Microplastics were collected continuously with a stainless steel funnel. Samples were then filtered and observed with a stereomicroscope. Fibers accounted for almost all the microplastics collected. An atmospheric fallout between 2 and 355 particles/m(2)/day was highlighted. Registered fluxes were systematically higher at the urban than at the sub-urban site. Chemical characterization allowed to estimate at 29% the proportion of these fibers being all synthetic (made with petrochemicals), or a mixture of natural and synthetic material. Extrapolation using weight and volume estimates of the collected fibers, allowed a rough estimation showing that between 3 and 10 tons of fibers are deposited by atmospheric fallout at the scale of the Parisian agglomeration every year (2500 km(2)). These results could serve the scientific community working on the different sources of microplastic in both continental and marine environments. (C) 2016 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1336, "Times Cited, All Databases": 1518, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2016, "Volume": 104, "Issue": "1-2", "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 290, "End Page": 293, "Article Number": null, "DOI": "10.1016/j.marpolbul.2016.01.006", "DOI Link": "http://dx.doi.org/10.1016/j.marpolbul.2016.01.006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology; Marine & Freshwater Biology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000374198100046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, GM; Paek, E; Hwang, GS; Manthiram, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Guangmin; Paek, Eunsu; Hwang, Gyeong S.; Manthiram, Arumugam", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Long-life Li/polysulphide batteries with high sulphur loading enabled by lightweight three-dimensional nitrogen/sulphur-codoped graphene sponge", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-sulphur batteries with a high theoretical energy density are regarded as promising energy storage devices for electric vehicles and large-scale electricity storage. However, the low active material utilization, low sulphur loading and poor cycling stability restrict their practical applications. Herein, we present an effective strategy to obtain Li/polysulphide batteries with high-energy density and long-cyclic life using three-dimensional nitrogen/sulphur codoped graphene sponge electrodes. The nitrogen/sulphur codoped graphene sponge electrode provides enough space for a high sulphur loading, facilitates fast charge transfer and better immobilization of polysulphide ions. The hetero-doped nitrogen/sulphur sites are demonstrated to show strong binding energy and be capable of anchoring polysulphides based on first-principles calculations. As a result, a high specific capacity of 1,200 mAhg(-1) at 0.2C rate, a high-rate capacity of 430 mAhg(-1) at 2C rate and excellent cycling stability for 500 cycles with similar to 0.078% capacity decay per cycle are achieved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 955, "Times Cited, All Databases": 1005, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2015, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7760, "DOI": "10.1038/ncomms8760", "DOI Link": "http://dx.doi.org/10.1038/ncomms8760", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000358858800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, LD; Tan, GJ; Hao, SQ; He, JQ; Pei, YL; Chi, H; Wang, H; Gong, SK; Xu, HB; Dravid, VP; Uher, C; Snyder, GJ; Wolverton, C; Kanatzidis, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Li-Dong; Tan, Gangjian; Hao, Shiqiang; He, Jiaqing; Pei, Yanling; Chi, Hang; Wang, Heng; Gong, Shengkai; Xu, Huibin; Dravid, Vinayak P.; Uher, Ctirad; Snyder, G. Jeffrey; Wolverton, Chris; Kanatzidis, Mercouri G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrahigh power factor and thermoelectric performance in hole-doped single-crystal SnSe", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermoelectric technology, harvesting electric power directly from heat, is a promising environmentally friendly means of energy savings and power generation. The thermoelectric efficiency is determined by the device dimensionless figure of merit ZT(dev), and optimizing this efficiency requires maximizing ZT values over a broad temperature range. Here, we report a record high ZT(dev) similar to 1.34, with ZT ranging from 0.7 to 2.0 at 300 to 773 kelvin, realized in hole-doped tin selenide (SnSe) crystals. The exceptional performance arises from the ultrahigh power factor, which comes from a high electrical conductivity and a strongly enhanced Seebeck coefficient enabled by the contribution of multiple electronic valence bands present in SnSe. SnSe is a robust thermoelectric candidate for energy conversion applications in the low and moderate temperature range.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1906, "Times Cited, All Databases": 2011, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 8", "Publication Year": 2016, "Volume": 351, "Issue": 6269, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 141, "End Page": 144, "Article Number": null, "DOI": "10.1126/science.aad3749", "DOI Link": "http://dx.doi.org/10.1126/science.aad3749", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367806500033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, J; Wang, T; Pohl, D; Rellinghaus, B; Dong, RH; Liu, SH; Zhuang, XD; Feng, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jian; Wang, Tao; Pohl, Darius; Rellinghaus, Bernd; Dong, Renhao; Liu, Shaohua; Zhuang, Xiaodong; Feng, Xinliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interface Engineering of MoS2/Ni3S2 Heterostructures for Highly Enhanced Electrochemical Overall-Water-Splitting Activity", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To achieve sustainable production of H-2 fuel through water splitting, low-cost electrocatalysts for the hydrogen-evolution reaction (HER) and the oxygen-evolution reaction (OER) are required to replace Pt and IrO2 catalysts. Herein, for the first time, we present the interface engineering of novel MoS2/Ni3S2 heterostructures, in which abundant interfaces are formed. For OER, such MoS2/Ni3S2 heterostructures show an extremely low overpotential of ca. 218 mV at 10 mAcm(-2), which is superior to that of the state-of-the-art OER electrocatalysts. Using MoS2/Ni3S2 heterostructures as bifunctional electrocatalysts, an alkali electrolyzer delivers a current density of 10 mAcm(-2) at a very low cell voltage of ca. 1.56 V. In combination with DFT calculations, this study demonstrates that the constructed interfaces synergistically favor the chemisorption of hydrogen and oxygen-containing intermediates, thus accelerating the overall electrochemical water splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1508, "Times Cited, All Databases": 1520, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 1", "Publication Year": 2016, "Volume": 55, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6702, "End Page": 6707, "Article Number": null, "DOI": "10.1002/anie.201602237", "DOI Link": "http://dx.doi.org/10.1002/anie.201602237", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377921300021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, XL; Tang, YB; Zhang, F; Lee, CS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xiaolong; Tang, Yongbing; Zhang, Fan; Lee, Chun-Sing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Novel Aluminum-Graphite Dual-Ion Battery", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": null, "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1748, "Times Cited, All Databases": 1772, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 8", "Publication Year": 2016, "Volume": 6, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1502588, "DOI": "10.1002/aenm.201502588", "DOI Link": "http://dx.doi.org/10.1002/aenm.201502588", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379311500012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bu, LZ; Zhang, N; Guo, SJ; Zhang, X; Li, J; Yao, JL; Wu, T; Lu, G; Ma, JY; Su, D; Huang, XQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bu, Lingzheng; Zhang, null; Guo, Shaojun; Zhang, Xu; Li, Jing; Yao, Jianlin; Wu, Tao; Lu, Gang; Ma, Jing-Yuan; Su, Dong; Huang, Xiaoqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biaxially strained PtPb/Pt core/shell nulloplate boosts oxygen reduction catalysis", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Compressive surface strains have been necessary to boost oxygen reduction reaction (ORR) activity in core/shell M/platinum (Pt) catalysts (where M can be nickel, cobalt, or iron). We report on a class of platinum-lead/platinum (PtPb/Pt) core/shell nulloplate catalysts that exhibit large biaxial strains. The stable Pt (110) facets of the nulloplates have high ORR specific and mass activities that reach 7.8 milliampere (mA) per centimeter squared and 4.3 ampere per milligram of platinum at 0.9 volts versus the reversible hydrogen electrode (RHE), respectively. Density functional theory calculations reveal that the edge-Pt and top (bottom)-Pt (110) facets undergo large tensile strains that help optimize the Pt-O bond strength. The intermetallic core and uniform four layers of Pt shell of the PtPb/Pt nulloplates appear to underlie the high endurance of these catalysts, which can undergo 50,000 voltage cycles with negligible activity decay and no apparent structure and composition changes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1351, "Times Cited, All Databases": 1430, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 16", "Publication Year": 2016, "Volume": 354, "Issue": 6318, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1410, "End Page": 1414, "Article Number": null, "DOI": "10.1126/science.aah6133", "DOI Link": "http://dx.doi.org/10.1126/science.aah6133", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000390261300040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lipatov, A; Alhabeb, M; Lukatskaya, MR; Boson, A; Gogotsi, Y; Sinitskii, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lipatov, Alexey; Alhabeb, Mohamed; Lukatskaya, Maria R.; Boson, Alex; Gogotsi, Yury; Sinitskii, Alexander", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of Synthesis on Quality, Electronic Properties and Environmental Stability of Individual Monolayer Ti3C2 MXene Flakes", "Source Title": "ADVANCED ELECTRONIC MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "2D transition metal carbide Ti3C2Tx (T stands for surface termination), the most widely studied MXene, has shown outstanding electrochemical properties and promise for a number of bulk applications. However, electronic properties of individual MXene flakes, which are important for understanding the potential of these materials, remain largely unexplored. Herein, a modified synthetic method is reported for producing high-quality monolayer Ti(3)C(2)Tx flakes. Field-effect transistors (FETs) based on monolayer Ti(3)C(2)Tx flakes are fabricated and their electronic properties are measured. Individual Ti(3)C(2)Tx flakes exhibit a high conductivity of 4600 +/- 1100 S cm(-1) and field-effect electron mobility of 2.6 +/- 0.7 cm(2) V-1 s(-1). The resistivity of multilayer Ti(3)C(2)Tx films is only one order of magnitude higher than the resistivity of individual flakes, which indicates a surprisingly good electron transport through the surface terminations of different flakes, unlike in many other 2D materials. Finally, the fabricated FETs are used to investigate the environmental stability and kinetics of oxidation of Ti(3)C(2)Tx flakes in humid air. The high-quality Ti(3)C(2)Tx flakes are reasonably stable and remain highly conductive even after their exposure to air for more than 24 h. It is demonstrated that after the initial exponential decay the conductivity of Ti(3)C(2)Tx flakes linearly decreases with time, which is consistent with their edge oxidation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1314, "Times Cited, All Databases": 1363, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2016, "Volume": 2, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1600255, "DOI": "10.1002/aelm.201600255", "DOI Link": "http://dx.doi.org/10.1002/aelm.201600255", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392939300004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Desai, SB; Madhvapathy, SR; Sachid, AB; Llinas, JP; Wang, QX; Ahn, GH; Pitner, G; Kim, MJ; Bokor, J; Hu, CM; Wong, HSP; Javey, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Desai, Sujay B.; Madhvapathy, Surabhi R.; Sachid, Angada B.; Llinas, Juan Pablo; Wang, Qingxiao; Ahn, Geun Ho; Pitner, Gregory; Kim, Moon J.; Bokor, Jeffrey; Hu, Chenming; Wong, H. -S. Philip; Javey, Ali", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MoS2 transistors with 1-nullometer gate lengths", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Scaling of silicon (Si) transistors is predicted to fail below 5-nullometer (nm) gate lengths because of severe short channel effects. As an alternative to Si, certain layered semiconductors are attractive for their atomically uniform thickness down to a monolayer, lower dielectric constants, larger band gaps, and heavier carrier effective mass. Here, we demonstrate molybdenum disulfide (MoS2) transistors with a 1-nm physical gate length using a single-walled carbon nullotube as the gate electrode. These ultrashort devices exhibit excellent switching characteristics with near ideal subthreshold swing of similar to 65 millivolts per decade and an On/Off current ratio of similar to 10(6). Simulations show an effective channel length of similar to 3.9 nm in the Off state and similar to 1 nm in the On state.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1217, "Times Cited, All Databases": 1368, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 7", "Publication Year": 2016, "Volume": 354, "Issue": 6308, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 99, "End Page": 102, "Article Number": null, "DOI": "10.1126/science.aah4698", "DOI Link": "http://dx.doi.org/10.1126/science.aah4698", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000387777900038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tao, XY; Wang, JG; Liu, C; Wang, HT; Yao, HB; Zheng, GY; Seh, ZW; Cai, QX; Li, WY; Zhou, GM; Zu, CX; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tao, Xinyong; Wang, Jianguo; Liu, Chong; Wang, Haotian; Yao, Hongbin; Zheng, Guangyuan; Seh, Zhi Wei; Cai, Qiuxia; Li, Weiyang; Zhou, Guangmin; Zu, Chenxi; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Balancing surface adsorption and diffusion of lithium-polysulfides on nonconductive oxides for lithium-sulfur battery design", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-sulfur batteries have attracted attention due to their six-fold specific energy compared with conventional lithium-ion batteries. Dissolution of lithium polysulfides, volume expansion of sulfur and uncontrollable deposition of lithium sulfide are three of the main challenges for this technology. State-of-the-art sulfur cathodes based on metal-oxide nullostructures can suppress the shuttle-effect and enable controlled lithium sulfide deposition. However, a clear mechanistic understanding and corresponding selection criteria for the oxides are still lacking. Herein, various nonconductive metal-oxide nulloparticle-decorated carbon flakes are synthesized via a facile biotemplating method. The cathodes based on magnesium oxide, cerium oxide and lanthanum oxide show enhanced cycling performance. Adsorption experiments and theoretical calculations reveal that polysulfide capture by the oxides is via monolayered chemisorption. Moreover, we show that better surface diffusion leads to higher deposition efficiency of sulfide species on electrodes. Hence, oxide selection is proposed to balance optimization between sulfide-adsorption and diffusion on the oxides.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1247, "Times Cited, All Databases": 1319, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11203, "DOI": "10.1038/ncomms11203", "DOI Link": "http://dx.doi.org/10.1038/ncomms11203", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373622000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "De Roo, J; Ibáñez, M; Geiregat, P; Nedelcu, G; Walravens, W; Maes, J; Martins, JC; Van Driessche, I; Koyalenko, MV; Hens, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "De Roo, Jonathan; Ibanez, Maria; Geiregat, Pieter; Nedelcu, Georgian; Walravens, Willem; Maes, Jorick; Martins, Jose C.; Van Driessche, Isabel; Koyalenko, Maksym V.; Hens, Zeger", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Dynamic Ligand Binding and Light Absorption Coefficient of Cesium Lead Bromide Perovskite nullocrystals", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lead halide perovskite materials have attracted significant attention in the context of photovoltaics and other optoelectronic applications, and recently, research efforts have been directed to nullostructured lead halide perovskites. Collodial nullocrystals (NCs) of cesium lead halides (CsPbX3, X = Cl, Br, I) exhibit bright photoluminescence, with emission tunable over the entire visible spectral region. However, previous studies on CsPbX3 NCs did not address key aspects of their chemistry and photophysics such as surface chemistry and quantitative light absorption. Here, we elaborate on the synthesis of CsPbBr3 NCs and their surface chemistry. In addition, the intrinsic absorption coefficient was determined experimentally by combining elemental analysis with accurate optical absorption measurements. H-1 solution nuclear magnetic resonullce spectroscopy was used to characterize sample purity, elucidate the surface chemistry, and evaluate the influence of purification methods on the surface composition. We find that ligand binding to the NC surface is highly dynamic, and therefore, ligands are easily lost during the isolation and purification procedures. However, when a small amount of both oleic acid and oleylamine is added, the NCs can be purified, maintaining optical, colloidal, and material integrity. In addition, we find that a high amine content in the ligand shell increases the quantum yield due to the improved binding of the carboxylic acid.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1547, "Times Cited, All Databases": 1636, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 10, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2071, "End Page": 2081, "Article Number": null, "DOI": "10.1021/acsnullo.5b06295", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.5b06295", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000370987400044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Seo, DH; Lee, J; Urban, A; Malik, R; Kang, S; Ceder, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Seo, Dong-Hwa; Lee, Jinhyuk; Urban, Alexander; Malik, Rahul; Kang, ShinYoung; Ceder, Gerbrand", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-ion batteries are now reaching the energy density limits set by their electrode materials, requiring new paradigms for Li+ and electron hosting in solid-state electrodes. Reversible oxygen redox in the solid state in particular has the potential to enable high energy density as it can deliver excess capacity beyond the theoretical transition-metal redox-capacity at a high voltage. Nevertheless, the structural and chemical origin of the process is not understood, preventing the rational design of better cathode materials. Here, we demonstrate how very specific local Li-excess environments around oxygen atoms necessarily lead to labile oxygen electrons that can be more easily extracted and participate in the practical capacity of cathodes. The identification of the local structural components that create oxygen redox sets a new direction for the design of high-energy-density cathode materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1190, "Times Cited, All Databases": 1265, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2016, "Volume": 8, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 692, "End Page": 697, "Article Number": null, "DOI": "10.1038/NCHEM.2524", "DOI Link": "http://dx.doi.org/10.1038/NCHEM.2524", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378280400013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ward, L; Agrawal, A; Choudhary, A; Wolverton, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ward, Logan; Agrawal, Ankit; Choudhary, Alok; Wolverton, Christopher", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A general-purpose machine learning framework for predicting properties of inorganic materials", "Source Title": "NPJ COMPUTATIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A very active area of materials research is to devise methods that use machine learning to automatically extract predictive models from existing materials data. While prior examples have demonstrated successful models for some applications, many more applications exist where machine learning can make a strong impact. To enable faster development of machine-learning-based models for such applications, we have created a framework capable of being applied to a broad range of materials data. Our method works by using a chemically diverse list of attributes, which we demonstrate are suitable for describing a wide variety of properties, and a novel method for partitioning the data set into groups of similar materials to boost the predictive accuracy. In this manuscript, we demonstrate how this new method can be used to predict diverse properties of crystalline and amorphous materials, such as band gap energy and glass-forming ability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1121, "Times Cited, All Databases": 1266, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 2, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 16028, "DOI": "10.1038/npjcompumats.2016.28", "DOI Link": "http://dx.doi.org/10.1038/npjcompumats.2016.28", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426821500024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wadley, P; Howells, B; Zelezny, J; Andrews, C; Hills, V; Campion, RP; Novák, V; Olejník, K; Maccherozzi, F; Dhesi, SS; Martin, SY; Wagner, T; Wunderlich, J; Freimuth, F; Mokrousov, Y; Kunes, J; Chauhan, JS; Grzybowski, MJ; Rushforth, AW; Edmonds, KW; Gallagher, BL; Jungwirth, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wadley, P.; Howells, B.; Zelezny, J.; Andrews, C.; Hills, V.; Campion, R. P.; Novak, V.; Olejnik, K.; Maccherozzi, F.; Dhesi, S. S.; Martin, S. Y.; Wagner, T.; Wunderlich, J.; Freimuth, F.; Mokrousov, Y.; Kunes, J.; Chauhan, J. S.; Grzybowski, M. J.; Rushforth, A. W.; Edmonds, K. W.; Gallagher, B. L.; Jungwirth, T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrical switching of an antiferromagnet", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Antiferromagnets are hard to control by external magnetic fields because of the alternating directions of magnetic moments on individual atoms and the resulting zero net magnetization. However, relativistic quantum mechanics allows for generating current-induced internal fields whose sign alternates with the periodicity of the antiferromagnetic lattice. Using these fields, which couple strongly to the antiferromagnetic order, we demonstrate room-temperature electrical switching between stable configurations in antiferromagnetic CuMnAs thin-film devices by applied current with magnitudes of order 10(6) ampere per square centimeter. Electrical writing is combined in our solid-state memory with electrical readout and the stored magnetic state is insensitive to and produces no external magnetic field perturbations, which illustrates the unique merits of antiferromagnets for spintronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1158, "Times Cited, All Databases": 1233, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 5", "Publication Year": 2016, "Volume": 351, "Issue": 6273, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 587, "End Page": 590, "Article Number": null, "DOI": "10.1126/science.aab1031", "DOI Link": "http://dx.doi.org/10.1126/science.aab1031", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369291600036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Williams, SW; Martina, F; Addison, AC; Ding, J; Pardal, G; Colegrove, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Williams, S. W.; Martina, F.; Addison, A. C.; Ding, J.; Pardal, G.; Colegrove, P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wire plus Arc Additive Manufacturing", "Source Title": "MATERIALS SCIENCE AND TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Depositing large components (>10 kg) in titanium, aluminium, steel and other metals is possible using Wire + Arc Additive Manufacturing. This technology adopts arc welding tools and wire as feedstock for additive manufacturing purposes. High deposition rates, low material and equipment costs, and good structural integrity make Wire + Arc Additive Manufacturing a suitable candidate for replacing the current method of manufacturing from solid billets or large forgings, especially with regards to low and medium complexity parts. A variety of components have been successfully manufactured with this process, including Ti-6Al-4V spars and landing gear assemblies, aluminium wing ribs, steel wind tunnel models and cones. Strategies on how to manage residual stress, improve mechanical properties and eliminate defects such as porosity are suggested. Finally, the benefits of non-destructive testing, online monitoring and in situ machining are discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1158, "Times Cited, All Databases": 1263, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 32, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 641, "End Page": 647, "Article Number": null, "DOI": "10.1179/1743284715Y.0000000073", "DOI Link": "http://dx.doi.org/10.1179/1743284715Y.0000000073", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378338600005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gludovatz, B; Hohenwarter, A; Thurston, KVS; Bei, HB; Wu, ZG; George, EP; Ritchie, RO", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gludovatz, Bernd; Hohenwarter, Anton; Thurston, Keli V. S.; Bei, Hongbin; Wu, Zhenggang; George, Easo P.; Ritchie, Robert O.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exceptional damage-tolerance of a medium-entropy alloy CrCoNi at cryogenic temperatures", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy alloys are an intriguing new class of metallic materials that derive their properties from being multi-element systems that can crystallize as a single phase, despite containing high concentrations of five or more elements with different crystal structures. Here we examine an equiatomic medium-entropy alloy containing only three elements, CrCoNi, as a single-phase face-centred cubic solid solution, which displays strength-toughness properties that exceed those of all high-entropy alloys and most multi-phase alloys. At room temperature, the alloy shows tensile strengths of almost 1 GPa, failure strains of similar to 70% and K-JIc fracture-toughness values above 200 MPa m(1/2); at cryogenic temperatures strength, ductility and toughness of the CrCoNi alloy improve to strength levels above 1.3 GPa, failure strains up to 90% and K-JIc values of 275 MPa m(1/2). Such properties appear to result from continuous steady strain hardening, which acts to suppress plastic instability, resulting from pronounced dislocation activity and deformation-induced nullo-twinning.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1416, "Times Cited, All Databases": 1498, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10602, "DOI": "10.1038/ncomms10602", "DOI Link": "http://dx.doi.org/10.1038/ncomms10602", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371019700020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bai, P; Li, J; Brushett, FR; Bazant, MZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bai, Peng; Li, Ju; Brushett, Fikile R.; Bazant, Martin Z.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Transition of lithium growth mechanisms in liquid electrolytes", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Next-generation high-energy batteries will require a rechargeable lithium metal anode, but lithium dendrites tend to form during recharging, causing short-circuit risk and capacity loss, by mechanisms that still remain elusive. Here, we visualize lithium growth in a glass capillary cell and demonstrate a change of mechanism from root-growing mossy lithium to tip-growing dendritic lithium at the onset of electrolyte diffusion limitation. In sandwich cells, we further demonstrate that mossy lithium can be blocked by nulloporous ceramic separators, while dendritic lithium can easily penetrate nullopores and short the cell. Our results imply a fundamental design constraint for metal batteries (Sand's capacity''), which can be increased by using concentrated electrolytes with stiff, permeable, nulloporous separators for improved safety.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1211, "Times Cited, All Databases": 1330, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 9, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3221, "End Page": 3229, "Article Number": null, "DOI": "10.1039/c6ee01674j", "DOI Link": "http://dx.doi.org/10.1039/c6ee01674j", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000386336200026", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yin, Y; Han, JC; Zhang, YM; Zhang, XH; Xu, P; Yuan, Q; Samad, L; Wang, XJ; Wang, Y; Zhang, ZH; Zhang, P; Cao, XZ; Song, B; Jin, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yin, Ying; Han, Jiecai; Zhang, Yumin; Zhang, Xinghong; Xu, Ping; Yuan, Quan; Samad, Leith; Wang, Xianjie; Wang, Yi; Zhang, Zhihua; Zhang, Peng; Cao, Xingzhong; Song, Bo; Jin, Song", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Contributions of Phase, Sulfur Vacancies, and Edges to the Hydrogen Evolution Reaction Catalytic Activity of Porous Molybdenum Disulfide nullosheets", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Molybdenum disulfide (MoS2) is a promising nonprecious catalyst for the hydrogen evolution reaction (HER) that has been extensively studied due to its excellent performance, but the lack of understanding of the factors that impact its catalytic activity hinders further design and enhancement of MoS2-based electrocatalysts. Here, by using novel porous (holey) metallic 1T phase MoS2 nullosheets synthesized by a liquid-ammonia-assisted lithiation route, we systematically investigated the contributions of crystal structure (phase), edges, and sulfur vacancies (S-vacancies) to the catalytic activity toward HER from five representative MoS2 nullosheet samples, including 2H and IT phase, porous 2H and IT phase, and sulfur-compensated porous 2H phase. Superior HER catalytic activity was achieved in the porous IT phase MoS2 nullosheets that have even more edges and S-vacancies than conventional 1T phase MoS2. A comparative study revealed that the phase serves as the key role in determining the HER performance, as IT phase MoS2 always outperforms the corresponding 2H phase MoS2 samples, and that both edges and S-vacancies also contribute significantly to the catalytic activity in porous MoS2 samples. Then, using combined defect characterization techniques of electron spin resonullce spectroscopy and positron annihilation lifetime spectroscopy to quantify the S-vacancies, the contributions of each factor were individually elucidated. This study presents new insights and opens up new avenues for designing electrocatalysts based on MoS2 or other layered materials with enhanced HER performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1095, "Times Cited, All Databases": 1163, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 29", "Publication Year": 2016, "Volume": 138, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7965, "End Page": 7972, "Article Number": null, "DOI": "10.1021/jacs.6b03714", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b03714", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378984300030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bharti, B; Kumar, S; Lee, HN; Kumar, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bharti, Bandna; Kumar, Santosh; Lee, Heung-No; Kumar, Rajesh", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Formation of oxygen vacancies and Ti3+ state in TiO2 thin film and enhanced optical properties by air plasma treatment", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This is the first time we report that simply air plasma treatment can also enhances the optical absorbance and absorption region of titanium oxide (TiO2) films, while keeping them transparent. TiO2 thin films having moderate doping of Fe and Co exhibit significant enhancement in the aforementioned optical properties upon air plasma treatment. The moderate doping could facilitate the formation of charge trap centers or avoid the formation of charge recombination centers. Variation in surface species viz. Ti3+, Ti4+, O2-, oxygen vacancies, OH group and optical properties was studied using X-ray photon spectroscopy (XPS) and UV-Vis spectroscopy. The air plasma treatment caused enhanced optical absorbance and optical absorption region as revealed by the formation of Ti3+ and oxygen vacancies in the band gap of TiO2 films. The samples were treated in plasma with varying treatment time from 0 to 60 seconds. With the increasing treatment time, Ti3+ and oxygen vacancies increased in the Fe and Co doped TiO2 films leading to increased absorbance; however, the increase in optical absorption region/red shift (from 3.22 to 3.00 eV) was observed in Fe doped TiO2 films, on the contrary Co doped TiO2 films exhibited blue shift (from 3.36 to 3.62 eV) due to Burstein Moss shift.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1122, "Times Cited, All Databases": 1152, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 30", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 32355, "DOI": "10.1038/srep32355", "DOI Link": "http://dx.doi.org/10.1038/srep32355", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000382157500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chao, DL; Zhu, CR; Yang, PH; Xia, XH; Liu, JL; Wang, J; Fan, XF; Savilov, SV; Lin, JY; Fan, HJ; Shen, ZX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chao, Dongliang; Zhu, Changrong; Yang, Peihua; Xia, Xinhui; Liu, Jilei; Wang, Jin; Fan, Xiaofeng; Savilov, Serguei V.; Lin, Jianyi; Fan, Hong Jin; Shen, Ze Xiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Array of nullosheets render ultrafast and high-capacity Na-ion storage by tunable pseudocapacitance", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sodium-ion batteries are a potentially low-cost and safe alternative to the prevailing lithium-ion battery technology. However, it is a great challenge to achieve fast charging and high power density for most sodium-ion electrodes because of the sluggish sodiation kinetics. Here we demonstrate a high-capacity and high-rate sodium-ion anode based on ultrathin layered tin(II) sulfide nullostructures, in which a maximized extrinsic pseudocapacitance contribution is identified and verified by kinetics analysis. The graphene foam supported tin(II) sulfide nulloarray anode delivers a high reversible capacity of similar to 1,100 mAhg(-1) at 30 mA g (-1) and similar to 420 mAh g(-1) at 30 A g(-1), which even outperforms its lithium-ion storage performance. The surface-dominated redox reaction rendered by our tailored ultrathin tin(II) sulfide nullostructures may also work in other layered materials for high-performance sodium-ion storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1196, "Times Cited, All Databases": 1215, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 12122, "DOI": "10.1038/ncomms12122", "DOI Link": "http://dx.doi.org/10.1038/ncomms12122", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379114900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, MF; Zhao, ZP; Cheng, T; Fortunelli, A; Chen, CY; Yu, R; Zhang, QH; Gu, L; Merinov, BV; Lin, ZY; Zhu, EB; Yu, T; Jia, QY; Guo, JH; Zhang, L; Goddard, WA ; Huang, Y; Duan, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Mufan; Zhao, Zipeng; Cheng, Tao; Fortunelli, Alessandro; Chen, Chih-Yen; Yu, Rong; Zhang, Qinghua; Gu, Lin; Merinov, Boris V.; Lin, Zhaoyang; Zhu, Enbo; Yu, Ted; Jia, Qingying; Guo, Jinghua; Zhang, Liang; Goddard, William A., III; Huang, Yu; Duan, Xiangfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrafine jagged platinum nullowires enable ultrahigh mass activity for the oxygen reduction reaction", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Improving the platinum (9Pt) mass activity for the oxygen reduction reaction (ORR) requires optimization of both the specific activity and the electrochemically active surface area (ECSA). We found that solution-synthesized Pt/NiO core/shell nullowires can be converted into PtNi alloy nullowires through a thermal annealing process and then transformed into jagged Pt nullowires via electrochemical dealloying. The jagged nullowires exhibit an ECSA of 118 square meters per gram of Pt and a specific activity of 11.5 milliamperes per square centimeter for ORR 9 (at 0.9 volts versus reversible hydrogen electrode), yielding a mass activity of 13.6 amperes per milligram of Pt, nearly double previously reported best values. Reactive molecular dynamics simulations suggest that highly stressed, undercoordinated rhombus-rich surface configurations of the jagged nullowires enhance ORR activity versus more relaxed surfaces.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1346, "Times Cited, All Databases": 1413, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 16", "Publication Year": 2016, "Volume": 354, "Issue": 6318, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1414, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aaf9050", "DOI Link": "http://dx.doi.org/10.1126/science.aaf9050", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000390261300041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Eperon, GE; Leijtens, T; Bush, KA; Prasanna, R; Green, T; Wang, JTW; McMeekin, DP; Volonakis, G; Milot, RL; May, R; Palmstrom, A; Slotcavage, DJ; Belisle, RA; Patel, JB; Parrott, ES; Sutton, RJ; Ma, W; Moghadam, F; Conings, B; Babayigit, A; Boyen, HG; Bent, S; Giustino, F; Herz, LM; Johnston, MB; McGehee, MD; Snaith, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Eperon, Giles E.; Leijtens, Tomas; Bush, Kevin A.; Prasanna, Rohit; Green, Thomas; Wang, Jacob Tse-Wei; McMeekin, David P.; Volonakis, George; Milot, Rebecca L.; May, Richard; Palmstrom, Axel; Slotcavage, Daniel J.; Belisle, Rebecca A.; Patel, Jay B.; Parrott, Elizabeth S.; Sutton, Rebecca J.; Ma, Wen; Moghadam, Farhad; Conings, Bert; Babayigit, Aslihan; Boyen, Hans-Gerd; Bent, Stacey; Giustino, Feliciano; Herz, Laura M.; Johnston, Michael B.; McGehee, Michael D.; Snaith, Henry J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Perovskite-perovskite tandem photovoltaics with optimized band gaps", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We demonstrate four-and two-terminal perovskite-perovskite tandem solar cells with ideally matched band gaps. We develop an infrared-absorbing 1.2-electron volt band-gap perovskite, FA(0.75)Cs(0.25)Sn(0.5)Pb(0.5)I(3), that can deliver 14.8% efficiency. By combining this material with a wider-band gap FA(0.83)Cs(0.17)Pb(I0.5Br0.5)(3) material, we achieve monolithic two-terminal tandem efficiencies of 17.0% with > 1.65-volt open-circuit voltage. We also make mechanically stacked four-terminal tandem cells and obtain 20.3% efficiency. Notably, we find that our infrared-absorbing perovskite cells exhibit excellent thermal and atmospheric stability, not previously achieved for Sn-based perovskites. This device architecture and materials set will enable all-perovskite thin-film solar cells to reach the highest efficiencies in the long term at the lowest costs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1224, "Times Cited, All Databases": 1316, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 18", "Publication Year": 2016, "Volume": 354, "Issue": 6314, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 861, "End Page": 865, "Article Number": null, "DOI": "10.1126/science.aaf9717", "DOI Link": "http://dx.doi.org/10.1126/science.aaf9717", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000388531900034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ye, GL; Gong, YJ; Lin, JH; Li, B; He, YM; Pantelides, ST; Zhou, W; Vajtai, R; Ajayan, PM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ye, Gonglan; Gong, Yongji; Lin, Junhao; Li, Bo; He, Yongmin; Pantelides, Sokrates T.; Zhou, Wu; Vajtai, Robert; Ajayan, Pulickel M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Defects Engineered Monolayer MoS2 for Improved Hydrogen Evolution Reaction", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MoS2 is a promising and low-cost material for electrochemical hydrogen production due to its high activity and stability during the reaction. However, the efficiency of hydrogen production is limited by the amount of active sites, for example, edges, in MoS2. Here, we demonstrate that oxygen plasma exposure and hydrogen treatment on pristine monolayer MoS2 could introduce more active sites via the formation of defects within the monolayer, leading to a high density of exposed edges and a significant improvement of the hydrogen evolution activity. These as-fabricated defects are characterized at the scale from macroscopic continuum to discrete atoms. Our work represents a facile method to increase the hydrogen production in electrochemical reaction of MoS2 via defect engineering, and helps to understand the catalytic properties of MoS2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1073, "Times Cited, All Databases": 1139, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 16, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1097, "End Page": 1103, "Article Number": null, "DOI": "10.1021/acs.nullolett.5b04331", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.5b04331", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000370215200042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wright, AD; Verdi, C; Milot, RL; Eperon, GE; Pérez-Osorio, MA; Snaith, HJ; Giustino, F; Johnston, MB; Herz, LM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wright, Adam D.; Verdi, Carla; Milot, Rebecca L.; Eperon, Giles E.; Perez-Osorio, Miguel A.; Snaith, Henry J.; Giustino, Feliciano; Johnston, Michael B.; Herz, Laura M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electron-phonon coupling in hybrid lead halide perovskites", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phonon scattering limits charge-carrier mobilities and governs emission line broadening in hybrid metal halide perovskites. Establishing how charge carriers interact with phonons in these materials is therefore essential for the development of high-efficiency perovskite photovoltaics and low-cost lasers. Here we investigate the temperature dependence of emission line broadening in the four commonly studied formamidinium and methylammonium perovskites, HC(NH2)(2)PbI3, HC(NH2)(2)PbBr3, CH3NH3PbI3 and CH3NH3PbBr3, and discover that scattering from longitudinal optical phonons via the Frohlich interaction is the dominullt source of electron-phonon coupling near room temperature, with scattering off acoustic phonons negligible. We determine energies for the interacting longitudinal optical phonon modes to be 11.5 and 15.3 meV, and Frohlich coupling constants of similar to 40 and 60 meV for the lead iodide and bromide perovskites, respectively. Our findings correlate well with first-principles calculations based on many-body perturbation theory, which underlines the suitability of an electronic band-structure picture for describing charge carriers in hybrid perovskites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1065, "Times Cited, All Databases": 1128, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11755, "DOI": "10.1038/ncomms11755", "DOI Link": "http://dx.doi.org/10.1038/ncomms11755", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000376674500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Halim, J; Kota, S; Lukatskaya, MR; Naguib, M; Zhao, MQ; Moon, EJ; Pitock, J; nullda, J; May, SJ; Gogotsi, Y; Barsoum, MW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Halim, Joseph; Kota, Sankalp; Lukatskaya, Maria R.; Naguib, Michael; Zhao, Meng-Qiang; Moon, Eun Ju; Pitock, Jeremy; nullda, Jagjit; May, Steven J.; Gogotsi, Yury; Barsoum, Michel W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis and Characterization of 2D Molybdenum Carbide (MXene)", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Large scale synthesis and delamination of 2D Mo2CTx (where T is a surface termination group) has been achieved by selectively etching gallium from the recently discovered nullolaminated, ternary transition metal carbide Mo2Ga2C. Different synthesis and delamination routes result in different flake morphologies. The resistivity of free-standing Mo2CTx films increases by an order of magnitude as the temperature is reduced from 300 to 10 K, suggesting semiconductor-like behavior of this MXene, in contrast to Ti3C2Tx which exhibits metallic behavior. At 10 K, the magnetoresistance is positive. Additionally, changes in electronic transport are observed upon annealing of the films. When 2 mu m thick films are tested as electrodes in supercapacitors, capacitances as high as 700 F cm(-3) in a 1 M sulfuric acid electrolyte and high capacity retention for at least 10,000 cycles at 10 A g(-1) are obtained. Free-standing Mo2CTx films, with approximate to 8 wt% carbon nullotubes, perform well when tested as an electrode material for Li-ions, especially at high rates. At 20 and 131 C cycling rates, stable reversible capacities of 250 and 76 mAh g(-1), respectively, are achieved for over 1000 cycles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1042, "Times Cited, All Databases": 1114, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 10", "Publication Year": 2016, "Volume": 26, "Issue": 18, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3118, "End Page": 3127, "Article Number": null, "DOI": "10.1002/adfm.201505328", "DOI Link": "http://dx.doi.org/10.1002/adfm.201505328", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377591500015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, HB; Miao, JW; Hung, SF; Chen, JZ; Tao, HB; Wang, XZ; Zhang, LP; Chen, R; Gao, JJ; Chen, HM; Dai, LM; Liu, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Hong Bin; Miao, Jianwei; Hung, Sung-Fu; Chen, Jiazang; Tao, Hua Bing; Wang, Xizu; Zhang, Liping; Chen, Rong; Gao, Jiajian; Chen, Hao Ming; Dai, Liming; Liu, Bin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identification of catalytic sites for oxygen reduction and oxygen evolution in N-doped graphene materials: Development of highly efficient metal-free bifunctional electrocatalyst", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) are critical to renewable energy conversion and storage technologies. Heteroatom-doped carbon nullomaterials have been reported to be efficient metal-free electrocatalysts for ORR in fuel cells for energy conversion, as well as ORR and OER in metal-air batteries for energy storage. We reported that metal-free three-dimensional (3D) graphene nulloribbon networks (N-GRW) doped with nitrogen exhibited superb bifunctional electrocatalytic activities for both ORR and OER, with an excellent stability in alkaline electrolytes (for example, KOH). For the first time, it was experimentally demonstrated that the electron-donating quaternary N sites were responsible for ORR, whereas the electron-withdrawing pyridinic N moieties in N-GRW served as active sites for OER. The unique 3D nulloarchitecture provided a high density of the ORR and OER active sites and facilitated the electrolyte and electron transports. As a result, the as-prepared N-GRW holds great potential as a low-cost, highly efficient air cathode in rechargeable metal-air batteries. Rechargeable zinc-air batteries with the N-GRW air electrode in a two-electrode configuration exhibited an open-circuit voltage of 1.46 V, a specific capacity of 873 mAh g(-1), and a peak power density of 65 mW cm(-2), which could be continuously charged and discharged with an excellent cycling stability. Our work should open up new avenues for the development of various carbon-based metal-free bifunctional electrocatalysts of practical significance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1086, "Times Cited, All Databases": 1123, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2016, "Volume": 2, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1501122", "DOI": "10.1126/sciadv.1501122", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1501122", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000380072100008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, SE; Deng, ZP; Li, MX; Jiang, BJ; Tian, CG; Pan, QJ; Fu, HG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Shien; Deng, Zhaopeng; Li, Mingxia; Jiang, Baojiang; Tian, Chungui; Pan, Qingjiang; Fu, Honggang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phosphorus-Doped Carbon Nitride Tubes with a Layered Micro-nullostructure for Enhanced Visible-Light Photocatalytic Hydrogen Evolution", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Phosphorus-doped hexagonal tubular carbon nitride (P-TCN) with the layered stacking structure was obtained from a hexagonal rod-like single crystal supramolecular precursor (monoclinic, C2/m). The production process of P-TCN involves two steps: 1) the precursor was prepared by self-assembly of melamine with cyanuric acid from in situ hydrolysis of melamine under phosphorous acid-assisted hydrothermal conditions; 2) the pyrolysis was initiated at the center of precursor under heating, thus giving the hexagonal P-TCN. The tubular structure favors the enhancement of light scattering and active sites. Meanwhile, the introduction of phosphorus leads to a narrow band gap and increased electric conductivity. Thus, the P-TCN exhibited a high hydrogen evolution rate of 67 mu mol.h(-1) (0.1 g catalyst, lambda > 420 nm) in the presence of sacrificial agents, and an apparent quantum efficiency of 5.68% at 420 nm, which is better than most of bulk g-C3N4 reported.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1032, "Times Cited, All Databases": 1059, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 26", "Publication Year": 2016, "Volume": 55, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1830, "End Page": 1834, "Article Number": null, "DOI": "10.1002/anie.201508505", "DOI Link": "http://dx.doi.org/10.1002/anie.201508505", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000369854000043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, C; Ni, X; Ge, H; Sun, XC; Chen, YB; Lu, MH; Liu, XP; Chen, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Cheng; Ni, Xu; Ge, Hao; Sun, Xiao-Chen; Chen, Yan-Bin; Lu, Ming-Hui; Liu, Xiao-Ping; Chen, Yan-Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Acoustic topological insulator and robust one-way sound transport", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topological design of materials enables topological symmetries and facilitates unique backscattering-immune wave transport(1-26). In airborne acoustics, however, the intrinsic longitudinal nature of sound polarization makes the use of the conventional spin-orbital interaction mechanism impossible for achieving band inversion. The topological gauge flux is then typically introduced with a moving background in theoretical models(19-22). Its practical implementation is a serious challenge, though, due to inherent dynamic instabilities and noise. Here we realize the inversion of acoustic energy bands at a double Dirac cone(15,27,28) and provide an experimental demonstration of an acoustic topological insulator. By manipulating the hopping interaction of neighbouring 'atoms' in this new topological material, we successfully demonstrate the acoustic quantum spin Hall effect, characterized by robust pseudospin-dependent one-way edge sound transport. Our results are promising for the exploration of new routes for experimentally studying topological phenomena and related applications, for example, sound-noise reduction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 989, "Times Cited, All Databases": 1056, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2016, "Volume": 12, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1124, "End Page": "+", "Article Number": null, "DOI": "10.1038/NPHYS3867", "DOI Link": "http://dx.doi.org/10.1038/NPHYS3867", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389133800014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Holliday, S; Ashraf, RS; Wadsworth, A; Baran, D; Yousaf, SA; Nielsen, CB; Tan, CH; Dimitrov, SD; Shang, ZR; Gasparini, N; Alamoudi, M; Laquai, F; Brabec, CJ; Salleo, A; Durrant, JR; McCulloch, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Holliday, Sarah; Ashraf, Raja Shahid; Wadsworth, Andrew; Baran, Derya; Yousaf, Syeda Amber; Nielsen, Christian B.; Tan, Ching-Hong; Dimitrov, Stoichko D.; Shang, Zhengrong; Gasparini, Nicola; Alamoudi, Maha; Laquai, Frederic; Brabec, Christoph J.; Salleo, Alberto; Durrant, James R.; McCulloch, Iain", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-efficiency and air-stable P3HT-based polymer solar cells with a new non-fullerene acceptor", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solution-processed organic photovoltaics (OPV) offer the attractive prospect of low-cost, light-weight and environmentally benign solar energy production. The highest efficiency OPV at present use low-bandgap donor polymers, many of which suffer from problems with stability and synthetic scalability. They also rely on fullerene-based acceptors, which themselves have issues with cost, stability and limited spectral absorption. Here we present a new non-fullerene acceptor that has been specifically designed to give improved performance alongside the wide bandgap donor poly(3-hexylthiophene), a polymer with significantly better prospects for commercial OPV due to its relative scalability and stability. Thanks to the well-matched optoelectronic and morphological properties of these materials, efficiencies of 6.4% are achieved which is the highest reported for fullerene-free P3HT devices. In addition, dramatically improved air stability is demonstrated relative to other high-efficiency OPV, showing the excellent potential of this new material combination for future technological applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1048, "Times Cited, All Databases": 1120, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11585, "DOI": "10.1038/ncomms11585", "DOI Link": "http://dx.doi.org/10.1038/ncomms11585", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000377909600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cassabois, G; Valvin, P; Gil, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cassabois, G.; Valvin, P.; Gil, B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hexagonal boron nitride is an indirect bandgap semiconductor", "Source Title": "NATURE PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hexagonal boron nitride is a wide bandgap semiconductor with very high thermal and chemical stability that is used in devices operating under extreme conditions. The growth of high-purity crystals has recently revealed the potential of this material for deep ultraviolet emission, with intense emission around 215 nm. In the last few years, hexagonal boron nitride has been attracting even more attention with the emergence of two-dimensional atomic crystals and van der Waals heterostructures, initiated with the discovery of graphene. Despite this growing interest and a seemingly simple structure, the basic questions of the bandgap nature and value are still controversial. Here, we resolve this long-debated issue by demonstrating evidence for an indirect bandgap at 5.955 eV by means of optical spectroscopy. We demonstrate the existence of phonon-assisted optical transitions and we measure an exciton binding energy of about 130 meV by two-photon spectroscopy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 992, "Times Cited, All Databases": 1107, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2016, "Volume": 10, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 262, "End Page": "+", "Article Number": null, "DOI": "10.1038/NPHOTON.2015.277", "DOI Link": "http://dx.doi.org/10.1038/NPHOTON.2015.277", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000372978900017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ni, G; Li, G; Boriskina, SV; Li, HX; Yang, WL; Zhang, TJ; Chen, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ni, George; Li, Gabriel; Boriskina, Svetlana V.; Li, Hongxia; Yang, Weilin; Zhang, TieJun; Chen, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Steam generation under one sun enabled by a floating structure with thermal concentration", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Harvesting solar energy as heat has many applications, such as power generation, residential water heating, desalination, distillation and wastewater treatment. However, the solar flux is diffuse, and often requires optical concentration, a costly component, to generate the high temperatures needed for some of these applications. Here we demonstrate a floating solar receiver capable of generating 100 degrees C steam under ambient air conditions without optical concentration. The high temperatures are achieved by using thermal concentration and heat localization, which reduce the convective, conductive and radiative heat losses. This demonstration of a low-cost and scalable solar vapour generator holds the promise of significantly expanding the application domain and reducing the cost of solar thermal systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 986, "Times Cited, All Databases": 1037, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 22", "Publication Year": 2016, "Volume": 1, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 16126, "DOI": "10.1038/NENERGY.2016.126", "DOI Link": "http://dx.doi.org/10.1038/NENERGY.2016.126", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000394184700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shearer, GC; Chavan, S; Bordiga, S; Svelle, S; Olsbye, U; Lillerud, KP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shearer, Greig C.; Chavan, Sachin; Bordiga, Silvia; Svelle, Stian; Olsbye, Unni; Lillerud, Karl Petter", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Defect Engineering: Tuning the Porosity and Composition of the Metal-Organic Framework UiO-66 via Modulated Synthesis", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Presented in this paper is a deep investigation into the defect chemistry of UiO-66 when synthesized in the presence of monocarboxylic acid modulators under the most commonly employed conditions. We unequivocally demonstrate that missing cluster defects are the predominullt defect and that their concentration (and thus the porosity and composition of the material) can be tuned to a remarkable extent by altering the concentration and/or acidity of the modulator. Finally, we attempt to rationalize these observations by speculating on the underlying solution chemistry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1032, "Times Cited, All Databases": 1107, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 14", "Publication Year": 2016, "Volume": 28, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3749, "End Page": 3761, "Article Number": null, "DOI": "10.1021/acs.chemmater.6b00602", "DOI Link": "http://dx.doi.org/10.1021/acs.chemmater.6b00602", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378016400025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, MX; Pan, Y; Yuan, FP; Zhu, YT; Wu, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Muxin; Pan, Yue; Yuan, Fuping; Zhu, Yuntian; Wu, Xiaolei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Back stress strengthening and strain hardening in gradient structure", "Source Title": "MATERIALS RESEARCH LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report significant back stress strengthening and strain hardening in gradient structured (GS) interstitial-free (IF) steel. Back stress is long-range stress caused by the pileup of geometrically necessary dislocations (GNDs). A simple equation and a procedure are developed to calculate back stress basing on its formation physics from the tensile unloading-reloading hysteresis loop. The gradient structure has mechanical incompatibility due to its grain size gradient. This induces strain gradient, which needs to be accommodated by GNDs. Back stress not only raises the yield strength but also significantly enhances strain hardening to increase the ductility. [GRAPHICS] .", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1013, "Times Cited, All Databases": 1054, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 4, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 145, "End Page": 151, "Article Number": null, "DOI": "10.1080/21663831.2016.1153004", "DOI Link": "http://dx.doi.org/10.1080/21663831.2016.1153004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000385011000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feng, JD; Graf, M; Liu, K; Ovchinnikov, D; Dumcenco, D; Heiranian, M; nulldigana, V; Aluru, NR; Kis, A; Radenovic, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feng, Jiandong; Graf, Michael; Liu, Ke; Ovchinnikov, Dmitry; Dumcenco, Dumitru; Heiranian, Mohammad; nulldigana, Vishal; Aluru, Narayana R.; Kis, Andras; Radenovic, Aleksandra", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-layer MoS2 nullopores as nullopower generators", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Making use of the osmotic pressure difference between fresh water and seawater is an attractive, renewable and clean way to generate power and is known as 'blue energy'(1-3). Another electrokinetic phenomenon, called the streaming potential, occurs when an electrolyte is driven through narrow pores either by a pressure gradient(4) or by an osmotic potential resulting from a salt concentration gradient(5). For this task, membranes made of two-dimensional materials are expected to be the most efficient, because water transport through a membrane scales inversely with membrane thickness(5-7). Here we demonstrate the use of single-layer molybdenum disulfide (MoS2) nullopores as osmotic nullopower generators. We observe a large, osmotically induced current produced from a salt gradient with an estimated power density of up to 10(6) watts per square metre-a current that can be attributed mainly to the atomically thin membrane of MoS2. Low power requirements for nulloelectronic and optoelectric devices can be provided by a neighbouring nullogenerator that harvests energy from the local environment(8-11)-for example, a piezoelectric zinc oxide nullowire array(8) or single-layer MoS2 (ref. 12). We use our MoS2 nullopore generator to power a MoS2 transistor, thus demonstrating a self-powered nullosystem.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 944, "Times Cited, All Databases": 1001, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 11", "Publication Year": 2016, "Volume": 536, "Issue": 7615, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 197, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature18593", "DOI Link": "http://dx.doi.org/10.1038/nature18593", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000381472100033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Koh, A; Kang, D; Xue, Y; Lee, S; Pielak, RM; Kim, J; Hwang, T; Min, S; Banks, A; Bastien, P; Manco, MC; Wang, L; Ammann, KR; Jang, KI; Won, P; Han, S; Ghaffari, R; Paik, U; Slepian, MJ; Balooch, G; Huang, YG; Rogers, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Koh, Ahyeon; Kang, Daeshik; Xue, Yeguang; Lee, Seungmin; Pielak, Rafal M.; Kim, Jeonghyun; Hwang, Taehwan; Min, Seunghwan; Banks, Anthony; Bastien, Philippe; Manco, Megan C.; Wang, Liang; Ammann, Kaitlyn R.; Jang, Kyung-In; Won, Phillip; Han, Seungyong; Ghaffari, Roozbeh; Paik, Ungyu; Slepian, Marvin J.; Balooch, Guive; Huang, Yonggang; Rogers, John A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A soft, wearable microfluidic device for the capture, storage, and colorimetric sensing of sweat", "Source Title": "SCIENCE TRANSLATIONAL MEDICINE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Capabilities in health monitoring enabled by capture and quantitative chemical analysis of sweat could complement, or potentially obviate the need for, approaches based on sporadic assessment of blood samples. Established sweat monitoring technologies use simple fabric swatches and are limited to basic analysis in controlled laboratory or hospital settings. We present a collection of materials and device designs for soft, flexible, and stretchable microfluidic systems, including embodiments that integrate wireless communication electronics, which can intimately and robustly bond to the surface of the skin without chemical and mechanical irritation. This integration defines access points for a small set of sweat glands such that perspiration spontaneously initiates routing of sweat through a microfluidic network and set of reservoirs. Embedded chemical analyses respond in colorimetric fashion to markers such as chloride and hydronium ions, glucose, and lactate. Wireless interfaces to digital image capture hardware serve as a means for quantitation. Human studies demonstrated the functionality of this microfluidic device during fitness cycling in a controlled environment and during long-distance bicycle racing in arid, outdoor conditions. The results include quantitative values for sweat rate, total sweat loss, pH, and concentration of chloride and lactate.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1001, "Times Cited, All Databases": 1107, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 23", "Publication Year": 2016, "Volume": 8, "Issue": 366, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "366ra165", "DOI": "10.1126/scitranslmed.aaf2593", "DOI Link": "http://dx.doi.org/10.1126/scitranslmed.aaf2593", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Cell Biology; Research & Experimental Medicine", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389449400005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shapeev, AV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shapeev, Alexander V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MOMENT TENSOR POTENTIALS: A CLASS OF SYSTEMATICALLY IMPROVABLE INTERATOMIC POTENTIALS", "Source Title": "MULTISCALE MODELING & SIMULATION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Density functional theory offers a very accurate way of computing materials properties from first principles. However, it is too expensive for modeling large-scale molecular systems whose properties are, in contrast, computed using interatomic potentials. The present paper considers, from a mathematical point of view, the problem of constructing interatomic potentials that approximate a given quantum-mechanical interaction model. In particular, a new class of systematically improvable potentials is proposed, analyzed, and tested on an existing quantum-mechanical database.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 944, "Times Cited, All Databases": 1033, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2016, "Volume": 14, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1153, "End Page": 1173, "Article Number": null, "DOI": "10.1137/15M1054183", "DOI Link": "http://dx.doi.org/10.1137/15M1054183", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Mathematics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000388444300008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, FD; Zhu, YZ; He, XF; Mo, YF; Wang, CS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Fudong; Zhu, Yizhou; He, Xingfeng; Mo, Yifei; Wang, Chunsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrochemical Stability of Li10GeP2S12 and Li7La3Zr2O12 Solid Electrolytes", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electrochemical stability window of solid electrolyte is overestimated by the conventional experimental method using a Li/electrolyte/inert metal semiblocking electrode because of the limited contact area between solid electrolyte and inert metal. Since the battery is cycled in the overestimated stability window, the decomposition of the solid electrolyte at the interfaces occurs but has been ignored as a cause for high interfacial resistances in previous studies, limiting the performance improvement of the bulk-type solid-state battery despite the decades of research efforts. Thus, there is an urgent need to identify the intrinsic stability window of the solid electrolyte. The thermodynamic electrochemical stability window of solid electrolytes is calculated using first principles computation methods, and an experimental method is developed to measure the intrinsic electrochemical stability window of solid electrolytes using a Li/electrolyte/electrolyte-carbon cell. The most promising solid electrolytes, Li10GeP2S12 and cubic Li-garnet Li7La3Zr2O12, are chosen as the model materials for sulfide and oxide solid electrolytes, respectively. The results provide valuable insights to address the most challenging problems of the interfacial stability and resistance in high-performance solid-state batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 911, "Times Cited, All Databases": 988, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 20", "Publication Year": 2016, "Volume": 6, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1501590, "DOI": "10.1002/aenm.201501590", "DOI Link": "http://dx.doi.org/10.1002/aenm.201501590", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000374703900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rasool, K; Helal, M; Ali, A; Ren, CE; Gogotsi, Y; Mahmoud, KA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rasool, Kashif; Helal, Mohamed; Ali, Adnull; Ren, Chang E.; Gogotsi, Yury; Mahmoud, Khaled A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Antibacterial Activity of Ti3C2Tx MXene", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MXenes are a family of atomically thin, two-dimensional (2D) transition metal carbides and carbonitrides with many attractive properties. Two-dimensional Ti3C2TX (MXene) has been recently explored for applications in water desalination/purification membranes. A. major success indicator for any water treatment membrane is the resistance to biofouling. To validate this and to understand better the health and environmental impacts of the new 2D carbides, we investigated the antibacterial properties of single- and few-Iayer Ti3C2TX MXene flakes in colloidal solution. The antibacterial properties of Ti3C2TX were tested against Escherichia coli (E.,coli) and Bacillus subtilis (B. subtilis) by using bacterial growth curves based on optical densities (OD) and colonies growth on agar nutritive plates. Ti3C2T shows a higher antibacterial efficiency toward both Gram-negative E. coli and Gram-positive. B. subtilis compared with graphene oxide (GO), which has been widely reported as an antibacterial agent. Concentration dependent antibacterial activity was observed and more than 98% bacterial cell viability loss was found at 200 jzg/mL Ti3C2TX for both bacterial cells within 4 h of exposure, as confirmed by colony forming unit (CFU) and regrowth curve. Antibacterial mechanism investigation by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) coupled with lactate dehydrogenase (LDH) release assay indicated the damage to the cell membrane, which resulted in release of cytoplasmic materials from the bacterial cells. Reactive oxygen species (ROS) dependent and independent stress induction by Ti3C2TX was investigated in two separate abiotic assays. MXenes are expected to be resistant to biofouling and offer bactericidal properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1013, "Times Cited, All Databases": 1055, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 10, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3674, "End Page": 3684, "Article Number": null, "DOI": "10.1021/acsnullo.6b00181", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.6b00181", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000372855400072", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, Y; Jiao, Y; Zhu, YH; Li, LH; Han, Y; Chen, Y; Jaroniec, M; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Yao; Jiao, Yan; Zhu, Yihan; Li, Lu Hua; Han, Yu; Chen, Ying; Jaroniec, Mietek; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High Electrocatalytic Hydrogen Evolution Activity of an Anomalous Ruthenium Catalyst", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen evolution reaction (HER) is a critical process due to its fundamental role in electrocatalysis. Practically, the development of high-performance electrocatalysts for HER in alkaline media is of great importance for the conversion of renewable energy to hydrogen fuel via photoelectrochemical water splitting. However, both mechanistic exploration and materials development for HER under alkaline conditions are very limited. Precious. Pt metal, which still serves as the state-of-the-art catalyst for HER, is unable to guarantee a sustainable hydrogen supply. Here we report an anomalously structured Ru catalyst that shows 2.5 times higher hydrogen generation rate than Pt and is among the most active HER electrocatalysts yet reported in alkaline solutions. The identification of new face-centered cubic crystallographic structure of Ru nulloparticles was investigated by high-resolution transmission electron microscopy imaging, and its formation mechanism was revealed by spectroscopic characterization and theoretical analysis. For the first time, it is found that the Ru nullo catalyst showed a pronounced effect of the crystal structure on the electrocatalytic activity tested under different conditions. The combination of electrochemical reaction rate measurements and density functional theory computation shows that the high activity of anomalous Ru catalyst in alkaline solution originates from its suitable adsorption energies to some key reaction intermediates and reaction kinetics in the HER process.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 918, "Times Cited, All Databases": 941, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 14", "Publication Year": 2016, "Volume": 138, "Issue": 49, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 16174, "End Page": 16181, "Article Number": null, "DOI": "10.1021/jacs.6b11291", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b11291", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389962800057", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuk, H; Zhang, T; Lin, ST; Parada, GA; Zhao, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuk, Hyunwoo; Zhang, Teng; Lin, Shaoting; Parada, German Alberto; Zhao, Xuanhe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tough bonding of hydrogels to diverse non-porous surfaces", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In many animals, the bonding of tendon and cartilage to bone is extremely tough (for example, interfacial toughness similar to 800 J m(-2); refs 1,2), yet such tough interfaces have not been achieved between synthetic hydrogels and non-porous surfaces of engineered solids(3-9). Here, we report a strategy to design tough transparent and conductive bonding of synthetic hydrogels containing 90% water to non-porous surfaces of diverse solids, including glass, silicon, ceramics, titanium and aluminium. The design strategy is to anchor the long-chain polymer networks of tough hydrogels covalently to non-porous solid surfaces, which can be achieved by the silanation of such surfaces. Compared with physical interactions, the chemical anchorage results in a higher intrinsic work of adhesion and in significant energy dissipation of bulk hydrogel during detachment, which lead to interfacial toughness values over 1,000 J m(-2). We also demonstrate applications of robust hydrogel-solid hybrids, including hydrogel superglues, mechanically protective hydrogel coatings, hydrogel joints for robotic structures and robust hydrogel-metal conductors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 912, "Times Cited, All Databases": 986, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 15, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 190, "End Page": "+", "Article Number": null, "DOI": "10.1038/NMAT4463", "DOI Link": "http://dx.doi.org/10.1038/NMAT4463", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000368766100023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, JH; Yamada, Y; Sodeyama, K; Chiang, CH; Tateyama, Y; Yamada, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Jianhui; Yamada, Yuki; Sodeyama, Keitaro; Chiang, Ching Hua; Tateyama, Yoshitaka; Yamada, Atsuo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superconcentrated electrolytes for a high-voltage lithium-ion battery", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Finding a viable electrolyte for next-generation 5V-class lithium-ion batteries is of primary importance. A long-standing obstacle has been metal-ion dissolution at high voltages. The LiPF6 salt in conventional electrolytes is chemically unstable, which accelerates transition metal dissolution of the electrode material, yet beneficially suppresses oxidative dissolution of the aluminium current collector; replacing LiPF6 with more stable lithium salts may diminish transition metal dissolution but unfortunately encounters severe aluminium oxidation. Here we report an electrolyte design that can solve this dilemma. By mixing a stable lithium salt LiN(SO2F)(2) with dimethyl carbonate solvent at extremely high concentrations, we obtain an unusual liquid showing a three-dimensional network of anions and solvent molecules that coordinate strongly to Li+ ions. This simple formulation of superconcentrated LiN(SO2F)(2)/dimethyl carbonate electrolyte inhibits the dissolution of both aluminium and transition metal at around 5V, and realizes a high-voltage LiNi0.5Mn1.5O4/graphite battery that exhibits excellent cycling durability, high rate capability and enhanced safety.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 905, "Times Cited, All Databases": 966, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 12032, "DOI": "10.1038/ncomms12032", "DOI Link": "http://dx.doi.org/10.1038/ncomms12032", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379110300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shao, JD; Xie, HH; Huang, H; Li, ZB; Sun, ZB; Xu, YH; Xiao, QL; Yu, XF; Zhao, YT; Zhang, H; Wang, HY; Chu, PK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shao, Jundong; Xie, Hanhan; Huang, Hao; Li, Zhibin; Sun, Zhengbo; Xu, Yanhua; Xiao, Quanlan; Yu, Xue-Feng; Zhao, Yuetao; Zhang, Han; Wang, Huaiyu; Chu, Paul K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Biodegradable black phosphorus-based nullospheres for in vivo photothermal cancer therapy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photothermal therapy (PTT) offers many advantages such as high efficiency and minimal invasiveness, but clinical adoption of PTT nulloagents have been stifled by unresolved concerns such as the biodegradability as well as long-term toxicity. Herein, poly (lactic-co-glycolic acid) (PLGA) loaded with black phosphorus quantum dots (BPQDs) is processed by an emulsion method to produce biodegradable BPQDs/PLGA nullospheres. The hydrophobic PLGA not only isolates the interior BPQDs from oxygen and water to enhance the photothermal stability, but also control the degradation rate of the BPQDs. The in vitro and in vivo experiments demonstrate that the BPQDs/PLGA nullospheres have inappreciable toxicity and good biocompatibility, and possess excellent PTT efficiency and tumour targeting ability as evidenced by highly efficient tumour ablation under near infrared (NIR) laser illumination. These BP-based nullospheres combine biodegradability and biocompatibility with high PTT efficiency, thus promising high clinical potential.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 892, "Times Cited, All Databases": 934, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 12967, "DOI": "10.1038/ncomms12967", "DOI Link": "http://dx.doi.org/10.1038/ncomms12967", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000385456600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bin, HJ; Gao, L; Zhang, ZG; Yang, YK; Zhang, YD; Zhang, CF; Chen, SS; Xue, LW; Yang, C; Xiao, M; Li, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bin, Haijun; Gao, Liang; Zhang, Zhi-Guo; Yang, Yankang; Zhang, Yindong; Zhang, Chunfeng; Chen, Shanshan; Xue, Lingwei; Yang, Changduk; Xiao, Min; Li, Yongfang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "11.4% Efficiency non-fullerene polymer solar cells with trialkylsilyl substituted 2D-conjugated polymer as donor", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Simutaneously high open circuit voltage and high short circuit current density is a big challenge for achieving high efficiency polymer solar cells due to the excitonic nature of organic semdonductors. Herein, we developed a trialkylsilyl substituted 2D-conjugated polymer with the highest occupied molecular orbital level down-shifted by Si-C bond interaction. The polymer solar cells obtained by pairing this polymer with a non-fullerene acceptor demonstrated a high power conversion efficiency of 11.41% with both high open circuit voltage of 0.94 V and high short circuit current density of 17.32 mA cm(-2) benefitted from the complementary absorption of the donor and acceptor, and the high hole transfer efficiency from acceptor to donor although the highest occupied molecular orbital level difference between the donor and acceptor is only 0.11 eV. The results indicate that the alkylsilyl substitution is an effective way in designing high performance conjugated polymer photovoltaic materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 935, "Times Cited, All Databases": 970, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 1", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13651, "DOI": "10.1038/ncomms13651", "DOI Link": "http://dx.doi.org/10.1038/ncomms13651", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000389651800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gild, J; Zhang, Y; Harrington, T; Jiang, S; Hu, T; Quinn, MC; Mellor, WM; Zhou, N; Vecchio, K; Luo, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gild, Joshua; Zhang, Yuanyao; Harrington, Tyler; Jiang, Sicong; Hu, Tao; Quinn, Matthew C.; Mellor, William M.; Zhou, Naixie; Vecchio, Kenneth; Luo, Jian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Entropy Metal Diborides: A New Class of High-Entropy Materials and a New Type of Ultrahigh Temperature Ceramics", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Seven equimolar, five-component, metal diborides were fabricated via high-energy ball milling and spark plasma sintering. Six of them, including (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)B-2, (Hf0.2Zr0.2Ta0.2Mo0.2Ti0.2)B-2, (Hf0.2Zr0.2Mo0.2Nb0.2Ti0.2)B-2, (Hf0.2Mo0.2Ta0.2Nb0.2Ti0.2)B-2, (Mo0.2Zr0.2Ta0.2Nb0.2Ti0.2)B-2, and (Hf0.2Zr0.2Ta0.2Cr0.2Ti0.2)B-2, possess virtually one solid-solution boride phase of the hexagonal AlB2 structure. Revised Hume-Rothery size-difference factors are used to rationalize the formation of high-entropy solid solutions in these metal diborides. Greater than 92% of the theoretical densities have been generally achieved with largely uniform compositions from nulloscale to microscale. Aberration-corrected scanning transmission electron microscopy (AC STEM), with high-angle annular dark-field and annular bright-field (HAADF and ABF) imaging and nulloscale compositional mapping, has been conducted to confirm the formation of 2-D high-entropy metal layers, separated by rigid 2-D boron nets, without any detectable layered segregation along the c-axis. These materials represent a new type of ultra-high temperature ceramics (UHTCs) as well as a new class of high-entropy materials, which not only exemplify the first high-entropy non-oxide ceramics (borides) fabricated but also possess a unique non-cubic (hexagonal) and layered (quasi-2D) high-entropy crystal structure that markedly differs from all those reported in prior studies. Initial property assessments show that both the hardness and the oxidation resistance of these high-entropy metal diborides are generally higher/better than the average performances of five individual metal diborides made by identical fabrication processing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 901, "Times Cited, All Databases": 985, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 29", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 37946, "DOI": "10.1038/srep37946", "DOI Link": "http://dx.doi.org/10.1038/srep37946", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000388791700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deng, MT; Vaitiekenas, S; Hansen, EB; Danon, J; Leijnse, M; Flensberg, K; Nygård, J; Krogstrup, P; Marcus, CM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deng, M. T.; Vaitiekenas, S.; Hansen, E. B.; Danon, J.; Leijnse, M.; Flensberg, K.; Nygard, J.; Krogstrup, P.; Marcus, C. M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Majorana bound state in a coupled quantum-dot hybrid-nullowire system", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hybrid nullowires combining semiconductor and superconductor materials appear well suited for the creation, detection, and control of Majorana bound states (MBSs). We demonstrate the emergence of MBSs from coalescing Andreev bound states (ABSs) in a hybrid InAs nullowire with epitaxial Al, using a quantum dot at the end of the nullowire as a spectrometer. Electrostatic gating tuned the nullowire density to a regime of one or a few ABSs. In an applied axial magnetic field, a topological phase emerges in which ABSs move to zero energy and remain there, forming MBSs. We observed hybridization of the MBS with the end-dot bound state, which is in agreement with a numerical model. The ABS/MBS spectra provide parameters that are useful for understanding topological superconductivity in this system.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 863, "Times Cited, All Databases": 928, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 23", "Publication Year": 2016, "Volume": 354, "Issue": 6319, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1557, "End Page": 1562, "Article Number": null, "DOI": "10.1126/science.aaf3961", "DOI Link": "http://dx.doi.org/10.1126/science.aaf3961", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000390254300045", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mefford, JT; Rong, X; Abakumov, AM; Hardin, WG; Dai, S; Kolpak, AM; Johnston, KP; Stevenson, KJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mefford, J. Tyler; Rong, Xi; Abakumov, Artem M.; Hardin, William G.; Dai, Sheng; Kolpak, Alexie M.; Johnston, Keith P.; Stevenson, Keith J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Water electrolysis on La1-xSrxCoO3-δ perovskite electrocatalysts", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite oxides are attractive candidates as catalysts for the electrolysis of water in alkaline energy storage and conversion systems. However, the rational design of active catalysts has been hampered by the lack of understanding of the mechanism of water electrolysis on perovskite surfaces. Key parameters that have been overlooked include the role of oxygen vacancies, B-O bond covalency, and redox activity of lattice oxygen species. Here we present a series of cobaltite perovskites where the covalency of the Co-O bond and the concentration of oxygen vacancies are controlled through Sr2+ substitution into La1 - xSrxCoO3 - delta. We attempt to rationalize the high activities of La1 - xSrxCoO3 - delta through the electronic structure and participation of lattice oxygen in the mechanism of water electrolysis as revealed through ab initio modelling. Using this approach, we report a material, SrCoO2.7, with a high, room temperature-specific activity and mass activity towards alkaline water electrolysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 919, "Times Cited, All Databases": 966, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11053, "DOI": "10.1038/ncomms11053", "DOI Link": "http://dx.doi.org/10.1038/ncomms11053", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000372721700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, FC; You, L; Seyler, KL; Li, XB; Yu, P; Lin, JH; Wang, XW; Zhou, JD; Wang, H; He, HY; Pantelides, ST; Zhou, W; Sharma, P; Xu, XD; Ajayan, PM; Wang, JL; Liu, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Fucai; You, Lu; Seyler, Kyle L.; Li, Xiaobao; Yu, Peng; Lin, Junhao; Wang, Xuewen; Zhou, Jiadong; Wang, Hong; He, Haiyong; Pantelides, Sokrates T.; Zhou, Wu; Sharma, Pradeep; Xu, Xiaodong; Ajayan, Pulickel M.; Wang, Junling; Liu, Zheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Room-temperature ferroelectricity in CuInP2S6 ultrathin flakes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) materials have emerged as promising candidates for various optoelectronic applications based on their diverse electronic properties, ranging from insulating to superconducting. However, cooperative phenomena such as ferroelectricity in the 2D limit have not been well explored. Here, we report room-temperature ferroelectricity in 2D CuInP2S6 (CIPS) with a transition temperature of similar to 320 K. Switchable polarization is observed in thin CIPS of similar to 4 nm. To demonstrate the potential of this 2D ferroelectric material, we prepare a van der Waals (vdW) ferroelectric diode formed by CIPS/Si heterostructure, which shows good memory behaviour with on/off ratio of similar to 100. The addition of ferroelectricity to the 2D family opens up possibilities for numerous novel applications, including sensors, actuators, non-volatile memory devices, and various vdW heterostructures based on 2D ferroelectricity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 856, "Times Cited, All Databases": 920, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 12357, "DOI": "10.1038/ncomms12357", "DOI Link": "http://dx.doi.org/10.1038/ncomms12357", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000381525200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, XJ; Feng, W; Chang, J; Tan, YW; Li, JC; Chen, M; Sun, Y; Li, FY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Xingjun; Feng, Wei; Chang, Jian; Tan, Yan-Wen; Li, Jiachang; Chen, Min; Sun, Yun; Li, Fuyou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Temperature-feedback upconversion nullocomposite for accurate photothermal therapy at facile temperature", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photothermal therapy (PTT) at present, following the temperature definition for conventional thermal therapy, usually keeps the temperature of lesions at 42-45 degrees C or even higher. Such high temperature kills cancer cells but also increases the damage of normal tissues near lesions through heat conduction and thus brings about more side effects and inhibits therapeutic accuracy. Here we use temperature-feedback upconversion nulloparticle combined with photothermal material for real-time monitoring of microscopic temperature in PTT. We observe that microscopic temperature of photothermal material upon illumination is high enough to kill cancer cells when the temperature of lesions is still low enough to prevent damage to normal tissue. On the basis of the above phenomenon, we further realize high spatial resolution photothermal ablation of labelled tumour with minimal damage to normal tissues in vivo. Our work points to a method for investigating photothermal properties at nulloscale, and for the development of new generation of PTT strategy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 892, "Times Cited, All Databases": 940, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 10437, "DOI": "10.1038/ncomms10437", "DOI Link": "http://dx.doi.org/10.1038/ncomms10437", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000371011500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ge, Q; Sakhaei, AH; Lee, H; Dunn, CK; Fang, NX; Dunn, ML", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ge, Qi; Sakhaei, Amir Hosein; Lee, Howon; Dunn, Conner K.; Fang, Nicholas X.; Dunn, Martin L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multimaterial 4D Printing with Tailorable Shape Memory Polymers", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present a new 4D printing approach that can create high resolution (up to a few microns), multimaterial shape memory polymer (SMP) architectures. The approach is based on high resolution projection microstereolithography (P mu SL) and uses a family of photo-curable methacrylate based copolymer networks. We designed the constituents and compositions to exhibit desired thermomechanical behavior (including rubbery modulus, glass transition temperature and failure strain which is more than 300% and larger than any existing printable materials) to enable controlled shape memory behavior. We used a high resolution, high contrast digital micro display to ensure high resolution of photo-curing methacrylate based SMPs that requires higher exposure energy than more common acrylate based polymers. An automated material exchange process enables the manufacture of 3D composite architectures from multiple photo-curable SMPs. In order to understand the behavior of the 3D composite microarchitectures, we carry out high fidelity computational simulations of their complex nonlinear, time-dependent behavior and study important design considerations including local deformation, shape fixity and free recovery rate. Simulations are in good agreement with experiments for a series of single and multimaterial components and can be used to facilitate the design of SMP 3D structures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 839, "Times Cited, All Databases": 934, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 8", "Publication Year": 2016, "Volume": 6, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 31110, "DOI": "10.1038/srep31110", "DOI Link": "http://dx.doi.org/10.1038/srep31110", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392100600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, K; Chen, H; Ji, YF; Huang, H; Claesson, PM; Daniel, Q; Philippe, B; Rensmo, H; Li, FS; Luo, Y; Sun, LC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Ke; Chen, Hong; Ji, Yongfei; Huang, Hui; Claesson, Per Martin; Daniel, Quentin; Philippe, Bertrand; Rensmo, Hakan; Li, Fusheng; Luo, Yi; Sun, Licheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nickel-vanadium monolayer double hydroxide for efficient electrochemical water oxidation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Highly active and low-cost electrocatalysts for water oxidation are required due to the demands on sustainable solar fuels; however, developing highly efficient catalysts to meet industrial requirements remains a challenge. Herein, we report a monolayer of nickel-vanadium-layered double hydroxide that shows a current density of 27 mA cm(-2) (57 mA cm(-2) after ohmic-drop correction) at an overpotential of 350 mV for water oxidation. Such performance is comparable to those of the best-performing nickel-iron-layered double hydroxides for water oxidation in alkaline media. Mechanistic studies indicate that the nickel-vanadium-layered double hydroxides can provide high intrinsic catalytic activity, mainly due to enhanced conductivity, facile electron transfer and abundant active sites. This work may expand the scope of cost-effective electrocatalysts for water splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 900, "Times Cited, All Databases": 925, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11981, "DOI": "10.1038/ncomms11981", "DOI Link": "http://dx.doi.org/10.1038/ncomms11981", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000378815100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kulbak, M; Gupta, S; Kedem, N; Levine, I; Bendikov, T; Hodes, G; Cahen, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kulbak, Michael; Gupta, Satyajit; Kedem, Nir; Levine, Igal; Bendikov, Tatyana; Hodes, Gary; Cahen, David", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cesium Enhances Long-Term Stability of Lead Bromide Perovskite-Based Solar Cells", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Direct comparison between perovskite-structured hybrid organic inorganic methylammonium lead bromide (MAPbBr(3)) and all-inorganic cesium lead bromide (CsPbBr3), allows identifying possible fundamental differences in their structural, thermal and electronic characteristics. Both materials possess a similar direct optical band gap, but CsPbBr3 demonstrates a higher thermal stability than MAPbBr(3). In order to compare device properties, we fabricated solar cells, with similarly synthesized MAPbBr(3) or CsPbBr3, over mesoporous titania scaffolds. Both cell types demonstrated comparable photovoltaic performances under AM1.5 illumination, reaching power conversion efficiencies of similar to 6% with a poly aryl amine-based derivative as hole transport material. Further analysis shows that Cs-based devices are as efficient as, and more stable than methylammonium-based ones, after aging (storing the cells for 2 weeks in a dry (relative humidity 15-20%) air atmosphere in the dark) for 2 weeks, under constant illumination (at maximum power), and under electron beam irradiation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 879, "Times Cited, All Databases": 936, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 7", "Publication Year": 2016, "Volume": 7, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 167, "End Page": 172, "Article Number": null, "DOI": "10.1021/acs.jpclett.5b02597", "DOI Link": "http://dx.doi.org/10.1021/acs.jpclett.5b02597", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000367968700029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, JS; Wang, Y; Liu, CH; Li, SL; Wang, YG; Dong, LZ; Dai, ZH; Li, YF; Lan, YQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Ji-Sen; Wang, Yu; Liu, Chun-Hui; Li, Shun-Li; Wang, Yu-Guang; Dong, Long-Zhang; Dai, Zhi-Hui; Li, Ya-Fei; Lan, Ya-Qian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Coupled molybdenum carbide and reduced graphene oxide electrocatalysts for efficient hydrogen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical water splitting is one of the most economical and sustainable methods for large-scale hydrogen production. However, the development of low-cost and earth-abundant non-noble-metal catalysts for the hydrogen evolution reaction remains a challenge. Here we report a two-dimensional coupled hybrid of molybdenum carbide and reduced graphene oxide with a ternary polyoxometalate-polypyrrole/reduced graphene oxide nullocomposite as a precursor. The hybrid exhibits outstanding electrocatalytic activity for the hydrogen evolution reaction and excellent stability in acidic media, which is, to the best of our knowledge, the best among these reported non-noble-metal catalysts. Theoretical calculations on the basis of density functional theory reveal that the active sites for hydrogen evolution stem from the pyridinic nitrogens, as well as the carbon atoms, in the graphene. In a proof-of-concept trial, an electrocatalyst for hydrogen evolution is fabricated, which may open new avenues for the design of nullomaterials utilizing POMs/conducting polymer/reduced-graphene oxide nullocomposites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 950, "Times Cited, All Databases": 983, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2016, "Volume": 7, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 11204, "DOI": "10.1038/ncomms11204", "DOI Link": "http://dx.doi.org/10.1038/ncomms11204", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000373478700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, K; Gong, YH; Dai, JQ; Gong, A; Han, XG; Yao, YG; Wang, CW; Wang, YB; Chen, YN; Yan, CY; Li, YJ; Wachsman, ED; Hu, LB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Kun (Kelvin); Gong, Yunhui; Dai, Jiaqi; Gong, Amy; Han, Xiaogang; Yao, Yonggang; Wang, Chengwei; Wang, Yibo; Chen, Yanull; Yan, Chaoyi; Li, Yiju; Wachsman, Eric D.; Hu, Liangbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flexible, solid-state, ion-conducting membrane with 3D garnet nullofiber networks for lithium batteries", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Beyond state-of-the-art lithium-ion battery (LIB) technology with metallic lithium anodes to replace conventional ion intercalation anode materials is highly desirable because of lithium's highest specific capacity (3,860 mA/g) and lowest negative electrochemical potential (similar to 3.040 V vs. the standard hydrogen electrode). In this work, we report for the first time, to our knowledge, a 3D lithium-ion-conducting ceramic network based on garnet-type Li6.4La3Zr2Al0.2O12 (LLZO) lithium-ion conductor to provide continuous Li+ transfer channels in a polyethylene oxide (PEO)-based composite. This composite structure further provides structural reinforcement to enhance the mechanical properties of the polymer matrix. The flexible solid-state electrolyte composite membrane exhibited an ionic conductivity of 2.5 x 10(-4) S/cm at room temperature. The membrane can effectively block dendrites in a symmetric Li vertical bar electrolyte vertical bar Li cell during repeated lithium stripping/plating at room temperature, with a current density of 0.2 mA/cm(2) for around 500 h and a current density of 0.5 mA/cm(2) for over 300 h. These results provide an all solid ion-conducting membrane that can be applied to flexible LIBs and other electrochemical energy storage systems, such as lithium-sulfur batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 801, "Times Cited, All Databases": 906, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 28", "Publication Year": 2016, "Volume": 113, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7094, "End Page": 7099, "Article Number": null, "DOI": "10.1073/pnas.1600422113", "DOI Link": "http://dx.doi.org/10.1073/pnas.1600422113", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000379033400047", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Giannozzi, P; Andreussi, O; Brumme, T; Bunau, O; Nardelli, MB; Calandra, M; Car, R; Cavazzoni, C; Ceresoli, D; Cococcioni, M; Colonna, N; Carnimeo, I; Dal Corso, A; de Gironcoli, S; Delugas, P; DiStasio, RA; Ferretti, A; Floris, A; Fratesi, G; Fugallo, G; Gebauer, R; Gerstmann, U; Giustino, F; Gorni, T; Jia, J; Kawamura, M; Ko, HY; Kokalj, A; Küçükbenli, E; Lazzeri, M; Marsili, M; Marzari, N; Mauri, F; Nguyen, NL; Nguyen, HV; Otero-de-la-Roza, A; Paulatto, L; Poncé, S; Rocca, D; Sabatini, R; Santra, B; Schlipf, M; Seitsonen, AP; Smogunov, A; Timrov, I; Thonhauser, T; Umari, P; Vast, N; Wu, X; Baroni, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Giannozzi, P.; Andreussi, O.; Brumme, T.; Bunau, O.; Nardelli, M. Buongiorno; Calandra, M.; Car, R.; Cavazzoni, C.; Ceresoli, D.; Cococcioni, M.; Colonna, N.; Carnimeo, I.; Dal Corso, A.; de Gironcoli, S.; Delugas, P.; DiStasio, R. A., Jr.; Ferretti, A.; Floris, A.; Fratesi, G.; Fugallo, G.; Gebauer, R.; Gerstmann, U.; Giustino, F.; Gorni, T.; Jia, J.; Kawamura, M.; Ko, H-Y; Kokalj, A.; Kucukbenli, E.; Lazzeri, M.; Marsili, M.; Marzari, N.; Mauri, F.; Nguyen, N. L.; Nguyen, H-V; Otero-de-la-Roza, A.; Paulatto, L.; Ponce, S.; Rocca, D.; Sabatini, R.; Santra, B.; Schlipf, M.; Seitsonen, A. P.; Smogunov, A.; Timrov, I.; Thonhauser, T.; Umari, P.; Vast, N.; Wu, X.; Baroni, S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Advanced capabilities for materials modelling with QUANTUM ESPRESSO", "Source Title": "JOURNAL OF PHYSICS-CONDENSED MATTER", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "QUANTUM ESPRESSO is an integrated suite of open-source computer codes for quantum simulations of materials using state-of-the-art electronic-structure techniques, based on density-functional theory, density-functional perturbation theory, and many-body perturbation theory, within the plane-wave pseudopotential and projector-augmented-wave approaches. QUANTUM ESPRESSO owes its popularity to the wide variety of properties and processes it allows to simulate, to its performance on an increasingly broad array of hardware architectures, and to a community of researchers that rely on its capabilities as a core open-source development platform to implement their ideas. In this paper we describe recent extensions and improvements, covering new methodologies and property calculators, improved parallelization, code modularization, and extended interoperability both within the distribution and with external software.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 6474, "Times Cited, All Databases": 6784, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 22", "Publication Year": 2017, "Volume": 29, "Issue": 46, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 465901, "DOI": "10.1088/1361-648X/aa8f79", "DOI Link": "http://dx.doi.org/10.1088/1361-648X/aa8f79", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413705400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, B; Clark, G; Navarro-Moratalla, E; Klein, DR; Cheng, R; Seyler, KL; Zhong, D; Schmidgall, E; McGuire, MA; Cobden, DH; Yao, W; Xiao, D; Jarillo-Herrero, P; Xu, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Bevin; Clark, Genevieve; Navarro-Moratalla, Efren; Klein, Dahlia R.; Cheng, Ran; Seyler, Kyle L.; Zhong, Ding; Schmidgall, Emma; McGuire, Michael A.; Cobden, David H.; Yao, Wang; Xiao, Di; Jarillo-Herrero, Pablo; Xu, Xiaodong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Layer-dependent ferromagnetism in a van der Waals crystal down to the monolayer limit", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Since the discovery of graphene(1), the family of two-dimensional materials has grown, displaying a broad range of electronic properties. Recent additions include semiconductors with spin-valley coupling(2), Ising superconductors(3-5) that can be tuned into a quantum metal(6), possible Mott insulators with tunable charge-density waves(7), and topological semimetals with edge transport(8,9). However, no two-dimensional crystal with intrinsic magnetism has yet been discovered(10-14); such a crystal would be useful in many technologies from sensing to data storage(15). Theoretically, magnetic order is prohibited in the two-dimensional isotropic Heisenberg model at finite temperatures by the Mermin-Wagner theorem(16). Magnetic anisotropy removes this restriction, however, and enables, for instance, the occurrence of two-dimensional Ising ferromagnetism. Here we use magneto-optical Kerr effect microscopy to demonstrate that monolayer chromium triiodide (CrI3) is an Ising ferromagnet with out-of-plane spin orientation. Its Curie temperature of 45 kelvin is only slightly lower than that of the bulk crystal, 61 kelvin, which is consistent with a weak interlayer coupling. Moreover, our studies suggest a layer-dependent magnetic phase, highlighting thickness-dependent physical properties typical of van der Waals crystals(17-19). Remarkably, bilayer CrI3 displays suppressed magnetization with a metamagnetic effect(20), whereas in trilayer CrI3 the interlayer ferromagnetism observed in the bulk crystal is restored. This work creates opportunities for studying magnetism by harnessing the unusual features of atomically thin materials, such as electrical control for realizing magnetoelectronics(12), and van der Waals engineering to produce interface phenomena(15).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 4484, "Times Cited, All Databases": 4790, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 8", "Publication Year": 2017, "Volume": 546, "Issue": 7657, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 270, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature22391", "DOI Link": "http://dx.doi.org/10.1038/nature22391", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402823400033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lukatskaya, MR; Kota, S; Lin, ZF; Zhao, MQ; Shpigel, N; Levi, MD; Halim, J; Taberna, PL; Barsoum, M; Simon, P; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lukatskaya, Maria R.; Kota, Sankalp; Lin, Zifeng; Zhao, Meng-Qiang; Shpigel, Netanel; Levi, Mikhael D.; Halim, Joseph; Taberna, Pierre-Louis; Barsoum, MichelW.; Simon, Patrice; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-high-rate pseudocapacitive energy storage in two-dimensional transition metal carbides", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The use of fast surface redox storage (pseudocapacitive) mechanisms can enable devices that store much more energy than electrical double-layer capacitors (EDLCs) and, unlike batteries, can do so quite rapidly. Yet, few pseudocapacitive transition metal oxides can provide a high power capability due to their low intrinsic electronic and ionic conductivity. Here we demonstrate that two-dimensional transition metal carbides (MXenes) can operate at rates exceeding those of conventional EDLCs, but still provide higher volumetric and areal capacitance than carbon, electrically conducting polymers or transition metal oxides. We applied two distinct designs for MXene electrode architectures with improved ion accessibility to redox-active sites. A macroporous Ti(3)C(2)Tx MXene film delivered up to 210 F g(-1) at scan rates of 10Vs(-1), surpassing the best carbon supercapacitors known. In contrast, we show that MXene hydrogels are able to deliver volumetric capacitance of similar to 1,500 F cm(-3) reaching the previously unmatched volumetric performance of RuO2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1847, "Times Cited, All Databases": 1936, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2017, "Volume": 2, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 17105, "DOI": "10.1038/nenergy.2017.105", "DOI Link": "http://dx.doi.org/10.1038/nenergy.2017.105", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000411264300015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Grimaud, A; Diaz-Morales, O; Han, BH; Hong, WT; Lee, YL; Giordano, L; Stoerzinger, KA; Koper, MTM; Shao-Horn, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Grimaud, Alexis; Diaz-Morales, Oscar; Han, Binghong; Hong, Wesley T.; Lee, Yueh-Lin; Giordano, Livia; Stoerzinger, Kelsey A.; Koper, Marc T. M.; Shao-Horn, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Activating lattice oxygen redox reactions in metal oxides to catalyse oxygen evolution", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Understanding how materials that catalyse the oxygen evolution reaction (OER) function is essential for the development of efficient energy-storage technologies. The traditional understanding of the OER mechanism on metal oxides involves four concerted proton-electron transfer steps on metal-ion centres at their surface and product oxygen molecules derived from water. Here, using in situ O-18 isotope labelling mass spectrometry, we provide direct experimental evidence that the O-2 generated during the OER on some highly active oxides can come from lattice oxygen. The oxides capable of lattice-oxygen oxidation also exhibit pH-dependent OER activity on the reversible hydrogen electrode scale, indicating non-concerted proton-electron transfers in the OER mechanism. Based on our experimental data and density functional theory calculations, we discuss mechanisms that are fundamentally different from the conventional scheme and show that increasing the covalency of metal-oxygen bonds is critical to trigger lattice-oxygen oxidation and enable non-concerted proton-electron transfers during OER.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1718, "Times Cited, All Databases": 1786, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2017, "Volume": 9, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 457, "End Page": 465, "Article Number": null, "DOI": "10.1038/NCHEM.2695", "DOI Link": "http://dx.doi.org/10.1038/NCHEM.2695", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000399785500013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, HJ; Shi, R; Zhao, YX; Bian, T; Zhao, YF; Zhou, C; Waterhouse, GIN; Wu, LZ; Tung, CH; Zhang, TR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Huijun; Shi, Run; Zhao, Yunxuan; Bian, Tong; Zhao, Yufei; Zhou, Chao; Waterhouse, Geoffrey I. N.; Wu, Li-Zhu; Tung, Chen-Ho; Zhang, Tierui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Alkali-Assisted Synthesis of Nitrogen Deficient Graphitic Carbon Nitride with Tunable Band Structures for Efficient Visible-Light-Driven Hydrogen Evolution", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A facile synthetic strategy for nitrogen-deficient graphitic carbon nitride (g-C3Nx) is established, involving a simple alkali-assisted thermal polymerization of urea, melamine, or thiourea. In situ introduced nitrogen vacancies significantly red-shift the absorption edge of g-C3Nx, with the defect concentration depending on the alkali to nitrogen precursor ratio. The g-C3Nx products show superior visible-light photocatalytic performance compared to pristine g-C3N4.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1900, "Times Cited, All Databases": 1950, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 25", "Publication Year": 2017, "Volume": 29, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1605148, "DOI": "10.1002/adma.201605148", "DOI Link": "http://dx.doi.org/10.1002/adma.201605148", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000400024500015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ran, JR; Gao, GP; Li, FT; Ma, TY; Du, AJ; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ran, Jingrun; Gao, Guoping; Li, Fa-Tang; Ma, Tian-Yi; Du, Aijun; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ti3C2 MXene co-catalyst on metal sulfide photo-absorbers for enhanced visible-light photocatalytic hydrogen production", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Scalable and sustainable solar hydrogen production through photocatalytic water splitting requires highly active and stable earth-abundant co-catalysts to replace expensive and rare platinum. Here we employ density functional theory calculations to direct atomic-level exploration, design and fabrication of a MXene material, Ti3C2 nulloparticles, as a highly efficient co-catalyst. Ti3C2 nulloparticles are rationally integrated with cadmium sulfide via a hydrothermal strategy to induce a super high visible-light photocatalytic hydrogen production activity of 14,342 mu mol h(-1) g(-1) and an apparent quantum efficiency of 40.1% at 420 nm. This high performance arises from the favourable Fermi level position, electrical conductivity and hydrogen evolution capacity of Ti3C2 nulloparticles. Furthermore, Ti3C2 nulloparticles also serve as an efficient co-catalyst on ZnS or ZnxCd1-xS. This work demonstrates the potential of earth-abundant MXene family materials to construct numerous high performance and low-cost photocatalysts/photoelectrodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1707, "Times Cited, All Databases": 1770, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 3", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13907, "DOI": "10.1038/ncomms13907", "DOI Link": "http://dx.doi.org/10.1038/ncomms13907", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000391020200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "On Maxwell's displacement current for energy and sensors: the origin of nullogenerators", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Self-powered system is a system that can sustainably operate without an external power supply for sensing, detection, data processing and data transmission. nullogenerators were first developed for self-powered systems based on piezoelectric effect and triboelectrification effect for converting tiny mechanical energy into electricity, which have applications in internet of things, environmental/infrastructural monitoring, medical science and security. In this paper, we present the fundamental theory of the nullogenerators starting from the Maxwell equations. In the Maxwell's displacement current, the first term epsilon(0) partial derivative E/partial derivative t gives the birth of electromagnetic wave, which is the foundation of wireless communication, radar and later the information technology. Our study indicates that the second term partial derivative P/partial derivative t in the Maxwell's displacement current is directly related to the output electric current of the nullogenerator, meaning that our nullogenerators are the applications of Maxwell's displacement current in energy and sensors. By contrast, electromagnetic generators are built based on Lorentz force driven flow of free electrons in a conductor. This study presents the similarity and differences between pieozoelectric nullogenerator and triboelectric nullogenerator, as well as the classical electromagnetic generator, so that the impact and uniqueness of the nullogenerators can be clearly understood. We also present the three major applications of nullogenerators as micro/nullo-power source, self-powered sensors and blue energy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1592, "Times Cited, All Databases": 1610, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2017, "Volume": 20, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 74, "End Page": 82, "Article Number": null, "DOI": "10.1016/j.mattod.2016.12.001", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2016.12.001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000398895800016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yan, J; Ren, CE; Maleski, K; Hatter, CB; Anasori, B; Urbankowski, P; Sarycheva, A; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan, Jun; Ren, Chang E.; Maleski, Kathleen; Hatter, Christine B.; Anasori, Babak; Urbankowski, Patrick; Sarycheva, Asya; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flexible MXene/Graphene Films for Ultrafast Supercapacitors with Outstanding Volumetric Capacitance", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A strategy to prepare flexible and conductive MXene/graphene (reduced graphene oxide, rGO) supercapacitor electrodes by using electrostatic self-assembly between positively charged rGO modified with poly(diallyldimethylammonium chloride) and negatively charged titanium carbide MXene nullosheets is presented. After electrostatic assembly, rGO nullosheets are inserted in-between MXene layers. As a result, the self-restacking of MXene nullosheets is effectively prevented, leading to a considerably increased interlayer spacing. Accelerated diffusion of electrolyte ions enables more electroactive sites to become accessible. The freestanding MXene/rGO-5 wt% electrode displays a volumetric capacitance of 1040 F cm(-3) at a scan rate of 2 mV s(-1), an impressive rate capability with 61% capacitance retention at 1 V s(-1) and long cycle life. Moreover, the fabricated binder-free symmetric supercapacitor shows an ultrahigh volumetric energy density of 32.6 Wh L-1, which is among the highest values reported for carbon and MXene based materials in aqueous electrolytes. This work provides fundamental insight into the effect of interlayer spacing on the electrochemical performance of 2D hybrid materials and sheds light on the design of next-generation flexible, portable and highly integrated supercapacitors with high volumetric and rate performances.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1561, "Times Cited, All Databases": 1625, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 11", "Publication Year": 2017, "Volume": 27, "Issue": 30, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1701264, "DOI": "10.1002/adfm.201701264", "DOI Link": "http://dx.doi.org/10.1002/adfm.201701264", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000407261700011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Y; Zhu, CX; Pfattner, R; Yan, HP; Jin, LH; Chen, SC; Molina-Lopez, F; Lissel, F; Liu, J; Rabiah, NI; Chen, Z; Chung, JW; Linder, C; Toney, MF; Murmann, B; Bao, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yue; Zhu, Chenxin; Pfattner, Raphael; Yan, Hongping; Jin, Lihua; Chen, Shucheng; Molina-Lopez, Francisco; Lissel, Franziska; Liu, Jia; Rabiah, Noelle I.; Chen, Zheng; Chung, Jong Won; Linder, Christian; Toney, Michael F.; Murmann, Boris; Bao, Zhenull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A highly stretchable, transparent, and conductive polymer", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Previous breakthroughs in stretchable electronics stem from strain engineering and nullocomposite approaches. Routes toward intrinsically stretchable molecular materials remain scarce but, if successful, will enable simpler fabrication processes, such as direct printing and coating, mechanically robust devices, and more intimate contact with objects. We report a highly stretchable conducting polymer, realized with a range of enhancers that serve a dual function: (i) they change morphology and (ii) they act as conductivity-enhancing dopants in poly(3,4-ethylene-dioxythiophene): poly(styrenesulfonate) (PEDOT: PSS). The polymer films exhibit conductivities comparable to the best reported values for PEDOT: PSS, with over 3100 S/cm under 0% strain and over 4100 S/cm under 100% strain-among the highest for reported stretchable conductors. It is highly durable under cyclic loading, with the conductivity maintained at 3600 S/cm even after 1000 cycles to 100% strain. The conductivity remained above 100 S/cmunder 600% strain, with a fracture strain of 800%, which is superior to even the best silver nullowire-or carbon nullotube-based stretchable conductor films. The combination of excellent electrical and mechanical properties allowed it to serve as interconnects for field-effect transistor arrays with a device density that is five times higher than typical lithographically patterned wavy interconnects.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1260, "Times Cited, All Databases": 1384, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2017, "Volume": 3, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1602076", "DOI": "10.1126/sciadv.1602076", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1602076", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397044000024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Birkl, CR; Roberts, MR; McTurk, E; Bruce, PG; Howey, DA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Birkl, Christoph R.; Roberts, Matthew R.; McTurk, Euan; Bruce, Peter G.; Howey, David A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Degradation diagnostics for lithium ion cells", "Source Title": "JOURNAL OF POWER SOURCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Degradation in lithium ion (Li-ion) battery cells is the result of a complex interplay of a host of different physical and chemical mechanisms. The measurable, physical effects of these degradation mechanisms on the cell can be summarised in terms of three degradation modes, namely loss of lithium inventory, loss of active positive electrode material and loss of active negative electrode material. The different degradation modes are assumed to have unique and measurable effects on the open circuit voltage (OCV) of Li-ion cells and electrodes. The presumptive nature and extent of these effects has so far been based on logical arguments rather than experimental proof. This work presents, for the first time, experimental evidence supporting the widely reported degradation modes by means of tests conducted on coin cells, engineered to include different, known amounts of lithium inventory and active electrode material. Moreover, the general theory behind the effects of degradation modes on the OCV of cells and electrodes is refined and a diagnostic algorithm is devised, which allows the identification and quantification of the nature and extent of each degradation mode in Li-ion cells at any point in their service lives, by fitting the cells' OCV. (C) 2016 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1116, "Times Cited, All Databases": 1220, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2017, "Volume": 341, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 373, "End Page": 386, "Article Number": null, "DOI": "10.1016/j.jpowsour.2016.12.011", "DOI Link": "http://dx.doi.org/10.1016/j.jpowsour.2016.12.011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000393003400044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, J; Jia, S; Kholmanov, I; Dong, L; Er, DQ; Chen, WB; Guo, H; Jin, ZH; Shenoy, VB; Shi, L; Lou, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jing; Jia, Shuai; Kholmanov, Iskandar; Dong, Liang; Er, Dequan; Chen, Weibing; Guo, Hua; Jin, Zehua; Shenoy, Vivek B.; Shi, Li; Lou, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Janus Monolayer Transition-Metal Dichalcogenides", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The crystal configuration of sandwiched S-Mo-Se structure (Janus SMoSe) at the monolayer limit has been synthesized and carefully characterized in this work. By controlled sulfurization of monolayer MoSe2, the top layer of selenium atoms is substituted by sulfur atoms, while the bottom selenium layer remains intact. The structure of this material is systematically investigated by Raman, photoluminescence, transmission electron microscopy, and X-ray photoelectron spectroscopy and confirmed by time-of-flight secondary ion mass spectrometry. Density functional theory (DFT) calculations are performed to better understand the Raman vibration modes and electronic structures of the Janus SMoSe monolayer, which are found to correlate well with corresponding experimental results. Finally, high basal plane hydrogen evolution reaction activity is discovered for the Janus monolayer, and DFT calculation implies that the activity originates from the synergistic effect of the intrinsic defects and structural strain inherent in the Janus structure.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1206, "Times Cited, All Databases": 1260, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2017, "Volume": 11, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8192, "End Page": 8198, "Article Number": null, "DOI": "10.1021/acsnullo.7b03186", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.7b03186", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000408520900069", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, X; Wu, ZS; Zhang, X; Li, LW; Li, YY; Xu, HM; Li, XX; Yu, XL; Zhang, ZS; Liang, YY; Wang, HL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xing; Wu, Zishan; Zhang, Xiao; Li, Liewu; Li, Yanyan; Xu, Haomin; Li, Xiaoxiao; Yu, Xiaolu; Zhang, Zisheng; Liang, Yongye; Wang, Hailiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly selective and active CO2 reduction electro-catalysts based on cobalt phthalocyanine/carbon nullotube hybrid structures", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical reduction of carbon dioxide with renewable energy is a sustainable way of producing carbon-neutral fuels. However, developing active, selective and stable electrocatalysts is challenging and entails material structure design and tailoring across a range of length scales. Here we report a cobalt-phthalocyanine-based high-performance carbon dioxide reduction electrocatalyst material developed with a combined nulloscale and molecular approach. On the nulloscale, cobalt phthalocyanine (CoPc) molecules are uniformly anchored on carbon nullotubes to afford substantially increased current density, improved selectivity for carbon monoxide, and enhanced durability. On the molecular level, the catalytic performance is further enhanced by introducing cyano groups to the CoPc molecule. The resulting hybrid catalyst exhibits 495% Faradaic efficiency for carbon monoxide production in a wide potential range and extraordinary catalytic activity with a current density of 15.0mAcm(-2) and a turnover frequency of 4.1 s(-1) at the overpotential of 0.52V in a near-neutral aqueous solution.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1195, "Times Cited, All Databases": 1246, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 8", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14675, "DOI": "10.1038/ncomms14675", "DOI Link": "http://dx.doi.org/10.1038/ncomms14675", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395727800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Arora, N; Dar, MI; Hinderhofer, A; Pellet, N; Schreiber, F; Zakeeruddin, SM; Grätzel, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Arora, Neha; Dar, M. Ibrahim; Hinderhofer, Alexander; Pellet, Norman; Schreiber, Frank; Zakeeruddin, Shaik Mohammed; Graetzel, Michael", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Perovskite solar cells with CuSCN hole extraction layers yield stabilized efficiencies greater than 20%", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite solar cells (PSCs) with efficiencies greater than 20% have been realized only with expensive organic hole-transporting materials. We demonstrate PSCs that achieve stabilized efficiencies exceeding 20% with copper(I) thiocyanate (CuSCN) as the hole extraction layer. A fast solvent removal method enabled the creation of compact, highly conformal CuSCN layers that facilitate rapid carrier extraction and collection. The PSCs showed high thermal stability under long-term heating, although their operational stability was poor. This instability originated from potential-induced degradation of the CuSCN/Au contact. The addition of a conductive reduced graphene oxide spacer layer between CuSCN and gold allowed PSCs to retain >95% of their initial efficiency after aging at a maximum power point for 1000 hours under full solar intensity at 60 degrees C. Under both continuous full-sun illumination and thermal stress, CuSCN-based devices surpassed the stability of spiro-OMeTAD-based PSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1299, "Times Cited, All Databases": 1382, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 10", "Publication Year": 2017, "Volume": 358, "Issue": 6364, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 768, "End Page": 771, "Article Number": null, "DOI": "10.1126/science.aam5655", "DOI Link": "http://dx.doi.org/10.1126/science.aam5655", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000414847100040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, GB; Xu, LG; Chao, Y; Xu, J; Sun, XQ; Wu, YF; Peng, R; Liu, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Guangbao; Xu, Ligeng; Chao, Yu; Xu, Jun; Sun, Xiaoqi; Wu, Yifan; Peng, Rui; Liu, Zhuang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hollow MnO2 as a tumor-microenvironment-responsive biodegradable nullo-platform for combination therapy favoring antitumor immune responses", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Herein, an intelligent biodegradable hollow manganese dioxide (H-MnO2) nullo-platform is developed for not only tumor microenvironment (TME)-specific imaging and on-demand drug release, but also modulation of hypoxic TME to enhance cancer therapy, resulting in comprehensive effects favoring anti-tumor immune responses. With hollow structures, H-MnO2 nulloshells post modification with polyethylene glycol (PEG) could be co-loaded with a photodynamic agent chlorine e6 (Ce6), and a chemotherapy drug doxorubicin (DOX). The obtained H-MnO2-PEG/C&D would be dissociated under reduced pH within TME to release loaded therapeutic molecules, and in the meantime induce decomposition of tumor endogenous H2O2 to relieve tumor hypoxia. As a result, a remarkable in vivo synergistic therapeutic effect is achieved through the combined chemo-photodynamic therapy, which simultaneously triggers a series of anti-tumor immune responses. Its further combination with checkpoint-blockade therapy would lead to inhibition of tumors at distant sites, promising for tumor metastasis treatment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1240, "Times Cited, All Databases": 1274, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 12", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 902, "DOI": "10.1038/s41467-017-01050-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-01050-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000412860100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pei, A; Zheng, GY; Shi, FF; Li, YZ; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pei, Allen; Zheng, Guangyuan; Shi, Feifei; Li, Yuzhang; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nulloscale Nucleation and Growth of Electrodeposited Lithium Metal", "Source Title": "nullO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium metal has re-emerged as an exciting anode for high energy lithium-ion batteries due to its high specific capacity of 3860 mAh g(-1) and lowest electrochemical potential of all known materials. However, lithium has been plagued by the issues of dendrite formation, high chemical reactivity with electrolyte, and infinite relative volume expansion during plating and stripping, which present safety hazards and low cycling efficiency in batteries with lithium metal electrodes. There have been a lot of recent studies on Li metal although little work has focused on the initial nucleation and growth behavior of Li metal, neglecting a critical fundamental scientific foundation of Li plating. Here, we study experimentally the morphology of lithium in the early stages of nucleation and growth on planar copper electrodes in liquid organic electrolyte. We elucidate the dependence of lithium nuclei size, shape, and areal density on current rate, consistent with classical nucleation and growth theory. We found that the nuclei size is proportional to the inverse of overpotential and the number density of nuclei is proportional to the cubic power of overpotential. Based on this understanding, we propose a strategy to increase the uniformity of electrodeposited lithium on the electrode surface.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1287, "Times Cited, All Databases": 1380, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2017, "Volume": 17, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1132, "End Page": 1139, "Article Number": null, "DOI": "10.1021/acs.nullolett.6b04755", "DOI Link": "http://dx.doi.org/10.1021/acs.nullolett.6b04755", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000393848800075", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, J; Celiz, AD; Yang, J; Yang, Q; Wamala, I; Whyte, W; Seo, BR; Vasilyev, NV; Vlassak, JJ; Suo, Z; Mooney, DJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, J.; Celiz, A. D.; Yang, J.; Yang, Q.; Wamala, I.; Whyte, W.; Seo, B. R.; Vasilyev, N. V.; Vlassak, J. J.; Suo, Z.; Mooney, D. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tough adhesives for diverse wet surfaces", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Adhesion to wet and dynamic surfaces, including biological tissues, is important in many fields but has proven to be extremely challenging. Existing adhesives are cytotoxic, adhere weakly to tissues, or cannot be used in wet environments. We report a bioinspired design for adhesives consisting of two layers: an adhesive surface and a dissipative matrix. The former adheres to the substrate by electrostatic interactions, covalent bonds, and physical interpenetration. The latter amplifies energy dissipation through hysteresis. The two layers synergistically lead to higher adhesion energies on wet surfaces as compared with those of existing adhesives. Adhesion occurs within minutes, independent of blood exposure and compatible with in vivo dynamic movements. This family of adhesives may be useful in many areas of application, including tissue adhesives, wound dressings, and tissue repair.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1214, "Times Cited, All Databases": 1304, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 28", "Publication Year": 2017, "Volume": 357, "Issue": 6349, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 378, "End Page": 381, "Article Number": null, "DOI": "10.1126/science.aah6362", "DOI Link": "http://dx.doi.org/10.1126/science.aah6362", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000406362300039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, ZH; Zhang, JQ; Yin, LC; Hu, GJ; Fang, RP; Cheng, HM; Li, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Zhenhua; Zhang, Jingqi; Yin, Lichang; Hu, Guangjian; Fang, Ruopian; Cheng, Hui-Ming; Li, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Conductive porous vanadium nitride/graphene composite as chemical anchor of polysulfides for lithium-sulfur batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although the rechargeable lithium-sulfur battery is an advanced energy storage system, its practical implementation has been impeded by many issues, in particular the shuttle effect causing rapid capacity fade and low Coulombic efficiency. Herein, we report a conductive porous vanadium nitride nulloribbon/graphene composite accommodating the catholyte as the cathode of a lithium-sulfur battery. The vanadium nitride/graphene composite provides strong anchoring for polysulfides and fast polysulfide conversion. The anchoring effect of vanadium nitride is confirmed by experimental and theoretical results. Owing to the high conductivity of vanadium nitride, the composite cathode exhibits lower polarization and faster redox reaction kinetics than a reduced graphene oxide cathode, showing good rate and cycling performances. The initial capacity reaches 1,471mAhg(-1) and the capacity after 100 cycles is 1,252 mAhg(-1) at 0.2 C, a loss of only 15%, offering a potential for use in high energy lithium-sulfur batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1068, "Times Cited, All Databases": 1134, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 3", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14627, "DOI": "10.1038/ncomms14627", "DOI Link": "http://dx.doi.org/10.1038/ncomms14627", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000395280000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, RY; Zhang, LB; Shi, L; Wang, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Renyuan; Zhang, Lianbin; Shi, Le; Wang, Peng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MXene Ti3C2: An Effective 2D Light-to-Heat Conversion Material", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MXene, a new series of 2D material, has been steadily advancing its applications to a variety of fields, such as catalysis, supercapacitor, molecular separation, electromagnetic wave interference shielding. This work reports a carefully designed aqueous droplet light heating system along with a thorough mathematical procedure, which combined leads to a precise determination of internal light-to-heat conversion efficiency of a variety of nullomaterials. The internal light-to-heat conversion efficiency of MXene, more specifically Ti3C2, was measured to be 100%, indicating a perfect energy conversion. Furthermore, a self-floating MXene thin membrane was prepared by simple vacuum filtration and the membrane, in the presence of a rationally chosen heat barrier, produced a light-to-water evaporation efficiency of 84% under one sun irradiation, which is among the state of art energy efficiency for similar photothermal evaporation system. The outstanding internal light-to-heat conversion efficiency and great light-to-water evaporation efficiency reported in this work suggest that MXene is a very promising light-to-heat conversion material and thus deserves more research attention toward practical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1392, "Times Cited, All Databases": 1451, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2017, "Volume": 11, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3752, "End Page": 3759, "Article Number": null, "DOI": "10.1021/acsnullo.6b08415", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.6b08415", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000400233200033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Grancini, G; Roldán-Carmona, C; Zimmermann, I; Mosconi, E; Lee, X; Martineau, D; Narbey, S; Oswald, F; De Angelis, F; Graetzel, M; Nazeeruddin, MK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Grancini, G.; Roldan-Carmona, C.; Zimmermann, I.; Mosconi, E.; Lee, X.; Martineau, D.; Narbey, S.; Oswald, F.; De Angelis, F.; Graetzel, M.; Nazeeruddin, Mohammad Khaja", "Book Author Full Names": null, "Group Authors": null, "Article Title": "One-Year stable perovskite solar cells by 2D/3D interface engineering", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite the impressive photovoltaic performances with power conversion efficiency beyond 22%, perovskite solar cells are poorly stable under operation, failing by far the market requirements. Various technological approaches have been proposed to overcome the instability problem, which, while delivering appreciable incremental improvements, are still far from a market-proof solution. Here we show one-year stable perovskite devices by engineering an ultra-stable 2D/3D (HOOC(CH2)(4)NH3)(2)PbI4/CH3NH3PbI3 perovskite junction. The 2D/3D forms an exceptional gradually-organized multi-dimensional interface that yields up to 12.9% efficiency in a carbon-based architecture, and 14.6% in standard mesoporous solar cells. To demonstrate the up-scale potential of our technology, we fabricate 10 x 10 cm(2) solar modules by a fully printable industrial-scale process, delivering 11.2% efficiency stable for >10,000 h with zero loss in performances measured under controlled standard conditions. This innovative stable and low-cost architecture will enable the timely commercialization of perovskite solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1255, "Times Cited, All Databases": 1262, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 1", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15684, "DOI": "10.1038/ncomms15684", "DOI Link": "http://dx.doi.org/10.1038/ncomms15684", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402524300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, N; Cheng, FY; Liu, JX; Wang, LB; Long, XH; Liu, XS; Li, FJ; Chen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Ning; Cheng, Fangyi; Liu, Junxiang; Wang, Liubin; Long, Xinghui; Liu, Xiaosong; Li, Fujun; Chen, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rechargeable aqueous zinc-manganese dioxide batteries with high energy and power densities", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although alkaline zinc-manganese dioxide batteries have dominated the primary battery applications, it is challenging to make them rechargeable. Here we report a high-performance rechargeable zinc-manganese dioxide system with an aqueous mild-acidic zinc triflate electrolyte. We demonstrate that the tunnel structured manganese dioxide polymorphs undergo a phase transition to layered zinc-buserite on first discharging, thus allowing subsequent intercalation of zinc cations in the latter structure. Based on this electrode mechanism, we formulate an aqueous zinc/manganese triflate electrolyte that enables the formation of a protective porous manganese oxide layer. The cathode exhibits a high reversible capacity of 225 mAh g(-1) and long-term cyclability with 94% capacity retention over 2000 cycles. Remarkably, the pouch zinc-manganese dioxide battery delivers a total energy density of 75.2 Wh kg(-1). As a result of the superior battery performance, the high safety of aqueous electrolyte, the facile cell assembly and the cost benefit of the source materials, this zinc-manganese dioxide system is believed to be promising for large-scale energy storage applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1138, "Times Cited, All Databases": 1170, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 405, "DOI": "10.1038/s41467-017-00467-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-00467-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000408820700005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, GM; Tian, HZ; Jin, Y; Tao, XY; Liu, BF; Zhang, RF; Seh, ZW; Zhuo, D; Liu, YY; Sun, J; Zhao, J; Zu, CX; Wu, DS; Zhang, QF; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Guangmin; Tian, Hongzhen; Jin, Yang; Tao, Xinyong; Liu, Bofei; Zhang, Rufan; Seh, Zhi Wei; Zhuo, Denys; Liu, Yayuan; Sun, Jie; Zhao, Jie; Zu, Chenxi; Wu, David Sichen; Zhang, Qianfan; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Catalytic oxidation of Li2S on the surface of metal sulfides for Li-S batteries", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polysulfide binding and trapping to prevent dissolution into the electrolyte by a variety of materials has been well studied in Li-S batteries. Here we discover that some of those materials can play an important role as an activation catalyst to facilitate oxidation of the discharge product, Li2S, back to the charge product, sulfur. Combining theoretical calculations and experimental design, we select a series of metal sulfides as a model system to identify the key parameters in determining the energy barrier for Li2S oxidation and polysulfide adsorption. We demonstrate that the Li2S decomposition energy barrier is associated with the binding between isolated Li ions and the sulfur in sulfides; this is the main reason that sulfide materials can induce lower overpotential compared with commonly used carbon materials. Fundamental understanding of this reaction process is a crucial step toward rational design and screening of materials to achieve high reversible capacity and long cycle life in Li-S batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1097, "Times Cited, All Databases": 1149, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 31", "Publication Year": 2017, "Volume": 114, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 840, "End Page": 845, "Article Number": null, "DOI": "10.1073/pnas.1615837114", "DOI Link": "http://dx.doi.org/10.1073/pnas.1615837114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000393196300042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pu, X; Liu, MM; Chen, XY; Sun, JM; Du, CH; Zhang, Y; Zhai, JY; Hu, WG; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pu, Xiong; Liu, Mengmeng; Chen, Xiangyu; Sun, Jiangman; Du, Chunhua; Zhang, Yang; Zhai, Junyi; Hu, Weiguo; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrastretchable, transparent triboelectric nullogenerator as electronic skin for biomechanical energy harvesting and tactile sensing", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rapid advancements in stretchable and multifunctional electronics impose the challenge on corresponding power devices that they should have comparable stretchability and functionality. We report a soft skin-like triboelectric nullogenerator (STENG) that enables both biomechanical energy harvesting and tactile sensing by hybridizing elastomer and ionic hydrogel as the electrification layer and electrode, respectively. For the first time, ultrahigh stretchability (uniaxial strain, 1160%) and transparency (average transmittance, 96.2% for visible light) are achieved simultaneously for an energy-harvesting device. The soft TENG is capable of outputting alternative electricity with an instantaneous peak power density of 35 mW m(-2) and driving wearable electronics (for example, an electronic watch) with energy converted from human motions, whereas the STENG is pressuresensitive, enabling its application as artificial electronic skin for touch/pressure perception. Our work provides new opportunities for multifunctional power sources and potential applications in soft/wearable electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1103, "Times Cited, All Databases": 1164, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2017, "Volume": 3, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1700015", "DOI": "10.1126/sciadv.1700015", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1700015", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000419752300014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ding, WJ; Zhu, JB; Wang, Z; Gao, YF; Xiao, D; Gu, Y; Zhang, ZY; Zhu, WG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ding, Wenjun; Zhu, Jianbao; Wang, Zhe; Gao, Yanfei; Xiao, Di; Gu, Yi; Zhang, Zhenyu; Zhu, Wenguang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Prediction of intrinsic two-dimensional ferroelectrics in In2Se3 and other III2-VI3 van der Waals materials", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Interest in two-dimensional (2D) van der Waals materials has grown rapidly across multiple scientific and engineering disciplines in recent years. However, ferroelectricity, the presence of a spontaneous electric polarization, which is important in many practical applications, has rarely been reported in such materials so far. Here we employ first-principles calculations to discover a branch of the 2D materials family, based on In2Se3 and other III2-VI3 van der Waals materials, that exhibits room-temperature ferroelectricity with reversible spontaneous electric polarization in both out-of-plane and in-plane orientations. The device potential of these 2D ferroelectric materials is further demonstrated using the examples of van der Waals heterostructures of In2Se3/graphene, exhibiting a tunable Schottky barrier, and In2Se3/WSe2, showing a significant band gap reduction in the combined system. These findings promise to substantially broaden the tunability of van der Waals heterostructures for a wide range of applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1055, "Times Cited, All Databases": 1128, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 7", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14956, "DOI": "10.1038/ncomms14956", "DOI Link": "http://dx.doi.org/10.1038/ncomms14956", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000398455400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Benalcazar, WA; Bernevig, BA; Hughes, TL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Benalcazar, Wladimir A.; Bernevig, B. Andrei; Hughes, Taylor L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electric multipole moments, topological multipole moment pumping, and chiral hinge states in crystalline insulators", "Source Title": "PHYSICAL REVIEW B", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We extend the theory of dipole moments in crystalline insulators to higher multipole moments. As first formulated in Benalcazar et al. [Science 357, 61 (2017)], we show that bulk quadrupole and octupole moments can be realized in crystalline insulators. In this paper, we expand in great detail the theory presented previously [Benalcazar et al., Science 357, 61 (2017)] and extend it to cover associated topological pumping phenomena, and a class of three-dimensional (3D) insulator with chiral hinge states. We start by deriving the boundary properties of continuous classical dielectrics hosting only bulk dipole, quadrupole, or octupole moments. In quantum mechanical crystalline insulators, these higher multipole bulk moments manifest themselves by the presence of boundary-localized moments of lower dimension, in exact correspondence with the electromagnetic theory of classical continuous dielectrics. In the presence of certain symmetries, these moments are quantized, and their boundary signatures are fractionalized. These multipole moments then correspond to new symmetry-protected topological phases. The topological structure of these phases is described by nested Wilson loops, which we define. These Wilson loops reflect the bulk-boundary correspondence in a way that makes evident a hierarchical classification of the multipole moments. Just as a varying dipole generates charge pumping, a varying quadrupole generates dipole pumping, and a varying octupole generates quadrupole pumping. For nontrivial adiabatic cycles, the transport of these moments is quantized. An analysis of these interconnected phenomena leads to the conclusion that a new kind of Chern-type insulator exists, which has chiral, hinge-localized modes in 3D. We provide the minimal models for the quantized multipole moments, the nontrivial pumping processes, and the hinge Chern insulator, and describe the topological invariants that protect them.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1068, "Times Cited, All Databases": 1124, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 11", "Publication Year": 2017, "Volume": 96, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 245115, "DOI": "10.1103/PhysRevB.96.245115", "DOI Link": "http://dx.doi.org/10.1103/PhysRevB.96.245115", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000417639900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Duan, JJ; Chen, S; Zhao, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Duan, Jingjing; Chen, Sheng; Zhao, Chuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrathin metal-organic framework array for efficient electrocatalytic water splitting", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional metal-organic frameworks represent a family of materials with attractive chemical and structural properties, which are usually prepared in the form of bulk powders. Here we show a generic approach to fabricate ultrathin nullosheet array of metal-organic frameworks on different substrates through a dissolution-crystallization mechanism. These materials exhibit intriguing properties for electrocatalysis including highly exposed active molecular metal sites owning to ultra-small thickness of nullosheets, improved electrical conductivity and a combination of hierarchical porosity. We fabricate a nickel-iron-based metal-organic framework array, which demonstrates superior electrocatalytic performance towards oxygen evolution reaction with a small overpotential of 240 mV at 10 mA cm(-2), and robust operation for 20,000 s with no detectable activity decay. Remarkably, the turnover frequency of the electrode is 3.8 s(-1) at an overpotential of 400 mV. We further demonstrate the promise of these electrodes for other important catalytic reactions including hydrogen evolution reaction and overall water splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1090, "Times Cited, All Databases": 1117, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 5", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15341, "DOI": "10.1038/ncomms15341", "DOI Link": "http://dx.doi.org/10.1038/ncomms15341", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402742100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Aristidou, N; Eames, C; Sanchez-Molina, I; Bu, XN; Kosco, J; Islam, MS; Haque, SA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Aristidou, Nicholas; Eames, Christopher; Sanchez-Molina, Irene; Bu, Xiangnull; Kosco, Jan; Islam, M. Saiful; Haque, Saif A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fast oxygen diffusion and iodide defects mediate oxygen-induced degradation of perovskite solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Methylammonium lead halide perovskites are attracting intense interest as promising materials for next-generation solar cells, but serious issues related to long-term stability need to be addressed. Perovskite films based on CH3NH3PbI3 undergo rapid degradation when exposed to oxygen and light. Here, we report mechanistic insights into this oxygen-induced photodegradation from a range of experimental and computational techniques. We find fast oxygen diffusion into CH3NH3PbI3 films is accompanied by photo-induced formation of highly reactive superoxide species. Perovskite films composed of small crystallites show higher yields of superoxide and lower stability. Ab initio simulations indicate that iodide vacancies are the preferred sites in mediating the photo-induced formation of superoxide species from oxygen. Thin-film passivation with iodide salts is shown to enhance film and device stability. The understanding of degradation phenomena gained from this study is important for the future design and optimization of stable perovskite solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1027, "Times Cited, All Databases": 1090, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 11", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15218, "DOI": "10.1038/ncomms15218", "DOI Link": "http://dx.doi.org/10.1038/ncomms15218", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000400962100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, J; Wang, T; Liu, P; Liao, ZQ; Liu, SH; Zhuang, XD; Chen, MW; Zschech, E; Feng, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jian; Wang, Tao; Liu, Pan; Liao, Zhongquan; Liu, Shaohua; Zhuang, Xiaodong; Chen, Mingwei; Zschech, Ehrenfried; Feng, Xinliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient hydrogen production on MoNi4 electrocatalysts with fast water dissociation kinetics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Various platinum-free electrocatalysts have been explored for hydrogen evolution reaction in acidic solutions. However, in economical water-alkali electrolysers, sluggish water dissociation kinetics (Volmer step) on platinum-free electrocatalysts results in poor hydrogen-production activities. Here we report a MoNi4 electrocatalyst supported by MoO2 cuboids on nickel foam (MoNi4/MoO2@Ni), which is constructed by controlling the outward diffusion of nickel atoms on annealing precursor NiMoO4 cuboids on nickel foam. Experimental and theoretical results confirm that a rapid Tafel-step-decided hydrogen evolution proceeds on MoNi4 electrocatalyst. As a result, the MoNi4 electrocatalyst exhibits zero onset overpotential, an overpotential of 15 mV at 10 mA cm(-2) and a low Tafel slope of 30 mV per decade in 1M potassium hydroxide electrolyte, which are comparable to the results for platinum and superior to those for state-of-the-art platinum-free electrocatalysts. Benefiting from its scalable preparation and stability, the MoNi4 electrocatalyst is promising for practical water-alkali electrolysers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 995, "Times Cited, All Databases": 1031, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 17", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15437, "DOI": "10.1038/ncomms15437", "DOI Link": "http://dx.doi.org/10.1038/ncomms15437", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401513800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Laplanche, G; Kostka, A; Reinhart, C; Hunfeld, J; Eggeler, G; George, EP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Laplanche, G.; Kostka, A.; Reinhart, C.; Hunfeld, J.; Eggeler, G.; George, E. P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reasons for the superior mechanical properties of medium-entropy CrCoNi compared to high-entropy CrMnFeCoNi", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The tensile properties of CrCoNi, a medium-entropy alloy, have been shown to be significantly better than those of CrMnFeCoNi, a high-entropy alloy. To understand the deformation mechanisms responsible for its superiority, tensile tests were performed on CrCoNi at liquid nitrogen temperature (77 K) and room temperature (293 K) and interrupted at different strains. Microstructural analyses by transmission electron microscopy showed that, during the early stage of plasticity, deformation occurs by the glide of 1/2 < 110 > dislocations dissociated into 1/6 < 112 > Shockley partials on 011) planes, similar to the behavior of CrMnFeCoNi. Measurements of the partial separations yielded a stacking fault energy of 22 +/- 4 mJ m(-2), which is similar to 25% lower than that of CrMnFeCoNi. With increasing strain, nullotwinning appears as an additional deformation mechanism in CrCoNi. The critical resolved shear stress for twinning in CrCoNi with 16 mu m grain size is 260 +/- 30 MPa, roughly independent of temperature, and comparable to that of CrMnFeCoNi having similar grain size. However, the yield strength and work hardening rate of CrCoNi are higher than those of CrMnFeCoNi. Consequently, the twinning stress is reached earlier (at lower strains) in CrCoNi. This in turn results in an extended strain range where nullotwinning can provide high, steady work hardening, leading to the superior mechanical properties (ultimate strength, ductility, and toughness) of medium-entropy CrCoNi compared to high-entropy CrMnFeCoNi. (C) 2017 Acta Materialia Inc. Published by Elsevier Ltd.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 984, "Times Cited, All Databases": 1028, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 15", "Publication Year": 2017, "Volume": 128, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 292, "End Page": 303, "Article Number": null, "DOI": "10.1016/j.actamat.2017.02.036", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2017.02.036", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397692600030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, XL; Zhu, YT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Xiaolei; Zhu, Yuntian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Heterogeneous materials: a new class of materials with unprecedented mechanical properties", "Source Title": "MATERIALS RESEARCH LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Here we present a perspective on heterogeneous materials, a new class of materials possessing superior combinations of strength and ductility that are not accessible to their homogeneous counterparts. Heterogeneous materials consist of domains with dramatic strength differences. The domain sizes may vary in the range of micrometers to millimeters. Large strain gradients near domain interfaces are produced during deformation, which produces a significant back-stress to strengthen the material and to produce high back-stress work hardening for good ductility. High interface density is required to maximize the back-stress, which is a new strengthening mechanism for improving mechanical properties. [GRAPHICS] .", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1048, "Times Cited, All Databases": 1104, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2017, "Volume": 5, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 527, "End Page": 532, "Article Number": null, "DOI": "10.1080/21663831.2017.1343208", "DOI Link": "http://dx.doi.org/10.1080/21663831.2017.1343208", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428140600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, CF; Anasori, B; Seral-Ascaso, A; Park, SH; McEvoy, N; Shmeliov, A; Duesberg, GS; Coleman, JN; Gogotsi, Y; Nicolosi, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Chuanfang (John); Anasori, Babak; Seral-Ascaso, Andres; Park, Sang-Hoon; McEvoy, Niall; Shmeliov, Aleksey; Duesberg, Georg S.; Coleman, Jonathan N.; Gogotsi, Yury; Nicolosi, Valeria", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Transparent, Flexible, and Conductive 2D Titanium Carbide (MXene) Films with High Volumetric Capacitance", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "2D transition-metal carbides and nitrides, known as MXenes, have displayed promising properties in numerous applications, such as energy storage, electromagnetic interference shielding, and catalysis. Titanium carbide MXene (Ti3C2Tx), in particular, has shown significant energy-storage capability. However, previously, only micrometer-thick, nontransparent films were studied. Here, highly transparent and conductive Ti3C2Tx films and their application as transparent, solid-state supercapacitors are reported. Transparent films are fabricated via spin-casting of Ti3C2Tx nullosheet colloidal solutions, followed by vacuum annealing at 200 degrees C. Films with transmittance of 93% (approximate to 4 nm) and 29% (approximate to 88 nm) demonstrate DC conductivity of approximate to 5736 and approximate to 9880 S cm(-1), respectively. Such highly transparent, conductive Ti3C2Tx films display impressive volumetric capacitance (676 F cm(-3)) combined with fast response. Transparent solid-state, asymmetric supercapacitors (72% transmittance) based on Ti3C2Tx and single-walled carbon nullotube (SWCNT) films are also fabricated. These electrodes exhibit high capacitance (1.6 mF cm(-2)) and energy density (0.05 mu W h cm(-2)), and long lifetime (no capacitance decay over 20 000 cycles), exceeding that of graphene or SWCNT-based transparent supercapacitor devices. Collectively, the Ti3C2Tx films are among the state-of-the-art for future transparent, conductive, capacitive electrodes, and translate into technologically viable devices for next-generation wearable, portable electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 943, "Times Cited, All Databases": 984, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 27", "Publication Year": 2017, "Volume": 29, "Issue": 36, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1702678, "DOI": "10.1002/adma.201702678", "DOI Link": "http://dx.doi.org/10.1002/adma.201702678", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000411379000027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Blancon, JC; Tsai, H; Nie, W; Stoumpos, CC; Pedesseau, L; Katan, C; Kepenekian, M; Soe, CMM; Appavoo, K; Sfeir, MY; Tretiak, S; Ajayan, PM; Kanatzidis, MG; Even, J; Crochet, JJ; Mohite, AD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Blancon, J. -C.; Tsai, H.; Nie, W.; Stoumpos, C. C.; Pedesseau, L.; Katan, C.; Kepenekian, M.; Soe, C. M. M.; Appavoo, K.; Sfeir, M. Y.; Tretiak, S.; Ajayan, P. M.; Kanatzidis, M. G.; Even, J.; Crochet, J. J.; Mohite, A. D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "PEROVSKITE PHYSICS Extremely efficient internal exciton dissociation through edge states in layered 2D perovskites", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Understanding and controlling charge and energy flow in state-of-the-art semiconductor quantum wells has enabled high-efficiency optoelectronic devices. Two-dimensional (2D) Ruddlesden-Popper perovskites are solution-processed quantum wells wherein the band gap can be tuned by varying the perovskite-layer thickness, which modulates the effective electron-hole confinement. We report that, counterintuitive to classical quantum-confined systems where photogenerated electrons and holes are strongly bound by Coulomb interactions or excitons, the photophysics of thin films made of Ruddlesden-Popper perovskites with a thickness exceeding two perovskite-crystal units (>1.3 nullometers) is dominated by lower-energy states associated with the local intrinsic electronic structure of the edges of the perovskite layers. These states provide a direct pathway for dissociating excitons into longer-lived free carriers that substantially improve the performance of optoelectronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 922, "Times Cited, All Databases": 997, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 24", "Publication Year": 2017, "Volume": 355, "Issue": 6331, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1288, "End Page": 1291, "Article Number": null, "DOI": "10.1126/science.aal4211", "DOI Link": "http://dx.doi.org/10.1126/science.aal4211", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397082900033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sherkar, TS; Momblona, C; Gil-Escrig, L; Avila, J; Sessolo, M; Bolink, HJ; Koster, LJA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sherkar, Tejas S.; Momblona, Cristina; Gil-Escrig, Lidon; Avila, Jorge; Sessolo, Michele; Bolink, Henk J.; Koster, L. Jan Anton", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Recombination in Perovskite Solar Cells: Significance of Grain Boundaries, Interface Traps, and Defect Ions", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Trap-assisted recombination, despite being lower as compared with traditional inorganic solar cells, is still the dominullt recombination mechanism in perovskite solar cells (PSCs) and limits their efficiency. We investigate the attributes of the primary trap assisted recombination channels (grain boundaries and interfaces) and their correlation to defect ions in PSCs. We achieve this by using a validated device model to fit the simulations to the experimental data of efficient vacuum-deposited p-i-n and n-i-p CH3NH3PbI3 solar cells, including the light intensity dependence of the open circuit voltage and fill factor. We find that, despite the presence of traps at interfaces and grain boundaries (GBs), their neutral (when filled with photogenerated charges) disposition along with the long-lived nature of holes leads to the high performance of PSCs. The sign of the traps (when filled) is of little importance in efficient solar cells with compact morphologies (fused GBs, low trap density). On the other hand, solar cells with noncompact morphologies (open GBs, high trap density) are sensitive to the sign of the traps and hence to the cell preparation methods. Even in the presence of traps at GBs, trap-assisted recombination at interfaces (between the transport layers and the perovskite) is the dominullt loss mechanism. We find a direct correlation between the density of traps, the density of mobile ionic defects, and the degree of hysteresis observed in the current voltage (J-V) characteristics. The presence of defect states or mobile ions not only limits the device performance but also plays a role in the J-V hysteresis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 917, "Times Cited, All Databases": 955, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2017, "Volume": 2, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1214, "End Page": 1222, "Article Number": null, "DOI": "10.1021/acsenergylett.7b00236", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.7b00236", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401500200040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chmiela, S; Tkatchenko, A; Sauceda, HE; Poltavsky, I; Schütt, KT; Müller, KR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chmiela, Stefan; Tkatchenko, Alexandre; Sauceda, Huziel E.; Poltavsky, Igor; Schuett, Kristof T.; Mueller, Klaus-Robert", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Machine learning of accurate energy-conserving molecular force fields", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Using conservation of energy-a fundamental property of closed classical and quantum mechanical systems-we develop an efficient gradient-domain machine learning (GDML) approach to construct accurate molecular force fields using a restricted number of samples from ab initio molecular dynamics (AIMD) trajectories. The GDML implementation is able to reproduce global potential energy surfaces of intermediate-sized molecules with an accuracy of 0.3 kcal mol(-1) for energies and 1 kcal mol(-1) angstrom(-1) for atomic forces using only 1000 conformational geometries for training. We demonstrate this accuracy for AIMD trajectories of molecules, including benzene, toluene, naphthalene, ethanol, uracil, and aspirin. The challenge of constructing conservative force fields is accomplished in our work by learning in a Hilbert space of vector-valued functions that obey the law of energy conservation. The GDML approach enables quantitative molecular dynamics simulations for molecules at a fraction of cost of explicit AIMD calculations, thereby allowing the construction of efficient force fields with the accuracy and transferability of high-level ab initio methods.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 852, "Times Cited, All Databases": 949, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2017, "Volume": 3, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1603015, "DOI": "10.1126/sciadv.1603015", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1603015", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401955300043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jung, R; Metzger, M; Maglia, F; Stinner, C; Gasteiger, HA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jung, Roland; Metzger, Michael; Maglia, Filippo; Stinner, Christoph; Gasteiger, Hubert A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Oxygen Release and Its Effect on the Cycling Stability of LiNixMnyCozO2 (NMC) Cathode Materials for Li-Ion Batteries", "Source Title": "JOURNAL OF THE ELECTROCHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Layered LiNixMnyCozO2 (NMC) is a widely used class of cathode materials with LiNi1/3Mn1/3Co1/3O2 (NMC111) being the most common representative. However, Ni-rich NMCs are more and more in the focus of current research due to their higher specific capacity and energy. In this work we will compare LiNi1/3Mn1/3Co1/3O2 (NMC111), LiNi0.6Mn0.2Co0.2O2 (NMC622), and LiNi0.8Mn0.1Co0.1O2 (NMC811) with respect to their cycling stability in NMC-graphite full-cells at different end-of-charge potentials. It will be shown that stable cycling is possible up to 4.4 V for NMC111 and NMC622 and only up to 4.0 V for NMC811. At higher potentials, significant capacity fading was observed, which was traced back to an increase in the polarization of the NMC electrode, contrary to the nearly constant polarization of the graphite electrode. Furthermore, we show that the increase in the polarization occurs when the NMC materials are cycled up to a high-voltage feature in the dq/dV plot, which occurs at similar to 4.7 V vs. Li/Li+ for NMC111 and NMC622 and at similar to 4.3 V vs. Li/Li+ for NMC811. For the latter material, this feature corresponds to the H2 -> H3 phase transition. Contrary to the common understanding that the electrochemical oxidation of carbonate electrolytes causes the CO2 and CO evolution at potentials above 4.7 V vs. Li/Li+, we believe that the observed CO2 and CO are mainly due to the chemical reaction of reactive lattice oxygen with the electrolyte. This hypothesis is based on gas analysis using On-line Electrochemical Mass Spectrometry (OEMS), by which we prove that all three materials release oxygen from the particle surface and that the oxygen evolution coincides with the onset of CO2 and CO evolution. Interestingly, the onsets of oxygen evolution for the different NMCs correlate well with the high-voltage redox feature at similar to 4.7 V vs. Li/Li+ for NMC111 and NMC622 as well as at similar to 4.3 V vs. Li/Li+ for NMC811. To support this hypothesis, we show that no CO2 or CO is evolved for the LiNi0.43Mn1.57O4 (LNMO) spinel up to 5 V vs. Li/Li+, consistent with the absence of oxygen release. Lastly, we demonstrate by the use of C-13 labeled conductive carbon that it is the electrolyte rather than the conductive carbon which is oxidized by the released lattice oxygen. Taking these findings into consideration, a mechanism is proposed for the reaction of released lattice oxygen with ethylene carbonate yielding CO2, CO, and H2O. (C) The Author(s) 2017. Published by ECS. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 978, "Times Cited, All Databases": 1050, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2017, "Volume": 164, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": "A1361", "End Page": "A1377", "Article Number": null, "DOI": "10.1149/2.0021707jes", "DOI Link": "http://dx.doi.org/10.1149/2.0021707jes", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Electrochemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404397300004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, YP; Gao, XZ; Jiang, L; Chen, ZN; Wang, TM; Jie, JC; Kang, HJ; Zhang, YB; Guo, S; Ruan, HH; Zhao, YH; Cao, ZQ; Li, TJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Yiping; Gao, Xuzhou; Jiang, Li; Chen, Zongning; Wang, Tongmin; Jie, Jinchuan; Kang, Huijun; Zhang, Yubo; Guo, Sheng; Ruan, Haihui; Zhao, Yonghao; Cao, Zhiqiang; Li, Tingju", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Directly cast bulk eutectic and near-eutectic high entropy alloys with balanced strength and ductility in a wide temperature range", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High entropy alloys (HEAs) usually possess weak liquidity and castability, and considerable compositional inhomogeneity, mainly because they contain multiple elements with high concentrations. As a result, large-scale production of HEAs by casting is limited. To address the issue, the concept of eutectic high entropy alloys (EHEAs) was proposed, which has led to some promise in achieving good quality industrial scale HEAs ingots, and more importantly also good mechanical properties. In the practical large-scale casting, the actual composition of designed EHEAs could potentially deviate from the eutectic composition. The influence of such deviation on mechanical properties of EHEAs is important for industrial production, which constitutes the topic of the current work. Here we prepared industrial-scale HEAs ingots near the eutectic composition: hypoeutectic alloy, eutectic alloy and hypereutectic alloy. Our results showed that the deviation from eutectic composition does not significantly affect the mechanical properties, castability and the good mechanical properties of EHEAs can be achieved in a wide compositional range, and at both room and cryogenic temperatures. Our results suggested that EHEAs with simultaneous high strength and high ductility, and good liquidity and castability can be readily adapted to large-scale industrial production. The deformation behavior and microstructure evolution of the eutectic and near-eutectic HEAs were thoroughly studied using a combination of techniques, including strain measurement by digital image correlation, in-situ synchrotron X-ray diffraction, and transmission electron microscopy. The wavy strain distribution and the therefore resulted delay of necking in EHEAs were reported for the first time. (C) 2016 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 877, "Times Cited, All Databases": 920, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 1", "Publication Year": 2017, "Volume": 124, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 143, "End Page": 150, "Article Number": null, "DOI": "10.1016/j.actamat.2016.11.016", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2016.11.016", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000393000800016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, H; Song, C; Hong, YS; Kim, MS; Cho, HR; Kang, T; Shin, K; Choi, SH; Hyeon, T; Kim, DH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, Hyunjae; Song, Changyeong; Hong, Yong Seok; Kim, Min Sung; Cho, Hye Rim; Kang, Taegyu; Shin, Kwangsoo; Choi, Seung Hong; Hyeon, Taeghwan; Kim, Dae-Hyeong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wearable/disposable sweat-based glucose monitoring device with multistage transdermal drug delivery module", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical analysis of sweat using soft bioelectronics on human skin provides a new route for noninvasive glucose monitoring without painful blood collection. However, sweat-based glucose sensing still faces many challenges, such as difficulty in sweat collection, activity variation of glucose oxidase due to lactic acid secretion and ambient temperature changes, and delamination of the enzyme when exposed to mechanical friction and skin deformation. Precise point-of-care therapy in response to the measured glucose levels is still very challenging. We present a wearable/disposable sweat-based glucose monitoring device integrated with a feedback transdermal drug delivery module. Careful multilayer patch design and miniaturization of sensors increase the efficiency of the sweat collection and sensing process. Multimodal glucose sensing, as well as its real-time correction based on pH, temperature, and humidity measurements, maximizes the accuracy of the sensing. The minimal layout design of the same sensors also enables a strip-type disposable device. Drugs for the feedback transdermal therapy are loaded on two different temperature-responsive phase change nulloparticles. These nulloparticles are embedded in hyaluronic acid hydrogel microneedles, which are additionally coated with phase change materials. This enables multistage, spatially patterned, and precisely controlled drug release in response to the patient's glucose level. The system provides a novel closed-loop solution for the noninvasive sweat-based management of diabetes mellitus.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 895, "Times Cited, All Databases": 971, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2017, "Volume": 3, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1601314", "DOI": "10.1126/sciadv.1601314", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1601314", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397044000018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Torrejon, J; Riou, M; Araujo, FA; Tsunegi, S; Khalsa, G; Querlioz, D; Bortolotti, P; Cros, V; Yakushiji, K; Fukushima, A; Kubota, H; Uasa, SY; Stiles, MD; Grollier, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Torrejon, Jacob; Riou, Mathieu; Araujo, Flavio Abreu; Tsunegi, Sumito; Khalsa, Guru; Querlioz, Damien; Bortolotti, Paolo; Cros, Vincent; Yakushiji, Kay; Fukushima, Akio; Kubota, Hitoshi; Uasa, Shinji Y.; Stiles, Mark D.; Grollier, Julie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Neuromorphic computing with nulloscale spintronic oscillators", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Neurons in the brain behave as nonlinear oscillators, which develop rhythmic activity and interact to process information(1). Taking inspiration from this behaviour to realize high-density, low-power neuromorphic computing will require very large numbers of nulloscale nonlinear oscillators. A simple estimation indicates that to fit 10(8) oscillators organized in a two-dimensional array inside a chip the size of a thumb, the lateral dimension of each oscillator must be smaller than one micrometre. However, nulloscale devices tend to be noisy and to lack the stability that is required to process data in a reliable way. For this reason, despite multiple theoretical proposals(2-5) and several candidates, including memristive(6) and superconducting(7) oscillators, a proof of concept of neuromorphic computing using nulloscale oscillators has yet to be demonstrated. Here we show experimentally that a nulloscale spintronic oscillator (a magnetic tunnel junction)(8,9) can be used to achieve spoken-digit recognition with an accuracy similar to that of state-of-the-art neural networks. We also determine the regime of magnetization dynamics that leads to the greatest performance. These results, combined with the ability of the spintronic oscillators to interact with each other, and their long lifetime and low energy consumption, open up a path to fast, parallel, on-chip computation based on networks of oscillators.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 983, "Times Cited, All Databases": 1044, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 27", "Publication Year": 2017, "Volume": 547, "Issue": 7664, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 428, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature23011", "DOI Link": "http://dx.doi.org/10.1038/nature23011", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000406358300030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, J; Wang, SH; Wang, GJN; Zhu, CX; Luo, SC; Jin, LH; Gu, XD; Chen, SC; Feig, VR; To, JWF; Rondeau-Gagne, S; Park, J; Schroeder, BC; Lu, C; Oh, JY; Wang, YM; Kim, YH; Yan, H; Sinclair, R; Zhou, DS; Xue, G; Murmann, B; Linder, C; Cai, W; Tok, JBH; Chung, JW; Bao, ZN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Jie; Wang, Sihong; Wang, Ging-Ji Nathan; Zhu, Chenxin; Luo, Shaochuan; Jin, Lihua; Gu, Xiaodan; Chen, Shucheng; Feig, Vivian R.; To, John W. F.; Rondeau-Gagne, Simon; Park, Joonsuk; Schroeder, Bob C.; Lu, Chien; Oh, Jin Young; Wang, Yanming; Kim, Yun-Hi; Yan, He; Sinclair, Robert; Zhou, Dongshan; Xue, Gi; Murmann, Boris; Linder, Christian; Cai, Wei; Tok, Jeffery B. -H.; Chung, Jong Won; Bao, Zhenull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly stretchable polymer semiconductor films through the nulloconfinement effect", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Soft and conformable wearable electronics require stretchable semiconductors, but existing ones typically sacrifice charge transport mobility to achieve stretchability. We explore a concept based on the nulloconfinement of polymers to substantially improve the stretchability of polymer semiconductors, without affecting charge transport mobility. The increased polymer chain dynamics under nulloconfinement significantly reduces the modulus of the conjugated polymer and largely delays the onset of crack formation under strain. As a result, our fabricated semiconducting film can be stretched up to 100% strain without affecting mobility, retaining values comparable to that of amorphous silicon. The fully stretchable transistors exhibit high biaxial stretchability with minimal change in on current even when poked with a sharp object. We demonstrate a skinlike finger-wearable driver for a light-emitting diode.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 992, "Times Cited, All Databases": 1070, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 6", "Publication Year": 2017, "Volume": 355, "Issue": 6320, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 59, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aah4496", "DOI Link": "http://dx.doi.org/10.1126/science.aah4496", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000391739900042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, EQ; Asada, M; Xu, Q; Dalapati, S; Addicoat, MA; Brady, MA; Xu, H; Nakamura, T; Heine, T; Chen, QH; Jiang, DL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Enquan; Asada, Mizue; Xu, Qing; Dalapati, Sasanka; Addicoat, Matthew A.; Brady, Michael A.; Xu, Hong; Nakamura, Toshikazu; Heine, Thomas; Chen, Qiuhong; Jiang, Donglin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Two-dimensional sp2 carbon-conjugated covalent organic frameworks", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We synthesized a two-dimensional (2D) crystalline covalent organic framework (sp(2)c-COF) that was designed to be fully pi-conjugated and constructed from all sp(2) carbons by C=C condensation reactions of tetrakis(4-formylphenyl)pyrene and 1,4-phenylenediacetonitrile. The C=C linkages topologically connect pyrene knots at regular intervals into a 2D lattice with pi conjugations extended along both x and y directions and develop an eclipsed layer framework rather than the more conventionally obtained disordered structures. The sp(2)c-COF is a semiconductor with a discrete band gap of 1.9 electron volts and can be chemically oxidized to enhance conductivity by 12 orders of magnitude. The generated radicals are confined on the pyrene knots, enabling the formation of a paramagnetic carbon structure with high spin density. The sp(2) carbon framework induces ferromagnetic phase transition to develop spin-spin coherence and align spins unidirectionally across the material.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 924, "Times Cited, All Databases": 977, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 18", "Publication Year": 2017, "Volume": 357, "Issue": 6352, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 673, "End Page": 676, "Article Number": null, "DOI": "10.1126/science.aan0202", "DOI Link": "http://dx.doi.org/10.1126/science.aan0202", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000407793600031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YY; Lin, DC; Yuen, PY; Liu, K; Xie, J; Dauskardt, RH; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yayuan; Lin, Dingchang; Yuen, Pak Yan; Liu, Kai; Xie, Jin; Dauskardt, Reinhold H.; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An Artificial Solid Electrolyte Interphase with High Li-Ion Conductivity, Mechanical Strength, and Flexibility for Stable Lithium Metal Anodes", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An artificial solid electrolyte interphase (SEI) is demonstrated for the efficient and safe operation of a lithium metal anode. Composed of lithium-ion-conducting inorganic nulloparticles within a flexible polymer binder matrix, the rationally designed artificial SEI not only mechanically suppresses lithium dendrite formation but also promotes homogeneous lithium-ion flux, significantly enhancing the efficiency and cycle life of the lithium metal anode.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 838, "Times Cited, All Databases": 912, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 14", "Publication Year": 2017, "Volume": 29, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1605531, "DOI": "10.1002/adma.201605531", "DOI Link": "http://dx.doi.org/10.1002/adma.201605531", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000396166800023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cai, GF; Wang, JX; Qian, K; Chen, JW; Li, SH; Lee, PS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cai, Guofa; Wang, Jiangxin; Qian, Kai; Chen, Jingwei; Li, Shaohui; Lee, Pooi See", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Extremely Stretchable Strain Sensors Based on Conductive Self-Healing Dynamic Cross-Links Hydrogels for Human-Motion Detection", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": null, "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 827, "Times Cited, All Databases": 870, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2017, "Volume": 4, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1600190, "DOI": "10.1002/advs.201600190", "DOI Link": "http://dx.doi.org/10.1002/advs.201600190", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000397020800006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Greczynski, G; Hultman, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Greczynski, Grzegorz; Hultman, Lars", "Book Author Full Names": null, "Group Authors": null, "Article Title": "C1s Peak of Adventitious Carbon Aligns to the Vacuum Level: Dire Consequences for Material's Bonding Assignment by Photoelectron Spectroscopy", "Source Title": "CHEMPHYSCHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The C1s signal from ubiquitous carbon contamination on samples forming during air exposure, so called adventitious carbon (AdC) layers, is the most common binding energy (BE) reference in X-ray photoelectron spectroscopy studies. We demonstrate here, by using a series of transition-metal nitride films with different AdC coverage, that the BE of the C1s peak E-B(F) varies by as much as 1.44 eV. This is a factor of 10 more than the typical resolvable difference between two chemical states of the same element, which makes BE referencing against the C1s peak highly unreliable. Surprisingly, we find that C1s shifts correlate to changes in sample work function phi(SA), such that the sum E-B(F) + phi(SA) is constant at 289.50 +/- 0.15 eV, irrespective of materials system and air exposure time, indicating vacuum level alignment. This discovery allows for significantly better accuracy of chemical state determination than offered by the conventional methods. Our findings are not specific to nitrides and likely apply to all systems in which charge transfer at the AdC/substrate interface is negligible.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 860, "Times Cited, All Databases": 884, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 20", "Publication Year": 2017, "Volume": 18, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1507, "End Page": 1512, "Article Number": null, "DOI": "10.1002/cphc.201700126", "DOI Link": "http://dx.doi.org/10.1002/cphc.201700126", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000403885800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gelebart, AH; Mulder, DJ; Varga, M; Konya, A; Vantomme, G; Meijer, EW; Selinger, RLB; Broer, DJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gelebart, Anne Helene; Mulder, Dirk Jan; Varga, Michael; Konya, Andrew; Vantomme, Ghislaine; Meijer, E. W.; Selinger, Robin L. B.; Broer, Dirk J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Making waves in a photoactive polymer film", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Oscillating materials(1-4) that adapt their shapes in response to external stimuli are of interest for emerging applications in medicine and robotics. For example, liquid-crystal networks can be programmed to undergo stimulus-induced deformations in various geometries, including in response to light(5,6). Azobenzene molecules are often incorporated into liquid-crystal polymer films to make them photoresponsive(7-11); however, in most cases only the bending responses of these films have been studied, and relaxation after photo-isomerization is rather slow. Modifying the core or adding substituents to the azobenzene moiety can lead to marked changes in photophysical and photochemical properties(12-15), providing an opportunity to circumvent the use of a complex set-up that involves multiple light sources, lenses or mirrors. Here, by incorporating azobenzene derivatives with fast cis-to-trans thermal relaxation into liquid-crystal networks, we generate photoactive polymer films that exhibit continuous, directional, macroscopic mechanical waves under constant light illumination, with a feedback loop that is driven by self-shadowing. We explain the mechanism of wave generation using a theoretical model and numerical simulations, which show good qualitative agreement with our experiments. We also demonstrate the potential application of our photoactive films in light-driven locomotion and self-cleaning surfaces, and anticipate further applications in fields such as photomechanical energy harvesting and miniaturized transport.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 817, "Times Cited, All Databases": 862, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 29", "Publication Year": 2017, "Volume": 546, "Issue": 7660, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 632, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature22987", "DOI Link": "http://dx.doi.org/10.1038/nature22987", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000404332000043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yan, PF; Zheng, JM; Gu, M; Xiao, J; Zhang, JG; Wang, CM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yan, Pengfei; Zheng, Jianming; Gu, Meng; Xiao, Jie; Zhang, Ji-Guang; Wang, Chong-Min", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Intragranular cracking as a critical barrier for high-voltage usage of layer-structured cathode for lithium-ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "LiNi1/3Mn1/3Co1/3O2-layered cathode is often fabricated in the form of secondary particles, consisting of densely packed primary particles. This offers advantages for high energy density and alleviation of cathode side reactions/corrosions, but introduces drawbacks such as intergranular cracking. Here, we report unexpected observations on the nucleation and growth of intragranular cracks in a commercial LiNi1/3Mn1/3Co1/3O2 cathode by using advanced scanning transmission electron microscopy. We find the formation of the intragranular cracks is directly associated with high-voltage cycling, an electrochemically driven and diffusion-controlled process. The intragranular cracks are noticed to be characteristically initiated from the grain interior, a consequence of a dislocation-based crack incubation mechanism. This observation is in sharp contrast with general theoretical models, predicting the initiation of intragranular cracks from grain boundaries or particle surfaces. Our study emphasizes that maintaining structural stability is the key step towards high-voltage operation of layered-cathode materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 804, "Times Cited, All Databases": 864, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 16", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 14101, "DOI": "10.1038/ncomms14101", "DOI Link": "http://dx.doi.org/10.1038/ncomms14101", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392095500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Resasco, J; Chen, LD; Clark, E; Tsai, C; Hahn, C; Jaramillo, TF; Chan, K; Bell, AT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Resasco, Joaquin; Chen, Leanne D.; Clark, Ezra; Tsai, Charlie; Hahn, Christopher; Jaramillo, Thomas F.; Chan, Karen; Bell, Alexis T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Promoter Effects of Alkali Metal Cations on the Electrochemical Reduction of Carbon Dioxide", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electrochemical reduction of CO2 is known to be influenced by the identity of the alkali metal cation in the electrolyte; however, a satisfactory explanation for this phenomenon has not been developed. Here we present the results of experimental and theoretical studies aimed at elucidating the effects of electrolyte cation size on the intrinsic activity and selectivity of metal catalysts for the reduction of CO2. Experiments were conducted under conditions where the influence of electrolyte polarization is minimal in order to show that cation size affects the intrinsic rates of formation of certain reaction products, most notably for HCOO-, C2H4, and C2H5OH over Cu(100)- and Cu(111)-oriented thin films, and for CO and HCOO- over polycrystalline Ag and Sn. Interpretation of the findings for CO2 reduction was informed by studies of the reduction of glyoxal and CO, key intermediates along the reaction pathway to final products. Density functional theory calculations show that the alkali metal cations influence the distribution of products formed as a consequence of electrostatic interactions between solvated cations present at the outer Helmholtz plane and adsorbed species having large dipole moments. The observed trends in activity with cation size are attributed to an increase in the concentration of cations at the outer Helmholtz plane with increasing cation size.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 774, "Times Cited, All Databases": 849, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 16", "Publication Year": 2017, "Volume": 139, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11277, "End Page": 11287, "Article Number": null, "DOI": "10.1021/jacs.7b06765", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b06765", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000408074800054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, KK; Gong, YH; Liu, BY; Zhu, YZ; Xu, SM; Yao, YG; Luo, W; Wang, CW; Lacey, SD; Dai, JQ; Chen, YN; Mo, YF; Wachsman, E; Hu, LB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Kun (Kelvin); Gong, Yunhui; Liu, Boyang; Zhu, Yizhou; Xu, Shaomao; Yao, Yonggang; Luo, Wei; Wang, Chengwei; Lacey, Steven D.; Dai, Jiaqi; Chen, Yanull; Mo, Yifei; Wachsman, Eric; Hu, Liangbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Toward garnet electrolyte-based Li metal batteries: An ultrathin, highly effective, artificial solid-state electrolyte/metallic Li interface", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solid-state batteries are a promising option toward high energy and power densities due to the use of lithium (Li) metal as an anode. Among all solid electrolyte materials ranging from sulfides to oxides and oxynitrides, cubic garnet-type Li7La3Zr2O12 (LLZO) ceramic electrolytes are superior candidates because of their high ionic conductivity (10(-3) to 10(-4) S/cm) and good stability against Li metal. However, garnet solid electrolytes generally have poor contact with Li metal, which causes high resistance and uneven current distribution at the interface. To address this challenge, we demonstrate a strategy to engineer the garnet solid electrolyte and the Li metal interface by forming an intermediary Li-metal alloy, which changes the wettability of the garnet surface (lithiophobic to lithiophilic) and reduces the interface resistance by more than an order of magnitude: 950 ohm.cm(2) for the pristine garnet/Li and 75 ohm.cm(2) for the surface-engineered garnet/Li. Li7La2.75Ca0.25Zr1.75Nb0.25O12 (LLCZN) was selected as the solid-state electrolyte (SSE) in this work because of its low sintering temperature, stabilized cubic garnet phase, and high ionic conductivity. This low area-specific resistance enables a solid-state garnet SSE/Li metal configuration and promotes the development of a hybrid electrolyte system. The hybrid system uses the improved solid-state garnet SSE Li metal anode and a thin liquid electrolyte cathode interfacial layer. This work provides new ways to address the garnet SSE wetting issue against Li and get more stable cell performances based on the hybrid electrolyte system for Li-ion, Li-sulfur, and Li-oxygen batteries toward the next generation of Li metal batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 741, "Times Cited, All Databases": 837, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2017, "Volume": 3, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e1601659", "DOI": "10.1126/sciadv.1601659", "DOI Link": "http://dx.doi.org/10.1126/sciadv.1601659", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401954800011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Volonakis, G; Haghighirad, AA; Milot, RL; Sio, WH; Filip, MR; Wenger, B; Johnston, MB; Herz, LM; Snaith, HJ; Giustino, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Volonakis, George; Haghighirad, Amir Abbas; Milot, Rebecca L.; Sio, Weng H.; Filip, Marina R.; Wenger, Bernard; Johnston, Michael B.; Herz, Laura M.; Snaith, Henry J.; Giustino, Feliciano", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cs2InAgCl6: A New Lead-Free Halide Double Perovskite with Direct Band Gap", "Source Title": "JOURNAL OF PHYSICAL CHEMISTRY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A(2)BB'X-6 halide double perovskites based on bismuth and silver have recently been proposed as potential environmentally friendly alternatives to lead-based hybrid halide perovskites. In particular, Cs2BiAgX6 (X = Cl, Br) have been synthesized and found to exhibit band gaps in the visible range. However, the band gaps of these compounds are indirect, which is not ideal for applications in thin film photovoltaics. Here, we propose a new class of halide double perovskites, where the B3+ and B+ cations are In3+ and Ag+, respectively. Our first-principles calculations indicate that the hypothetical compounds Cs2InAgX6 (X = Cl, Br, I) should exhibit direct band gaps between the visible (I) and the ultraviolet (Cl). Based on these predictions, we attempt to synthesize Cs2InAgCl6 and Cs2InAgBr6, and we succeed to form the hitherto unknown double perovskite Cs2InAgCl6. X-ray diffraction yields a double perovskite structure with space group Fm3m. The measured band gap is 3.3 eV, and the compound is found to be photosensitive and turns reversibly from white to orange under ultraviolet illumination. We also perform an empirical analysis of the stability of Cs2InAgX6 and their mixed halides based on Goldschmidts rules, and we find that it should also be possible to form Cs2InAg(Cl1xBrx)(6) for x < 1. The synthesis of mixed halides will open the way to the development of lead-free double perovskites with direct and tunable band gaps.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 839, "Times Cited, All Databases": 887, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 16", "Publication Year": 2017, "Volume": 8, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 772, "End Page": 778, "Article Number": null, "DOI": "10.1021/acs.jpclett.6b02682", "DOI Link": "http://dx.doi.org/10.1021/acs.jpclett.6b02682", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000394484100011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, LF; Lu, Y; Yu, L; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Li-Feng; Lu, Yan; Yu, Le; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Designed formation of hollow particle-based nitrogen-doped carbon nullofibers for high-performance supercapacitors", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon-based materials, as one of the most important electrode materials for supercapacitors, have attracted tremendous attention. At present, it is highly desirable but remains challenging to prepare one-dimensional carbon complex hollow nullomaterials for further improving the performance of supercapacitors. Herein, we report an effective strategy for the synthesis of hollow particle-based nitrogen-doped carbon nullofibers (HPCNFs-N). By embedding ultrafine zeolitic imidazolate framework (ZIF-8) nulloparticles into electrospun polyacrylonitrile (PAN), the as-prepared composite nullofibers are carbonized into hierarchical porous nullofibers composed of interconnected nitrogen-doped carbon hollow nulloparticles. Owing to its unique structural feature and the desirable chemical composition, the derived HPCNFs-N material exhibits much enhanced electrochemical properties as an electrode material for supercapacitors with remarkable specific capacitance at various current densities, high energy/power density and long cycling stability over 10 000 cycles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 784, "Times Cited, All Databases": 811, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 1", "Publication Year": 2017, "Volume": 10, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1777, "End Page": 1783, "Article Number": null, "DOI": "10.1039/c7ee00488e", "DOI Link": "http://dx.doi.org/10.1039/c7ee00488e", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000407211200008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dai, SX; Zhao, FW; Zhang, QQ; Lau, TK; Li, TF; Liu, K; Ling, QD; Wang, CR; Lu, XH; You, W; Zhan, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dai, Shuixing; Zhao, Fuwen; Zhang, Qianqian; Lau, Tsz-Ki; Li, Tengfei; Liu, Kuan; Ling, Qidan; Wang, Chunru; Lu, Xinhui; You, Wei; Zhan, Xiaowei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fused Nonacyclic Electron Acceptors for Efficient Polymer Solar Cells", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We design and synthesize four fused-ring electron acceptors based on-6,6,12,12-tetrakis(4-hexylphenyl)-indacenobis(dithieno[3,2-b-2',3'-d]thiophene) as the electron-rich unit and 1,1-dicyanomethylene-3-indanones with 0-2 fluorine substituents as the electron-deficient units. These four molecules exhibit broad (550-850 nm) and strong absorption with high extinction coefficients of (2.1-2.5) x 10(5) M-1 cm(-1). Fluorine substitution downshifts the LUMO energy level, red-shifts the absorption spectrum, and enhances electron mobility. The polymer solar cells based on the fluorinated electron acceptors exhibit power conversion efficiencies as high as 11.5%, much higher than that of their nonfluorinated counterpart (7.7%). We investigate the effects of the fluorine atom number and position on electronic properties, charge transport, film morphology, and photovoltaic properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 823, "Times Cited, All Databases": 844, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 25", "Publication Year": 2017, "Volume": 139, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1336, "End Page": 1343, "Article Number": null, "DOI": "10.1021/jacs.6b12755", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b12755", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000393541000041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, LQ; Yang, XL; Jiang, Q; Wang, PY; Yin, ZG; Zhang, XW; Tan, HR; Yang, Y; Wei, MY; Sutherland, BR; Sargent, EH; You, JB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Liuqi; Yang, Xiaolei; Jiang, Qi; Wang, Pengyang; Yin, Zhigang; Zhang, Xingwang; Tan, Hairen; Yang, Yang Michael; Wei, Mingyang; Sutherland, Brandon R.; Sargent, Edward H.; You, Jingbi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-bright and highly efficient inorganic based perovskite light-emitting diodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Inorganic perovskites such as CsPbX3 (X = Cl, Br, I) have attracted attention due to their excellent thermal stability and high photoluminescence quantum efficiency. However, the electroluminescence quantum efficiency of their light-emitting diodes was <1%. We posited that this low efficiency was a result of high leakage current caused by poor perovskite morphology, high non-radiative recombination at interfaces and perovskite grain boundaries, and also charge injection imbalance. Here, we incorporated a small amount of methylammonium organic cation into the CsPbBr3 lattice and by depositing a hydrophilic and insulating polyvinyl pyrrolidine polymer atop the ZnO electron-injection layer to overcome these issues. As a result, we obtained light-emitting diodes exhibiting a high brightness of 91,000 cd m(-2) and a high external quantum efficiency of 10.4% using a mixed-cation perovskite Cs(0.87)MA(0.13)PbBr(3) as the emitting layer. To the best of our knowledge, this is the brightest and most-efficient green perovskite light-emitting diodes reported to date.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 791, "Times Cited, All Databases": 850, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 7", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15640, "DOI": "10.1038/ncomms15640", "DOI Link": "http://dx.doi.org/10.1038/ncomms15640", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000402804700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Reis, F; Li, G; Dudy, L; Bauernfeind, M; Glass, S; Hanke, W; Thomale, R; Schafer, J; Claessen, R", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Reis, F.; Li, G.; Dudy, L.; Bauernfeind, M.; Glass, S.; Hanke, W.; Thomale, R.; Schafer, J.; Claessen, R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bismuthene on a SiC substrate: A candidate for a high-temperature quantum spin Hall material", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Quantum spin Hall materials hold the promise of revolutionary devices with dissipationless spin currents but have required cryogenic temperatures owing to small energy gaps. Here we show theoretically that a room-temperature regime with a large energy gap may be achievable within a paradigm that exploits the atomic spin-orbit coupling. The concept is based on a substrate-supported monolayer of a high-atomic number element and is experimentally realized as a bismuth honeycomb lattice on top of the insulating silicon carbide substrate SiC(0001). Using scanning tunneling spectroscopy, we detect a gap of similar to 0.8 electron volt and conductive edge states consistent with theory. Our combined theoretical and experimental results demonstrate a concept for a quantum spin Hall wide-gap scenario, where the chemical potential resides in the global system gap, ensuring robust edge conductance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 801, "Times Cited, All Databases": 842, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 21", "Publication Year": 2017, "Volume": 357, "Issue": 6348, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1126/science.aai8142", "DOI Link": "http://dx.doi.org/10.1126/science.aai8142", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000405901600037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tao, W; Zhu, XB; Yu, XH; Zeng, XW; Xiao, QL; Zhang, XD; Ji, XY; Wang, XS; Shi, JJ; Zhang, H; Mei, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tao, Wei; Zhu, Xianbing; Yu, Xinghua; Zeng, Xiaowei; Xiao, Quanlan; Zhang, Xudong; Ji, Xiaoyuan; Wang, Xusheng; Shi, Jinjun; Zhang, Han; Mei, Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Black Phosphorus nullosheets as a Robust Delivery Platform for Cancer Theranostics", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "2D black phosphorus (BP) nullo-materials are presented as a delivery platform. The endocytosis pathways and biological activities of PEGylated BP nullosheets in cancer cells are revealed for the first time. Finally, a triple-response combined therapy strategy is achieved by PEGylated BP nullosheets, showing a promising and enhanced antitumor effect.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 759, "Times Cited, All Databases": 797, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 4", "Publication Year": 2017, "Volume": 29, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1603276, "DOI": "10.1002/adma.201603276", "DOI Link": "http://dx.doi.org/10.1002/adma.201603276", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000392729000008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, CZ; Zhang, XQ; Cheng, XB; Zhang, R; Xu, R; Chen, PY; Peng, HJ; Huang, JQ; Zhang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Chen-Zi; Zhang, Xue-Qiang; Cheng, Xin-Bing; Zhang, Rui; Xu, Rui; Chen, Peng-Yu; Peng, Hong-Jie; Huang, Jia-Qi; Zhang, Qiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An anion-immobilized composite electrolyte for dendrite-free lithium metal anodes", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium metal is strongly regarded as a promising electrode material in next-generation rechargeable batteries due to its extremely high theoretical specific capacity and lowest reduction potential. However, the safety issue and short lifespan induced by uncontrolled dendrite growth have hindered the practical applications of lithium metal anodes. Hence, we propose a flexible anion-immobilized ceramic-polymer composite electrolyte to inhibit lithium dendrites and construct safe batteries. Anions in the composite electrolyte are tethered by a polymer matrix and ceramic fillers, inducing a uniform distribution of space charges and lithium ions that contributes to a dendrite-free lithium deposition. The dissociation of anions and lithium ions also helps to reduce the polymer crystallinity, rendering stable and fast transportation of lithium ions. Ceramic fillers in the electrolyte extend the electrochemically stable window to as wide as 5.5 V and provide a barrier to short circuiting for realizing safe batteries at elevated temperature. The anion-immobilized electrolyte can be applied in all-solid-state batteries and exhibits a small polarization of 15 mV. Cooperated with LiFePO4 and LiNi0.5Co0.2Mn0.3O2 cathodes, the all-solid-state lithium metal batteries render excellent specific capacities of above 150 mAh.g(-1) and well withstand mechanical bending. These results reveal a promising opportunity for safe and flexible next-generation lithium metal batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 744, "Times Cited, All Databases": 796, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 17", "Publication Year": 2017, "Volume": 114, "Issue": 42, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 11069, "End Page": 11074, "Article Number": null, "DOI": "10.1073/pnas.1708489114", "DOI Link": "http://dx.doi.org/10.1073/pnas.1708489114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000413237900037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, XG; Yang, JH; Fu, YH; Yang, DW; Xu, QL; Yu, LP; Wei, SH; Zhang, LJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Xin-Gang; Yang, Ji-Hui; Fu, Yuhao; Yang, Dongwen; Xu, Qiaoling; Yu, Liping; Wei, Su-Huai; Zhang, Lijun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Design of Lead-Free Inorganic Halide Perovskites for Solar Cells via Cation-Transmutation", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hybrid organic inorganic halide perovskites with the prototype material of CH3NH3PbI3 have recently attracted intense interest as low-cost and high-performance photovoltaic absorbers. Despite the high power conversion efficiency exceeding 20% achieved by their solar cells, two key issues-the poor device stabilities associated with their intrinsic material instability and the toxicity due to water-soluble Pb2+-need to be resolved before large-scale commercialization. Here, we address these issues by exploiting the 6 strategy of cation-transmutation to design stable inorganic Pb-free halide perovskites for solar cells. The idea is to convert two divalent Pb2+ ions into one monovalent M+ and one trivalent M3+ ions, forming a rich class of quaternary halides in double-perovskite structure. We find through first-principles calculations this class of materials have good phase stability against decomposition and wide range tunable optoelectronic properties. With photovoltaic-functionality-directed materials screening, we identify 11 optimal materials with intrinsic thermodynamic stability, suitable band gaps, small carrier effective masses, and low excitons binding energies as promising candidates to replace Pb-based photovoltaic absorbers in perovskite solar cells. The chemical trends of phase stabilities and electronic properties are also established for this class of materials, offering useful guidance for the development of perovskite solar cells fabricated with them.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 770, "Times Cited, All Databases": 803, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 22", "Publication Year": 2017, "Volume": 139, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2630, "End Page": 2638, "Article Number": null, "DOI": "10.1021/jacs.6b09645", "DOI Link": "http://dx.doi.org/10.1021/jacs.6b09645", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000394829200019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Feaster, JT; Shi, C; Cave, ER; Hatsukade, TT; Abram, DN; Kuhl, KP; Hahn, C; Norskov, JK; Jaramillo, TF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Feaster, Jeremy T.; Shi, Chuan; Cave, Etosha R.; Hatsukade, Tom T.; Abram, David N.; Kuhl, Kendra P.; Hahn, Christopher; Norskov, Jens K.; Jaramillo, Thomas F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Understanding Selectivity for the Electrochemical Reduction of Carbon Dioxide to Formic Acid and Carbon Monoxide on Metal Electrodes", "Source Title": "ACS CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Increases in energy demand and in chemical production, together with the rise in CO2 levels in the atmosphere, motivate the development of renewable energy sources. Electrochemical CO2 reduction to fuels and chemicals is an appealing alternative to traditional pathways to fuels and chemicals due to its intrinsic ability to couple to solar and wind energy sources. Formate (HCOO-) is a key chemical for many industries; however, greater understanding is needed regarding the mechanism and key intermediates for HCOO- production. This work reports a joint experimental and theoretical investigation of the electrochemical reduction of CO2 to HCOO- on polycrystalline Sn surfaces, which have been identified as promising catalysts for selectively producing HCOO-. Our results show that Sn electrodes produce HCOO-, carbon monoxide (CO), and hydrogen (H-2) across a range of potentials and that HCOO- production becomes favored at potentials more negative than -0.8 V vs RHE, reaching a maximum Faradaic efficiency of 70% at -0.9 V vs RHE. Scaling relations for Sn and other transition metals are examined using experimental current densities and density functional theory (DFT) binding energies. While *COOH was determined to be the key intermediate for CO production on metal surfaces, we suggest that it is unlikely to be the primary intermediate for HCOO- production. Instead, *OCHO is suggested to be the key intermediate for the CO2RR to HCOO- transformation, and Sn's optimal *OCHO binding energy supports its high selectivity for HCOO-. These results suggest that oxygen-bound intermediates are critical to understand the mechanism of CO2 reduction to HCOO- on metal surfaces.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 736, "Times Cited, All Databases": 800, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2017, "Volume": 7, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4822, "End Page": 4827, "Article Number": null, "DOI": "10.1021/acscatal.7b00687", "DOI Link": "http://dx.doi.org/10.1021/acscatal.7b00687", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000405360800075", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, HB; Yang, LQ; Jiang, X; Li, GC; Zhang, TR; Yao, QF; Zheng, GW; Lee, JY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Haibin; Yang, Liuqing; Jiang, Xi; Li, Guochun; Zhang, Tianran; Yao, Qiaofeng; Zheng, Guangyuan Wesley; Lee, Jim Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrocatalysis of polysulfide conversion by sulfur-deficient MoS2 nulloflakes for lithium-sulfur batteries", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium-sulfur batteries are promising next-generation energy storage devices due to their high energy density and low material cost. Efficient conversion of lithium polysulfides to lithium sulfide (during discharge) and to sulfur (during recharge) is a performance-determining factor for lithium-sulfur batteries. Here we show that MoS2-x/reduced graphene oxide (MoS2-x/rGO) can be used to catalyze the polysulfide reactions to improve the battery performance. It was confirmed, through microstructural characterization of the materials, that sulfur deficiencies on the surface participated in the polysulfide reactions and significantly enhanced the polysulfide conversion kinetics. The fast conversion of soluble polysulfides decreased their accumulation in the sulfur cathode and their loss from the cathode by diffusion. Hence in the presence of a small amount of MoS2-x/rGO (4 wt% of the cathode mass), high rate (8C) performance of the sulfur cathode was improved from a capacity of 161.1 mA h g(-1) to 826.5 mA h g(-1). In addition, MoS2-x/rGO also enhanced the cycle stability of the sulfur cathode from a capacity fade rate of 0.373% per cycle (over 150 cycles) to 0.083% per cycle (over 600 cycles) at a typical 0.5C rate. These results provide direct experimental evidence for the catalytic role of MoS2-x/rGO in promoting the polysulfide conversion kinetics in the sulfur cathode.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 836, "Times Cited, All Databases": 867, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 1", "Publication Year": 2017, "Volume": 10, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1476, "End Page": 1486, "Article Number": null, "DOI": "10.1039/c7ee01047h", "DOI Link": "http://dx.doi.org/10.1039/c7ee01047h", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000403320300017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, XF; Zhu, YZ; Mo, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Xingfeng; Zhu, Yizhou; Mo, Yifei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Origin of fast ion diffusion in super-ionic conductors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Super-ionic conductor materials have great potential to enable novel technologies in energy storage and conversion. However, it is not yet understood why only a few materials can deliver exceptionally higher ionic conductivity than typical solids or how one can design fast ion conductors following simple principles. Using ab initio modelling, here we show that fast diffusion in super-ionic conductors does not occur through isolated ion hopping as is typical in solids, but instead proceeds through concerted migrations of multiple ions with low energy barriers. Furthermore, we elucidate that the low energy barriers of the concerted ionic diffusion are a result of unique mobile ion configurations and strong mobile ion interactions in super-ionic conductors. Our results provide a general framework and universal strategy to design solid materials with fast ionic diffusion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 727, "Times Cited, All Databases": 794, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 21", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15893, "DOI": "10.1038/ncomms15893", "DOI Link": "http://dx.doi.org/10.1038/ncomms15893", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000403770700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fei, HL; Dong, JC; Feng, YX; Allen, CS; Wan, CZ; Volosskiy, B; Li, MF; Zhao, ZP; Wang, YL; Sun, HT; An, PF; Chen, WX; Guo, ZY; Lee, C; Chen, DL; Shakir, I; Liu, MJ; Hu, TD; Li, YD; Kirkland, AI; Duan, XF; Huang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fei, Huilong; Dong, Juncai; Feng, Yexin; Allen, Christopher S.; Wan, Chengzhang; Volosskiy, Boris; Li, Mufan; Zhao, Zipeng; Wang, Yiliu; Sun, Hongtao; An, Pengfei; Chen, Wenxing; Guo, Zhiying; Lee, Chain; Chen, Dongliang; Shakir, Imran; Liu, Mingjie; Hu, Tiandou; Li, Yadong; Kirkland, Angus I.; Duan, Xiangfeng; Huang, Yu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "General synthesis and definitive structural identification of MN4C4 single-atom catalysts with tunable electrocatalytic activities", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-atom catalysts (SACs) have recently attracted broad research interest as they combine the merits of both homogeneous and heterogeneous catalysts. Rational design and synthesis of SACs are of immense significance but have so far been plagued by the lack of a definitive correlation between structure and catalytic properties. Here, we report a general approach to a series of monodispersed atomic transition metals (for example, Fe, Co, Ni) embedded in nitrogen-doped graphene with a common MN4C4 moiety, identified by systematic X-ray absorption fine structure analyses and direct transmission electron microscopy imaging. The unambiguous structure determination allows density functional theoretical prediction of MN4C4 moieties as efficient oxygen evolution catalysts with activities following the trend Ni > Co > Fe, which is confirmed by electrochemical measurements. Determination of atomistic structure and its correlation with catalytic properties represents a critical step towards the rational design and synthesis of precious or nonprecious SACs with exceptional atom utilization efficiency and catalytic activities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1622, "Times Cited, All Databases": 1672, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2018, "Volume": 1, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 63, "End Page": 72, "Article Number": null, "DOI": "10.1038/s41929-017-0008-y", "DOI Link": "http://dx.doi.org/10.1038/s41929-017-0008-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428619500012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, Y; Fatemi, V; Fang, S; Watanabe, K; Taniguchi, T; Kaxiras, E; Jarillo-Herrero, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Yuan; Fatemi, Valla; Fang, Shiang; Watanabe, Kenji; Taniguchi, Takashi; Kaxiras, Efthimios; Jarillo-Herrero, Pablo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unconventional superconductivity in magic-angle graphene superlattices", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The behaviour of strongly correlated materials, and in particular unconventional superconductors, has been studied extensively for decades, but is still not well understood. This lack of theoretical understanding has motivated the development of experimental techniques for studying such behaviour, such as using ultracold atom lattices to simulate quantum materials. Here we report the realization of intrinsic unconventional superconductivity-which cannot be explained by weak electron-phonon interactions-in a two-dimensional superlattice created by stacking two sheets of graphene that are twisted relative to each other by a small angle. For twist angles of about 1.1 degrees-the first 'magic' angle-the electronic band structure of this 'twisted bilayer graphene' exhibits flat bands near zero Fermi energy, resulting in correlated insulating states at half-filling. Upon electrostatic doping of the material away from these correlated insulating states, we observe tunable zero-resistance states with a critical temperature of up to 1.7 kelvin. The temperature-carrier-density phase diagram of twisted bilayer graphene is similar to that of copper oxides (or cuprates), and includes dome-shaped regions that correspond to superconductivity. Moreover, quantum oscillations in the longitudinal resistance of the material indicate the presence of small Fermi surfaces near the correlated insulating states, in analogy with underdoped cuprates. The relatively high superconducting critical temperature of twisted bilayer graphene, given such a small Fermi surface (which corresponds to a carrier density of about 1011 per square centimetre), puts it among the superconductors with the strongest pairing strength between electrons. Twisted bilayer graphene is a precisely tunable, purely carbon-based, two-dimensional superconductor. It is therefore an ideal material for investigations of strongly correlated phenomena, which could lead to insights into the physics of high-critical-temperature superconductors and quantum spin liquids.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 5816, "Times Cited, All Databases": 6389, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 5", "Publication Year": 2018, "Volume": 556, "Issue": 7699, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 43, "End Page": "+", "Article Number": null, "DOI": "10.1038/nature26160", "DOI Link": "http://dx.doi.org/10.1038/nature26160", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000429103300032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, QS; Zhang, SN; Song, HF; Troyer, M; Soluyanov, AA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, QuanSheng; Zhang, Shengnull; Song, Hai-Feng; Troyer, Matthias; Soluyanov, Alexey A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "WannierTools: An open-source software package for novel topological materials", "Source Title": "COMPUTER PHYSICS COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present an open-source software package Wannier Tools, a tool for investigation of novel topological materials. This code works in the tight-binding framework, which can be generated by another software package Wannier90 (Mostofi et al., 2008). It can help to classify the topological phase of a given material by calculating the Wilson loop, and can get the surface state spectrum, which is detected by angle resolved photoemission (ARPES) and in scanning tunneling microscopy (STM) experiments. It also identifies positions of Weyl/Dirac points and nodal line structures, calculates the Berry phase around a closed momentum loop and Berry curvature in a part of the Brillouin zone (BZ). Program summary Program title: WannierTools Program Files doi: http://dx.doi.org/10.17632/ygsmh4hyh6.1 Licensing provisions: GNU General Public Licence 3.0 Programming language: Fortran 90 External routines/libraries used: BIAS (http://www/netlib.org/blas) LAPACK (http://www.netlib.org/lapack) Nature of problem: Identifying topological classificatiOns of crystalline systems including insulators, semimetals, metals, and studying the electronic properties of the related slab and ribbon systems. Solution method: Tight-binding method is a good approximation for solid systems. Based on that, Wilson loop is used for topological phase classification. The iterative Green's function is used for obtaining the surface state spectrum. (C) 2017 Elsevier BV. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1950, "Times Cited, All Databases": 2057, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2018, "Volume": 224, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 405, "End Page": 416, "Article Number": null, "DOI": "10.1016/j.cpc.2017.09.033", "DOI Link": "http://dx.doi.org/10.1016/j.cpc.2017.09.033", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000424726700035", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yao, P; Wu, HQ; Gao, B; Eryilmaz, SB; Huang, XY; Zhang, WQ; Zhang, QT; Deng, N; Shi, LP; Wong, HSP; Qian, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yao, Peng; Wu, Huaqiang; Gao, Bin; Eryilmaz, Sukru Burc; Huang, Xueyao; Zhang, Wenqiang; Zhang, Qingtian; Deng, Ning; Shi, Luping; Wong, H. -S. Philip; Qian, He", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Face classification using electronic synapses", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conventional hardware platforms consume huge amount of energy for cognitive learning due to the data movement between the processor and the off-chip memory. Brain-inspired device technologies using analogue weight storage allow to complete cognitive tasks more efficiently. Here we present an analogue non-volatile resistive memory (an electronic synapse) with foundry friendly materials. The device shows bidirectional continuous weight modulation behaviour. Grey-scale face classification is experimentally demonstrated using an integrated 1024-cell array with parallel online training. The energy consumption within the analogue synapses for each iteration is 1,000x (20x) lower compared to an implementation using Intel Xeon Phi processor with off-chip memory (with hypothetical on-chip digital resistive random access memory). The accuracy on test sets is close to the result using a central processing unit. These experimental results consolidate the feasibility of analogue synaptic array and pave the way toward building an energy efficient and large-scale neuromorphic system.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 759, "Times Cited, All Databases": 805, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 12", "Publication Year": 2017, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15199, "DOI": "10.1038/ncomms15199", "DOI Link": "http://dx.doi.org/10.1038/ncomms15199", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000401222500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, T; Grossman, JC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Tian; Grossman, Jeffrey C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Crystal Graph Convolutional Neural Networks for an Accurate and Interpretable Prediction of Material Properties", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The use of machine learning methods for accelerating the design of crystalline materials usually requires manually constructed feature vectors or complex transformation of atom coordinates to input the crystal structure, which either constrains the model to certain crystal types or makes it difficult to provide chemical insights. Here, we develop a crystal graph convolutional neural networks framework to directly learn material properties from the connection of atoms in the crystal, providing a universal and interpretable representation of crystalline materials. Our method provides a highly accurate prediction of density functional theory calculated properties for eight different properties of crystals with various structure types and compositions after being trained with 104 data points. Further, our framework is interpretable because one can extract the contributions from local chemical environments to global properties. Using an example of perovskites, we show how this information can be utilized to discover empirical rules for materials design.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1518, "Times Cited, All Databases": 1718, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 6", "Publication Year": 2018, "Volume": 120, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 145301, "DOI": "10.1103/PhysRevLett.120.145301", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.120.145301", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000429451000012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Schütt, KT; Sauceda, HE; Kindermans, PJ; Tkatchenko, A; Müller, KR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Schuett, K. T.; Sauceda, H. E.; Kindermans, P. -J.; Tkatchenko, A.; Mueller, K. -R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "SchNet - A deep learning architecture for molecules and materials", "Source Title": "JOURNAL OF CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Deep learning has led to a paradigm shift in artificial intelligence, including web, text, and image search, speech recognition, as well as bioinformatics, with growing impact in chemical physics. Machine learning, in general, and deep learning, in particular, are ideally suitable for representing quantum-mechanical interactions, enabling us to model nonlinear potential-energy surfaces or enhancing the exploration of chemical compound space. Here we present the deep learning architecture SchNet that is specifically designed to model atomistic systems by making use of continuous-filter convolutional layers. We demonstrate the capabilities of SchNet by accurately predicting a range of properties across chemical space for molecules and materials, where our model learns chemically plausible embeddings of atom types across the periodic table. Finally, we employ SchNet to predict potential-energy surfaces and energy-conserving force fields for molecular dynamics simulations of small molecules and perform an exemplary study on the quantum-mechanical properties of C-20-fullerene that would have been infeasible with regular ab initio molecular dynamics. Published by AIP Publishing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1389, "Times Cited, All Databases": 1517, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 28", "Publication Year": 2018, "Volume": 148, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 241722, "DOI": "10.1063/1.5019779", "DOI Link": "http://dx.doi.org/10.1063/1.5019779", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000437190300025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, JJ; Wang, XM; Li, SR; Liu, J; Guo, YM; Niu, GD; Yao, L; Fu, YH; Gao, L; Dong, QS; Zhao, CY; Leng, MY; Ma, FS; Liang, WX; Wang, LD; Jin, SY; Han, JB; Zhang, LJ; Etheridge, J; Wang, JB; Yan, YF; Sargent, EH; Tang, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Jiajun; Wang, Xiaoming; Li, Shunran; Liu, Jing; Guo, Yueming; Niu, Guangda; Yao, Li; Fu, Yuhao; Gao, Liang; Dong, Qingshun; Zhao, Chunyi; Leng, Meiying; Ma, Fusheng; Liang, Wenxi; Wang, Liduo; Jin, Shengye; Han, Junbo; Zhang, Lijun; Etheridge, Joanne; Wang, Jianbo; Yan, Yanfa; Sargent, Edward H.; Tang, Jiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient and stable emission of warm-white light from lead-free halide double perovskites", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lighting accounts for one-fifth of global electricity consumption(1). Single materials with efficient and stable white-light emission are ideal for lighting applications, but photon emission covering the entire visible spectrum is difficult to achieve using a single material. Metal halide perovskites have outstanding emission properties(2,3); however, the best-performing materials of this type contain lead and have unsatisfactory stability. Here we report a lead-free double perovskite that exhibits efficient and stable white-light emission via self-trapped excitons that originate from the Jahn-Teller distortion of the AgCl6 octahedron in the excited state. By alloying sodium cations into Cs2AgInCl6, we break the dark transition (the inversion-symmetry-induced parity-forbidden transition) by manipulating the parity of the wavefunction of the self-trapped exciton and reduce the electronic dimensionality of the semiconductor(4). This leads to an increase in photoluminescence efficiency by three orders of magnitude compared to pure Cs2AgInCl6. The optimally alloyed Cs-2(Ag0.60Na0.40) InCl6 with 0.04 per cent bismuth doping emits warm-white light with 86 +/- 5 per cent quantum efficiency and works for over 1,000 hours. We anticipate that these results will stimulate research on singleemitter-based white-light-emitting phosphors and diodes for next-generation lighting and display technologies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1705, "Times Cited, All Databases": 1781, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 22", "Publication Year": 2018, "Volume": 563, "Issue": 7732, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 541, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-018-0691-0", "DOI Link": "http://dx.doi.org/10.1038/s41586-018-0691-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000450960000050", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Guo, FS; Day, BM; Chen, YC; Tong, ML; Mansikkamäki, A; Layfield, RA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Guo, Fu-Sheng; Day, Benjamin M.; Chen, Yan-Cong; Tong, Ming-Liang; Mansikkamaki, Akseli; Layfield, Richard A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnetic hysteresis up to 80 kelvin in a dysprosium metallocene single-molecule magnet", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-molecule magnets (SMMs) containing only one metal center may represent the lower size limit for molecule-based magnetic information storage materials. Their current drawback is that all SMMs require liquid-helium cooling to show magnetic memory effects. We now report a chemical strategy to access the dysprosium metallocene cation [(Cp-iPr5)Dy(Cp*)](+) (Cp-iPr5, penta-iso-propylcyclopentadienyl; Cp*, pentamethylcyclopentadienyl), which displays magnetic hysteresis above liquid-nitrogen temperatures. An effective energy barrier to reversal of the magnetization of U-eff = 1541 wave number is also measured. The magnetic blocking temperature of T-B = 80 kelvin for this cation overcomes an essential barrier toward the development of nullomagnet devices that function at practical temperatures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1491, "Times Cited, All Databases": 1549, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 21", "Publication Year": 2018, "Volume": 362, "Issue": 6421, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1400, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aav0652", "DOI Link": "http://dx.doi.org/10.1126/science.aav0652", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000453845000058", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hua, QL; Sun, JL; Liu, HT; Bao, RR; Yu, RM; Zhai, JY; Pan, CF; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hua, Qilin; Sun, Junlu; Liu, Haitao; Bao, Rongrong; Yu, Ruomeng; Zhai, Junyi; Pan, Caofeng; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Skin-inspired highly stretchable and conformable matrix networks for multifunctional sensing", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Mechanosensation electronics (or Electronic skin, e-skin) consists of mechanically flexible and stretchable sensor networks that can detect and quantify various stimuli to mimic the human somatosensory system, with the sensations of touch, heat/cold, and pain in skin through various sensory receptors and neural pathways. Here we present a skin-inspired highly stretchable and conformable matrix network (SCMN) that successfully expands the e-skin sensing functionality including but not limited to temperature, in-plane strain, humidity, light, magnetic field, pressure, and proximity. The actualized specific expandable sensor units integrated on a structured polyimide network, potentially in three-dimensional (3D) integration scheme, can also fulfill simultaneous multi-stimulus sensing and achieve an adjustable sensing range and large-area expandability. We further construct a personalized intelligent prosthesis and demonstrate its use in real-time spatial pressure mapping and temperature estimation. Looking forward, this SCMN has broader applications in humanoid robotics, new prosthetics, human-machine interfaces, and health-monitoring technologies.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1204, "Times Cited, All Databases": 1273, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 16", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 244, "DOI": "10.1038/s41467-017-02685-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-02685-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000422649500006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "van Setten, MJ; Giantomassi, M; Bousquet, E; Verstraete, MJ; Hamann, DR; Gonze, X; Rignullese, GM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "van Setten, M. J.; Giantomassi, M.; Bousquet, E.; Verstraete, M. J.; Hamann, D. R.; Gonze, X.; Rignullese, G. -M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The PSEUDODOJO: Training and grading a 85 element optimized norm-conserving pseudopotential table", "Source Title": "COMPUTER PHYSICS COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "First-principles calculations in crystalline structures are often performed with a planewave basis set. To make the number of basis functions tractable two approximations are usually introduced: core electrons are frozen and the diverging Coulomb potential near the nucleus is replaced by a smoother expression. The norm-conserving pseudopotential was the first successful method to apply these approximations in a fully ab initio way. Later on, more efficient and more exact approaches were developed based on the ultrasoft and the projector augmented wave formalisms. These formalisms are however more complex and developing new features in these frameworks is usually more difficult than in the norm conserving framework. Most of the existing tables of norm-conserving pseudopotentials, generated long ago, do not include the latest developments, are not systematically tested or are not designed primarily for high precision. In this paper, we present our PSEUDODOJO framework for developing and testing full tables of pseudopotentials, and demonstrate it with a new table generated with the ONCVPSP approach. The PSEUDODOJO is an open source project, building on the ABIPY package, for developing and systematically testing pseudopotentials. At present it contains 7 different batteries of tests executed with ABINIT, which are performed as a function of the energy cutoff. The results of these tests are then used to provide hints for the energy cutoff for actual production calculations. Our final set contains 141 pseudopotentials split into a standard and a stringent accuracy table. In total around 70,000 calculations were performed to test the pseudopotentials. The process of developing the final table led to new insights into the effects of both the core-valence partitioning and the non-linear core corrections on the stability, convergence, and transferability of norm-conserving pseudopotentials. The PSEUDODOJO hence provides a set of pseudopotentials and general purpose tools for further testing and development, focusing on highly accurate calculations and their use in the development of ab initio packages. The pseudopotential files are available on the PSEUDODOJO web-interface pseudo-dojo.org under the name NC (ONCVPSP) v0.4 in the psp8, UPF2, and PSML 1.1 formats. The webinterface also provides the inputs, which are compatible with the 3.3.1 and higher versions of ONCVPSP. All tests have been performed with ABINIT 8.4. (C) 2018 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1303, "Times Cited, All Databases": 1349, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2018, "Volume": 226, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 39, "End Page": 54, "Article Number": null, "DOI": "10.1016/j.cpc.2018.01.012", "DOI Link": "http://dx.doi.org/10.1016/j.cpc.2018.01.012", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428483000005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, ZY; Chen, GX; Siahrostami, S; Chen, ZH; Liu, K; Xie, J; Liao, L; Wu, T; Lin, DC; Liu, YY; Jaramillo, TF; Norskov, JK; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Zhiyi; Chen, Guangxu; Siahrostami, Samira; Chen, Zhihua; Liu, Kai; Xie, Jin; Liao, Lei; Wu, Tong; Lin, Dingchang; Liu, Yayuan; Jaramillo, Thomas F.; Norskov, Jens K.; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-efficiency oxygen reduction to hydrogen peroxide catalysed by oxidized carbon materials", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogen peroxide (H2O2) is a valuable chemical with a wide range of applications, but the current industrial synthesis of H2O2 involves an energy-intensive anthraquinone process. The electrochemical synthesis of H2O2 from oxygen reduction offers an alternative route for on-site applications; the efficiency of this process depends greatly on identifying cost-effective catalysts with high activity and selectivity. Here, we demonstrate a facile and general approach to catalyst development via the surface oxidation of abundant carbon materials to significantly enhance both the activity and selectivity (similar to 90%) for H2O2 production by electrochemical oxygen reduction. We find that both the activity and selectivity are positively correlated with the oxygen content of the catalysts. The density functional theory calculations demonstrate that the carbon atoms adjacent to several oxygen functional groups (-COOH and C-O-C) are the active sites for oxygen reduction reaction via the two-electron pathway, which are further supported by a series of control experiments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1353, "Times Cited, All Databases": 1437, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2018, "Volume": 1, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 156, "End Page": 162, "Article Number": null, "DOI": "10.1038/s41929-017-0017-x", "DOI Link": "http://dx.doi.org/10.1038/s41929-017-0017-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428621500015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, LF; Han, JQ; Wang, H; Car, R; Weinull, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Linfeng; Han, Jiequn; Wang, Han; Car, Roberto; Weinull, E.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Deep Potential Molecular Dynamics: A Scalable Model with the Accuracy of Quantum Mechanics", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We introduce a scheme for molecular simulations, the deep potential molecular dynamics (DPMD) method, based on a many-body potential and interatomic forces generated by a carefully crafted deep neural network trained with ab initio data. The neural network model preserves all the natural symmetries in the problem. It is first-principles based in the sense that there are no ad hoc components aside from the network model. We show that the proposed scheme provides an efficient and accurate protocol in a variety of systems, including bulk materials and molecules. In all these cases, DPMD gives results that are essentially indistinguishable from the original data, at a cost that scales linearly with system size.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1319, "Times Cited, All Databases": 1452, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 4", "Publication Year": 2018, "Volume": 120, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 143001, "DOI": "10.1103/PhysRevLett.120.143001", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.120.143001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000429119100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wan, F; Zhang, LL; Dai, X; Wang, XY; Niu, ZQ; Chen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wan, Fang; Zhang, Linlin; Dai, Xi; Wang, Xinyu; Niu, Zhiqiang; Chen, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Aqueous rechargeable zinc/sodium vanadate batteries with enhanced performance from simultaneous insertion of dual carriers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable aqueous zinc-ion batteries are promising energy storage devices due to their high safety and low cost. However, they remain in their infancy because of the limited choice of positive electrodes with high capacity and satisfactory cycling performance. Furthermore, their energy storage mechanisms are not well established yet. Here we report a highly reversible zinc/sodium vanadate system, where sodium vanadate hydrate nullobelts serve as positive electrode and zinc sulfate aqueous solution with sodium sulfate additive is used as electrolyte. Different from conventional energy release/storage in zinc-ion batteries with only zinc-ion insertion/extraction, zinc/sodium vanadate hydrate batteries possess a simultaneous proton, and zinc-ion insertion/extraction process that is mainly responsible for their excellent performance, such as a high reversible capacity of 380 mAh g(-1) and capacity retention of 82% over 1000 cycles. Moreover, the quasi-solid-state zinc/sodium vanadate hydrate battery is also a good candidate for flexible energy storage device.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1393, "Times Cited, All Databases": 1458, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 25", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1656, "DOI": "10.1038/s41467-018-04060-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04060-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430798100012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, SJ; Koh, HJ; Ren, CE; Kwon, O; Maleski, K; Cho, SY; Anasori, B; Kim, CK; Choi, YK; Kim, J; Gogotsi, Y; Jung, HT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Seon Joon; Koh, Hyeong-Jun; Ren, Chang E.; Kwon, Ohmin; Maleski, Kathleen; Cho, Soo-Yeon; Anasori, Babak; Kim, Choong-Ki; Choi, Yang-Kyu; Kim, Jihan; Gogotsi, Yury; Jung, Hee-Tae", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metallic Ti3C2TX MXene Gas Sensors with Ultrahigh Signal-to-Noise Ratio", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Achieving high sensitivity in solid-state gas sensors can allow the precise detection of chemical agents. In particular, detection of volatile organic compounds (VOCs) at the parts per billion (ppb) level is critical for the early diagnosis of diseases. To obtain high sensitivity, two requirements need to be simultaneously satisfied: (i) low electrical noise and (ii) strong signal, which existing sensor materials cannot meet. Here, we demonstrate that 2D metal carbide MXenes, which possess high metallic conductivity for low noise and a fully functionalized surface for a strong signal, greatly outperform the sensitivity of conventional semiconductor channel materials. Ti3C2Tx MXene gas sensors exhibited a very low limit of detection of 50-100 ppb for VOC gases at room temperature. Also, the extremely low noise led to a signal-to-noise ratio 2 orders of magnitude higher than that of other 2D materials, surpassing the best sensors known. Our results provide insight in utilizing highly functionalized metallic sensing channels for developing highly sensitive sensors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1286, "Times Cited, All Databases": 1349, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2018, "Volume": 12, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 986, "End Page": 993, "Article Number": null, "DOI": "10.1021/acsnullo.7b07460", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.7b07460", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426615600009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, JZ; Chen, MJ; Cullen, DA; Hwang, S; Wang, MY; Li, BY; Liu, KX; Karakalos, S; Lucero, M; Zhang, HG; Lei, C; Xu, H; Sterbinsky, GE; Feng, ZX; Su, D; More, KL; Wang, GF; Wang, ZB; Wu, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jiazhan; Chen, Mengjie; Cullen, David A.; Hwang, Sooyeon; Wang, Maoyu; Li, Boyang; Liu, Kexi; Karakalos, Stavros; Lucero, Marcos; Zhang, Hanguang; Lei, Chao; Xu, Hui; Sterbinsky, George E.; Feng, Zhenxing; Su, Dong; More, Karren L.; Wang, Guofeng; Wang, Zhenbo; Wu, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomically dispersed manganese catalysts for oxygen reduction in proton-exchange membrane fuel cells", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Platinum group metal (PGM)-free catalysts that are also iron free are highly desirable for the oxygen reduction reaction (ORR) in proton-exchange membrane fuel cells, as they avoid possible Fenton reactions. Here we report an efficient ORR catalyst that consists of atomically dispersed nitrogen-coordinated single Mn sites on partially graphitic carbon (Mn-N-C). Evidence for the embedding of the atomically dispersed MnN4 moieties within the carbon surface-exposed basal planes was established by X-ray absorption spectroscopy and their dispersion was confirmed by aberration-corrected electron microscopy with atomic resolution. The Mn-N-C catalyst exhibited a half-wave potential of 0.80 V versus the reversible hydrogen electrode, approaching that of Fe-N-C catalysts, along with significantly enhanced stability in acidic media. The encouraging performance of the Mn-N-C catalyst as a PGM-free cathode was demonstrated in fuel cell tests. First-principles calculations further support the MnN4 sites as the origin of the ORR activity via a 4e(-) pathway in acidic media.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1208, "Times Cited, All Databases": 1262, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2018, "Volume": 1, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 935, "End Page": 945, "Article Number": null, "DOI": "10.1038/s41929-018-0164-8", "DOI Link": "http://dx.doi.org/10.1038/s41929-018-0164-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000452918800010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, JH; Wang, Z; Hou, MY; Dong, XL; Liu, Y; Wang, YG; Xia, YY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Jianhang; Wang, Zhuo; Hou, Mengyan; Dong, Xiaoli; Liu, Yao; Wang, Yonggang; Xia, Yongyao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polyaniline-intercalated manganese dioxide nullolayers as a high-performance cathode material for an aqueous zinc-ion battery", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable zinc-manganese dioxide batteries that use mild aqueous electrolytes are attracting extensive attention due to high energy density and environmental friendliness. Unfortunately, manganese dioxide suffers from substantial phase changes (e.g., from initial alpha-, beta-, or gamma-phase to a layered structure and subsequent structural collapse) during cycling, leading to very poor stability at high charge/discharge depth. Herein, cyclability is improved by the design of a polyaniline-intercalated layered manganese dioxide, in which the polymerstrengthened layered structure and nulloscale size of manganese dioxide serves to eliminate phase changes and facilitate charge storage. Accordingly, an unprecedented stability of 200 cycles with at a high capacity of 280 mA h g(-1) (i.e., 90% utilization of the theoretical capacity of manganese dioxide) is achieved, as well as a long-term stability of 5000 cycles at a utilization of 40%. The encouraging performance sheds light on the design of advanced cathodes for aqueous zinc-ion batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1198, "Times Cited, All Databases": 1253, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 25", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2906, "DOI": "10.1038/s41467-018-04949-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04949-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000439687600004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, J; Zhang, KN; Zhang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jia; Zhang, Kaina; Zhang, Hua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Adsorption of antibiotics on microplastics", "Source Title": "ENVIRONMENTAL POLLUTION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Microplastics and antibiotics are two classes of emerging contaminullts with proposed negative impacts to aqueous ecosystems. Adsorption of antibiotics on microplastics may result in their long-range transport and may cause compound combination effects. In this study, we investigated the adsorption of 5 antibiotics [sulfadiazine (SDZ), amoxicillin (AMX), tetracycline (TC), ciprofloxacin (CIP), and trimethoprim (TMP)] on 5 types of microplastics [polyethylene (PE), polystyrene (PS), polypropylene (PP), polyamide (PA), and polyvinyl chloride (PVC)] in the freshwater and seawater systems. Scanning Electron Microscope (SEM) and X-ray diffractometer (XRD) analysis revealed that microplastics have different surface characterizes and various degrees of crystalline. Adsorption isotherms demonstrated that PA had the strongest adsorption capacity for antibiotics with distribution coefficient (K-d) values ranged from 7.36 +/- 0.257 to 756 +/- 48.0 L kg(-1) in the freshwater system, which can be attributed to its porous structure and hydrogen bonding. Relatively low adsorption capacity was observed on other four microplastics. The adsorption amounts of 5 antibiotics on PS, PE, PP, and PVC decreased in the order of CIP > AMX > TMP > SDZ > TC with K-f correlated positively with octanol-water partition coefficients (Log K-OW). Comparing to freshwater system, adsorption capacity in seawater decreased significantly and no adsorption was observed for CIP and AMX. Our results indicated that commonly observed polyamide particles can serve as a carrier of antibiotics in the aquatic environment. (C) 2018 Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 928, "Times Cited, All Databases": 1062, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2018, "Volume": 237, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 460, "End Page": 467, "Article Number": null, "DOI": "10.1016/j.envpol.2018.02.050", "DOI Link": "http://dx.doi.org/10.1016/j.envpol.2018.02.050", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431158900047", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xia, Y; Mathis, TS; Zhao, MQ; Anasori, B; Dang, A; Zhou, ZH; Cho, H; Gogotsi, Y; Yang, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xia, Yu; Mathis, Tyler S.; Zhao, Meng-Qiang; Anasori, Babak; Dang, Alei; Zhou, Zehang; Cho, Hyesung; Gogotsi, Yury; Yang, Shu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thickness - independent capacitance of vertically aligned liquid-crystalline MXenes", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The scalable and sustainable manufacture of thick electrode films with high energy and power densities is critical for the large-scale storage of electrochemical energy for application in transportation and stationary electric grids. Two-dimensional nullomaterials have become the predominullt choice of electrode material in the pursuit of high energy and power densities owing to their large surface area-to-volume ratios and lack of solid-state diffusion(1,2). However, traditional electrode fabrication methods often lead to restacking of two-dimensional nullomaterials, which limits ion transport in thick films and results in systems in which the electrochemical performance is highly dependent on the thickness of the film(1-4). Strategies for facilitating ion transport such as increasing the interlayer spacing by intercalation(5-8) or introducing film porosity by designing nulloarchitectures(9,10)-result in materials with low volumetric energy storage as well as complex and lengthy ion transport paths that impede performance at high charge-discharge rates. Vertical alignment of two-dimensional flakes enables directional ion transport that can lead to thickness-independent electrochemical performances in thick films(11-13). However, so far only limited success(11,12) has been reported, and the mitigation of performance losses remains a major challenge when working with films of two-dimensional nullomaterials with thicknesses that are near to or exceed the industrial standard of 100 micrometres. Here we demonstrate electrochemical energy storage that is independent of film thickness for vertically aligned two-dimensional titanium carbide (Ti3C2Tx), a material from the MXene family (two dimensional carbides and nitrides of transition metals (M), where X stands for carbon or nitrogen). The vertical alignment was achieved by mechanical shearing of a discotic lamellar liquid-crystal phase of Ti3C2Tx. The resulting electrode films show excellent performance that is nearly independent of film thickness up to 200 micrometres, which makes them highly attractive for energy storage applications. Furthermore, the self-assembly approach presented here is scalable and can be extended to other systems that involve directional transport, such as catalysis and filtration.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1062, "Times Cited, All Databases": 1129, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 17", "Publication Year": 2018, "Volume": 557, "Issue": 7705, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 409, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-018-0109-z", "DOI Link": "http://dx.doi.org/10.1038/s41586-018-0109-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000432242000057", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, D; Yang, RX; Wang, K; Wu, CC; Zhu, XJ; Feng, JS; Ren, XD; Fang, GJ; Priya, S; Liu, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Dong; Yang, Ruixia; Wang, Kai; Wu, Congcong; Zhu, Xuejie; Feng, Jiangshan; Ren, Xiaodong; Fang, Guojia; Priya, Shashank; Liu, Shengzhong (Frank)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High efficiency planar-type perovskite solar cells with negligible hysteresis using EDTA-complexed SnO2", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Even though the mesoporous-type perovskite solar cell (PSC) is known for high efficiency, its planar-type counterpart exhibits lower efficiency and hysteretic response. Herein, we report success in suppressing hysteresis and record efficiency for planar-type devices using EDTA-complexed tin oxide (SnO2) electron-transport layer. The Fermi level of EDTA-complexed SnO2 is better matched with the conduction band of perovskite, leading to high open-circuit voltage. Its electron mobility is about three times larger than that of the SnO2. The record power conversion efficiency of planar-type PSCs with EDTA-complexed SnO2 increases to 21.60% (certified at 21.52% by Newport) with negligible hysteresis. Meanwhile, the low-temperature processed EDTA-complexed SnO2 enables 18.28% efficiency for a flexible device. Moreover, the unsealed PSCs with EDTA-complexed SnO2 degrade only by 8% exposed in an ambient atmosphere after 2880 h, and only by 14% after 120 h under irradiation at 100 mW cm(-2).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1244, "Times Cited, All Databases": 1290, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 13", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3239, "DOI": "10.1038/s41467-018-05760-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-05760-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000441382000017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bandres, MA; Wittek, S; Harari, G; Parto, M; Ren, JH; Segev, M; Christodoulides, DN; Khajavikhan, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bandres, Miguel A.; Wittek, Steffen; Harari, Gal; Parto, Midya; Ren, Jinhan; Segev, Mordechai; Christodoulides, Demetrios N.; Khajavikhan, Mercedeh", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topological insulator laser: Experiments", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Physical systems exhibiting topological invariants are naturally endowed with robustness against perturbations, as manifested in topological insulators-materials exhibiting robust electron transport, immune from scattering by defects and disorder. Recent years have witnessed intense efforts toward exploiting these phenomena in photonics. Here we demonstrate a nonmagnetic topological insulator laser system exhibiting topologically protected transport in the cavity. Its topological properties give rise to single-mode lasing, robustness against defects, and considerably higher slope efficiencies compared to the topologically trivial counterparts. We further exploit the properties of active topological platforms by assembling the system from S-chiral microresonators, enforcing predetermined unidirectional lasing without magnetic fields. This work paves the way toward active topological devices with exciting properties and functionalities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1042, "Times Cited, All Databases": 1120, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 16", "Publication Year": 2018, "Volume": 359, "Issue": 6381, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaar4005", "DOI": "10.1126/science.aar4005", "DOI Link": "http://dx.doi.org/10.1126/science.aar4005", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435220800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, EK; Sun, Y; Kumar, N; Muechler, L; Sun, AL; Jiao, L; Yang, SY; Liu, DF; Liang, AJ; Xu, QN; Kroder, J; Süss, V; Borrmann, H; Shekhar, C; Wang, ZS; Xi, CY; Wang, WH; Schnelle, W; Wirth, S; Chen, YL; Goennenwein, STB; Felser, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Enke; Sun, Yan; Kumar, Nitesh; Muechler, Lukas; Sun, Aili; Jiao, Lin; Yang, Shuo-Ying; Liu, Defa; Liang, Aiji; Xu, Qiunull; Kroder, Johannes; Suess, Vicky; Borrmann, Horst; Shekhar, Chandra; Wang, Zhaosheng; Xi, Chuanying; Wang, Wenhong; Schnelle, Walter; Wirth, Steffen; Chen, Yulin; Goennenwein, Sebastian T. B.; Felser, Claudia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Giant anomalous Hall effect in a ferromagnetic kagome-lattice semimetal", "Source Title": "NATURE PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnetic Weyl semimetals with broken time-reversal symmetry are expected to generate strong intrinsic anomalous Hall effects, due to their large Berry curvature. Here, we report a magnetic Weyl semimetal candidate, Co3Sn2S2, with a quasi-two-dimensional crystal structure consisting of stacked kagome lattices. This lattice provides an excellent platform for hosting exotic topological quantum states. We observe a negative magnetoresistance that is consistent with the chiral anomaly expected from the presence of Weyl fermions close to the Fermi level. The anomalous Hall conductivity is robust against both increased temperature and charge conductivity, which corroborates the intrinsic Berry-curvature mechanism in momentum space. Owing to the low carrier density in this material and the considerably enhanced Berry curvature from its band structure, the anomalous Hall conductivity and the anomalous Hall angle simultaneously reach 1,130 Omega(-1) cm(-1) and 20%, respectively, an order of magnitude larger than typical magnetic systems. Combining the kagome-lattice structure and the long-range out-of-plane ferromagnetic order of Co3Sn2S2, we expect that this material is an excellent candidate for observation of the quantum anomalous Hall state in the two-dimensional limit.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1020, "Times Cited, All Databases": 1097, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2018, "Volume": 14, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1125, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41567-018-0234-5", "DOI Link": "http://dx.doi.org/10.1038/s41567-018-0234-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000448973100019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, TC; Cai, XH; Tu, MWY; Zhang, XO; Huang, BV; Wilson, NP; Seyler, KL; Zhu, L; Taniguchi, T; Watanabe, K; McGuire, MA; Cobden, DH; Xiao, D; Yao, W; Xu, XD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Tiancheng; Cai, Xinghan; Tu, Matisse Wei-Yuan; Zhang, Xiaoou; Huang, Bevin; Wilson, Nathan P.; Seyler, Kyle L.; Zhu, Lin; Taniguchi, Takashi; Watanabe, Kenji; McGuire, Michael A.; Cobden, David H.; Xiao, Di; Yao, Wang; Xu, Xiaodong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Giant tunneling magnetoresistance in spin-filter van der Waals heterostructures", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnetic multilayer devices that exploit magnetoresistance are the backbone of magnetic sensing and data storage technologies. Here, we report multiple-spin-filter magnetic tunnel junctions (sf-MTJs) based on van der Waals (vdW) heterostructures in which atomically thin chromium triiodide (CrI3) acts as a spin-filter tunnel barrier sandwiched between graphene contacts. We demonstrate tunneling magnetoresistance that is drastically enhanced with increasing CrI3 layer thickness, reaching a record 19,000% for magnetic multilayer structures using four-layer sf-MTJs at low temperatures. Using magnetic circular dichroism measurements, we attribute these effects to the intrinsic layer-by-layer antiferromagnetic ordering of the atomically thin CrI3. Our work reveals the possibility to push magnetic information storage to the atomically thin limit and highlights CrI3 as a superlative magnetic tunnel barrier for vdW heterostructure spintronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 997, "Times Cited, All Databases": 1079, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2018, "Volume": 360, "Issue": 6394, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1214, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aar4851", "DOI Link": "http://dx.doi.org/10.1126/science.aar4851", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435360400049", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, F; Zhou, HQ; Huang, YF; Sun, JY; Qin, F; Bao, JM; Goddardiii, WA; Chen, S; Ren, ZF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Fang; Zhou, Haiqing; Huang, Yufeng; Sun, Jingying; Qin, Fan; Bao, Jiming; Goddardiii, William A.; Chen, Shuo; Ren, Zhifeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-performance bifunctional porous non-noble metal phosphide catalyst for overall water splitting", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Water electrolysis is an advanced energy conversion technology to produce hydrogen as a clean and sustainable chemical fuel, which potentially stores the abundant but intermittent renewable energy sources scalably. Since the overall water splitting is an uphill reaction in low efficiency, innovative breakthroughs are desirable to greatly improve the efficiency by rationally designing non-precious metal-based robust bifunctional catalysts for promoting both the cathodic hydrogen evolution and anodic oxygen evolution reactions. We report a hybrid catalyst constructed by iron and dinickel phosphides on nickel foams that drives both the hydrogen and oxygen evolution reactions well in base, and thus substantially expedites overall water splitting at 10 mA cm(-2) with 1.42 V, which outperforms the integrated iridium (IV) oxide and platinum couple (1.57 V), and are among the best activities currently. Especially, it delivers 500 mA cm(-2) at 1.72 V without decay even after the durability test for 40 h, providing great potential for large-scale applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1028, "Times Cited, All Databases": 1058, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 29", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2551, "DOI": "10.1038/s41467-018-04746-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04746-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000436791400012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, Y; Zhang, CL; Zhou, M; Fu, Q; Zhao, CX; Wu, MH; Lei, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Yang; Zhang, Chenglin; Zhou, Min; Fu, Qun; Zhao, Chengxi; Wu, Minghong; Lei, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly nitrogen doped carbon nullofibers with superior rate capability and cyclability for potassium ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Potassium-ion batteries are a promising alternative to lithium-ion batteries. However, it is challenging to achieve fast charging/discharging and long cycle life with the current electrode materials because of the sluggish potassiation kinetics. Here we report a soft carbon anode, namely highly nitrogen-doped carbon nullofibers, with superior rate capability and cyclability. The anode delivers reversible capacities of 248 mAh g(-1) at 25 mA g(-1) and 101 mAh g(-1) at 20 A g(-1), and retains 146 mAh g(-1) at 2 A g(-1) after 4000 cycles. Surface-dominated K-storage is verified by quantitative kinetics analysis and theoretical investigation. A full cell coupling the anode and Prussian blue cathode delivers a reversible capacity of 195 mAh g(-1) at 0.2 A g(-1). Considering the cost-effectiveness and material sustainability, our work may shed some light on searching for K-storage materials with high performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1010, "Times Cited, All Databases": 1045, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 30", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1720, "DOI": "10.1038/s41467-018-04190-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04190-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000431113000008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, XL; Zhang, XW; Deng, JX; Chu, ZM; Jiang, Q; Meng, JH; Wang, PY; Zhang, LQ; Yin, ZG; You, JB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Xiaolei; Zhang, Xingwang; Deng, Jinxiang; Chu, Zema; Jiang, Qi; Meng, Junhua; Wang, Pengyang; Zhang, Liuqi; Yin, Zhigang; You, Jingbi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient green light-emitting diodes based on quasi-two-dimensional composition and phase engineered perovskite with surface passivation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite light-emitting diodes (LEDs) are attracting great attention due to their efficient and narrow emission. Quasi-two-dimensional perovskites with Ruddlesden-Popper-type layered structures can enlarge exciton binding energy and confine charge carriers and are considered good candidate materials for efficient LEDs. However, these materials usually contain a mixture of phases and the phase impurity could cause low emission efficiency. In addition, converting three-dimensional into quasi-two-dimensional perovskite introduces more defects on the surface or at the grain boundaries due to the reduction of crystal sizes. Both factors limit the emission efficiency of LEDs. Here, firstly, through composition and phase engineering, optimal quasi-two-dimensional perovskites are selected. Secondly, surface passivation is carried out by coating organic small molecule trioctylphosphine oxide on the perovskite thin film surface. Accordingly, green LEDs based on quasi-two-dimensional perovskite reach a current efficiency of 62.4 cd A(-1) and external quantum efficiency of 14.36%.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 908, "Times Cited, All Databases": 983, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 8", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 570, "DOI": "10.1038/s41467-018-02978-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-02978-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000424451300015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, X; Guo, BL; Wu, H; Liang, YP; Ma, PX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Xin; Guo, Baolin; Wu, Hao; Liang, Yongping; Ma, Peter X.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Injectable antibacterial conductive nullocomposite cryogels with rapid shape recovery for noncompressible hemorrhage and wound healing", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing injectable antibacterial and conductive shape memory hemostatic with high blood absorption and fast recovery for irregularly shaped and noncompressible hemorrhage remains a challenge. Here we report injectable antibacterial conductive cryogels based on carbon nullotube (CNT) and glycidyl methacrylate functionalized quaternized chitosan for lethal noncompressible hemorrhage hemostasis and wound healing. These cryogels present robust mechanical strength, rapid blood-triggered shape recovery and absorption speed, and high blood uptake capacity. Moreover, cryogels show better blood-clotting ability, higher blood cell and platelet adhesion and activation than gelatin sponge and gauze. Cryogel with 4mg/mL CNT (QCSG/CNT4) shows better hemostatic capability than gauze and gelatin hemostatic sponge in mouse-liver injury model and mouse-tail amputation model, and better wound healing performance than Tegaderm (TM) film. Importantly, QCSG/CNT4 presents excellent hemostatic performance in rabbit liver defect lethal noncompressible hemorrhage model and even better hemostatic ability than Combat Gauze in standardized circular liver bleeding model.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 980, "Times Cited, All Databases": 1015, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 17", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2784, "DOI": "10.1038/s41467-018-04998-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04998-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000438857400006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, XX; Cullen, DA; Pan, YT; Hwang, S; Wang, MY; Feng, ZX; Wang, JY; Engelhard, MH; Zhang, HG; He, YH; Shao, YY; Su, D; More, KL; Spendelow, JS; Wu, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xiao Xia; Cullen, David A.; Pan, Yung-Tin; Hwang, Sooyeon; Wang, Maoyu; Feng, Zhenxing; Wang, Jingyun; Engelhard, Mark H.; Zhang, Hanguang; He, Yanghua; Shao, Yuyan; Su, Dong; More, Karren L.; Spendelow, Jacob S.; Wu, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nitrogen-Coordinated Single Cobalt Atom Catalysts for Oxygen Reduction in Proton Exchange Membrane Fuel Cells", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Due to the Fenton reaction, the presence of Fe and peroxide in electrodes generates free radicals causing serious degradation of the organic ionomer and the membrane. Pt-free and Fe-free cathode catalysts therefore are urgently needed for durable and inexpensive proton exchange membrane fuel cells (PEMFCs). Herein, a high-performance nitrogen-coordinated single Co atom catalyst is derived from Co-doped metal-organic frameworks (MOFs) through a one-step thermal activation. Aberration-corrected electron microscopy combined with X-ray absorption spectroscopy virtually verifies the CoN4 coordination at an atomic level in the catalysts. Through investigating effects of Co doping contents and thermal activation temperature, an atomically Co site dispersed catalyst with optimal chemical and structural properties has achieved respectable activity and stability for the oxygen reduction reaction (ORR) in challenging acidic media (e.g., half-wave potential of 0.80 V vs reversible hydrogen electrode (RHE). The performance is comparable to Fe-based catalysts and 60 mV lower than Pt/C -60 mu g Pt cm(-2)). Fuel cell tests confirm that catalyst activity and stability can translate to high-performance cathodes in PEMFCs. The remarkably enhanced ORR performance is attributed to the presence of well-dispersed CoN4 active sites embedded in 3D porous MOF-derived carbon particles, omitting any inactive Co aggregates.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 975, "Times Cited, All Databases": 1026, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 15", "Publication Year": 2018, "Volume": 30, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1706758, "DOI": "10.1002/adma.201706758", "DOI Link": "http://dx.doi.org/10.1002/adma.201706758", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427111300028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chang, C; Wu, MH; He, DS; Pei, YL; Wu, CF; Wu, XF; Yu, HL; Zhu, FY; Wang, KD; Chen, Y; Huang, L; Li, JF; He, JQ; Zhao, LD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chang, Cheng; Wu, Minghui; He, Dongsheng; Pei, Yanling; Wu, Chao-Feng; Wu, Xuefeng; Yu, Hulei; Zhu, Fangyuan; Wang, Kedong; Chen, Yue; Huang, Li; Li, Jing-Feng; He, Jiaqing; Zhao, Li-Dong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D charge and 2D phonon transports leading to high out-of-plane ZT in n-type SnSe crystals", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermoelectric technology enables the harvest of waste heat and its direct conversion into electricity. The conversion efficiency is determined by the materials figure of merit ZT. Here we show a maximum ZT of similar to 2.8 +/- 0.5 at 773 kelvin in n-type tin selenide (SnSe) crystals out of plane. The thermal conductivity in layered SnSe crystals is the lowest in the out-of-plane direction [two-dimensional (2D) phonon transport]. We doped SnSe with bromine to make n-type SnSe crystals with the overlapping interlayer charge density (3D charge transport). A continuous phase transition increases the symmetry and diverges two converged conduction bands. These two factors improve carrier mobility, while preserving a large Seebeck coefficient. Our findings can be applied in 2D layered materials and provide a new strategy to enhance out-of-plane electrical transport properties without degrading thermal properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 960, "Times Cited, All Databases": 1009, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 18", "Publication Year": 2018, "Volume": 360, "Issue": 6390, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 778, "End Page": 782, "Article Number": null, "DOI": "10.1126/science.aaq1479", "DOI Link": "http://dx.doi.org/10.1126/science.aaq1479", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000432473500046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Madsen, GKH; Carrete, J; Verstraete, MJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Madsen, Georg K. H.; Carrete, Jesus; Verstraete, Matthieu J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "BoltzTraP2, a program for interpolating band structures and calculating semi-classical transport coefficients", "Source Title": "COMPUTER PHYSICS COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "BoltzTraP2 is a software package for calculating a smoothed Fourier expression of periodic functions and the Onsager transport coefficients for extended systems using the linearized Boltzmann transport equation. It uses only the band and k-dependent quasi-particle energies, as well as the intra-band optical matrix elements and scattering rates, as input. The code can be used via a command-line interface and/or as a Python module. It is tested and illustrated on a simple parabolic band example as well as silicon. The positive Seebeck coefficient of lithium is reproduced in an example of going beyond the constant relaxation time approximation. Program summary Program Title: Bolt zTraP2 Program Files doi: http://dx.doLorg/10.17632/bzb9byx8g8.1 Licensing provisions: GPLv3 Programming language: Python and C++ External routines/libraries: NumPy, SciPy, Matplotlib, spglib, ase, fftw, VTK, netCDF4, Eigen Nature of problem: Calculating the transport coefficients using the linearized Boltzmann transport equation within the relaxation time approximation. Solution method: Smoothed Fourier interpolation (C) 2018 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 960, "Times Cited, All Databases": 1006, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2018, "Volume": 231, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 140, "End Page": 145, "Article Number": null, "DOI": "10.1016/j.cpc.2018.05.010", "DOI Link": "http://dx.doi.org/10.1016/j.cpc.2018.05.010", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000437964200011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jung, MR; Horgen, FD; Orski, SV; Rodriguez, CV; Beers, KL; Balazs, GH; Jones, TT; Work, TM; Brignac, KC; Royer, SJ; Hyrenbach, KD; Jensen, BA; Lynch, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jung, Melissa R.; Horgen, F. David; Orski, Sara V.; Rodriguez, Viviana C.; Beers, Kathryn L.; Balazs, George H.; Jones, T. Todd; Work, Thierry M.; Brignac, Kayla C.; Royer, Sarah-Jeanne; Hyrenbach, K. David; Jensen, Brenda A.; Lynch, Jennifer M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Validation of ATR FT-IR to identify polymers of plastic marine debris, including those ingested by marine organisms", "Source Title": "MARINE POLLUTION BULLETIN", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Polymer identification of plastic marine debris can help identify its sources, degradation, and fate. We optimized and validated a fast, simple, and accessible technique, attenuated total reflectance Fourier transform infrared spectroscopy (ATR FT-IR), to identify polymers contained in plastic ingested by sea turtles. Spectra of consumer good items with known resin identification codes #1-6 and several #7 plastics were compared to standard and raw manufactured polymers. High temperature size exclusion chromatography measurements confirmed ATR Fr-IR could differentiate these polymers. High-density (HDPE) and low-density polyethylene (LDPE) discrimination is challenging but a clear step-by-step guide is provided that identified 78% of ingested PE samples. The optimal cleaning methods consisted of wiping ingested pieces with water or cutting. Of 828 ingested plastics pieces from 50 Pacific sea turtles, 96% were identified by ATR FT-IR as HDPE, LDPE, unknown PE, polypropylene (PP), PE and PP mixtures, polystyrene, polyvinyl chloride, and nylon.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 937, "Times Cited, All Databases": 996, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2018, "Volume": 127, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 704, "End Page": 716, "Article Number": null, "DOI": "10.1016/j.marpolbul.2017.12.061", "DOI Link": "http://dx.doi.org/10.1016/j.marpolbul.2017.12.061", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Environmental Sciences & Ecology; Marine & Freshwater Biology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427332900078", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, XY; Chen, LJ; Chong, SY; Little, MA; Wu, YZ; Zhu, WH; Clowes, R; Yan, Y; Zwijnenburg, MA; Sprick, RS; Cooper, AI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xiaoyan; Chen, Linjiang; Chong, Samantha Y.; Little, Marc A.; Wu, Yongzhen; Zhu, Wei-Hong; Clowes, Rob; Yan, Yong; Zwijnenburg, Martijn A.; Sprick, Reiner Sebastian; Cooper, Andrew I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sulfone-containing covalent organic frameworks for photocatalytic hydrogen evolution from water", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nature uses organic molecules for light harvesting and photosynthesis, but most man-made water splitting catalysts are inorganic semiconductors. Organic photocatalysts, while attractive because of their synthetic tunability, tend to have low quantum efficiencies for water splitting. Here we present a crystalline covalent organic framework (COF) based on a benzobis(benzothiophene sulfone) moiety that shows a much higher activity for photochemical hydrogen evolution than its amorphous or semicrystalline counterparts. The COF is stable under long-term visible irradiation and shows steady photochemical hydrogen evolution with a sacrificial electron donor for at least 50 hours. We attribute the high quantum efficiency of fusedsulfone-COF to its crystallinity, its strong visible light absorption, and its wettable, hydrophilic 3.2 nm mesopores. These pores allow the framework to be dye-sensitized, leading to a further 61% enhancement in the hydrogen evolution rate up to 16.3 mmol g(-1) h(-1). The COF also retained its photocatalytic activity when cast as a thin film onto a support.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 985, "Times Cited, All Databases": 1022, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2018, "Volume": 10, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1180, "End Page": 1189, "Article Number": null, "DOI": "10.1038/s41557-018-0141-5", "DOI Link": "http://dx.doi.org/10.1038/s41557-018-0141-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000450790300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liaskos, C; Nie, S; Tsioliaridou, A; Pitsillides, A; Ioannidis, S; Akyildiz, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liaskos, Christos; Nie, Shuai; Tsioliaridou, Ageliki; Pitsillides, Andreas; Ioannidis, Sotiris; Akyildiz, Ian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A New Wireless Communication Paradigm through Software-Controlled Metasurfaces", "Source Title": "IEEE COMMUNICATIONS MAGAZINE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electromagnetic waves undergo multiple uncontrollable alterations as they propagate within a wireless environment. Free space path loss, signal absorption, as well as reflections, refractions, and diffractions caused by physical objects within the environment highly affect the performance of wireless communications. Currently, such effects are intractable to account for and are treated as probabilistic factors. This article proposes a radically different approach, enabling deterministic, programmable control over the behavior of wireless environments. The key enabler is the so-called HyperSurface tile, a novel class of planar meta-materials that can interact with impinging electromagnetic waves in a controlled manner. The HyperSurface tiles can effectively re-engineer electromagnetic waves, including steering toward any desired direction, full absorption, polarization manipulation, and more. Multiple tiles are employed to coat objects such as walls, furniture, and overall, any objects in indoor and outdoor environments. An external software service calculates and deploys the optimal interaction types per tile to best fit the needs of communicating devices. Evaluation via simulations highlights the potential of the new concept.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 840, "Times Cited, All Databases": 878, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2018, "Volume": 56, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 162, "End Page": 169, "Article Number": null, "DOI": "10.1109/MCOM.2018.1700659", "DOI Link": "http://dx.doi.org/10.1109/MCOM.2018.1700659", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Telecommunications", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444843900029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ding, L; Wei, YY; Li, LB; Zhang, T; Wang, HH; Xue, J; Ding, LX; Wang, SQ; Caro, J; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ding, Li; Wei, Yanying; Li, Libo; Zhang, Tao; Wang, Haihui; Xue, Jian; Ding, Liang-Xin; Wang, Suqing; Caro, Juergen; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MXene molecular sieving membranes for highly efficient gas separation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Molecular sieving membranes with sufficient and uniform nullochannels that break the permeability-selectivity trade-off are desirable for energy-efficient gas separation, and the arising two-dimensional (2D) materials provide new routes for membrane development. However, for 2D lamellar membranes, disordered interlayer nullochannels for mass transport are usually formed between randomly stacked neighboring nullosheets, which is obstructive for highly efficient separation. Therefore, manufacturing lamellar membranes with highly ordered nullochannel structures for fast and precise molecular sieving is still challenging. Here, we report on lamellar stacked MXene membranes with aligned and regular subnullometer channels, taking advantage of the abundant surface-terminating groups on the MXene nullosheets, which exhibit excellent gas separation performance with H-2 permeability > 2200 Barrer and H-2/CO2 selectivity > 160, superior to the state-of-the-art membranes. The results of molecular dynamics simulations quantitatively support the experiments, confirming the subnullometer interlayer spacing between the neighboring MXene nullosheets as molecular sieving channels for gas separation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 895, "Times Cited, All Databases": 938, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 11", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 155, "DOI": "10.1038/s41467-017-02529-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-017-02529-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000419947200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, XM; Han, P; Wei, ZX; Huang, LS; Gu, ZX; Peng, SJ; Ma, JM; Zheng, GF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Xiaomin; Han, Peng; Wei, Zengxi; Huang, Linsong; Gu, Zhengxiang; Peng, Sijia; Ma, Jianmin; Zheng, Gengfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boron-Doped Graphene for Electrocatalytic N2 Reduction", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical N-2 reduction in aqueous solutions at ambient conditions is extremely challenging and requires rational design of electrocatalytic centers. We demonstrate a boron-doped graphene as an efficient metal-free N-2 reduction electrocatalyst. Boron doping in the graphene framework leads to redistribution of electron density, where the electron-deficient boron sites provide enhanced binding capability to N-2 molecules. Density functional theory calculations reveal the catalytic activities of different boron-doped carbon structures, in which the BC3 structure enables the lowest energy barrier for N-2 electroreduction to NH3. At a doping level of 6.2%, the boron-doped graphene achieves a NH3 production rate of 9.8 mu g.hr(-1).cm(-2) and one of the highest reported faradic efficiencies of 10.8% at -0.5 V versus reversible hydrogen electrode in aqueous solutions at ambient conditions. This work suggests the strong potential of atomic-scale design for efficient electrocatalysts for N-2 reduction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 830, "Times Cited, All Databases": 866, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 15", "Publication Year": 2018, "Volume": 2, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1610, "End Page": 1622, "Article Number": null, "DOI": "10.1016/j.joule.2018.06.007", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.06.007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000441627400023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, YS; Che, FL; Liu, M; Zou, CQ; Liang, ZQ; De Luna, P; Yuan, HF; Li, J; Wang, ZQ; Xie, HP; Li, HM; Chen, PN; Bladt, E; Quintero-Bermudez, R; Sham, TK; Bals, S; Hofkens, J; Sinton, D; Chen, G; Sargent, EH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Yansong; Che, Fanglin; Liu, Min; Zou, Chengqin; Liang, Zhiqin; De Luna, Phil; Yuan, Haifeng; Li, Jun; Wang, Zhiqiang; Xie, Haipeng; Li, Hongmei; Chen, Peining; Bladt, Eva; Quintero-Bermudez, Rafael; Sham, Tsun-Kong; Bals, Sara; Hofkens, Johan; Sinton, David; Chen, Gang; Sargent, Edward H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dopant-induced electron localization drives CO2 reduction to C2 hydrocarbons", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electrochemical reduction of CO2 to multi-carbon products has attracted much attention because it provides an avenue to the synthesis of value-added carbon-based fuels and feedstocks using renewable electricity. Unfortunately, the efficiency of CO2 conversion to C-2 products remains below that necessary for its implementation at scale. Modifying the local electronic structure of copper with positive valence sites has been predicted to boost conversion to C-2 products. Here, we use boron to tune the ratio of Cu delta+ to Cu-0 active sites and improve both stability and C-2-product generation. Simulations show that the ability to tune the average oxidation state of copper enables control over CO adsorption and dimerization, and makes it possible to implement a preference for the electrosynthesis of C-2 products. We report experimentally a C-2 Faradaic efficiency of 79 +/- 2% on boron-doped copper catalysts and further show that boron doping leads to catalysts that are stable for in excess of similar to 40 hours while electrochemically reducing CO2 to multi-carbon hydrocarbons.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 886, "Times Cited, All Databases": 924, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2018, "Volume": 10, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 974, "End Page": 980, "Article Number": null, "DOI": "10.1038/s41557-018-0092-x", "DOI Link": "http://dx.doi.org/10.1038/s41557-018-0092-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000442395200013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Stolterfoht, M; Wolff, CM; Márquez, JA; Zhang, SS; Hages, CJ; Rothhardt, D; Albrecht, S; Burn, PL; Meredith, P; Unold, T; Neher, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Stolterfoht, Martin; Wolff, Christian M.; Marquez, Jose A.; Zhang, Shanshan; Hages, Charles J.; Rothhardt, Daniel; Albrecht, Steve; Burn, Paul L.; Meredith, Paul; Unold, Thomas; Neher, Dieter", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Visualization and suppression of interfacial recombination for high-efficiency large-area pin perovskite solar cells", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The performance of perovskite solar cells is predominulltly limited by non-radiative recombination, either through trap-assisted recombination in the absorber layer or via minority carrier recombination at the perovskite/transport layer interfaces. Here, we use transient and absolute photoluminescence imaging to visualize all non-radiative recombination pathways in planar pintype perovskite solar cells with undoped organic charge transport layers. We find significant quasi-Fermi-level splitting losses (135 meV) in the perovskite bulk, whereas interfacial recombination results in an additional free energy loss of 80 meV at each individual interface, which limits the open-circuit voltage (V-oc) of the complete cell to similar to 1.12 V. Inserting ultrathin interlayers between the perovskite and transport layers leads to a substantial reduction of these interfacial losses at both the p and n contacts. Using this knowledge and approach, we demonstrate reproducible dopant-free 1 cm(2) perovskite solar cells surpassing 20% efficiency (19.83% certified) with stabilized power output, a high V-oc (1.17 V) and record fill factor (>81%).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 814, "Times Cited, All Databases": 846, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2018, "Volume": 3, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 847, "End Page": 854, "Article Number": null, "DOI": "10.1038/s41560-018-0219-8", "DOI Link": "http://dx.doi.org/10.1038/s41560-018-0219-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000446724600014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, DF; Kong, LY; Fan, P; Chen, H; Zhu, SY; Liu, WY; Cao, L; Sun, YJ; Du, SX; Schneeloch, J; Zhong, RD; Gu, GD; Fu, L; Ding, H; Gao, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Dongfei; Kong, Lingyuan; Fan, Peng; Chen, Hui; Zhu, Shiyu; Liu, Wenyao; Cao, Lu; Sun, Yujie; Du, Shixuan; Schneeloch, John; Zhong, Ruidan; Gu, Genda; Fu, Liang; Ding, Hong; Gao, Hong-Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Evidence for Majorana bound states in an iron-based superconductor", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The search for Majorana bound states (MBSs) has been fueled by the prospect of using their non-Abelian statistics for robust quantum computation. Two-dimensional superconducting topological materials have been predicted to host MBSs as zero-energy modes in vortex cores. By using scanning tunneling spectroscopy on the superconducting Dirac surface state of the iron-based superconductor FeTe0.55Se0.45, we observed a sharp zero-bias peak inside a vortex core that does not split when moving away from the vortex center. The evolution of the peak under varying magnetic field, temperature, and tunneling barrier is consistent with the tunneling to a nearly pure MBS, separated from nontopological bound states. This observation offers a potential platform for realizing and manipulating MBSs at a relatively high temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 821, "Times Cited, All Databases": 886, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 19", "Publication Year": 2018, "Volume": 362, "Issue": 6412, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 333, "End Page": 335, "Article Number": null, "DOI": "10.1126/science.aao1797", "DOI Link": "http://dx.doi.org/10.1126/science.aao1797", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000447680100046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, HW; Ross, MB; Kornienko, N; Zhang, L; Guo, JH; Yang, PD; McCloskey, BD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Hyo Won; Ross, Michael B.; Kornienko, Nikolay; Zhang, Liang; Guo, Jinghua; Yang, Peidong; McCloskey, Bryan D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient hydrogen peroxide generation using reduced graphene oxide-based oxygen reduction electrocatalysts", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical oxygen reduction has garnered attention as an emerging alternative to the traditional anthraquinone oxidation process to enable the distributed production of hydrogen peroxide. Here, we demonstrate a selective and efficient non-precious electrocatalyst, prepared through an easily scalable mild thermal reduction of graphene oxide, to form hydrogen peroxide from oxygen. During oxygen reduction, certain variants of the mildly reduced graphene oxide electrocatalyst exhibit highly selective and stable peroxide formation activity at low overpotentials (<10 mV) under basic conditions, exceeding the performance of current state-of-the-art alkaline catalysts. Spectroscopic structural characterization and in situ Raman spectroelectrochemistry provide strong evidence that sp(2)-hybridized carbon near-ring ether defects along sheet edges are the most active sites for peroxide production, providing new insight into the electrocatalytic design of carbon-based materials for effective peroxide production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 816, "Times Cited, All Databases": 870, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2018, "Volume": 1, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 282, "End Page": 290, "Article Number": null, "DOI": "10.1038/s41929-018-0044-2", "DOI Link": "http://dx.doi.org/10.1038/s41929-018-0044-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430451900015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sarkar, A; Velasco, L; Wang, D; Wang, QS; Talasila, G; de Biasi, L; Kübel, C; Brezesinski, T; Bhattacharya, SS; Hahn, H; Breitung, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sarkar, Abhishek; Velasco, Leonardo; Wang, Di; Wang, Qingsong; Talasila, Gopichand; de Biasi, Lea; Kuebel, Christian; Brezesinski, Torsten; Bhattacharya, Subramshu S.; Hahn, Horst; Breitung, Ben", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High entropy oxides for reversible energy storage", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In recent years, the concept of entropy stabilization of crystal structures in oxide systems has led to an increased research activity in the field of high entropy oxides. These compounds comprise the incorporation of multiple metal cations into single-phase crystal structures and interactions among the various metal cations leading to interesting novel and unexpected properties. Here, we report on the reversible lithium storage properties of the high entropy oxides, the underlying mechanisms governing these properties, and the influence of entropy stabilization on the electrochemical behavior. It is found that the stabilization effect of entropy brings significant benefits for the storage capacity retention of high entropy oxides and greatly improves the cycling stability. Additionally, it is observed that the electrochemical behavior of the high entropy oxides depends on each of the metal cations present, thus providing the opportunity to tailor the electrochemical properties by simply changing the elemental composition.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 924, "Times Cited, All Databases": 980, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 24", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3400, "DOI": "10.1038/s41467-018-05774-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-05774-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000442594800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuan, FL; Yuan, T; Sui, LZ; Wang, ZB; Xi, ZF; Li, YC; Li, XH; Fan, LZ; Tan, ZA; Chen, AM; Jin, MX; Yang, SH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuan, Fanglong; Yuan, Ting; Sui, Laizhi; Wang, Zhibin; Xi, Zifan; Li, Yunchao; Li, Xiaohong; Fan, Louzhen; Tan, Zhan'ao; Chen, Anmin; Jin, Mingxing; Yang, Shihe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering triangular carbon quantum dots with unprecedented narrow bandwidth emission for multicolored LEDs", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon quantum dots (CQDs) have emerged as promising materials for optoelectronic applications on account of carbon's intrinsic merits of high stability, low cost, and environment-friendliness. However, the CQDs usually give broad emission with full width at half maximum exceeding 80 nm, which fundamentally limit their display applications. Here we demonstrate multicolored narrow bandwidth emission (full width at half maximum of 30 nm) from triangular CQDs with a quantum yield up to 54-72%. Detailed structural and optical characterizations together with theoretical calculations reveal that the molecular purity and crystalline perfection of the triangular CQDs are key to the high color-purity. Moreover, multicolored light-emitting diodes based on these CQDs display good stability, high color-purity, and high-performance with maximum luminullce of 1882-4762 cd m(-2) and current efficiency of 1.22-5.11 cd A(-1). This work will set the stage for developing nextgeneration high-performance CQDs-based light-emitting diodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 825, "Times Cited, All Databases": 862, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 8", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2249, "DOI": "10.1038/s41467-018-04635-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04635-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000434648400005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "De Luna, P; Quintero-Bermudez, R; Dinh, CT; Ross, MB; Bushuyev, OS; Todorovic, P; Regier, T; Kelley, SO; Yang, PD; Sargent, EH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "De Luna, Phil; Quintero-Bermudez, Rafael; Cao-Thang Dinh; Ross, Michael B.; Bushuyev, Oleksandr S.; Todorovic, Petar; Regier, Tom; Kelley, Shana O.; Yang, Peidong; Sargent, Edward H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Catalyst electro-redeposition controls morphology and oxidation state for selective carbon dioxide reduction", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The reduction of carbon dioxide to renewable fuels and feedstocks offers opportunities for large-scale, long-term energy storage. The synthesis of efficient CO2 reduction electrocatalysts with high C2:C1 selectivity remains a field of intense interest. Here we present electro-redeposition, the dissolution and redeposition of copper from a sol-gel, to enhance copper catalysts in terms of their morphology, oxidation state and consequent performance. We utilized in situ soft X-ray absorption spectroscopy to track the oxidation state of copper under CO2 reduction conditions with time resolution. The sol-gel material slows the electrochemical reduction of copper, enabling control over nulloscale morphology and the stabilization of Cu+ at negative potentials. CO2 reduction experiments, in situ X-ray spectroscopy and density functional theory simulations revealed the beneficial interplay between sharp morphologies and Cu+ oxidation state. The catalyst exhibits a partial ethylene current density of 160 mA cm(-2) (-1.0 V versus reversible hydrogen electrode) and an ethylene/methane ratio of 200.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 799, "Times Cited, All Databases": 839, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2018, "Volume": 1, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 103, "End Page": 110, "Article Number": null, "DOI": "10.1038/s41929-017-0018-9", "DOI Link": "http://dx.doi.org/10.1038/s41929-017-0018-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000428621500008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ZY; Wang, ZX; Lin, SH; Jin, HL; Gao, SJ; Zhu, YZ; Jin, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zhenyi; Wang, Zhangxin; Lin, Shihong; Jin, Huile; Gao, Shoujian; Zhu, Yuzhang; Jin, Jian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nulloparticle-templated nullofiltration membranes for ultrahigh performance desalination", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullofiltration (NF) membranes with ultrahigh permeance and high rejection are highly beneficial for efficient desalination and wastewater treatment. Improving water permeance while maintaining the high rejection of state-of-the-art thin film composite (TFC) NF membranes remains a great challenge. Herein, we report the fabrication of a TFC NF membrane with a crumpled polyamide (PA) layer via interfacial polymerization on a single-walled carbon nullotubes/polyether sulfone composite support loaded with nulloparticles as a sacrificial templating material, using metal-organic framework nulloparticles (ZIF-8) as an example. The nulloparticles, which can be removed by water dissolution after interfacial polymerization, facilitate the formation of a rough PA active layer with crumpled nullostructure. The NF membrane obtained thereby exhibits high permeance up to 53.5 l m(-2)h(-1) bar(-1) with a rejection above 95% for Na2SO4, yielding an overall desalination performance superior to state-of-the-art NF membranes reported so far. Our work provides a simple avenue to fabricate advanced PA NF membranes with outstanding performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 797, "Times Cited, All Databases": 840, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 21", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2004, "DOI": "10.1038/s41467-018-04467-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04467-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000432535300008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pan, J; Shang, YQ; Yin, J; De Bastiani, M; Peng, W; Dursun, I; Sinatra, L; El-Zohry, AM; Hedhili, MN; Emwas, AH; Mohammed, OF; Ning, ZJ; Bakr, OM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pan, Jun; Shang, Yuequn; Yin, Jun; De Bastiani, Michele; Peng, Wei; Dursun, Ibrahim; Sinatra, Lutfan; El-Zohry, Ahmed M.; Hedhili, Mohamed N.; Emwas, Abdul-Hamid; Mohammed, Omar F.; Ning, Zhijun; Bakr, Osman M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bidentate Ligand-Passivated CsPbI3 Perovskite nullocrystals for Stable Near-Unity Photoluminescence Quantum Yield and Efficient Red Light-Emitting Diodes", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although halide perovskite :nullocrystals (NCs) are promising materials for optoelectronic devices, they suffer severely from chemical and phase instabilities. Moreover, the common capping'.ligands like oleic acid and oleylamine that encapsulate the NCs will form an insulating layer, precluding their futility in optoelectronic devices. To overcome these limitations, we develop a postsynthesis passivation process for CsPbI3 NCs by using a bidentate ligand, namely 2,2'-iminodibenzoic acid. Our passivated NCs exhibit narrow red photoluminescence with exceptional quantum yield (close to unity) and substantially improved stability. The passivated NCs enabled us to realize red light-emitting diodes (LEDs) with 5.02% external quantum efficiency and 748 cd/m(2) luminullce, surpassing by far LEDs made from the nonpassivated NCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 790, "Times Cited, All Databases": 826, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 17", "Publication Year": 2018, "Volume": 140, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 562, "End Page": 565, "Article Number": null, "DOI": "10.1021/jacs.7b10647", "DOI Link": "http://dx.doi.org/10.1021/jacs.7b10647", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000423012600009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lipatov, A; Lu, HD; Alhabeb, M; Anasori, B; Gruverman, A; Gogotsi, Y; Sinitskii, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lipatov, Alexey; Lu, Haidong; Alhabeb, Mohamed; Anasori, Babak; Gruverman, Alexei; Gogotsi, Yury; Sinitskii, Alexander", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Elastic properties of 2D Ti3C2Tx MXene monolayers and bilayers", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) transition metal carbides and nitrides, known as MXenes, are a large class of materials that are finding numerous applications ranging from energy storage and electromagnetic interference shielding to water purification and antibacterial coatings. Yet, despite the fact that more than 20 different MXenes have been synthesized, the mechanical properties of a MXene monolayer have not been experimentally studied. We measured the elastic properties of monolayers and bilayers of the most important MXene material to date, Ti3C2Tx (T-x stands for surface termination). We developed a method for preparing well-strained membranes of Ti3C2Tx monolayers and bilayers, and performed their nulloindentation with the tip of an atomic force microscope to record the force-displacement curves. The effective Young's modulus of a single layer of Ti3C2Tx was found to be 0.33 +/- 0.03 TPa, which is the highest among the mean values reported in nulloindentation experiments for other solution-processed 2D materials, including graphene oxide. This work opens a pathway for investigating the mechanical properties of monolayers and bilayers of other MXenes and extends the already broad range of MXenes' applications to structural composites, protective coatings, nulloresonators, and membranes that require materials with exceptional mechanical properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 800, "Times Cited, All Databases": 837, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2018, "Volume": 4, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaat0491", "DOI": "10.1126/sciadv.aat0491", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aat0491", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000443175500060", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, EY; Yu, XQ; Lin, RQ; Bi, XX; Lu, J; Bak, SM; Nam, KW; Xin, HLL; Jaye, C; Fischer, DA; Amine, K; Yang, XQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Enyuan; Yu, Xiqian; Lin, Ruoqian; Bi, Xuanxuan; Lu, Jun; Bak, Seongmin; Nam, Kyung-Wan; Xin, Huolin L.; Jaye, Cherno; Fischer, Daniel A.; Amine, Kahlil; Yang, Xiao-Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Evolution of redox couples in Li- and Mn-rich cathode materials and mitigation of voltage fade by reducing oxygen release", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Voltage fade is a major problem in battery applications for high-energy lithium- and manganese-rich (LMR) layered materials. As a result of the complexity of the LMR structure, the voltage fade mechanism is not well understood. Here we conduct both in situ and ex situ studies on a typical LMR material (Li1.2Ni0.15Co0.1Mn0.55O2) during charge-discharge cycling, using multi-lengthscale X-ray spectroscopic and three-dimensional electron microscopic imaging techniques. Through probing from the surface to the bulk, and from individual to whole ensembles of particles, we show that the average valence state of each type of transition metal cation is continuously reduced, which is attributed to oxygen release from the LMR material. Such reductions activate the lower-voltage Mn3+/Mn4+ and Co2+ /Co3+ redox couples in addition to the original redox couples including Ni2+/Ni3+, Ni3+/Ni4+ and O2-/O-, directly leading to the voltage fade. We also show that the oxygen release causes microstructural defects such as the formation of large pores within particles, which also contributes to the voltage fade. Surface coating and modification methods are suggested to be effective in suppressing the voltage fade through reducing the oxygen release.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 789, "Times Cited, All Databases": 836, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2018, "Volume": 3, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 690, "End Page": 698, "Article Number": null, "DOI": "10.1038/s41560-018-0207-z", "DOI Link": "http://dx.doi.org/10.1038/s41560-018-0207-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000441098100018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, Q; Huang, WW; Luo, ZQ; Liu, LJ; Lu, Y; Li, YX; Li, L; Hu, JY; Ma, H; Chen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Qing; Huang, Weiwei; Luo, Zhiqiang; Liu, Luojia; Lu, Yong; Li, Yixin; Li, Lin; Hu, Jinyan; Ma, Hua; Chen, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-capacity aqueous zinc batteries using sustainable quinone electrodes", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Quinones, which are ubiquitous in nature, can act as sustainable and green electrode materials but face dissolution in organic electrolytes, resulting in fast fading of capacity and short cycle life. We report that quinone electrodes, especially calix[4] quinone (C4Q) in rechargeable metal zinc batteries coupled with a cation-selective membrane using an aqueous electrolyte, exhibit a high capacity of 335mA h g(-1) with an energy efficiency of 93% at 20 mA g(-1) and a long life of 1000 cycles with a capacity retention of 87% at 500 mA g(-1). The pouch zinc batteries with a respective depth of discharge of 89% (C4Q) and 49% (zinc anode) can deliver an energy density of 220 Wh kg(-1) by mass of both a C4Q cathode and a theoretical Zn anode. We also develop an electrostatic potential computing method to demonstrate that carbonyl groups are active centers of electrochemistry. Moreover, the structural evolution and dissolution behavior of activematerials during discharge and charge processes are investigated by operando spectral techniques such as IR, Raman, and ultraviolet-visible spectroscopies. Our results show that batteries using quinone cathodes and metal anodes in aqueous electrolyte are reliable approaches for mass energy storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 797, "Times Cited, All Databases": 837, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2018, "Volume": 4, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaao1761", "DOI": "10.1126/sciadv.aao1761", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aao1761", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427892700012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mao, LL; Ke, WJ; Pedesseau, L; Wu, YL; Katan, C; Even, J; Wasielewski, MR; Stoumpos, CC; Kanatzidis, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mao, Lingling; Ke, Weijun; Pedesseau, Laurent; Wu, Yilei; Katan, Claudine; Even, Jacky; Wasielewski, Michael R.; Stoumpos, Constantinos C.; Kanatzidis, Mercouri G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hybrid Dion-Jacobson 2D Lead Iodide Perovskites", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The three-dimensional hybrid organic-inorganic perovskites have shown huge potential for use in solar cells and other optoelectronic devices. Although these materials are under intense investigation, derivative materials with lower dimensionality are emerging, offering higher tunability of physical properties and new capabilities. Here, we present two new series of hybrid two-dimensional (2D) perovskites that adopt the Dion-Jacobson (DJ) structure type, which are the first complete homologous series reported in halide perovskite chemistry. Lead iodide DJ perovskites adopt a general formula A'A(n-1),PbnI3n+1 (A' = 3-(aminomethyl)piperidinium (3AMP) or 4-(aminomethyl)piperidinium (4AMP), A = methylammonium (MA)). These materials have layered structures where the stacking of inorganic layers is unique as they lay exactly on top of another. With a slightly different position of the functional group in the templating cation 3AMP and 4AMP, the as-formed DJ perovskites show different optical properties, with the 3AMP series having smaller band gaps than the 4AMP series. Analysis on the crystal structures and density functional theory (DFT) calculations suggest that the origin of the systematic band gap shift is the strong but indirect influence of the organic cation on the inorganic framework. Fabrication of photovoltaic devices utilizing these materials as light absorbers reveals that (3AMP)(MA)(3)Pb4I13 has the best power conversion efficiency (PCE) of 7.32%, which is much higher than that of the corresponding (4AMP)(MA)(3)Pb4I13.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 764, "Times Cited, All Databases": 831, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 14", "Publication Year": 2018, "Volume": 140, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3775, "End Page": 3783, "Article Number": null, "DOI": "10.1021/jacs.8b00542", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b00542", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427910700042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sarker, P; Harrington, T; Toher, C; Oses, C; Samiee, M; Maria, JP; Brenner, DW; Vecchio, KS; Curtarolo, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sarker, Pranab; Harrington, Tyler; Toher, Cormac; Oses, Corey; Samiee, Mojtaba; Maria, Jon-Paul; Brenner, Donald W.; Vecchio, Kenneth S.; Curtarolo, Stefano", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-entropy high-hardness metal carbides discovered by entropy descriptors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy materials have attracted considerable interest due to the combination of useful properties and promising applications. Predicting their formation remains the major hindrance to the discovery of new systems. Here we propose a descriptor-entropy forming ability-for addressing synthesizability from first principles. The formalism, based on the energy distribution spectrum of randomized calculations, captures the accessibility of equally-sampled states near the ground state and quantifies configurational disorder capable of stabilizing high-entropy homogeneous phases. The methodology is applied to disordered refractory 5-metal carbides-promising candidates for high-hardness applications. The descriptor correctly predicts the ease with which compositions can be experimentally synthesized as rock-salt high-entropy homogeneous phases, validating the ansatz, and in some cases, going beyond intuition. Several of these materials exhibit hardness up to 50% higher than rule of mixtures estimations. The entropy descriptor method has the potential to accelerate the search for high-entropy systems by rationally combining first principles with experimental synthesis and characterization.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 765, "Times Cited, All Databases": 823, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 26", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4980, "DOI": "10.1038/s41467-018-07160-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-07160-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000451176100005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, J; Zhen, X; Wang, B; Gao, XM; Ren, ZC; Wang, JQ; Xie, YJ; Li, JR; Peng, Q; Pu, KY; Li, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Jie; Zhen, Xu; Wang, Bin; Gao, Xuming; Ren, Zichun; Wang, Jiaqiang; Xie, Yujun; Li, Jianrong; Peng, Qian; Pu, Kanyi; Li, Zhen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The influence of the molecular packing on the room temperature phosphorescence of purely organic luminogens", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic luminogens with persistent room temperature phosphorescence (RTP) have attracted great attention for their wide applications in optoelectronic devices and bioimaging. However, these materials are still very scarce, partially due to the unclear mechanism and lack of designing guidelines. Herein we develop seven 10-phenyl-10H-phenothiazine-5,5dioxide- based derivatives, reveal their different RTP properties and underlying mechanism, and exploit their potential imaging applications. Coupled with the preliminary theoretical calculations, it is found that strong pi-pi interactions in solid state can promote the persistent RTP. Particularly, CS-CF3 shows the unique photo-induced phosphorescence in response to the changes in molecular packing, further confirming the key influence of the molecular packing on the RTP property. Furthermore, CS-F with its long RTP lifetime could be utilized for real-time excitation-free phosphorescent imaging in living mice. Thus, our study paves the way for the development of persistent RTP materials, in both the practical applications and the inherent mechanism.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 810, "Times Cited, All Databases": 832, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 26", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 840, "DOI": "10.1038/s41467-018-03236-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03236-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000426049300007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, LF; Ding, QQ; Zhong, Y; Zou, J; Wu, J; Chiu, YL; Li, JX; Zhang, Z; Yu, Q; Shen, ZJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Leifeng; Ding, Qingqing; Zhong, Yuan; Zou, Ji; Wu, Jing; Chiu, Yu-Lung; Li, Jixue; Zhang, Ze; Yu, Qian; Shen, Zhijian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dislocation network in additive manufactured steel breaks strength-ductility trade-off", "Source Title": "MATERIALS TODAY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Most mechanisms used for strengthening crystalline materials, e.g. introducing crystalline interfaces, lead to the reduction of ductility. An additive manufacturing process - selective laser melting breaks this trade-off by introducing dislocation network, which produces a stainless steel with both significantly enhanced strength and ductility. Systematic electron microscopy characterization reveals that the pre-existing dislocation network, which maintains its configuration during the entire plastic deformation, is an ideal modulator that is able to slow down but not entirely block the dislocation motion. It also promotes the formation of a high density of nullo-twins during plastic deformation. This finding paves the way for developing high performance metals by tailoring the microstructure through additive manufacturing processes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 777, "Times Cited, All Databases": 822, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2018, "Volume": 21, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 354, "End Page": 361, "Article Number": null, "DOI": "10.1016/j.mattod.2017.11.004", "DOI Link": "http://dx.doi.org/10.1016/j.mattod.2017.11.004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000433264200014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, J; Sun, FF; Zhou, S; Hu, W; Zhang, H; Dong, JC; Jiang, Z; Zhao, JJ; Li, JF; Yan, WS; Wang, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Jian; Sun, Fanfei; Zhou, Si; Hu, Wei; Zhang, Hao; Dong, Jinchao; Jiang, Zheng; Zhao, Jijun; Li, Jianfeng; Yan, Wensheng; Wang, Mei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomic-level insight into super-efficient electrocatalytic oxygen evolution on iron and vanadium co-doped nickel (oxy)hydroxide", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It is of great importance to understand the origin of high oxygen-evolving activity of state-of the-art multimetal oxides/(oxy)hydroxides at atomic level. Herein we report an evident improvement of oxygen evolution reaction activity via incorporating iron and vanadium into nickel hydroxide lattices. X-ray photoelectron/absorption spectroscopies reveal the synergistic interaction between iron/vanadium dopants and nickel in the host matrix, which subtly modulates local coordination environments and electronic structures of the iron/vanadium/nickel cations. Further, in-situ X-ray absorption spectroscopic analyses manifest contraction of metal-oxygen bond lengths in the activated catalyst, with a short vanadium-oxygen bond distance. Density functional theory calculations indicate that the vanadium site of the iron/ vanadium co-doped nickel (oxy)hydroxide gives near-optimal binding energies of oxygen evolution reaction intermediates and has lower overpotential compared with nickel and iron sites. These findings suggest that the doped vanadium with distorted geometric and disturbed electronic structures makes crucial contribution to high activity of the trimetallic catalyst.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 798, "Times Cited, All Databases": 816, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 23", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2885, "DOI": "10.1038/s41467-018-05341-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-05341-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000439426100012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fumagalli, L; Esfandiar, A; Fabregas, R; Hu, S; Ares, P; Janardanull, A; Yang, Q; Radha, B; Taniguchi, T; Watanabe, K; Gomila, G; Novoselov, KS; Geim, AK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fumagalli, L.; Esfandiar, A.; Fabregas, R.; Hu, S.; Ares, P.; Janardanull, A.; Yang, Q.; Radha, B.; Taniguchi, T.; Watanabe, K.; Gomila, G.; Novoselov, K. S.; Geim, A. K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anomalously low dielectric constant of confined water", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The dielectric constant epsilon of interfacial water has been predicted to be smaller than that of bulk water (epsilon approximate to 80) because the rotational freedom of water dipoles is expected to decrease near surfaces, yet experimental evidence is lacking. We report local capacitance measurements for water confined between two atomically flat walls separated by various distances down to 1 nullometer. Our experiments reveal the presence of an interfacial layer with vanishingly small polarization such that its out-of-plane e is only similar to 2. The electrically dead layer is found to be two to three molecules thick. These results provide much-needed feedback for theories describing water-mediated surface interactions and the behavior of interfacial water, and show a way to investigate the dielectric properties of other fluids and solids under extreme confinement.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 758, "Times Cited, All Databases": 812, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 22", "Publication Year": 2018, "Volume": 360, "Issue": 6395, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1339, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aat4191", "DOI Link": "http://dx.doi.org/10.1126/science.aat4191", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000436040600041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fei, ZY; Zhao, WJ; Palomaki, TA; Sun, BS; Miller, MK; Zhao, ZY; Yan, JQ; Xu, XD; Cobden, DH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fei, Zaiyao; Zhao, Wenjin; Palomaki, Tauno A.; Sun, Bosong; Miller, Moira K.; Zhao, Zhiying; Yan, Jiaqiang; Xu, Xiaodong; Cobden, David H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ferroelectric switching of a two-dimensional metal", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A ferroelectric is a material with a polar structure whose polarity can be reversed (switched) by applying an electric field(1,2). In metals, itinerant electrons screen electrostatic forces between ions, which explains in part why polar metals are very rare(3-7). Screening also excludes external electric fields, apparently ruling out the possibility of ferroelectric switching. However, in principle, a thin enough polar metal could be sufficiently penetrated by an electric field to have its polarity switched. Here we show that the topological semimetal WTe2 provides an embodiment of this principle. Although monolayer WTe2 is centro-symmetric and thus non-polar, the stacked bulk structure is polar. We find that two-or three-layer WTe2 exhibits spontaneous out-of-plane electric polarization that can be switched using gate electrodes. We directly detect and quantify the polarization using graphene as an electric-field sensor(8). Moreover, the polarization states can be differentiated by conductivity and the carrier density can be varied to modify the properties. The temperature at which polarization vanishes is above 350 kelvin, and even when WTe2 is sandwiched between graphene layers it retains its switching capability at room temperature, demonstrating a robustness suitable for applications in combination with other two-dimensional materials(9-12).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 752, "Times Cited, All Databases": 814, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 16", "Publication Year": 2018, "Volume": 560, "Issue": 7718, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 336, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-018-0336-3", "DOI Link": "http://dx.doi.org/10.1038/s41586-018-0336-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000441673400033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, SW; Shan, J; Mak, KF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Shengwei; Shan, Jie; Mak, Kin Fai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electric-field switching of two-dimensional van der Waals magnets", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Controlling magnetism by purely electrical means is a key challenge to better information technology(1). A variety of material systems, including ferromagnetic (FM) metals(2-4), FM semiconductors(5), multiferroics(6-8) and magnetoelectric (ME) materials(9,10), have been explored for the electric-field control of magnetism. The recent discovery of two-dimensional (2D) van der Waals magnets(11,12) has opened a new door for the electrical control of magnetism at the nullometre scale through a van der Waals heterostructure device platform(13). Here we demonstrate the control of magnetism in bilayer CrI3, an antiferromagnetic (AFM) semiconductor in its ground state(12), by the application of small gate voltages in field-effect devices and the detection of magnetization using magnetic circular dichroism (MCD) microscopy. The applied electric field creates an interlayer potential difference, which results in a large linear ME effect, whose sign depends on the interlayer AFM order. We also achieve a complete and reversible electrical switching between the interlayer AFM and FM states in the vicinity of the interlayer spin-flip transition. The effect originates from the electric-field dependence of the interlayer exchange bias.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 742, "Times Cited, All Databases": 810, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2018, "Volume": 17, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 406, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41563-018-0040-6", "DOI Link": "http://dx.doi.org/10.1038/s41563-018-0040-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000430942800015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Han, N; Wang, Y; Yang, H; Deng, J; Wu, JH; Li, YF; Li, YG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Han, Na; Wang, Yu; Yang, Hui; Deng, Jun; Wu, Jinghua; Li, Yafei; Li, Yanguang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrathin bismuth nullosheets from in situ topotactic transformation for selective electrocatalytic CO2 reduction to formate", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrocatalytic carbon dioxide reduction to formate is desirable but challenging. Current attention is mostly focused on tin-based materials, which, unfortunately, often suffer from limited Faradaic efficiency. The potential of bismuth in carbon dioxide reduction has been suggested but remained understudied. Here, we report that ultrathin bismuth nullosheets are prepared from the in situ topotactic transformation of bismuth oxyiodide nullosheets. They process single crystallinity and enlarged surface areas. Such an advantageous nullostructure affords the material with excellent electrocatalytic performance for carbon dioxide reduction to formate. High selectivity (similar to 100%) and large current density are measured over a broad potential, as well as excellent durability for >10 h. Its selectivity for formate is also understood by density functional theory calculations. In addition, bismuth nullosheets were coupled with an iridium-based oxygen evolution electrocatalyst to achieve efficient full-cell electrolysis. When powered by two AA-size alkaline batteries, the full cell exhibits impressive Faradaic efficiency and electricity-to-formate conversion efficiency.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 750, "Times Cited, All Databases": 776, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 3", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1320, "DOI": "10.1038/s41467-018-03712-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03712-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000429004500013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, CK; Pan, F; Bin, HJ; Zhang, JQ; Xue, LW; Qiu, BB; Wei, ZX; Zhang, ZG; Li, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Chenkai; Pan, Fei; Bin, Haijun; Zhang, Jianqi; Xue, Lingwei; Qiu, Beibei; Wei, Zhixiang; Zhang, Zhi-Guo; Li, Yongfang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A low cost and high performance polymer donor material for polymer solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The application of polymer solar cells requires the realization of high efficiency, high stability, and low cost devices. Here we demonstrate a low-cost polymer donor poly[(thiophene)-alt(6,7-difluoro-2-(2-hexyldecyloxy)quinoxaline)] (PTQ10), which is synthesized with high overall yield of 87.4% via only two-step reactions from cheap raw materials. More importantly, an impressive efficiency of 12.70% is obtained for the devices with PTQ10 as donor, and the efficiency of the inverted structured PTQ10-based device also reaches 12.13% (certificated to be 12.0%). Furthermore, the as-cast devices also demonstrate a high efficiency of 10.41% and the devices exhibit insensitivity of active layer thickness from 100 nm to 300 nm, which is conductive to the large area fabrication of the devices. In considering the advantages of low cost and high efficiency with thickness insensitivity, we believe that PTQ10 will be a promising polymer donor for commercial application of polymer solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 734, "Times Cited, All Databases": 773, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 21", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 743, "DOI": "10.1038/s41467-018-03207-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-03207-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000425594200003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shao, SY; Liu, J; Portale, G; Fang, HH; Blake, GR; ten Brink, GH; Koster, LJA; Loi, MA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shao, Shuyan; Liu, Jian; Portale, Giuseppe; Fang, Hong-Hua; Blake, Graeme R.; ten Brink, Gert H.; Koster, L. Jan Anton; Loi, Maria Antonietta", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Reproducible Sn-Based Hybrid Perovskite Solar Cells with 9% Efficiency", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The low power conversion efficiency (PCE) of tin-based hybrid perovskite solar cells (HPSCs) is mainly attributed to the high background carrier density due to a high density of intrinsic defects such as Sn vacancies and oxidized species (Sn4+) that characterize Sn-based HPSCs. Herein, this study reports on the successful reduction of the background carrier density by more than one order of magnitude by depositing near-single-crystalline formamidinium tin iodide (FASnI(3)) films with the orthorhombic a-axis in the out-of-plane direction. Using these highly crystalline films, obtained by mixing a very small amount (0.08 m) of layered (2D) Sn perovskite with 0.92 m (3D) FASnI(3), for the first time a PCE as high as 9.0% in a planar p-i-n device structure is achieved. These devices display negligible hysteresis and light soaking, as they benefit from very low trap-assisted recombination, low shunt losses, and more efficient charge collection. This represents a 50% improvement in PCE compared to the best reference cell based on a pure FASnI(3) film using SnF2 as a reducing agent. Moreover, the 2D/3D-based HPSCs show considerable improved stability due to the enhanced robustness of the perovskite film compared to the reference cell.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 741, "Times Cited, All Databases": 769, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 5", "Publication Year": 2018, "Volume": 8, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1702019, "DOI": "10.1002/aenm.201702019", "DOI Link": "http://dx.doi.org/10.1002/aenm.201702019", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000424152200018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ni, G; Zandavi, SH; Javid, SM; Boriskina, SV; Cooper, TA; Chen, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ni, George; Zandavi, Seyed Hadi; Javid, Seyyed Morteza; Boriskina, Svetlana V.; Cooper, Thomas A.; Chen, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A salt-rejecting floating solar still for low-cost desalination", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although desalination technologies have been widely adopted as a means to produce freshwater, many of them require large installations and access to advanced infrastructure. Recently, floating structures for solar evaporation have been proposed, employing the concept of interfacial solar heat localization as a high-efficiency approach to desalination. However, the challenge remains to prevent salt accumulation while simultaneously maintaining heat localization. This paper presents an experimental demonstration of a salt-rejecting evaporation structure that can operate continuously under sunlight to generate clean vapor while floating in a saline body of water such as an ocean. The evaporation structure is coupled with a low-cost polymer film condensation cover to produce freshwater at a rate of 2.5 L m(-2) day(-1), enough to satisfy individual drinking needs. The entire system's material cost is $3 m(-2) - over an order of magnitude lower than conventional solar stills, does not require energy infrastructure, and can provide cheap drinking water to water-stressed and disaster-stricken communities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 743, "Times Cited, All Databases": 780, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 1", "Publication Year": 2018, "Volume": 11, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1510, "End Page": 1519, "Article Number": null, "DOI": "10.1039/c8ee00220g", "DOI Link": "http://dx.doi.org/10.1039/c8ee00220g", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435351000014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Z; Gutiérrez-Lezama, I; Ubrig, N; Kroner, M; Gibertini, M; Taniguchi, T; Watanabe, K; Imamoglu, A; Giannini, E; Morpurgo, AF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zhe; Gutierrez-Lezama, Ignacio; Ubrig, Nicolas; Kroner, Martin; Gibertini, Marco; Taniguchi, Takashi; Watanabe, Kenji; Imamoglu, Atac; Giannini, Enrico; Morpurgo, Alberto F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Very large tunneling magnetoresistance in layered magnetic semiconductor CrI3", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnetic layered van der Waals crystals are an emerging class of materials giving access to new physical phenomena, as illustrated by the recent observation of 2D ferromagnetism in Cr2Ge2Te6 and CrI3. Of particular interest in semiconductors is the interplay between magnetism and transport, which has remained unexplored. Here we report magneto-transport measurements on exfoliated CrI3 crystals. We find that tunneling conduction in the direction perpendicular to the crystalline planes exhibits a magnetoresistance as large as 10,000%. The evolution of the magnetoresistance with magnetic field and temperature reveals that the phenomenon originates from multiple transitions to different magnetic states, whose possible microscopic nature is discussed on the basis of all existing experimental observations. This observed dependence of the conductance of a tunnel barrier on its magnetic state is a phenomenon that demonstrates the presence of a strong coupling between transport and magnetism in magnetic van der Waals semiconductors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 748, "Times Cited, All Databases": 802, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 28", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2516, "DOI": "10.1038/s41467-018-04953-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-04953-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000436548700007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, SF; Fatemi, V; Gibson, QD; Watanabe, K; Taniguchi, T; Cava, RJ; Jarillo-Herrero, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Sanfeng; Fatemi, Valla; Gibson, Quinn D.; Watanabe, Kenji; Taniguchi, Takashi; Cava, Robert J.; Jarillo-Herrero, Pablo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of the quantum spin Hall effect up to 100 kelvin in a monolayer crystal", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A variety of monolayer crystals have been proposed to be two-dimensional topological insulators exhibiting the quantum spin Hall effect (QSHE), possibly even at high temperatures. Here we report the observation of the QSHE in monolayer tungsten ditelluride (WTe2) at temperatures up to 100 kelvin. In the short-edge limit, the monolayer exhibits the hallmark transport conductance, similar to e(2)/h per edge, where e is the electron charge and h is Planck's constant. Moreover, a magnetic field suppresses the conductance, and the observed Zeeman-type gap indicates the existence of a Kramers degenerate point and the importance of time-reversal symmetry for protection from elastic backscattering. Our results establish the QSHE at temperatures much higher than in semiconductor heterostructures and allow for exploring topological phases in atomically thin crystals.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 667, "Times Cited, All Databases": 746, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 5", "Publication Year": 2018, "Volume": 359, "Issue": 6371, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 76, "End Page": 79, "Article Number": null, "DOI": "10.1126/science.aan6003", "DOI Link": "http://dx.doi.org/10.1126/science.aan6003", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000419324700070", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Klein, DR; MacNeill, D; Lado, JL; Soriano, D; Navarro-Moratalla, E; Watanabe, K; Taniguchi, T; Manni, S; Canfield, P; Fernández-Rossier, J; Jarillo-Herrero, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Klein, D. R.; MacNeill, D.; Lado, J. L.; Soriano, D.; Navarro-Moratalla, E.; Watanabe, K.; Taniguchi, T.; Manni, S.; Canfield, P.; Fernulldez-Rossier, J.; Jarillo-Herrero, P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Probing magnetism in 2D van der Waals crystalline insulators via electron tunneling", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Magnetic insulators are a key resource for next-generation spintronic and topological devices. The family of layered metal halides promises varied magnetic states, including ultrathin insulating multiferroics, spin liquids, and ferromagnets, but device-oriented characterization methods are needed to unlock their potential. Here, we report tunneling through the layered magnetic insulator CrI3 as a function of temperature and applied magnetic field. We electrically detect the magnetic ground state and interlayer coupling and observe a field-induced metamagnetic transition. Themetamagnetic transition results in magnetoresistances of 95, 300, and 550% for bilayer, trilayer, and tetralayer CrI3 barriers, respectively. We further measure inelastic tunneling spectra for our junctions, unveiling a rich spectrum consistent with collective magnetic excitations (magnons) in CrI3.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 732, "Times Cited, All Databases": 798, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 15", "Publication Year": 2018, "Volume": 360, "Issue": 6394, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1218, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aar3617", "DOI Link": "http://dx.doi.org/10.1126/science.aar3617", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000435360400050", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Christians, JA; Schulz, P; Tinkham, JS; Schloemer, TH; Harvey, SP; de Villers, BJT; Sellinger, A; Berry, JJ; Luther, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Christians, Jeffrey A.; Schulz, Philip; Tinkham, Jonathan S.; Schloemer, Tracy H.; Harvey, Steven P.; de Villers, Bertrand J. Tremolet; Sellinger, Alan; Berry, Joseph J.; Luther, Joseph M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tailored interfaces of unencapsulated perovskite solar cells for >1,000 hour operational stability", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Long-term device stability is the most pressing issue that impedes perovskite solar cell commercialization, given the achieved 22.7% efficiency. The perovskite absorber material itself has been heavily scrutinized for being prone to degradation by water, oxygen and ultraviolet light. To date, most reports characterize device stability in the absence of these extrinsic factors. Here we show that, even under the combined stresses of light (including ultraviolet light), oxygen and moisture, perovskite solar cells can retain 94% of peak efficiency despite 1,000 hours of continuous unencapsulated operation in ambient air conditions (relative humidity of 10-20%). Each interface and contact layer throughout the device stack plays an important role in the overall stability which, when appropriately modified, yields devices in which both the initial rapid decay (often termed burn-in) and the gradual slower decay are suppressed. This extensively modified device architecture and the understanding developed will lead towards durable long-term device performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 744, "Times Cited, All Databases": 799, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2018, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 68, "End Page": 74, "Article Number": null, "DOI": "10.1038/s41560-017-0067-y", "DOI Link": "http://dx.doi.org/10.1038/s41560-017-0067-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000419976100016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Krieg, F; Ochsenbein, ST; Yakunin, S; ten Brinck, S; Aellen, P; Suess, A; Clerc, B; Guggisberg, D; Nazarenko, O; Shynkarenko, Y; Kumar, S; Shih, CJ; Infante, I; Kovalenko, MV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Krieg, Franziska; Ochsenbein, Stefan T.; Yakunin, Sergii; ten Brinck, Stephanie; Aellen, Philipp; Suess, Adrian; Clerc, Baptiste; Guggisberg, Dominic; Nazarenko, Olga; Shynkarenko, Yevhen; Kumar, Sudhir; Shih, Chih-Jen; Infante, Ivan; Kovalenko, Maksym V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Colloidal CsPbX3 (X = CI, Br, I) nullocrystals 2.0: Zwitterionic Capping Ligands for Improved Durability and Stability", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Colloidal lead halide perovskite nullocrystals (NCs) have recently emerged as versatile photonic sources. Their processing and optoelectronic applications are hampered by the loss of colloidal stability and structural integrity due to the facile desorption of surface capping molecules during isolation and purification. To address this issue, herein, we propose a new ligand capping strategy utilizing common and inexpensive long-chain zwitterionic molecules such as 3-(N,N-dimethyloctadecylammonio)propanesulfonate, resulting in much improved chemical durability. In particular, this class of ligands allows for the isolation of clean NCs with high photoluminescence quantum yields (PL QYs) of above 90% after four rounds of precipitation/redispersion along with much higher overall reaction yields of uniform and colloidal dispersible NCs. Densely packed films of these NCs exhibit high PL QY values and effective charge transport. Consequently, they exhibit photoconductivity and low thresholds for amplified spontaneous emission of 2 mu J cm(-2) under femtosecond optical excitation and are suited for efficient light-emitting diodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 715, "Times Cited, All Databases": 753, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2018, "Volume": 3, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 641, "End Page": 646, "Article Number": null, "DOI": "10.1021/acsenergylett.8b00035", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.8b00035", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000427444300021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yankowitz, M; Chen, SW; Polshyn, H; Zhang, YX; Watanabe, K; Taniguchi, T; Graf, D; Young, AF; Dean, CR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yankowitz, Matthew; Chen, Shaowen; Polshyn, Hryhoriy; Zhang, Yuxuan; Watanabe, K.; Taniguchi, T.; Graf, David; Young, Andrea F.; Dean, Cory R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuning superconductivity in twisted bilayer graphene", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Materials with flat electronic bands often exhibit exotic quantum phenomena owing to strong correlations. An isolated low-energy flat band can be induced in bilayer graphene by simply rotating the layers by 1.1 degrees, resulting in the appearance of gate-tunable superconducting and correlated insulating phases. In this study, we demonstrate that in addition to the twist angle, the interlayer coupling can be varied to precisely tune these phases. We induce superconductivity at a twist angle larger than 1.1 degrees-in which correlated phases are otherwise absent-by varying the interlayer spacing with hydrostatic pressure. Our low-disorder devices reveal details about the superconducting phase diagram and its relationship to the nearby insulator. Our results demonstrate twisted bilayer graphene to be a distinctively tunable platform for exploring correlated states.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1693, "Times Cited, All Databases": 1844, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 8", "Publication Year": 2019, "Volume": 363, "Issue": 6431, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1059, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aav1910", "DOI Link": "http://dx.doi.org/10.1126/science.aav1910", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460750100038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YX; Qiu, G; Wang, RX; Huang, SY; Wang, QX; Liu, YY; Du, YC; Goddard, WA ; Kim, MJ; Xu, XF; Ye, PD; Wu, WZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yixiu; Qiu, Gang; Wang, Ruoxing; Huang, Shouyuan; Wang, Qingxiao; Liu, Yuanyue; Du, Yuchen; Goddard, William A., III; Kim, Moon J.; Xu, Xianfan; Ye, Peide D.; Wu, Wenzhuo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Field-effect transistors made from solution-grown two-dimensional tellurene", "Source Title": "NATURE ELECTRONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The reliable production of two-dimensional (2D) crystals is essential for the development of new technologies based on 2D materials. However, current synthesis methods suffer from a variety of drawbacks, including limitations in crystal size and stability. Here, we report the fabrication of large-area, high-quality 2D tellurium (tellurene) using a substrate-free solution process. Our approach can create crystals with process-tunable thickness, from a monolayer to tens of nullometres, and with lateral sizes of up to 100 mu m. The chiral-chain van der Waals structure of tellurene gives rise to strong in-plane anisotropic properties and large thickness-dependent shifts in Raman vibrational modes, which is not observed in other 2D layered materials. We also fabricate tellurene field-effect transistors, which exhibit air-stable performance at room temperature for over two months, on/off ratios on the order of 10(6), and field-effect mobilities of about 700 cm(2) V-1 s(-1). Furthermore, by scaling down the channel length and integrating with high-k dielectrics, transistors with a significant on-state current density of 1 A mm(-1) are demonstrated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 701, "Times Cited, All Databases": 758, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2018, "Volume": 1, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 228, "End Page": 236, "Article Number": null, "DOI": "10.1038/s41928-018-0058-4", "DOI Link": "http://dx.doi.org/10.1038/s41928-018-0058-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000444074900011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peurifoy, J; Shen, YC; Jing, L; Yang, Y; Cano-Renteria, F; DeLacy, BG; Joannopoulos, JD; Tegmark, M; Soljacic, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peurifoy, John; Shen, Yichen; Jing, Li; Yang, Yi; Cano-Renteria, Fidel; DeLacy, Brendan G.; Joannopoulos, John D.; Tegmark, Max; Soljacic, Marin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullophotonic particle simulation and inverse design using artificial neural networks", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We propose a method to use artificial neural networks to approximate light scattering by multilayer nulloparticles. We find that the network needs to be trained on only a small sampling of the data to approximate the simulation to high precision. Once the neural network is trained, it can simulate such optical processes orders of magnitude faster than conventional simulations. Furthermore, the trained neural network can be used to solve nullophotonic inverse design problems by using back propagation, where the gradient is analytical, not numerical.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 681, "Times Cited, All Databases": 748, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2018, "Volume": 4, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaar4206", "DOI": "10.1126/sciadv.aar4206", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aar4206", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000443175500028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiao, L; Wan, G; Zhang, R; Zhou, H; Yu, SH; Jiang, HL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiao, Long; Wan, Gang; Zhang, Rui; Zhou, Hua; Yu, Shu-Hong; Jiang, Hai-Long", "Book Author Full Names": null, "Group Authors": null, "Article Title": "From Metal-Organic Frameworks to Single-Atom Fe Implanted N-doped Porous Carbons: Efficient Oxygen Reduction in Both Alkaline and Acidic Media", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It remains highly desired but a great challenge to achieve atomically dispersed metals in high loadings for efficient catalysis. Now porphyrinic metal-organic frameworks (MOFs) have been synthesized based on a novel mixed-ligand strategy to afford high-content (1.76wt%) single-atom (SA) iron-implanted N-doped porous carbon (Fe-SA-N-C) via pyrolysis. Thanks to the single-atom Fe sites, hierarchical pores, oriented mesochannels and high conductivity, the optimized Fe-SA-N-C exhibits excellent oxygen reduction activity and stability, surpassing almost all non-noble-metal catalysts and state-of-the-art Pt/C, in both alkaline and more challenging acidic media. More far-reaching, this MOF-based mixed-ligand strategy opens a novel avenue to the precise fabrication of efficient single-atom catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 734, "Times Cited, All Databases": 762, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 9", "Publication Year": 2018, "Volume": 57, "Issue": 28, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8525, "End Page": 8529, "Article Number": null, "DOI": "10.1002/anie.201803262", "DOI Link": "http://dx.doi.org/10.1002/anie.201803262", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000437668700027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuan, J; Zhang, YQ; Zhou, LY; Zhang, GC; Yip, HL; Lau, TK; Lu, XH; Zhu, C; Peng, HJ; Johnson, PA; Leclerc, M; Cao, Y; Ulanski, J; Li, YF; Zou, YP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuan, Jun; Zhang, Yunqiang; Zhou, Liuyang; Zhang, Guichuan; Yip, Hin-Lap; Lau, Tsz-Ki; Lu, Xinhui; Zhu, Can; Peng, Hongjian; Johnson, Paul A.; Leclerc, Mario; Cao, Yong; Ulanski, Jacek; Li, Yongfang; Zou, Yingping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-Junction Organic Solar Cell with over 15% Efficiency Using Fused-Ring Acceptor with Electron-Deficient Core", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently, non-fullerene n-type organic semiconductors have attracted significant attention as acceptors in organic photovoltaics (OPVs) due to their great potential to realize high-power conversion efficiencies. The rational design of the central fused ring unit of these acceptor molecules is crucial to maximize device performance. Here, we report a new class of non-fullerene acceptor, Y6, that employs a ladder-type electron-deficient-core-based central fused ring (dithienothiophen[3.2-b]-pyrrolobenzothiadiazole) with a benzothiadiazole (BT) core to fine-tune its absorption and electron affinity. OPVs made from Y6 in conventional and inverted architectures each exhibited a high efficiency of 15.7%, measured in two separate labs. Inverted device structures were certified at Enli Tech Laboratory demonstrated an efficiency of 14.9%. We further observed that the Y6-based devices maintain a high efficiency of 13.6% with an active layer thickness of 300 nm. The electron-deficient-core-based fused ring reported in this work opens a new door in the molecular design of high-performance acceptors for OPVs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 4849, "Times Cited, All Databases": 5037, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 17", "Publication Year": 2019, "Volume": 3, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1140, "End Page": 1151, "Article Number": null, "DOI": "10.1016/j.joule.2019.01.004", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.01.004", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000465149000023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sharpe, AL; Fox, EJ; Barnard, AW; Finney, J; Watanabe, K; Taniguchi, T; Kastner, MA; Goldhaber-Gordon, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sharpe, Aaron L.; Fox, Eli J.; Barnard, Arthur W.; Finney, Joe; Watanabe, Kenji; Taniguchi, Takashi; Kastner, M. A.; Goldhaber-Gordon, David", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Emergent ferromagnetism near three-quarters filling in twisted bilayer graphene", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "When two sheets of graphene are stacked at a small twist angle, the resulting flat superlattice minibands are expected to strongly enhance electron-electron interactions. Here, we present evidence that near three-quarters (3/4) filling of the conduction miniband, these enhanced interactions drive the twisted bilayer graphene into a ferromagnetic state. In a narrow density range around an apparent insulating state at 3/4, we observe emergent ferromagnetic hysteresis, with a giant anomalous Hall (AH) effect as large as 10.4 kilohms and indications of chiral edge states. Notably, the magnetization of the sample can be reversed by applying a small direct current. Although the AH resistance is not quantized, and dissipation is present, our measurements suggest that the system may be an incipient Chern insulator.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1346, "Times Cited, All Databases": 1481, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 9", "Publication Year": 2019, "Volume": 365, "Issue": 6453, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 605, "End Page": 608, "Article Number": null, "DOI": "10.1126/science.aaw3780", "DOI Link": "http://dx.doi.org/10.1126/science.aaw3780", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000483195200043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Severson, KA; Attia, PM; Jin, N; Perkins, N; Jiang, B; Yang, Z; Chen, MH; Aykol, M; Herring, PK; Fraggedakis, D; Bazan, MZ; Harris, SJ; Chueh, WC; Braatz, RD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Severson, Kristen A.; Attia, Peter M.; Jin, Norman; Perkins, Nicholas; Jiang, Benben; Yang, Zi; Chen, Michael H.; Aykol, Muratahan; Herring, Patrick K.; Fraggedakis, Dimitrios; Bazan, Martin Z.; Harris, Stephen J.; Chueh, William C.; Braatz, Richard D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Data-driven prediction of battery cycle life before capacity degradation", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Accurately predicting the lifetime of complex, nonlinear systems such as lithium-ion batteries is critical for accelerating technology development. However, diverse aging mechanisms, significant device variability and dynamic operating conditions have remained major challenges. We generate a comprehensive dataset consisting of 124 commercial lithium iron phosphate/graphite cells cycled under fast-charging conditions, with widely varying cycle lives ranging from 150 to 2,300 cycles. Using discharge voltage curves from early cycles yet to exhibit capacity degradation, we apply machine-learning tools to both predict and classify cells by cycle life. Our best models achieve 9.1% test error for quantitatively predicting cycle life using the first 100 cycles (exhibiting a median increase of 0.2% from initial capacity) and 4.9% test error using the first 5 cycles for classifying cycle life into two groups. This work highlights the promise of combining deliberate data generation with data-driven modelling to predict the behaviour of complex dynamical systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1569, "Times Cited, All Databases": 1690, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2019, "Volume": 4, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 383, "End Page": 391, "Article Number": null, "DOI": "10.1038/s41560-019-0356-8", "DOI Link": "http://dx.doi.org/10.1038/s41560-019-0356-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000467965700011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, XB; Stepanov, P; Yang, W; Xie, M; Aamir, MA; Das, I; Urgell, C; Watanabe, K; Taniguchi, T; Zhang, GY; Bachtold, A; MacDonald, AH; Efetov, DK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Xiaobo; Stepanov, Petr; Yang, Wei; Xie, Ming; Aamir, Mohammed Ali; Das, Ipsita; Urgell, Carles; Watanabe, Kenji; Taniguchi, Takashi; Zhang, Guangyu; Bachtold, Adrian; MacDonald, Allan H.; Efetov, Dmitri K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superconductors, orbital magnets and correlated states in magic-angle bilayer graphene", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Superconductivity can occur under conditions approaching broken-symmetry parent states(1). In bilayer graphene, the twisting of one layer with respect to the other at 'magic' twist angles of around 1 degree leads to the emergence of ultra-flat moire superlattice minibands. Such bands are a rich and highly tunable source of strong-correlation physics(2-5), notably superconductivity, which emerges close to interaction-induced insulating states(6,7). Here we report the fabrication of magic-angle twisted bilayer graphene devices with highly uniform twist angles. The reduction in twist-angle disorder reveals the presence of insulating states at all integer occupancies of the fourfold spin-valley degenerate flat conduction and valence bands-that is, at moire band filling factors nu = 0, +/- 1, +/- 2, +/- 3. At nu approximate to -2, superconductivity is observed below critical temperatures of up to 3 kelvin. We also observe three new superconducting domes at much lower temperatures, close to the nu = 0 and. = +/- 1 insulating states. Notably, at nu = +/- 1 we find states with non-zero Chern numbers. For nu = -1 the insulating state exhibits a sharp hysteretic resistance enhancement when a perpendicular magnetic field greater than 3.6 tesla is applied, which is consistent with a field-driven phase transition. Our study shows that broken-symmetry states, interaction-driven insulators, orbital magnets, states with non-zero Chern numbers and superconducting domes occur frequently across a wide range of moire flat band fillings, including close to charge neutrality. This study provides a more detailed view of the phenomenology of magic-angle twisted bilayer graphene, adding to our evolving understanding of its emergent properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1191, "Times Cited, All Databases": 1283, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 31", "Publication Year": 2019, "Volume": 574, "Issue": 7780, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 653, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-019-1695-0", "DOI Link": "http://dx.doi.org/10.1038/s41586-019-1695-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000493807800038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bartel, CJ; Sutton, C; Goldsmith, BR; Ouyang, RH; Musgrave, CB; Ghiringhelli, LM; Scheffler, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bartel, Christopher J.; Sutton, Christopher; Goldsmith, Bryan R.; Ouyang, Runhai; Musgrave, Charles B.; Ghiringhelli, Luca M.; Scheffler, Matthias", "Book Author Full Names": null, "Group Authors": null, "Article Title": "New tolerance factor to predict the stability of perovskite oxides and halides", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Predicting the stability of the perovskite structure remains a long-standing challenge for the discovery of new functional materials for many applications including photovoltaics and electrocatalysts. We developed an accurate, physically interpretable, and one-dimensional tolerance factor, 'r, that correctly predicts 92% of compounds as perovskite or nonperovskite for an experimental dataset of 576 ABX(3) materials (X = O2-, F-, Cl-, Br-, I-) using a novel data analytics approach based on SISSO (sure independence screening and sparsifying operator). tau is shown to generalize outside the training set for 1034 experimentally realized single and double perovskites (91% accuracy) and is applied to identify 23,314 new double perovskites (A(2)BB'X-6) ranked by their probability of being stable as perovskite. This work guides experimentalists and theorists toward which perovskites are most likely to be successfully synthesized and demonstrates an approach to descriptor identification that can be extended to arbitrary applications beyond perovskite stability predictions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1070, "Times Cited, All Databases": 1158, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2019, "Volume": 5, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaav0693", "DOI": "10.1126/sciadv.aav0693", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aav0693", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000460145700051", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, T; Zhai, Y; He, SM; Gan, WT; Wei, ZY; Heidarinejad, M; Dalgo, D; Mi, RY; Zhao, XP; Song, JW; Dai, JQ; Chen, CJ; Aili, A; Vellore, A; Martini, A; Yang, RG; Srebric, J; Yin, XB; Hu, LB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Tian; Zhai, Yao; He, Shuaiming; Gan, Wentao; Wei, Zhiyuan; Heidarinejad, Mohammad; Dalgo, Daniel; Mi, Ruiyu; Zhao, Xinpeng; Song, Jianwei; Dai, Jiaqi; Chen, Chaoji; Aili, Ablimit; Vellore, Azhar; Martini, Ashlie; Yang, Ronggui; Srebric, Jelena; Yin, Xiaobo; Hu, Liangbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A radiative cooling structural material", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Reducing human reliance on energy-inefficient cooling methods such as air conditioning would have a large impact on the global energy landscape. By a process of complete delignification and densification of wood, we developed a structural material with a mechanical strength of 404.3 megapascals, more than eight times that of natural wood. The cellulose nullofibers in our engineered material backscatter solar radiation and emit strongly in mid-infrared wavelengths, resulting in continuous subambient cooling during both day and night. We model the potential impact of our cooling wood and find energy savings between 20 and 60%, which is most pronounced in hot and dry climates.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1081, "Times Cited, All Databases": 1158, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 24", "Publication Year": 2019, "Volume": 364, "Issue": 6442, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 760, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aau9101", "DOI Link": "http://dx.doi.org/10.1126/science.aau9101", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000469296000039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tian, XL; Zhao, X; Su, YQ; Wang, LJ; Wang, HM; Dang, D; Chi, B; Liu, HF; Hensen, EJM; Lou, XW; Xia, BY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tian, Xinlong; Zhao, Xiao; Su, Ya-Qiong; Wang, Lijuan; Wang, Hongming; Dang, Dai; Chi, Bin; Liu, Hongfang; Hensen, Emiel J. M.; Lou, Xiong Wen (David); Xia, Bao Yu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering bunched Pt-Ni alloy nullocages for efficient oxygen reduction in practical fuel cells", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Development of efficient and robust electrocatalysts is critical for practical fuel cells. We report one-dimensional bunched platinum-nickel (Pt-Ni) alloy nullocages with a Pt-skin structure for the oxygen reduction reaction that display high mass activity (3.52 amperes per milligram platinum) and specific activity (5.16 milliamperes per square centimeter platinum), or nearly 17 and 14 times higher as compared with a commercial platinum on carbon (Pt/C) catalyst. The catalyst exhibits high stability with negligible activity decay after 50,000 cycles. Both the experimental results and theoretical calculations reveal the existence of fewer strongly bonded platinum-oxygen (Pt-O) sites induced by the strain and ligand effects. Moreover, the fuel cell assembled by this catalyst delivers a current density of 1.5 amperes per square centimeter at 0.6 volts and can operate steadily for at least 180 hours.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1197, "Times Cited, All Databases": 1246, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 15", "Publication Year": 2019, "Volume": 366, "Issue": 6467, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 850, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aaw7493", "DOI Link": "http://dx.doi.org/10.1126/science.aaw7493", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000496946200049", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lee, A; Hudson, AR; Shiwarski, DJ; Tashman, JW; Hinton, TJ; Yerneni, S; Bliley, JM; Campbell, PG; Feinberg, AW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lee, A.; Hudson, A. R.; Shiwarski, D. J.; Tashman, J. W.; Hinton, T. J.; Yerneni, S.; Bliley, J. M.; Campbell, P. G.; Feinberg, A. W.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D bioprinting of collagen to rebuild components of the human heart", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Collagen is the primary component of the extracellular matrix in the human body. It has proved challenging to fabricate collagen scaffolds capable of replicating the structure and function of tissues and organs. We present a method to 3D-bioprint collagen using freeform reversible embedding of suspended hydrogels (FRESH) to engineer components of the human heart at various scales, from capillaries to the full organ. Control of pH-driven gelation provides 20-micrometer filament resolution, a porous microstructure that enables rapid cellular infiltration and microvascularization, and mechanical strength for fabrication and perfusion of multiscale vasculature and tri-leaflet valves. We found that FRESH 3D-bioprinted hearts accurately reproduce patient-specific anatomical structure as determined by micro-computed tomography. Cardiac ventricles printed with human cardiomyocytes showed synchronized contractions, directional action potential propagation, and wall thickening up to 14% during peak systole.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1229, "Times Cited, All Databases": 1394, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 2", "Publication Year": 2019, "Volume": 365, "Issue": 6452, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 482, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aav9051", "DOI Link": "http://dx.doi.org/10.1126/science.aav9051", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000485768400044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, YJ; Ji, SF; Zhao, S; Chen, WX; Dong, JC; Cheong, WC; Shen, RA; Wen, XD; Zheng, LR; Rykov, AI; Cai, SC; Tang, HL; Zhuang, ZB; Chen, C; Peng, Q; Wang, DS; Li, YD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Yuanjun; Ji, Shufang; Zhao, Shu; Chen, Wenxing; Dong, Juncai; Cheong, Weng-Chon; Shen, Rongan; Wen, Xiaodong; Zheng, Lirong; Rykov, Alexandre I.; Cai, Shichang; Tang, Haolin; Zhuang, Zhongbin; Chen, Chen; Peng, Qing; Wang, Dingsheng; Li, Yadong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced oxygen reduction with single-atomic-site iron catalysts for a zinc-air battery and hydrogen-air fuel cell", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Efficient, durable and inexpensive electrocatalysts that accelerate sluggish oxygen reduction reaction kinetics and achieve high-performance are highly desirable. Here we develop a strategy to fabricate a catalyst comprised of single iron atomic sites supported on a nitrogen, phosphorus and sulfur co-doped hollow carbon polyhedron from a metal-organic framework@polymer composite. The polymer-based coating facilitates the construction of a hollow structure via the Kirkendall effect and electronic modulation of an active metal center by long-range interaction with sulfur and phosphorus. Benefiting from structure functionalities and electronic control of a single-atom iron active center, the catalyst shows a remarkable performance with enhanced kinetics and activity for oxygen reduction in both alkaline and acid media. Moreover, the catalyst shows promise for substitution of expensive platinum to drive the cathodic oxygen reduction reaction in zinc-air batteries and hydrogenair fuel cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 747, "Times Cited, All Databases": 774, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 21", "Publication Year": 2018, "Volume": 9, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5422, "DOI": "10.1038/s41467-018-07850-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-07850-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000454137600003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Somayazulu, M; Ahart, M; Mishra, AK; Geballe, ZM; Baldini, M; Meng, Y; Struzhkin, VV; Hemley, RJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Somayazulu, Maddury; Ahart, Muhtar; Mishra, Ajay K.; Geballe, Zachary M.; Baldini, Maria; Meng, Yue; Struzhkin, Viktor V.; Hemley, Russell J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Evidence for Superconductivity above 260 K in Lanthanum Superhydride at Megabar Pressures", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent predictions and experimental observations of high T-c superconductivity in hydrogen-rich materials at very high pressures are driving the search for superconductivity in the vicinity of room temperature. We have developed a novel preparation technique that is optimally suited for megabar pressure syntheses of superhydrides using modulated laser heating while maintaining the integrity of sample-probe contacts for electrical transport measurements to 200 GPa. We detail the synthesis and characterization of lanthanum superhydride samples, including four-probe electrical transport measurements that display significant drops in resistivity on cooling up to 260 K and 180-200 GPa, and resistivity transitions at both lower and higher temperatures in other experiments. Additional current-voltage measurements, critical current estimates, and low-temperature x-ray diffraction are also obtained. We suggest that the transitions represent signatures of superconductivity to near room temperature in phases of lanthanum superhydride, in good agreement with density functional structure search and BCS theory calculations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 955, "Times Cited, All Databases": 1036, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 14", "Publication Year": 2019, "Volume": 122, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 27001, "DOI": "10.1103/PhysRevLett.122.027001", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.122.027001", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455687700008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, WD; Hu, Q; Bai, S; Bao, CX; Miao, YF; Yuan, ZC; Borzda, T; Barker, AJ; Tyukalova, E; Hu, ZJ; Kawecki, M; Wang, HY; Yan, ZB; Liu, XJ; Shi, XB; Uvdal, K; Fahlman, M; Zhang, WJ; Duchamp, M; Liu, JM; Petrozza, A; Wang, JP; Liu, LM; Huang, W; Gao, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Weidong; Hu, Qi; Bai, Sai; Bao, Chunxiong; Miao, Yanfeng; Yuan, Zhongcheng; Borzda, Tetiana; Barker, Alex J.; Tyukalova, Elizaveta; Hu, Zhangjun; Kawecki, Maciej; Wang, Heyong; Yan, Zhibo; Liu, Xianjie; Shi, Xiaobo; Uvdal, Kajsa; Fahlman, Mats; Zhang, Wenjing; Duchamp, Martial; Liu, Jun-Ming; Petrozza, Annamaria; Wang, Jianpu; Liu, Li-Min; Huang, Wei; Gao, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rational molecular passivation for high-performance perovskite light-emitting diodes", "Source Title": "NATURE PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A major efficiency limit for solution-processed perovskite optoelectronic devices, for example light-emitting diodes, is trap-mediated non-radiative losses. Defect passivation using organic molecules has been identified as an attractive approach to tackle this issue. However, implementation of this approach has been hindered by a lack of deep understanding of how the molecular structures influence the effectiveness of passivation. We show that the so far largely ignored hydrogen bonds play a critical role in affecting the passivation. By weakening the hydrogen bonding between the passivating functional moieties and the organic cation featuring in the perovskite, we significantly enhance the interaction with defect sites and minimize non-radiative recombination losses. Consequently, we achieve exceptionally high-performance near-infrared perovskite light-emitting diodes with a record external quantum efficiency of 21.6%. In addition, our passivated perovskite light-emitting diodes maintain a high external quantum efficiency of 20.1% and a wall-plug efficiency of 11.0% at a high current density of 200 mA cm(-2), making them more attractive than the most efficient organic and quantum-dot light-emitting diodes at high excitations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1058, "Times Cited, All Databases": 1112, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2019, "Volume": 13, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 418, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41566-019-0390-x", "DOI Link": "http://dx.doi.org/10.1038/s41566-019-0390-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000468752300019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, NX; Tao, SX; Chen, YH; Niu, XX; Onwudinullti, CK; Hu, C; Qiu, ZW; Xu, ZQ; Zheng, GHJ; Wang, LG; Zhang, Y; Li, L; Liu, HF; Lun, YZ; Hong, JW; Wang, XY; Liu, YQ; Xie, HP; Gao, YL; Bai, Y; Yang, SH; Brocks, G; Chen, Q; Zhou, HP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Nengxu; Tao, Shuxia; Chen, Yihua; Niu, Xiuxiu; Onwudinullti, Chidozie K.; Hu, Chen; Qiu, Zhiwen; Xu, Ziqi; Zheng, Guanhaojie; Wang, Ligang; Zhang, Yu; Li, Liang; Liu, Huifen; Lun, Yingzhuo; Hong, Jiawang; Wang, Xueyun; Liu, Yuquan; Xie, Haipeng; Gao, Yongli; Bai, Yang; Yang, Shihe; Brocks, Geert; Chen, Qi; Zhou, Huanping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cation and anion immobilization through chemical bonding enhancement with fluorides for stable halide perovskite solar cells", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Defects play an important role in the degradation processes of hybrid halide perovskite absorbers, impeding their application for solar cells. Among all defects, halide anion and organic cation vacancies are ubiquitous, promoting ion diffusion and leading to thin-film decomposition at surfaces and grain boundaries. Here, we employ fluoride to simultaneously passivate both anion and cation vacancies, by taking advantage of the extremely high electronegativity of fluoride. We obtain a power conversion efficiency of 21.46% (and a certified 21.3%-efficient cell) in a device based on the caesium, methylammonium (MA) and for-mamidinium (FA) triple-cation perovskite (Cs(0.05)FA(0.54)MA(0.41))Pb(I0.98Br0.02)(3) treated with sodium fluoride. The device retains 90% of its original power conversion efficiency after 1,000 h of operation at the maximum power point. With the help of first-principles density functional theory calculations, we argue that the fluoride ions suppress the formation of halide anion and organic cation vacancies, through a unique strengthening of the chemical bonds with the surrounding lead and organic cations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 951, "Times Cited, All Databases": 992, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2019, "Volume": 4, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 408, "End Page": 415, "Article Number": null, "DOI": "10.1038/s41560-019-0382-6", "DOI Link": "http://dx.doi.org/10.1038/s41560-019-0382-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000467965700014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gates-Rector, S; Blanton, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gates-Rector, Stacy; Blanton, Thomas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The Powder Diffraction File: a quality materials characterization database", "Source Title": "POWDER DIFFRACTION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ICDD' s Powder Diffraction File (TM) (PDF (R)) is a database of inorganic and organic diffraction data used for phase identification and materials characterization by powder diffraction. The PDF has been available for over 75 years and finds application in X-ray, synchrotron, electron, and neutron diffraction analyses. With entries based on powder and single crystal data, the PDF is the only crystallographic database where every entry is editorially reviewed and marked with a quality mark that alerts the user to the reliability/quality of the submitted data. The editorial processes of ICDD' s quality management system are unique in that they are ISO 9001:2015 certified. Initially offered as text on paper cards and books, the PDF evolved to a computer-readable database in the 1960s and today is both computer and web accessible. With data mining and phase identification software available in PDF products, and the databases' compatibility with vendor (third party) software, the 1 000 000+ published PDF entries serve a wide range of disciplines covering academic, industrial, and government laboratories. Details describing the content of database entries are presented to enhance the use of the PDF. (C) 2019 International Centre for Diffraction Data.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 961, "Times Cited, All Databases": 1003, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2019, "Volume": 34, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 352, "End Page": 360, "Article Number": null, "DOI": "10.1017/S0885715619000812", "DOI Link": "http://dx.doi.org/10.1017/S0885715619000812", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000500163500010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, R; Xue, JJ; Wang, KL; Wang, ZK; Luo, YQ; Fenning, D; Xu, GW; Nuryyeva, S; Huang, TY; Zhao, YP; Yang, JL; Zhu, JH; Wang, MH; Tan, S; Yavuz, I; Houk, KN; Yang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Rui; Xue, Jingjing; Wang, Kai-Li; Wang, Zhao-Kui; Luo, Yanqi; Fenning, David; Xu, Guangwei; Nuryyeva, Selbi; Huang, Tianyi; Zhao, Yepin; Yang, Jonathan Lee; Zhu, Jiahui; Wang, Minhuan; Tan, Shaun; Yavuz, Ilhan; Houk, Kendall N.; Yang, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Constructive molecular configurations for surface-defect passivation of perovskite photovoltaics", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Surface trap-mediated nonradiative charge recombination is a major limit to achieving high-efficiency metal-halide perovskite photovoltaics. The ionic character of perovskite lattice has enabled molecular defect passivation approaches through interaction between functional groups and defects. However, a lack of in-depth understanding of how the molecular configuration influences the passivation effectiveness is a challenge to rational molecule design. Here, the chemical environment of a functional group that is activated for defect passivation was systematically investigated with theophylline, caffeine, and theobromine. When N-H and C=O were in an optimal configuration in the molecule, hydrogen-bond formation between N-H and I (iodine) assisted the primary C=O binding with the antisite Pb (lead) defect to maximize surface-defect binding. A stabilized power conversion efficiency of 22.6% of photovoltaic device was demonstrated with theophylline treatment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1015, "Times Cited, All Databases": 1051, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 20", "Publication Year": 2019, "Volume": 366, "Issue": 6472, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1509, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aay9698", "DOI Link": "http://dx.doi.org/10.1126/science.aay9698", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000503861000054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, M; Lu, J; Luo, K; Li, YB; Chang, KK; Chen, K; Zhou, J; Rosen, J; Hultman, L; Eklund, P; Persson, POÅ; Du, SY; Chai, ZF; Huang, ZR; Huang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Mian; Lu, Jun; Luo, Kan; Li, Youbing; Chang, Keke; Chen, Ke; Zhou, Jie; Rosen, Johanna; Hultman, Lars; Eklund, Per; Persson, Per O. A.; Du, Shiyu; Chai, Zhifang; Huang, Zhengren; Huang, Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Element Replacement Approach by Reaction with Lewis Acidic Molten Salts to Synthesize nullolaminated MAX Phases and MXenes", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "nullolaminated materials are important because of their exceptional properties and wide range of applications. Here, we demonstrate a general approach to synthesizing a series of Zn-based MAX phases and Cl-terminated MXenes originating from the replacement reaction between the MAX phase and the late transition-metal halides. The approach is a top-down route that enables the late transitional element atom (Zn in the present case) to occupy the A site in the pre-existing MAX phase structure. Using this replacement reaction between the Zn element from molten ZnCl2 and the Al element in MAX phase precursors (Ti3AlC2, Ti2AlC, Ti2AlN, and V2AlC), novel MAX phases Ti3ZnC2, Ti2ZnC, Ti2ZnN, and V2ZnC were synthesized. When employing excess ZnCl2, Cl-terminated MXenes (such as Ti3C2Cl2 and Ti2CCl2) were derived by a subsequent exfoliation of Ti3ZnC2 and Ti2ZnC due to the strong Lewis acidity of molten ZnCl2. These results indicate that A-site element replacement in traditional MAX phases by late transition-metal halides opens the door to explore MAX phases that are not thermodynamically stable at high temperature and would be difficult to synthesize through the commonly employed powder metallurgy approach. In addition, this is the first time that exclusively Cl-terminated MXenes were obtained, and the etching effect of Lewis acid in molten salts provides a green and viable route to preparing MXenes through an HF-free chemical approach.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1024, "Times Cited, All Databases": 1083, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 20", "Publication Year": 2019, "Volume": 141, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 4730, "End Page": 4737, "Article Number": null, "DOI": "10.1021/jacs.9b00574", "DOI Link": "http://dx.doi.org/10.1021/jacs.9b00574", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462260400032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Y; Dar, MI; Ono, LK; Zhang, TY; Kan, M; Li, YW; Zhang, LJ; Wang, XT; Yang, YG; Gao, XY; Qi, YB; Grätzel, M; Zhao, YX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yong; Dar, M. Ibrahim; Ono, Luis K.; Zhang, Taiyang; Kan, Miao; Li, Yawen; Zhang, Lijun; Wang, Xingtao; Yang, Yingguo; Gao, Xingyu; Qi, Yabing; Gratzel, Michael; Zhao, Yixin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermodynamically stabilized β-CsPbI3-based perovskite solar cells with efficiencies >18%", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although beta-CsPbI3 has a bandgap favorable for application in tandem solar cells, depositing and stabilizing beta-CsPbI3 experimentally has remained a challenge. We obtained highly crystalline beta-CsPbI3 films with an extended spectral response and enhanced phase stability. Synchrotron-based x-ray scattering revealed the presence of highly oriented beta-CsPbI3 grains, and sensitive elemental analyses-including inductively coupled plasma mass spectrometry and time-of-flight secondary ion mass spectrometry-confirmed their all-inorganic composition. We further mitigated the effects of cracks and pinholes in the perovskite layer by surface treating with choline iodide, which increased the charge-carrier lifetime and improved the energy-level alignment between the beta-CsPbI3 absorber layer and carrier-selective contacts. The perovskite solar cells made from the treated material have highly reproducible and stable efficiencies reaching 18.4% under 45 +/- 5 degrees C ambient conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1035, "Times Cited, All Databases": 1070, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 9", "Publication Year": 2019, "Volume": 365, "Issue": 6453, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 591, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aav8680", "DOI Link": "http://dx.doi.org/10.1126/science.aav8680", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000483195200040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hart, JL; Hantanasirisakul, K; Lang, AC; Anasori, B; Pinto, D; Pivak, Y; van Omme, JT; May, SJ; Gogotsi, Y; Taheri, ML", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hart, James L.; Hantanasirisakul, Kanit; Lang, Andrew C.; Anasori, Babak; Pinto, David; Pivak, Yevheniy; van Omme, J. Tijn; May, Steven J.; Gogotsi, Yury; Taheri, Mitra L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Control of MXenes' electronic properties through termination and intercalation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MXenes are an emerging family of highly-conductive 2D materials which have demonstrated state-of-the-art performance in electromagnetic interference shielding, chemical sensing, and energy storage. To further improve performance, there is a need to increase MXenes' electronic conductivity. Tailoring the MXene surface chemistry could achieve this goal, as density functional theory predicts that surface terminations strongly influence MXenes' Fermi level density of states and thereby MXenes' electronic conductivity. Here, we directly correlate MXene surface de-functionalization with increased electronic conductivity through in situ vacuum annealing, electrical biasing, and spectroscopic analysis within the transmission electron microscope. Furthermore, we show that intercalation can induce transitions between metallic and semiconductor-like transport (transitions from a positive to negative temperature-dependence of resistance) through inter-flake effects. These findings lay the groundwork for intercalation-and termination-engineered MXenes, which promise improved electronic conductivity and could lead to the realization of semiconducting, magnetic, and topologically insulating MXenes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 950, "Times Cited, All Databases": 997, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 31", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 522, "DOI": "10.1038/s41467-018-08169-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-08169-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457291300010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, L; Zhu, Q; Song, SW; McElhenny, B; Wang, DZ; Wu, CZ; Qin, ZJ; Bao, JM; Yu, Y; Chen, S; Ren, ZF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Luo; Zhu, Qing; Song, Shaowei; McElhenny, Brian; Wang, Dezhi; Wu, Chunzheng; Qin, Zhaojun; Bao, Jiming; Yu, Ying; Chen, Shuo; Ren, Zhifeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Non-noble metal-nitride based electrocatalysts for high-performance alkaline seawater electrolysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Seawater is one of the most abundant natural resources on our planet. Electrolysis of seawater is not only a promising approach to produce clean hydrogen energy, but also of great significance to seawater desalination. The implementation of seawater electrolysis requires robust and efficient electrocatalysts that can sustain seawater splitting without chloride corrosion, especially for the anode. Here we report a three-dimensional core-shell metal-nitride catalyst consisting of NiFeN nulloparticles uniformly decorated on NiMoN nullorods supported on Ni foam, which serves as an eminently active and durable oxygen evolution reaction catalyst for alkaline seawater electrolysis. Combined with an efficient hydrogen evolution reaction catalyst of NiMoN nullorods, we have achieved the industrially required current densities of 500 and 1000 mA cm(-2) at record low voltages of 1.608 and 1.709 V, respectively, for overall alkaline seawater splitting at 60 degrees C. This discovery significantly advances the development of seawater electrolysis for large-scale hydrogen production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 985, "Times Cited, All Databases": 1017, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 8", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5106, "DOI": "10.1038/s41467-019-13092-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-13092-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000495393000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cui, Y; Yao, HF; Zhang, JQ; Zhang, T; Wang, YM; Hong, L; Xian, KH; Xu, BW; Zhang, SQ; Peng, J; Wei, ZX; Gao, F; Hou, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cui, Yong; Yao, Huifeng; Zhang, Jianqi; Zhang, Tao; Wang, Yuming; Hong, Ling; Xian, Kaihu; Xu, Bowei; Zhang, Shaoqing; Peng, Jing; Wei, Zhixiang; Gao, Feng; Hou, Jianhui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Over 16% efficiency organic photovoltaic cells enabled by a chlorinated acceptor with increased open-circuit voltages", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Broadening the optical absorption of organic photovoltaic (OPV) materials by enhancing the intramolecular push-pull effect is a general and effective method to improve the power conversion efficiencies of OPV cells. However, in terms of the electron acceptors, the most common molecular design strategy of halogenation usually results in down-shifted molecular energy levels, thereby leading to decreased open-circuit voltages in the devices. Herein, we report a chlorinated non-fullerene acceptor, which exhibits an extended optical absorption and meanwhile displays a higher voltage than its fluorinated counterpart in the devices. This unexpected phenomenon can be ascribed to the reduced non-radiative energy loss (0.206 eV). Due to the simultaneously improved short-circuit current density and open-circuit voltage, a high efficiency of 16.5% is achieved. This study demonstrates that finely tuning the OPV materials to reduce the bandgap-voltage offset has great potential for boosting the efficiency.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 906, "Times Cited, All Databases": 911, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 7", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2515, "DOI": "10.1038/s41467-019-10351-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-10351-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000470656800023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, JH; Wang, PC; Wang, HH; Li, C; Si, XQ; Qi, JL; Cao, J; Zhong, ZX; Fei, WD; Feng, JC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Jinghuang; Wang, Pengcheng; Wang, Haohan; Li, Chun; Si, Xiaoqing; Qi, Junlei; Cao, Jian; Zhong, Zhengxiang; Fei, Weidong; Feng, Jicai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Defect-Rich Heterogeneous MoS2/NiS2 nullosheets Electrocatalysts for Efficient Overall Water Splitting", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Designing and constructing bifunctional electrocatalysts is vital for water splitting. Particularly, the rational interface engineering can effectively modify the active sites and promote the electronic transfer, leading to the improved splitting efficiency. Herein, free-standing and defect-rich heterogeneous MoS2/NiS2 nullosheets for overall water splitting are designed. The abundant heterogeneous interfaces in MoS2/NiS2 can not only provide rich electroactive sites but also facilitate the electron transfer, which further cooperate synergistically toward electrocatalytic reactions. Consequently, the optimal MoS2/NiS2 nullosheets show the enhanced electrocatalytic performances as bifunctional electrocatalysts for overall water splitting. This study may open up a new route for rationally constructing heterogeneous interfaces to maximize their electrochemical performances, which may help to accelerate the development of nonprecious electrocatalysts for overall water splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 946, "Times Cited, All Databases": 984, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 17", "Publication Year": 2019, "Volume": 6, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1900246, "DOI": "10.1002/advs.201900246", "DOI Link": "http://dx.doi.org/10.1002/advs.201900246", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000477711600019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, C; Ye, WK; Zuo, YX; Zheng, C; Ong, SP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Chi; Ye, Weike; Zuo, Yunxing; Zheng, Chen; Ong, Shyue Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Graph Networks as a Universal Machine Learning Framework for Molecules and Crystals", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Graph networks are a new machine learning (ML) paradigm that supports both relational reasoning and combinatorial generalization. Here, we develop universal MatErials Graph Network (MEGNet) models for accurate property prediction in both molecules and crystals. We demonstrate that the MEGNet models outperform prior ML models such as the SchNet in 11 out of 13 properties of the QM9 molecule data set. Similarly, we show that MEGNet models trained on similar to 60 000 crystals in the Materials Project substantially outperform prior ML models in the prediction of the formation energies, band gaps, and elastic moduli of crystals, achieving better than density functional theory accuracy over a much larger data set. We present two new strategies to address data limitations common in materials science and chemistry. First, we demonstrate a physically intuitive approach to unify four separate molecular MEGNet models for the internal energy at 0 K and room temperature, enthalpy, and Gibbs free energy into a single free energy MEGNet model by incorporating the temperature, pressure, and entropy as global state inputs. Second, we show that the learned element embeddings in MEGNet models encode periodic chemical trends and can be transfer-learned from a property model trained on a larger data set (formation energies) to improve property models with smaller amounts of data (band gaps and elastic moduli).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 796, "Times Cited, All Databases": 903, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 14", "Publication Year": 2019, "Volume": 31, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3564, "End Page": 3572, "Article Number": null, "DOI": "10.1021/acs.chemmater.9b01294", "DOI Link": "http://dx.doi.org/10.1021/acs.chemmater.9b01294", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000468242300054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Grigoryan, B; Paulsen, SJ; Corbett, DC; Sazer, DW; Fortin, CL; Zaita, AJ; Greenfield, PT; Calafat, NJ; Gounley, JP; Ta, AH; Johansson, F; Randles, A; Rosenkrantz, JE; Louis-Rosenberg, JD; Galie, PA; Stevens, KR; Miller, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Grigoryan, Bagrat; Paulsen, Samantha J.; Corbett, Daniel C.; Sazer, Daniel W.; Fortin, Chelsea L.; Zaita, Alexander J.; Greenfield, Paul T.; Calafat, Nicholas J.; Gounley, John P.; Ta, Anderson H.; Johansson, Fredrik; Randles, Amanda; Rosenkrantz, Jessica E.; Louis-Rosenberg, Jesse D.; Galie, Peter A.; Stevens, Kelly R.; Miller, Jordan S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "BIOMEDICINE Multivascular networks and functional intravascular topologies within biocompatible hydrogels", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solid organs transport fluids through distinct vascular networks that are biophysically and biochemically entangled, creating complex three-dimensional (3D) transport regimes that have remained difficult to produce and study. We establish intravascular andmultivascular design freedoms with photopolymerizable hydrogels by using food dye additives as biocompatible yet potent photoabsorbers for projection stereolithography. We demonstrate monolithic transparent hydrogels, produced in minutes, comprising efficient intravascular 3D fluid mixers and functional bicuspid valves. We further elaborate entangled vascular networks from space-filling mathematical topologies and explore the oxygenation and flow of human red blood cells during tidal ventilation and distension of a proximate airway. In addition, we deploy structured biodegradable hydrogel carriers in a rodent model of chronic liver injury to highlight the potential translational utility of this materials innovation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 996, "Times Cited, All Databases": 1128, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 3", "Publication Year": 2019, "Volume": 364, "Issue": 6439, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 458, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aav9750", "DOI Link": "http://dx.doi.org/10.1126/science.aav9750", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000466809600028", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, LG; Zhou, HP; Hu, JN; Huang, BL; Sun, MZ; Dong, BW; Zheng, GHJ; Huang, Y; Chen, YH; Li, L; Xu, ZQ; Li, NX; Liu, Z; Chen, Q; Sun, LD; Yan, CH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Ligang; Zhou, Huanping; Hu, Junnull; Huang, Bolong; Sun, Mingzi; Dong, Bowei; Zheng, Guanghaojie; Huang, Yuan; Chen, Yihua; Li, Liang; Xu, Ziqi; Li, Nengxu; Liu, Zheng; Chen, Qi; Sun, Ling-Dong; Yan, Chun-Hua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Eu3+-Eu2+ ion redox shuttle imparts operational durability to Pb-I perovskite solar cells", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The components with soft nature in the metal halide perovskite absorber usually generate lead (Pb)degrees and iodine (I)degrees defects during device fabrication and operation. These defects serve as not only recombination centers to deteriorate device efficiency but also degradation initiators to hamper device lifetimes. We show that the europium ion pair Eu3+-Eu2+ acts as the redox shuttle that selectively oxidized Pb degrees and reduced I degrees defects simultaneously in a cyclical transition. The resultant device achieves a power conversion efficiency (PCE) of 21.52% (certified 20.52%) with substantially improved long-term durability. The devices retained 92% and 89% of the peak PCE under 1-sun continuous illumination or heating at 850 degrees C for 1500 hours and 91% of the original stable PCE after maximum power point tracking for 500 hours, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 864, "Times Cited, All Databases": 910, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 18", "Publication Year": 2019, "Volume": 363, "Issue": 6424, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 265, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aau5701", "DOI Link": "http://dx.doi.org/10.1126/science.aau5701", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000456140700033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bai, S; Da, PM; Li, C; Wang, ZP; Yuan, ZC; Fu, F; Kawecki, M; Liu, XJ; Sakai, N; Wang, JTW; Huettner, S; Buecheler, S; Fahlman, M; Gao, F; Snaith, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bai, Sai; Da, Peimei; Li, Cheng; Wang, Zhiping; Yuan, Zhongcheng; Fu, Fan; Kawecki, Maciej; Liu, Xianjie; Sakai, Nobuya; Wang, Jacob Tse-Wei; Huettner, Sven; Buecheler, Stephan; Fahlman, Mats; Gao, Feng; Snaith, Henry J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Planar perovskite solar cells with long-term stability using ionic liquid additives", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solar cells based on metal halide perovskites are one of the most promising photovoltaic technologies(1-4). Over the past few years, the long-term operational stability of such devices has been greatly improved by tuning the composition of the perovskites(5-9), optimizing the interfaces within the device structures(10-13), and using new encapsulation techniques(14,15). However, further improvements are required in order to deliver a longer-lasting technology. Ion migration in the perovskite active layer-especially under illumination and heat-is arguably the most difficult aspect to mitigate(16-18). Here we incorporate ionic liquids into the perovskite film and thence into positive-intrinsic-negative photovoltaic devices, increasing the device efficiency and markedly improving the long-term device stability. Specifically, we observe a degradation in performance of only around five per cent for the most stable encapsulated device under continuous simulated full-spectrum sunlight for more than 1,800 hours at 70 to 75 degrees Celsius, and estimate that the time required for the device to drop to eighty per cent of its peak performance is about 5,200 hours. Our demonstration of long-term operational, stable solar cells under intense conditions is a key step towards a reliable perovskite photovoltaic technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 825, "Times Cited, All Databases": 847, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 11", "Publication Year": 2019, "Volume": 571, "Issue": 7764, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 245, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-019-1357-2", "DOI Link": "http://dx.doi.org/10.1038/s41586-019-1357-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000474843400036", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fang, CC; Li, JX; Zhang, MH; Zhang, YH; Yang, F; Lee, JZ; Lee, MH; Alvarado, J; Schroeder, MA; Yang, YYC; Lu, BY; Williams, N; Ceja, M; Yang, L; Cai, M; Gu, J; Xu, K; Wang, XF; Meng, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fang, Chengcheng; Li, Jinxing; Zhang, Minghao; Zhang, Yihui; Yang, Fan; Lee, Jungwoo Z.; Lee, Min-Han; Alvarado, Judith; Schroeder, Marshall A.; Yang, Yangyuchen; Lu, Bingyu; Williams, Nicholas; Ceja, Miguel; Yang, Li; Cai, Mei; Gu, Jing; Xu, Kang; Wang, Xuefeng; Meng, Ying Shirley", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quantifying inactive lithium in lithium metal batteries", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium metal anodes offer high theoretical capacities (3,860 milliampere-hours per gram)(1), but rechargeable batteries built with such anodes suffer from dendrite growth and low Coulombic efficiency (the ratio of charge output to charge input), preventing their commercial adoption(2,3). The formation of inactive ('dead') lithium- which consists of both (electro)chemically formed Li+ compounds in the solid electrolyte interphase and electrically isolated unreacted metallic Li-0 (refs(4,5))-causes capacity loss and safety hazards. Quantitatively distinguishing between Li+ in components of the solid electrolyte interphase and unreacted metallic Li-0 has not been possible, owing to the lack of effective diagnostic tools. Optical microscopy(6), in situ environmental transmission electron microscopy(7,8), X-ray microtomography(9) and magnetic resonullce imaging(10) provide a morphological perspective with little chemical information. Nuclear magnetic resonullce(11), X-ray photoelectron spectroscopy(12) and cryogenic transmission electron microscopy(13,14) can distinguish between Li+ in the solid electrolyte interphase and metallic Li-0, but their detection ranges are limited to surfaces or local regions. Here we establish the analytical method of titration gas chromatography to quantify the contribution of unreacted metallic Li-0 to the total amount of inactive lithium. We identify the unreacted metallic Li-0, not the (electro)chemically formed Li+ in the solid electrolyte interphase, as the dominullt source of inactive lithium and capacity loss. By coupling the unreacted metallic Li-0 content to observations of its local microstructure and nullostructure by cryogenic electron microscopy (both scanning and transmission), we also establish the formation mechanism of inactive lithium in different types of electrolytes and determine the underlying cause of low Coulombic efficiency in plating and stripping (the charge and discharge processes, respectively, in a full cell) of lithium metal anodes. We propose strategies for making lithium plating and stripping more efficient so that lithium metal anodes can be used for next-generation high-energy batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 817, "Times Cited, All Databases": 903, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 22", "Publication Year": 2019, "Volume": 572, "Issue": 7770, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 511, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-019-1481-z", "DOI Link": "http://dx.doi.org/10.1038/s41586-019-1481-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000482219600042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tao, HC; Choi, C; Ding, LX; Jiang, Z; Hang, ZS; Jia, MW; Fan, Q; Gao, YN; Wang, HH; Robertson, AW; Hong, S; Jung, YS; Liu, SZ; Sun, ZY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tao, Hengcong; Choi, Changhyeok; Ding, Liang-Xin; Jiang, Zheng; Hang, Zishan; Jia, Mingwen; Fan, Qun; Gao, Yunnull; Wang, Haihui; Robertson, Alex W.; Hong, Song; Jung, Yousung; Liu, Shizhen; Sun, Zhenyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nitrogen Fixation by Ru Single-Atom Electrocatalytic Reduction", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nitrogen fixation under ambient conditions remains a significant challenge. Here, we report nitrogen fixation by Ru single-atom electrocatalytic reduction at room temperature and pressure. In contrast to Ru nulloparticles, single Ru sites supported on N-doped porous carbon greatly promoted electroreduction of aqueous N-2 selectively to NH3, affording an NH3 formation rate of 3.665 mg(NH3) h(-1) mg(Ru)(-1) at -0.21 V versus the reversible hydrogen electrode. Importantly, the addition of ZrO2 was found to significantly suppress the competitive hydrogen evolution reaction. An NH3 faradic efficiency of about 21% was achieved at a low overpotential (0.17 V), surpassing many other reported catalysts. Experiments combined with density functional theory calculations showed that the Ru sites with oxygen vacancies were major active centers that permitted stabilization of *NNH, destabilization of *H, and enhanced N-2 adsorption. We envision that optimization of ZrO2 loading could further facilitate electroreduction of N-2 at both high NH3 synthesis rate and faradic efficiency.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 804, "Times Cited, All Databases": 845, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2019, "Volume": 5, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 204, "End Page": 214, "Article Number": null, "DOI": "10.1016/j.chempr.2018.10.007", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2018.10.007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455452800017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gan, DL; Xing, WS; Jiang, LL; Fang, J; Zhao, CC; Ren, FZ; Fang, LM; Wang, KF; Lu, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gan, Donglin; Xing, Wensi; Jiang, Lili; Fang, Ju; Zhao, Cancan; Ren, Fuzeng; Fang, Liming; Wang, Kefeng; Lu, Xiong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Plant-inspired adhesive and tough hydrogel based on Ag-Lignin nulloparticles-triggered dynamic redox catechol chemistry", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Adhesive hydrogels have gained popularity in biomedical applications, however, traditional adhesive hydrogels often exhibit short-term adhesiveness, poor mechanical properties and lack of antibacterial ability. Here, a plant-inspired adhesive hydrogel has been developed based on Ag-Lignin nulloparticles (NPs)triggered dynamic redox catechol chemistry. Ag-Lignin NPs construct the dynamic catechol redox system, which creates long-lasting reductive-oxidative environment inner hydrogel networks. This redox system, generating catechol groups continuously, endows the hydrogel with long-term and repeatable adhesiveness. Furthermore, Ag-Lignin NPs generate free radicals and trigger self-gelation of the hydrogel under ambient environment. This hydrogel presents high toughness for the existence of covalent and non-covalent interaction in the hydrogel networks. The hydrogel also possesses good cell affinity and high antibacterial activity due to the catechol groups and bactericidal ability of Ag-Lignin NPs. This study proposes a strategy to design tough and adhesive hydrogels based on dynamic plant catechol chemistry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 835, "Times Cited, All Databases": 867, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 2", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1487, "DOI": "10.1038/s41467-019-09351-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09351-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462985600005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mathew, K; Kolluru, VSC; Mula, S; Steinmann, SN; Hennig, RG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mathew, Kiran; Kolluru, V. S. Chaitanya; Mula, Srinidhi; Steinmann, Stephan N.; Hennig, Richard G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Implicit self-consistent electrolyte model in plane-wave density-functional theory", "Source Title": "JOURNAL OF CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The ab initio computational treatment of electrochemical systems requires an appropriate treatment of the solid/liquid interfaces. A fully quantum mechanical treatment of the interface is computationally demanding due to the large number of degrees of freedom involved. In this work, we develop a computationally efficient model where the electrode part of the interface is described at the density-functional theory (DFT) level, and the electrolyte part is represented through an implicit solvation model based on the Poisson-Boltzmann equation. We describe the implementation of the linearized Poisson-Boltzmann equation into the Vienna Ab initio Simulation Package, a widely used DFT code, followed by validation and benchmarking of the method. To demonstrate the utility of the implicit electrolyte model, we apply it to study the surface energy of Cu crystal facets in an aqueous electrolyte as a function of applied electric potential. We show that the applied potential enables the control of the shape of nullocrystals from an octahedral to a truncated octahedral morphology with increasing potential. Published under license by AIP Publishing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 829, "Times Cited, All Databases": 865, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 21", "Publication Year": 2019, "Volume": 151, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 234101, "DOI": "10.1063/1.5132354", "DOI Link": "http://dx.doi.org/10.1063/1.5132354", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000513157600004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, CF; McKeon, L; Kremer, MP; Park, SH; Ronull, O; Seral-Ascaso, A; Barwich, S; Coileáin, CO; McEvoy, N; Nerl, HC; Anasori, B; Coleman, JN; Gogotsi, Y; Nicolosi, V", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Chuanfang (John); McKeon, Lorcan; Kremer, Matthias P.; Park, Sang-Hoon; Ronull, Oskar; Seral-Ascaso, Andres; Barwich, Sebastian; Coileain, Cormac O.; McEvoy, Niall; Nerl, Hannah C.; Anasori, Babak; Coleman, Jonathan N.; Gogotsi, Yury; Nicolosi, Valeria", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Additive-free MXene inks and direct printing of micro-supercapacitors", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Direct printing of functional inks is critical for applications in diverse areas including electrochemical energy storage, smart electronics and healthcare. However, the available printable ink formulations are far from ideal. Either surfactants/additives are typically involved or the ink concentration is low, which add complexity to the manufacturing and compromises the printing resolution. Here, we demonstrate two types of two-dimensional titanium carbide (Ti3C2Tx) MXene inks, aqueous and organic in the absence of any additive or binary-solvent systems, for extrusion printing and inkjet printing, respectively. We show examples of all-MXene-printed structures, such as micro-supercapacitors, conductive tracks and ohmic resistors on untreated plastic and paper substrates, with high printing resolution and spatial uniformity. The volumetric capacitance and energy density of the all-MXene-printed micro-supercapacitors are orders of magnitude greater than existing inkjet/extrusion-printed active materials. The versatile direct-ink-printing technique highlights the promise of additive-free MXene inks for scalable fabrication of easy-to-integrate components of printable electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 802, "Times Cited, All Databases": 841, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 17", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1795, "DOI": "10.1038/s41467-019-09398-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09398-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000464976500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, K; Wei, QY; Lai, JYL; Peng, ZX; Kim, H; Yuan, J; Ye, L; Ade, H; Zou, YP; Yan, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Kui; Wei, Qingya; Lai, Joshua Yuk Lin; Peng, Zhengxing; Kim, Ha Kyung; Yuan, Jun; Ye, Long; Ade, Harald; Zou, Yingping; Yan, He", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Alkyl Chain Tuning of Small Molecule Acceptors for Efficient Organic Solar Cells", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The field of organic solar cells has seen rapid developments after the report of a high-efficiency (15.7%) small molecule acceptor (SMA) named Y6. In this paper, we design and synthesize a family of SMAs with an aromatic backbone identical to that of Y6 but with different alkyl chains to investigate the influence of alkyl chains on the properties and performance of the SMAs. First, we show that it is beneficial to use branched alkyl chains on the nitrogen atoms of the pyrrole motif of the Y6. In addition, the branching position of the alkyl chains also has a major influence on material and device properties. The SMA with 3rd-position branched alkyl chains (named N3) exhibits optimal solubility and electronic and morphological properties, thus yielding the best performance. Further device optimization using a ternary strategy allows us to achieve a high efficiency of 16.74% (and a certified efficiency of 16.42%).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 815, "Times Cited, All Databases": 838, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 18", "Publication Year": 2019, "Volume": 3, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3020, "End Page": 3033, "Article Number": null, "DOI": "10.1016/j.joule.2019.09.010", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.09.010", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000503428000012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, DY; Qiu, D; Gibson, MA; Zheng, YF; Fraser, HL; StJohn, DH; Easton, MA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Duyao; Qiu, Dong; Gibson, Mark A.; Zheng, Yufeng; Fraser, Hamish L.; StJohn, David H.; Easton, Mark A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Additive manufacturing of ultrafine-grained high-strength titanium alloys", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Additive manufacturing, often known as three-dimensional (3D) printing, is a process in which a part is built layer-by-layer and is a promising approach for creating components close to their final (net) shape. This process is challenging the dominullce of conventional manufacturing processes for products with high complexity and low material waste(1). Titanium alloys made by additive manufacturing have been used in applications in various industries. However, the intrinsic high cooling rates and high thermal gradient of the fusion-based metal additive manufacturing process often leads to a very fine microstructure and a tendency towards almost exclusively columnar grains, particularly in titanium-based alloys(1). (Columnar grains in additively manufactured titanium components can result in anisotropic mechanical properties and are therefore undesirable(2).) Attemptsto optimize the processing parameters of additive manufacturing have shown that it is difficult to alter the conditions to promote equiaxed growth of titaniumgrains(3). In contrast with other common engineering alloys such as aluminium, there is no commercial grain refiner for titanium that is able to effectively refine the microstructure. To address this challenge, here we report on the development of titanium-copper alloys that have a high constitutional supercooling capacity as a result of partitioning of the alloying element during solidification, which can override the negative effect of a high thermal gradient in the laser-melted region during additive manufacturing. Without any special process control or additional treatment, our as-printed titanium-copper alloy specimens have a fully equiaxed fine-grained microstructure. They also display promising mechanical properties, such as high yield strength and uniform elongation, compared to conventional alloys under similar processing conditions, owing to the formation of an ultrafine eutectoid microstructure that appears as a result of exploiting the high cooling rates and multiple thermal cycles of the manufacturing process. We anticipate that this approach will be applicable to other eutectoid-forming alloy systems, and that it will have applications in the aerospace and biomedical industries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 745, "Times Cited, All Databases": 798, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 5", "Publication Year": 2019, "Volume": 576, "Issue": 7785, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 91, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-019-1783-1", "DOI Link": "http://dx.doi.org/10.1038/s41586-019-1783-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000501599200046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Al-Ashouri, A; Magomedov, A; Ross, M; Jost, M; Talaikis, M; Chistiakova, G; Bertram, T; Márquez, JA; Köhnen, E; Kasparavicius, E; Levcenco, S; Gil-Escrig, L; Hages, CJ; Schlatmann, R; Rech, B; Malinauskas, T; Unold, T; Kaufmann, CA; Korte, L; Niaura, G; Getautis, V; Albrecht, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Al-Ashouri, Amran; Magomedov, Artiom; Ross, Marcel; Jost, Marko; Talaikis, Martynas; Chistiakova, Ganna; Bertram, Tobias; Marquez, Jose A.; Kohnen, Eike; Kasparavicius, Ernestas; Levcenco, Sergiu; Gil-Escrig, Lidon; Hages, Charles J.; Schlatmann, Rutger; Rech, Bernd; Malinauskas, Tadas; Unold, Thomas; Kaufmann, Christian A.; Korte, Lars; Niaura, Gediminas; Getautis, Vytautas; Albrecht, Steve", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Conformal monolayer contacts with lossless interfaces for perovskite single junction and monolithic tandem solar cells", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The rapid rise of perovskite solar cells (PSCs) is increasingly limited by the available charge-selective contacts. This work introduces two new hole-selective contacts for p-i-n PSCs that outperform all typical p-contacts in versatility, scalability and PSC power-conversion efficiency (PCE). The molecules are based on carbazole bodies with phosphonic acid anchoring groups and can form self-assembled monolayers (SAMs) on various oxides. Besides minimal material consumption and parasitic absorption, the self-assembly process enables conformal coverage of arbitrarily formed oxide surfaces with simple process control. The SAMs are designed to create an energetically aligned interface to the perovskite absorber without non-radiative losses. For three different perovskite compositions, one of which is prepared by co-evaporation, we show dopant-, additive- and interlayer-free PSCs with stabilized PCEs of up to 21.1%. Further, the conformal coverage allows to realize a monolithic CIGSe/perovskite tandem solar cell with as-deposited, rough CIGSe surface and certified efficiency of 23.26% on an active area of 1 cm(2). The simplicity and diverse substrate compatibility of the SAMs might help to further progress perovskite photovoltaics towards a low-cost, widely adopted solar technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 765, "Times Cited, All Databases": 793, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 1", "Publication Year": 2019, "Volume": 12, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3356, "End Page": 3369, "Article Number": null, "DOI": "10.1039/c9ee02268f", "DOI Link": "http://dx.doi.org/10.1039/c9ee02268f", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000494816300007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, XY; Zhao, F; Guo, YH; Rosenberger, B; Yu, GH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Xingyi; Zhao, Fei; Guo, Youhong; Rosenberger, Brian; Yu, Guihua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Architecting highly hydratable polymer networks to tune the water state for solar water purification", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Water purification by solar distillation is a promising technology to produce fresh water. However, solar vapor generation, is energy intensive, leading to a low water yield under natural sunlight. Therefore, developing new materials that can reduce the energy requirement of water vaporization and speed up solar water purification is highly desirable. Here, we introduce a highly hydratable light-absorbing hydrogel (h-LAH) consisting of polyvinyl alcohol and chitosan as the hydratable skeleton and polypyrrole as the light absorber, which can use less energy (<50% of bulk water) for water evaporation. We demonstrate that enhancing the hydrability of the h-LAH could change the water state and partially activate the water, hence facilitating water evaporation. The h-LAH raises the solar vapor generation to a record rate of similar to 3.6 kg m(-2) hour(-1) under 1 sun. The h-LAH-based solar still also exhibits long-termdurability and antifouling functionality toward complex ionic contaminullts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 772, "Times Cited, All Databases": 805, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2019, "Volume": 5, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaaw5484", "DOI": "10.1126/sciadv.aaw5484", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aaw5484", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000473798500083", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, TZ; Sun, SN; Song, JJ; Xi, SB; Du, YH; Chen, B; Sasangka, WA; Liao, HB; Gan, CL; Scherer, GG; Zeng, L; Wang, HJ; Li, H; Grimaud, A; Xu, ZJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Tianze; Sun, Shengnull; Song, Jiajia; Xi, Shibo; Du, Yonghua; Chen, Bo; Sasangka, Wardhana Aji; Liao, Hanbin; Gan, Chee Lip; Scherer, Guenther G.; Zeng, Lin; Wang, Haijiang; Li, Hui; Grimaud, Alexis; Xu, Zhichuan J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Iron-facilitated dynamic active-site generation on spinel CoAl2O4 with self-termination of surface reconstruction for water oxidation", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of efficient and low-cost electrocatalysts for the oxygen evolution reaction (OER) is critical for improving the efficiency of water electrolysis. Here, we report a strategy using Fe substitution to enable the inactive spinel CoAl2O4 to become highly active and superior to the benchmark IrO2. The Fe substitution is revealed to facilitate surface reconstruction into active Co oxyhydroxides under OER conditions. It also activates deprotonation on the reconstructed oxyhydroxide to induce negatively charged oxygen as an active site, thus significantly enhancing the OER activity of CoAl2O4. Furthermore, it promotes the pre-oxidation of Co and introduces great structural flexibility due to the uplift of the oxygen 2p levels. This results in the accumulation of surface oxygen vacancies along with lattice oxygen oxidation that terminates as Al3+ leaches, preventing further reconstruction. We showcase a promising way to achieve tunable electrochemical reconstruction by optimizing the electronic structure for low-cost and robust spinel oxide OER catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 797, "Times Cited, All Databases": 817, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2019, "Volume": 2, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 763, "End Page": 772, "Article Number": null, "DOI": "10.1038/s41929-019-0325-4", "DOI Link": "http://dx.doi.org/10.1038/s41929-019-0325-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000486144700008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, YH; Hwang, S; Cullen, DA; Uddin, MA; Langhorst, L; Li, BY; Karakalos, S; Kropf, AJ; Wegener, EC; Sokolowski, J; Chen, MJ; Myers, D; Su, D; More, KL; Wang, GF; Litster, S; Wu, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Yanghua; Hwang, Sooyeon; Cullen, David A.; Uddin, M. Aman; Langhorst, Lisa; Li, Boyang; Karakalos, Stavros; Kropf, A. Jeremy; Wegener, Evan C.; Sokolowski, Joshua; Chen, Mengjie; Myers, Debbie; Su, Dong; More, Karren L.; Wang, Guofeng; Litster, Shawn; Wu, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly active atomically dispersed CoN4 fuel cell cathode catalysts derived from surfactant-assisted MOFs: carbon-shell confinement strategy", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Development of platinum group metal (PGM)-free catalysts for oxygen reduction reaction (ORR) is essential for affordable proton exchange membrane fuel cells. Herein, a new type of atomically dispersed Co doped carbon catalyst with a core-shell structure has been developed via a surfactant-assisted metal-organic framework approach. The cohesive interactions between the selected surfactant and the Co-doped zeolitic imidazolate framework (ZIF-8) nullocrystals lead to a unique confinement effect. During the thermal activation, this confinement effect suppressed the agglomeration of Co atomic sites and mitigated the collapse of internal microporous structures of ZIF-8. Among the studied surfactants, Pluronic F127 block copolymer led to the greatest performance gains with a doubling of the active site density relative to that of the surfactant-free catalyst. According to density functional theory calculations, unlike other Co catalysts, this new atomically dispersed Co-N-C@F127 catalyst is believed to contain substantial CoN2+2 sites, which are active and thermodynamically favorable for the four-electron ORR pathway. The Co-N-C@F127 catalyst exhibits an unprecedented ORR activity with a half-wave potential (E-1/2) of 0.84 V (vs. RHE) as well as enhanced stability in the corrosive acidic media. It also demonstrated high initial performance with a power density of 0.87 W cm(-2) along with encouraging durability in H-2-O-2 fuel cells. The atomically dispersed Co site catalyst approaches that of the Fe-N-C catalyst and represents the highest reported PGM-free and Fe-free catalyst performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 741, "Times Cited, All Databases": 789, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2019, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 250, "End Page": 260, "Article Number": null, "DOI": "10.1039/c8ee02694g", "DOI Link": "http://dx.doi.org/10.1039/c8ee02694g", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457194500015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, Y; Wan, CJ; Yang, YS; Yang, H; Wang, SC; Dai, ZD; Ji, KJ; Jiang, H; Chen, XD; Long, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Yang; Wan, Changjin; Yang, Yongsheng; Yang, Hui; Wang, Shancheng; Dai, Zhendong; Ji, Keju; Jiang, Hui; Chen, Xiaodong; Long, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Stretchable, Elastic, and Ionic Conductive Hydrogel for Artificial Soft Electronics", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High conductivity, large mechanical strength, and elongation are important parameters for soft electronic applications. However, it is difficult to find a material with balanced electronic and mechanical performance. Here, a simple method is developed to introduce ion-rich pores into strong hydrogel matrix and fabricate a novel ionic conductive hydrogel with a high level of electronic and mechanical properties. The proposed ionic conductive hydrogel is achieved by physically cross-linking the tough biocompatible polyvinyl alcohol (PVA) gel as the matrix and embedding hydroxypropyl cellulose (HPC) biopolymer fibers inside matrix followed by salt solution soaking. The wrinkle and dense structure induced by salting in PVA matrix provides large stress (1.3 MPa) and strain (975%). The well-distributed porous structure as well as ion migration-facilitated ion-rich environment generated by embedded HPC fibers dramatically enhances ionic conductivity (up to 3.4 S m(-1), at f = 1 MHz). The conductive hybrid hydrogel can work as an artificial nerve in a 3D printed robotic hand, allowing passing of stable and tunable electrical signals and full recovery under robotic hand finger movements. This natural rubber-like ionic conductive hydrogel has a promising application in artificial flexible electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 771, "Times Cited, All Databases": 801, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 4", "Publication Year": 2019, "Volume": 29, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1806220, "DOI": "10.1002/adfm.201806220", "DOI Link": "http://dx.doi.org/10.1002/adfm.201806220", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000454703900029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, TT; Jiang, K; Ta, N; Hu, YF; Zeng, J; Liu, JY; Wang, HT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Tingting; Jiang, Kun; Ta, Na; Hu, Yongfeng; Zeng, Jie; Liu, Jingyue; Wang, Haotian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large-Scale and Highly Selective CO2 Electrocatalytic Reduction on Nickel Single-Atom Catalyst", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The scaling up of electrocatalytic CO2 reduction for practical applications is still hindered by a few challenges: low selectivity, small current density tomaintain a reasonable selectivity, and the cost of the catalytic materials. Here we report a facile synthesis of earth-abundant Ni single-atom catalysts on commercial carbon black, which were further employed in a gas-phase electrocatalytic reactor under ambient conditions. As a result, those single-atomic sites exhibit an extraordinary performance in reducing CO2 to CO, yielding a current density above 100 mA cm(-2), with nearly 100% selectivity for CO and around 1% toward the hydrogen evolution side reaction. By further scaling up the electrode into a 10 3 10-cm(2) modular cell, the overall current in one unit cell can easily ramp up to more than 8 A while maintaining an exclusive CO evolution with a generation rate of 3.34 L hr(-1) per unit cell.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 716, "Times Cited, All Databases": 755, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 16", "Publication Year": 2019, "Volume": 3, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 265, "End Page": 278, "Article Number": null, "DOI": "10.1016/j.joule.2018.10.015", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2018.10.015", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457552800023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kerelsky, A; McGilly, LJ; Kennes, DM; Xian, LD; Yankowitz, M; Chen, SW; Watanabe, K; Taniguchi, T; Hone, J; Dean, C; Rubio, A; Pasupathy, AN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kerelsky, Alexander; McGilly, Leo J.; Kennes, Dante M.; Xian, Lede; Yankowitz, Matthew; Chen, Shaowen; Watanabe, K.; Taniguchi, T.; Hone, James; Dean, Cory; Rubio, Angel; Pasupathy, Abhay N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Maximized electron interactions at the magic angle in twisted bilayer graphene", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electronic properties of heterostructures of atomically thin van der Waals crystals can be modified substantially by moire superlattice potentials from an interlayer twist between crystals(1,2). Moire tuning of the band structure has led to the recent discovery of superconductivity(3,4) and correlated insulating phases5 in twisted bilayer graphene (TBG) near the 'magic angle' of twist of about 1.1 degrees, with a phase diagram reminiscent of high-transition-temperature superconductors. Here we directly map the atomic-scale structural and electronic properties of TBG near the magic angle using scanning tunnelling microscopy and spectroscopy. We observe two distinct van Hove singularities (VHSs) in the local density of states around the magic angle, with an energy separation of 57 millielectronvolts that drops to 40 millielectronvolts with high electron/hole doping. Unexpectedly, the VHS energy separation continues to decrease with decreasing twist angle, with a lowest value of 7 to 13 millielectronvolts at a magic angle of 0.79 degrees. More crucial to the correlated behaviour of this material, we find that at the magic angle, the ratio of the Coulomb interaction to the bandwidth of each individual VHS (U/t) is maximized, which is optimal for electronic Cooper pairing mechanisms. When doped near the half-moire-band filling, a correlation-induced gap splits the conduction VHS with a maximum size of 6.5 millielectronvolts at 1.15 degrees, dropping to 4 millielectronvolts at 0.79 degrees. We capture the doping-dependent and angle-dependent spectroscopy results using a Hartree-Fock model, which allows us to extract the on-site and nearest-neighbour Coulomb interactions. This analysis yields a U/t of order unity indicating that magic-angle TBG is moderately correlated. In addition, scanning tunnelling spectroscopy maps reveal an energy-and doping-dependent threefold rotational-symmetry breaking of the local density of states in TBG, with the strongest symmetry breaking near the Fermi level and further enhanced when doped to the correlated gap regime. This indicates the presence of a strong electronic nematic susceptibility or even nematic order in TBG in regions of the phase diagram where superconductivity is observed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 730, "Times Cited, All Databases": 800, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 1", "Publication Year": 2019, "Volume": 572, "Issue": 7767, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 95, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-019-1431-9", "DOI Link": "http://dx.doi.org/10.1038/s41586-019-1431-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000478017900042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Z; Huang, JH; Guo, ZW; Dong, XL; Liu, Y; Wang, YG; Xia, YY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Zhuo; Huang, Jianhang; Guo, Zhaowei; Dong, Xiaoli; Liu, Yao; Wang, Yonggang; Xia, Yongyao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A Metal-Organic Framework Host for Highly Reversible Dendrite-free Zinc Metal Anodes", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Zinc metal featuring low cost, high capacity, low potential, and environmental benignity is an exciting anode material for aqueous energy storage devices. Unfortunately, the dendrite growth, limited reversibility, and undesired hydrogen evolution hinder its application. Herein, we demonstrate that MOF ZIF-8 annealed at 500 degrees C (ZIF-8-500) can be used as a host material for high-efficiency (approximately 100%) and dendrite-free Zn plating and stripping because of its porous structure, trace amount of zinc in the framework, and high over-potential for hydrogen evolution. The Zn@ZIF-8-500 anode (i.e., ZIF-8-500 pre-plated with 10.0 mAh cm(-2) Zn) is coupled with an activated carbon cathode or an I-2 cathode to form a hybrid supercapacitor or a rechargeable battery, respectively. The supercapacitor delivers a high energy density of 140.8 Wh kg(-1) (normalized to the mass of active materials in electrodes) while retaining 72% capacity over 20,000 cycles, and the battery shows a long life of 1,600 cycles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 753, "Times Cited, All Databases": 780, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2019, "Volume": 3, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1289, "End Page": 1300, "Article Number": null, "DOI": "10.1016/j.joule.2019.02.012", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.02.012", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000467969300015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, L; Zhang, Y; Huang, LB; Liu, XZ; Zhang, QH; He, C; Wu, ZY; Zhang, LJ; Wu, JP; Yang, WL; Gu, L; Hu, JS; Wan, LJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Lu; Zhang, Yun; Huang, Lin-Bo; Liu, Xiao-Zhi; Zhang, Qing-Hua; He, Chao; Wu, Ze-Yuan; Zhang, Lin-Juan; Wu, Jinpeng; Yang, Wanli; Gu, Lin; Hu, Jin-Song; Wan, Li-Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cascade anchoring strategy for general mass production of high-loading single-atomic metal-nitrogen catalysts", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although single-atomically dispersed metal-N-x on carbon support (M-NC) has great potential in heterogeneous catalysis, the scalable synthesis of such single-atom catalysts (SACs) with high-loading metal-Nx is greatly challenging since the loading and single-atomic dispersion have to be balanced at high temperature for forming metal-Nx. Herein, we develop a general cascade anchoring strategy for the mass production of a series of M-NC SACs with a metal loading up to 12.1 wt%. Systematic investigation reveals that the chelation of metal ions, physical isolation of chelate complex upon high loading, and the binding with N-species at elevated temperature are essential to achieving high-loading M-NC SACs. As a demonstration, high-loading Fe-NC SAC shows superior electrocatalytic performance for O-2 reduction and Ni-NC SAC exhibits high electrocatalytic activity for CO2 reduction. The strategy paves a universal way to produce stable M-NC SAC with high-density metal-N-x sites for diverse high-performance applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 713, "Times Cited, All Databases": 736, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 20", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1278, "DOI": "10.1038/s41467-019-09290-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09290-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000461757800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Stolterfoht, M; Caprioglio, P; Wolff, CM; Márquez, JA; Nordmann, J; Zhang, SS; Rothhardt, D; Hörmann, U; Amir, Y; Redinger, A; Kegelmann, L; Zu, FS; Albrecht, S; Koch, N; Kirchartz, T; Saliba, M; Unold, T; Neher, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Stolterfoht, Martin; Caprioglio, Pietro; Wolff, Christian M.; Marquez, Jose A.; Nordmann, Joleik; Zhang, Shanshan; Rothhardt, Daniel; Hoermann, Ulrich; Amir, Yohai; Redinger, Alex; Kegelmann, Lukas; Zu, Fengshuo; Albrecht, Steve; Koch, Norbert; Kirchartz, Thomas; Saliba, Michael; Unold, Thomas; Neher, Dieter", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The impact of energy alignment and interfacial recombination on the internal and external open-circuit voltage of perovskite solar cells", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Charge transport layers (CTLs) are key components of diffusion controlled perovskite solar cells, however, they can induce additional non-radiative recombination pathways which limit the open circuit voltage (V-OC) of the cell. In order to realize the full thermodynamic potential of the perovskite absorber, both the electron and hole transport layer (ETL/HTL) need to be as selective as possible. By measuring the photoluminescence yield of perovskite/CTL heterojunctions, we quantify the non-radiative interfacial recombination currents in pin- and nip-type cells including high efficiency devices (21.4%). Our study comprises a wide range of commonly used CTLs, including various hole-transporting polymers, spiro-OMeTAD, metal oxides and fullerenes. We find that all studied CTLs limit the V-OC by inducing an additional non-radiative recombination current that is in most cases substantially larger than the loss in the neat perovskite and that the least-selective interface sets the upper limit for the V-OC of the device. Importantly, the V-OC equals the internal quasi-Fermi level splitting (QFLS) in the absorber layer only in high efficiency cells, while in poor performing devices, the V-OC is substantially lower than the QFLS. Using ultraviolet photoelectron spectroscopy and differential charging capacitance experiments we show that this is due to an energy level mis-alignment at the p-interface. The findings are corroborated by rigorous device simulations which outline important considerations to maximize the V-OC. This work highlights that the challenge to suppress non-radiative recombination losses in perovskite cells on their way to the radiative limit lies in proper energy level alignment and in suppression of defect recombination at the interfaces.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 704, "Times Cited, All Databases": 726, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2019, "Volume": 12, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2778, "End Page": 2788, "Article Number": null, "DOI": "10.1039/c9ee02020a", "DOI Link": "http://dx.doi.org/10.1039/c9ee02020a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000486019600011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, C; Niu, XX; Fu, YH; Li, NX; Hu, C; Chen, YH; He, X; Na, GR; Liu, PF; Zai, HC; Ge, Y; Lu, Y; Ke, XX; Bai, Y; Yang, SH; Chen, PW; Li, YJ; Sui, ML; Zhang, LJ; Zhou, HP; Chen, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Cheng; Niu, Xiuxiu; Fu, Yuhao; Li, Nengxu; Hu, Chen; Chen, Yihua; He, Xin; Na, Guangren; Liu, Pengfei; Zai, Huachao; Ge, Yang; Lu, Yue; Ke, Xiaoxing; Bai, Yang; Yang, Shihe; Chen, Pengwan; Li, Yujing; Sui, Manling; Zhang, Lijun; Zhou, Huanping; Chen, Qi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strain engineering in perovskite solar cells and its impacts on carrier dynamics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The mixed halide perovskites have emerged as outstanding light absorbers for efficient solar cells. Unfortunately, it reveals inhomogeneity in these polycrystalline films due to composition separation, which leads to local lattice mismatches and emergent residual strains consequently. Thus far, the understanding of these residual strains and their effects on photovoltaic device performance is absent. Herein we study the evolution of residual strain over the films by depth-dependent grazing incident X-ray diffraction measurements. We identify the gradient distribution of in-plane strain component perpendicular to the substrate. Moreover, we reveal its impacts on the carrier dynamics over corresponding solar cells, which is stemmed from the strain induced energy bands bending of the perovskite absorber as indicated by first-principles calculations. Eventually, we modulate the status of residual strains in a controllable manner, which leads to enhanced PCEs up to 20.7% (certified) in devices via rational strain engineering.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 763, "Times Cited, All Databases": 799, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 18", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 815, "DOI": "10.1038/s41467-019-08507-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-08507-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000458864600018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qiu, HY; Du, XF; Zhao, JW; Wang, YT; Ju, JW; Chen, Z; Hu, ZL; Yan, DP; Zhou, XH; Cui, GL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qiu, Huayu; Du, Xiaofan; Zhao, Jingwen; Wang, Yantao; Ju, Jiangwei; Chen, Zheng; Hu, Zhenglin; Yan, Dongpeng; Zhou, Xinhong; Cui, Guanglei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Zinc anode-compatible in-situ solid electrolyte interphase via cation solvation modulation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The surface chemistry of solid electrolyte interphase is one of the critical factors that govern the cycling life of rechargeable batteries. However, this chemistry is less explored for zinc anodes, owing to their relatively high redox potential and limited choices in electrolyte. Here, we report the observation of a zinc fluoride-rich organic/inorganic hybrid solid electrolyte interphase on zinc anode, based on an acetamide-Zn(TFSI)(2) eutectic electrolyte. A combination of experimental and modeling investigations reveals that the presence of anioncomplexing zinc species with markedly lowered decomposition energies contributes to the in situ formation of an interphase. The as-protected anode enables reversible (similar to 100% Coulombic efficiency) and dendrite-free zinc plating/stripping even at high areal capacities (>2.5 mAh cm(-2)), endowed by the fast ion migration coupled with high mechanical strength of the protective interphase. With this interphasial design the assembled zinc batteries exhibit excellent cycling stability with negligible capacity loss at both low and high rates.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 697, "Times Cited, All Databases": 716, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 26", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5374, "DOI": "10.1038/s41467-019-13436-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-13436-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000498795200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, PJ; Ren, WL; Zheng, TX; Ren, ZM; Hou, XL; Peng, JC; Hu, PF; Gao, YF; Zhong, YB; Liaw, PK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Peijian; Ren, Weili; Zheng, Tianxiang; Ren, Zhongming; Hou, Xueling; Peng, Jianchao; Hu, Pengfei; Gao, Yanfei; Zhong, Yunbo; Liaw, Peter K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced strength-ductility synergy in ultrafine-grained eutectic high-entropy alloys by inheriting microstructural lamellae", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Realizing improved strength-ductility synergy in eutectic alloys acting as in situ composite materials remains a challenge in conventional eutectic systems, which is why eutectic high-entropy alloys (EHEAs), a newly-emerging multi-principal-element eutectic category, may offer wider in situ composite possibilities. Here, we use an AlCoCrFeNi2.1 EHEA to engineer an ultrafine-grained duplex microstructure that deliberately inherits its composite lamellar nature by tailored thermo-mechanical processing to achieve property combinations which are not accessible to previously-reported reinforcement methodologies. The as-prepared samples exhibit hierarchically-structural heterogeneity due to phase decomposition, and the improved mechanical response during deformation is attributed to both a two-hierarchical constraint effect and a self-generated microcrack-arresting mechanism. This work provides a pathway for strengthening eutectic alloys and widens the design toolbox for high-performance materials based upon EHEAs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 703, "Times Cited, All Databases": 737, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 30", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 489, "DOI": "10.1038/s41467-019-08460-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-08460-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000457130800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fan, XL; Ji, X; Chen, L; Chen, J; Deng, T; Han, FD; Yue, J; Piao, N; Wang, RX; Zhou, XQ; Xiao, XZ; Chen, LX; Wang, CS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fan, Xiulin; Ji, Xiao; Chen, Long; Chen, Ji; Deng, Tao; Han, Fudong; Yue, Jie; Piao, null; Wang, Ruixing; Zhou, Xiuquan; Xiao, Xuezhang; Chen, Lixin; Wang, Chunsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "All-temperature batteries enabled by fluorinated electrolytes with non-polar solvents", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbonate electrolytes are commonly used in commercial non-aqueous Li-ion batteries. However, the high affinity between the solvents and the ions and high flammability of the carbonate electrolytes limits the battery operation temperature window to -20 to + 50 degrees C and the voltage window to 0.0 to 4.3 V. Here, we tame the affinity between solvents and Li ions by dissolving fluorinated electrolytes into highly fluorinated non-polar solvents. In addition to their non-flammable characteristic, our electrolytes enable high electrochemical stability in a wide voltage window of 0.0 to 5.6 V, and high ionic conductivities in a wide temperature range from -125 to + 70 degrees C. We show that between -95 and + 70 degrees C, the electrolytes enable LiNi0.8Co0.15Al0.05O2 cathodes to achieve high Coulombic efficiencies of >99.9%, and the aggressive Li anodes and the high-voltage (5.4 V) LiCoMnO4 to achieve Coulombic efficiencies of >99.4% and 99%, respectively. Even at -85 degrees C, the LiNi0.8Co0.15Al0.05O2 parallel to Li battery can still deliver similar to 50% of its room-temperature capacity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 696, "Times Cited, All Databases": 750, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2019, "Volume": 4, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 882, "End Page": 890, "Article Number": null, "DOI": "10.1038/s41560-019-0474-3", "DOI Link": "http://dx.doi.org/10.1038/s41560-019-0474-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000489768100019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, JN; Li, QH; Ouyang, CY; Yu, XQ; Ge, MY; Huang, XJ; Hu, EY; Ma, C; Li, SF; Xiao, RJ; Yang, WL; Chu, Y; Liu, YJ; Yu, HG; Yang, XQ; Huang, XJ; Chen, LQ; Li, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jie-null; Li, Qinghao; Ouyang, Chuying; Yu, Xiqian; Ge, Mingyuan; Huang, Xiaojing; Hu, Enyuan; Ma, Chao; Li, Shaofeng; Xiao, Ruijuan; Yang, Wanli; Chu, Yong; Liu, Yijin; Yu, Huigen; Yang, Xiao-Qing; Huang, Xuejie; Chen, Liquan; Li, Hong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Trace doping of multiple elements enables stable battery cycling of LiCoO2 at 4.6V", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "LiCoO2 is a dominullt cathode material for lithium-ion (Li-ion) batteries due to its high volumetric energy density, which could potentially be further improved by charging to high voltages. However, practical adoption of high-voltage charging is hindered by LiCoO2 's structural instability at the deeply delithiated state and the associated safety concerns. Here, we achieve stable cycling of LiCoO2 at 4.6V (versus Li/Li+) through trace Ti-Mg-Al co-doping. Using state-of-the-art synchrotron X-ray imaging and spectroscopic techniques, we report the incorporation of Mg and Al into the LiCoO2 lattice, which inhibits the undesired phase transition at voltages above 4.5 V. We also show that, even in trace amounts, Ti segregates significantly at grain boundaries and on the surface, modifying the microstructure of the particles while stabilizing the surface oxygen at high voltages. These dopants contribute through different mechanisms and synergistically promote the cycle stability of LiCoO2 at 4.6 V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 688, "Times Cited, All Databases": 732, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2019, "Volume": 4, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 594, "End Page": 603, "Article Number": null, "DOI": "10.1038/s41560-019-0409-z", "DOI Link": "http://dx.doi.org/10.1038/s41560-019-0409-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000474920100016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ren, XD; Zou, LF; Cao, X; Engelhard, MH; Liu, W; Burton, SD; Lee, H; Niu, CJ; Matthews, BE; Zhu, ZH; Wang, CM; Arey, BW; Xiao, J; Liu, J; Zhang, JG; Xu, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ren, Xiaodi; Zou, Lianfeng; Cao, Xia; Engelhard, Mark H.; Liu, Wen; Burton, Sarah D.; Lee, Hongkyung; Niu, Chaojiang; Matthews, Bethany E.; Zhu, Zihua; Wang, Chongmin; Arey, Bruce W.; Xiao, Jie; Liu, Jun; Zhang, Ji-Guang; Xu, Wu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enabling High-Voltage Lithium-Metal Batteries under Practical Conditions", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable lithium (Li)-metal batteries (LMBs) offer a great opportunity for applications needing high-energy-density battery systems. However, rare progress has been demonstrated so far under practical conditions, including high voltage, high-loading cathode, thin Li anode, and lean electrolyte. Here, in opposition to common wisdom, we report an ether-based localized high-concentration electrolyte that can greatly enhance the stability of a Ni-rich LiNi0.8Mn0.1Co0.1O2 (NMC811) cathode under 4.4 and 4.5 V with an effective protection interphase enriched in LiF. This effect, in combination with the superior Li stability in this electrolyte, enables dramatically improved cycling performances of Li parallel to NMC811 batteries under highly challenging conditions. The LMBs can retain over 80% capacity in 150 stable cycles with extremely limited amounts of the Li anode and electrolyte. The findings in this work point out a very promising strategy to develop practical high-energy LMBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 728, "Times Cited, All Databases": 767, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 17", "Publication Year": 2019, "Volume": 3, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1662, "End Page": 1676, "Article Number": null, "DOI": "10.1016/j.joule.2019.05.006", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2019.05.006", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000476463300010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, DQ; Shi, MJ; Zhu, TS; Xing, DY; Zhang, HJ; Wang, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Dongqin; Shi, Minji; Zhu, Tongshuai; Xing, Dingyu; Zhang, Haijun; Wang, Jing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topological Axion States in the Magnetic Insulator MnBi2Te4 with the Quantized Magnetoelectric Effect", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Topological states of quantum matter have attracted great attention in condensed matter physics and materials science. The study of time-reversal-invariant topological states in quantum materials has made tremendous progress. However, the study of magnetic topological states falls much behind due to the complex magnetic structures. Here, we predict the tetradymite-type compound MnBi2Te4 and its related materials host topologically nontrivial magnetic states. The magnetic ground state of MnBi2Te4 is an antiferromagetic topological insulator state with a large topologically nontrivial energy gap (similar to 0.2 eV). It presents the axion state, which has gapped bulk and surface states, and the quantized topological magnetoelectric effect. The ferromagnetic phase of MnBi2Te4 might lead to a minimal ideal Weyl semimetal.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 672, "Times Cited, All Databases": 743, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 20", "Publication Year": 2019, "Volume": 122, "Issue": 20, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 206401, "DOI": "10.1103/PhysRevLett.122.206401", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.122.206401", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000469032700008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lothenbach, B; Kulik, DA; Matschei, T; Balonis, M; Baquerizo, L; Dilnesa, B; Miron, GD; Myers, RJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lothenbach, Barbara; Kulik, Dmitrii A.; Matschei, Thomas; Balonis, Magdalena; Baquerizo, Luis; Dilnesa, Belay; Miron, George D.; Myers, Rupert J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Cemdata 18: A chemical thermodynamic database for hydrated Portland cements and alkali-activated materials", "Source Title": "CEMENT AND CONCRETE RESEARCH", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermodynamic modelling can reliably predict hydrated cement phase assemblages and chemical compositions, including their interactions with prevailing service environments, provided an accurate and complete thermodynamic database is used. Here, we summarise the Cemdata18 database, which has been developed specifically for hydrated Portland, calcium aluminate, calcium sulfoaluminate and blended cements, as well as for alkali activated materials. It is available in GEMS and PHREEQC computer program formats, and includes thermodynamic properties determined from various experimental data published in recent years. Cemdata18 contains thermodynamic data for common cement hydrates such as C-S-H, AFm and AFt phases, hydrogarnet, hydrotalcite, zeolites, and M-S-H that are valid over temperatures ranging from 0 to at least 100 degrees C. Solid solution models for AFm, AFt, C-S-H, and M-S-H are also included in the Cemdata18 database.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 750, "Times Cited, All Databases": 780, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2019, "Volume": 115, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 472, "End Page": 506, "Article Number": null, "DOI": "10.1016/j.cemconres.2018.04.018", "DOI Link": "http://dx.doi.org/10.1016/j.cemconres.2018.04.018", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Construction & Building Technology; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000452935100041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, Y; Kim, JC; Wu, RJ; Martinez, J; Song, XJ; Yang, J; Zhao, F; Mkhoyan, KA; Jeong, HY; Chhowalla, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yan; Kim, Jong Chan; Wu, Ryan J.; Martinez, Jenny; Song, Xiuju; Yang, Jieun; Zhao, Fang; Mkhoyan, K. Andre; Jeong, Hu Young; Chhowalla, Manish", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Van der Waals contacts between three-dimensional metals and two-dimensional semiconductors", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As the dimensions of the semiconducting channels in fieldeffect transistors decrease, the contact resistance of the metalsemiconductor interface at the source and drain electrodes increases, dominating the performance of devices(1-3). Two-dimensional (2D) transition-metal dichalcogenides such as molybdenum disulfide (MoS2) have been demonstrated to be excellent semiconductors for ultrathin field-effect transistors(4,5). However, unusually high contact resistance has been observed across the interface between the metal and the 2D transition-metal dichalcogenide(3,5-9). Recent studies have shown that van der Waals contacts formed by transferred graphene(10,11) and metals(12) on few-layered transitionmetal dichalcogenides produce good contact properties. However, van der Waals contacts between a three-dimensional metal and a monolayer 2D transition-metal dichalcogenide have yet to be demonstrated. Here we report the realization of ultraclean van der Waals contacts between 10-nullometre-thick indium metal capped with 100-nullometre-thick gold electrodes and monolayer MoS2. Using scanning transmission electron microscopy imaging, we show that the indium and gold layers form a solid solution after annealing at 200 degrees Celsius and that the interface between the gold-capped indium and the MoS2 is atomically sharp with no detectable chemical interaction between the metal and the 2D transition-metal dichalcogenide, suggesting van-der-Waals-type bonding between the gold-capped indium and monolayer MoS2. The contact resistance of the indium/gold electrodes is 3,000 +/- 300 ohm micrometres for monolayer MoS2 and 800 +/- 200 ohm micrometres for few-layered MoS2. These values are among the lowest observed for three-dimensional metal electrodes evaporated onto MoS2, enabling high-performance field-effect transistors with a mobility of 167 +/- 20 square centimetres per volt per second. We also demonstrate a low contact resistance of 220 +/- 50 ohm micrometres on ultrathin niobium disulfide (NbS2) and near-ideal band offsets, indicative of defect-free interfaces, in tungsten disulfide (WS2) and tungsten diselenide (WSe2) contacted with indium alloy. Our work provides a simple method of making ultraclean van der Waals contacts using standard laboratory technology on monolayer 2D semiconductors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 653, "Times Cited, All Databases": 712, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 4", "Publication Year": 2019, "Volume": 568, "Issue": 7750, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 70, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-019-1052-3", "DOI Link": "http://dx.doi.org/10.1038/s41586-019-1052-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000463384900041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, XT; Liang, ET; Yuan, JJ; Qiu, HY; Chen, XD; Zhao, FL; Dong, JW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Xin-Tao; Liang, En-Tao; Yuan, Jia-Jun; Qiu, Hao-Yang; Chen, Xiao-Dong; Zhao, Fu-Li; Dong, Jian-Wen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A silicon-on-insulator slab for topological valley transport", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Backscattering suppression in silicon-on-insulator (SOI) is one of the central issues to reduce energy loss and signal distortion, enabling for capability improvement of modern information processing systems. Valley physics provides an intriguing way for robust information transfer and unidirectional coupling in topological nullophotonics. Here we realize topological transport in a SOI valley photonic crystal slab. Localized Berry curvature near zone corners guarantees the existence of valley-dependent edge states below light cone, maintaining in-plane robustness and light confinement simultaneously. Topologically robust transport at telecommunication is observed along two sharp-bend interfaces in subwavelength scale, showing flat-top high transmission of similar to 10% bandwidth. Topological photonic routing is achieved in a bearded-stack interface, due to unidirectional excitation of valley-chirality-locked edge state from the phase vortex of a nulloscale microdisk. These findings show the prototype of robustly integrated devices, and open a new door towards the observation of non-trivial states even in non-Hermitian systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 652, "Times Cited, All Databases": 702, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 20", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 872, "DOI": "10.1038/s41467-019-08881-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-08881-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000459097100007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xue, TY; Liang, WY; Li, YW; Sun, YH; Xiang, YJ; Zhang, YP; Dai, ZG; Duo, YH; Wu, LM; Qi, K; Shiyanullju, BN; Zhang, LJ; Cui, XQ; Zhang, H; Bao, QL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xue, Tianyu; Liang, Weiyuan; Li, Yawen; Sun, Yuanhui; Xiang, Yuanjiang; Zhang, Yupeng; Dai, Zhigao; Duo, Yanhong; Wu, Leiming; Qi, Kun; Shiyanullju, Bannur nulljunda; Zhang, Lijun; Cui, Xiaoqiang; Zhang, Han; Bao, Qiaoliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrasensitive detection of miRNA with an antimonene-based surface plasmon resonullce sensor", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MicroRNA exhibits differential expression levels in cancer and can affect cellular transformation, carcinogenesis and metastasis. Although fluorescence techniques using dye molecule labels have been studied, label-free molecular-level quantification of miRNA is extremely challenging. We developed a surface plasmon resonullce sensor based on two-dimensional nullomaterial of antimonene for the specific label-free detection of clinically relevant biomarkers such as miRNA-21 and miRNA-155. First-principles energetic calculations reveal that antimonene has substantially stronger interaction with ssDNA than the graphene that has been previously used in DNA molecule sensing, due to thanking for more delocalized 5s/5p orbitals in antimonene. The detection limit can reach 10 aM, which is 2.3-10,000 times higher than those of existing miRNA sensors. The combination of not-attempted-before exotic sensing material and SPR architecture represents an approach to unlocking the ultrasensitive detection of miRNA and DNA and provides a promising avenue for the early diagnosis, staging, and monitoring of cancer.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 665, "Times Cited, All Databases": 693, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 3", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 28, "DOI": "10.1038/s41467-018-07947-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-07947-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000454756900005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, M; Ju, MG; Garces, HF; Carl, AD; Ono, LK; Hawash, Z; Zhang, Y; Shen, TY; Qi, YB; Grimm, RL; Pacifici, D; Zeng, XC; Zhou, YY; Padture, NP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Min; Ju, Ming-Gang; Garces, Hector F.; Carl, Alexander D.; Ono, Luis K.; Hawash, Zafer; Zhang, Yi; Shen, Tianyi; Qi, Yabing; Grimm, Ronald L.; Pacifici, Domenico; Zeng, Xiao Cheng; Zhou, Yuanyuan; Padture, Nitin P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly stable and efficient all-inorganic lead-free perovskite solar cells with native-oxide passivation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "There has been an urgent need to eliminate toxic lead from the prevailing halide perovskite solar cells (PSCs), but the current lead-free PSCs are still plagued with the critical issues of low efficiency and poor stability. This is primarily due to their inadequate photovoltaic properties and chemical stability. Herein we demonstrate the use of the lead-free, all-inorganic cesium tin-germanium triiodide (CsSn(0.5)Ge(0.5)l(3)) solid-solution perovskite as the light absorber in PSCs, delivering promising efficiency of up to 7.11%. More importantly, these PSCs show very high stability, with less than 10% decay in efficiency after 500 h of continuous operation in N-2 atmosphere under one-sun illumination. The key to this striking performance of these PSCs is the formation of a full-coverage, stable native-oxide layer, which fully encapsulates and passivates the perovskite surfaces. The native-oxide passivation approach reported here represents an alternate avenue for boosting the efficiency and stability of lead-free PSCs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 629, "Times Cited, All Databases": 690, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 3", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 16, "DOI": "10.1038/s41467-018-07951-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-07951-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000454756600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kuang, Y; Kenney, MJ; Meng, YT; Hung, WH; Liu, YJ; Huang, JE; Prasanna, R; Li, PS; Li, YP; Wang, L; Lin, MC; McGehee, MD; Sun, XM; Dai, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kuang, Yun; Kenney, Michael J.; Meng, Yongtao; Hung, Wei-Hsuan; Liu, Yijin; Huang, Jianull Erick; Prasanna, Rohit; Li, Pengsong; Li, Yaping; Wang, Lei; Lin, Meng-Chang; McGehee, Michael D.; Sun, Xiaoming; Dai, Hongjie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solar-driven, highly sustained splitting of seawater into hydrogen and oxygen fuels", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrolysis of water to generate hydrogen fuel is an attractive renewable energy storage technology. However, grid-scale freshwater electrolysis would put a heavy strain on vital water resources. Developing cheap electrocatalysts and electrodes that can sustain seawater splitting without chloride corrosion could address the water scarcity issue. Here we present a multilayer anode consisting of a nickel-iron hydroxide (NiFe) electrocatalyst layer uniformly coated on a nickel sulfide (NiSx) layer formed on porous Ni foam (NiFe/NiSx-Ni), affording superior catalytic activity and corrosion resistance in solar-driven alkaline seawater electrolysis operating at industrially required current densities (0.4 to 1 A/cm(2)) over 1,000 h. A continuous, highly oxygen evolution reaction-active NiFe electrocatalyst layer drawing anodic currents toward water oxidation and an in situ-generated polyatomic sulfate and carbonate-rich passivating layers formed in the anode are responsible for chloride repelling and superior corrosion resistance of the salty-water-splitting anode.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 652, "Times Cited, All Databases": 686, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 2", "Publication Year": 2019, "Volume": 116, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6624, "End Page": 6629, "Article Number": null, "DOI": "10.1073/pnas.1900556116", "DOI Link": "http://dx.doi.org/10.1073/pnas.1900556116", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000463069900024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, S; Dai, J; Yu, ZH; Shao, YC; Zhou, Y; Xiao, X; Zeng, XC; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Shuang; Dai, Jun; Yu, Zhenhua; Shao, Yuchuan; Zhou, Yu; Xiao, Xun; Zeng, Xiao Cheng; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tailoring Passivation Molecular Structures for Extremely Small Open-Circuit Voltage Loss in Perovskite Solar Cells", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Passivation of electronic defects at the surface and grain boundaries of perovskite materials has become one of the most important strategies to suppress charge recombination in both polycrystalline and single-crystalline perovskite solar cells. Although many passivation molecules have been reported, it remains very unclear regarding the passivation mechanisms of various functional groups. Here, we systematically engineer the structures of passivation molecular functional groups, including carboxyl, amine, isopropyl, phenethyl, and tert-butylphenethyl groups, and study their passivation capability to perovskites. It reveals the carboxyl and amine groups would heal charged defects via electrostatic interactions, and the neutral iodine related defects can be reduced by the aromatic structures. The judicious control of the interaction between perovskite and molecules can further realize grain boundary passivation, including those that are deep toward substrates. Understanding of the underlining mechanisms allows us to design a new passivation molecule, D-4-tert-butylphenylalanine, yielding high-performance p-i-structure solar cells with a stabilized efficiency of 21.4%. The open-circuit voltage (V-OC) of a device with an optical bandgap of 1.57 eV for the perovskite layer reaches 1.23 V, corresponding to a record small V-OC deficit of 0.34 V. Our findings provide a guidance for future design of new passivation molecules to realize multiple facets applications in perovskite electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 644, "Times Cited, All Databases": 674, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 10", "Publication Year": 2019, "Volume": 141, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 5781, "End Page": 5787, "Article Number": null, "DOI": "10.1021/jacs.8b13091", "DOI Link": "http://dx.doi.org/10.1021/jacs.8b13091", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000464769000030", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, CG; Wang, M; Xu, TZ; Zhang, XX; Lin, C; Gao, WY; Xu, HZ; Lei, B; Mao, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Chenggui; Wang, Min; Xu, Tianzhen; Zhang, Xingxing; Lin, Cai; Gao, Weiyang; Xu, Huazi; Lei, Bo; Mao, Cong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering Bioactive Self-Healing Antibacterial Exosomes Hydrogel for Promoting Chronic Diabetic Wound Healing and Complete Skin Regeneration", "Source Title": "THERANOSTICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rationale: Chronic nonhealing diabetic wound therapy and complete skin regeneration remains a critical clinical challenge. The controlled release of bioactive factors from a multifunctional hydrogel was a promising strategy to repair chronic wounds. Methods: Herein, for the first time, we developed an injectable, self-healing and antibacterial polypeptide-based FHE hydrogel (F127/OHA-EPL) with stimuli-responsive adipose-derived mesenchymal stem cells exosomes (AMSCs-exo) release for synergistically enhancing chronic wound healing and complete skin regeneration. The materials characterization, antibacterial activity, stimulated cellular behavior and in vivo full-thickness diabetic wound healing ability of the hydrogels were performed and analyzed. Results: The FHE hydrogel possessed multifunctional properties including fast self-healing process, shear-thinning injectable ability, efficient antibacterial activity, and long term pH-responsive bioactive exosomes release behavior. In vitro, the FHE@exosomes (FHE@exo) hydrogel significantly promoted the proliferation, migration and tube formation ability of human umbilical vein endothelial cells (HUVECs). In vivo, the FHE@exo hydrogel significantly enhanced the healing efficiency of diabetic full-thickness cutaneous wounds, characterized with enhanced wound closure rates, fast angiogenesis, re-epithelization and collagen deposition within the wound site. Moreover, the FHE@exo hydrogel displayed better healing outcomes than those of exosomes or FHE hydrogel alone, suggesting that the sustained release of exosomes and FHE hydrogel can synergistically facilitate diabetic wound healing. Skin appendages and less scar tissue also appeared in FHE@exo hydrogel treated wounds, indicating its potent ability to achieve complete skin regeneration. Conclusion: This work offers a new approach for repairing chronic wounds completely through a multifunctional hydrogel with controlled exosomes release.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 648, "Times Cited, All Databases": 679, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": null, "Publication Year": 2019, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 65, "End Page": 76, "Article Number": null, "DOI": "10.7150/thno.29766", "DOI Link": "http://dx.doi.org/10.7150/thno.29766", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Research & Experimental Medicine", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000452508600006", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Blaha, P; Schwarz, K; Tran, F; Laskowski, R; Madsen, GKH; Marks, LD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Blaha, Peter; Schwarz, Karlheinz; Tran, Fabien; Laskowski, Robert; Madsen, Georg K. H.; Marks, Laurence D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "WIEN2k: An APW+lo program for calculating the properties of solids", "Source Title": "JOURNAL OF CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The WIEN2k program is based on the augmented plane wave plus local orbitals (APW+lo) method to solve the Kohn-Sham equations of density functional theory. The APW+lo method, which considers all electrons (core and valence) self-consistently in a full-potential treatment, is implemented very efficiently in WIEN2k, since various types of parallelization are available and many optimized numerical libraries can be used. Many properties can be calculated, ranging from the basic ones, such as the electronic band structure or the optimized atomic structure, to more specialized ones such as the nuclear magnetic resonullce shielding tensor or the electric polarization. After a brief presentation of the APW+lo method, we review the usage, capabilities, and features of WIEN2k (version 19) in detail. The various options, properties, and available approximations for the exchange-correlation functional, as well as the external libraries or programs that can be used with WIEN2k, are mentioned. References to relevant applications and some examples are also given. (C) 2020 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1611, "Times Cited, All Databases": 1641, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 21", "Publication Year": 2020, "Volume": 152, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 74101, "DOI": "10.1063/1.5143061", "DOI Link": "http://dx.doi.org/10.1063/1.5143061", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000519820500008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, ZQ; Liang, XY; Li, G; Liu, HX; Zhang, HY; Guo, JX; Chen, JW; Shen, K; San, XY; Yu, W; Schropp, REI; Mai, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Zhiqiang; Liang, Xiaoyang; Li, Gang; Liu, Haixu; Zhang, Huiyu; Guo, Jianxin; Chen, Jingwei; Shen, Kai; San, Xingyuan; Yu, Wei; Schropp, Ruud E. I.; Mai, Yaohua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "9.2%-efficient core-shell structured antimony selenide nullorod array solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Antimony selenide (Sb2Se3) has a one-dimensional (1D) crystal structure comprising of covalently bonded (Sb4Se6)(n) ribbons stacking together through van der Waals force. This special structure results in anisotropic optical and electrical properties. Currently, the photovoltaic device performance is dominated by the grain orientation in the Sb2Se3 thin film absorbers. Effective approaches to enhance the carrier collection and overall power-conversion efficiency are urgently required. Here, we report the construction of Sb2Se3 solar cells with high-quality Sb2Se3 nullorod arrays absorber along the [001] direction, which is beneficial for sun-light absorption and charge carrier extraction. An efficiency of 9.2%, which is the highest value reported so far for this type of solar cells, is achieved by junction interface engineering. Our cell design provides an approach to further improve the efficiency of Sb2Se3-based solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 611, "Times Cited, All Databases": 637, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 125, "DOI": "10.1038/s41467-018-07903-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-018-07903-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000455354800022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yong, TY; Zhang, XQ; Bie, NN; Zhang, HB; Zhang, XT; Li, FY; Hakeem, A; Hu, J; Gan, L; Santos, HA; Yang, XL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yong, Tuying; Zhang, Xiaoqiong; Bie, nulla; Zhang, Hongbo; Zhang, Xuting; Li, Fuying; Hakeem, Abdul; Hu, Jun; Gan, Lu; Santos, Helder A.; Yang, Xiangliang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tumor exosome-based nulloparticles are efficient drug carriers for chemotherapy", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing biomimetic nulloparticles without loss of the integrity of proteins remains a major challenge in cancer chemotherapy. Here, we develop a biocompatible tumor-cell-exocytosed exosome-biomimetic porous silicon nulloparticles (PSiNPs) as drug carrier for targeted cancer chemotherapy. Exosome-sheathed doxorubicin-loaded PSiNPs (DOX@E-PSiNPs), generated by exocytosis of the endocytosed DOX-loaded PSiNPs from tumor cells, exhibit enhanced tumor accumulation, extravasation from blood vessels and penetration into deep tumor parenchyma following intravenous administration. In addition, DOX@E-PSiNPs, regardless of their origin, possess significant cellular uptake and cytotoxicity in both bulk cancer cells and cancer stem cells (CSCs). These properties endow DOX@E-PSiNPs with great in vivo enrichment in total tumor cells and side population cells with features of CSCs, resulting in anticancer activity and CSCs reduction in subcutaneous, orthotopic and metastatic tumor models. These results provide a proof-of-concept for the use of exosome-biomimetic nulloparticles exocytosed from tumor cells as a promising drug carrier for efficient cancer chemotherapy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 609, "Times Cited, All Databases": 636, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 23", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3838, "DOI": "10.1038/s41467-019-11718-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-11718-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000482398900040", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gong, Y; Guo, JW; Li, JH; Zhu, KJ; Liao, MH; Liu, XZ; Zhang, QH; Gu, L; Tang, L; Feng, X; Zhang, D; Li, W; Song, CL; Wang, LL; Yu, P; Chen, X; Wang, YY; Yao, H; Duan, WH; Xu, Y; Zhang, SC; Ma, XC; Xue, QK; He, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gong, Yan; Guo, Jingwen; Li, Jiaheng; Zhu, Kejing; Liao, Menghan; Liu, Xiaozhi; Zhang, Qinghua; Gu, Lin; Tang, Lin; Feng, Xiao; Zhang, Ding; Li, Wei; Song, Canli; Wang, Lili; Yu, Pu; Chen, Xi; Wang, Yayu; Yao, Hong; Duan, Wenhui; Xu, Yong; Zhang, Shou-Cheng; Ma, Xucun; Xue, Qi-Kun; He, Ke", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Experimental Realization of an Intrinsic Magnetic Topological Insulator", "Source Title": "CHINESE PHYSICS LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An intrinsic magnetic topological insulator (TI) is a stoichiometric magnetic compound possessing both inherent magnetic order and topological electronic states. Such a material can provide a shortcut to various novel topological quantum effects but remained elusive experimentally for a long time. Here we report the experimental realization of thin films of an intrinsic magnetic TI, MnBi2Te4, by alternate growth of a Bi2Te3 quintuple layer and a MnTe bilayer with molecular beam epitaxy. The material shows the archetypical Dirac surface states in angle-resolved photoemission spectroscopy and is demonstrated to be an antiferromagnetic topological insulator with ferromagnetic surfaces by magnetic and transport measurements as well as first-principles calculations. The unique magnetic and topological electronic structures and their interplays enable the material to embody rich quantum phases such as quantum anomalous Hall insulators and axion insulators at higher temperature and in a well-controlled way.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 554, "Times Cited, All Databases": 626, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2019, "Volume": 36, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 76801, "DOI": "10.1088/0256-307X/36/7/076801", "DOI Link": "http://dx.doi.org/10.1088/0256-307X/36/7/076801", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000475395200016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "An, WL; Gao, BA; Mei, SX; Xiang, B; Fu, JJ; Wang, L; Zhang, QB; Chu, PK; Huo, KF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "An, Weili; Gao, Biao; Mei, Shixiong; Xiang, Ben; Fu, Jijiang; Wang, Lei; Zhang, Qiaobao; Chu, Paul K.; Huo, Kaifu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Scalable synthesis of ant-nest-like bulk porous silicon for high-performance lithium-ion battery anodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although silicon is a promising anode material for lithium-ion batteries, scalable synthesis of silicon anodes with good cyclability and low electrode swelling remains a significant challenge. Herein, we report a scalable top-down technique to produce ant-nest-like porous silicon from magnesium-silicon alloy. The ant-nest-like porous silicon comprising threedimensional interconnected silicon nulloligaments and bicontinuous nullopores can prevent pulverization and accommodate volume expansion during cycling resulting in negligible particle-level outward expansion. The carbon-coated porous silicon anode delivers a high capacity of 1,271 mAh g(-1) at 2,100 mA g(-1) with 90% capacity retention after 1,000 cycles and has a low electrode swelling of 17.8% at a high areal capacity of 5.1 mAh cm(-2). The full cell with the prelithiated silicon anode and Li(Ni1/3Co1/3Mn1/3)O-2 cathode boasts a high energy density of 502 Wh Kg(-1) and 84% capacity retention after 400 cycles. This work provides insights into the rational design of alloy anodes for high-energy batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 631, "Times Cited, All Databases": 655, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 29", "Publication Year": 2019, "Volume": 10, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1447, "DOI": "10.1038/s41467-019-09510-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-09510-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000462722200004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Comesaña-Gándara, B; Chen, J; Bezzu, CG; Carta, M; Rose, I; Ferrari, MC; Esposito, E; Fuoco, A; Jansen, JC; McKeown, NB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Comesana-Gandara, Bibiana; Chen, Jie; Bezzu, C. Grazia; Carta, Mariolino; Rose, Ian; Ferrari, Maria-Chiara; Esposito, Elisa; Fuoco, Alessio; Jansen, Johannes C.; McKeown, Neil B.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Redefining the Robeson upper bounds for CO2/CH4 and CO2/N2 separations using a series of ultrapermeable benzotriptycene-based polymers of intrinsic microporosity", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Membranes composed of Polymers of Intrinsic Microporosity (PIMs) have the potential for energy efficient industrial gas separations. Here we report the synthesis and gas permeability data of a series of ultrapermeable PIMs, of two-dimensional chain conformation and based on benzotriptycene structural units, that demonstrate remarkable ideal selectivity for most gas pairs of importance. In particular, the CO2 ultrapermeability and high selectivity for CO2 over CH4, of key importance for the upgrading of natural gas and biogas, and for CO2 over N2, of importance for cost-effective carbon capture from power plants, exceed the performance of the current state-of-the-art polymers. All of the gas permeability data from this series of benzotriptycene-based PIMs are placed well above the current 2008 Robeson upper bounds for CO2/CH4 and CO2/N2. Indeed, the data for some of these polymers fall into a linear correlation on the benchmark Robeson plots [i.e. log(PCO2/PCH4) versus log PCO2 and log(PCO2/PN2) versus log PCO2], which are parallel to, but significantly above, that of the 2008 CO2/CH4 and CO2/N2 upper bounds, allowing their revision. The redefinition of these upper bounds sets new aspirational targets for polymer chemists to aim for and will result in more attractive parametric estimates of energy and cost efficiencies for carbon capture and natural/bio gas upgrading using state-of-the-art CO2 separation membranes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 611, "Times Cited, All Databases": 641, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 1", "Publication Year": 2019, "Volume": 12, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2733, "End Page": 2740, "Article Number": null, "DOI": "10.1039/c9ee01384a", "DOI Link": "http://dx.doi.org/10.1039/c9ee01384a", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000486019600007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Smidstrup, S; Markussen, T; Vancraeyveld, P; Wellendorff, J; Schneider, J; Gunst, T; Verstichel, B; Stradi, D; Khomyakov, PA; Vej-Hansen, UG; Lee, ME; Chill, ST; Rasmussen, F; Penazzi, G; Corsetti, F; Ojanperä, A; Jensen, K; Palsgaard, MLN; Martinez, U; Blom, A; Brandbyge, M; Stokbro, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Smidstrup, Soren; Markussen, Troels; Vancraeyveld, Pieter; Wellendorff, Jess; Schneider, Julian; Gunst, Tue; Verstichel, Brecht; Stradi, Daniele; Khomyakov, Petr A.; Vej-Hansen, Ulrik G.; Lee, Maeng-Eun; Chill, Samuel T.; Rasmussen, Filip; Penazzi, Gabriele; Corsetti, Fabiano; Ojanpera, Ari; Jensen, Kristian; Palsgaard, Mattias L. N.; Martinez, Umberto; Blom, Anders; Brandbyge, Mads; Stokbro, Kurt", "Book Author Full Names": null, "Group Authors": null, "Article Title": "QuantumATK: an integrated platform of electronic and atomic-scale modelling tools", "Source Title": "JOURNAL OF PHYSICS-CONDENSED MATTER", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "QuantumATK is an integrated set of atomic-scale modelling tools developed since 2003 by professional software engineers in collaboration with academic researchers. While different aspects and individual modules of the platform have been previously presented, the purpose of this paper is to give a general overview of the platform. The QuantumATK simulation engines enable electronic-structure calculations using density functional theory or tight-binding model Hamiltonians, and also offers bonded or reactive empirical force fields in many different parametrizations. Density functional theory is implemented using either a plane-wave basis or expansion of electronic states in a linear combination of atomic orbitals. The platform includes a long list of advanced modules, including Green?s-function methods for electron transport simulations and surface calculations, first-principles electron-phonon and electron-photon couplings, simulation of atomic-scale heat transport, ion dynamics, spintronics, optical properties of materials, static polarization, and more. Seamless integration of the different simulation engines into a common platform allows for easy combination of different simulation methods into complex workflows. Besides giving a general overview and presenting a number of implementation details not previously published, we also present four different application examples. These are calculations of the phonon-limited mobility of Cu, Ag and Au, electron transport in a gated 2D device, multi-model simulation of lithium ion drift through a battery cathode in an external electric field, and electronic-structure calculations of the composition-dependent band gap of SiGe alloys.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1409, "Times Cited, All Databases": 1439, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2020, "Volume": 32, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 15901, "DOI": "10.1088/1361-648X/ab4007", "DOI Link": "http://dx.doi.org/10.1088/1361-648X/ab4007", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000499348200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pizzi, G; Vitale, V; Arita, R; Blügel, S; Freimuth, F; Géranton, G; Gibertini, M; Gresch, D; Johnson, C; Koretsune, T; Ibañez-Azpiroz, J; Lee, H; Lihm, JM; Marchand, D; Marrazzo, A; Mokrousov, Y; Mustafa, JI; Nohara, Y; Nomura, Y; Paulatto, L; Poncé, S; Ponweiser, T; Qiao, JF; Thöle, F; Tsirkin, SS; Wierzbowska, M; Marzari, N; Vanderbilt, D; Souza, I; Mostofi, AA; Yates, JR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pizzi, Giovanni; Vitale, Valerio; Arita, Ryotaro; Bluegel, Stefan; Freimuth, Frank; Geranton, Guillaume; Gibertini, Marco; Gresch, Dominik; Johnson, Charles; Koretsune, Takashi; Ibanez-Azpiroz, Julen; Lee, Hyungjun; Lihm, Jae-Mo; Marchand, Daniel; Marrazzo, Antimo; Mokrousov, Yuriy; Mustafa, Jamal, I; Nohara, Yoshiro; Nomura, Yusuke; Paulatto, Lorenzo; Ponce, Samuel; Ponweiser, Thomas; Qiao, Junfeng; Thoele, Florian; Tsirkin, Stepan S.; Wierzbowska, Malgorzata; Marzari, Nicola; Vanderbilt, David; Souza, Ivo; Mostofi, Arash A.; Yates, Jonathan R.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wannier90 as a community code: new features and applications", "Source Title": "JOURNAL OF PHYSICS-CONDENSED MATTER", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wannier90 is an open-source computer program for calculating maximally-localised Wannier functions (MLWFs) from a set of Bloch states. It is interfaced to many widely used electronic-structure codes thanks to its independence from the basis sets representing these Bloch states. In the past few years the development of Wannier90 has transitioned to a community-driven model; this has resulted in a number of new developments that have been recently released in Wannier90 v3.0. In this article we describe these new functionalities, that include the implementation of new features for wannierisation and disentanglement (symmetry-adapted Wannier functions, selectively-localised Wannier functions, selected columns of the density matrix) and the ability to calculate new properties (shift currents and Berry-curvature dipole, and a new interface to many-body perturbation theory); performance improvements, including parallelisation of the core code; enhancements in functionality (support for spinor-valued Wannier functions, more accurate methods to interpolate quantities in the Brillouin zone); improved usability (improved plotting routines, integration with high-throughput automation frameworks), as well as the implementation of modern software engineering practices (unit testing, continuous integration, and automatic source-code documentation). These new features, capabilities, and code development model aim to further sustain and expand the community uptake and range of applicability, that nowadays spans complex and accurate dielectric, electronic, magnetic, optical, topological and transport properties of materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1281, "Times Cited, All Databases": 1341, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 17", "Publication Year": 2020, "Volume": 32, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 165902, "DOI": "10.1088/1361-648X/ab51ff", "DOI Link": "http://dx.doi.org/10.1088/1361-648X/ab51ff", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000520450700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, FY; Meng, K; Cheng, B; Wang, SY; Xu, JS; Yu, JG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Feiyan; Meng, Kai; Cheng, Bei; Wang, Shengyao; Xu, Jingsan; Yu, Jiaguo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unique S-scheme heterojunctions in self-assembled TiO2/CsPbBr3 hybrids for CO2 photoreduction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Exploring photocatalysts to promote CO2 photoreduction into solar fuels is of great significance. We develop TiO2/perovskite (CsPbBr3) S-scheme heterojunctions synthesized by a facile electrostatic-driven self-assembling approach. Density functional theory calculation combined with experimental studies proves the electron transfer from CsPbBr3 quantum dots (QDs) to TiO2, resulting in the construction of internal electric field (IEF) directing from CsPbBr3 to TiO2 upon hybridization. The IEF drives the photoexcited electrons in TiO2 to CsPbBr3 upon light irradiation as revealed by in-situ X-ray photoelectron spectroscopy analysis, suggesting the formation of an S-scheme heterojunction in the TiO2/CsPbBr3 nullohybrids which greatly promotes the separation of electron-hole pairs to foster efficient CO2 photoreduction. The hybrid nullofibers unveil a higher CO2-reduction rate (9.02 mu mol g(-1) h(-1)) comparing with pristine TiO2 nullofibers (4.68 mu mol g(-1) h(-1)). Isotope ((CO2)-C-13) tracer results confirm that the reduction products originate from CO2 source.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1175, "Times Cited, All Databases": 1211, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 16", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4613, "DOI": "10.1038/s41467-020-18350-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-18350-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000604254000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Serlin, M; Tschirhart, CL; Polshyn, H; Zhang, Y; Zhu, J; Watanabe, K; Taniguchi, T; Balents, L; Young, AF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Serlin, M.; Tschirhart, C. L.; Polshyn, H.; Zhang, Y.; Zhu, J.; Watanabe, K.; Taniguchi, T.; Balents, L.; Young, A. F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Intrinsic quantized anomalous Hall effect in a moire heterostructure", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The quantum anomalous Hall (QAH) effect combines topology and magnetism to produce precisely quantized Hall resistance at zero magnetic field. We report the observation of a QAH effect in twisted bilayer graphene aligned to hexagonal boron nitride. The effect is driven by intrinsic strong interactions, which polarize the electrons into a single spin- and valley-resolved moire miniband with Chern number C = 1. In contrast to magnetically doped systems, the measured transport energy gap is larger than the Curie temperature for magnetic ordering, and quantization to within 0.1% of the von Klitzing constant persists to temperatures of several kelvin at zero magnetic field. Electrical currents as small as 1 nulloampere controllably switch the magnetic order between states of opposite polarization, forming an electrically rewritable magnetic memory.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1084, "Times Cited, All Databases": 1189, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 21", "Publication Year": 2020, "Volume": 367, "Issue": 6480, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 900, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aay5533", "DOI Link": "http://dx.doi.org/10.1126/science.aay5533", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000515235800041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hao, JN; Li, B; Li, XL; Zeng, XH; Zhang, SL; Yang, FH; Liu, SL; Li, D; Wu, C; Guo, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hao, Junnull; Li, Bo; Li, Xiaolong; Zeng, Xiaohui; Zhang, Shilin; Yang, Fuhua; Liu, Sailin; Li, Dan; Wu, Chao; Guo, Zaiping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An In-Depth Study of Zn Metal Surface Chemistry for Advanced Aqueous Zn-Ion Batteries", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although Zn metal has been regarded as the most promising anode for aqueous batteries, it persistently suffers from serious side reactions and dendrite growth in mild electrolyte. Spontaneous Zn corrosion and hydrogen evolution damage the shelf life and calendar life of Zn-based batteries, severely affecting their industrial applications. Herein, a robust and homogeneous ZnS interphase is built in situ on the Zn surface by a vapor-solid strategy to enhance Zn reversibility. The thickness of the ZnS film is controlled via the treatment temperature, and the performance of the protected Zn electrode is optimized. The dense ZnS artificial layer obtained at 350 degrees C not only suppresses Zn corrosion by forming a physical barrier on the Zn surface, but also inhibits dendrite growth via guiding the Zn plating/stripping underneath the artificial layer. Accordingly, a side reaction-free and dendrite-free Zn electrode is developed, the effectiveness of which is also convincing in a MnO2/ZnS@Zn full-cell with 87.6% capacity retention after 2500 cycles.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 901, "Times Cited, All Databases": 920, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2020, "Volume": 32, "Issue": 34, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2003021, "DOI": "10.1002/adma.202003021", "DOI Link": "http://dx.doi.org/10.1002/adma.202003021", "Book DOI": null, "Early Access Date": "JUL 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000546717000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hourahine, B; Aradi, B; Blum, V; Bonafé, F; Buccheri, A; Camacho, C; Cevallos, C; Deshaye, MY; Dumitrica, T; Dominguez, A; Ehlert, S; Elstner, M; van der Heide, T; Hermann, J; Irle, S; Kranz, JJ; Köhler, C; Kowalczyk, T; Kubar, T; Lee, IS; Lutsker, V; Maurer, RJ; Min, SK; Mitchell, I; Negre, C; Niehaus, TA; Niklasson, AMN; Page, AJ; Pecchia, A; Penazzi, G; Persson, MP; Rezác, J; Sánchez, CG; Sternberg, M; Stöhr, M; Stuckenberg, F; Tkatchenko, A; Yu, VWZ; Frauenheim, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hourahine, B.; Aradi, B.; Blum, V.; Bonafe, F.; Buccheri, A.; Camacho, C.; Cevallos, C.; Deshaye, M. Y.; Dumitrica, T.; Dominguez, A.; Ehlert, S.; Elstner, M.; van der Heide, T.; Hermann, J.; Irle, S.; Kranz, J. J.; Koehler, C.; Kowalczyk, T.; Kubar, T.; Lee, I. S.; Lutsker, V.; Maurer, R. J.; Min, S. K.; Mitchell, I.; Negre, C.; Niehaus, T. A.; Niklasson, A. M. N.; Page, A. J.; Pecchia, A.; Penazzi, G.; Persson, M. P.; Rezac, J.; Sanchez, C. G.; Sternberg, M.; Stoehr, M.; Stuckenberg, F.; Tkatchenko, A.; Yu, V. W. -z.; Frauenheim, T.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "DFTB plus , a software package for efficient approximate density functional theory based atomistic simulations", "Source Title": "JOURNAL OF CHEMICAL PHYSICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "DFTB+ is a versatile community developed open source software package offering fast and efficient methods for carrying out atomistic quantum mechanical simulations. By implementing various methods approximating density functional theory (DFT), such as the density functional based tight binding (DFTB) and the extended tight binding method, it enables simulations of large systems and long timescales with reasonable accuracy while being considerably faster for typical simulations than the respective ab initio methods. Based on the DFTB framework, it additionally offers approximated versions of various DFT extensions including hybrid functionals, time dependent formalism for treating excited systems, electron transport using non-equilibrium Green's functions, and many more. DFTB+ can be used as a user-friendly standalone application in addition to being embedded into other software packages as a library or acting as a calculation-server accessed by socket communication. We give an overview of the recently developed capabilities of the DFTB+ code, demonstrating with a few use case examples, discuss the strengths and weaknesses of the various features, and also discuss on-going developments and possible future perspectives. (C) 2020 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 780, "Times Cited, All Databases": 806, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 31", "Publication Year": 2020, "Volume": 152, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 124101, "DOI": "10.1063/1.5143190", "DOI Link": "http://dx.doi.org/10.1063/1.5143190", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000521986100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, Z; Wang, HS; Kong, X; Huang, W; Tsao, YC; Mackanic, DG; Wang, KC; Wang, XC; Huang, WX; Choudhury, S; Zheng, Y; Amanchukwu, CV; Hung, ST; Ma, YT; Lomeli, EG; Qin, J; Cui, Y; Bao, ZN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Zhiao; Wang, Hansen; Kong, Xian; Huang, William; Tsao, Yuchi; Mackanic, David G.; Wang, Kecheng; Wang, Xinchang; Huang, Wenxiao; Choudhury, Snehashis; Zheng, Yu; Amanchukwu, Chibueze, V; Hung, Samantha T.; Ma, Yuting; Lomeli, Eder G.; Qin, Jian; Cui, Yi; Bao, Zhenull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Molecular design for electrolyte solvents enabling energy-dense and long-cycling lithium metal batteries", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrolyte engineering is critical for developing Li metal batteries. While recent works improved Li metal cyclability, a methodology for rational electrolyte design remains lacking. Herein, we propose a design strategy for electrolytes that enable anode-free Li metal batteries with single-solvent single-salt formations at standard concentrations. Rational incorporation of -CF2- units yields fluorinated 1,4-dimethoxylbutane as the electrolyte solvent. Paired with 1 M lithium bis(fluorosulfonyl)imide, this electrolyte possesses unique Li-F binding and high anion/solvent ratio in the solvation sheath, leading to excellent compatibility with both Li metal anodes (Coulombic efficiency similar to 99.52% and fast activation within five cycles) and high-voltage cathodes (similar to 6 V stability). Fifty-mu m-thick Li|NMC batteries retain 90% capacity after 420 cycles with an average Coulombic efficiency of 99.98%. Industrial anode-free pouch cells achieve similar to 325 Wh kg(-1)single-cell energy density and 80% capacity retention after 100 cycles. Our design concept for electrolytes provides a promising path to high-energy, long-cycling Li metal batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 823, "Times Cited, All Databases": 858, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2020, "Volume": 5, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 526, "End Page": 533, "Article Number": null, "DOI": "10.1038/s41560-020-0634-5", "DOI Link": "http://dx.doi.org/10.1038/s41560-020-0634-5", "Book DOI": null, "Early Access Date": "JUN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000542060100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hao, JN; Li, XL; Zhang, SL; Yang, FH; Zeng, XH; Zhang, S; Bo, GY; Wang, CS; Guo, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hao, Junnull; Li, Xiaolong; Zhang, Shilin; Yang, Fuhua; Zeng, Xiaohui; Zhang, Shuai; Bo, Guyue; Wang, Chunsheng; Guo, Zaiping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Designing Dendrite-Free Zinc Anodes for Advanced Aqueous Zinc Batteries", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Zn metal has been regarded as the most promising anode for aqueous batteries due to its high capacity, low cost, and environmental benignity. Zn anode still suffers, however, from low Coulombic efficiency due to the side reactions and dendrite growth in slightly acidic electrolytes. Here, the Zn plating/stripping mechanism is thoroughly investigated in 1 m ZnSO4 electrolyte, demonstrating that the poor performance of Zn metal in mild electrolyte should be ascribed to the formation of a porous by-product (Zn4SO4(OH)(6)center dot xH(2)O) layer and serious dendrite growth. To suppress the side reactions and dendrite growth, a highly viscoelastic polyvinyl butyral film, functioning as an artificial solid/electrolyte interphase (SEI), is homogeneously deposited on the Zn surface via a simple spin-coating strategy. This dense artificial SEI film not only effectively blocks water from the Zn surface but also guides the uniform stripping/plating of Zn ions underneath the film due to its good adhesion, hydrophilicity, ionic conductivity, and mechanical strength. Consequently, this side-reaction-free and dendrite-free Zn electrode exhibits high cycling stability and enhanced Coulombic efficiency, which also contributes to enhancement of the full-cell performance when it is coupled with MnO2 and LiFePO4 cathodes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 756, "Times Cited, All Databases": 791, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2020, "Volume": 30, "Issue": 30, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2001263, "DOI": "10.1002/adfm.202001263", "DOI Link": "http://dx.doi.org/10.1002/adfm.202001263", "Book DOI": null, "Early Access Date": "JUN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000537764400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Dionigi, F; Zeng, ZH; Sinev, I; Merzdorf, T; Deshpande, S; Lopez, MB; Kunze, S; Zegkinoglou, I; Sarodnik, H; Fan, DX; Bergmann, A; Drnec, J; de Araujo, JF; Gliech, M; Teschner, D; Zhu, J; Li, WX; Greeley, J; Roldan Cuenya, B; Strasser, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Dionigi, Fabio; Zeng, Zhenhua; Sinev, Ilya; Merzdorf, Thomas; Deshpande, Siddharth; Lopez, Miguel Bernal; Kunze, Sebastian; Zegkinoglou, Ioannis; Sarodnik, Hannes; Fan, Dingxin; Bergmann, Arno; Drnec, Jakub; de Araujo, Jorge Ferreira; Gliech, Manuel; Teschner, Detre; Zhu, Jing; Li, Wei-Xue; Greeley, Jeffrey; Roldan Cuenya, Beatriz; Strasser, Peter", "Book Author Full Names": null, "Group Authors": null, "Article Title": "In-situ structure and catalytic mechanism of NiFe and CoFe layered double hydroxides during oxygen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "NiFe and CoFe (MFe) layered double hydroxides (LDHs) are among the most active electrocatalysts for the alkaline oxygen evolution reaction (OER). Herein, we combine electrochemical measurements, operando X-ray scattering and absorption spectroscopy, and density functional theory (DFT) calculations to elucidate the catalytically active phase, reaction center and the OER mechanism. We provide the first direct atomic-scale evidence that, under applied anodic potentials, MFe LDHs oxidize from as-prepared alpha -phases to activated gamma -phases. The OER-active gamma -phases are characterized by about 8% contraction of the lattice spacing and switching of the intercalated ions. DFT calculations reveal that the OER proceeds via a Mars van Krevelen mechanism. The flexible electronic structure of the surface Fe sites, and their synergy with nearest-neighbor M sites through formation of O-bridged Fe-M reaction centers, stabilize OER intermediates that are unfavorable on pure M-M centers and single Fe sites, fundamentally accounting for the high catalytic activity of MFe LDHs. NiFe and CoFe layered double hydroxides are among the most active electrocatalysts for the alkaline oxygen evolution reaction. Here, by combining operando experiments and rigorous DFT calculations, the authors unravel their active phase, the reaction center and the catalytic mechanism.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 757, "Times Cited, All Databases": 776, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 20", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2522, "DOI": "10.1038/s41467-020-16237-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-16237-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000537059500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yuk, H; Lu, BY; Lin, S; Qu, K; Xu, JK; Luo, JH; Zhao, XH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yuk, Hyunwoo; Lu, Baoyang; Lin, Shen; Qu, Kai; Xu, Jingkun; Luo, Jianhong; Zhao, Xuanhe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D printing of conducting polymers", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Conducting polymers are promising material candidates in diverse applications including energy storage, flexible electronics, and bioelectronics. However, the fabrication of conducting polymers has mostly relied on conventional approaches such as ink-jet printing, screen printing, and electron-beam lithography, whose limitations have hampered rapid innovations and broad applications of conducting polymers. Here we introduce a high-performance 3D printable conducting polymer ink based on poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) for 3D printing of conducting polymers. The resultant superior printability enables facile fabrication of conducting polymers into high resolution and high aspect ratio microstructures, which can be integrated with other materials such as insulating elastomers via multi-material 3D printing. The 3D-printed conducting polymers can also be converted into highly conductive and soft hydrogel microstructures. We further demonstrate fast and streamlined fabrications of various conducting polymer devices, such as a soft neural probe capable of in vivo single-unit recording.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 722, "Times Cited, All Databases": 756, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 30", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1604, "DOI": "10.1038/s41467-020-15316-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15316-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000563559600005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ni, ZY; Bao, CX; Liu, Y; Jiang, Q; Wu, WQ; Chen, SS; Dai, XZ; Chen, B; Hartweg, B; Yu, ZS; Holman, Z; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ni, Zhenyi; Bao, Chunxiong; Liu, Ye; Jiang, Qi; Wu, Wu-Qiang; Chen, Shangshang; Dai, Xuezeng; Chen, Bo; Hartweg, Barry; Yu, Zhengshan; Holman, Zachary; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Resolving spatial and energetic distributions of trap states in metal halide perovskite solar cells", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report the profiling of spatial and energetic distributions of trap states in metal halide perovskite single-crystalline and polycrystalline solar cells. The trap densities in single crystals varied by five orders of magnitude, with a lowest value of 2 x 10(11) per cubic centimeter and most of the deep traps located at crystal surfaces. The charge trap densities of all depths of the interfaces of the polycrystalline films were one to two orders of magnitude greater than that of the film interior, and the trap density at the film interior was still two to three orders of magnitude greater than that in high-quality single crystals. Suprisingly, after surface passivation, most deep traps were detected near the interface of perovskites and hole transport layers, where a large density of nullocrystals were embedded, limiting the efficiency of solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 916, "Times Cited, All Databases": 958, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 20", "Publication Year": 2020, "Volume": 367, "Issue": 6484, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1352, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aba0893", "DOI Link": "http://dx.doi.org/10.1126/science.aba0893", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000522167400047", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Burger, B; Maffettone, PM; Gusev, VV; Aitchison, CM; Bai, Y; Wang, XY; Li, XB; Alston, B; Li, BY; Clowes, R; Rankin, N; Harris, B; Sprick, RS; Cooper, AI", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Burger, Benjamin; Maffettone, Phillip M.; Gusev, Vladimir V.; Aitchison, Catherine M.; Bai, Yang; Wang, Xiaoyan; Li, Xiaobo; Alston, Ben M.; Li, Buyi; Clowes, Rob; Rankin, Nicola; Harris, Brandon; Sprick, Reiner Sebastian; Cooper, Andrew I.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A mobile robotic chemist", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Technologies such as batteries, biomaterials and heterogeneous catalysts have functionsthat are defined by mixtures of molecular and mesoscale components. As yet, this multi-length-scale complexity cannot be fully captured by atomistic simulations, and the design of such materials from first principles is still rare(1-5). Likewise, experimental complexity scales exponentially with the number of variables, restricting most searches to narrow areas of materials space. Robots can assist in experimental searches(6-14)but their widespread adoption in materials research is challenging because of the diversity of sample types, operations, instruments and measurements required. Here we use a mobile robot to search for improved photocatalysts for hydrogen production from water(15). The robot operated autonomously over eight days, performing 688 experiments within a ten-variable experimental space, driven by a batched Bayesian search algorithm(16-18). This autonomous search identified photocatalyst mixturesthat were six times more active than the initial formulations, selecting beneficial components and deselecting negative ones. Our strategy uses a dexterous(19,20)free-roaming robot(21-24), automating the researcher ratherthan the instruments. This modular approach could be deployed in conventional laboratories for a range of research problems beyond photocatalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 793, "Times Cited, All Databases": 877, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 9", "Publication Year": 2020, "Volume": 583, "Issue": 7815, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 237, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-020-2442-2", "DOI Link": "http://dx.doi.org/10.1038/s41586-020-2442-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000546767100015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Al-Ashouri, A; Köhnen, E; Li, B; Magomedov, A; Hempel, H; Caprioglio, P; Márquez, JA; Vilches, ABM; Kasparavicius, E; Smith, JA; Phung, N; Menzel, D; Grischek, M; Kegelmann, L; Skroblin, D; Gollwitzer, C; Malinauskas, T; Jost, M; Matic, G; Rech, B; Schlatmann, R; Topic, M; Korte, L; Abate, A; Stannowski, B; Neher, D; Stolterfoht, M; Unold, T; Getautis, V; Albrecht, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Al-Ashouri, Amran; Kohnen, Eike; Li, Bor; Magomedov, Artiom; Hempel, Hannes; Caprioglio, Pietro; Marquez, Jose A.; Vilches, Anna Belen Morales; Kasparavicius, Ernestas; Smith, Joel A.; Phung, Nga; Menzel, Dorothee; Grischek, Max; Kegelmann, Lukas; Skroblin, Dieter; Gollwitzer, Christian; Malinauskas, Tadas; Jost, Marko; Matic, Gasper; Rech, Bernd; Schlatmann, Rutger; Topic, Marko; Korte, Lars; Abate, Antonio; Stannowski, Bernd; Neher, Dieter; Stolterfoht, Martin; Unold, Thomas; Getautis, Vytautas; Albrecht, Steve", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Monolithic perovskite/silicon tandem solar cell with >29% efficiency by enhanced hole extraction", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tandem solar cells that pair silicon with a metal halide perovskite are a promising option for surpassing the single-cell efficiency limit. We report a monolithic perovskite/silicon tandem with a certified power conversion efficiency of 29.15%. The perovskite absorber, with a bandgap of 1.68 electron volts, remained phase-stable under illumination through a combination of fast hole extraction and minimized nonradiative recombination at the hole-selective interface. These features were made possible by a self-assembled, methyl-substituted carbazole monolayer as the hole-selective layer in the perovskite cell. The accelerated hole extraction was linked to a low ideality factor of 1.26 and single-junction fill factors of up to 84%, while enabling a tandem open-circuit voltage of as high as 1.92 volts. In air, without encapsulation, a tandem retained 95% of its initial efficiency after 300 hours of operation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1420, "Times Cited, All Databases": 1485, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 11", "Publication Year": 2020, "Volume": 370, "Issue": 6522, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1300, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abd4016", "DOI Link": "http://dx.doi.org/10.1126/science.abd4016", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000597271300039", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liao, YH; Koelewijn, SF; Van den Bossche, G; Van Aelst, J; Van den Bosch, S; Renders, T; Navare, K; Nicolai, T; Van Aelst, K; Maesen, M; Matsushima, H; Thevelein, JM; Van Acker, K; Lagrain, B; Verboekend, D; Sels, BF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liao, Yuhe; Koelewijn, Steven-Friso; Van den Bossche, Gil; Van Aelst, Joost; Van den Bosch, Sander; Renders, Tom; Navare, Kranti; Nicolai, Thomas; Van Aelst, Korneel; Maesen, Maarten; Matsushima, Hironori; Thevelein, Johan M.; Van Acker, Karel; Lagrain, Bert; Verboekend, Danny; Sels, Bert F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A sustainable wood biorefinery for low-carbon footprint chemicals production", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The profitability and sustainability of future biorefineries are dependent on efficient feedstock use. Therefore, it is essential to valorize lignin when using wood. We have developed an integrated biorefinery that converts 78 weight % (wt %) of birch into xylochemicals. Reductive catalytic fractionation of the wood produces a carbohydrate pulp amenable to bioethanol production and a lignin oil. After extraction of the lignin oil, the crude, unseparated mixture of phenolic monomers is catalytically funneled into 20 wt % of phenol and 9 wt % of propylene (on the basis of lignin weight) by gas-phase hydroprocessing and dealkylation; the residual phenolic oligomers (30 wt %) are used in printing ink as replacements for controversial para-nonylphenol. A techno-economic analysis predicts an economically competitive production process, and a life-cycle assessment estimates a lower carbon dioxide footprint relative to that of fossil-based production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 745, "Times Cited, All Databases": 772, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 20", "Publication Year": 2020, "Volume": 367, "Issue": 6484, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1385, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aau1567", "DOI Link": "http://dx.doi.org/10.1126/science.aau1567", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000522167400054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sarycheva, A; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sarycheva, Asia; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Raman Spectroscopy Analysis of the Structure and Surface Chemistry of Ti3C2Tx MXene", "Source Title": "CHEMISTRY OF MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Raman spectroscopy is one of the most useful tools for the analysis of two-dimensional (2D) materials. While MXenes are a very large family of 2D transition metal carbides and nitrides, there have been just a few Raman studies of materials from this family. Here, we report on a systematic study of the most widely used and most important MXene to date: Ti3C2Tx. By synthesizing material using different methods, we show that Raman spectra of Ti3C2Tx are affected not only by the composition and surface groups but also by intercalated species and stacking. Due to a plasmonic peak of Ti3C2Tx around 785 nm, resonullt conditions are achieved, enabling us to observe an extra peak at similar to 120 cm(-1), when excited with a red diode laser. We report differences in Raman spectra collected from single flakes of Ti3C2Tx colloidal solutions, and multilayer films. Lastly, we show how an undesirable photoluminescent background could serve as evidence of material degradation, which leads to the formation of defective titania and amorphous carbon. This study shows how Raman spectroscopy can be used for the characterization of important emerging 2D materials: MXenes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 965, "Times Cited, All Databases": 992, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 28", "Publication Year": 2020, "Volume": 32, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3480, "End Page": 3488, "Article Number": null, "DOI": "10.1021/acs.chemmater.0c00359", "DOI Link": "http://dx.doi.org/10.1021/acs.chemmater.0c00359", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000529878600017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, CL; Wang, QD; Yao, ZP; Wang, JL; Sánchez-Lengeling, B; Ding, FX; Qi, XG; Lu, YX; Bai, XD; Li, BH; Li, H; Aspuru-Guzik, A; Huang, XJ; Delmas, C; Wagemaker, M; Chen, LQ; Hu, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Chenglong; Wang, Qidi; Yao, Zhenpeng; Wang, Jianlin; Sanchez-Lengeling, Benjamin; Ding, Feixiang; Qi, Xingguo; Lu, Yaxiang; Bai, Xuedong; Li, Baohua; Li, Hong; Aspuru-Guzik, Alan; Huang, Xuejie; Delmas, Claude; Wagemaker, Marnix; Chen, Liquan; Hu, Yong-Sheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rational design of layered oxide materials for sodium-ion batteries", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sodium-ion batteries have captured widespread attention for grid-scale energy storage owing to the natural abundance of sodium. The performance of such batteries is limited by available electrode materials, especially for sodium-ion layered oxides, motivating the exploration of high compositional diversity. How the composition determines the structural chemistry is decisive for the electrochemical performance but very challenging to predict, especially for complex compositions. We introduce the cationic potential that captures the key interactions of layered materials and makes it possible to predict the stacking structures. This is demonstrated through the rational design and preparation of layered electrode materials with improved performance. As the stacking structure determines the functional properties, this methodology offers a solution toward the design of alkali metal layered oxides.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 717, "Times Cited, All Databases": 755, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 6", "Publication Year": 2020, "Volume": 370, "Issue": 6517, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 708, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aay9972", "DOI Link": "http://dx.doi.org/10.1126/science.aay9972", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000586868600043", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, C; Zhu, XR; Wen, XJ; Zhou, YY; Zhou, L; Li, H; Tao, L; Li, QL; Du, SQ; Liu, TT; Yan, DF; Xie, C; Zou, YQ; Wang, YY; Chen, R; Huo, J; Li, YF; Cheng, J; Su, H; Zhao, X; Cheng, WR; Liu, QH; Lin, HZ; Luo, J; Chen, J; Dong, MD; Cheng, K; Li, CG; Wang, SY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Chen; Zhu, Xiaorong; Wen, Xiaojian; Zhou, Yangyang; Zhou, Ling; Li, Hao; Tao, Li; Li, Qiling; Du, Shiqian; Liu, Tingting; Yan, Dafeng; Xie, Chao; Zou, Yuqin; Wang, Yanyong; Chen, Ru; Huo, Jia; Li, Yafei; Cheng, Jun; Su, Hui; Zhao, Xu; Cheng, Weiren; Liu, Qinghua; Lin, Hongzhen; Luo, Jun; Chen, Jun; Dong, Mingdong; Cheng, Kai; Li, Conggang; Wang, Shuangyin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Coupling N2 and CO2 in H2O to synthesize urea under ambient conditions", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The use of nitrogen fertilizers has been estimated to have supported 27% of the world's population over the past century. Urea (CO(NH2)(2)) is conventionally synthesized through two consecutive industrial processes, N-2 + H-2 -> NH(3)followed by NH3 + CO2 -> urea. Both reactions operate under harsh conditions and consume more than 2% of the world's energy. Urea synthesis consumes approximately 80% of the NH(3)produced globally. Here we directly coupled N(2)and CO(2)in H2O to produce urea under ambient conditions. The process was carried out using an electrocatalyst consisting of PdCu alloy nulloparticles on TiO(2)nullosheets. This coupling reaction occurs through the formation of C-N bonds via the thermodynamically spontaneous reaction between *N=N* and CO. Products were identified and quantified using isotope labelling and the mechanism investigated using isotope-labelled operando synchrotron-radiation Fourier transform infrared spectroscopy. A high rate of urea formation of 3.36 mmol g(-1) h(-1) and corresponding Faradic efficiency of 8.92% were measured at -0.4 V versus reversible hydrogen electrode.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 676, "Times Cited, All Databases": 706, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2020, "Volume": 12, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41557-020-0481-9", "DOI Link": "http://dx.doi.org/10.1038/s41557-020-0481-9", "Book DOI": null, "Early Access Date": "JUN 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000540397300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shang, HS; Zhou, XY; Dong, JC; Li, A; Zhao, X; Liu, QH; Lin, Y; Pei, JJ; Li, Z; Jiang, ZL; Zhou, DN; Zheng, LR; Wang, Y; Zhou, J; Yang, ZK; Cao, R; Sarangi, R; Sun, TT; Yang, X; Zheng, XS; Yan, WS; Zhuang, ZB; Li, J; Chen, WX; Wang, DS; Zhang, JT; Li, YD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shang, Huishan; Zhou, Xiangyi; Dong, Juncai; Li, Ang; Zhao, Xu; Liu, Qinghua; Lin, Yue; Pei, Jiajing; Li, Zhi; Jiang, Zhuoli; Zhou, Danni; Zheng, Lirong; Wang, Yu; Zhou, Jing; Yang, Zhengkun; Cao, Rui; Sarangi, Ritimukta; Sun, Tingting; Yang, Xin; Zheng, Xusheng; Yan, Wensheng; Zhuang, Zhongbin; Li, Jia; Chen, Wenxing; Wang, Dingsheng; Zhang, Jiatao; Li, Yadong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering unsymmetrically coordinated Cu-S1N3 single atom sites with enhanced oxygen reduction activity", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Atomic interface regulation is thought to be an efficient method to adjust the performance of single atom catalysts. Herein, a practical strategy was reported to rationally design single copper atoms coordinated with both sulfur and nitrogen atoms in metal-organic framework derived hierarchically porous carbon (S-Cu-ISA/SNC). The atomic interface configuration of the copper site in S-Cu-ISA/SNC is detected to be an unsymmetrically arranged Cu-S1N3 moiety. The catalyst exhibits excellent oxygen reduction reaction activity with a half-wave potential of 0.918V vs. RHE. Additionally, through in situ X-ray absorption fine structure tests, we discover that the low-valent Cuprous-S1N3 moiety acts as an active center during the oxygen reduction process. Our discovery provides a universal scheme for the controllable synthesis and performance regulation of single metal atom catalysts toward energy applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 688, "Times Cited, All Databases": 705, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 16", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3049, "DOI": "10.1038/s41467-020-16848-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-16848-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000542988800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ortiz, BR; Teicher, SML; Hu, Y; Zuo, JL; Sarte, PM; Schueller, EC; Abeykoon, AMM; Krogstad, MJ; Rosenkranz, S; Osborn, R; Seshadri, R; Balents, L; He, JF; Wilson, SD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ortiz, Brenden R.; Teicher, Samuel M. L.; Hu, Yong; Zuo, Julia L.; Sarte, Paul M.; Schueller, Emily C.; Abeykoon, A. M. Milinda; Krogstad, Matthew J.; Rosenkranz, Stephan; Osborn, Raymond; Seshadri, Ram; Balents, Leon; He, Junfeng; Wilson, Stephen D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "CsV3Sb5: A Z2 Topological Kagome Metal with a Superconducting Ground State", "Source Title": "PHYSICAL REVIEW LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recently discovered alongside its sister compounds KV3Sb5 and RbV3Sb5, CsV3Sb5 crystallizes with an ideal kagome network of vanadium and antimonene layers separated by alkali metal ions. This work presents the electronic properties of CsV3Sb5, demonstrating bulk superconductivity in single crystals with a T-c = 2.5 K. The normal state electronic structure is studied via angle-resolved photoemission spectroscopy and density-functional theory, which categorize CsV3Sb5 as a Z(2) topological metal. Multiple protected Dirac crossings are predicted in close proximity to the Fermi level (E-F), and signatures of normal state correlation effects are also suggested by a high-temperature charge density wavelike instability. The implications for the formation of unconventional superconductivity in this material are discussed.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 649, "Times Cited, All Databases": 703, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 10", "Publication Year": 2020, "Volume": 125, "Issue": 24, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 247002, "DOI": "10.1103/PhysRevLett.125.247002", "DOI Link": "http://dx.doi.org/10.1103/PhysRevLett.125.247002", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000597151900015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheema, SS; Kwon, D; Shanker, N; dos Reis, R; Hsu, SL; Xiao, J; Zhang, HG; Wagner, R; Datar, A; McCarter, MR; Serrao, CR; Yadav, AK; Karbasian, G; Hsu, CH; Tan, AJ; Wang, LC; Thakare, V; Zhang, X; Mehta, A; Karapetrova, E; Chopdekar, R; Shafer, P; Arenholz, E; Hu, CM; Proksch, R; Ramesh, R; Ciston, J; Salahuddin, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheema, Suraj S.; Kwon, Daewoong; Shanker, Nirmaan; dos Reis, Roberto; Hsu, Shang-Lin; Xiao, Jun; Zhang, Haigang; Wagner, Ryan; Datar, Adhiraj; McCarter, Margaret R.; Serrao, Claudy R.; Yadav, Ajay K.; Karbasian, Golnaz; Hsu, Cheng-Hsiang; Tan, Ava J.; Wang, Li-Chen; Thakare, Vishal; Zhang, Xiang; Mehta, Apurva; Karapetrova, Evguenia; Chopdekar, Rajesh, V; Shafer, Padraic; Arenholz, Elke; Hu, Chenming; Proksch, Roger; Ramesh, Ramamoorthy; Ciston, Jim; Salahuddin, Sayeef", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced ferroelectricity in ultrathin films grown directly on silicon", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ultrathin ferroelectric materials could potentially enable low-power perovskite ferroelectric tetragonality logic and nonvolatile memories(1,2). As ferroelectric materials are made thinner, however, the ferroelectricity is usually suppressed. Size effects in ferroelectrics have been thoroughly investigated in perovskite oxides-the archetypal ferroelectric system(3). Perovskites, however, have so far proved unsuitable for thickness scaling and integration with modern semiconductor processes(4). Here we report ferroelectricity in ultrathin doped hafnium oxide (HfO2), a fluorite-structure oxide grown by atomic layer deposition on silicon. We demonstrate the persistence of inversion symmetry breaking and spontaneous, switchable polarization down to a thickness of one nullometre. Our results indicate not only the absence of a ferroelectric critical thickness but also enhanced polar distortions as film thickness is reduced, unlike in perovskite ferroelectrics. This approach to enhancing ferroelectricity in ultrathin layers could provide a route towards polarization-driven memories and ferroelectric-based advanced transistors. This work shifts the search for the fundamental limits of ferroelectricity to simpler transition-metal oxide systems-that is, from perovskite-derived complex oxides to fluorite-structure binary oxides-in which 'reverse' size effects counterintuitively stabilize polar symmetry in the ultrathin regime. Enhanced switchable ferroelectric polarization is achieved in doped hafnium oxide films grown directly onto silicon using low-temperature atomic layer deposition, even at thicknesses of just one nullometre.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 634, "Times Cited, All Databases": 670, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2020, "Volume": 580, "Issue": 7804, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 478, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-020-2208-x", "DOI Link": "http://dx.doi.org/10.1038/s41586-020-2208-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000528065800018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, Y; Pan, YH; Yang, R; Bao, LH; Meng, L; Luo, HL; Cai, YQ; Liu, GD; Zhao, WJ; Zhou, Z; Wu, LM; Zhu, ZL; Huang, M; Liu, LW; Liu, L; Cheng, P; Wu, KH; Tian, SB; Gu, CZ; Shi, YG; Guo, YF; Cheng, ZG; Hu, JP; Zhao, L; Yang, GH; Sutter, E; Sutter, P; Wang, YL; Ji, W; Zhou, XJ; Gao, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Yuan; Pan, Yu-Hao; Yang, Rong; Bao, Li-Hong; Meng, Lei; Luo, Hai-Lan; Cai, Yong-Qing; Liu, Guo-Dong; Zhao, Wen-Juan; Zhou, Zhang; Wu, Liang-Mei; Zhu, Zhi-Li; Huang, Ming; Liu, Li-Wei; Liu, Lei; Cheng, Peng; Wu, Ke-Hui; Tian, Shi-Bing; Gu, Chang-Zhi; Shi, You-Guo; Guo, Yan-Feng; Cheng, Zhi Gang; Hu, Jiang-Ping; Zhao, Lin; Yang, Guan-Hua; Sutter, Eli; Sutter, Peter; Wang, Ye-Liang; Ji, Wei; Zhou, Xing-Jiang; Gao, Hong-Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Universal mechanical exfoliation of large-area 2D crystals", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional materials provide extraordinary opportunities for exploring phenomena arising in atomically thin crystals. Beginning with the first isolation of graphene, mechanical exfoliation has been a key to provide high-quality two-dimensional materials, but despite improvements it is still limited in yield, lateral size and contamination. Here we introduce a contamination-free, one-step and universal Au-assisted mechanical exfoliation method and demonstrate its effectiveness by isolating 40 types of single-crystalline monolayers, including elemental two-dimensional crystals, metal-dichalcogenides, magnets and superconductors. Most of them are of millimeter-size and high-quality, as shown by transfer-free measurements of electron microscopy, photo spectroscopies and electrical transport. Large suspended two-dimensional crystals and heterojunctions were also prepared with high-yield. Enhanced adhesion between the crystals and the substrates enables such efficient exfoliation, for which we identify a gold-assisted exfoliation method that underpins a universal route for producing large-area monolayers and thus supports studies of fundamental properties and potential application of two-dimensional materials. Here, the authors develop a one-step, contamination-free, Au-assisted mechanical exfoliation method for 2D materials, and isolate 40 types of single-crystalline monolayers, including elemental 2D crystals, metal-dichalcogenides, magnets and superconductors with millimetre size.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 631, "Times Cited, All Databases": 687, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2453, "DOI": "10.1038/s41467-020-16266-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-16266-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000536569900051", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Koshelev, K; Kruk, S; Melik-Gaykazyan, E; Choi, JH; Bogdanov, A; Park, HG; Kivshar, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Koshelev, Kirill; Kruk, Sergey; Melik-Gaykazyan, Elizaveta; Choi, Jae-Hyuck; Bogdanov, Andrey; Park, Hong-Gyu; Kivshar, Yuri", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Subwavelength dielectric resonators for nonlinear nullophotonics", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Subwavelength optical resonators made of high-index dielectric materials provide efficient ways to manipulate light at the nulloscale through mode interferences and enhancement of both electric and magnetic fields. Such Mie-resonullt dielectric structures have low absorption, and their functionalities are limited predominulltly by radiative losses. We implement a new physical mechanism for suppressing radiative losses of individual nulloscale resonators to engineer special modes with high quality factors. optical bound states in the continuum (BICs). We demonstrate that an individual subwavelength dielectric resonator hosting a BIC mode can boost nonlinear effects increasing second-harmonic generation efficiency. Our work suggests a route to use subwavelength high-index dielectric resonators for a strong enhancement of light-matter interactions with applications to nonlinear optics, nulloscale lasers, quantum photonics, and sensors.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 697, "Times Cited, All Databases": 744, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 17", "Publication Year": 2020, "Volume": 367, "Issue": 6475, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 288, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aaz3985", "DOI Link": "http://dx.doi.org/10.1126/science.aaz3985", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000509802700037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lu, HZ; Liu, YH; Ahlawat, P; Mishra, A; Tress, WR; Eickemeyer, FT; Yang, YG; Fu, F; Wang, ZW; Avalos, CE; Carlsen, BI; Agarwalla, A; Zhang, X; Li, XG; Zhan, YQ; Zakeeruddin, SM; Emsley, L; Rothlisberger, U; Zheng, LR; Hagfeldt, A; Grätzel, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lu, Haizhou; Liu, Yuhang; Ahlawat, Paramvir; Mishra, Aditya; Tress, Wolfgang R.; Eickemeyer, Felix T.; Yang, Yingguo; Fu, Fan; Wang, Zaiwei; Avalos, Claudia E.; Carlsen, Brian, I; Agarwalla, Anulld; Zhang, Xin; Li, Xiaoguo; Zhan, Yiqiang; Zakeeruddin, Shaik M.; Emsley, Lyndon; Rothlisberger, Ursula; Zheng, Lirong; Hagfeldt, Anders; Gratzel, Michael", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Vapor-assisted deposition of highly efficient, stable black-phase FAPbI3 perovskite solar cells", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Mixtures of cations or halides with FAPbI(3) (where FA is formamidinium) lead to high efficiency in perovskite solar cells (PSCs) but also to blue-shifted absorption and long-term stability issues caused by loss of volatile methylammonium (MA) and phase segregation. We report a deposition method using MA thiocyanate (MASCN) or FASCN vapor treatment to convert yellow delta-FAPbI(3) perovskite films to the desired pure alpha-phase. NMR quantifies MA incorporation into the framework. Molecular dynamics simulations show that SCN- anions promote the formation and stabilization of alpha-FAPbI(3) below the thermodynamic phase-transition temperature. We used these low-defect-density alpha-FAPbI(3) films to make PSCs with >23% power-conversion efficiency and long-term operational and thermal stability, as well as a low (330 millivolts) open-circuit voltage loss and a low (0.75 volt) turn-on voltage of electroluminescence.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 636, "Times Cited, All Databases": 660, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 2", "Publication Year": 2020, "Volume": 370, "Issue": 6512, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 74, "End Page": "+", "Article Number": "eabb8985", "DOI": "10.1126/science.abb8985", "DOI Link": "http://dx.doi.org/10.1126/science.abb8985", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000579169000046", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, X; Dong, K; Ye, CY; Jiang, Y; Zhai, SY; Cheng, RW; Liu, D; Gao, XP; Wang, J; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Xiao; Dong, Kai; Ye, Cuiying; Jiang, Yang; Zhai, Siyuan; Cheng, Renwei; Liu, Di; Gao, Xiaoping; Wang, Jie; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A breathable, biodegradable, antibacterial, and self-powered electronic skin based on all-nullofiber triboelectric nullogenerators", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Mimicking the comprehensive functions of human sensing via electronic skins (e-skins) is highly interesting for the development of human-machine interactions and artificial intelligences. Some e-skins with high sensitivity and stability were developed; however, little attention is paid to their comfortability, environmental friendliness, and antibacterial activity. Here, we report a breathable, biodegradable, and antibacterial e-skin based on all-nullofiber triboelectric nullogenerators, which is fabricated by sandwiching silver nullowire (Ag NW) between polylactic-coglycolic acid (PLGA) and polyvinyl alcohol (PVA). With micro-to-nullo hierarchical porous structure, the e-skin has high specific surface area for contact electrification and numerous capillary channels for thermal-moisture transfer. Through adjusting the concentration of Ag NW and the selection of PVA and PLGA, the antibacterial and biodegradable capability of e-skins can be tuned, respectively. Our e-skin can achieve real-time and self-powered monitoring of whole-body physiological signal and joint movement. This work provides a previously unexplored strategy for multifunctional e-skins with excellent practicability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 715, "Times Cited, All Databases": 735, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2020, "Volume": 6, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eaba9624", "DOI": "10.1126/sciadv.aba9624", "DOI Link": "http://dx.doi.org/10.1126/sciadv.aba9624", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000543504100033", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chung, DY; Lopes, PP; Martins, PFBD; He, HY; Kawaguchi, T; Zapol, P; You, HD; Tripkovic, D; Strmcnik, D; Zhu, YS; Seifert, S; Lee, SS; Stamenkovic, VR; Markovic, NM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chung, Dong Young; Lopes, Pietro P.; Martins, Pedro Farinazzo Bergamo Dias; He, Haiying; Kawaguchi, Tomoya; Zapol, Peter; You, Hoydoo; Tripkovic, Dusan; Strmcnik, Dusan; Zhu, Yisi; Seifert, Soenke; Lee, Sungsik; Stamenkovic, Vojislav R.; Markovic, Nenad M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dynamic stability of active sites in hydr(oxy)oxides for the oxygen evolution reaction", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The poor activity and stability of electrode materials for the oxygen evolution reaction are the main bottlenecks in the water-splitting reaction for H-2 production. Here, by studying the activity-stability trends for the oxygen evolution reaction on conductive (MOxHy)-O-1, Fe-(MOxHy)-O-1 and Fe-(MMOxHy)-M-1-O-2 hydr(oxy)oxide clusters (M-1 = Ni, Co, Fe; M-2 = Mn, Co, Cu), we show that balancing the rates of Fe dissolution and redeposition over a MOxHy host establishes dynamically stable Fe active sites. Together with tuning the Fe content of the electrolyte, the strong interaction of Fe with the MOxHy host is the key to controlling the average number of Fe active sites present at the solid/liquid interface. We suggest that the Fe-M adsorption energy can therefore serve as a reaction descriptor that unifies oxygen evolution reaction catalysis on 3d transition-metal hydr(oxy)oxides in alkaline media. Thus, the introduction of dynamically stable active sites extends the design rules for creating active and stable interfaces. Understanding what underpins the activity and stability of oxygen evolution catalysts is an ongoing issue in the field of water splitting. Now, researchers show that balancing the rate of Fe dissolution and deposition over a metal hydr(oxy)oxide host yields dynamically stable Fe active sites, with the Fe-host interaction key to the performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 690, "Times Cited, All Databases": 711, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2020, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 222, "End Page": 230, "Article Number": null, "DOI": "10.1038/s41560-020-0576-y", "DOI Link": "http://dx.doi.org/10.1038/s41560-020-0576-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000520704000014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bai, NN; Wang, L; Wang, Q; Deng, J; Wang, Y; Lu, P; Huang, J; Li, G; Zhang, Y; Yang, JL; Xie, KW; Zhao, XH; Guo, CF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bai, Ningning; Wang, Liu; Wang, Qi; Deng, Jue; Wang, Yan; Lu, Peng; Huang, Jun; Li, Gang; Zhang, Yuan; Yang, Junlong; Xie, Kewei; Zhao, Xuanhe; Guo, Chuan Fei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Graded intrafillable architecture-based iontronic pressure sensor with ultra-broad-range high sensitivity", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sensitivity is a crucial parameter for flexible pressure sensors and electronic skins. While introducing microstructures (e.g., micro-pyramids) can effectively improve the sensitivity, it in turn leads to a limited pressure-response range due to the poor structural compressibility. Here, we report a strategy of engineering intrafillable microstructures that can significantly boost the sensitivity while simultaneously broadening the pressure responding range. Such intrafillable microstructures feature undercuts and grooves that accommodate deformed surface microstructures, effectively enhancing the structural compressibility and the pressure-response range. The intrafillable iontronic sensor exhibits an unprecedentedly high sensitivity (S-min > 220 kPa(-1)) over a broad pressure regime (0.08 Pa-360 kPa), and an ultrahigh pressure resolution (18 Pa or 0.0056%) over the full pressure range, together with remarkable mechanical stability. The intrafillable structure is a general design expected to be applied to other types of sensors to achieve a broader pressure-response range and a higher sensitivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 600, "Times Cited, All Databases": 631, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 209, "DOI": "10.1038/s41467-019-14054-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-14054-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000551459800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, SB; Ran, Q; Yao, RQ; Shi, H; Wen, Z; Zhao, M; Lang, XY; Jiang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Sheng-Bo; Ran, Qing; Yao, Rui-Qi; Shi, Hang; Wen, Zi; Zhao, Ming; Lang, Xing-You; Jiang, Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lamella-nullostructured eutectic zinc-aluminum alloys as reversible and dendrite-free anodes for aqueous rechargeable batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metallic zinc is an attractive anode material for aqueous rechargeable batteries because of its high theoretical capacity and low cost. However, state-of-the-art zinc anodes suffer from low coulombic efficiency and severe dendrite growth during stripping/plating processes, hampering their practical applications. Here we show that eutectic-composition alloying of zinc and aluminum as an effective strategy substantially tackles these irreversibility issues by making use of their lamellar structure, composed of alternating zinc and aluminum nullolamellas. The lamellar nullostructure not only promotes zinc stripping from precursor eutectic Zn88Al12 (at%) alloys, but produces core/shell aluminum/aluminum sesquioxide interlamellar nullopatterns in situ to in turn guide subsequent growth of zinc, enabling dendrite-free zinc stripping/plating for more than 2000h in oxygen-absent aqueous electrolyte. These outstanding electrochemical properties enlist zinc-ion batteries constructed with Zn88Al12 alloy anode and KxMnO2 cathode to deliver high-density energy at high levels of electrical power and retain 100% capacity after 200hours. Aqueous rechargeable Zn-ion batteries are attractive energy storage devices, but their wide adoption is impeded by the irreversible metallic Zn anode. Here the authors report lamellar-nullostructured eutectic Zn/Al alloys as reversible and dendrite-free anodes for improved battery performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 596, "Times Cited, All Databases": 619, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 2", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1634, "DOI": "10.1038/s41467-020-15478-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15478-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000525081200010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zou, HY; Guo, LT; Xue, H; Zhang, Y; Shen, XF; Liu, XT; Wang, PH; He, X; Dai, GZ; Jiang, P; Zheng, HW; Zhang, BB; Xu, C; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zou, Haiyang; Guo, Litong; Xue, Hao; Zhang, Ying; Shen, Xiaofang; Liu, Xiaoting; Wang, Peihong; He, Xu; Dai, Guozhang; Jiang, Peng; Zheng, Haiwu; Zhang, Binbin; Xu, Cheng; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quantifying and understanding the triboelectric series of inorganic non-metallic materials", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Contact-electrification is a universal effect for all existing materials, but it still lacks a quantitative materials database to systematically understand its scientific mechanisms. Using an established measurement method, this study quantifies the triboelectric charge densities of nearly 30 inorganic nonmetallic materials. From the matrix of their triboelectric charge densities and band structures, it is found that the triboelectric output is strongly related to the work functions of the materials. Our study verifies that contact-electrification is an electronic quantum transition effect under ambient conditions. The basic driving force for contact-electrification is that electrons seek to fill the lowest available states once two materials are forced to reach atomically close distance so that electron transitions are possible through strongly overlapping electron wave functions. We hope that the quantified series could serve as a textbook standard and a fundamental database for scientific research, practical manufacturing, and engineering. The mechanism of contact electrification remains a topic of debate. Here, the authors present a quantitative database of the triboelectric charge density and band structure of many inorganic materials, verifying that contact electrification between solids is an electron quantum transition effect.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 626, "Times Cited, All Databases": 647, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 29", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2093, "DOI": "10.1038/s41467-020-15926-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15926-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000531855500023", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cai, ST; Hao, SQ; Luo, ZZ; Li, X; Hadar, I; Bailey, T; Hu, XB; Uher, C; Hu, YY; Wolverton, C; Dravid, VP; Kanatzidis, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cai, Songting; Hao, Shiqiang; Luo, Zhong-Zhen; Li, Xiang; Hadar, Ido; Bailey, Trevor; Hu, Xiaobing; Uher, Ctirad; Hu, Yan-Yan; Wolverton, Christopher; Dravid, Vinayak P.; Kanatzidis, Mercouri G.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Discordant nature of Cd in PbSe: off-centering and core-shell nulloscale CdSe precipitates lead to high thermoelectric performance", "Source Title": "ENERGY & ENVIRONMENTAL SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We report a novel hierarchical microstructure in the PbSe-CdSe system, which collectively contributes to significant enhancement in thermoelectric performance, with ZT(ave) similar to 0.83 across the 400-923 K temperature range, the highest reported for p-type, Te-free PbSe systems. We have investigated the local atomic structure as well as the microstructure of a series of PbSe-xCdSe materials, up to x = 10%. We find that the behavior of the Cd atoms in the octahedral rock salt sites is discordant and results in off-center displacement and distortion. Such off-centered Cd in the PbSe matrix creates (1) L-sigma electronic energy band convergence, (2) a flattened L band, both contributing to higher Seebeck coefficients, and (3) enhanced phonon scattering, which leads to lower thermal conductivity. These conclusions are supported by photoemission yield spectroscopy in air (PYSA), solid state Cd-111, Se-77 NMR spectroscopy and DFT calculations. Above the solubility limit (>6%CdSe), we also observe endotaxial CdSe nullo-precipitates with core-shell architecture formed in PbSe, whose size, distribution and structure gradually change with the Cd content. The nullo-precipitates exhibit a zinc blende crystal structure and a tetrahedral shape with significant local strain, but are covered with a thin wurtzite layer along the precipitate/matrix interface, creating a core-shell structure embedded in PbSe. This newly discovered architecture causes a further reduction in lattice thermal conductivity. Moreover, potassium is found to be an effective p-type dopant in the PbSe-CdSe system, leading to an enhanced power factor, a maximum ZT of similar to 1.4 at 923 K for Pb0.98K0.02Se-6%CdSe.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 456, "Times Cited, All Databases": 622, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2020, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 200, "End Page": 211, "Article Number": null, "DOI": "10.1039/c9ee03087e", "DOI Link": "http://dx.doi.org/10.1039/c9ee03087e", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000508857600012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Attia, PM; Grover, A; Jin, N; Severson, KA; Markov, TM; Liao, YH; Chen, MH; Cheong, B; Perkins, N; Yang, Z; Herring, PK; Aykol, M; Harris, SJ; Braatz, RD; Ermon, S; Chueh, WC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Attia, Peter M.; Grover, Aditya; Jin, Norman; Severson, Kristen A.; Markov, Todor M.; Liao, Yang-Hung; Chen, Michael H.; Cheong, Bryan; Perkins, Nicholas; Yang, Zi; Herring, Patrick K.; Aykol, Muratahan; Harris, Stephen J.; Braatz, Richard D.; Ermon, Stefano; Chueh, William C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Closed-loop optimization of fast-charging protocols for batteries with machine learning", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Simultaneously optimizing many design parameters in time-consuming experiments causes bottlenecks in a broad range of scientific and engineering disciplines(1,2). One such example is process and control optimization for lithium-ion batteries during materials selection, cell manufacturing and operation. A typical objective is to maximize battery lifetime; however, conducting even a single experiment to evaluate lifetime can take months to years(3-5). Furthermore, both large parameter spaces and high sampling variability(3,6,7) necessitate a large number of experiments. Hence, the key challenge is to reduce both the number and the duration of the experiments required. Here we develop and demonstrate a machine learning methodology to efficiently optimize a parameter space specifying the current and voltage profiles of six-step, ten-minute fast-charging protocols for maximizing battery cycle life, which can alleviate range anxiety for electric-vehicle users(8,9). We combine two key elements to reduce the optimization cost: an early-prediction model(5), which reduces the time per experiment by predicting the final cycle life using data from the first few cycles, and a Bayesian optimization algorithm(10,11), which reduces the number of experiments by balancing exploration and exploitation to efficiently probe the parameter space of charging protocols. Using this methodology, we rapidly identify high-cycle-life charging protocols among 224 candidates in 16 days (compared with over 500 days using exhaustive search without early prediction), and subsequently validate the accuracy and efficiency of our optimization approach. Our closed-loop methodology automatically incorporates feedback from past experiments to inform future decisions and can be generalized to other applications in battery design and, more broadly, other scientific domains that involve time-intensive experiments and multi-dimensional design spaces.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 538, "Times Cited, All Databases": 577, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 20", "Publication Year": 2020, "Volume": 578, "Issue": 7795, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 397, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-020-1994-5", "DOI Link": "http://dx.doi.org/10.1038/s41586-020-1994-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000543762000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jia, ZW; Yuan, CX; Liu, YF; Wang, XJ; Sun, P; Wang, L; Jiang, HC; Jiang, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jia, Zhenwei; Yuan, Chenxu; Liu, Yongfu; Wang, Xiao-Jun; Sun, Peng; Wang, Lei; Jiang, Haochuan; Jiang, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strategies to approach high performance in Cr3+-doped phosphors for high-power NIR-LED light sources", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Optics: Visibly powerful near-infrared light-emitting diodes A near-infrared light-emitting (NIR-LED) diode that emits high-power light could pave the way for the development of next-generation monitoring and detecting devices. Although solid-state NIR-LEDs are used in such devices, their narrow emission band limits their range of applications. Broadband NIR-emitting phosphor-converted LEDs offer the best solution. However, creating NIR phosphors that are sufficiently excited by blue light is challenging. Now, a team of Chinese and American researchers, led by Yongfu Liu from the Chinese Academy of Sciences, has created a NIR-LED that emits light in the 700-900 nm with an output of 109.9 mW at 520 mA after excitation with blue light. The device has the highest recorded power rating to date and could be used in applications from bioimaging and night-vision technologies, to monitoring food and medicines. Broadband near-infrared (NIR)-emitting phosphors are key for next-generation smart NIR light sources based on blue LEDs. To achieve excellent NIR phosphors, we propose a strategy of enhancing the crystallinity, modifying the micromorphology, and maintaining the valence state of Cr3+ in Ca3Sc2Si3O12 garnet (CSSG). By adding fluxes and sintering in a reducing atmosphere, the internal quantum efficiency (IQE) is greatly enhanced to 92.3%. The optimized CSSG:6%Cr3+ exhibits excellent thermal stability. At 150 degrees C, 97.4% of the NIR emission at room temperature can be maintained. The fabricated NIR-LED device emits a high optical power of 109.9 mW at 520 mA. The performances of both the achieved phosphor and the NIR-LED are almost the best results until now. The mechanism for the optimization is investigated. An application of the NIR-LED light source is demonstrated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 561, "Times Cited, All Databases": 587, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 15", "Publication Year": 2020, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 86, "DOI": "10.1038/s41377-020-0326-8", "DOI Link": "http://dx.doi.org/10.1038/s41377-020-0326-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000533075300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Snyder, GJ; Snyder, AH; Wood, M; Gurunathan, R; Snyder, BH; Niu, CN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Snyder, G. Jeffrey; Snyder, Alemayouh H.; Wood, Maxwell; Gurunathan, Ramya; Snyder, Berhanu H.; Niu, Changning", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Weighted Mobility", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Engineering semiconductor devices requires an understanding of charge carrier mobility. Typically, mobilities are estimated using Hall effect and electrical resistivity meausrements, which are are routinely performed at room temperature and below, in materials with mobilities greater than 1 cm(2) V-1 s(-1). With the availability of combined Seebeck coefficient and electrical resistivity measurement systems, it is now easy to measure the weighted mobility (electron mobility weighted by the density of electronic states). A simple method to calculate the weighted mobility from Seebeck coefficient and electrical resistivity measurements is introduced, which gives good results at room temperature and above, and for mobilities as low as 10(-3) cm(2) V-1 s(-1), mu w=331cm2Vs(m omega cm rho) (T300 K)-3/2[ exp[ |S|kB/e-2]1+exp[-5(|S|kB/e-1) ]+3 pi 2|S|kB/e1+exp[5(|S|kB/e-1) ] ]Here, mu(w) is the weighted mobility, rho is the electrical resistivity measured in m omega cm, T is the absolute temperature in K, S is the Seebeck coefficient, and k(B)/e = 86.3 mu V K-1. Weighted mobility analysis can elucidate the electronic structure and scattering mechanisms in materials and is particularly helpful in understanding and optimizing thermoelectric systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 640, "Times Cited, All Databases": 656, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2020, "Volume": 32, "Issue": 25, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2001537, "DOI": "10.1002/adma.202001537", "DOI Link": "http://dx.doi.org/10.1002/adma.202001537", "Book DOI": null, "Early Access Date": "MAY 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000532658500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, CL; Wang, HL; Wang, F; Li, TF; Xu, MJ; Wang, H; Wang, Z; Zhan, XW; Hu, WD; Shen, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Chenglong; Wang, Hailu; Wang, Fang; Li, Tengfei; Xu, Mengjian; Wang, Hao; Wang, Zhen; Zhan, Xiaowei; Hu, Weida; Shen, Liang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrafast and broadband photodetectors based on a perovskite/organic bulk heterojunction for large-dynamic-range imaging", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskites peer into near-infrared Novel photodetectors developed by researchers in China provide imaging in the near-infrared (NIR) region with record-breaking efficiency and speed. A new class of semiconducting materials called organic-inorganic hybrid perovskites (OIHPs) display excellent optical and electrical properties for thin-film solar cells, LEDs and light detectors. To expand their detection range to NIR, which is useful for biomedical applications, OIHPs can be combined with structures called organic bulk-heterojunctions (BHJs). Now, Weida Hu, Liang Shen and co-workers at Jilin University, Chinese Academy of Sciences and Peking University have designed new OIHP-BHJ photodetectors that efficiently detect a wide range of both visible and NIR radiation. Their prototype sensors have ultra-fast response times of just 5.6 nulloseconds and remain sensitive even in low brightness, suggesting that they could accelerate the movement of OIHP devices from lab tests to commercial imaging. Organic-inorganic hybrid perovskite (OIHP) photodetectors that simultaneously achieve an ultrafast response and high sensitivity in the near-infrared (NIR) region are prerequisites for expanding current monitoring, imaging, and optical communication capbilities. Herein, we demonstrate photodetectors constructed by OIHP and an organic bulk heterojunction (BHJ) consisting of a low-bandgap nonfullerene and polymer, which achieve broadband response spectra up to 1 mu m with a highest external quantum efficiency of approximately 54% at 850 nm, an ultrafast response speed of 5.6 ns and a linear dynamic range (LDR) of 191 dB. High sensitivity, ultrafast speed and a large LDR are preeminent prerequisites for the practical application of photodetectors. Encouragingly, due to the high-dynamic-range imaging capacity, high-quality visible-NIR actual imaging is achieved by employing the OIHP photodetectors. We believe that state-of-the-art OIHP photodetectors can accelerate the translation of solution-processed photodetector applications from the laboratory to the imaging market.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 537, "Times Cited, All Databases": 565, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 3", "Publication Year": 2020, "Volume": 9, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 31, "DOI": "10.1038/s41377-020-0264-5", "DOI Link": "http://dx.doi.org/10.1038/s41377-020-0264-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000517904800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, LL; Wei, ZY; Wan, CZ; Li, J; Chen, Z; Zhu, D; Baumann, D; Liu, HT; Allen, CS; Xu, X; Kirkland, AI; Shakir, I; Almutairi, Z; Tolbert, S; Dunn, B; Huang, Y; Sautet, P; Duan, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Lele; Wei, Ziyang; Wan, Chengzhang; Li, Jing; Chen, Zhuo; Zhu, Dan; Baumann, Daniel; Liu, Haotian; Allen, Christopher S.; Xu, Xiang; Kirkland, Angus I.; Shakir, Imran; Almutairi, Zeyad; Tolbert, Sarah; Dunn, Bruce; Huang, Yu; Sautet, Philippe; Duan, Xiangfeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A fundamental look at electrocatalytic sulfur reduction reaction", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The fundamental kinetics of the electrocatalytic sulfur reduction reaction (SRR), a complex 16-electron conversion process in lithium-sulfur batteries, is so far insufficiently explored. Here, by directly profiling the activation energies in the multistep SRR, we reveal that the initial reduction of sulfur to the soluble polysulfides is relatively easy owing to the low activation energy, whereas the subsequent conversion of the polysulfides into the insoluble Li2S2/Li2S has a much higher activation energy, contributing to the accumulation of polysulfides and exacerbating the polysulfide shuttling effect. We use heteroatom-doped graphene as a model system to explore electrocatalytic SRR. We show that nitrogen and sulfur dual-doped graphene considerably reduces the activation energy to improve SRR kinetics. Density functional calculations confirm that the doping tunes the p-band centre of the active carbons for an optimal adsorption strength of intermediates and electroactivity. This study establishes electrocatalysis as a promising pathway to tackle the fundamental challenges facing lithium-sulfur batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 593, "Times Cited, All Databases": 612, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2020, "Volume": 3, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 762, "End Page": 770, "Article Number": null, "DOI": "10.1038/s41929-020-0498-x", "DOI Link": "http://dx.doi.org/10.1038/s41929-020-0498-x", "Book DOI": null, "Early Access Date": "AUG 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000564491500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, RJ; Liu, LJ; Lu, Y; Wang, CC; Li, YX; Li, L; Yan, ZH; Chen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Ruijuan; Liu, Luojia; Lu, Yong; Wang, Chenchen; Li, Yixin; Li, Lin; Yan, Zhenhua; Chen, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Nitrogen-rich covalent organic frameworks with multiple carbonyls for high-performance sodium batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Covalent organic frameworks with designable periodic skeletons and ordered nullopores have attracted increasing attention as promising cathode materials for rechargeable batteries. However, the reported cathodes are plagued by limited capacity and unsatisfying rate performance. Here we report a honeycomb-like nitrogen-rich covalent organic framework with multiple carbonyls. The sodium storage ability of pyrazines and carbonyls and the up-to twelve sodium-ion redox chemistry mechanism for each repetitive unit have been demonstrated by in/ex-situ Fourier transform infrared spectra and density functional theory calculations. The insoluble electrode exhibits a remarkably high specific capacity of 452.0 mAh g(-1), excellent cycling stability (similar to 96% capacity retention after 1000 cycles) and high rate performance (134.3 mAh g(-1) at 10.0 A g(-1)). Furthermore, a pouch-type battery is assembled, displaying the gravimetric and volumetric energy density of 101.1 Wh kg(cell)(-1) and 78.5 Wh L-cell(-1), respectively, indicating potentially practical applications of conjugated polymers in rechargeable batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 561, "Times Cited, All Databases": 570, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 178, "DOI": "10.1038/s41467-019-13739-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-13739-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000551458600007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gao, JJ; Yang, HB; Huang, X; Hung, SF; Cai, WZ; Jia, CM; Miao, S; Chen, HM; Yang, XF; Huang, YQ; Zhang, T; Liu, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gao, Jiajian; Yang, Hong Bin; Huang, Xiang; Hung, Sung-Fu; Cai, Weizheng; Jia, Chunmiao; Miao, Shu; Chen, Hao Ming; Yang, Xiaofeng; Huang, Yanqiang; Zhang, Tao; Liu, Bin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enabling Direct H2O2 Production in Acidic Media through Rational Design of Transition Metal Single Atom Catalyst", "Source Title": "CHEM", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electrochemical oxygen reduction reaction in acidic media offers an attractive route for direct hydrogen peroxide (H2O2) generation and on-site applications, Unfortunately there is still a lack of cost-effective electrocatalysts with high catalytic performance. Here, we theoretically designed and experimentally demonstrated that a cobalt single-atom catalyst (Co SAC) anchored in nitrogen-doped graphene, with optimized adsorption energy of the *OOH intermediate, exhibited a high H2O2 production rate, which even slightly outperformed the state-of-the-art noble-metal-based electrocatalysts. The kinetic current of H2O2 production over Co SAC could reach 1 mA/cm(disk)(2) at 0.6 V versus reversible hydrogen electrode in 0.1 M HClO4 with H2O2 faraday efficiency > 90%, and these performance measures could be sustained for 10 h without decay. Further kinetic analysis and operando X-ray absorption study combined with density functional theory (DFT) calculation demonstrated that the nitrogen-coordinated single Co atom was the active site and the reaction was rate-limited by the first electron transfer step.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 534, "Times Cited, All Databases": 562, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 12", "Publication Year": 2020, "Volume": 6, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 658, "End Page": 674, "Article Number": null, "DOI": "10.1016/j.chempr.2019.12.008", "DOI Link": "http://dx.doi.org/10.1016/j.chempr.2019.12.008", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000519997200011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, YH; Sakai, N; Da, P; Wu, JY; Sansom, HC; Ramadan, AJ; Mahesh, S; Liu, JL; Oliver, RDJ; Lim, J; Aspitarte, L; Sharma, K; Madhu, PK; Morales-Vilches, AB; Nayak, PK; Bai, S; Gao, F; Grovenor, CRM; Johnston, MB; Labram, JG; Durrant, JR; Ball, JM; Wenger, B; Stannowski, B; Snaith, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Yen-Hung; Sakai, Nobuya; Da, Peimei; Wu, Jiaying; Sansom, Harry C.; Ramadan, Alexandra J.; Mahesh, Suhas; Liu, Junliang; Oliver, Robert D. J.; Lim, Jongchul; Aspitarte, Lee; Sharma, Kshama; Madhu, P. K.; Morales-Vilches, Anna B.; Nayak, Pabitra K.; Bai, Sai; Gao, Feng; Grovenor, Chris R. M.; Johnston, Michael B.; Labram, John G.; Durrant, James R.; Ball, James M.; Wenger, Bernard; Stannowski, Bernd; Snaith, Henry J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A piperidinium salt stabilizes efficient metal-halide perovskite solar cells", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Longevity has been a long-standing concern for hybrid perovskite photovoltaics. We demonstrate high-resilience positive-intrinsic-negative perovskite solar cells by incorporating a piperidinium-based ionic compound into the formamidinium-cesium lead-trihalide perovskite absorber. With the bandgap tuned to be well suited for perovskite-on-silicon tandem cells, this piperidinium additive enhances the open-circuit voltage and cell efficiency. This additive also retards compositional segregation into impurity phases and pinhole formation in the perovskite absorber layer during aggressive aging. Under full-spectrum simulated sunlight in ambient atmosphere, our unencapsulated and encapsulated cells retain 80 and 95% of their peak and post-burn-in efficiencies for 1010 and 1200 hours at 60 degrees and 85 degrees C, respectively. Our analysis reveals detailed degradation routes that contribute to the failure of aged cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 540, "Times Cited, All Databases": 567, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 3", "Publication Year": 2020, "Volume": 369, "Issue": 6499, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 96, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aba1628", "DOI Link": "http://dx.doi.org/10.1126/science.aba1628", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000548751700053", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Todaro, CJ; Easton, MA; Qiu, D; Zhang, D; Bermingham, MJ; Lui, EW; Brandt, M; StJohn, DH; Qian, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Todaro, C. J.; Easton, M. A.; Qiu, D.; Zhang, D.; Bermingham, M. J.; Lui, E. W.; Brandt, M.; StJohn, D. H.; Qian, M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Grain structure control during metal 3D printing by high-intensity ultrasound", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Additive manufacturing (AM) of metals, also known as metal 3D printing, typically leads to the formation of columnar grain structures along the build direction in most as-built metals and alloys. These long columnar grains can cause property anisotropy, which is usually detrimental to component qualification or targeted applications. Here, without changing alloy chemistry, we demonstrate an AM solidification-control solution to printing metallic alloys with an equiaxed grain structure and improved mechanical properties. Using the titanium alloy Ti-6Al-4V as a model alloy, we employ high-intensity ultrasound to achieve full transition from columnar grains to fine (similar to 100 mu m) equiaxed grains in AM Ti-6Al-4V samples by laser powder deposition. This results in a 12% improvement in both the yield stress and tensile strength compared with the conventional AM columnar Ti-6Al-4V. We further demonstrate the generality of our technique by achieving similar grain structure control results in the nickel-based superalloy Inconel 625, and expect that this method may be applicable to other metallic materials that exhibit columnar grain structures during AM.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 525, "Times Cited, All Databases": 574, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 9", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 142, "DOI": "10.1038/s41467-019-13874-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-13874-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000511897900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, WH; Du, XF; Zhao, JW; Chen, Z; Li, JJ; Xie, J; Zhang, YJ; Cui, ZL; Kong, QY; Zhao, ZM; Wang, CG; Zhang, QC; Cui, GL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Wuhai; Du, Xiaofan; Zhao, Jingwen; Chen, Zheng; Li, Jiajia; Xie, Jian; Zhang, Yaojian; Cui, Zili; Kong, Qingyu; Zhao, Zhiming; Wang, Cunguo; Zhang, Qichun; Cui, Guanglei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hydrated Eutectic Electrolytes with Ligand-Oriented Solvation Shells for Long-Cycling Zinc-Organic Batteries", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite their intrinsic safety and cost-effectiveness, aqueous zinc (Zn)-organic batteries have been struggling with the rapid performance degradation arising from the poor reversibility of Zn anodes and the dissolution of cathodes. Here, we present a new aqueous eutectic electrolyte by coupling a hydrated Zn salt (Zn(ClO4)(2)center dot 6H(2)O) exclusively with a neutral ligand (succinonitrile) to mitigate these issues. The unique aqua Zn2+ solvates with a succinonitrile-assisted solvation shell enable an unusual Zn/Zn2+ reversibility of 98.4% Coulombic efficiency along with smooth Zn deposition. Moreover, all water molecules contribute to the formation of the eutectic network, resulting in a delayed oxidation and suppressed solvating ability. When a quinone-based polymermaterial (38 wt% sulfur content) is utilized as a cathode, the Zn-organic battery with this aqueous eutectic electrolyte exhibits an unprecedented cyclability with a low capacity decay rate (0.004% per cycle over 3,500 cycles) and superior low-temperature performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 546, "Times Cited, All Databases": 565, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 15", "Publication Year": 2020, "Volume": 4, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1557, "End Page": 1574, "Article Number": null, "DOI": "10.1016/j.joule.2020.05.018", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2020.05.018", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000551427400020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xie, XH; He, C; Li, BY; He, YH; Cullen, DA; Wegener, EC; Kropf, AJ; Martinez, U; Cheng, YW; Engelhard, MH; Bowden, ME; Song, M; Lemmon, T; Li, XS; Nie, ZM; Liu, J; Myers, DJ; Zelenay, P; Wang, GF; Wu, G; Ramani, V; Shao, YY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xie, Xiaohong; He, Cheng; Li, Boyang; He, Yanghua; Cullen, David A.; Wegener, Evan C.; Kropf, A. Jeremy; Martinez, Ulises; Cheng, Yingwen; Engelhard, Mark H.; Bowden, Mark E.; Song, Miao; Lemmon, Teresa; Li, Xiaohong S.; Nie, Zimin; Liu, Jian; Myers, Deborah J.; Zelenay, Piotr; Wang, Guofeng; Wu, Gang; Ramani, Vijay; Shao, Yuyan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Performance enhancement and degradation mechanism identification of a single-atom Co-N-C catalyst for proton exchange membrane fuel cells", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of catalysts free of platinum-group metals and with both a high activity and durability for the oxygen reduction reaction in proton exchange membrane fuel cells is a grand challenge. Here we report an atomically dispersed Co and N co-doped carbon (Co-N-C) catalyst with a high catalytic oxygen reduction reaction activity comparable to that of a similarly synthesized Fe-N-C catalyst but with a four-time enhanced durability. The Co-N-C catalyst achieved a current density of 0.022 A cm(-2) at 0.9 ViR-free (internal resistance-compensated voltage) and peak power density of 0.64 W cm(-2) in 1.0 bar H-2/O-2 fuel cells, higher than that of non-iron platinum-group-metal-free catalysts reported in the literature. Importantly, we identified two main degradation mechanisms for metal (M)-N-C catalysts: catalyst oxidation by radicals and active-site demetallation. The enhanced durability of Co-N-C relative to Fe-N-C is attributed to the lower activity of Co ions for Fenton reactions that produce radicals from the main oxygen reduction reaction by-product, H2O2, and the significantly enhanced resistance to demetallation of Co-N-C.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 538, "Times Cited, All Databases": 568, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2020, "Volume": 3, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1044, "End Page": 1054, "Article Number": null, "DOI": "10.1038/s41929-020-00546-1", "DOI Link": "http://dx.doi.org/10.1038/s41929-020-00546-1", "Book DOI": null, "Early Access Date": "NOV 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000594808400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, N; Feng, XB; Rao, DW; Deng, X; Cai, LJ; Qiu, BC; Long, R; Xiong, YJ; Lu, Y; Chai, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Ning; Feng, Xiaobin; Rao, Dewei; Deng, Xi; Cai, Lejuan; Qiu, Bocheng; Long, Ran; Xiong, Yujie; Lu, Yang; Chai, Yang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lattice oxygen activation enabled by high-valence metal sites for enhanced water oxidation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Anodic oxygen evolution reaction (OER) is recognized as kinetic bottleneck in water electrolysis. Transition metal sites with high valence states can accelerate the reaction kinetics to offer highly intrinsic activity, but suffer from thermodynamic formation barrier. Here, we show subtle engineering of highly oxidized Ni4+ species in surface reconstructed (oxy)hydroxides on multicomponent FeCoCrNi alloy film through interatomically electronic interplay. Our spectroscopic investigations with theoretical studies uncover that Fe component enables the formation of Ni4+ species, which is energetically favored by the multistep evolution of Ni2+-> Ni3+-> Ni4+. The dynamically constructed Ni4+ species drives holes into oxygen ligands to facilitate intramolecular oxygen coupling, triggering lattice oxygen activation to form Fe-Ni dual-sites as ultimate catalytic center with highly intrinsic activity. As a result, the surface reconstructed FeCoCrNi OER catalyst delivers outstanding mass activity and turnover frequency of 3601A g(metal)(-1) and 0.483s(-1) at an overpotential of 300mV in alkaline electrolyte, respectively. Electrocatalytic water oxidation is facilitated by high valence states, but these are challenging to achieve at low applied potentials. Here, authors report a multicomponent FeCoCrNi alloy with dynamically formed Ni4+ species to offer high catalytic activity via lattice oxygen activation mechanism.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 543, "Times Cited, All Databases": 553, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 13", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4066, "DOI": "10.1038/s41467-020-17934-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-17934-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000564248600004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, F; Meng, AY; Cheng, B; Ho, WK; Yu, JG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Fei; Meng, Aiyun; Cheng, Bei; Ho, Wingkei; Yu, Jiaguo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced photocatalytic H2-production activity of WO3/TiO2 step-scheme heterojunction by graphene modification", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sunlight-driven photocatalytic water-splitting for hydrogen (H-2) evolution is a desirable strategy to utilize solar energy. However, this strategy is restricted by insufficient light harvesting and high photogenerated electron-hole recombination rates of TiO2-based photocatalysts. Here, a graphene-modified WO3/TiO2 step-scheme heterojunction (S-scheme heterojunction) composite photocatalyst was fabricated by a facile one-step hydrothermal method. In the ternary composite, TiO2 and WO3 nulloparticles adhered closely to reduced graphene oxide (rGO) and formed a novel S-scheme heterojunction. Moreover, rGO in the composite not only supplied abundant adsorption and catalytically active sites as an ideal support but also promoted electron separation and transfer from the conduction band of TiO2 by forming a Schottky junction between TiO2 and rGO. The positive cooperative effect of the S-scheme heterojunction formed between WO3 and TiO2 and the Schottky heterojunction formed between TiO2 and graphene sheets suppressed the recombination of relatively useful electrons and holes. This effect also enhanced the light harvesting and promoted the reduction reaction at the active sites. Thus, the novel ternary WO3/TiO2/rGO composite demonstrated a remarkably enhanced photocatalytic H-2 evolution rate of 245.8 Fmol g(-1) h(-1), which was approximately 3.5-fold that of pure TiO2. This work not only presents a low-cost graphene-based S-scheme heterojunction photocatalyst that was obtained via a feasible one-step hydrothermal approach to realize highly efficient H-2 generation without using noble metals, but also provides new insights into the design of novel heterojunction photocatalysts. (C) 2020, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 531, "Times Cited, All Databases": 556, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2020, "Volume": 41, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 9, "End Page": 20, "Article Number": null, "DOI": "10.1016/S1872-2067(19)63382-6", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(19)63382-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000495145800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, SS; Li, Q; Xue, HG; Pang, H; Xu, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Shasha; Li, Qing; Xue, Huaiguo; Pang, Huan; Xu, Qiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A highly alkaline-stable metal oxide@metal-organic framework composite for high-performance electrochemical energy storage", "Source Title": "NATIONAL SCIENCE REVIEW", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Most metal-organic frameworks (MOFs) hardly maintain their physical and chemical properties after exposure to alkaline aqueous solutions, thus precluding their use as potential electrode materials for electrochemical energy storage devices. Here, we present the design and synthesis of a highly alkaline-stable metal oxide@MOF composite, Co3O4 nullocube@Co-MOF (Co3O4@Co-MOF), via a controllable and facile one-pot hydrothermal method under highly alkaline conditions. The obtained composite possesses exceptional alkaline stability, retaining its original structure in 3.0 M KOH for at least 15 days. Benefitting from the exceptional alkaline stability, unique structure, and larger surface area, the Co3O4@Co-MOF composite shows a specific capacitance as high as 1020 F g(-1) at 0.5 A g(-1) and a high cycling stability with only 3.3% decay after 5000 cycles at 5 A g(-1). The as-constructed solid-state flexible device exhibits a maximum energy density of 21.6 mWh cm(-3).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 541, "Times Cited, All Databases": 555, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2020, "Volume": 7, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 305, "End Page": 314, "Article Number": null, "DOI": "10.1093/nsr/nwz137", "DOI Link": "http://dx.doi.org/10.1093/nsr/nwz137", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000528014900011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, SQ; Xu, L; Wang, AC; Wang, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Shiquan; Xu, Liang; Chi Wang, Aurelia; Wang, Zhong Lin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Quantifying electron-transfer in liquid-solid contact electrification and the formation of electric double-layer", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Contact electrification (CE) has been known for more than 2600 years but the nature of charge carriers and their transfer mechanisms still remain poorly understood, especially for the cases of liquid-solid CE. Here, we study the CE between liquids and solids and investigate the decay of CE charges on the solid surfaces after liquid-solid CE at different thermal conditions. The contribution of electron transfer is distinguished from that of ion transfer on the charged surfaces by using the theory of electron thermionic emission. Our study shows that there are both electron transfer and ion transfer in the liquid-solid CE. We reveal that solutes in the solution, pH value of the solution and the hydrophilicity of the solid affect the ratio of electron transfers to ion transfers. Further, we propose a two-step model of electron or/and ion transfer and demonstrate the formation of electric double-layer in liquid-solid CE.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 537, "Times Cited, All Databases": 554, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 21", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 399, "DOI": "10.1038/s41467-019-14278-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-019-14278-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000511940400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, KJ; Liu, K; An, PD; Li, HJW; Lin, YY; Hu, JH; Jia, CK; Fu, JW; Li, HM; Liu, H; Lin, Z; Li, WZ; Li, JH; Lu, YR; Chan, TS; Zhang, N; Liu, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Kejun; Liu, Kang; An, Pengda; Li, Huangjingwei; Lin, Yiyang; Hu, Junhua; Jia, Chuankun; Fu, Junwei; Li, Hongmei; Liu, Hui; Lin, Zhang; Li, Wenzhang; Li, Jiahang; Lu, Ying-Rui; Chan, Ting-Shan; Zhang, Ning; Liu, Min", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Iron phthalocyanine with coordination induced electronic localization to boost oxygen reduction reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Iron phthalocyanine (FePc) is a promising non-precious catalyst for the oxygen reduction reaction (ORR). Unfortunately, FePc with plane-symmetric FeN4 site usually exhibits an unsatisfactory ORR activity due to its poor O-2 adsorption and activation. Here, we report an axial Fe-O coordination induced electronic localization strategy to improve its O-2 adsorption, activation and thus the ORR performance. Theoretical calculations indicate that the Fe-O coordination evokes the electronic localization among the axial direction of O-FeN4 sites to enhance O-2 adsorption and activation. To realize this speculation, FePc is coordinated with an oxidized carbon. Synchrotron X-ray absorption and Mossbauer spectra validate Fe-O coordination between FePc and carbon. The obtained catalyst exhibits fast kinetics for O-2 adsorption and activation with an ultralow Tafel slope of 27.5mVdec(-1) and a remarkable half-wave potential of 0.90V. This work offers a new strategy to regulate catalytic sites for better performance. Iron phthalocyanine with a 2D structure and symmetric electron distribution around Fe-N-4 active sites is not optimal for O-2 adsorption and activation. Here, the authors report an axial Fe-O coordination induced electronic localization strategy to enhance oxygen reduction reaction performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 540, "Times Cited, All Databases": 553, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 20", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4173, "DOI": "10.1038/s41467-020-18062-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-18062-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000568893000012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Himanen, L; Jäger, MOJ; Morooka, EV; Canova, FF; Ranawat, YS; Gao, DZ; Rinke, P; Foster, AS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Himanen, Lauri; Jager, Marc O. J.; Morooka, Eiaki, V; Canova, Filippo Federici; Ranawat, Yashasvi S.; Gao, David Z.; Rinke, Patrick; Foster, Adam S.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "DScribe: Library of descriptors for machine learning in materials science", "Source Title": "COMPUTER PHYSICS COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "DScribe is a software package for machine learning that provides popular feature transformations (descriptors) for atomistic materials simulations. DScribe accelerates the application of machine learning for atomistic property prediction by providing user-friendly, off-the-shelf descriptor implementations. The package currently contains implementations for Coulomb matrix, Ewald sum matrix, sine matrix, Many-body Tensor Representation (MBTR), Atom-centered Symmetry Function (ACSF) and Smooth Overlap of Atomic Positions (SOAP). Usage of the package is illustrated for two different applications: formation energy prediction for solids and ionic charge prediction for atoms in organic molecules. The package is freely available under the open-source Apache License 2.0. Program summary Program Title: DScribe Program Files doi: http://dx.doLorg/10.17632/vzrs8n8pk6.1 Licensing provisions: Apache-2.0 Programming language: Python/C/C++ Supplementary material: Supplementary Information as PDF Nature of problem: The application of machine learning for materials science is hindered by the lack of consistent software implementations for feature transformations. These feature transformations, also called descriptors, are a key step in building machine learning models for property prediction in materials science. Solution method: We have developed a library for creating common descriptors used in machine learning applied to materials science. We provide an implementation the following descriptors: Coulomb matrix, Ewald sum matrix, sine matrix, Many-body Tensor Representation (MBTR), Atom centered Symmetry Functions (ACSF) and Smooth Overlap of Atomic Positions (SOAP). The library has a python interface with computationally intensive routines written in C or C++. The source code, tutorials and documentation are provided online. A continuous integration mechanism is set up to automatically run a series of regression tests and check code coverage when the codebase is updated. (C) 2019 The Authors. Published by Elsevier B.V.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 520, "Times Cited, All Databases": 569, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2020, "Volume": 247, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 106949, "DOI": "10.1016/j.cpc.2019.106949", "DOI Link": "http://dx.doi.org/10.1016/j.cpc.2019.106949", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000503093400032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, ZJ; Yin, HJ; Wang, Y; Chuang, CH; Xing, L; Dong, MY; Lu, YR; Casillas-Garcia, G; Zheng, YL; Chen, S; Dou, YH; Liu, P; Cheng, QL; Zhao, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Zhengju; Yin, Huajie; Wang, Yun; Chuang, Cheng-Hao; Xing, Lei; Dong, Mengyang; Lu, Ying-Rui; Casillas-Garcia, Gilberto; Zheng, Yonglong; Chen, Shan; Dou, Yuhai; Liu, Porun; Cheng, Qilin; Zhao, Huijun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Coexisting Single-Atomic Fe and Ni Sites on Hierarchically Ordered Porous Carbon as a Highly Efficient ORR Electrocatalyst", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of oxygen reduction reaction (ORR) electrocatalysts based on earth-abundant nonprecious materials is critically important for sustainable large-scale applications of fuel cells and metal-air batteries. Herein, a hetero-single-atom (h-SA) ORR electrocatalyst is presented, which has atomically dispersed Fe and Ni coanchored to a microsized nitrogen-doped graphitic carbon support with unique trimodal-porous structure configured by highly ordered macropores interconnected through mesopores. Extended X-ray absorption fine structure spectra confirm that Fe- and Ni-SAs are affixed to the carbon support via Fe-N(4)and Ni-N(4)coordination bonds. The resultant Fe/Ni h-SA electrocatalyst exhibits an outstanding ORR activity, outperforming SA electrocatalysts with only Fe- or Ni-SAs, and the benchmark Pt/C. The obtained experimental results indicate that the achieved outstanding ORR performance results from the synergetic enhancement induced by the coexisting Fe-N(4)and Ni-N(4)sites, and the superior mass-transfer capability promoted by the trimodal-porous-structured carbon support.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 510, "Times Cited, All Databases": 528, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 22", "Publication Year": 2020, "Volume": 32, "Issue": 42, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2004670, "DOI": "10.1002/adma.202004670", "DOI Link": "http://dx.doi.org/10.1002/adma.202004670", "Book DOI": null, "Early Access Date": "SEP 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000569825900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, CW; Ping, WW; Bai, Q; Cui, HC; Hensleigh, R; Wang, RL; Brozena, AH; Xu, ZP; Dai, JQ; Pei, Y; Zheng, CL; Pastel, G; Gao, JL; Wang, XZ; Wang, H; Zhao, JC; Yang, B; Zheng, XY; Luo, J; Mo, YF; Dunn, B; Hu, LB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Chengwei; Ping, Weiwei; Bai, Qiang; Cui, Huachen; Hensleigh, Ryan; Wang, Ruiliu; Brozena, Alexandra H.; Xu, Zhenpeng; Dai, Jiaqi; Pei, Yong; Zheng, Chaolun; Pastel, Glenn; Gao, Jinlong; Wang, Xizheng; Wang, Howard; Zhao, Ji-Cheng; Yang, Bao; Zheng, Xiaoyu (Rayne); Luo, Jian; Mo, Yifei; Dunn, Bruce; Hu, Liangbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A general method to synthesize and sinter bulk ceramics in seconds", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ceramics are an important class of materials with widespread applications because of their high thermal, mechanical. and chemical stability. Computational predictions based on first principles methods can be a valuable tool in accelerating materials discovery to develop improved ceramics. It is essential to experimentally confirm the material properties of such predictions. However, materials screening rates are limited by the long processing times and the poor compositional control from volatile element loss in conventional ceramic sintering techniques. To overcome these limitations, we developed an ultrafast high-temperature sintering (UHS) process for the fabrication of ceramic materials by radiative heating under an inert atmosphere. We provide several examples of the UHS process to demonstrate its potential utility and applications, including advancements in solid-state electrolytes, mufticomponent structures, and high-throughput materials screening.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 493, "Times Cited, All Databases": 544, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 1", "Publication Year": 2020, "Volume": 368, "Issue": 6490, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 521, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.aaz7681", "DOI Link": "http://dx.doi.org/10.1126/science.aaz7681", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000531178400047", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, HP; Rebollar, D; He, HY; Chong, LN; Liu, YZ; Liu, C; Sun, CJ; Li, T; Muntean, JV; Winulls, RE; Liu, DJ; Xu, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Haiping; Rebollar, Dominic; He, Haiying; Chong, Lina; Liu, Yuzi; Liu, Cong; Sun, Cheng-Jun; Li, Tao; Muntean, John, V; Winulls, Randall E.; Liu, Di-Jia; Xu, Tao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly selective electrocatalytic CO2reduction to ethanol by metallic clusters dynamically formed from atomically dispersed copper", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Direct electrochemical conversion of CO(2)to ethanol offers a promising strategy to lower CO(2)emissions while storing energy from renewable electricity. However, current electrocatalysts offer only limited selectivity toward ethanol. Here we report a carbon-supported copper (Cu) catalyst, synthesized by an amalgamated Cu-Li method, that achieves a single-product Faradaic efficiency (FE) of 91% at -0.7 V (versus the reversible hydrogen electrode) and onset potential as low as -0.4 V (reversible hydrogen electrode) for electrocatalytic CO2-to-ethanol conversion. The catalyst operated stably over 16 h. The FE of ethanol was highly sensitive to the initial dispersion of Cu atoms and decreased significantly when CuO and large Cu clusters become predominullt species. Operando X-ray absorption spectroscopy identified a reversible transformation from atomically dispersed Cu atoms to Cu(n)clusters (n = 3 and 4) on application of electrochemical conditions. First-principles calculations further elucidate the possible catalytic mechanism of CO(2)reduction over Cu-n. Electrocatalytically reducing CO(2)to ethanol can provide renewably generated fuel, but catalysts are often poorly selective for this conversion. Here the authors use a Cu catalyst to produce ethanol with high selectivity. Cu dispersion is key to the performance and operando studies indicate that it changes under reaction conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 499, "Times Cited, All Databases": 524, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2020, "Volume": 5, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 623, "End Page": 632, "Article Number": null, "DOI": "10.1038/s41560-020-0666-x", "DOI Link": "http://dx.doi.org/10.1038/s41560-020-0666-x", "Book DOI": null, "Early Access Date": "JUL 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000552931500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deysher, G; Shuck, CE; Hantanasirisakul, K; Frey, NC; Foucher, AC; Maleski, K; Sarycheva, A; Shenoy, VB; Stach, EA; Anasori, B; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deysher, Grayson; Shuck, Christopher Eugene; Hantanasirisakul, Kanit; Frey, Nathan C.; Foucher, Alexandre C.; Maleski, Kathleen; Sarycheva, Asia; Shenoy, Vivek B.; Stach, Eric A.; Anasori, Babak; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synthesis of Mo4VAlC4 MAX Phase and Two-Dimensional Mo4VC4 MXene with Five Atomic Layers of Transition Metals", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "MXenes are a family of two-dimensional (2D) transition metal carbides, nitrides, and carbonitrides with a general formula of Mn+1XnTx, in which two, three, or four atomic layers of a transition metal (M: Ti, Nb, V, Cr, Mo, Ta, etc.) are interleaved with layers of C and/or N (shown as X), and T-x represents surface termination groups such as -OH, =O, and -F. Here, we report the scalable synthesis and characterization of a MXene with five atomic layers of transition metals (Mo4VC4Tx), by synthesizing its Mo4VAlC4 MAX phase precursor that contains no other MAX phase impurities. These phases display twinning at their central M layers which is not present in any other known MAX phases or MXenes. Transmission electron microscopy and X-ray diffraction were used to examine the structure of both phases. Energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, Raman spectroscopy, and high- resolution scanning transmission electron microscopy with energy-dispersive X-ray spectroscopy were used to study the composition of these materials. Density functional theory calculations indicate that other five transition metal-layer MAX phases (M'M-4 '' AlC4) may be possible, where M' and M '' are two different transition metals. The predicted existence of additional Al-containing MAX phases suggests that more M5C4Tx MXenes can be synthesized. Additionally, we characterized the optical, electronic, and thermal properties of Mo4VC4Tx. This study demonstrates the existence of an additional subfamily of M5X4Tx MXenes as well as a twinned structure, allowing for a wider range of 2D structures and compositions for more control over properties, which could lead to many different applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 506, "Times Cited, All Databases": 532, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2020, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 204, "End Page": 217, "Article Number": null, "DOI": "10.1021/acsnullo.9b07708", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.9b07708", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000510531500015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gu, LL; Poddar, S; Lin, YJ; Long, ZH; Zhang, DQ; Zhang, QP; Shu, L; Qiu, X; Kam, M; Javey, A; Fan, ZY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gu, Leilei; Poddar, Swapnadeep; Lin, Yuanjing; Long, Zhenghao; Zhang, Daquan; Zhang, Qianpeng; Shu, Lei; Qiu, Xiao; Kam, Matthew; Javey, Ali; Fan, Zhiyong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A biomimetic eye with a hemispherical perovskite nullowire array retina", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A biomimetic electrochemical eye is presented that has a hemispherical retina made from a high-density array of perovskite nullowires that are sensitive to light, mimicking the photoreceptors of a biological retina. Human eyes possess exceptional image-sensing characteristics such as an extremely wide field of view, high resolution and sensitivity with low aberration(1). Biomimetic eyes with such characteristics are highly desirable, especially in robotics and visual prostheses. However, the spherical shape and the retina of the biological eye pose an enormous fabrication challenge for biomimetic devices(2,3). Here we present an electrochemical eye with a hemispherical retina made of a high-density array of nullowires mimicking the photoreceptors on a human retina. The device design has a high degree of structural similarity to a human eye with the potential to achieve high imaging resolution when individual nullowires are electrically addressed. Additionally, we demonstrate the image-sensing function of our biomimetic device by reconstructing the optical patterns projected onto the device. This work may lead to biomimetic photosensing devices that could find use in a wide spectrum of technological applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 517, "Times Cited, All Databases": 550, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2020, "Volume": 581, "Issue": 7808, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 278, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-020-2285-x", "DOI Link": "http://dx.doi.org/10.1038/s41586-020-2285-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000534818200010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, Y; Rodan-Legrain, D; Rubies-Bigorda, O; Park, JM; Watanabe, K; Taniguchi, T; Jarillo-Herrero, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Yuan; Rodan-Legrain, Daniel; Rubies-Bigorda, Oriol; Park, Jeong Min; Watanabe, Kenji; Taniguchi, Takashi; Jarillo-Herrero, Pablo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tunable correlated states and spin-polarized phases in twisted bilayer-bilayer graphene", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The recent discovery of correlated insulator states and superconductivity in magic-angle twisted bilayer graphene(1,2) has enabled the experimental investigation of electronic correlations in tunable flat-band systems realized in twisted van der Waals heterostructures(3-6). This novel twist angle degree of freedom and control should be generalizable to other two-dimensional systems, which may exhibit similar correlated physics behaviour, and could enable techniques to tune and control the strength of electron-electron interactions. Here we report a highly tunable correlated system based on small-angle twisted bilayer-bilayer graphene (TBBG), consisting of two rotated sheets of Bernal-stacked bilayer graphene. We find that TBBG exhibits a rich phase diagram, with tunable correlated insulator states that are highly sensitive to both the twist angle and the application of an electric displacement field, the latter reflecting the inherent polarizability of Bernal-stacked bilayer graphene(7,8). The correlated insulator states can be switched on and off by the displacement field at all integer electron fillings of the moire unit cell. The response of these correlated states to magnetic fields suggests evidence of spin-polarized ground states, in stark contrast to magic-angle twisted bilayer graphene. Furthermore, in the regime of lower twist angles, TBBG shows multiple sets of flat bands near charge neutrality, resulting in numerous correlated states corresponding to half-filling of each of these flat bands, all of which are tunable by the displacement field as well. Our results could enable the exploration of twist-angle- and electric-field-controlled correlated phases of matter in multi-flat-band twisted superlattices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 451, "Times Cited, All Databases": 509, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 9", "Publication Year": 2020, "Volume": 583, "Issue": 7815, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 215, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-020-2260-6", "DOI Link": "http://dx.doi.org/10.1038/s41586-020-2260-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000623832900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhai, PL; Zhang, YX; Wu, YZ; Gao, JF; Zhang, B; Cao, SY; Zhang, YT; Li, ZW; Sun, LC; Hou, JG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhai, Panlong; Zhang, Yanxue; Wu, Yunzhen; Gao, Junfeng; Zhang, Bo; Cao, Shuyan; Zhang, Yanting; Li, Zhuwei; Sun, Licheng; Hou, Jungang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering active sites on hierarchical transition bimetal oxides/sulfides heterostructure array enabling robust overall water splitting", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rational design of the catalysts is impressive for sustainable energy conversion. However, there is a grand challenge to engineer active sites at the interface. Herein, hierarchical transition bimetal oxides/sulfides heterostructure arrays interacting two-dimensional MoOx/MoS2 nullosheets attached to one-dimensional NiOx/Ni3S2 nullorods were fabricated by oxidation/hydrogenation-induced surface reconfiguration strategy. The NiMoOx/NiMoS heterostructure array exhibits the overpotentials of 38mV for hydrogen evolution and 186mV for oxygen evolution at 10mAcm(-2), even surviving at a large current density of 500mAcm(-2) with long-term stability. Due to optimized adsorption energies and accelerated water splitting kinetics by theory calculations, the assembled two-electrode cell delivers the industrially relevant current densities of 500 and 1000mAcm(-2) at record low cell voltages of 1.60 and 1.66V with excellent durability. This research provides a promising avenue to enhance the electrocatalytic performance of the catalysts by engineering interfacial active sites toward large-scale water splitting. While water splitting is an appealing carbon-neutral strategy for renewable energy generation, there is a need to develop new active, cost-effective catalysts. Here, authors prepare a nickel-molybdenum oxide/sulfide heterojunctions as bifunctional H-2 and O-2 evolution electrocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 516, "Times Cited, All Databases": 525, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 29", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5462, "DOI": "10.1038/s41467-020-19214-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-19214-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000591379900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cui, WR; Zhang, CR; Jiang, W; Li, FF; Liang, RP; Liu, JW; Qiu, JD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cui, Wei-Rong; Zhang, Cheng-Rong; Jiang, Wei; Li, Fang-Fang; Liang, Ru-Ping; Liu, Juewen; Qiu, Jian-Ding", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Regenerable and stable sp2 carbon-conjugated covalent organic frameworks for selective detection and extraction of uranium", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Uranium is a key element in the nuclear industry, but its unintended leakage has caused health and environmental concerns. Here we report a sp(2) carbon-conjugated fluorescent covalent organic framework (COF) named TFPT-BTAN-AO with excellent chemical, thermal and radiation stability is synthesized by integrating triazine-based building blocks with amidoxime-substituted linkers. TFPT-BTAN-AO shows an exceptional UO22+ adsorption capacity of 427mgg(-1) attributable to the abundant selective uranium-binding groups on the highly accessible pore walls of open 1D channels. In addition, it has an ultra-fast response time (2s) and an ultra-low detection limit of 6.7nM UO22+ suitable for on-site and real-time monitoring of UO22+, allowing not only extraction but also monitoring the quality of the extracted water. This study demonstrates great potential of fluorescent COFs for radionuclide detection and extraction. By rational designing target ligands, this strategy can be extended to the detection and extraction of other contaminullts. Porous materials for uranium capture have been developed in the past, but materials for simultaneous uranium capture and detection are scarce. Here the authors develop a stable covalent organic framework capable of adsorbing and detecting uranyl ions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 503, "Times Cited, All Databases": 516, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 23", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 436, "DOI": "10.1038/s41467-020-14289-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-14289-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000558877100005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, C; Jiao, Y; Shi, BY; Liu, JN; Xie, ZH; Chen, X; Zhang, Q; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Cheng; Jiao, Yan; Shi, Bingyang; Liu, Jia-Ning; Xie, Zhenhua; Chen, Xiao; Zhang, Qiang; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Coordination Tunes Selectivity: Two-Electron Oxygen Reduction on High-Loading Molybdenum Single-Atom Catalysts", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-atom catalysts (SACs) have great potential in electrocatalysis. Their performance can be rationally optimized by tailoring the metal atoms, adjacent coordinative dopants, and metal loading. However, doing so is still a great challenge because of the limited synthesis approach and insufficient understanding of the structure-property relationships. Herein, we report a new kind of Mo SAC with a unique O,S coordination and a high metal loading over 10 wt %. The isolation and local environment was identified by high-angle annular dark-field scanning transmission electron microscopy and extended X-ray absorption fine structure. The SACs catalyze the oxygen reduction reaction (ORR) via a 2 e(-) pathway with a high H2O2 selectivity of over 95 % in 0.10 m KOH. The critical role of the Mo single atoms and the coordination structure was revealed by both electrochemical tests and theoretical calculations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 486, "Times Cited, All Databases": 508, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 2", "Publication Year": 2020, "Volume": 59, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9171, "End Page": 9176, "Article Number": null, "DOI": "10.1002/anie.202003842", "DOI Link": "http://dx.doi.org/10.1002/anie.202003842", "Book DOI": null, "Early Access Date": "APR 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000524335500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, XY; Wang, F; Wei, Q; Li, HS; Shang, YQ; Zhou, WJ; Wang, C; Cheng, PH; Chen, Q; Chen, LW; Ning, ZJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Xianyuan; Wang, Fei; Wei, Qi; Li, Hansheng; Shang, Yuequn; Zhou, Wenjia; Wang, Cheng; Cheng, Peihong; Chen, Qi; Chen, Liwei; Ning, Zhijun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-high open-circuit voltage of tin perovskite solar cells via an electron transporting layer design", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tin perovskite is rising as a promising candidate to address the toxicity and theoretical efficiency limitation of lead perovskite. However, the voltage and efficiency of tin perovskite solar cells are much lower than lead counterparts. Herein, indene-C-60 bisadduct with higher energy level is utilized as an electron transporting material for tin perovskite solar cells. It suppresses carrier concentration increase caused by remote doping, which significantly reduces interface carriers recombination. Moreover, indene-C-60 bisadduct increases the maximum attainable photovoltage of the device. As a result, the use of indene-C-60 bisadduct brings unprecedentedly high voltage of 0.94 V, which is over 50% higher than that of 0.6 V for device based on [6,6]-phenyl-C61-butyric acid methyl ester. The device shows a record power conversion efficiency of 12.4% reproduced in an accredited independent photovoltaic testing lab.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 498, "Times Cited, All Databases": 510, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 6", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1245, "DOI": "10.1038/s41467-020-15078-2", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15078-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000549162600022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Q; Luan, JY; Huang, XB; Wang, Q; Sun, D; Tang, YG; Ji, XB; Wang, HY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Qi; Luan, Jingyi; Huang, Xiaobing; Wang, Qi; Sun, Dan; Tang, Yougen; Ji, Xiaobo; Wang, Haiyan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Revealing the role of crystal orientation of protective layers for stable zinc anode", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable aqueous zinc-ion batteries are a promising candidate for next-generation energy storage devices. However, their practical application is limited by the severe safety issue caused by uncontrollable dendrite growth on zinc anodes. Here we develop faceted titanium dioxide with relatively low zinc affinity, which can restrict dendrite formation and homogenize zinc deposition when served as the protective layer on zinc anodes. The as-prepared zinc anodes can be stripped and plated steadily for more than 460h with low voltage hysteresis and flat voltage plateau in symmetric cells. This work reveals the key role of crystal orientation in zinc affinity and its internal mechanism is suitable for various crystal materials applied in the surface modification of other metal anodes such as lithium and sodium. Zinc affinity plays a key role in the zinc plating and stripping processes but its internal mechanism is still unclear. Here, the authors report a protective layer with controllable zinc affinity by adjusting the crystal orientation to suppress the dendrite growth on the zinc anode interface.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 509, "Times Cited, All Databases": 520, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 7", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3961, "DOI": "10.1038/s41467-020-17752-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-17752-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000561098400014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, B; Wang, L; Cao, Z; Kozlov, SM; de Arquer, FPG; Dinh, CT; Li, J; Wang, ZY; Zheng, XL; Zhang, LS; Wen, YZ; Voznyy, O; Comin, R; De Luna, P; Regier, T; Bi, WL; Alp, EE; Pao, CW; Zheng, LR; Hu, YF; Ji, YJ; Li, YY; Zhang, Y; Cavallo, L; Peng, HS; Sargent, EH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Bo; Wang, Lie; Cao, Zhen; Kozlov, Sergey M.; Garcia de Arquer, F. Pelayo; Dinh, Cao Thang; Li, Jun; Wang, Ziyun; Zheng, Xueli; Zhang, Longsheng; Wen, Yunzhou; Voznyy, Oleksandr; Comin, Riccardo; De Luna, Phil; Regier, Tom; Bi, Wenli; Alp, E. Ercan; Pao, Chih-Wen; Zheng, Lirong; Hu, Yongfeng; Ji, Yujin; Li, Youyong; Zhang, Ye; Cavallo, Luigi; Peng, Huisheng; Sargent, Edward H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-valence metals improve oxygen evolution reaction performance by modulating 3dmetal oxidation cycle energetics", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Multimetal oxyhydroxides have recently been reported that outperform noble metal catalysts for oxygen evolution reaction (OER). In such 3d-metal-based catalysts, the oxidation cycle of 3dmetals has been posited to act as the OER thermodynamic-limiting process; however, further tuning of its energetics is challenging due to similarities among the electronic structures of neighbouring 3dmetal modulators. Here we report a strategy to reprogram the Fe, Co and Ni oxidation cycles by incorporating high-valence transition-metal modulators X (X = W, Mo, Nb, Ta, Re and MoW). We use in situ and ex situ soft and hard X-ray absorption spectroscopies to characterize the oxidation transition in modulated NiFeX and FeCoX oxyhydroxide catalysts, and conclude that the lower OER overpotential is facilitated by the readier oxidation transition of 3dmetals enabled by high-valence modulators. We report an similar to 17-fold mass activity enhancement compared with that for the OER catalysts widely employed in industrial water-splitting electrolysers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 521, "Times Cited, All Databases": 537, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2020, "Volume": 3, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 985, "End Page": 992, "Article Number": null, "DOI": "10.1038/s41929-020-00525-6", "DOI Link": "http://dx.doi.org/10.1038/s41929-020-00525-6", "Book DOI": null, "Early Access Date": "OCT 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000579724100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bertsch, KM; de Bellefon, GM; Kuehl, B; Thoma, DJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bertsch, K. M.; de Bellefon, G. Meric; Kuehl, B.; Thoma, D. J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Origin of dislocation structures in an additively manufactured austenitic stainless steel 316L", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this experiment, the origin of dislocation structures in AM stainless steels was systematically investigated by controlling the effect of thermal stress through geometric constraints for the first time. Stainless steel 316L parts were produced in the form of 1D rods, 2D walls, and 3D rectangular prisms to evaluate the effect of constraints to thermal expansion/shrinkage on the development of defect microstructures and to elucidate the origin of additively manufactured (AM) dislocation microstructures. Dislocation density, organization, chemical micro-segregation, precipitate structures, and misorientations were analyzed as a function of increasing constraints around solidifying material in 1D, 2D, and 3D components built using both directed energy deposition (DED) and powder-bed selective laser melting (SLM). In DED parts, the dislocation density was not dependent on local misorientations or micro-segregation patterns, but evolved from approximately rho(perpendicular to)approximate to 10(12) m(-)(2) in 1D parts to rho(perpendicular to) approximate to 10(14) m(-2) in 3D parts, indicating that it is primarily thermal distortions that produce AM dislocation structures. In DED 3D parts and SLM parts, dislocation densities were highest (rho(perpendicular to) approximate to 10(14) m(-2)) and corresponded to the formation of dislocation cells approximately 300-450 nm in diameter. Dislocation cells overlapped with dendrite micro-segregation in some but not all cases. The results illustrate that dendritic micro-segregation, precipitates, or local misorientations influence how the dislocations organize during processing, but are not responsible for producing the organized cell structures. This work shows that AM dislocation structures originate due to thermal distortions during printing, which are primarily dictated by constraints surrounding the melt pool and thermal cycling. (C) 2020 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 497, "Times Cited, All Databases": 516, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 15", "Publication Year": 2020, "Volume": 199, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 19, "End Page": 33, "Article Number": null, "DOI": "10.1016/j.actamat.2020.07.063", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2020.07.063", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000577994500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, DG; Park, EJ; Zhu, WL; Shi, QR; Zhou, Y; Tian, HY; Lin, YH; Serov, A; Zulevi, B; Baca, ED; Fujimoto, C; Chung, HT; Kim, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Dongguo; Park, Eun Joo; Zhu, Wenlei; Shi, Qiurong; Zhou, Yang; Tian, Hangyu; Lin, Yuehe; Serov, Alexey; Zulevi, Barr; Baca, Ehren Donel; Fujimoto, Cy; Chung, Hoon T.; Kim, Yu Seung", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly quaternized polystyrene ionomers for high performance anion exchange membrane water electrolysers", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Alkaline anion exchange membrane (AEM) electrolysers to produce hydrogen from water are still at an early stage of development, and their performance is far lower than that of systems based on proton exchange membranes. Here, we report an ammonium-enriched anion exchange ionomer that improves the performance of an AEM electrolyser to levels approaching that of state-of-the-art proton exchange membrane electrolysers. Using rotating-disk electrode experiments, we show that a high pH (>13) in the electrode binder is the critical factor for improving the activity of the hydrogen- and oxygen-evolution reactions in AEM electrolysers. Based on this observation, we prepared and tested several quaternized polystyrene electrode binders in an AEM electrolyser. Using the binder with the highest ionic concentration and a NiFe oxygen evolution catalyst, we demonstrated performance of 2.7 A cm(-2) at 1.8 V without a corrosive circulating alkaline solution. The limited durability of the AEM electrolyser remains a challenge to be addressed in the future. Anion exchange membrane water electrolysers have potential cost advantages over proton exchange membrane electrolysers, but their performance has lagged behind. Here the authors investigate the cause of the poor performance of anion exchange membrane electrolysers and design ionomers that can overcome some of the challenges.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 490, "Times Cited, All Databases": 517, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2020, "Volume": 5, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 378, "End Page": 385, "Article Number": null, "DOI": "10.1038/s41560-020-0577-x", "DOI Link": "http://dx.doi.org/10.1038/s41560-020-0577-x", "Book DOI": null, "Early Access Date": "MAR 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000518736900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pan, YL; Xu, XM; Zhong, YJ; Ge, L; Chen, YB; Veder, JPM; Guan, DQ; O'Hayre, R; Li, MR; Wang, GX; Wang, H; Zhou, W; Shao, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pan, Yangli; Xu, Xiaomin; Zhong, Yijun; Ge, Lei; Chen, Yubo; Veder, Jean-Pierre Marcel; Guan, Daqin; O'Hayre, Ryan; Li, Mengran; Wang, Guoxiong; Wang, Hao; Zhou, Wei; Shao, Zongping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct evidence of boosted oxygen evolution over perovskite by enhanced lattice oxygen participation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of oxygen evolution reaction (OER) electrocatalysts remains a major challenge that requires significant advances in both mechanistic understanding and material design. Recent studies show that oxygen from the perovskite oxide lattice could participate in the OER via a lattice oxygen-mediated mechanism, providing possibilities for the development of alternative electrocatalysts that could overcome the scaling relations-induced limitations found in conventional catalysts utilizing the adsorbate evolution mechanism. Here we distinguish the extent to which the participation of lattice oxygen can contribute to the OER through the rational design of a model system of silicon-incorporated strontium cobaltite perovskite electrocatalysts with similar surface transition metal properties yet different oxygen diffusion rates. The as-derived silicon-incorporated perovskite exhibits a 12.8-fold increase in oxygen diffusivity, which matches well with the 10-fold improvement of intrinsic OER activity, suggesting that the observed activity increase is dominulltly a result of the enhanced lattice oxygen participation. While water splitting provides a renewable means to store energy, the sluggish O-2 evolution half-reaction limits applications. Here, authors examine a silicon-incorporated strontium cobaltite perovskite and correlate lattice oxygen participation in O-2 evolution to the oxygen ion diffusivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 492, "Times Cited, All Databases": 506, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 24", "Publication Year": 2020, "Volume": 11, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2002, "DOI": "10.1038/s41467-020-15873-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-15873-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000558820800020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, ZY; Karamad, M; Yong, X; Huang, QZ; Cullen, DA; Zhu, P; Xia, CA; Xiao, QF; Shakouri, M; Chen, FY; Kim, JY; Xia, Y; Heck, K; Hu, YF; Wong, MS; Li, QL; Gates, I; Siahrostami, S; Wang, HT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Zhen-Yu; Karamad, Mohammadreza; Yong, Xue; Huang, Qizheng; Cullen, David A.; Zhu, Peng; Xia, Chuan; Xiao, Qunfeng; Shakouri, Mohsen; Chen, Feng-Yang; (Timothy) Kim, Jung Yoon; Xia, Yang; Heck, Kimberly; Hu, Yongfeng; Wong, Michael S.; Li, Qilin; Gates, Ian; Siahrostami, Samira; Wang, Haotian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrochemical ammonia synthesis via nitrate reduction on Fe single atom catalyst", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemically converting nitrate, a widespread water pollutant, back to valuable ammonia is a green and delocalized route for ammonia synthesis, and can be an appealing and supplementary alternative to the Haber-Bosch process. However, as there are other nitrate reduction pathways present, selectively guiding the reaction pathway towards ammonia is currently challenged by the lack of efficient catalysts. Here we report a selective and active nitrate reduction to ammonia on Fe single atom catalyst, with a maximal ammonia Faradaic efficiency of similar to 75% and a yield rate of up to similar to 20,000 mu gh(-1) mg(cat.)(-1) (0.46mmolh(-1) cm(-2)). Our Fe single atom catalyst can effectively prevent the N-N coupling step required for N-2 due to the lack of neighboring metal sites, promoting ammonia product selectivity. Density functional theory calculations reveal the reaction mechanisms and the potential limiting steps for nitrate reduction on atomically dispersed Fe sites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 998, "Times Cited, All Databases": 1023, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 17", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2870, "DOI": "10.1038/s41467-021-23115-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-23115-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000658736000013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, L; Li, WT; Yin, LQ; Liu, YJ; Guo, HZ; Lai, JW; Han, Y; Li, G; Li, M; Zhang, JH; Vajtai, R; Ajayan, PM; Wu, MH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Liang; Li, Weitao; Yin, Luqiao; Liu, Yijian; Guo, Huazhang; Lai, Jiawei; Han, Yu; Li, Gao; Li, Ming; Zhang, Jianhua; Vajtai, Robert; Ajayan, Pulickel M.; Wu, Minghong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Full-color fluorescent carbon quantum dots", "Source Title": "SCIENCE ADVANCES", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Quantum dots have innate advantages as the key component of optoelectronic devices. For white light-emitting diodes (WLEDs), the modulation of the spectrum and color of the device often involves various quantum dots of different emission wavelengths. Here, we fabricate a series of carbon quantum dots (CQDs) through a scalable acid reagent engineering strategy. The growing electron-withdrawing groups on the surface of CQDs that originated from acid reagents boost their photoluminescence wavelength red shift and raise their particle sizes, elucidating the quantum size effect. These CQDs emit bright and remarkably stable full-color fluorescence ranging from blue to red light and even white light. Full-color emissive polymer films and all types of high-color rendering index WLEDs are synthesized by mixing multiple kinds of CQDs in appropriate ratios. The universal electron-donating/withdrawing group engineering approach for synthesizing tunable emissive CQDs will facilitate the progress of carbon-based luminescent materials for manufacturing forward-looking films and devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 477, "Times Cited, All Databases": 498, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2020, "Volume": 6, "Issue": 40, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "eabb6772", "DOI": "10.1126/sciadv.abb6772", "DOI Link": "http://dx.doi.org/10.1126/sciadv.abb6772", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000579157800027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, X; Zuo, Y; Zhai, P; Shen, JH; Yang, YYW; Gao, Z; Liao, M; Wu, JX; Wang, JW; Xu, XJ; Tong, Q; Zhang, B; Wang, BJ; Sun, XM; Zhang, LH; Pei, QB; Jin, DY; Chen, PN; Peng, HS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Xiang; Zuo, Yong; Zhai, Peng; Shen, Jiahao; Yang, Yangyiwei; Gao, Zhen; Liao, Meng; Wu, Jingxia; Wang, Jiawei; Xu, Xiaojie; Tong, Qi; Zhang, Bo; Wang, Bingjie; Sun, Xuemei; Zhang, Lihua; Pei, Qibing; Jin, Dayong; Chen, Peining; Peng, Huisheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Large-area display textiles integrated with functional systems", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Displays are basic building blocks of modern electronics(1,2). Integrating displays into textiles offers exciting opportunities for smart electronictextiles-the ultimate goal of wearable technology, poised to change the way in which we interact with electronic devices(3-6). Display textiles serve to bridge human-machine interactions(7-9), offering, for instance, a real-time communication tool for individuals with voice or speech difficulties. Electronictextiles capable of communicating(10), sensing(11,12) and supplying electricity(13,14) have been reported previously. However, textiles with functional, large-area displays have not yet been achieved, because it is challenging to obtain small illuminating unitsthat are both durable and easy to assemble over a wide area. Here we report a 6-metre-long, 25-centimetre-wide display textile containing 5 x10(5 )electroluminescent units spaced approximately 800 micrometres apart. Weaving conductive weft and luminescent warp fibres forms micrometre-scale electroluminescent units at the weft-warp contact points. The brightness between electroluminescent units deviates by less than 8 per cent and remains stable even when the textile is bent, stretched or pressed. Our display textile is flexible and breathable and withstands repeated machine-washing, making it suitable for practical applications. We showthat an integrated textile system consisting of display, keyboard and power supply can serve as a communication tool, demonstrating the system's potential within the Internet of things' in various areas, including healthcare. Our approach unifies the fabrication and function of electronic devices with textiles, and we expect that woven-fibre materials will shape the next generation of electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 755, "Times Cited, All Databases": 803, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 11", "Publication Year": 2021, "Volume": 591, "Issue": 7849, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 240, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-03295-8", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03295-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000627422700011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, XH; Wang, XH; Huang, JF; Li, SX; Meng, A; Li, ZJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Xuehua; Wang, Xianghu; Huang, Jianfeng; Li, Shaoxiang; Meng, Alan; Li, Zhenjiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interfacial chemical bond and internal electric field modulated Z-scheme Sv-ZnIn2S4/MoSe2 photocatalyst for efficient hydrogen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Construction of Z-scheme heterostructure is of great significance for realizing efficient photocatalytic water splitting. However, the conscious modulation of Z-scheme charge transfer is still a great challenge. Herein, interfacial Mo-S bond and internal electric field modulated Z-scheme heterostructure composed by sulfur vacancies-rich ZnIn2S4 and MoSe2 was rationally fabricated for efficient photocatalytic hydrogen evolution. Systematic investigations reveal that Mo-S bond and internal electric field induce the Z-scheme charge transfer mechanism as confirmed by the surface photovoltage spectra, DMPO spin-trapping electron paramagnetic resonullce spectra and density functional theory calculations. Under the intense synergy among the Mo-S bond, internal electric field and S-vacancies, the optimized photocatalyst exhibits high hydrogen evolution rate of 63.21mmol.g(-1)h(-1) with an apparent quantum yield of 76.48% at 420nm monochromatic light, which is about 18.8-fold of the pristine ZIS. This work affords a useful inspiration on consciously modulating Z-scheme charge transfer by atomic-level interface control and internal electric field to signally promote the photocatalytic performance. The construction of Z-scheme heterostructures is of great significance for realizing efficient photocatalytic water splitting. Here, the authors report an interfacial chemical bond and internal electric field modulated Z-Scheme S-v-ZnIn2S4/MoSe2 photocatalyst for efficient hydrogen evolution.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 714, "Times Cited, All Databases": 722, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 5", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4112, "DOI": "10.1038/s41467-021-24511-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24511-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000672713100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, V; Xu, N; Liu, JC; Tang, G; Geng, WT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Vei; Xu, null; Liu, Jin-Cheng; Tang, Gang; Geng, Wen-Tong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "VASPKIT: A user-friendly interface facilitating high-throughput computing and analysis using VASP code", "Source Title": "COMPUTER PHYSICS COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We present the VASPKIT, a command-line program that aims at providing a robust and user-friendly interface to perform high-throughput analysis of a variety of material properties from the raw data produced by the VASP code. It consists of mainly the pre-and post-processing modules. The former module is designed to prepare and manipulate input files such as the necessary input files generation, symmetry analysis, supercell transformation, k-path generation for a given crystal structure. The latter module is designed to extract and analyze the raw data about elastic mechanics, electronic structure, charge density, electrostatic potential, linear optical coefficients, wave function plots in real space, etc. This program can run conveniently in either interactive user interface or command line mode. The command-line options allow the user to perform high-throughput calculations together with bash scripts. This article gives an overview of the program structure and presents illustrative examples for some of its usages. The program can run on Linux, macOS, and Windows platforms. The executable versions of VASPKIT and the related examples and tutorials are available on its official website vaspkit .com. Program summary Program title: VASPKIT CPC Library link to program files: https://doi.org/10.17632/v3bvcypg9v.1 Licensing provisions: GPLv3 Programming language: Fortran, Python Nature of problem: This program has the purpose of providing a powerful and user-friendly interface to perform high-throughput calculations together with the widely-used VASP code. Solution method: VASPKIT can extract, calculate and even plot the mechanical, electronic, optical and magnetic properties from density functional calculations together with bash and python scripts. It can run in either interactive user interface or command line mode. (C) 2021 Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 3941, "Times Cited, All Databases": 4028, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2021, "Volume": 267, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 108033, "DOI": "10.1016/j.cpc.2021.108033", "DOI Link": "http://dx.doi.org/10.1016/j.cpc.2021.108033", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000678508900017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, GG; Zhu, JW; Yuan, PF; Hu, YF; Qu, G; Lu, BA; Xue, XY; Yin, HB; Cheng, WZ; Cheng, JQ; Xu, WJ; Li, J; Hu, JS; Mu, SC; Zhang, JN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Gege; Zhu, Jiawei; Yuan, Pengfei; Hu, Yongfeng; Qu, Gan; Lu, Bang-An; Xue, Xiaoyi; Yin, Hengbo; Cheng, Wenzheng; Cheng, Junqi; Xu, Wenjing; Li, Jin; Hu, Jinsong; Mu, Shichun; Zhang, Jia-null", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Regulating Fe-spin state by atomically dispersed Mn-N in Fe-N-C catalysts with high oxygen reduction activity", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "As low-cost electrocatalysts for oxygen reduction reaction applied to fuel cells and metal-air batteries, atomic-dispersed transition metal-nitrogen-carbon materials are emerging, but the genuine mechanism thereof is still arguable. Herein, by rational design and synthesis of dual-metal atomically dispersed Fe,Mn/N-C catalyst as model object, we unravel that the O-2 reduction preferentially takes place on Fe-III in the FeN4/C system with intermediate spin state which possesses one e(g) electron (t(2g)4e(g)1) readily penetrating the antibonding pi-orbital of oxygen. Both magnetic measurements and theoretical calculation reveal that the adjacent atomically dispersed Mn-N moieties can effectively activate the Fe-III sites by both spin-state transition and electronic modulation, rendering the excellent ORR performances of Fe, Mn/N-C in both alkaline and acidic media (halfwave positionals are 0.928 V in 0.1 M KOH, and 0.804 V in 0.1 M HClO4), and good durability, which outperforms and has almost the same activity of commercial Pt/C, respectively. In addition, it presents a superior power density of 160.8 mW cm(-2) and long-term durability in reversible zinc-air batteries. The work brings new insight into the oxygen reduction reaction process on the metal-nitrogen-carbon active sites, undoubtedly leading the exploration towards high effective low-cost non-precious catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 702, "Times Cited, All Databases": 712, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 19", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1734, "DOI": "10.1038/s41467-021-21919-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21919-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000631927600019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Park, JM; Cao, Y; Watanabe, K; Taniguchi, T; Jarillo-Herrero, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Park, Jeong Min; Cao, Yuan; Watanabe, Kenji; Taniguchi, Takashi; Jarillo-Herrero, Pablo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tunable strongly coupled superconductivity in magic-angle twisted trilayer graphene", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Moire superlattices(1,2) have recently emerged as a platform upon which correlated physics and superconductivity can be studied with unprecedented tunability(3-6). Although correlated effects have been observed in several other moire system(7-17), magic-angle twisted bilayergraphene remains the only one in which robust superconductivity has been reproducibly measured(4-6). Here we realize a moire superconductor in magic-angle twisted trilayer graphene (MATTG)(18), which has better tunability of its electronic structure and superconducting properties than magic-angle twisted bilayer graphene. Measurements ofthe Hall effect and quantum oscillations as a function of density and electric field enable us to determine the tunable phase boundaries of the system in the normal metallic state. Zero-magnetic-field resistivity measurements reveal that the existence of superconductivity is intimately connected to the broken-symmetry phase that emerges from two carriers per moire unit cell. We find that the superconducting phase is suppressed and bounded at the Van Hove singularities that partially surround the broken-symmetry phase, which is difficult to reconcile with weak-coupling Bardeen-Cooper-Schrieffer theory. Moreover, the extensive in situ tunability of our system allows us to reach the ultrastrong-coupling regime, characterized by a Ginzburg-Landau coherence length that reaches the average inter-particle distance, and very large T-BKT/F, values, in excess of 0.1 (where T-BKT and T-F are the Berezinskii-Kosterlitz-Thouless transition and Fermi temperatures, respectively). These observations suggest that MATTG can be electrically tuned close to the crossover to a two-dimensional Bose-Einstein condensate. Our results establish a family of tunable moire superconductors that have the potential to revolutionize our fundamental understanding of and the applications for strongly coupled superconductivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 613, "Times Cited, All Databases": 673, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 11", "Publication Year": 2021, "Volume": 590, "Issue": 7845, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41586-021-03192-0", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03192-0", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000613628300002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, C; Zhou, JD; Song, JL; Xu, JQ; Zhang, HT; Zhang, XN; Guo, J; Zhu, L; Wei, DH; Han, GC; Min, J; Zhang, Y; Xie, ZQ; Yi, YP; Yan, H; Gao, F; Liu, F; Sun, YM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Chao; Zhou, Jiadong; Song, Jiali; Xu, Jinqiu; Zhang, Huotian; Zhang, Xuning; Guo, Jing; Zhu, Lei; Wei, Donghui; Han, Guangchao; Min, Jie; Zhang, Yuan; Xie, Zengqi; Yi, Yuanping; Yan, He; Gao, Feng; Liu, Feng; Sun, Yanming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Non-fullerene acceptors with branched side chains and improved molecular packing to exceed 18% efficiency in organic solar cells", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Molecular design of acceptor and donor molecules has enabled major progress in organic photovoltaics. Li et al. show that branched alkyl chains in non-fullerene acceptors allow favourable morphology in the active layer, enabling a certified device efficiency of 17.9%. Molecular design of non-fullerene acceptors is of vital importance for high-efficiency organic solar cells. The branched alkyl chain modification is often regarded as a counter-intuitive approach, as it may introduce an undesirable steric hindrance that reduces charge transport in non-fullerene acceptors. Here we show the design and synthesis of a highly efficient non-fullerene acceptor family by substituting the beta position of the thiophene unit on a Y6-based dithienothiophen[3,2-b]-pyrrolobenzothiadiazole core with branched alkyl chains. It was found that such a modification to a different alkyl chain length could completely change the molecular packing behaviour of non-fullerene acceptors, leading to improved structural order and charge transport in thin films. An unprecedented efficiency of 18.32% (certified value of 17.9%) with a fill factor of 81.5% is achieved for single-junction organic solar cells. This work reveals the importance of the branched alkyl chain topology in tuning the molecular packing and blend morphology, which leads to improved organic photovoltaic performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 1693, "Times Cited, All Databases": 1745, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2021, "Volume": 6, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 605, "End Page": 613, "Article Number": null, "DOI": "10.1038/s41560-021-00820-x", "DOI Link": "http://dx.doi.org/10.1038/s41560-021-00820-x", "Book DOI": null, "Early Access Date": "MAY 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000648836900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hua, MT; Wu, SW; Ma, YF; Zhao, YS; Chen, ZL; Frenkel, I; Strzalka, J; Zhou, H; Zhu, XY; He, XM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hua, Mutian; Wu, Shuwang; Ma, Yanfei; Zhao, Yusen; Chen, Zilin; Frenkel, Imri; Strzalka, Joseph; Zhou, Hua; Zhu, Xinyuan; He, Ximin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strong tough hydrogels via the synergy of freeze-casting and salting out", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Natural load-bearing materials such as tendons have a high water content of about 70 per cent but are still strong and tough, even when used for over one million cycles per year, owing to the hierarchical assembly of anisotropic structures across multiple length scales(1). Synthetic hydrogels have been created using methods such as electro-spinning(2), extrusion(3), compositing(4,5), freeze-casting(6,7), self-assembly(8) and mechanical stretching(9,10) for improved mechanical performance. However, in contrast to tendons, many hydrogels with the same high water content do not show high strength, toughness or fatigue resistance. Here we present a strategy to produce a multi-length-scale hierarchical hydrogel architecture using a freezing-assisted salting-out treatment. The produced poly(vinyl alcohol) hydrogels are highly anisotropic, comprising micrometre-scale honeycomb-like pore walls, which in turn comprise interconnected nullofibril meshes. These hydrogels have a water content of 70-95 per cent and properties that compare favourably to those of other tough hydrogels and even natural tendons; for example, an ultimate stress of 23.5 +/- 2.7 megapascals, strain levels of 2,900 +/- 450 per cent, toughness of 210 +/- 13 megajoules per cubic metre, fracture energy of 170 +/- 8 kilojoules per square metre and a fatigue threshold of 10.5 +/- 1.3 kilojoules per square metre. The presented strategy is generalizable to other polymers, and could expand the applicability of structural hydrogels to conditions involving more demanding mechanical loading. A strategy that combines freeze-casting and salting-out treatments produces strong, tough, stretchable and fatigue-resistant poly(vinyl alcohol) hydrogels.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 959, "Times Cited, All Databases": 998, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 25", "Publication Year": 2021, "Volume": 590, "Issue": 7847, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41586-021-03212-z", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03212-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000621583600011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jeong, J; Kim, M; Seo, J; Lu, HZ; Ahlawat, P; Mishra, A; Yang, YG; Hope, MA; Eickemeyer, FT; Kim, M; Yoon, YJ; Choi, IW; Darwich, BP; Choi, SJ; Jo, Y; Lee, JH; Walker, B; Zakeeruddin, SM; Emsley, L; Rothlisberger, U; Hagfeldt, A; Kim, DS; Grätzel, M; Kim, JY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jeong, Jaeki; Kim, Minjin; Seo, Jongdeuk; Lu, Haizhou; Ahlawat, Paramvir; Mishra, Aditya; Yang, Yingguo; Hope, Michael A.; Eickemeyer, Felix T.; Kim, Maengsuk; Yoon, Yung Jin; Choi, In Woo; Darwich, Barbara Primera; Choi, Seung Ju; Jo, Yimhyun; Lee, Jun Hee; Walker, Bright; Zakeeruddin, Shaik M.; Emsley, Lyndon; Rothlisberger, Ursula; Hagfeldt, Anders; Kim, Dong Suk; Graetzel, Michael; Kim, Jin Young", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Pseudo-halide anion engineering for α-FAPbI3 perovskite solar cells", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal halide perovskites of the general formula ABX(3)-where A is a monovalent cation such as caesium, methylammonium or formamidinium; B is divalent lead, tin or germanium; and X is a halide anion-have shown great potential as light harvesters for thin-film photovoltaics(1-5). Among a large number of compositions investigated, the cubic a-phase of formamidinium lead triiodide (FAPbI(3)) hasemerged as the most promising semiconductor for highly efficient and stable perovskite solar cells(6-9), and maximizing the performance of this material in such devices is of vital importance for the perovskite researchcommunity. Here we introduce an anion engineering concept that uses the pseudo-halide anion formate (HCOO-) to suppress anion-vacancy defects that are present at grain boundaries and at the surface of the perovskite films and to augment the crystallinity of the films. Theresulting solar cell devices attain a power conversion efficiency of 25.6 per cent (certified 25.2 per cent), have long-term operational stability (450 hours) and show intense electroluminescence with external quantum efficiencies of more than 10 per cent. Our findings provide a direct route to eliminate the most abundant and deleterious lattice defects present in metal halide perovskites, providing a facile access to solution-processable films with improved optoelectronic performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 2467, "Times Cited, All Databases": 2580, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 15", "Publication Year": 2021, "Volume": 592, "Issue": 7854, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 381, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-03406-5", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03406-5", "Book DOI": null, "Early Access Date": "APR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000636947600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, J; Wang, GH; Cheng, B; Yu, JG; Fan, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Juan; Wang, Guohong; Cheng, Bei; Yu, Jiaguo; Fan, Jiajie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Sulfur-doped g-C3N4/TiO2 S-scheme heterojunction photocatalyst for Congo Red photodegradation", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Constructing step-scheme (S-scheme) heterojunctions has been confirmed as a promising strategy for enhancing the photocatalytic activity of composite materials. In this work, a series of sulfur-doped g-C3N4 (SCN)/TiO2 S-scheme photocatalysts were synthesized using electrospinning and calcination methods. The as-prepared SCN/TiO2 composites showed superior photocatalytic performance than pure TiO2 and SCN in the photocatalytic degradation of Congo Red (CR) aqueous solution. The significant enhancement in photocatalytic activity benefited not only from the 1D well-distributed nullostructure, but also from the S-scheme heterojunction. Furthermore, the XPS analyses and DFT calculations demonstrated that electrons were transferred from SCN to TiO2 across the interface of the SCN/TiO2 composites. The built-in electric field, band edge bending, and Coulomb interaction synergistically facilitated the recombination of relatively useless electrons and holes in hybrid when the interface was irradiated by simulated solar light. Therefore, the remaining electrons and holes with higher reducibility and oxidizability endowed the composite with supreme redox ability. These results were adequately verified by radical trapping experiments, ESR tests, and in situ XPS analyses, suggesting that the electron immigration in the photocatalyst followed the S-scheme heterojunction mechanism. This work can enrich our knowledge of the design and fabrication of novel S-scheme heterojunction photocatalysts and provide a promising strategy for solving environmental pollution in the future. (C) 2021, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 621, "Times Cited, All Databases": 650, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 42, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 56, "End Page": 68, "Article Number": null, "DOI": "10.1016/S1872-2067(20)63634-8", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(20)63634-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000582725100007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hao, JN; Yuan, LB; Ye, C; Chao, DL; Davey, K; Guo, ZP; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hao, Junnull; Yuan, Libei; Ye, Chao; Chao, Dongliang; Davey, Kenneth; Guo, Zaiping; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boosting Zinc Electrode Reversibility in Aqueous Electrolytes by Using Low-Cost Antisolvents", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Antisolvent addition has been widely studied in crystallization in the pharmaceutical industries by breaking the solvation balance of the original solution. Here we report a similar antisolvent strategy to boost Zn reversibility via regulation of the electrolyte on a molecular level. By adding for example methanol into ZnSO4 electrolyte, the free water and coordinated water in Zn2+ solvation sheath gradually interact with the antisolvent, which minimizes water activity and weakens Zn2+ solvation. Concomitantly, dendrite-free Zn deposition occurs via change in the deposition orientation, as evidenced by in situ optical microscopy. Zn reversibility is significantly boosted in antisolvent electrolyte of 50 % methanol by volume (Anti-M-50 %) even under harsh environments of -20 degrees C and 60 degrees C. Additionally, the suppressed side reactions and dendrite-free Zn plating/stripping in Anti-M-50 % electrolyte significantly enhance performance of Zn/polyaniline coin and pouch cells. We demonstrate this low-cost strategy can be readily generalized to other solvents, indicating its practical universality. Results will be of immediate interest and benefit to a range of researchers in electrochemistry and energy storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 696, "Times Cited, All Databases": 719, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 22", "Publication Year": 2021, "Volume": 60, "Issue": 13, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7366, "End Page": 7375, "Article Number": null, "DOI": "10.1002/anie.202016531", "DOI Link": "http://dx.doi.org/10.1002/anie.202016531", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000621048500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yasuda, K; Wang, XR; Watanabe, K; Taniguchi, T; Jarillo-Herrero, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yasuda, Kenji; Wang, Xirui; Watanabe, Kenji; Taniguchi, Takashi; Jarillo-Herrero, Pablo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stacking-engineered ferroelectricity in bilayer boron nitride", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional (2D) ferroelectrics with robust polarization down to atomic thicknesses provide building blocks for functional heterostructures. Experimental realization remains challenging because of the requirement of a layered polar crystal. Here, we demonstrate a rational design approach to engineering 2D ferroelectrics from a nonferroelectric parent compound by using van der Waals assembly. Parallel-stacked bilayer boron nitride exhibits out-of-plane electric polarization that reverses depending on the stacking order. The polarization switching is probed through the resistance of an adjacently stacked graphene sheet. Twisting the boron nitride sheets by a small angle changes the dynamics of switching because of the formation of moire ferroelectricity with staggered polarization. The ferroelectricity persists to room temperature while keeping the high mobility of graphene, paving the way for potential ultrathin nonvolatile memory applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 544, "Times Cited, All Databases": 577, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 25", "Publication Year": 2021, "Volume": 372, "Issue": 6549, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1458, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abd3230", "DOI Link": "http://dx.doi.org/10.1126/science.abd3230", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000665860000051", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mathis, TS; Maleski, K; Goad, A; Sarycheva, A; Anayee, M; Foucher, AC; Hantanasirisakul, K; Shuck, CE; Stach, EA; Gogotsi, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mathis, Tyler S.; Maleski, Kathleen; Goad, Adam; Sarycheva, Asia; Anayee, Mark; Foucher, Alexandre C.; Hantanasirisakul, Kanit; Shuck, Christopher E.; Stach, Eric A.; Gogotsi, Yury", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Modified MAX Phase Synthesis for Environmentally Stable and Highly Conductive Ti3C2 MXene", "Source Title": "ACS nullO", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "One of the primary factors limiting further research and commercial use of the two-dimensional (2D) titanium carbide MXene Ti3C2, as well as MXenes in general, is the rate at which freshly made samples oxidize and degrade when stored as aqueous suspensions. Here, we show that including excess aluminum during synthesis of the Ti3AlC2 MAX phase precursor leads to Ti3AlC2 grains with improved crystallinity and carbon stoichiometry (termed Al-Ti3AlC2). MXene nullosheets (Al-Ti3C2) produced from this precursor are of higher quality, as evidenced by their increased resistance to oxidation and an increase in their electronic conductivity up to 20 000 S/cm. Aqueous suspensions of stoichiometric single-to few-layer Al-Ti3C2 flakes produced from the modified Al-Ti3AlC2 have a shelf life of over ten months, compared to 1 to 2 weeks for previously published Ti3C2, even when stored in ambient conditions. Freestanding films made from Al-Ti3C2 suspensions stored for ten months show minimal decreases in electrical conductivity and negligible oxidation. Furthermore, oxidation of the improved Al-Ti3C2 in air initiates at temperatures that are 100-150 degrees C higher than that of conventional Ti3C2. The observed improvements in both the shelf life and properties of Al-Ti3C2 will facilitate the widespread use of this material.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 589, "Times Cited, All Databases": 624, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 27", "Publication Year": 2021, "Volume": 15, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 6420, "End Page": 6429, "Article Number": null, "DOI": "10.1021/acsnullo.0c08357", "DOI Link": "http://dx.doi.org/10.1021/acsnullo.0c08357", "Book DOI": null, "Early Access Date": "APR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000645436800038", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhai, PL; Xia, MY; Wu, YZ; Zhang, GH; Gao, JF; Zhang, B; Cao, SY; Zhang, YT; Li, ZW; Fan, ZZ; Wang, C; Zhang, XM; Miller, JT; Sun, LC; Hou, JG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhai, Panlong; Xia, Mingyue; Wu, Yunzhen; Zhang, Guanghui; Gao, Junfeng; Zhang, Bo; Cao, Shuyan; Zhang, Yanting; Li, Zhuwei; Fan, Zhaozhong; Wang, Chen; Zhang, Xiaomeng; Miller, Jeffrey T.; Sun, Licheng; Hou, Jungang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering single-atomic ruthenium catalytic sites on defective nickel-iron layered double hydroxide for overall water splitting", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rational design of single atom catalyst is critical for efficient sustainable energy conversion. However, the atomic-level control of active sites is essential for electrocatalytic materials in alkaline electrolyte. Moreover, well-defined surface structures lead to in-depth understanding of catalytic mechanisms. Herein, we report a single-atomic-site ruthenium stabilized on defective nickel-iron layered double hydroxide nullosheets (Ru-1/D-NiFe LDH). Under precise regulation of local coordination environments of catalytically active sites and the existence of the defects, Ru-1/D-NiFe LDH delivers an ultralow overpotential of 18mV at 10mAcm(-2) for hydrogen evolution reaction, surpassing the commercial Pt/C catalyst. Density functional theory calculations reveal that Ru-1/D-NiFe LDH optimizes the adsorption energies of intermediates for hydrogen evolution reaction and promotes the O-O coupling at a Ru-O active site for oxygen evolution reaction. The Ru-1/D-NiFe LDH as an ideal model reveals superior water splitting performance with potential for the development of promising water-alkali electrocatalysts. Rational design of single atom catalyst is critical for efficient sustainable energy conversion. Single-atomic-site ruthenium stabilized on defective nickel-iron layered double hydroxide nullosheets achieve superior HER and OER performance in alkaline media.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 577, "Times Cited, All Databases": 597, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 28", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4587, "DOI": "10.1038/s41467-021-24828-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24828-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000680875400015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, Y; Ma, ZR; Xiao, YY; Yin, YC; Huang, WM; Huang, ZC; Zheng, YZ; Mu, FY; Huang, R; Shi, GY; Sun, YY; Xia, XH; Chen, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Yi; Ma, Zhi-Rui; Xiao, Yi-Ying; Yin, Yun-Chao; Huang, Wen-Mao; Huang, Zhi-Chao; Zheng, Yun-Zhe; Mu, Fang-Ya; Huang, Rong; Shi, Guo-Yue; Sun, Yi-Yang; Xia, Xing-Hua; Chen, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electronic metal-support interaction modulates single-atom platinum catalysis for hydrogen evolution reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Tuning metal-support interaction has been considered as an effective approach to modulate the electronic structure and catalytic activity of supported metal catalysts. At the atomic level, the understanding of the structure-activity relationship still remains obscure in heterogeneous catalysis, such as the conversion of water (alkaline) or hydronium ions (acid) to hydrogen (hydrogen evolution reaction, HER). Here, we reveal that the fine control over the oxidation states of single-atom Pt catalysts through electronic metal-support interaction significantly modulates the catalytic activities in either acidic or alkaline HER. Combined with detailed spectroscopic and electrochemical characterizations, the structure-activity relationship is established by correlating the acidic/alkaline HER activity with the average oxidation state of single-atom Pt and the Pt-H/Pt-OH interaction. This study sheds light on the atomic-level mechanistic understanding of acidic and alkaline HER, and further provides guidelines for the rational design of high-performance single-atom catalysts. Insights into the rational design of single-atom metal catalysts remains obscure in heterogeneous catalysis. Here, the authors establish the atomic-level structure-activity relationship for a wide-pH-range hydrogen evolution reaction through the electronic metal-support interaction modulation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 608, "Times Cited, All Databases": 619, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 21", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3021, "DOI": "10.1038/s41467-021-23306-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-23306-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000658766200003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, P; Liu, B; Liang, CB; Ruan, KP; Qiu, H; Ma, ZL; Guo, YQ; Gu, JW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Ping; Liu, Bei; Liang, Chaobo; Ruan, Kunpeng; Qiu, Hua; Ma, Zhonglei; Guo, Yongqiang; Gu, Junwei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lightweight, Flexible Cellulose-Derived Carbon Aerogel@Reduced Graphene Oxide/PDMS Composites with Outstanding EMI Shielding Performances and Excellent Thermal Conductivities", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In order to ensure the operational reliability and information security of sophisticated electronic components and to protect human health, efficient electromagnetic interference (EMI) shielding materials are required to attenuate electromagnetic wave energy. In this work, the cellulose solution is obtained by dissolving cotton through hydrogen bond driving self-assembly using sodium hydroxide (NaOH)/urea solution, and cellulose aerogels (CA) are prepared by gelation and freeze-drying. Then, the cellulose carbon aerogel@reduced graphene oxide aerogels (CCA@rGO) are prepared by vacuum impregnation, freeze-drying followed by thermal annealing, and finally, the CCA@rGO/polydimethylsiloxane (PDMS) EMI shielding composites are prepared by backfilling with PDMS. Owing to skin-core structure of CCA@rGO, the complete three-dimensional (3D) double-layer conductive network can be successfully constructed. When the loading of CCA@rGO is 3.05 wt%, CCA@rGO/PDMS EMI shielding composites have an excellent EMI shielding effectiveness (EMI SE) of 51 dB, which is 3.9 times higher than that of the co-blended CCA/rGO/PDMS EMI shielding composites (13 dB) with the same loading of fillers. At this time, the CCA@rGO/PDMS EMI shielding composites have excellent thermal stability (T-HRI of 178.3 degrees C) and good thermal conductivity coefficient (lambda of 0.65 W m(-1) K-1). Excellent comprehensive performance makes CCA@rGO/PDMS EMI shielding composites great prospect for applications in lightweight, flexible EMI shielding composites.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 588, "Times Cited, All Databases": 606, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 16", "Publication Year": 2021, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 91, "DOI": "10.1007/s40820-021-00624-4", "DOI Link": "http://dx.doi.org/10.1007/s40820-021-00624-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000629787500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, M; Zhu, L; Zhou, GQ; Hao, TY; Qiu, CQ; Zhao, Z; Hu, Q; Larson, BW; Zhu, HM; Ma, ZF; Tang, Z; Feng, W; Zhang, YM; Russell, TP; Liu, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Ming; Zhu, Lei; Zhou, Guanqing; Hao, Tianyu; Qiu, Chaoqun; Zhao, Zhe; Hu, Qin; Larson, Bryon W.; Zhu, Haiming; Ma, Zaifei; Tang, Zheng; Feng, Wei; Zhang, Yongming; Russell, Thomas P.; Liu, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-layered organic photovoltaics with double cascading charge transport pathways: 18% efficiencies", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The chemical structure of donors and acceptors limit the power conversion efficiencies achievable with active layers of binary donor-acceptor mixtures. Here, using quaternary blends, double cascading energy level alignment in bulk heterojunction organic photovoltaic active layers are realized, enabling efficient carrier splitting and transport. Numerous avenues to optimize light absorption, carrier transport, and charge-transfer state energy levels are opened by the chemical constitution of the components. Record-breaking PCEs of 18.07% are achieved where, by electronic structure and morphology optimization, simultaneous improvements of the open-circuit voltage, short-circuit current and fill factor occur. The donor and acceptor chemical structures afford control over electronic structure and charge-transfer state energy levels, enabling manipulation of hole-transfer rates, carrier transport, and non-radiative recombination losses.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 596, "Times Cited, All Databases": 633, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 12", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 309, "DOI": "10.1038/s41467-020-20580-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20580-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000662810100013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, KL; Wang, ZL; Han, CB; Ke, XX; Wang, CH; Jin, YH; Zhang, QQ; Liu, JB; Wang, H; Yan, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Kai Ling; Wang, Zelin; Han, Chang Bao; Ke, Xiaoxing; Wang, Changhao; Jin, Yuhong; Zhang, Qianqian; Liu, Jingbing; Wang, Hao; Yan, Hui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Platinum single-atom catalyst coupled with transition metal/metal oxide heterostructure for accelerating alkaline hydrogen evolution reaction", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-atom catalysts provide an effective approach to reduce the amount of precious metals meanwhile maintain their catalytic activity. However, the sluggish activity of the catalysts for alkaline water dissociation has hampered advances in highly efficient hydrogen production. Herein, we develop a single-atom platinum immobilized NiO/Ni heterostructure (Pt-SA-NiO/Ni) as an alkaline hydrogen evolution catalyst. It is found that Pt single atom coupled with NiO/Ni heterostructure enables the tunable binding abilities of hydroxyl ions (OH*) and hydrogen (H*), which efficiently tailors the water dissociation energy and promotes the H* conversion for accelerating alkaline hydrogen evolution reaction. A further enhancement is achieved by constructing Pt-SA-NiO/Ni nullosheets on Ag nullowires to form a hierarchical three-dimensional morphology. Consequently, the fabricated Pt-SA-NiO/Ni catalyst displays high alkaline hydrogen evolution performances with a quite high mass activity of 20.6Amg(-1) for Pt at the overpotential of 100mV, significantly outperforming the reported catalysts. While H-2 evolution from water may represent a renewable energy source, there is a strong need to improve catalytic efficiencies while maximizing materials utilization. Here, authors examine single-atom Pt on nickel-based heterostructures as highly active electrocatalysts for alkaline H-2 evolution.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 549, "Times Cited, All Databases": 561, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 18", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3783, "DOI": "10.1038/s41467-021-24079-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24079-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000665040300012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, T; Wu, Y; Shi, L; Hu, XH; Chen, M; Wu, LM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Tong; Wu, Yi; Shi, Lan; Hu, Xinhua; Chen, Min; Wu, Limin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A structural polymer for highly efficient all-day passive radiative cooling", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-day passive radiative cooling has recently attracted tremendous interest by reflecting sunlight and radiating heat to the ultracold outer space. While some progress has been made, it still remains big challenge in fabricating highly efficient and low-cost radiative coolers for all-day and all-climates. Herein, we report a hierarchically structured polymethyl methacrylate (PMMA) film with a micropore array combined with random nullopores for highly efficient day- and nighttime passive radiative cooling. This hierarchically porous array PMMA film exhibits sufficiently high solar reflectance (0.95) and superior longwave infrared thermal emittance (0.98) and realizes subambient cooling of similar to 8.2 degrees C during the night and similar to 6.0 degrees C to similar to 8.9 degrees C during midday with an average cooling power of similar to 85W/m(2) under solar intensity of similar to 900W/m(2), and promisingly similar to 5.5 degrees C even under solar intensity of similar to 930W/m(2) and relative humidity of similar to 64% in hot and moist climate. The micropores and nullopores in the polymer film play crucial roles in enhancing the solar reflectance and thermal emittance. There still remains a big challenge in fabricating highly efficient and low-cost radiative coolers for all-day and all-climates. Here, the authors report a hierarchically structured polymethyl methacrylate film with a micropore array combined with random nullopores for highly efficient day- and nighttime passive radiative cooling.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 545, "Times Cited, All Databases": 574, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 14", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 365, "DOI": "10.1038/s41467-020-20646-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20646-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000610677200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ou, XY; Qin, X; Huang, BL; Zan, J; Wu, QX; Hong, ZZ; Xie, LL; Bian, HY; Yi, ZG; Chen, XF; Wu, YM; Song, XR; Li, J; Chen, QS; Yang, HH; Liu, XG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ou, Xiangyu; Qin, Xian; Huang, Bolong; Zan, Jie; Wu, Qinxia; Hong, Zhongzhu; Xie, Lili; Bian, Hongyu; Yi, Zhigao; Chen, Xiaofeng; Wu, Yiming; Song, Xiaorong; Li, Juan; Chen, Qiushui; Yang, Huanghao; Liu, Xiaogang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-resolution X-ray luminescence extension imaging", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Current X-ray imaging technologies involving flat-panel detectors have difficulty in imaging three-dimensional objects because fabrication of large-area, flexible, silicon-based photodetectors on highly curved surfaces remains a challenge(1-3). Here we demonstrate ultralong-lived X-ray trapping for flat-panel-free, high-resolution, three-dimensional imaging using a series of solution-processable, lanthanide-doped nulloscintillators. Corroborated by quantum mechanical simulations of defect formation and electronic structures, our experimental characterizations reveal that slow hopping of trapped electrons due to radiation-triggered anionic migration in host lattices can induce more than 30 days of persistent radioluminescence. We further demonstrate X-ray luminescence extension imaging with resolution greater than 20 line pairs per millimetre and optical memory longer than 15 days. These findings provide insight into mechanisms underlying X-ray energy conversion through enduring electron trapping and offer a paradigm to motivate future research in wearable X-ray detectors for patient-centred radiography and mammography, imaging-guided therapeutics, high-energy physics and deep learning in radiology. Using lanthanide-doped nullomaterials and flexible substrates, an approach that enables flat-panel-free, high-resolution, three-dimensional imaging is demonstrated and termed X-ray luminescence extension imaging.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 545, "Times Cited, All Databases": 571, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 18", "Publication Year": 2021, "Volume": 590, "Issue": 7846, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41586-021-03251-6", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03251-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000683860300003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Teng, ZY; Zhang, QT; Yang, HB; Kato, K; Yang, WJ; Lu, YR; Liu, SX; Wang, CY; Yamakata, A; Su, CL; Liu, B; Ohno, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Teng, Zhenyuan; Zhang, Qitao; Yang, Hongbin; Kato, Kosaku; Yang, Wenjuan; Lu, Ying-Rui; Liu, Sixiao; Wang, Chengyin; Yamakata, Akira; Su, Chenliang; Liu, Bin; Ohno, Teruhisa", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomically dispersed antimony on carbon nitride for the artificial photosynthesis of hydrogen peroxide", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Artificial photosynthesis offers a promising strategy to produce hydrogen peroxide (H2O2)-an environmentally friendly oxidant and a clean fuel. However, the low activity and selectivity of the two-electron oxygen reduction reaction (ORR) in the photocatalytic process greatly restricts the H2O2 production efficiency. Here we show a robust antimony single-atom photocatalyst (Sb-SAPC, single Sb atoms dispersed on carbon nitride) for the synthesis of H2O2 in a simple water and oxygen mixture under visible light irradiation. An apparent quantum yield of 17.6% at 420 nm together with a solar-to-chemical conversion efficiency of 0.61% for H2O2 synthesis was achieved. On the basis of time-dependent density function theory calculations, isotopic experiments and advanced spectroscopic characterizations, the photocatalytic performance is ascribed to the notably promoted two-electron ORR by forming mu-peroxide at the Sb sites and highly concentrated holes at the neighbouring N atoms. The in situ generated O-2 via water oxidation is rapidly consumed by ORR, leading to boosted overall reaction kinetics. Hydrogen peroxide is an interesting target for artificial photosynthesis, although its actual production via the two-electron oxygen reduction reaction remains limited. Now, a carbon nitride-supported antimony single atom photocatalyst has been developed with a superior performance for this process.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 545, "Times Cited, All Databases": 557, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2021, "Volume": 4, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 374, "End Page": 384, "Article Number": null, "DOI": "10.1038/s41929-021-00605-1", "DOI Link": "http://dx.doi.org/10.1038/s41929-021-00605-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000653054400008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, XF; Wang, Q; Cheng, ZY; Zhu, ML; Zhou, H; Jiang, P; Zhou, LL; Xue, QQ; Yuan, FP; Zhu, J; Wu, XL; Ma, E", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Xuefei; Wang, Qi; Cheng, Zhiying; Zhu, Mingliu; Zhou, Hao; Jiang, Ping; Zhou, Lingling; Xue, Qiqi; Yuan, Fuping; Zhu, Jing; Wu, Xiaolei; Ma, En", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct observation of chemical short-range order in a medium-entropy alloy", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Direct experimental evidence of chemical short-range atomic-scale ordering (CSRO) in a VCoNi medium-entropy alloy is provided via diffraction and electron microscopy, analysed from specific crystallographic directions. Complex concentrated solutions of multiple principal elements are being widely investigated as high- or medium-entropy alloys (HEAs or MEAs)(1-11), often assuming that these materials have the high configurational entropy of an ideal solution. However, enthalpic interactions among constituent elements are also expected at normal temperatures, resulting in various degrees of local chemical order(12-22). Of the local chemical orders that can develop, chemical short-range order (CSRO) is arguably the most difficult to decipher and firm evidence of CSRO in these materials has been missing thus far(16,22). Here we discover that, using an appropriate zone axis, micro/nullobeam diffraction, together with atomic-resolution imaging and chemical mapping via transmission electron microscopy, can explicitly reveal CSRO in a face-centred-cubic VCoNi concentrated solution. Our complementary suite of tools provides concrete information about the degree/extent of CSRO, atomic packing configuration and preferential occupancy of neighbouring lattice planes/sites by chemical species. Modelling of the CSRO order parameters and pair correlations over the nearest atomic shells indicates that the CSRO originates from the nearest-neighbour preference towards unlike (V-Co and V-Ni) pairs and avoidance of V-V pairs. Our findings offer a way of identifying CSRO in concentrated solution alloys. We also use atomic strain mapping to demonstrate the dislocation interactions enhanced by the CSROs, clarifying the effects of these CSROs on plasticity mechanisms and mechanical properties upon deformation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 496, "Times Cited, All Databases": 516, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 29", "Publication Year": 2021, "Volume": 592, "Issue": 7856, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 712, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-03428-z", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03428-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000645368900011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, CJ; Chi, ZG; Chong, KC; Batsanov, AS; Yang, Z; Mao, Z; Yang, ZY; Liu, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Chengjian; Chi, Zhenguo; Chong, Kok Chan; Batsanov, Andrei S.; Yang, Zhan; Mao, Zhu; Yang, Zhiyong; Liu, Bin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carbazole isomers induce ultralong organic phosphorescence", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Commercial carbazole has been widely used to synthesize organic functional materials A carbazole isomer, typically present as an impurity in commercially produced carbazole batches, is shown to be responsible for the ultralong phosphorescence observed in these compounds and their derivatives.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 504, "Times Cited, All Databases": 515, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2021, "Volume": 20, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 175, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41563-020-0797-2", "DOI Link": "http://dx.doi.org/10.1038/s41563-020-0797-2", "Book DOI": null, "Early Access Date": "SEP 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000571692500007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, JK; Sougrati, MT; Zitolo, A; Ablett, JM; Oguz, IC; Mineva, T; Matanovic, I; Atanassov, P; Huang, Y; Zenyuk, I; Di Cicco, A; Kumar, K; Dubau, L; Maillard, F; Drazic, G; Jaouen, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Jingkun; Sougrati, Moulay Tahar; Zitolo, Andrea; Ablett, James M.; Oguz, Ismail Can; Mineva, Tzonka; Matanovic, Ivana; Atanassov, Plamen; Huang, Ying; Zenyuk, Iryna; Di Cicco, Andrea; Kumar, Kavita; Dubau, Laetitia; Maillard, Frederic; Drazic, Goran; Jaouen, Frederic", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identification of durable and non-durable FeNx sites in Fe-N-C materials for proton exchange membrane fuel cells", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While Fe-N-C materials are a promising alternative to platinum for catalysing the oxygen reduction reaction in acidic polymer fuel cells, limited understanding of their operando degradation restricts rational approaches towards improved durability. Here we show that Fe-N-C catalysts initially comprising two distinct FeNx sites (S1 and S2) degrade via the transformation of S1 into iron oxides while the structure and number of S2 were unmodified. Structure-activity correlations drawn from end-of-test Fe-57 Mossbauer spectroscopy reveal that both sites initially contribute to the oxygen reduction reaction activity but only S2 substantially contributes after 50 h of operation. From in situ Fe-57 Mossbauer spectroscopy in inert gas coupled to calculations of the Mossbauer signature of FeNx moieties in different electronic states, we identify S1 to be a high-spin FeN4C12 moiety and S2 a low- or intermediate-spin FeN4C10 moiety. These insights lay the groundwork for rational approaches towards Fe-N-C cathodes with improved durability in acidic fuel cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 491, "Times Cited, All Databases": 511, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 4, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41929-020-00545-2", "DOI Link": "http://dx.doi.org/10.1038/s41929-020-00545-2", "Book DOI": null, "Early Access Date": "DEC 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000599021700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, SS; Dai, XZ; Xu, S; Jiao, HY; Zhao, L; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Shangshang; Dai, Xuezeng; Xu, Shuang; Jiao, Haoyang; Zhao, Liang; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stabilizing perovskite-substrate interfaces for high-performance perovskite modules", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The interfaces of perovskite solar cells (PSCs) are important in determining their efficiency and stability, but the morphology and stability of imbedded perovskite-substrate interfaces have received less attention than have top interfaces. We found that dimethyl sulfoxide (DMSO), which is a liquid additive broadly applied to enhance perovskite film morphology, was trapped during film formation and led to voids at perovskite-substrate interfaces that accelerated the film degradation under illumination. Partial replacement of DMSO with solid-state carbohydrazide reduces interfacial voids. A maximum stabilized power conversion efficiency (PCE) of 23.6% was realized for blade-coated p-type/intrinsic/n-type (p-i-n) structure PSCs with no efficiency loss after 550-hour operational stability tests at 60 degrees C. The perovskite mini-modules showed certified PCEs of 19.3 and 19.2%, with aperture areas of 18.1 and 50.0 square centimeters, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 597, "Times Cited, All Databases": 626, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 20", "Publication Year": 2021, "Volume": 373, "Issue": 6557, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 902, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abi6323", "DOI Link": "http://dx.doi.org/10.1126/science.abi6323", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000686562400034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bu, TL; Li, J; Li, HY; Tian, CC; Su, J; Tong, GQ; Ono, LK; Wang, C; Lin, ZP; Chai, NAY; Zhang, XL; Chang, JJ; Lu, JF; Zhong, J; Huang, WC; Qi, YB; Cheng, YB; Huang, FZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bu, Tongle; Li, Jing; Li, Hengyi; Tian, Congcong; Su, Jie; Tong, Guoqing; Ono, Luis K.; Wang, Chao; Lin, Zhipeng; Chai, Nianyao; Zhang, Xiao-Li; Chang, Jingjing; Lu, Jianfeng; Zhong, Jie; Huang, Wenchao; Qi, Yabing; Cheng, Yi-Bing; Huang, Fuzhi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lead halide-templated crystallization of methylamine-free perovskite for efficient photovoltaic modules", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Upscaling efficient and stable perovskite layers is one of the most challenging issues in the commercialization of perovskite solar cells. Here, a lead halide-templated crystallization strategy is developed for printing formamidinium (FA)-cesium (Cs) lead triiodide perovskite films. High-quality large-area films are achieved through controlled nucleation and growth of a lead halide_N-methyl-2-pyrrolidone adduct that can react in situ with embedded FAI/CsI to directly form alpha-phase perovskite, sidestepping the phase transformation from delta-phase. A nonencapsulated device with 23% efficiency and excellent long-term thermal stability (at 85 degrees C) in ambient air (similar to 80% efficiency retention after 500 hours) is achieved with further addition of potassium hexafluorophosphate. The slot die-printed minimodules achieve champion efficiencies of 20.42% (certified efficiency 19.3%) and 19.54% with an active area of 17.1 and 65.0 square centimeters, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 487, "Times Cited, All Databases": 510, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 18", "Publication Year": 2021, "Volume": 372, "Issue": 6548, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1327, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abh1035", "DOI Link": "http://dx.doi.org/10.1126/science.abh1035", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000665616000032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, SW; Hua, MT; Alsaid, Y; Du, YJ; Ma, YF; Zhao, YS; Lo, CY; Wang, CR; Wu, D; Yao, BW; Strzalka, J; Zhou, H; Zhu, XY; He, XM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Shuwang; Hua, Mutian; Alsaid, Yousif; Du, Yingjie; Ma, Yanfei; Zhao, Yusen; Lo, Chiao-Yueh; Wang, Canran; Wu, Dong; Yao, Bowen; Strzalka, Joseph; Zhou, Hua; Zhu, Xinyuan; He, Ximin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Poly(vinyl alcohol) Hydrogels with Broad-Range Tunable Mechanical Properties via the Hofmeister Effect", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Hydrogels, exhibiting wide applications in soft robotics, tissue engineering, implantable electronics, etc., often require sophisticately tailoring of the hydrogel mechanical properties to meet specific demands. For examples, soft robotics necessitates tough hydrogels; stem cell culturing demands various tissue-matching modulus; and neuron probes desire dynamically tunable modulus. Herein, a strategy to broadly alter the mechanical properties of hydrogels reversibly via tuning the aggregation states of the polymer chains by ions based on the Hofmeister effect is reported. An ultratough poly(vinyl alcohol) (PVA) hydrogel as an exemplary material (toughness 150 +/- 20 MJ m(-3)), which surpasses synthetic polymers like poly(dimethylsiloxane), synthetic rubber, and natural spider silk is fabricated. With various ions, the hydrogel's various mechanical properties are continuously and reversibly in situ modulated over a large window: tensile strength from 50 +/- 9 kPa to 15 +/- 1 MPa, toughness from 0.0167 +/- 0.003 to 150 +/- 20 MJ m(-3), elongation from 300 +/- 100% to 2100 +/- 300%, and modulus from 24 +/- 2 to 2500 +/- 140 kPa. Importantly, the ions serve as gelation triggers and property modulators only, not necessarily required to remain in the gel, maintaining the high biocompatibility of PVA without excess ions. This strategy, enabling high mechanical performance and broad dynamic tunability, presents a universal platform for broad applications from biomedicine to wearable electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 503, "Times Cited, All Databases": 517, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 33, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2007829, "DOI": "10.1002/adma.202007829", "DOI Link": "http://dx.doi.org/10.1002/adma.202007829", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000615816100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Holoubek, J; Liu, HD; Wu, ZH; Yin, YJ; Xing, X; Cai, GR; Yu, SC; Zhou, HY; Pascal, TA; Chen, Z; Liu, P", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Holoubek, John; Liu, Haodong; Wu, Zhaohui; Yin, Yijie; Xing, Xing; Cai, Guorui; Yu, Sicen; Zhou, Hongyao; Pascal, Tod A.; Chen, Zheng; Liu, Ping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tailoring electrolyte solvation for Li metal batteries cycled at ultra-low temperature", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lithium metal batteries hold promise for pushing cell-level energy densities beyond 300 Wh kg(-1) while operating at ultra-low temperatures (below -30 degrees C). Batteries capable of both charging and discharging at these temperature extremes are highly desirable due to their inherent reduction in the need for external warming. Here we demonstrate that the local solvation structure of the electrolyte defines the charge-transfer behaviour at ultra-low temperature, which is crucial for achieving high Li metal Coulombic efficiency and avoiding dendritic growth. These insights were applied to Li metal full-cells, where a high-loading 3.5 mAh cm(-2) sulfurized polyacrylonitrile (SPAN) cathode was paired with a onefold excess Li metal anode. The cell retained 84% and 76% of its room temperature capacity when cycled at -40 and -60 degrees C, respectively, which presented stable performance over 50 cycles. This work provides design criteria for ultra-low-temperature lithium metal battery electrolytes, and represents a defining step for the performance of low-temperature batteries. Charging and discharging Li-metal batteries (LMBs) at low temperatures is problematic due to the sluggish charge-transfer process. Here the authors discuss the roles of solvation structures of Li-ions in the charge-transfer kinetics and design an electrolyte to enable low-temperature operations of LMBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 546, "Times Cited, All Databases": 575, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 6, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 303, "End Page": 313, "Article Number": null, "DOI": "10.1038/s41560-021-00783-z", "DOI Link": "http://dx.doi.org/10.1038/s41560-021-00783-z", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000621706600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, ZD; Wang, R; Peng, CX; Chen, WJ; Wu, TQ; Hu, B; Weng, WJ; Yao, Y; Zeng, JX; Chen, ZH; Liu, PY; Liu, YC; Li, GS; Guo, J; Lu, HB; Guo, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Zedong; Wang, Rong; Peng, Chengxin; Chen, Wuji; Wu, Tianqi; Hu, Bo; Weng, Weijun; Yao, Ying; Zeng, Jiaxi; Chen, Zhihong; Liu, Peiying; Liu, Yicheng; Li, Guisheng; Guo, Jia; Lu, Hongbin; Guo, Zaiping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Horizontally arranged zinc platelet electrodeposits modulated by fluorinated covalent organic framework film for high-rate and durable aqueous zinc ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rechargeable aqueous zinc-ion batteries (RZIBs) provide a promising complementarity to the existing lithium-ion batteries due to their low cost, non-toxicity and intrinsic safety. However, Zn anodes suffer from zinc dendrite growth and electrolyte corrosion, resulting in poor reversibility. Here, we develop an ultrathin, fluorinated two-dimensional porous covalent organic framework (FCOF) film as a protective layer on the Zn surface. The strong interaction between fluorine (F) in FCOF and Zn reduces the surface energy of the Zn (002) crystal plane, enabling the preferred growth of (002) planes during the electrodeposition process. As a result, Zn deposits show horizontally arranged platelet morphology with (002) orientations preferred. Furthermore, F-containing nullochannels facilitate ion transport and prevent electrolyte penetration for improving corrosion resistance. The FCOF@Zn symmetric cells achieve stability for over 750 h at an ultrahigh current density of 40 mA cm(-2). The high-areal-capacity full cells demonstrate hundreds of cycles under high Zn utilization conditions. Rechargeable aqueous zinc-ion batteries are promising but the zinc anode suffers from dendrite growth and electrolyte corrosion. Here, the authors develop a fluorinated covalent organic framework film as a protective layer for aqueous zinc anode battery.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 485, "Times Cited, All Databases": 495, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 16", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6606, "DOI": "10.1038/s41467-021-26947-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-26947-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000719546000021", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, CJ; Lee, YK; Yu, Y; Byun, S; Luo, ZZ; Lee, H; Ge, BZ; Lee, YL; Chen, XQ; Lee, JY; Cojocaru-Mirédin, O; Chang, H; Im, J; Cho, SP; Wuttig, M; Dravid, VP; Kanatzidis, MG; Chung, I", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Chongjian; Lee, Yong Kyu; Yu, Yuan; Byun, Sejin; Luo, Zhong-Zhen; Lee, Hyungseok; Ge, Bangzhi; Lee, Yea-Lee; Chen, Xinqi; Lee, Ji Yeong; Cojocaru-Miredin, Oana; Chang, Hyunju; Im, Jino; Cho, Sung-Pyo; Wuttig, Matthias; Dravid, Vinayak P.; Kanatzidis, Mercouri G.; Chung, In", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Polycrystalline SnSe with a thermoelectric figure of merit greater than the single crystal", "Source Title": "NATURE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermoelectric materials generate electric energy from waste heat, with conversion efficiency governed by the dimensionless figure of merit, ZT. Single-crystal tin selenide (SnSe) was discovered to exhibit a high ZT of roughly 2.2-2.6 at 913 K, but more practical and deployable polycrystal versions of the same compound suffer from much poorer overall ZT, thereby thwarting prospects for cost-effective lead-free thermoelectrics. The poor polycrystal bulk performance is attributed to traces of tin oxides covering the surface of SnSe powders, which increases thermal conductivity, reduces electrical conductivity and thereby reduces ZT. Here, we report that hole-doped SnSe polycrystalline samples with reagents carefully purified and tin oxides removed exhibit an ZT of roughly 3.1 at 783 K. Its lattice thermal conductivity is ultralow at roughly 0.07 W m(-1) K-1 at 783 K, lower than the single crystals. The path to ultrahigh thermoelectric performance in polycrystalline samples is the proper removal of the deleterious thermally conductive oxides from the surface of SnSe grains. These results could open an era of high-performance practical thermoelectrics from this high-performance material. SnSe has a very high thermoelectric figure of merit ZT, but uncommonly polycrystalline samples have higher lattice thermal conductivity than single crystals. Here, by controlling Sn reagent purity and removing SnOx impurities, a lower thermal conductivity is achieved, enabling ZT of 3.1 at 783 K.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 480, "Times Cited, All Databases": 491, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2021, "Volume": 20, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1378, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41563-021-01064-6", "DOI Link": "http://dx.doi.org/10.1038/s41563-021-01064-6", "Book DOI": null, "Early Access Date": "AUG 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000680338900002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bi, PQ; Zhang, SQ; Chen, ZH; Xu, Y; Cui, Y; Zhang, T; Ren, JZ; Qin, JZ; Hong, L; Hao, XT; Hou, JH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bi, Pengqing; Zhang, Shaoqing; Chen, Zhihao; Xu, Ye; Cui, Yong; Zhang, Tao; Ren, Junzhen; Qin, Jinzhao; Hong, Ling; Hao, Xiaotao; Hou, Jianhui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reduced non-radiative charge recombination enables organic photovoltaic cell approaching 19% efficiency", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Reducing non-radiative charge recombination is of critical importance to achieving high- performance organic photovoltaic (OPV) cells. The correlation between the exciton behaviors and non-radiative charge recombination is rarely studied. In this work, we achieved an increase in the exciton diffusion length (L-D) in the acceptor phase via introducing HDO-4Cl to the PBDB-TF: eC9-based system. Compared with the eC9-based film, the exciton L-D in the HDO- 4Cl: eC9-based film is increased from 12.2 to 16.3 nm. The enlarged exciton L-D can obviously decrease the non- radiative charge recombination and increase the efficiency of photon utilization in the PBDB-TF: eC9-based OPV cell. Finally, we not only obtained an outstanding power conversion efficiency (PCE) of 18.86% but also demonstrated the correlations between the nonradiative energy loss and exciton behaviors. The results show that regulating the exciton behaviors is an effective way to reduce the non-radiative energy loss and realize high-efficiency OPV cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 479, "Times Cited, All Databases": 494, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 15", "Publication Year": 2021, "Volume": 5, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2408, "End Page": 2419, "Article Number": null, "DOI": "10.1016/j.joule.2021.06.020", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2021.06.020", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000696854300014", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mortazavi, B; Javvaji, B; Shojaei, F; Rabczuk, T; Shapeev, A; Zhuang, XY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mortazavi, Bohayra; Javvaji, Brahmanulldam; Shojaei, Fazel; Rabczuk, Timon; Shapeev, Alexander, V; Zhuang, Xiaoying", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Exceptional piezoelectricity, high thermal conductivity and stiffness and promising photocatalysis in two-dimensional MoSi2N4 family confirmed by first-principles", "Source Title": "nullO ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Chemical vapor deposition has been most recently employed to fabricate centimeter-scale high-quality singlelayer MoSi2N4 (Science; 2020;369; 670). Motivated by this exciting experimental advance, herein we conduct extensive first-principles based simulations to explore the stability, mechanical properties, lattice thermal conductivity, piezoelectric and flexoelectric response, and photocatalytic and electronic features of MA(2)Z(4) (M = Cr, Mo, W; A = Si, Ge; Z = N, P) monolayers. The considered nullosheets are found to exhibit dynamical stability and remarkably high mechanical properties. Moreover, they show diverse electronic properties from antiferromagnetic metal to half metal and to semiconductors with band gaps ranging from 0.31 to 2.57 eV. Among the studied nullosheets, the MoSi2N4 and WSi2N4 monolayers yield appropriate band edge positions, high electron and hole mobilities, and strong visible light absorption, highly promising for applications in optoelectronics and photocatalytic water splitting. The MoSi2N4 and WSi2N4 monolayers are also predicted to show outstandingly high lattice thermal conductivity of 440 and 500 W/mK, respectively. For the first time we show that machine learning interatomic potentials trained over small supercells can be employed to examine the flexoelectric and piezoelectric properties of complex structures. As the most exciting finding, WSi2N4, CrSi2N4 and MoSi2N4 are found to exhibit the highest piezoelectric coefficients, outperforming all other-known 2D materials. Our results highlight that MA(2)Z(4) nullosheets not only undoubtedly outperform the transition metal dichalcogenides family but also can compete with graphene for applications in nulloelectronics, optoelectronic, energy storage/conversion and thermal management systems.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 460, "Times Cited, All Databases": 467, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 82, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 105716, "DOI": "10.1016/j.nulloen.2020.105716", "DOI Link": "http://dx.doi.org/10.1016/j.nulloen.2020.105716", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000634235000004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pan, QS; Zhang, LX; Feng, R; Lu, QH; An, K; Chuang, AC; Poplawsky, JD; Liaw, PK; Lu, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pan, Qingsong; Zhang, Liangxue; Feng, Rui; Lu, Qiuhong; An, Ke; Chuang, Andrew Chihpin; Poplawsky, Jonathan D.; Liaw, Peter K.; Lu, Lei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Gradient cell-structured high-entropy alloy with exceptional strength and ductility", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Similar to conventional materials, most multicomponent high-entropy alloys (HEAs) lose ductility as they gain strength. In this study, we controllably introduced gradient nulloscaled dislocation cell structures in a stable single-phase HEA with face-centered cubic structure, thus resulting in enhanced strength without apparent loss of ductility. Upon application of strain, the sample-level structural gradient induces progressive formation of a high density of tiny stacking faults (SFs) and twins, nucleating from abundant low-angle dislocation cells. Furthermore, the SF-induced plasticity and the resultant refined structures, coupled with intensively accumulated dislocations, contribute to plasticity, increased strength, and work hardening. These findings offer a promising paradigm for tailoring properties with gradient dislocation cells at the nulloscale and advance our fundamental understanding of the intrinsic deformation behavior of HEAs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 470, "Times Cited, All Databases": 479, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 19", "Publication Year": 2021, "Volume": 374, "Issue": 6570, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 984, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abj8114", "DOI Link": "http://dx.doi.org/10.1126/science.abj8114", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000720789200034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xia, C; Qiu, YR; Xia, Y; Zhu, P; King, G; Zhang, X; Wu, ZY; Kim, JY; Cullen, DA; Zheng, DX; Li, P; Shakouri, M; Heredia, E; Cui, PX; Alshareef, HN; Hu, YF; Wang, HT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xia, Chuan; Qiu, Yunrui; Xia, Yang; Zhu, Peng; King, Graham; Zhang, Xiao; Wu, Zhenyu; Kim, Jung Yoon (Timothy); Cullen, David A.; Zheng, Dongxing; Li, Peng; Shakouri, Mohsen; Heredia, Emilio; Cui, Peixin; Alshareef, Husam N.; Hu, Yongfeng; Wang, Haotian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "General synthesis of single-atom catalysts with high metal loading using graphene quantum dots", "Source Title": "NATURE CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transition-metal single-atom catalysts present extraordinary activity per metal atomic site, but suffer from low metal-atom densities (typically less than 5 wt% or 1 at.%), which limits their overall catalytic performance. Here we report a general method for the synthesis of single-atom catalysts with high transition-metal-atom loadings of up to 40 wt% or 3.8 at.%, representing several-fold improvements compared to benchmarks in the literature. Graphene quantum dots, later interweaved into a carbon matrix, were used as a support, providing numerous anchoring sites and thus facilitating the generation of high densities of transition-metal atoms with sufficient spacing between the metal atoms to avoid aggregation. A significant increase in activity in electrochemical CO2 reduction (used as a representative reaction) was demonstrated on a Ni single-atom catalyst with increased Ni loading.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 460, "Times Cited, All Databases": 471, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2021, "Volume": 13, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 887, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41557-021-00734-x", "DOI Link": "http://dx.doi.org/10.1038/s41557-021-00734-x", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000665817700002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Y; Chen, B; Guan, DQ; Xu, MG; Ran, R; Ni, M; Zhou, W; O'Hayre, R; Shao, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yuan; Chen, Bin; Guan, Daqin; Xu, Meigui; Ran, Ran; Ni, Meng; Zhou, Wei; O'Hayre, Ryan; Shao, Zongping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermal-expansion offset for high-performance fuel cell cathodes", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "One challenge for the commercial development of solid oxide fuel cells as efficient energy-conversion devices isthermo-mechanical instability. Large internal-strain gradients caused by the mismatch in thermal expansion behaviour between different fuel cell components are the main cause of this instability, which can lead to cell degradation, delamination or fracture(1-4). Here we demonstrate an approach to realizing full thermo-mechanical compatibility between the cathode and other cell components by introducing a thermal-expansion offset. We use reactive sintering to combine a cobalt-based perovskite with high electrochemical activity and large thermal-expansion coefficient with a negative-thermal-expansion material, thus forming a composite electrode with a thermal-expansion behaviour that is well matched to that of the electrolyte. A new interphase is formed because of the limited reaction between the two materials in the composite during the calcination process, which also creates A-site deficiencies in the perovskite. As a result, the composite shows both high activity and excellent stability. The introduction of reactive negative-thermal-expansion components may provide a general strategy for the development of fully compatible and highly active electrodes for solid oxide fuel cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 436, "Times Cited, All Databases": 460, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 11", "Publication Year": 2021, "Volume": 591, "Issue": 7849, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 246, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-03264-1", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03264-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000627422700012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, ZF; Huang, RK; Zheng, BN; Guo, WT; Li, CK; He, WY; Wei, YG; Du, Y; Wang, HM; Wu, DC; Wang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Zifeng; Huang, Rongkang; Zheng, Bingna; Guo, Wentai; Li, Chuangkun; He, Wenyi; Wei, Yingqi; Du, Yang; Wang, Huaiming; Wu, Dingcai; Wang, Hui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Stretchable, Adhesive, Biocompatible, and Antibacterial Hydrogel Dressings for Wound Healing", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Treatment of wounds in special areas is challenging due to inevitable movements and difficult fixation. Common cotton gauze suffers from incomplete joint surface coverage, confinement of joint movement, lack of antibacterial function, and frequent replacements. Hydrogels have been considered as good candidates for wound dressing because of their good flexibility and biocompatibility. Nevertheless, the adhesive, mechanical, and antibacterial properties of conventional hydrogels are not satisfactory. Herein, cationic polyelectrolyte brushes grafted from bacterial cellulose (BC) nullofibers are introduced into polydopamine/polyacrylamide hydrogels. The 1D polymer brushes have rigid BC backbones to enhance mechanical property of hydrogels, realizing high tensile strength (21-51 kPa), large tensile strain (899-1047%), and ideal compressive property. Positively charged quaternary ammonium groups of tethered polymer brushes provide long-lasting antibacterial property to hydrogels and promote crawling and proliferation of negatively charged epidermis cells. Moreover, the hydrogels are rich in catechol groups and capable of adhering to various surfaces, meeting adhesive demand of large movement for special areas. With the above merits, the hydrogels demonstrate less inflammatory response and faster healing speed for in vivo wound healing on rats. Therefore, the multifunctional hydrogels show stable covering, little displacement, long-lasting antibacteria, and fast wound healing, demonstrating promise in wound dressing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 439, "Times Cited, All Databases": 452, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 8, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2003627, "DOI": "10.1002/advs.202003627", "DOI Link": "http://dx.doi.org/10.1002/advs.202003627", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000625411600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Gu, WH; Sheng, JQ; Huang, QQ; Wang, GH; Chen, JB; Ji, GB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Gu, Weihua; Sheng, Jiaqi; Huang, Qianqian; Wang, Gehuan; Chen, Jiabin; Ji, Guangbin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Environmentally Friendly and Multifunctional Shaddock Peel-Based Carbon Aerogel for Thermal-Insulation and Microwave Absorption", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "HighlightsThe eco-friendly shaddock peel-derived carbon aerogels were prepared by a freeze-drying method.Multiple functions such as thermal insulation, compression resistance and microwave absorption can be integrated into one material-carbon aerogel.Novel computer simulation technology strategy was selected to simulate significant radar cross-sectional reduction values under real far field condition..AbstractEco-friendly electromagnetic wave absorbing materials with excellent thermal infrared stealth property, heat-insulating ability and compression resistance are highly attractive in practical applications. Meeting the aforesaid requirements simultaneously is a formidable challenge. Herein, ultra-light carbon aerogels were fabricated via fresh shaddock peel by facile freeze-drying method and calcination process, forming porous network architecture. With the heating platform temperature of 70 degrees C, the upper surface temperatures of the as-prepared carbon aerogel present a slow upward trend. The color of the sample surface in thermal infrared images is similar to that of the surroundings. With the maximum compressive stress of 2.435 kPa, the carbon aerogels can provide favorable endurance. The shaddock peel-based carbon aerogels possess the minimum reflection loss value (RLmin) of - 29.50 dB in X band. Meanwhile, the effective absorption bandwidth covers 5.80 GHz at a relatively thin thickness of only 1.7 mm. With the detection theta of 0 degrees, the maximum radar cross-sectional (RCS) reduction values of 16.28 dB m(2) can be achieved. Theoretical simulations of RCS have aroused extensive interest owing to their ingenious design and time-saving feature. This work paves the way for preparing multi-functional microwave absorbers derived from biomass raw materials under the guidance of RCS simulations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 431, "Times Cited, All Databases": 449, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 5", "Publication Year": 2021, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 102, "DOI": "10.1007/s40820-021-00635-1", "DOI Link": "http://dx.doi.org/10.1007/s40820-021-00635-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000637357900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, JW; Zheng, XL; Feng, ZP; Lu, ZY; Zhang, ZW; Huang, W; Li, YB; Vuckovic, D; Li, YQ; Dai, S; Chen, GX; Wang, KC; Wang, HS; Chen, JK; Mitch, W; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Jinwei; Zheng, Xueli; Feng, Zhiping; Lu, Zhiyi; Zhang, Zewen; Huang, William; Li, Yanbin; Vuckovic, Djordje; Li, Yuanqing; Dai, Sheng; Chen, Guangxu; Wang, Kecheng; Wang, Hansen; Chen, James K.; Mitch, William; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Organic wastewater treatment by a single-atom catalyst and electrolytically produced H2O2", "Source Title": "NATURE SUSTAINABILITY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The presence of organic contaminullts in wastewater poses considerable risks to the health of both humans and ecosystems. Although advanced oxidation processes that rely on highly reactive radicals to destroy organic contaminullts are appealing treatment options, substantial energy and chemical inputs limit their practical applications. Here we demonstrate that Cu single atoms incorporated in graphitic carbon nitride can catalytically activate H2O2 to generate hydroxyl radicals at pH 7.0 without energy input, and show robust stability within a filtration device. We further design an electrolysis reactor for the on-site generation of H2O2 from air, water and renewable energy. Coupling the single-atom catalytic filter and the H2O2 electrolytic generator in tandem delivers a wastewater treatment system. These findings provide a promising path toward reducing the energy and chemical demands of advanced oxidation processes, as well as enabling their implementation in remote areas and isolated communities. Here the authors design an electrolysis reactor to generate H2O2 which could be further catalytically activated by Cu single atoms to yield hydroxyl radicals. Combining the two reactions enables a system that could treat organic wastewater, providing a path toward sustainable advanced oxidation processes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 479, "Times Cited, All Databases": 494, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2021, "Volume": 4, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 233, "End Page": 241, "Article Number": null, "DOI": "10.1038/s41893-020-00635-w", "DOI Link": "http://dx.doi.org/10.1038/s41893-020-00635-w", "Book DOI": null, "Early Access Date": "NOV 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000588002700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, YM; Xue, ZQ; Liu, QL; Jia, YL; Li, YL; Liu, K; Lin, YY; Liu, M; Li, GQ; Su, CY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Yamei; Xue, Ziqian; Liu, Qinglin; Jia, Yaling; Li, Yinle; Liu, Kang; Lin, Yiyang; Liu, Min; Li, Guangqin; Su, Cheng-Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Modulating electronic structure of metal-organic frameworks by introducing atomically dispersed Ru for efficient hydrogen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing high-performance electrocatalysts toward hydrogen evolution reaction is important for clean and sustainable hydrogen energy, yet still challenging. Herein, we report a single-atom strategy to construct excellent metal-organic frameworks (MOFs) hydrogen evolution reaction electrocatalyst (NiRu0.13-BDC) by introducing atomically dispersed Ru. Significantly, the obtained NiRu0.13-BDC exhibits outstanding hydrogen evolution activity in all pH, especially with a low overpotential of 36mV at a current density of 10mAcm(-2) in 1M phosphate buffered saline solution, which is comparable to commercial Pt/C. X-ray absorption fine structures and the density functional theory calculations reveal that introducing Ru single-atom can modulate electronic structure of metal center in the MOF, leading to the optimization of binding strength for H2O and H*, and the enhancement of HER performance. This work establishes single-atom strategy as an efficient approach to modulate electronic structure of MOFs for catalyst design. Developing high-performance, neutral-media H-2-evolution electrocatalysts is important for clean and sustainable hydrogen energy, yet rare, expensive elements are most active. Here, authors show that metal-organic frameworks modified with single ruthenium atoms as high-performances catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 489, "Times Cited, All Databases": 498, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1369, "DOI": "10.1038/s41467-021-21595-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21595-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000626168500025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Stern, MV; Waschitz, Y; Cao, W; Nevo, ; Watanabe, K; Taniguchi, T; Sela, E; Urbakh, M; Hod, O; Ben Shalom, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Stern, M. Vizner; Waschitz, Y.; Cao, W.; Nevo, I; Watanabe, K.; Taniguchi, T.; Sela, E.; Urbakh, M.; Hod, O.; Ben Shalom, M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interfacial ferroelectricity by van der Waals sliding", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Despite their partial ionic nature, many-layered diatomic crystals avoid internal electric polarization by forming a centrosymmetric lattice at their optimal van der Waals stacking. Here, we report a stable ferroelectric order emerging at the interface between two naturally grown flakes of hexagonal boron nitride, which are stacked together in a metastable non-centrosymmetric parallel orientation. We observe alternating domains of inverted normal polarization, caused by a lateral shift of one lattice site between the domains. Reversible polarization switching coupled to lateral sliding is achieved by scanning a biased tip above the surface. Our calculations trace the origin of the phenomenon to a subtle interplay between charge redistribution and ionic displacement and provide intuitive insights to explore the interfacial polarization and its distinctive slidetronics switching mechanism.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 447, "Times Cited, All Databases": 459, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 25", "Publication Year": 2021, "Volume": 372, "Issue": 6549, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1462, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abe8177", "DOI Link": "http://dx.doi.org/10.1126/science.abe8177", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000665860000052", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mu, SN; Liu, QR; Kidkhunthod, P; Zhou, XL; Wang, WL; Tang, YB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mu, Sainull; Liu, Qirong; Kidkhunthod, Pinit; Zhou, Xiaolong; Wang, Wenlou; Tang, Yongbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Molecular grafting towards high-fraction active nullodots implanted in N-doped carbon for sodium dual-ion batteries", "Source Title": "NATIONAL SCIENCE REVIEW", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sodium-based dual-ion batteries (Na-DIBs) show a promising potential for large-scale energy storage applications due to the merits of environmental friendliness and low cost. However, Na-DIBs are generally subject to poor rate capability and cycling stability for the lack of suitable anodes to accommodate large Na+ ions. Herein, we propose a molecular grafting strategy to in situ synthesize tin pyrophosphate nullodots implanted in N-doped carbon matrix (SnP2O7@N-C), which exhibits a high fraction of active SnP2O7 up to 95.6 wt% and a low content of N-doped carbon (4.4 wt%) as the conductive framework. As a result, this anode delivers a high specific capacity similar to 400 mAh g(-1) at 0.1Ag(-1), excellent rate capability up to 5.0Ag(-1) and excellent cycling stability with a capacity retention of 92% after 1200 cycles under a current density of 1.5Ag(-1). Further, pairing this anode with an environmentally friendly KS6 graphite cathode yields a SnP2O7@N-C||KS6 Na-DIB, exhibiting an excellent rate capability up to 30 C, good fast-charge/slow-discharge performance and long-term cycling life with a capacity retention of similar to 96% after 1000 cycles at 20 C. This study provides a feasible strategy to develop high-performance anodes with high-fraction active materials for Na-based energy storage applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 464, "Times Cited, All Databases": 468, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2021, "Volume": 8, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "nwaa178", "DOI": "10.1093/nsr/nwaa178", "DOI Link": "http://dx.doi.org/10.1093/nsr/nwaa178", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000697170300004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, JZ; Sheng, HY; Ross, RD; Han, JC; Wang, XJ; Song, B; Jin, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Jinzhen; Sheng, Hongyuan; Ross, R. Dominic; Han, Jiecai; Wang, Xianjie; Song, Bo; Jin, Song", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Modifying redox properties and local bonding of Co3O4 by CeO2 enhances oxygen evolution catalysis in acid", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing efficient and stable earth-abundant electrocatalysts for acidic oxygen evolution reaction is the bottleneck for water splitting using proton exchange membrane electrolyzers. Here, we show that nullocrystalline CeO2 in a Co3O4/CeO2 nullocomposite can modify the redox properties of Co3O4 and enhances its intrinsic oxygen evolution reaction activity, and combine electrochemical and structural characterizations including kinetic isotope effect, pH- and temperature-dependence, in situ Raman and ex situ X-ray absorption spectroscopy analyses to understand the origin. The local bonding environment of Co3O4 can be modified after the introduction of nullocrystalline CeO2, which allows the Co-III species to be easily oxidized into catalytically active Co-IV species, bypassing the potential-determining surface reconstruction process. Co3O4/CeO2 displays a comparable stability to Co3O4 thus breaks the activity/stability tradeoff. This work not only establishes an efficient earth-abundant catalysts for acidic oxygen evolution reaction, but also provides strategies for designing more active catalysts for other reactions. Developing efficient and stable earth-abundant electrocatalysts for acidic oxygen evolution reaction is challenging. Here, the authors modify the local bonding environment of Co3O4 by CeO2 nullocrystallites to regulate the redox properties, thus enhance the catalytic activity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 457, "Times Cited, All Databases": 466, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 24", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3036, "DOI": "10.1038/s41467-021-23390-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-23390-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000658769300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hassan, Y; Park, JH; Crawford, ML; Sadhanala, A; Lee, J; Sadighian, JC; Mosconi, E; Shivanna, R; Radicchi, E; Jeong, M; Yang, C; Choi, H; Park, SH; Song, MH; De Angelis, F; Wong, CY; Friend, RH; Lee, BR; Snaith, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hassan, Yasser; Park, Jong Hyun; Crawford, Michael L.; Sadhanala, Aditya; Lee, Jeongjae; Sadighian, James C.; Mosconi, Edoardo; Shivanna, Ravichandran; Radicchi, Eros; Jeong, Mingyu; Yang, Changduk; Choi, Hyosung; Park, Sung Heum; Song, Myoung Hoon; De Angelis, Filippo; Wong, Cathy Y.; Friend, Richard H.; Lee, Bo Ram; Snaith, Henry J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ligand-engineered bandgap stability in mixed-halide perovskite LEDs", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lead halide perovskites are promising semiconductors for light-emitting applications because they exhibit bright, bandgap-tunable luminescence with high colour purity(1,2). Photoluminescence quantum yields close to unity have been achieved for perovskite nullocrystals across a broad range of emission colours, and light-emitting diodes with external quantum efficiencies exceeding 20 per cent-approaching those of commercial organic light-emitting diodes-have been demonstrated in both the infrared and the green emission channels(1,3,4). However, owing to the formation of lower-bandgap iodide-rich domains, efficient and colour-stable red electroluminescence from mixed-halide perovskites has not yet been realized(5,6). Here we report the treatment of mixed-halide perovskite nullocrystals with multidentate ligands to suppress halide segregation under electroluminescent operation. We demonstrate colour-stable, red emission centred at 620 nullometres, with an electroluminescence external quantum efficiency of 20.3 per cent. We show that a key function of the ligand treatment is to 'clean' the nullocrystal surface through the removal of lead atoms. Density functional theory calculations reveal that the binding between the ligands and the nullocrystal surface suppresses the formation of iodine Frenkel defects, which in turn inhibits halide segregation. Our work exemplifies how the functionality of metal halide perovskites is extremely sensitive to the nature of the (nullo)crystalline surface and presents a route through which to control the formation and migration of surface defects. This is critical to achieve bandgap stability for light emission and could also have a broader impact on other optoelectronic applications-such as photovoltaics-for which bandgap stability is required.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 421, "Times Cited, All Databases": 439, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 4", "Publication Year": 2021, "Volume": 591, "Issue": 7848, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 72, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-03217-8", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03217-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000626921700012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tan, DHS; Chen, YT; Yang, HD; Bao, W; Sreenarayanull, B; Doux, JM; Li, WK; Lu, BY; Ham, SY; Sayahpour, B; Scharf, J; Wu, EA; Deysher, G; Han, HE; Hah, HJ; Jeong, H; Lee, JB; Chen, Z; Meng, YS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tan, Darren H. S.; Chen, Yu-Ting; Yang, Hedi; Bao, Wurigumula; Sreenarayanull, Bhagath; Doux, Jean-Marie; Li, Weikang; Lu, Bingyu; Ham, So-Yeon; Sayahpour, Baharak; Scharf, Jonathan; Wu, Erik A.; Deysher, Grayson; Han, Hyea Eun; Hah, Hoe Jin; Jeong, Hyeri; Lee, Jeong Beom; Chen, Zheng; Meng, Ying Shirley", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Carbon-free high-loading silicon anodes enabled by sulfide solid electrolytes", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of silicon anodes for lithium-ion batteries has been largely impeded by poor interfacial stability against liquid electrolytes. Here, we enabled the stable operation of a 99.9 weight % microsilicon anode by using the interface passivating properties of sulfide solid electrolytes. Bulk and surface characterization, and quantification of interfacial components, showed that such an approach eliminates continuous interfacial growth and irreversible lithium losses. Microsilicon full cells were assembled and found to achieve high areal current density, wide operating temperature range, and high areal loadings for the different cells. The promising performance can be attributed to both the desirable interfacial property between microsilicon and sulfide electrolytes and the distinctive chemomechanical behavior of the lithium-silicon alloy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 592, "Times Cited, All Databases": 632, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 24", "Publication Year": 2021, "Volume": 373, "Issue": 6562, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1494, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abg7217", "DOI Link": "http://dx.doi.org/10.1126/science.abg7217", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000698977800047", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, SF; Ji, X; Piao, N; Chen, J; Eidson, N; Xu, JJ; Wang, PF; Chen, L; Zhang, JX; Deng, T; Hou, S; Jin, T; Wan, HL; Li, JR; Tu, JP; Wang, CS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Sufu; Ji, Xiao; Piao, null; Chen, Ji; Eidson, Nico; Xu, Jijian; Wang, Pengfei; Chen, Long; Zhang, Jiaxun; Deng, Tao; Hou, Singyuk; Jin, Ting; Wan, Hongli; Li, Jingru; Tu, Jiangping; Wang, Chunsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An Inorganic-Rich Solid Electrolyte Interphase for Advanced Lithium-Metal Batteries in Carbonate Electrolytes", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In carbonate electrolytes, the organic-inorganic solid electrolyte interphase (SEI) formed on the Li-metal anode surface is strongly bonded to Li and experiences the same volume change as Li, thus it undergoes continuous cracking/reformation during plating/stripping cycles. Here, an inorganic-rich SEI is designed on a Li-metal surface to reduce its bonding energy with Li metal by dissolving 4m concentrated LiNO3 in dimethyl sulfoxide (DMSO) as an additive for a fluoroethylene-carbonate (FEC)-based electrolyte. Due to the aggregate structure of NO3- ions and their participation in the primary Li+ solvation sheath, abundant Li2O, Li3N, and LiNxOy grains are formed in the resulting SEI, in addition to the uniform LiF distribution from the reduction of PF6- ions. The weak bonding of the SEI (high interface energy) to Li can effectively promote Li diffusion along the SEI/Li interface and prevent Li dendrite penetration into the SEI. As a result, our designed carbonate electrolyte enables a Li anode to achieve a high Li plating/stripping Coulombic efficiency of 99.55 % (1 mA cm(-2), 1.0 mAh cm(-2)) and the electrolyte also enables a Li||LiNi0.8Co0.1Mn0.1O2 (NMC811) full cell (2.5 mAh cm(-2)) to retain 75 % of its initial capacity after 200 cycles with an outstanding CE of 99.83 %.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 403, "Times Cited, All Databases": 420, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2021, "Volume": 60, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3661, "End Page": 3671, "Article Number": null, "DOI": "10.1002/anie.202012005", "DOI Link": "http://dx.doi.org/10.1002/anie.202012005", "Book DOI": null, "Early Access Date": "DEC 2020", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000599074500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xing, Z; Hu, L; Ripatti, DS; Hu, X; Feng, XF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xing, Zhuo; Hu, Lin; Ripatti, Donald S.; Hu, Xun; Feng, Xiaofeng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhancing carbon dioxide gas-diffusion electrolysis by creating a hydrophobic catalyst microenvironment", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electroreduction of carbon dioxide (CO2) over copper-based catalysts provides an attractive approach for sustainable fuel production. While efforts are focused on developing catalytic materials, it is also critical to understand and control the microenvironment around catalytic sites, which can mediate the transport of reaction species and influence reaction pathways. Here, we show that a hydrophobic microenvironment can significantly enhance CO2 gas-diffusion electrolysis. For proof-of-concept, we use commercial copper nulloparticles and disperse hydrophobic polytetrafluoroethylene (PTFE) nulloparticles inside the catalyst layer. Consequently, the PTFE-added electrode achieves a greatly improved activity and Faradaic efficiency for CO2 reduction, with a partial current density >250 mA cm(-2) and a single-pass conversion of 14% at moderate potentials, which are around twice that of a regular electrode without added PTFE. The improvement is attributed to a balanced gas/liquid microenvironment that reduces the diffusion layer thickness, accelerates CO2 mass transport, and increases CO2 local concentration for the electrolysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 420, "Times Cited, All Databases": 435, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 8", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 136, "DOI": "10.1038/s41467-020-20397-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20397-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000626604800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, J; Gui, H; Banfield, CC; Wen, Y; Zang, HD; Dippold, MA; Charlton, A; Jones, DL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Jie; Gui, Heng; Banfield, Callum C.; Wen, Yuan; Zang, Huadong; Dippold, Michaela A.; Charlton, Adam; Jones, Davey L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The microplastisphere: Biodegradable microplastics addition alters soil microbial community structure and function", "Source Title": "SOIL BIOLOGY & BIOCHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Plastics accumulating in the environment, especially microplastics (defined as particles <5 mm), can lead to a range of problems and potential loss of ecosystem services. Polyhydroxyalkanoates (PHAs) are biodegradable plastics used in mulch films, and in packaging material to minimize plastic waste and to reduce soil pollution. Little is known, however, about the effect of microbioplastics on soil-plant interactions, especially soil microbial community structure and functioning in agroecosystems. For the first time, we combined zymography (to localize enzyme activity hotspots) with substrate-induced growth respiration to investigate the effect of PHAs addition on soil microbial community structure, growth, and exoenzyme kinetics in the microplastisphere (i.e. interface between soil and microplastic particles) compared to the rhizosphere and bulk soil. We used a common PHAs biopolymer, poly (3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) and showed that PHBV was readily used by the microbial community as a source of carbon (C) resulting in an increased specific microbial growth rate and a more active microbial biomass in the microplastisphere in comparison to the bulk soil. Higher ss-glucosidase and leucine aminopeptidase activities (0.6-5.0 times higher Vmax) and lower enzyme affinities (1.5-2.0 times higher Km) were also detected in the microplastisphere relative to the rhizosphere. Furthermore, the PHBV addition changed the soil bacterial community at different taxonomical levels and increased the alpha diversity, as well as the relative abundance of Acidobacteria and Verrucomicrobia phyla, compared to the untreated soils. Overall, PHBV addition created soil hotspots where C and nutrient turnover is greatly enhanced, mainly driven by the accelerated microbial biomass and activity. In conclusion, microbioplastics have the potential to alter soil ecological functioning and biogeochemical cycling (e.g., SOM decomposition).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 371, "Times Cited, All Databases": 412, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2021, "Volume": 156, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 108211, "DOI": "10.1016/j.soilbio.2021.108211", "DOI Link": "http://dx.doi.org/10.1016/j.soilbio.2021.108211", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Agriculture", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000640189100034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Karlsson, M; Yi, ZY; Reichert, S; Luo, XY; Lin, WH; Zhang, ZY; Bao, CX; Zhang, R; Bai, S; Zheng, GHJ; Teng, PP; Duan, L; Lu, Y; Zheng, KB; Pullerits, T; Deibel, C; Xu, WD; Friend, R; Gao, F", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Karlsson, Max; Yi, Ziyue; Reichert, Sebastian; Luo, Xiyu; Lin, Weihua; Zhang, Zeyu; Bao, Chunxiong; Zhang, Rui; Bai, Sai; Zheng, Guanhaojie; Teng, Pengpeng; Duan, Lian; Lu, Yue; Zheng, Kaibo; Pullerits, Tonu; Deibel, Carsten; Xu, Weidong; Friend, Richard; Gao, Feng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mixed halide perovskites for spectrally stable and high-efficiency blue light-emitting diodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Bright and efficient blue emission is key to further development of metal halide perovskite light-emitting diodes. Although modifying bromide/chloride composition is straightforward to achieve blue emission, practical implementation of this strategy has been challenging due to poor colour stability and severe photoluminescence quenching. Both detrimental effects become increasingly prominent in perovskites with the high chloride content needed to produce blue emission. Here, we solve these critical challenges in mixed halide perovskites and demonstrate spectrally stable blue perovskite light-emitting diodes over a wide range of emission wavelengths from 490 to 451 nullometres. The emission colour is directly tuned by modifying the halide composition. Particularly, our blue and deep-blue light-emitting diodes based on three-dimensional perovskites show high EQE values of 11.0% and 5.5% with emission peaks at 477 and 467nm, respectively. These achievements are enabled by a vapour-assisted crystallization technique, which largely mitigates local compositional heterogeneity and ion migration. Achieving bright and efficient blue emission in metal halide perovskite light-emitting diodes has proven to be challenging. Here, the authors demonstrate high EQE and spectrally stable blue light-emitting diodes based on mixed halide perovskites, with emission from 490 to 451nm by using a vapour-assisted crystallization technique.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 386, "Times Cited, All Databases": 409, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 13", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 361, "DOI": "10.1038/s41467-020-20582-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-020-20582-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000609611000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Novikov, IS; Gubaev, K; Podryabinkin, E; Shapeev, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Novikov, Ivan S.; Gubaev, Konstantin; Podryabinkin, Evgeny, V; Shapeev, Alexander, V", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The MLIP package: moment tensor potentials with MPI and active learning", "Source Title": "MACHINE LEARNING-SCIENCE AND TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The subject of this paper is the technology (the 'how') of constructing machine-learning interatomic potentials, rather than science (the 'what' and 'why') of atomistic simulations using machine-learning potentials. Namely, we illustrate how to construct moment tensor potentials using active learning as implemented in the MLIP package, focusing on the efficient ways to automatically sample configurations for the training set, how expanding the training set changes the error of predictions, how to set up ab initio calculations in a cost-effective manner, etc. The MLIP package (short for Machine-Learning Interatomic Potentials) is available at https://mlip.skoltech.ru/download/.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 423, "Times Cited, All Databases": 440, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2021, "Volume": 2, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 25002, "DOI": "10.1088/2632-2153/abc9fe", "DOI Link": "http://dx.doi.org/10.1088/2632-2153/abc9fe", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000660868300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, RF; Wang, Y; Ma, Y; Mal, A; Gao, XY; Gao, L; Qiao, LJ; Li, XB; Wu, LZ; Wang, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Rufan; Wang, Yang; Ma, Yuan; Mal, Arindam; Gao, Xiao-Ya; Gao, Lei; Qiao, Lijie; Li, Xu-Bing; Wu, Li-Zhu; Wang, Cheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rational design of isostructural 2D porphyrin-based covalent organic frameworks for tunable photocatalytic hydrogen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Covalent organic frameworks have recently gained increasing attention in photocatalytic hydrogen generation from water. However, their structure-property-activity relationship, which should be beneficial for the structural design, is still far-away explored. Herein, we report the designed synthesis of four isostructural porphyrinic two-dimensional covalent organic frameworks (MPor-DETH-COF, M=H-2, Co, Ni, Zn) and their photocatalytic activity in hydrogen generation. Our results clearly show that all four covalent organic frameworks adopt AA stacking structures, with high crystallinity and large surface area. Interestingly, the incorporation of different transition metals into the porphyrin rings can rationally tune the photocatalytic hydrogen evolution rate of corresponding covalent organic frameworks, with the order of CoPor-DETH-COF", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 395, "Times Cited, All Databases": 403, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 1", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1354, "DOI": "10.1038/s41467-021-21527-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-21527-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000626168500010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yoon, M; Dong, YH; Hwang, J; Sung, J; Cha, H; Ahn, K; Huang, YM; Kang, SJ; Li, J; Cho, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yoon, Moonsu; Dong, Yanhao; Hwang, Jaeseong; Sung, Jaekyung; Cha, Hyungyeon; Ahn, Kihong; Huang, Yimeng; Kang, Seok Ju; Li, Ju; Cho, Jaephil", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reactive boride infusion stabilizes Ni-rich cathodes for lithium-ion batteries", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Engineered polycrystalline electrodes are critical to the cycling stability and safety of lithium-ion batteries, yet it is challenging to construct high-quality coatings at both the primary- and secondary-particle levels. Here we present a room-temperature synthesis route to achieve a full surface coverage of secondary particles and facile infusion into grain boundaries, and thus offer a complete 'coating-plus-infusion' strategy. Cobalt boride metallic glass was successfully applied to a Ni-rich layered cathode LiNi0.8Co0.1Mn0.1O2. It dramatically improved the rate capability and cycling stability, including under high-discharge-rate and elevated-temperature conditions and in pouch full-cells. The superior performance originates from a simultaneous suppression of the microstructural degradation of the intergranular cracking and of side reactions with the electrolyte. Atomistic simulations identified the critical role of strong selective interfacial bonding, which offers not only a large chemical driving force to ensure uniform reactive wetting and facile infusion, but also lowers the surface/interface oxygen activity, which contributes to the exceptional mechanical and electrochemical stabilities of the infused electrode. Coating is commonly used to improve electrode performance in batteries, but it is challenging to achieve and maintain complete coverage of electrode particles during cycling. Here the authors present a coating-and-infusion approach on Ni-rich cathodes that effectively retards stress corrosion cracking.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 383, "Times Cited, All Databases": 407, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 6, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 362, "End Page": 371, "Article Number": null, "DOI": "10.1038/s41560-021-00782-0", "DOI Link": "http://dx.doi.org/10.1038/s41560-021-00782-0", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000623725900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, CB; Liu, TF; Sheng, OW; Li, M; Liu, TC; Yuan, YF; Nai, JW; Ju, ZJ; Zhang, WK; Liu, YJ; Wang, Y; Lin, Z; Lu, J; Tao, XY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Chengbin; Liu, Tiefeng; Sheng, Ouwei; Li, Matthew; Liu, Tongchao; Yuan, Yifei; Nai, Jianwei; Ju, Zhijin; Zhang, Wenkui; Liu, Yujing; Wang, Yao; Lin, Zhan; Lu, Jun; Tao, Xinyong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rejuvenating dead lithium supply in lithium metal anodes by iodine redox", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Inactive lithium (more frequently called dead lithium) in the forms of solid-electrolyte interphase and electrically isolated metallic lithium is principally responsible for the performance decay commonly observed in lithium metal batteries. A fundamental solution of recovering dead lithium is urgently needed to stabilize lithium metal batteries. Here we quantify the solid-electrolyte interphase components, and determine their relation with the formation of electrically isolated dead lithium metal. We present a lithium restoration method based on a series of iodine redox reactions mainly involving I-3(-)/I-. Using a biochar capsule host for iodine, we show that the I-3(-)/I- redox takes place spontaneously, effectively rejuvenating dead lithium to compensate the lithium loss. Through this design, a full-cell using a very limited lithium metal anode exhibits an excellent lifespan of 1,000 cycles with a high Coulombic efficiency of 99.9%. We also demonstrate the design with a commercial cathode in pouch cells. Cycling lithium batteries often results in inactive lithium that no longer participates in redox reactions, leading to performance deterioration. Here the authors use an iodic species to react with inactive lithium, bringing it back to life and thus making batteries last longer.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 373, "Times Cited, All Databases": 400, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2021, "Volume": 6, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 378, "End Page": 387, "Article Number": null, "DOI": "10.1038/s41560-021-00789-7", "DOI Link": "http://dx.doi.org/10.1038/s41560-021-00789-7", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000627674900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Le Corre, VM; Duijnstee, EA; El Tambouli, O; Ball, JM; Snaith, HJ; Lim, J; Koster, LJA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Le Corre, Vincent M.; Duijnstee, Elisabeth A.; El Tambouli, Omar; Ball, James M.; Snaith, Henry J.; Lim, Jongchul; Koster, L. Jan Anton", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Revealing Charge Carrier Mobility and Defect Densities in Metal Halide Perovskites via Space-Charge-Limited Current Measurements", "Source Title": "ACS ENERGY LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Space-charge-limited current (SCLC) measurements have been widely used to study the charge carrier mobility and trap density in semiconductors. However, their applicability to metal halide perovskites is not straightforward, due to the mixed ionic and electronic nature of these materials. Here, we discuss the pitfalls of SCLC for perovskite semiconductors, and especially the effect of mobile ions. We show, using driftdiffusion (DD) simulations, that the ions strongly affect the measurement and that the usual analysis and interpretation of SCLC need to be refined. We highlight that the trap density and mobility cannot be directly quantified using classical methods. We discuss the advantages of pulsed SCLC for obtaining reliable data with minimal influence of the ionic motion. We then show that fitting the pulsed SCLC with DD modeling is a reliable method for extracting mobility, trap, and ion densities simultaneously. As a proof of concept, we obtain a trap density of 1.3 x 10(13) cm(-3), an ion density of 1.1 x 10(13) cm(-3), and a mobility of 13 cm(2) V-1 s(-1) for a MAPbBr(3) single crystal.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 405, "Times Cited, All Databases": 409, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 12", "Publication Year": 2021, "Volume": 6, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1087, "End Page": 1094, "Article Number": null, "DOI": "10.1021/acsenergylett.0c02599", "DOI Link": "http://dx.doi.org/10.1021/acsenergylett.0c02599", "Book DOI": null, "Early Access Date": "FEB 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000629230800029", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Place, APM; Rodgers, LVH; Mundada, P; Smitham, BM; Fitzpatrick, M; Leng, ZQ; Premkumar, A; Bryon, J; Vrajitoarea, A; Sussman, S; Cheng, GM; Madhavan, T; Babla, HK; Le, XH; Gang, YQ; Jäck, B; Gyenis, A; Yao, N; Cava, RJ; de Leon, NP; Houck, AA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Place, Alexander P. M.; Rodgers, Lila V. H.; Mundada, Pranav; Smitham, Basil M.; Fitzpatrick, Mattias; Leng, Zhaoqi; Premkumar, Anjali; Bryon, Jacob; Vrajitoarea, Andrei; Sussman, Sara; Cheng, Guangming; Madhavan, Trisha; Babla, Harshvardhan K.; Le, Xuan Hoang; Gang, Youqi; Jack, Berthold; Gyenis, Andras; Yao, null; Cava, Robert J.; de Leon, Nathalie P.; Houck, Andrew A.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "New material platform for superconducting transmon qubits with coherence times exceeding 0.3 milliseconds", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The superconducting transmon qubit is a leading platform for quantum computing and quantum science. Building large, useful quantum systems based on transmon qubits will require significant improvements in qubit relaxation and coherence times, which are orders of magnitude shorter than limits imposed by bulk properties of the constituent materials. This indicates that relaxation likely originates from uncontrolled surfaces, interfaces, and contaminullts. Previous efforts to improve qubit lifetimes have focused primarily on designs that minimize contributions from surfaces. However, significant improvements in the lifetime of two-dimensional transmon qubits have remained elusive for several years. Here, we fabricate two-dimensional transmon qubits that have both lifetimes and coherence times with dynamical decoupling exceeding 0.3 milliseconds by replacing niobium with tantalum in the device. We have observed increased lifetimes for seventeen devices, indicating that these material improvements are robust, paving the way for higher gate fidelities in multi-qubit processors. Quantum computers based on superconducting transmon qubits are limited by single qubit lifetimes and coherence times, which are orders of magnitude shorter than limits imposed by bulk material properties. Here, the authors fabricate two-dimensional transmon qubits with both lifetimes and coherence times longer than 0.3 milliseconds by replacing niobium with tantalum in the device.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 331, "Times Cited, All Databases": 400, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 19", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1779, "DOI": "10.1038/s41467-021-22030-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-22030-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000631934100011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ortiz, BR; Sarte, PM; Kenney, EM; Graf, MJ; Teicher, SML; Seshadri, R; Wilson, SD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ortiz, Brenden R.; Sarte, Paul M.; Kenney, Eric M.; Graf, Michael J.; Teicher, Samuel M. L.; Seshadri, Ram; Wilson, Stephen D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Superconductivity in the Z2 kagome metal KV3Sb5", "Source Title": "PHYSICAL REVIEW MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Here we report the observation of bulk superconductivity in single crystals of the two-dimensional kagome metal KV3Sb5. Magnetic susceptibility, resistivity, and heat capacity measurements reveal superconductivity below T-c = 0.93 K, and density functional theory (DFT) calculations further characterize the normal state as a Z(2) topological metal. Our results demonstrate that the recent observation of superconductivity within the related kagome metal CsV3Sb5 is likely a common feature across the AV(3)Sb(5) (A: K, Rb, Cs) family of compounds and establishes them as a rich arena for studying the interplay between bulk superconductivity, topological surface states, and likely electronic density wave order in an exfoliable kagome lattice.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 380, "Times Cited, All Databases": 412, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 2", "Publication Year": 2021, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 34801, "DOI": "10.1103/PhysRevMaterials.5.034801", "DOI Link": "http://dx.doi.org/10.1103/PhysRevMaterials.5.034801", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000627741900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, P; Yuan, XH; Xia, YB; Zhang, Y; Fu, LJ; Liu, LL; Yu, NF; Huang, QH; Wang, B; Hu, XW; Wu, YP; van Ree, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Peng; Yuan, Xinhai; Xia, Yingbin; Zhang, Yi; Fu, Lijun; Liu, Lili; Yu, Nengfei; Huang, Qinghong; Wang, Bin; Hu, Xianwei; Wu, Yuping; van Ree, Teunis", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An Artificial Polyacrylonitrile Coating Layer Confining Zinc Dendrite Growth for Highly Reversible Aqueous Zinc-Based Batteries", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous rechargeable zinc-metal-based batteries are an attractive alternative to lithium-ion batteries for grid-scale energy-storage systems because of their high specific capacity, low cost, eco-friendliness, and nonflammability. However, uncontrollable zinc dendrite growth limits the cycle life by piercing the separator, resulting in low zinc utilization in both alkaline and mild/neutral electrolytes. Herein, a polyacrylonitrile coating layer on a zinc anode produced by a simple drop coating approach to address the dendrite issue is reported. The coating layer not only improves the hydrophilicity of the zinc anode but also regulates zinc-ion transport, consequently facilitating the uniform deposition of zinc ions to avoid dendrite formation. A symmetrical cell with the polymer-coating-layer-modified Zn anode displays dendrite-free plating/stripping with a long cycle lifespan (>1100 h), much better than that of the bare Zn anode. The modified zinc anode coupled with a Mn-doped V2O5 cathode forms a stable rechargeable full battery. This method is a facile and feasible way to solve the zinc dendrite problem for rechargeable aqueous zinc-metal batteries, providing a solid basis for application of aqueous rechargeable Zn batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 382, "Times Cited, All Databases": 395, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2021, "Volume": 8, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2100309, "DOI": "10.1002/advs.202100309", "DOI Link": "http://dx.doi.org/10.1002/advs.202100309", "Book DOI": null, "Early Access Date": "MAR 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000634747100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nguyen, TX; Liao, YC; Lin, CC; Su, YH; Ting, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Thi Xuyen Nguyen; Liao, Yi-Cheng; Lin, Chia-Chun; Su, Yen-Hsun; Ting, Jyh-Ming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Advanced High Entropy Perovskite Oxide Electrocatalyst for Oxygen Evolution Reaction", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A new type of lanthanum-based high entropy perovskite oxide (HEPO) electrocatalyst for the oxygen evolution reaction is reported. The B-site lattices in the HEPO consist of five consecutive first-row transition metals, including Cr, Mn, Fe, Co, and Ni. Equimolar and five non-equimolar HEPO electrocatalysts are studied for their OER electrocatalytic performance. In the five non-equimolar HEPOs, the concentration of one of the five transition metals is doubled in individual samples. The performances of all the HEPOs outperform the single perovskite oxides. The optimized La(CrMnFeCo2Ni)O-3 HEPO exhibits an outstanding OER overpotential of 325 mV at a current density of 10 mA cm(-2) and excellent electrochemical stability after 50 h of testing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 384, "Times Cited, All Databases": 391, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2021, "Volume": 31, "Issue": 27, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2101632, "DOI": "10.1002/adfm.202101632", "DOI Link": "http://dx.doi.org/10.1002/adfm.202101632", "Book DOI": null, "Early Access Date": "MAY 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000646958100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, H; Yang, HT; Hu, B; Zhao, Z; Yuan, J; Xing, YQ; Qian, GJ; Huang, ZH; Li, G; Ye, YH; Ma, S; Ni, SL; Zhang, H; Yin, QW; Gong, CS; Tu, ZJ; Lei, HC; Tan, HX; Zhou, S; Shen, CM; Dong, XL; Yan, BH; Wang, ZQ; Gao, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Hui; Yang, Haitao; Hu, Bin; Zhao, Zhen; Yuan, Jie; Xing, Yuqing; Qian, Guojian; Huang, Zihao; Li, Geng; Ye, Yuhan; Ma, Sheng; Ni, Shunli; Zhang, Hua; Yin, Qiangwei; Gong, Chunsheng; Tu, Zhijun; Lei, Hechang; Tan, Hengxin; Zhou, Sen; Shen, Chengmin; Dong, Xiaoli; Yan, Binghai; Wang, Ziqiang; Gao, Hong-Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Roton pair density wave in a strong-coupling kagome superconductor", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The transition metal kagome lattice materials host frustrated, correlated and topological quantum states of matter(1-9). Recently, a new family of vanadium-based kagome metals, AV(3)Sb(5) (A = K, Rb or Cs), with topological band structures has been discovered(10,11). These layered compounds are nonmagnetic and undergo charge density wave transitions before developing superconductivity at low temperatures(11-19). Here we report the observation of unconventional superconductivity and a pair density wave (PDW) in CsV3Sb5 using scanning tunnelling microscope/spectroscopy and Josephson scanning tunnelling spectroscopy. We find that CsV3Sb5 exhibits a V-shaped pairing gap Delta similar to 0.5 meV and is a strong-coupling superconductor (2 Delta/k(B)T(c) - 5) that coexists with 4a(0) unidirectional and 2a(0) x 2a(0) charge order. Remarkably, we discover a 3Q PDW accompanied by bidirectional 4a(0)/3 spatial modulations of the superconducting gap, coherence peak and gap depth in the tunnelling conductance. We term this novel quantum state a roton PDW associated with an underlying vortex-antivortex lattice that can account for the observed conductance modulations. Probing the electronic states in the vortex halo in an applied magnetic field, in strong field that suppresses superconductivity and in zero field above T-c, reveals that the PDW is a primary state responsible for an emergent pseudogap and intertwined electronic order. Our findings show striking analogies and distinctions to the phenomenology of high-T-c cuprate superconductors, and provide groundwork for understanding the microscopic origin of correlated electronic states and superconductivity in vanadium-based kagome metals.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 404, "Times Cited, All Databases": 443, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 11", "Publication Year": 2021, "Volume": 599, "Issue": 7884, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 222, "End Page": 228, "Article Number": null, "DOI": "10.1038/s41586-021-03983-5", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-03983-5", "Book DOI": null, "Early Access Date": "SEP 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000714336200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, YBT; Panwisawas, C; Ghoussoub, JN; Gong, YL; Clark, JWG; Németh, AAN; McCartney, DG; Reed, RC", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Yuanbo T.; Panwisawas, Chinnapat; Ghoussoub, Joseph N.; Gong, Yilun; Clark, John W. G.; Nemeth, Andre A. N.; McCartney, D. Graham; Reed, Roger C.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Alloys-by-design: Application to new superalloys for additive manufacturing", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "New grades of gamma/gamma' nickel-based superalloy for the additive manufacturing process are designed using computational approaches. Account is taken of the need to avoid defect formation via solidification and solid-state cracking. Processing trials are carried out using powder-based selective laser melting, comparing with the heritage alloys IN939 and CM247LC. Microstructural characterisation, calorimetry and hot tensile testing are used to assess the approach employed. The superior processability and mechanical behaviour of the new alloys are demonstrated. Suggestions are made for refinements to the modelling approach. (C) 2020 Published by Elsevier Ltd on behalf of Acta Materialia Inc.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 360, "Times Cited, All Databases": 391, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2021, "Volume": 202, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 417, "End Page": 436, "Article Number": null, "DOI": "10.1016/j.actamat.2020.09.023", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2020.09.023", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000599929500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Nguyen, PQ; Soenksen, LR; Donghia, NM; Angenent-Mari, NM; de Puig, H; Huang, A; Lee, R; Slomovic, S; Galbersanini, T; Lansberry, G; Sallum, HM; Zhao, EM; Niemi, JB; Collins, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Nguyen, Peter Q.; Soenksen, Luis R.; Donghia, Nina M.; Angenent-Mari, Nicolaas M.; de Puig, Helena; Huang, Ally; Lee, Rose; Slomovic, Shimyn; Galbersanini, Tommaso; Lansberry, Geoffrey; Sallum, Hani M.; Zhao, Evan M.; Niemi, James B.; Collins, James J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wearable materials with embedded synthetic biology sensors for biomolecule detection", "Source Title": "NATURE BIOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Wearable materials are endowed with synthetic biology circuits to detect biomolecules, including SARS-CoV-2 RNA. Integrating synthetic biology into wearables could expand opportunities for noninvasive monitoring of physiological status, disease states and exposure to pathogens or toxins. However, the operation of synthetic circuits generally requires the presence of living, engineered bacteria, which has limited their application in wearables. Here we report lightweight, flexible substrates and textiles functionalized with freeze-dried, cell-free synthetic circuits, including CRISPR-based tools, that detect metabolites, chemicals and pathogen nucleic acid signatures. The wearable devices are activated upon rehydration from aqueous exposure events and report the presence of specific molecular targets by colorimetric changes or via an optical fiber network that detects fluorescent and luminescent outputs. The detection limits for nucleic acids rival current laboratory methods such as quantitative PCR. We demonstrate the development of a face mask with a lyophilized CRISPR sensor for wearable, noninvasive detection of SARS-CoV-2 at room temperature within 90 min, requiring no user intervention other than the press of a button.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 344, "Times Cited, All Databases": 379, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2021, "Volume": 39, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1366, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41587-021-00950-3", "DOI Link": "http://dx.doi.org/10.1038/s41587-021-00950-3", "Book DOI": null, "Early Access Date": "JUN 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biotechnology & Applied Microbiology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000667605500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Thompson, AP; Aktulga, HM; Berger, R; Bolintineanu, DS; Brown, WM; Crozier, PS; Veld, PJI; Kohlmeyer, A; Moore, SG; Nguyen, TD; Shan, R; Stevens, MJ; Tranchida, J; Trott, C; Plimpton, SJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Thompson, Aidan P.; Aktulga, H. Metin; Berger, Richard; Bolintineanu, Dan S.; Brown, W. Michael; Crozier, Paul S.; Veld, Pieter J. in 't; Kohlmeyer, Axel; Moore, Stan G.; Nguyen, Trung Dac; Shan, Ray; Stevens, Mark J.; Tranchida, Julien; Trott, Christian; Plimpton, Steven J.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "LAMMPS-a flexible simulation tool for particle-based materials modeling at the atomic, meso, and continuum scales", "Source Title": "COMPUTER PHYSICS COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Since the classical molecular dynamics simulator LAMMPS was released as an open source code in 2004, it has become a widely-used tool for particle-based modeling of materials at length scales ranging from atomic to mesoscale to continuum. Reasons for its popularity are that it provides a wide variety of particle interaction models for different materials, that it runs on any platform from a single CPU core to the largest supercomputers with accelerators, and that it gives users control over simulation details, either via the input script or by adding code for new interatomic potentials, constraints, diagnostics, or other features needed for their models. As a result, hundreds of people have contributed new capabilities to LAMMPS and it has grown from fifty thousand lines of code in 2004 to a million lines today. In this paper several of the fundamental algorithms used in LAMMPS are described along with the design strategies which have made it flexible for both users and developers. We also highlight some capabilities recently added to the code which were enabled by this flexibility, including dynamic load balancing, on-the-fly visualization, magnetic spin dynamics models, and quantum-accuracy machine learning interatomic potentials. Program Summary Program Title: Large-scale Atomic/Molecular Massively Parallel Simulator (LAMMPS) CPC Library link to program files: https://doi .org /10 .17632 /cxbxs9btsv.1 Developer's repository link: https://github .com /lammps /lammps Licensing provisions: GPLv2 Programming language: C++, Python, C, Fortran Supplementary material: https://www.lammps .org Nature of problem: Many science applications in physics, chemistry, materials science, and related fields require parallel, scalable, and efficient generation of long, stable classical particle dynamics trajectories. Within this common problem definition, there lies a great diversity of use cases, distinguished by different particle interaction models, external constraints, as well as timescales and lengthscales ranging from atomic to mesoscale to macroscopic. Solution method: The LAMMPS code uses parallel spatial decomposition, distributed neighbor lists, and parallel FFTs for long-range Coulombic interactions [1]. The time integration algorithm is based on the Stormer-Verlet symplectic integrator [2], which provides better stability than higher-order non-symplectic methods. In addition, LAMMPS supports a wide range of interatomic potentials, constraints, diagnostics, software interfaces, and pre- and post-processing features. Additional comments including restrictions and unusual features: This paper serves as the definitive reference for the LAMMPS code. References [1] S. Plimpton, Fast parallel algorithms for short-range molecular dynamics. J. Comp. Phys. 117 (1995) 1-19. [2] L. Verlet, Computer experiments on classical fluids: I. Thermodynamical properties of Lennard-Jones molecules, Phys. Rev. 159 (1967) 98-103. (c) 2021 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 5692, "Times Cited, All Databases": 5969, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 271, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 108171, "DOI": "10.1016/j.cpc.2021.108171", "DOI Link": "http://dx.doi.org/10.1016/j.cpc.2021.108171", "Book DOI": null, "Early Access Date": "OCT 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000720461800009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, W; Wu, BH; Sun, ST; Wu, PY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Wei; Wu, Baohu; Sun, Shengtong; Wu, Peiyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Skin-like mechanoresponsive self-healing ionic elastomer from supramolecular zwitterionic network", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Stretchable ionic skins are intriguing in mimicking the versatile sensations of natural skins. However, for their applications in advanced electronics, good elastic recovery, self-healing, and more importantly, skin-like nonlinear mechanoresponse (strain-stiffening) are essential but can be rarely met in one material. Here we demonstrate a robust proton-conductive ionic skin design via introducing an entropy-driven supramolecular zwitterionic reorganizable network to the hydrogen-bonded polycarboxylic acid network. The design allows two dynamic networks with distinct interacting strength to sequentially debond with stretch, and the conflict among elasticity, self-healing, and strain-stiffening can be thus defeated. The representative polyacrylic acid/betaine elastomer exhibits high stretchability (1600% elongation), immense strain-stiffening (24-fold modulus enhancement), similar to 100% self-healing, excellent elasticity (97.9 +/- 1.1% recovery ratio, <14% hysteresis), high transparency (99.7 +/- 0.1%), moisture-preserving, anti-freezing (elastic at -40 degrees C), water reprocessibility, as well as easy-to-peel adhesion. The combined advantages make the present ionic elastomer very promising in wearable iontronic sensors for human-machine interfacing.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 375, "Times Cited, All Databases": 385, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 2", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4082, "DOI": "10.1038/s41467-021-24382-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24382-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000672163900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, JS; Heo, JM; Park, GS; Woo, SJ; Cho, C; Yun, HJ; Kim, DH; Park, J; Lee, SC; Park, SH; Yoon, E; Greenham, NC; Lee, TW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Joo Sung; Heo, Jung-Min; Park, Gyeong-Su; Woo, Seung-Je; Cho, Changsoon; Yun, Hyung Joong; Kim, Dong-Hyeok; Park, Jinwoo; Lee, Seung-Chul; Park, Sang-Hwan; Yoon, Eojin; Greenham, Neil C.; Lee, Tae-Woo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-bright, efficient and stable perovskite light-emitting diodes", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metal halide perovskites are attracting a lot of attention as next-generation lighte-mitting materials owing to their excellent emission properties, with narrow band emission(1-4). However, perovskite light-emitting diodes (PeLEDs), irrespective of their material type (polycrystals or nullocrystals), have not realized high luminullce, high efficiency and long lifetime simultaneously, as they are influenced by intrinsic limitations related to the trade-off of properties between charge transport and confinement in each type of perovskite material(5-8). Here, we report an ultra-bright, efficient and stable PeLED made of core/shell perovskite nullocrystals with a size of approximately 10 nm, obtained using a simple in situ reaction of benzylphosphonic acid (BPA) additive with three-dimensional (3D) polycrystalline perovskite films, without separate synthesis processes. During the reaction, large 3D crystals are split into nullocrystals and the BPA surroundsthe nullocrystals, achieving strong carrier confinement. The BPA shell passivates the undercoordinated lead atoms by forming covalent bonds, and there by greatly reduces the trap density while maintaining good charge-transport properties for the 3D perovskites. We demonstrate simultaneously efficient, bright and stable PeLEDs that have a maximum brightness of approximately 470,000 cd m(-2), maximum external quantum efficiency of 28.9% (average = 25.2 +/- 1.6% over 40 devices), maximum current efficiency of 151 cd A(-1) and half-lifetime of 520 hat 1,000 cd m(-)(2) (estimated half-lifetime >30,000 h at 100 cd m(-2)). Our work sheds light on the possibility that PeLEDs can be commercialized in the future display industry.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 594, "Times Cited, All Databases": 622, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 24", "Publication Year": 2022, "Volume": 611, "Issue": 7937, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 688, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-022-05304-w", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-05304-w", "Book DOI": null, "Early Access Date": "NOV 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000880580300011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, F; Qin, JS; Wang, ZY; Yu, MZ; Wu, XH; Sun, XM; Qiu, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Fu; Qin, Jingshan; Wang, Zhiyu; Yu, Mengzhou; Wu, Xianhong; Sun, Xiaoming; Qiu, Jieshan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Energy-saving hydrogen production by chlorine-free hybrid seawater splitting coupling hydrazine degradation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Seawater electrolysis represents a potential solution to grid-scale production of carbon-neutral hydrogen energy without reliance on freshwater. However, it is challenged by high energy costs and detrimental chlorine chemistry in complex chemical environments. Here we demonstrate chlorine-free hydrogen production by hybrid seawater splitting coupling hydrazine degradation. It yields hydrogen at a rate of 9.2 mol h(-1) g(cat)(-1) on NiCo/MXene-based electrodes with a low electricity expense of 2.75 kWh per m(3) H-2 at 500 mA cm(-2) and 48% lower energy equivalent input relative to commercial alkaline water electrolysis. Chlorine electrochemistry is avoided by low cell voltages without anode protection regardless Cl- crossover. This electrolyzer meanwhile enables fast hydrazine degradation to similar to 3 ppb residual. Self-powered hybrid seawater electrolysis is realized by integrating low-voltage direct hydrazine fuel cells or solar cells. These findings enable further opportunities for efficient conversion of ocean resources to hydrogen fuel while removing harmful pollutants.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 397, "Times Cited, All Databases": 410, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 7", "Publication Year": 2021, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 4182, "DOI": "10.1038/s41467-021-24529-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-24529-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000687325900025", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, DY; Zhang, DZ; Li, P; Yang, ZM; Mi, QA; Yu, LD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Dongyue; Zhang, Dongzhi; Li, Peng; Yang, Zhimin; Mi, Qian; Yu, Liandong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrospinning of Flexible Poly(vinyl alcohol)/MXene nullofiber-Based Humidity Sensor Self-Powered by Monolayer Molybdenum Diselenide Piezoelectric nullogenerator", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional material has been widely investigated for potential applications in sensor and flexible electronics. In this work, a self-powered flexible humidity sensing device based on poly(vinyl alcohol)/Ti3C2Tx (PVA/MXene) nullofibers film and monolayer molybdenum diselenide (MoSe2) piezoelectric nullogenerator (PENG) was reported for the first time. The monolayer MoSe2-based PENG was fabricated by atmospheric pressure chemical vapor deposition techniques, which can generate a peak output of 35 mV and a power density of 42 mW m(-2). The flexible PENG integrated on polyethylene terephthalate (PET) substrate can harvest energy generated by different parts of human body and exhibit great application prospects in wearable devices. The electrospinned PVA/MXene nullofiber-based humidity sensor with flexible PET substrate under the driven of monolayer MoSe2 PENG, shows high response of similar to 40, fast response/recovery time of 0.9/6.3 s, low hysteresis of 1.8% and excellent repeatability. The self-powered flexible humidity sensor yields the capability of detecting human skin moisture and ambient humidity. This work provides a pathway to explore the high-performance humidity sensor integrated with PENG for the self-powered flexible electronic devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 366, "Times Cited, All Databases": 381, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2021, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 57, "DOI": "10.1007/s40820-020-00580-5", "DOI Link": "http://dx.doi.org/10.1007/s40820-020-00580-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000609817400002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, KC; Dong, KC; Li, JC; Gordon, MP; Reichertz, FG; Kim, H; Rho, Y; Wang, QJ; Lin, CY; Grigoropoulos, CP; Javey, A; Urban, JJ; Yao, J; Levinson, R; Wu, JQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Kechao; Dong, Kaichen; Li, Jiachen; Gordon, Madeleine P.; Reichertz, Finnegan G.; Kim, Hyungjin; Rho, Yoonsoo; Wang, Qingjun; Lin, Chang-Yu; Grigoropoulos, Costas P.; Javey, Ali; Urban, Jeffrey J.; Yao, Jie; Levinson, Ronnen; Wu, Junqiao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Temperature-adaptive radiative coating for all-season household thermal regulation", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The sky is a natural heat sink that has been extensively used for passive radiative cooling of households. A lot of focus has been on maximizing the radiative cooling power of roof coating in the hot daytime using static, cooling-optimized material properties. However, the resultant overcooling in cold night or winter times exacerbates the heating cost, especially in climates where heating dominates energy consumption. We approached thermal regulation from an all-season perspective by developing a mechanically flexible coating that adapts its thermal emittance to different ambient temperatures. The fabricated temperature-adaptive radiative coating (TARC) optimally absorbs the solar energy and automatically switches thermal emittance from 0.20 for ambient temperatures lower than 15 degrees C to 0.90 for temperatures above 30 degrees C, driven by a photonically amplified metal-insulator transition. Simulations show that this system outperforms existing roof coatings for energy saving in most climates, especially those with substantial seasonal variations.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 411, "Times Cited, All Databases": 452, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 17", "Publication Year": 2021, "Volume": 374, "Issue": 6574, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1504, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abf7136", "DOI Link": "http://dx.doi.org/10.1126/science.abf7136", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000733380100054", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YJ; Tao, XY; Wang, Y; Jiang, C; Ma, C; Sheng, OW; Lu, GX; Lou, XW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yujing; Tao, Xinyong; Wang, Yao; Jiang, Chi; Ma, Cong; Sheng, Ouwei; Lu, Gongxun; Lou, Xiong Wen (David)", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Self-assembled monolayers direct a LiF-rich interphase toward long-life lithium metal batteries", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-energy density lithium (Li) metal batteries (LMBs) are promising for energy storage applications but suffer from uncontrollable electrolyte degradation and the consequently formed unstable solid-electrolyte interphase (SEI). In this study, we designed self-assembled monolayers (SAMs) with high-density and long-range-ordered polar carboxyl groups linked to an aluminum oxide-coated separator to provide strong dipole moments, thus offering excess electrons to accelerate the degradation dynamics of carbon-fluorine bond cleavage in Li bis(trifluoromethanesulfonyl)imide. Hence, an SEI with enriched lithium fluoride (LiF) nullocrystals is generated, facilitating rapid Li+ transfer and suppressing dendritic Li growth. In particular, the SAMs endow the full cells with substantially enhanced cyclability under high cathode loading, limited Li excess, and lean electrolyte conditions. As such, our work extends the long-established SAMs technology into a platform to control electrolyte degradation and SEI formation toward LMBs with ultralong life spans.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 569, "Times Cited, All Databases": 589, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 18", "Publication Year": 2022, "Volume": 375, "Issue": 6582, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 739, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abn1818", "DOI Link": "http://dx.doi.org/10.1126/science.abn1818", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000758142600041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yu, Z; Rudnicki, PE; Zhang, ZW; Huang, ZJ; Celik, H; Oyakhire, ST; Chen, YL; Kong, X; Kim, SC; Xiao, X; Wang, HS; Zheng, Y; Kamat, GA; Kim, MS; Bent, SF; Qin, J; Cui, Y; Bao, ZN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yu, Zhiao; Rudnicki, Paul E.; Zhang, Zewen; Huang, Zhuojun; Celik, Hasan; Oyakhire, Solomon T.; Chen, Yuelang; Kong, Xian; Kim, Sang Cheol; Xiao, Xin; Wang, Hansen; Zheng, Yu; Kamat, Gaurav A.; Kim, Mun Sek; Bent, Stacey F.; Qin, Jian; Cui, Yi; Bao, Zhenull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rational solvent molecule tuning for high-performance lithium metal battery electrolytes", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrolyte engineering improved cycling of Li metal batteries and anode-free cells at low current densities; however, high-rate capability and tuning of ionic conduction in electrolytes are desirable yet less-studied. Here, we design and synthesize a family of fluorinated-1,2-diethoxyethanes as electrolyte solvents. The position and amount of F atoms functionalized on 1,2-diethoxyethane were found to greatly affect electrolyte performance. Partially fluorinated, locally polar -CHF2 is identified as the optimal group rather than fully fluorinated -CF3 in common designs. Paired with 1.2 M lithium bis(fluorosulfonyl)imide, these developed single-salt-single-solvent electrolytes simultaneously enable high conductivity, low and stable overpotential, >99.5% Li||Cu half-cell efficiency (up to 99.9%, +/- 0.1% fluctuation) and fast activation (Li efficiency >99.3% within two cycles). Combined with high-voltage stability, these electrolytes achieve roughly 270 cycles in 50-mu m-thin Li||high-loading-NMC811 full batteries and >140 cycles in fast-cycling Cu||microparticle-LiFePO4 industrial pouch cells under realistic testing conditions. The correlation of Li+-solvent coordination, solvation environments and battery performance is investigated to understand structure-property relationships. Cycling capability, especially at high rates, is limited for lithium metal batteries. Here the authors report electrolyte solvent design through fine-tuning of molecular structures to address the cyclability issue and unravel the electrolyte structure-property relationship for battery applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 539, "Times Cited, All Databases": 561, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 7, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 94, "End Page": 106, "Article Number": null, "DOI": "10.1038/s41560-021-00962-y", "DOI Link": "http://dx.doi.org/10.1038/s41560-021-00962-y", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000742253900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, YT; Liang, YP; Chen, JY; Duan, XL; Guo, BL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Yutong; Liang, Yongping; Chen, Jueying; Duan, Xianglong; Guo, Baolin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mussel-inspired adhesive antioxidant antibacterial hemostatic composite hydrogel wound dressing via photo-polymerization for infected skin wound healing", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "With the increasing prevalence of drug-resistant bacterial infections and the slow healing of chronically infected wounds, the development of new antibacterial and accelerated wound healing dressings has become a serious challenge. In order to solve this problem, we developed photo-crosslinked multifunctional antibacterial adhesive anti-oxidant hemostatic hydrogel dressings based on polyethylene glycol monomethyl ether modified glycidyl methacrylate functionalized chitosan (CSG-PEG), methacrylamide dopamine (DMA) and zinc ion for disinfection of drug-resistant bacteria and promoting wound healing. The mechanical properties, rheological properties and morphology of hydrogels were characterized, and the biocompatibility of these hydrogels was studied through cell compatibility and blood compatibility tests. These hydrogels were tested for the in vitro blood-clotting ability of whole blood and showed good hemostatic ability in the mouse liver hemorrhage model and the mouse-tail amputation model. In addition, it has been confirmed that the multifunctional hydrogels have good inherent antibacterial properties against Methicillin-resistant Staphylococcus aureus (MRSA). In the full-thickness skin defect model infected with MRSA, the wound closure ratio, thickness of granulation tissue, number of collagen deposition, regeneration of blood vessels and hair follicles were measured. The inflammation-related cytokines (CD68) and angiogenesis-related cytokines (CD31) expressed during skin regeneration were studied. All results indicate that these multifunctional antibacterial adhesive hemostatic hydrogels have better healing effects than commercially available Tegaderm (TM) Film, revealing that they have become promising alternative in the healing of infected wounds.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 440, "Times Cited, All Databases": 456, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 8, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 341, "End Page": 354, "Article Number": null, "DOI": "10.1016/j.bioactmat.2021.06.014", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2021.06.014", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000751867500024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ming, FW; Zhu, YP; Huang, G; Emwas, AH; Liang, HF; Cui, Y; Alshareef, HN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ming, Fangwang; Zhu, Yunpei; Huang, Gang; Emwas, Abdul-Hamid; Liang, Hanfeng; Cui, Yi; Alshareef, Husam N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Co-Solvent Electrolyte Engineering for Stable Anode-Free Zinc Metal Batteries", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Anode-free metal batteries can in principle offer higher energy density, but this requires them to have extraordinary Coulombic efficiency (>99.7%). Although Zn-based metal batteries are promising for stationary storage, the parasitic side reactions make anode-free batteries difficult to achieve in practice. In this work, a salting-in-effect-induced hybrid electrolyte is proposed as an effective strategy that enables both a highly reversible Zn anode and good stability and compatibility toward various cathodes. The as-prepared electrolyte can also work well under a wide temperature range (i.e., from -20 to 50 degrees C). It is demonstrated that in the presence of propylene carbonate, triflate anions are involved in the Zn2+ solvation sheath structure, even at a low salt concentration (2.14 M). The unique solvation structure results in the reduction of anions, thus forming a hydrophobic solid electrolyte interphase. The waterproof interphase along with the decreased water activity in the hybrid electrolyte effectively prevents side reactions, thus ensuring a stable Zn anode with an unprecedented Coulombic efficiency (99.93% over 500 cycles at 1 mA cm(-2)). More importantly, we design an anode-free Zn metal battery that exhibits excellent cycling stability (80% capacity retention after 275 cycles at 0.5 mA cm(-2)). This work provides a universal strategy to design co-solvent electrolytes for anode-free Zn metal batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 437, "Times Cited, All Databases": 444, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 27", "Publication Year": 2022, "Volume": 144, "Issue": 16, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 7160, "End Page": 7170, "Article Number": null, "DOI": "10.1021/jacs.1c12764", "DOI Link": "http://dx.doi.org/10.1021/jacs.1c12764", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000799141600018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hai, X; Xi, SB; Mitchell, S; Harrath, K; Xu, HM; Akl, DF; Kong, DB; Li, J; Li, ZJ; Sun, T; Yang, HM; Cui, YG; Su, CL; Zhao, XX; Li, J; Pérez-Ramírez, J; Lu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hai, Xiao; Xi, Shibo; Mitchell, Sharon; Harrath, Karim; Xu, Haomin; Akl, Dario Faust; Kong, Debin; Li, Jing; Li, Zejun; Sun, Tao; Yang, Huimin; Cui, Yige; Su, Chenliang; Zhao, Xiaoxu; Li, Jun; Perez-Ramirez, Javier; Lu, Jiong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Scalable two-step annealing method for preparing ultra-high-density single-atom catalyst libraries", "Source Title": "NATURE nullOTECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A general versatile approach combining wet-chemistry impregnation and two-step annealing is devised for the scalable synthesis of a library of ultra-high-density single-atom catalysts with drastically enhanced reactivity. The stabilization of transition metals as isolated centres with high areal density on suitably tailored carriers is crucial for maximizing the industrial potential of single-atom heterogeneous catalysts. However, achieving single-atom dispersions at metal contents above 2 wt% remains challenging. Here we introduce a versatile approach combining impregnation and two-step annealing to synthesize ultra-high-density single-atom catalysts with metal contents up to 23 wt% for 15 metals on chemically distinct carriers. Translation to a standardized, automated protocol demonstrates the robustness of our method and provides a path to explore virtually unlimited libraries of mono- or multimetallic catalysts. At the molecular level, characterization of the synthesis mechanism through experiments and simulations shows that controlling the bonding of metal precursors with the carrier via stepwise ligand removal prevents their thermally induced aggregation into nulloparticles. The drastically enhanced reactivity with increasing metal content exemplifies the need to optimize the surface metal density for a given application. Moreover, the loading-dependent site-specific activity observed in three distinct catalytic systems reflects the well-known complexity in heterogeneous catalyst design, which now can be tackled with a library of single-atom catalysts with widely tunable metal loadings.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 422, "Times Cited, All Databases": 442, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 17, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 174, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41565-021-01022-y", "DOI Link": "http://dx.doi.org/10.1038/s41565-021-01022-y", "Book DOI": null, "Early Access Date": "NOV 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000722472000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, YM; Zhao, JH; Wang, H; Xiao, B; Zhang, W; Zhao, XB; Lv, TP; Thangamuthu, M; Zhang, J; Guo, Y; Ma, JN; Lin, LN; Tang, JW; Huang, R; Liu, QJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yumin; Zhao, Jianhong; Wang, Hui; Xiao, Bin; Zhang, Wen; Zhao, Xinbo; Lv, Tianping; Thangamuthu, Madasamy; Zhang, Jin; Guo, Yan; Ma, Jiani; Lin, Lina; Tang, Junwang; Huang, Rong; Liu, Qingju", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Single-atom Cu anchored catalysts for photocatalytic renewable H2 production with a quantum efficiency of 56%", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single-atom catalysts anchoring offers a desirable pathway for efficiency maximization and cost-saving for photocatalytic hydrogen evolution. However, the single-atoms loading amount is always within 0.5% in most of the reported due to the agglomeration at higher loading concentrations. In this work, the highly dispersed and large loading amount (>1 wt%) of copper single-atoms were achieved on TiO2, exhibiting the H-2 evolution rate of 101.7 mmol g(-1) h(-1) under simulated solar light irradiation, which is higher than other photocatalysts reported, in addition to the excellent stability as proved after storing 380 days. More importantly, it exhibits an apparent quantum efficiency of 56% at 365 nm, a significant breakthrough in this field. The highly dispersed and large amount of Cu single-atoms incorporation on TiO2 enables the efficient electron transfer via Cu2+-Cu+ process. The present approach paves the way to design advanced materials for remarkable photocatalytic activity and durability. In this work, the highly dispersed and large loading amount (>1 wt%) of copper single-atoms were achieved on TiO2, resulting into an apparent quantum efficiency of 56% at 365 nm, in addition to an excellent thermal stability as proved after storing 380 days.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 417, "Times Cited, All Databases": 440, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 58, "DOI": "10.1038/s41467-021-27698-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-27698-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000781259400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, LD; Zuo, TT; Kwok, CY; Kim, SY; Assoud, A; Zhang, Q; Janek, J; Nazar, LF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Laidong; Zuo, Tong-Tong; Kwok, Chun Yuen; Kim, Se Young; Assoud, Abdeljalil; Zhang, Qiang; Janek, Juergen; Nazar, Linda F.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High areal capacity, long cycle life 4 V ceramic all-solid-state Li-ion batteries enabled by chloride solid electrolytes", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "All-solid-state Li batteries (ASSBs) employing inorganic solid electrolytes offer improved safety and are exciting candidates for next-generation energy storage. Herein, we report a family of lithium mixed-metal chlorospinels, Li2InxSc0.666-xCl4 (0 <= x <= 0.666), with high ionic conductivity (up to 2.0 mS cm(-1)) owing to a highly disordered Li-ion distribution, and low electronic conductivity (4.7 x 10(-10) S cm(-1)), which are implemented for high-performance ASSBs. Owing to the excellent interfacial stability of the SE against uncoated high-voltage cathode materials, ASSBs utilizing LiCoO2 or LiNi0.85Co0.1Mn0.05O2 exhibit superior rate capability and long-term cycling (up to 4.8 V versus Li+/Li) compared to state-of-the-art ASSBs. In particular, the ASSB with LiNi0.85Co0.1Mn0.05O2 exhibits a long life of >3,000 cycles with 80% capacity retention at room temperature. High cathode loadings are also demonstrated in ASSBs with stable capacity retention of >4 mAh cm(-2) (similar to 190 mAh g(-1)).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 388, "Times Cited, All Databases": 412, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 7, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 83, "End Page": 93, "Article Number": null, "DOI": "10.1038/s41560-021-00952-0", "DOI Link": "http://dx.doi.org/10.1038/s41560-021-00952-0", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000737783400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jiang, YW; Zhang, ZT; Wang, YX; Li, DL; Coen, CT; Hwaun, E; Chen, G; Wu, HC; Zhong, DL; Niu, SM; Wang, WC; Saberi, A; Lai, JC; Wu, YL; Wang, Y; Trotsyuk, AA; Loh, KY; Shih, CC; Xu, WH; Liang, K; Zhang, KL; Bai, YH; Gurusankar, G; Hu, WP; Jia, W; Cheng, Z; Dauskardt, RH; Gurtner, GC; Tok, JBH; Deisseroth, K; Soltesz, I; Bao, ZN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jiang, Yuanwen; Zhang, Zhitao; Wang, Yi-Xuan; Li, Deling; Coen, Charles-Theophile; Hwaun, Ernie; Chen, Gan; Wu, Hung-Chin; Zhong, Donglai; Niu, Simiao; Wang, Weichen; Saberi, Aref; Lai, Jian-Cheng; Wu, Yilei; Wang, Yang; Trotsyuk, Artem A.; Loh, Kang Yong; Shih, Chien-Chung; Xu, Wenhui; Liang, Kui; Zhang, Kailiang; Bai, Yihong; Gurusankar, Gurupranav; Hu, Wenping; Jia, Wang; Cheng, Zhen; Dauskardt, Reinhold H.; Gurtner, Geoffrey C.; Tok, Jeffrey B-H; Deisseroth, Karl; Soltesz, Ivan; Bao, Zhenull", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Topological supramolecular network enabled high-conductivity, stretchable organic bioelectronics", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Intrinsically stretchable bioelectronic devices based on soft and conducting organic materials have been regarded as the ideal interface for seamless and biocompatible integration with the human body. A remaining challenge is to combine high mechanical robustness with good electrical conduction, especially when patterned at small feature sizes. We develop a molecular engineering strategy based on a topological supramolecular network, which allows for the decoupling of competing effects from multiple molecular building blocks to meet complex requirements. We obtained simultaneously high conductivity and crack-onset strain in a physiological environment, with direct photopatternability down to the cellular scale. We further collected stable electromyography signals on soft and malleable octopus and performed localized neuromodulation down to single-nucleus precision for controlling organ-specific activities through the delicate brainstem.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 383, "Times Cited, All Databases": 397, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 25", "Publication Year": 2022, "Volume": 375, "Issue": 6587, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 1411, "End Page": "+", "Article Number": null, "DOI": "10.1126/science.abj7564", "DOI Link": "http://dx.doi.org/10.1126/science.abj7564", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000778894800044", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mehmood, A; Gong, MJ; Jaouen, F; Roy, A; Zitolo, A; Khan, A; Sougrati, MT; Primbs, M; Bonastres, AM; Fongalland, D; Drazic, G; Strasser, P; Kucernak, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mehmood, Asad; Gong, Mengjun; Jaouen, Frederic; Roy, Aaron; Zitolo, Andrea; Khan, Anastassiya; Sougrati, Moulay-Tahar; Primbs, Mathias; Bonastres, Alex Martinez; Fongalland, Dash; Drazic, Goran; Strasser, Peter; Kucernak, Anthony", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High loading of single atomic iron sites in Fe-NC oxygen reduction catalysts for proton exchange membrane fuel cells", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Non-precious iron-based catalysts (Fe-NCs) require high active site density to meet the performance targets as cathode catalysts in proton exchange membrane fuel cells. Site density is generally limited to that achieved at a 1-3 wt%(Fe) loading due to the undesired formation of iron-containing nulloparticles at higher loadings. Here we show that by preforming a carbon-nitrogen matrix using a sacrificial metal (Zn) in the initial synthesis step and then exchanging iron into this preformed matrix we achieve 7 wt% iron coordinated solely as single-atom Fe-N-4 sites, as identified by Fe-57 cryogenic Mossbauer spectroscopy and X-ray absorption spectroscopy. Site density values measured by in situ nitrite stripping and ex situ CO chemisorption methods are 4.7 x 10(19) and 7.8 x 10(19) sites g(-1), with a turnover frequency of 5.4 electrons sites(-1) s(-1) at 0.80 V in a 0.5 M H2SO4 electrolyte. The catalyst delivers an excellent proton exchange membrane fuel cell performance with current densities of 41.3 mA cm(-2) at 0.90 ViR-free using H-2-O-2 and 145 mA cm(-2) at 0.80 V (199 mA cm(-2) at 0.80 ViR-free) using H-2-air.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 377, "Times Cited, All Databases": 386, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR", "Publication Year": 2022, "Volume": 5, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 311, "End Page": 323, "Article Number": null, "DOI": "10.1038/s41929-022-00772-9", "DOI Link": "http://dx.doi.org/10.1038/s41929-022-00772-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000787831800012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fang, JY; Zheng, QZ; Lou, YY; Zhao, KM; Hu, SN; Li, G; Akdim, O; Huang, XY; Sun, SG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fang, Jia-Yi; Zheng, Qi-Zheng; Lou, Yao-Yin; Zhao, Kuang-Min; Hu, Sheng-null; Li, Guang; Akdim, Ouardia; Huang, Xiao-Yang; Sun, Shi-Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ampere-level current density ammonia electrochemical synthesis using CuCo nullosheets simulating nitrite reductase bifunctional nature", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of electrocatalysts capable of efficient reduction of nitrate (NO3-) to ammonia (NH3) is drawing increasing interest for the sake of low carbon emission and environmental protection. Herein, we present a CuCo bimetallic catalyst able to imitate the bifunctional nature of copper-type nitrite reductase, which could easily remove NO2- via the collaboration of two active centers. Indeed, Co acts as an electron/proton donating center, while Cu facilitates NOx- adsorption/association. The bio-inspired CuCo nullosheet electrocatalyst delivers a 1001% Faradaic efficiency at an ampere-level current density of 1035mAcm(-2) at -0.2V vs. Reversible Hydrogen Electrode. The NH3 production rate reaches a high activity of 4.8mmolcm(-2) h(-1) (960mmol g(cat)(-1) h(-1)). A mechanistic study, using electrochemical in situ Fourier transform infrared spectroscopy and shell-isolated nulloparticle enhanced Raman spectroscopy, reveals a strong synergy between Cu and Co, with Co sites promoting the hydrogenation of NO3- to NH3 via adsorbed *H species. The well-modulated coverage of adsorbed *H and *NO3 led simultaneously to high NH3 selectivity and yield.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 387, "Times Cited, All Databases": 389, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 22", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7899, "DOI": "10.1038/s41467-022-35533-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-35533-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000972743600016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, JD; Chen, CH; Qin, MK; Li, B; Lin, BB; Mao, Q; Yang, HB; Liu, B; Wang, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Jiadong; Chen, Chunhong; Qin, Minkai; Li, Ben; Lin, Binbin; Mao, Qing; Yang, Hongbin; Liu, Bin; Wang, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reversible hydrogen spillover in Ru-WO3-x enhances hydrogen evolution activity in neutral pH water splitting", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Noble metal electrocatalysts (e.g., Pt, Ru, etc.) suffer from sluggish kinetics of water dissociation for the electrochemical reduction of water to molecular hydrogen in alkaline and neutral pH environments. Herein, we found that an integration of Ru nulloparticles (NPs) on oxygen-deficient WO3-x manifested a 24.0-fold increase in hydrogen evolution reaction (HER) activity compared with commercial Ru/C electrocatalyst in neutral electrolyte. Oxygen-deficient WO3-x is shown to possess large capacity for storing protons, which could be transferred to the Ru NPs under cathodic potential. This significantly increases the hydrogen coverage on the surface of Ru NPs in HER and thus changes the rate-determining step of HER on Ru from water dissociation to hydrogen recombination.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 349, "Times Cited, All Databases": 360, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 14", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5382, "DOI": "10.1038/s41467-022-33007-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-33007-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000853935100017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shi, XW; Dai, C; Wang, X; Hu, JY; Zhang, JY; Zheng, LX; Mao, L; Zheng, HJ; Zhu, MS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shi, Xiaowei; Dai, Chao; Wang, Xin; Hu, Jiayue; Zhang, Junying; Zheng, Lingxia; Mao, Liang; Zheng, Huajun; Zhu, Mingshan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Protruding Pt single-sites on hexagonal ZnIn2S4 to accelerate photocatalytic hydrogen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An alternative approach to defect-trapped Pt single-sites on a semiconductor is reported. Here, protruding Pt sites inhibit charge recombination and cause a tip effect which enhances H-2 evolution yield rates with minimal co-catalyst loading. Single-site cocatalysts engineered on supports offer a cost-efficient pathway to utilize precious metals, yet improving the performance further with minimal catalyst loading is still highly desirable. Here we have conducted a photochemical reaction to stabilize ultralow Pt co-catalysts (0.26 wt%) onto the basal plane of hexagonal ZnIn2S4 nullosheets (Pt-SS-ZIS) to form a Pt-S-3 protrusion tetrahedron coordination structure. Compared with the traditional defect-trapped Pt single-site counterparts, the protruding Pt single-sites on h-ZIS photocatalyst enhance the H-2 evolution yield rate by a factor of 2.2, which could reach 17.5 mmol g(-1) h(-1) under visible light irradiation. Importantly, through simple drop-casting, a thin Pt-SS-ZIS film is prepared, and large amount of observable H-2 bubbles are generated, providing great potential for practical solar-light-driven H-2 production. The protruding single Pt atoms in Pt-SS-ZIS could inhibit the recombination of electron-hole pairs and cause a tip effect to optimize the adsorption/desorption behavior of H through effective proton mass transfer, which synergistically promote reaction thermodynamics and kinetics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 356, "Times Cited, All Databases": 363, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 11", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1287, "DOI": "10.1038/s41467-022-28995-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28995-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000767892300022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, SJ; Cai, MJ; Liu, YP; Wang, CC; Lv, KL; Chen, XB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Shijie; Cai, Mingjie; Liu, Yanping; Wang, Chunchun; Lv, Kangle; Chen, Xiaobo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "S-Scheme photocatalyst TaON/Bi2WO6 nullofibers with oxygen vacancies for efficient abatement of antibiotics and Cr(VI): Intermediate eco-toxicity analysis and mechanistic insights", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Enlightened by natural photosynthesis, developing efficient S-scheme heterojunction photocatalysts for deleterious pollutant removal is of prime importance to restore environment. Herein, novel TaON/Bi2WO6 S-scheme heterojunction nullofibers were designed and developed by in-situ growing Bi2WO6 nullosheets with oxygen vacancies (OVs) on TaON nullofibers. Thanks to the efficiently spatial charge disassociation and preserved great redox power by the unique S-scheme mechanism and OVs, as well as firmly interfacial contact by the core-shell 1D/2D fibrous hetero-structure via the in-situ growth, the optimized TaON/Bi2WO6 heterojunction unveils exceptional visible-light photocatalytic property for abatement of tetracycline (TC), levofloxacin (LEV), and Cr(VI), respectively by 2.8-fold, 1.0-fold, and 1.9-fold enhancement compared to the bare Bi2WO6, while maintaining satisfactory stability. Furthermore, the systematic photoreaction tests indicate TaON/Bi2WO6 has the high practicality in the elimination of pollutants in aquatic environment. The degradation pathway of tetracycline and intermediate eco-toxicity were determined based on HPLC-MS combined with QSAR calculation, and a possible photocatalytic mechanism was elucidated. This work provides a guideline for designing high-performance TaON-based S-scheme photocatalysts with defects for environment protection. (C) 2022, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 360, "Times Cited, All Databases": 378, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2022, "Volume": 43, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 2652, "End Page": 2664, "Article Number": null, "DOI": "10.1016/S1872-2067(22)64106-8", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(22)64106-8", "Book DOI": null, "Early Access Date": "OCT 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000884673500004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, HM; Lang, XY; Zhu, C; Timoshenko, J; Rüscher, M; Bai, LC; Guijarro, N; Yin, HB; Peng, Y; Li, JH; Liu, Z; Wang, WC; Roldan Cuenya, B; Luo, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Huimin; Lang, Xiuyao; Zhu, Chao; Timoshenko, Janis; Ruescher, Martina; Bai, Lichen; Guijarro, Nestor; Yin, Haibo; Peng, Yue; Li, Junhua; Liu, Zheng; Wang, Weichao; Roldan Cuenya, Beatriz; Luo, Jingshan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient Electrochemical Nitrate Reduction to Ammonia with Copper-Supported Rhodium Cluster and Single-Atom Catalysts", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electrochemical nitrate reduction reaction (NITRR) provides a promising solution for restoring the imbalance in the global nitrogen cycle while enabling a sustainable and decentralized route to source ammonia. Here, we demonstrate a novel electrocatalyst for NITRR consisting of Rh clusters and single-atoms dispersed onto Cu nullowires (NWs), which delivers a partial current density of 162 mA cm(-2) for NH3 production and a Faradaic efficiency (FE) of 93 % at -0.2 V vs. RHE. The highest ammonia yield rate reached a record value of 1.27 mmol h(-1) cm(-2). Detailed investigations by electron paramagnetic resonullce, in situ infrared spectroscopy, differential electrochemical mass spectrometry and density functional theory modeling suggest that the high activity originates from the synergistic catalytic cooperation between Rh and Cu sites, whereby adsorbed hydrogen on Rh site transfers to vicinal *NO intermediate species adsorbed on Cu promoting the hydrogenation and ammonia formation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 369, "Times Cited, All Databases": 377, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 7", "Publication Year": 2022, "Volume": 61, "Issue": 23, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e202202556", "DOI": "10.1002/anie.202202556", "DOI Link": "http://dx.doi.org/10.1002/anie.202202556", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000780914100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hao, JC; Zhuang, ZC; Cao, KC; Gao, GH; Wang, C; Lai, FL; Lu, SL; Ma, PM; Dong, WF; Liu, TX; Du, ML; Zhu, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hao, Jiace; Zhuang, Zechao; Cao, Kecheng; Gao, Guohua; Wang, Chan; Lai, Feili; Lu, Shuanglong; Ma, Piming; Dong, Weifu; Liu, Tianxi; Du, Mingliang; Zhu, Han", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unraveling the electronegativity-dominated intermediate adsorption on high-entropy alloy electrocatalysts", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy alloy catalysts are an emerging class of materials and identification of catalytically active sites is critical. Here, we provide evidence that metal site electronegativity differences stabilize bound *OH and *H intermediates. High-entropy alloys have received considerable attention in the field of catalysis due to their exceptional properties. However, few studies hitherto focus on the origin of their outstanding performance and the accurate identification of active centers. Herein, we report a conceptual and experimental approach to overcome the limitations of single-element catalysts by designing a FeCoNiXRu (X: Cu, Cr, and Mn) High-entropy alloys system with various active sites that have different adsorption capacities for multiple intermediates. The electronegativity differences between mixed elements in HEA induce significant charge redistribution and create highly active Co and Ru sites with optimized energy barriers for simultaneously stabilizing OH* and H* intermediates, which greatly enhances the efficiency of water dissociation in alkaline conditions. This work provides an in-depth understanding of the interactions between specific active sites and intermediates, which opens up a fascinating direction for breaking scaling relation issues for multistep reactions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 410, "Times Cited, All Databases": 413, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 13", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2662, "DOI": "10.1038/s41467-022-30379-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-30379-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000795204200020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "He, ZY; Zhang, J; Gong, ZH; Lei, H; Zhou, D; Zhang, NA; Mai, WJ; Zhao, SJ; Chen, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "He, Zuyun; Zhang, Jun; Gong, Zhiheng; Lei, Hang; Zhou, Deng; Zhang, Nian; Mai, Wenjie; Zhao, Shijun; Chen, Yan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Activating lattice oxygen in NiFe-based (oxy)hydroxide for water electrolysis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Transition metal oxides or (oxy)hydroxides have been intensively investigated as promising electrocatalysts for energy and environmental applications. Oxygen in the lattice was reported recently to actively participate in surface reactions. Herein, we report a sacrificial template-directed approach to synthesize Mo-doped NiFe (oxy)hydroxide with modulated oxygen activity as an enhanced electrocatalyst towards oxygen evolution reaction (OER). The obtained MoNiFe (oxy)hydroxide displays a high mass activity of 1910 A/g(metal) at the overpotential of 300 mV. The combination of density functional theory calculations and advanced spectroscopy techniques suggests that the Mo dopant upshifts the O 2p band and weakens the metal-oxygen bond of NiFe (oxy)hydroxide, facilitating oxygen vacancy formation and shifting the reaction pathway for OER. Our results provide critical insights into the role of lattice oxygen in determining the activity of (oxy)hydroxides and demonstrate tuning oxygen activity as a promising approach for constructing highly active electrocatalysts. While (oxy)hydroxides are effective oxygen evolution electrocatalysts, the impacts of pre-catalyst properties on catalyst activities are challenging to assess. Here, authors find Mo dopants in Ni-Fe (oxyhydroxides) to promote lattice oxygen participation and to boost oxygen evolution activities.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 366, "Times Cited, All Databases": 370, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 21", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2191, "DOI": "10.1038/s41467-022-29875-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29875-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000785003900005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wright, LG; Onodera, T; Stein, MM; Wang, TY; Schachter, DT; Hu, Z; McMahon, PL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wright, Logan G.; Onodera, Tatsuhiro; Stein, Martin M.; Wang, Tianyu; Schachter, Darren T.; Hu, Zoey; McMahon, Peter L.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Deep physical neural networks trained with backpropagation", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Deep-learning models have become pervasive tools in science and engineering. However, their energy requirements now increasingly limit their scalability(1). Deep-learning accelerators(2-9) aim to perform deep learning energy-efficiently, usually targeting the inference phase and often by exploiting physical substrates beyond conventional electronics. Approaches so far(10-22) have been unable to apply the backpropagation algorithm to train unconventional novel hardware in situ. The advantages of backpropagation have made it the de facto training method for large-scale neural networks, so this deficiency constitutes a major impediment. Here we introduce a hybrid in situ-in silico algorithm, called physics-aware training, that applies backpropagation to train controllable physical systems. Just as deep learning realizes computations with deep neural networks made from layers of mathematical functions, our approach allows us to train deep physical neural networks made from layers of controllable physical systems, even when the physical layers lack any mathematical isomorphism to conventional artificial neural network layers. To demonstrate the universality of our approach, we train diverse physical neural networks based on optics, mechanics and electronics to experimentally perform audio and image classification tasks. Physics-aware training combines the scalability of backpropagation with the automatic mitigation of imperfections and noise achievable with in situ algorithms. Physical neural networks have the potential to perform machine learning faster and more energy-efficiently than conventional electronic processors and, more broadly, can endow physical systems with automatically designed physical functionalities, for example, for robotics(23-26), materials(27-29) and smart sensors(30-32).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 355, "Times Cited, All Databases": 386, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 27", "Publication Year": 2022, "Volume": 601, "Issue": 7894, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 549, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-04223-6", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-04223-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000749546400022", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, JC; Dong, PF; Dang, K; Zhang, YN; Yan, QL; Xiang, H; Su, J; Liu, ZH; Si, MW; Gao, JC; Kong, MF; Zhou, H; Hao, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Jincheng; Dong, Pengfei; Dang, Kui; Zhang, Yanni; Yan, Qinglong; Xiang, Hu; Su, Jie; Liu, Zhihong; Si, Mengwei; Gao, Jiacheng; Kong, Moufu; Zhou, Hong; Hao, Yue", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-wide bandgap semiconductor Ga2O3 power diodes", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ultra-wide bandgap semiconductor Ga2O3 based electronic devices are expected to perform beyond wide bandgap counterparts GaN and SiC. However, the reported power figure-of-merit hardly can exceed, which is far below the projected Ga2O3 material limit. Major obstacles are high breakdown voltage requires low doping material and PN junction termination, contradicting with low specific on-resistance and simultaneous achieving of n- and p-type doping, respectively. In this work, we demonstrate that Ga2O3 heterojunction PN diodes can overcome above challenges. By implementing the holes injection in the Ga2O3, bipolar transport can induce conductivity modulation and low resistance in a low doping Ga2O3 material. Therefore, breakdown voltage of 8.32 kV, specific on-resistance of 5.24 m Omega.cm(2), power figure-of-merit of 13.2 GW/cm(2), and turn-on voltage of 1.8 V are achieved. The power figure-of-merit value surpasses the 1-D unipolar limit of GaN and SiC. Those Ga2O3 power diodes demonstrate their great potential for next-generation power electronics applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 372, "Times Cited, All Databases": 381, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 6", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3900, "DOI": "10.1038/s41467-022-31664-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-31664-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000821634700017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, JG; Wang, YX; Huang, Y; Gopaluni, RB; Cao, YK; Heere, M; Mühlbauer, MJ; Mereacre, L; Dai, HF; Liu, XH; Senyshyn, A; Wei, XZ; Knapp, M; Ehrenberg, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Jiangong; Wang, Yixiu; Huang, Yuan; Gopaluni, R. Bhushan; Cao, Yankai; Heere, Michael; Muhlbauer, Martin J.; Mereacre, Liuda; Dai, Haifeng; Liu, Xinhua; Senyshyn, Anatoliy; Wei, Xuezhe; Knapp, Michael; Ehrenberg, Helmut", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Data-driven capacity estimation of commercial lithium-ion batteries from voltage relaxation", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Accurate capacity estimation is crucial for lithium-ion batteries' reliable and safe operation. Here, the authors propose an approach exploiting features from the relaxation voltage curve for battery capacity estimation without requiring other previous cycling information. Accurate capacity estimation is crucial for the reliable and safe operation of lithium-ion batteries. In particular, exploiting the relaxation voltage curve features could enable battery capacity estimation without additional cycling information. Here, we report the study of three datasets comprising 130 commercial lithium-ion cells cycled under various conditions to evaluate the capacity estimation approach. One dataset is collected for model building from batteries with LiNi0.86Co0.11Al0.03O2-based positive electrodes. The other two datasets, used for validation, are obtained from batteries with LiNi0.83Co0.11Mn0.07O2-based positive electrodes and batteries with the blend of Li(NiCoMn)O-2 - Li(NiCoAl)O-2 positive electrodes. Base models that use machine learning methods are employed to estimate the battery capacity using features derived from the relaxation voltage profiles. The best model achieves a root-mean-square error of 1.1% for the dataset used for the model building. A transfer learning model is then developed by adding a featured linear transformation to the base model. This extended model achieves a root-mean-square error of less than 1.7% on the datasets used for the model validation, indicating the successful applicability of the capacity estimation approach utilizing cell voltage relaxation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 342, "Times Cited, All Databases": 360, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 27", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2261, "DOI": "10.1038/s41467-022-29837-w", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29837-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000788592600010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, F; Tian, H; Shen, Y; Hou, Z; Ren, J; Gou, GY; Sun, YB; Yang, Y; Ren, TL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Fan; Tian, He; Shen, Yang; Hou, Zhan; Ren, Jie; Gou, Guangyang; Sun, Yabin; Yang, Yi; Ren, Tian-Ling", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Vertical MoS2 transistors with sub-1-nm gate lengths", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ultra-scaled transistors are of interest in the development of next-generation electronic devices(1-3). Although atomically thin molybdenum disulfide (MoS2) transistors have been reported(4), the fabrication of devices with gate lengths below 1 nm has been challenging(5). Here we demonstrate side-wall MoS2 transistors with an atomically thin channel and a physical gate length of sub-1 nm using the edge of a graphene layer as the gate electrode. The approach uses large-area graphene and MoS2 films grown by chemical vapour deposition for the fabrication of side-wall transistors on a 2-inch wafer. These devices have On/Off ratios up to 1.02 x 10(5) and subthreshold swing values down to 117 mV dec(-1). Simulation results indicate that the MoS2 side-wall effective channel length approaches 0.34 nm in the On state and 4.54 nm in the Off state. This work can promote Moore's law of the scaling down of transistors for next-generation electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 332, "Times Cited, All Databases": 358, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 10", "Publication Year": 2022, "Volume": 603, "Issue": 7900, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 259, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-04323-3", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-04323-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000918198200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Smejkal, L; Sinova, J; Jungwirth, T", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Smejkal, Libor; Sinova, Jairo; Jungwirth, Tomas", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Beyond Conventional Ferromagnetism and Antiferromagnetism: A Phase with Nonrelativistic Spin and Crystal Rotation Symmetry", "Source Title": "PHYSICAL REVIEW X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Recent series of theoretical and experimental reports have driven attention to time-reversal symmetry -breaking spintronic and spin-splitting phenomena in materials with collinear-compensated magnetic order incompatible with conventional ferromagnetism or antiferromagnetism. Here we employ an approach based on nonrelativistic spin-symmetry groups that resolves the conflicting notions of unconventional ferromagnetism or antiferromagnetism by delimiting a third basic collinear magnetic phase. We derive that all materials hosting this collinear-compensated magnetic phase are characterized by crystal-rotation symmetries connecting opposite-spin sublattices separated in the real space and opposite-spin electronic states separated in the momentum space. We describe prominent extraordinary characteristics of the phase, including the alternating spin-splitting sign and broken time-reversal symmetry in the nonrelativistic band structure, the planar or bulk d-, g-, or i-wave symmetry of the spin-dependent Fermi surfaces, spin -degenerate nodal lines and surfaces, band anisotropy of individual spin channels, and spin-split general, as well as time-reversal invariant momenta. Guided by the spin-symmetry principles, we discover in ab initio calculations outlier materials with an extraordinary nonrelativistic spin splitting, whose eV-scale and momentum dependence are determined by the crystal potential of the nonmagnetic phase. This spin -splitting mechanism is distinct from conventional relativistic spin-orbit coupling and ferromagnetic exchange, as well as from the previously considered anisotropic exchange mechanism in compensated magnets. Our results, combined with our identification of material candidates for the phase ranging from insulators and metals to a parent crystal of cuprate superconductors, underpin research of novel quantum phenomena and spintronic functionalities in high-temperature magnets with light elements, vanishing net magnetization, and strong spin coherence. In the discussion, we argue that the conflicting notions of unconventional ferromagnetism or antiferromagnetism, on the one hand, and our symmetry-based delimitation of the third phase, on the other hand, favor a distinct term referring to the phase. The alternating spin polarizations in both the real-space crystal structure and the momentum-space band structure characteristic of this unconventional magnetic phase suggest a term altermagnetism. We point out that d-wave altermagnetism represents a realization of the long-sought-after counterpart in magnetism of the unconventional d-wave superconductivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 349, "Times Cited, All Databases": 356, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 23", "Publication Year": 2022, "Volume": 12, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 31042, "DOI": "10.1103/PhysRevX.12.031042", "DOI Link": "http://dx.doi.org/10.1103/PhysRevX.12.031042", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000865310200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, HB; Yu, RF; Ma, SC; Xu, KZ; Chen, Y; Jiang, K; Fang, Y; Zhu, CX; Liu, XC; Tang, Y; Wu, LZ; Wu, YQ; Jiang, QK; He, P; Liu, ZP; Tan, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Huibo; Yu, Ruofan; Ma, Sicong; Xu, Kaizhuang; Chen, Yang; Jiang, Kun; Fang, Yuan; Zhu, Caixia; Liu, Xiaochen; Tang, Yu; Wu, Lizhi; Wu, Yingquan; Jiang, Qike; He, Peng; Liu, Zhipan; Tan, Li", "Book Author Full Names": null, "Group Authors": null, "Article Title": "The role of Cu1-O3 species in single-atom Cu/ZrO2 catalyst for CO2 hydrogenation", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Copper-based catalysts for the hydrogenation of CO2 to methanol have attracted much interest. The complex nature of these catalysts, however, renders the elucidation of their structure-activity properties difficult. Here we report a copper-based catalyst with isolated active copper sites for the hydrogenation of CO2 to methanol. It is revealed that the single-atom Cu-Zr catalyst with Cu-1-O-3 units contributes solely to methanol synthesis around 180 degrees C, while the presence of small copper clusters or nulloparticles with Cu-Cu structural patterns are responsible for forming the CO by-product. Furthermore, the gradual migration of Cu-1-O-3 units with a quasiplanar structure to the catalyst surface is observed during the catalytic process and accelerates CO2 hydrogenation. The highly active, isolated copper sites and the distinguishable structural pattern identified here extend the horizon of single-atom catalysts for applications in thermal catalytic CO2 hydrogenation and could guide the further design of high-performance copper-based catalysts to meet industrial demand.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 342, "Times Cited, All Databases": 351, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2022, "Volume": 5, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 818, "End Page": 831, "Article Number": null, "DOI": "10.1038/s41929-022-00840-0", "DOI Link": "http://dx.doi.org/10.1038/s41929-022-00840-0", "Book DOI": null, "Early Access Date": "SEP 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000854746500003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, RR; Wang, HF; Du, HR; Yang, Y; Gao, ZH; Qie, L; Huang, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Ruirui; Wang, Haifeng; Du, Haoran; Yang, Ying; Gao, Zhonghui; Qie, Long; Huang, Yunhui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lanthanum nitrate as aqueous electrolyte additive for favourable zinc metal electrodeposition", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous zinc batteries are appealing devices for cost-effective and environmentally sustainable energy storage. However, the zinc metal deposition at the anode strongly influences the battery cycle life and performance. To circumvent this issue, here we propose the use of lanthanum nitrate (La(NO3)(3)) as supporting salt for aqueous zinc sulfate (ZnSO4) electrolyte solutions. Via physicochemical and electrochemical characterizations, we demonstrate that this peculiar electrolyte formulation weakens the electric double layer repulsive force, thus, favouring dense metallic zinc deposits and regulating the charge distribution at the zinc metal|electrolyte interface. When tested in Zn||VS2 full coin cell configuration (with cathode mass loading of 16 mg cm(-2)), the electrolyte solution containing the lanthanum ions enables almost 1000 cycles at 1 A g(-1) (after 5 activation cycles at 0.05 A g(-1)) with a stable discharge capacity of about 90 mAh g(-1) and an average cell discharge voltage of similar to 0.54 V. Zinc metal is a promising anode material for aqueous secondary batteries. However, the unfavourable morphologies formed on the electrode surface during cycling limit its application. Here, the authors report the tailoring of the surface morphology using a lanthanum nitrate aqueous electrolyte additive.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 339, "Times Cited, All Databases": 346, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 6", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3252, "DOI": "10.1038/s41467-022-30939-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-30939-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000808000200007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, Y; Ruan, PC; Mao, CW; Chang, YX; Wang, L; Dai, L; Zhou, P; Lu, BA; Zhou, J; He, ZX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Yang; Ruan, Pengchao; Mao, Caiwang; Chang, Yuxin; Wang, Ling; Dai, Lei; Zhou, Peng; Lu, Bingan; Zhou, Jiang; He, Zhangxing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metal-Organic Frameworks Functionalized Separators for Robust Aqueous Zinc-Ion Batteries", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous zinc-ion batteries (AZIBs) are one of the promising energy storage systems, which consist of electrode materials, electrolyte, and separator. The first two have been significantly received ample development, while the prominent role of the separators in manipulating the stability of the electrode has not attracted sufficient attention. In this work, a separator (UiO-66-GF) modified by Zr-based metal organic framework for robust AZIBs is proposed. UiO-66-GF effectively enhances the transport ability of charge carriers and demonstrates preferential orientation of (002) crystal plane, which is favorable for corrosion resistance and dendrite-free zinc deposition. Consequently, ZnlUiO-66-GF-2.21Zn cells exhibit highly reversible plating/stripping behavior with long cycle life over 1650 h at 2.0 mA cm(-2) , and Zn1UiO-66-GF-2.21MnO(2) cells show excellent long-term stability with capacity retention of 85% after 1000 cycles. The reasonable design and application of multifunctional metal organic frameworks modified separators provide useful guidance for constructing durable AZIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 339, "Times Cited, All Databases": 352, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 218, "DOI": "10.1007/s40820-022-00960-z", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00960-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000885744900003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bai, JX; Shen, RC; Jiang, ZM; Zhang, P; Li, YJ; Li, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bai, Junxian; Shen, Rongchen; Jiang, Zhimin; Zhang, Peng; Li, Youji; Li, Xin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Integration of 2D layered CdS/WO3 S-scheme heterojunctions and metallic Ti3C2 MXene-based Ohmic junctions for effective photocatalytic H2 generation", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article; Proceedings Paper", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The rapid recombination of photo-generated electron-hole pairs, insufficient active sites, and strong photocorrosion have considerably restricted the practical application of CdS in photocatalytic fields. Herein, we designed and constructed a 2D/2D/2D layered heterojunction photocatalyst with cascaded 2D coupling interfaces. Experiments using electron spin resonullce spectroscopy, ultraviolet photoelectron spectroscopy, and in-situ irradiation X-ray photoelectron spectroscopy were conducted to confirm the 2D layered CdS/WO3 step-scheme (S-scheme) heterojunctions and CdS/MX ohmic junctions. Impressively, it was found that the strong interfacial electric fields in the S-scheme heterojunction photocatalysts could effectively promote spatially directional charge separation and transport between CdS and WO3 nullosheets. In addition, 2D Ti3C2 MXene nullosheets with a smaller work function and excellent metal conductivity when used as a co-catalyst could build ohmic junctions with CdS nullosheets, thus providing a greater number of electron transfer pathways and hydrogen evolution sites. Results showed that the highest visible-light hydrogen evolution rate of the optimized MX-CdS/WO3 layered multi-heterostructures could reach as high as 27.5 mmol/g/h, which was 11.0 times higher than that of pure CdS nullosheets. Notably, the apparent quantum efficiency reached 12.0% at 450 nm. It is hoped that this study offers a reliable approach for developing multifunctional photocatalysts by integrating S-scheme and ohmic-junction built-in electric fields and rationally designing a 2D/2D interface for efficient light-to-hydrogen fuel production. (C) 2022, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 324, "Times Cited, All Databases": 339, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2022, "Volume": 43, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 359, "End Page": 369, "Article Number": null, "DOI": "10.1016/S1872-2067(21)63883-4", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(21)63883-4", "Book DOI": null, "Early Access Date": "JAN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000746696100016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Landi, S Jr; Segundo, IR; Freitas, E; Vasilevskiy, M; Carneiro, J; Tavares, CJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Landi, Salmon, Jr.; Segundo, Iran Rocha; Freitas, Elisabete; Vasilevskiy, Mikhail; Carneiro, Joaquim; Tavares, Carlos Jose", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Use and misuse of the Kubelka-Munk function to obtain the band gap energy from diffuse reflectance measurements", "Source Title": "SOLID STATE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The determination of the optical band gap energy (E-g) is important for optimization of the generation of electron/hole pairs in semiconductor materials under illumination. For this purpose, the classical theory proposed by Kubelka and Munk (K-M) has been largely employed for the study of amorphous and polycrystalline materials. In this paper, the authors demonstrate, step by step, how to use the K-M function and apply it thoroughly to the determination of the E-g of TiO2 semiconductor powder (pressed at different thicknesses) from diffuse reflectance spectroscopy (DRS) measurements. For the sample thicknesses 1-4 mm, E-g values of 3.12-3.14 eV were obtained. With this work it is envisaged a clarification to the procedure of determination of the E-g from the K-M theory and DRS data, since some drawbacks, and misconceptions have been identified in the recent literature. In particular, the widely used practice of determining the E-g of a material directly from the K-M function is found to be inadequate.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 328, "Times Cited, All Databases": 332, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2022, "Volume": 341, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 114573, "DOI": "10.1016/j.ssc.2021.114573", "DOI Link": "http://dx.doi.org/10.1016/j.ssc.2021.114573", "Book DOI": null, "Early Access Date": "OCT 2021", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000725057500009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sidhik, S; Wang, YF; De Siena, M; Asadpour, R; Torma, AJ; Terlier, T; Ho, K; Li, WB; Puthirath, AB; Shuai, XT; Agrawal, A; Traore, B; Jones, M; Giridharagopal, R; Ajayan, PM; Strzalka, J; Ginger, DS; Katan, C; Alam, MA; Even, J; Kanatzidis, MG; Mohite, AD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sidhik, Siraj; Wang, Yafei; De Siena, Michael; Asadpour, Reza; Torma, Andrew J.; Terlier, Tanguy; Ho, Kevin; Li, Wenbin; Puthirath, Anulld B.; Shuai, Xinting; Agrawal, Ayush; Traore, Boubacar; Jones, Matthew; Giridharagopal, Rajiv; Ajayan, Pulickel M.; Strzalka, Joseph; Ginger, David S.; Katan, Claudine; Alam, Muhammad Ashraful; Even, Jacky; Kanatzidis, Mercouri G.; Mohite, Aditya D.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Deterministic fabrication of 3D/2D perovskite bilayer stacks for durable and efficient solar cells", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Realizing solution-processed heterostructures is a long-enduring challenge in halide perovskites because of solvent incompatibilities that disrupt the underlying layer. By leveraging the solvent dielectric constant and Gutmann donor number, we could grow phase-pure two-dimensional (2D) halide perovskite stacks of the desired composition, thickness, and bandgap onto 3D perovskites without dissolving the underlying substrate. Characterization reveals a 3D-2D transition region of 20 nullometers mainly determined by the roughness of the bottom 3D layer. Thickness dependence of the 2D perovskite layer reveals the anticipated trends for n-i-p and p-i-n architectures, which is consistent with band alignment and carrier transport limits for 2D perovskites. We measured a photovoltaic efficiency of 24.5%, with exceptional stability of T-99 (time required to preserve 99% of initial photovoltaic efficiency) of >2000 hours, implying that the 3D/2D bilayer inherits the intrinsic durability of 2D perovskite without compromising efficiency.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 319, "Times Cited, All Databases": 332, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 23", "Publication Year": 2022, "Volume": 377, "Issue": 6613, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1425, "End Page": 1430, "Article Number": null, "DOI": "10.1126/science.abq7652", "DOI Link": "http://dx.doi.org/10.1126/science.abq7652", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000887934300037", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, W; Zhai, PB; Li, AW; Wei, B; Si, KP; Wei, Y; Wang, XG; Zhu, GD; Chen, Q; Gu, XK; Zhang, RF; Zhou, W; Gong, YJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Wei; Zhai, Pengbo; Li, Aowen; Wei, Bo; Si, Kunpeng; Wei, Yi; Wang, Xingguo; Zhu, Guangda; Chen, Qian; Gu, Xiaokang; Zhang, Ruifeng; Zhou, Wu; Gong, Yongji", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electrochemical CO2 reduction to ethylene by ultrathin CuO nulloplate arrays", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical reduction of CO2 to multi-carbon fuels and chemical feedstocks is an appealing approach to mitigate excessive CO2 emissions. However, the reported catalysts always show either a low Faradaic efficiency of the C2+ product or poor long-term stability. Herein, we report a facile and scalable anodic corrosion method to synthesize oxygen-rich ultrathin CuO nulloplate arrays, which form Cu/Cu2O heterogeneous interfaces through self-evolution during electrocatalysis. The catalyst exhibits a high C2H4 Faradaic efficiency of 84.5%, stable electrolysis for similar to 55 h in a flow cell using a neutral KCI electrolyte, and a full-cell ethylene energy efficiency of 27.6% at 200 mA cm(-2) in a membrane electrode assembly electrolyzer. Mechanism analyses reveal that the stable nullostructures, stable Cu/Cu2O interfaces, and enhanced adsorption of the *OCCOH intermediate preserve selective and prolonged C2H4 production. The robust and scalable produced catalyst coupled with mild electrolytic conditions facilitates the practical application of electrochemical CO2 reduction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 333, "Times Cited, All Databases": 349, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 6", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1877, "DOI": "10.1038/s41467-022-29428-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29428-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000779311200034", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, F; Park, SY; Yao, CL; Lu, HP; Dunfield, SP; Xiao, CX; Ulicná, S; Zhao, XM; Du Hill, L; Chen, XH; Wang, XM; Mundt, LE; Stone, KH; Schelhas, LT; Teeter, G; Parkin, S; Ratcliff, EL; Loo, YL; Berry, JJ; Beard, MC; Yan, YF; Larson, BW; Zhu, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Fei; Park, So Yeon; Yao, Canglang; Lu, Haipeng; Dunfield, Sean P.; Xiao, Chuanxiao; Ulicna, Sona; Zhao, Xiaoming; Du Hill, Linze; Chen, Xihan; Wang, Xiaoming; Mundt, Laura E.; Stone, Kevin H.; Schelhas, Laura T.; Teeter, Glenn; Parkin, Sean; Ratcliff, Erin L.; Loo, Yueh-Lin; Berry, Joseph J.; Beard, Matthew C.; Yan, Yanfa; Larson, Bryon W.; Zhu, Kai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Metastable Dion-Jacobson 2D structure enables efficient and stable perovskite solar cells", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The performance of three-dimensional (3D) organic-inorganic halide perovskite solar cells (PSCs) can be enhanced through surface treatment with 2D layered perovskites that have efficient charge transport. We maximized hole transport across the layers of a metastable Dion-Jacobson (DJ) 2D perovskite that tuned the orientational arrangements of asymmetric bulky organic molecules. The reduced energy barrier for hole transport increased out-of-plane transport rates by a factor of 4 to 5, and the power conversion efficiency (PCE) for the 2D PSC was 4.9%. With the metastable DJ 2D surface layer, the PCE of three common 3D PSCs was enhanced by approximately 12 to 16% and could reach approximately 24.7%. For a triple-cation-mixed-halide PSC, 90% of the initial PCE was retained after 1000 hours of 1-sun operation at similar to 40 degrees C in nitrogen.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 319, "Times Cited, All Databases": 330, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 7", "Publication Year": 2022, "Volume": 375, "Issue": 6576, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 71, "End Page": "+", "Article Number": "eabj2637", "DOI": "10.1126/science.abj2637", "DOI Link": "http://dx.doi.org/10.1126/science.abj2637", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000740261400042", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, YX; Miao, JS; Hua, T; Huang, ZY; Qi, YY; Zou, Y; Qiu, YT; Xia, H; Liu, H; Cao, XS; Yang, CL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Yu Xuan; Miao, Jingsheng; Hua, Tao; Huang, Zhongyan; Qi, Yanyu; Zou, Yang; Qiu, Yuntao; Xia, Han; Liu, He; Cao, Xiaosong; Yang, Chuluo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Efficient selenium-integrated TADF OLEDs with reduced roll-off", "Source Title": "NATURE PHOTONICS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic light emitters based on multiresonullce-induced thermally activated delayed fluorescent materials have great potential for realizing efficient, narrowband organic light-emitting diodes (OLEDs). However, at high brightness operation, efficiency roll-off attributed to the slow reverse intersystem crossing (RISC) process hinders the use of multiresonullce-induced thermally activated delayed fluorescent materials in practical applications. Here we report a heavy-atom incorporating emitter, BNSeSe, which is based on a selenium-integrated boron-nitrogen skeleton and exhibits 100% photoluminescence quantum yield and a high RISC rate (k(RISC)) of 2.0 x 10(6) s(-1). The corresponding green OLEDs exhibit excellent external quantum efficiencies of up to 36.8% and ultra-low roll-off character at high brightnesses (with very small roll-off values of 2.8% and 14.9% at 1,000 cd m(-2) and 10,000 cd m(-2), respectively). Furthermore, the outstanding capability to harvest triplet excitons also enables BNSeSe to be a superior sensitizer for a hyperfluorescence OLED, which shows state-of-the-art performance with a high excellent external quantum efficiency of 40.5%, power efficiency beyond 200 lm W-1, and luminullce close to 20,0000 cd m(-2). Green OLEDs based on BNSeSe offer high operational efficiency and reduced efficiency roll-off.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 319, "Times Cited, All Databases": 329, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV", "Publication Year": 2022, "Volume": 16, "Issue": 11, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 803, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41566-022-01083-y", "DOI Link": "http://dx.doi.org/10.1038/s41566-022-01083-y", "Book DOI": null, "Early Access Date": "OCT 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000867521100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, JW; Hu, XZ; Wang, C; Liang, C; Chen, C; Xiao, M; Li, JS; Tao, C; Xing, GC; Yu, R; Ke, WJ; Fang, GJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Jiwei; Hu, Xuzhi; Wang, Chen; Liang, Chao; Chen, Cong; Xiao, Meng; Li, Jiashuai; Tao, Chen; Xing, Guichuan; Yu, Rui; Ke, Weijun; Fang, Guojia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Origins and influences of metallic lead in perovskite solar cells", "Source Title": "JOULE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Metallic lead (Pb-0) impurities in metal-halide perovskites have attracted tremendous research concerns owing to their detrimental effects on perovskite solar cells (PSCs). However, the origins and influences of the Pb-0 behind this issue have yet to bewell understood. Herein, we show that Pb-0 is hardly formed in the growth of halide perovskites but is easily postformed in the perovskite films with excess PbI2. It is found that Pb-0 impurities are decomposition byproducts of residual PbI2 in perovskites under light or X-ray irradiation. Therefore, PSCs obtained using photodegraded PbI2 films show large efficiency and stability losses. By contrast, the perovskite devices without detectable Pb-0 impurities have a much better efficiency and stability. This work reveals the origins and influences of Pb-0 in halide perovskites and provides a strategy for avoiding the formation of detrimental Pb-0 byproducts, which would drive further enhancements in device performance of halide perovskite solar cells, detectors, etc.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 325, "Times Cited, All Databases": 330, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 20", "Publication Year": 2022, "Volume": 6, "Issue": 4, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 816, "End Page": 833, "Article Number": null, "DOI": "10.1016/j.joule.2022.03.005", "DOI Link": "http://dx.doi.org/10.1016/j.joule.2022.03.005", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000798575600013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, D; Yang, YJ; Yang, J; Fang, MM; Tang, BZ; Li, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Dan; Yang, Yujie; Yang, Jie; Fang, Manman; Tang, Ben Zhong; Li, Zhen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Completely aqueous processable stimulus responsive organic room temperature phosphorescence materials with tunable afterglow color", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Stimuli responsive luminescent materials are important in applied research but many of these materials are based on fluorescent stimuli responsive materials. Here, the authors report a stimulus-responsive room temperature phosphorescent materials composed of a phosphorescent chromophore of arylboronic acid and poly(vinylalcohol) with color tunable and water process able properties. Many luminescent stimuli responsive materials are based on fluorescence emission, while stimuli-responsive room temperature phosphorescent materials are less explored. Here, we show a kind of stimulus-responsive room temperature phosphorescence materials by the covalent linkage of phosphorescent chromophore of arylboronic acid and polymer matrix of poly(vinylalcohol). Attributed to the rigid environment offered from hydrogen bond and B-O covalent bond between arylboronic acid and poly(vinylalcohol), the yielded polymer film exhibits ultralong room temperature phosphorescence with lifetime of 2.43 s and phosphorescence quantum yield of 7.51%. Interestingly, the RTP property of this film is sensitive to the water and heat stimuli, because water could destroy the hydrogen bonds between adjacent poly(vinylalcohol) polymers, then changing the rigidity of this system. Furthermore, by introducing another two fluorescent dyes to this system, the color of afterglow with stimulus response effect could be adjusted from blue to green to orange through triplet-to-singlet Forster-resonullce energy-transfer. Finally, due to the water/heat-sensitive, multicolor and completely aqueous processable feature for these three afterglow hybrids, they are successfully applied in multifunctional ink for anti-counterfeit, screen printing and fingerprint record.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 322, "Times Cited, All Databases": 329, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 17", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 347, "DOI": "10.1038/s41467-022-28011-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28011-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000744540800018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mielke, C; Das, D; Yin, JX; Liu, H; Gupta, R; Jiang, YX; Medarde, M; Wu, X; Lei, HC; Chang, J; Dai, PC; Si, Q; Miao, H; Thomale, R; Neupert, T; Shi, Y; Khasanov, R; Hasan, MZ; Luetkens, H; Guguchia, Z", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mielke, C.; Das, D.; Yin, J-X; Liu, H.; Gupta, R.; Jiang, Y-X; Medarde, M.; Wu, X.; Lei, H. C.; Chang, J.; Dai, Pengcheng; Si, Q.; Miao, H.; Thomale, R.; Neupert, T.; Shi, Y.; Khasanov, R.; Hasan, M. Z.; Luetkens, H.; Guguchia, Z.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Time-reversal symmetry-breaking charge order in a kagome superconductor", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The kagome lattice(1), which is the most prominent structural motif in quantum physics, benefits from inherent non-trivial geometry so that it can host diverse quantum phases, ranging from spin-liquid phases, to topological matter, to intertwined orders(2-8) and, most rarely, to unconventional superconductivity(6,9). Recently, charge sensitive probes have indicated that the kagome superconductors AV(3)Sb(5) (A = K, Rb, Cs)(9-11) exhibit unconventional chiral charge order(12-19), which is analogousto the long-sought-after quantum order in the Haldane model(20) or Varma model(21). However, direct evidence for the time-reversal symmetry breaking of the charge order remains elusive. Here we use muon spin relaxation to probe the kagome charge order and superconductivity in KV3Sb5. We observe a noticeable enhancement of the internal field width sensed by the muon ensemble, which takes place just below the charge orderingtemperature and persists into the superconducting state. Notably, the muon spin relaxation rate below the charge orderingtemperature is substantially enhanced by applying an external magnetic field. We further show the multigap nature of superconductivity in KV3Sb5 and that the T-c/lambda(-2)(ab) ratio (where T-c is the superconducting transition temperature and lambda(ab) is the magnetic penetration depth in the kagome plane) is comparable to those of unconventional high-temperature superconductors. Our results point to time-reversal symmetry-breaking charge order intertwining with unconventional superconductivity in the correlated kagome lattice.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 315, "Times Cited, All Databases": 329, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 10", "Publication Year": 2022, "Volume": 602, "Issue": 7896, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 245, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-021-04327-z", "DOI Link": "http://dx.doi.org/10.1038/s41586-021-04327-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000753550800017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, WW; Chen, LJ; Dai, S; Zhao, CX; Ma, C; Wei, L; Zhu, MH; Chong, SY; Yang, HF; Liu, LJ; Bai, Y; Yu, MJ; Xu, YJ; Zhu, XW; Zhu, Q; An, SH; Sprick, RS; Little, MA; Wu, XF; Jiang, S; Wu, YZ; Zhang, YB; Tian, H; Zhu, WH; Cooper, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Weiwei; Chen, Linjiang; Dai, Sheng; Zhao, Chengxi; Ma, Cheng; Wei, Lei; Zhu, Minghui; Chong, Samantha Y.; Yang, Haofan; Liu, Lunjie; Bai, Yang; Yu, Miaojie; Xu, Yongjie; Zhu, Xiao-Wei; Zhu, Qiang; An, Shuhao; Sprick, Reiner Sebastian; Little, Marc A.; Wu, Xiaofeng; Jiang, Shan; Wu, Yongzhen; Zhang, Yue-Biao; Tian, He; Zhu, Wei-Hong; Cooper, Andrew, I", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Reconstructed covalent organic frameworks", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Covalent organic frameworks (COFs) are distinguished from other organic polymers by their crystallinity(1-3), but it remains challenging to obtain robust, highly crystalline COFs because the framework-forming reactions are poorly reversible(4,5). More reversible chemistry can improve crystallinity(6-9), but this typically yields COFs with poor physicochemical stability and limited application scope(5). Here we report a general and scalable protocol to prepare robust, highly crystalline imine COFs, based on an unexpected framework reconstruction. In contrast to standard approaches in which monomers are initially randomly aligned, our method involves the pre-organization of monomers using a reversible and removable covalent tether, followed by confined polymerization. This reconstruction route produces reconstructed COFs with greatly enhanced crystallinity and much higher porosity by means of a simple vacuum-free synthetic procedure. The increased crystallinity in the reconstructed COFs improves charge carrier transport, leading to sacrificial photocatalytic hydrogen evolution rates of up to 27.98 mmol h(-1) g(-1). This nulloconfinement-assisted reconstruction strategy is a step towards programming function in organic materials through atomistic structural control.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 318, "Times Cited, All Databases": 327, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 7", "Publication Year": 2022, "Volume": 604, "Issue": 7904, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 72, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-022-04443-4", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-04443-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000779100400018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, RT; Ren, ZF; Liang, Y; Zhang, GH; Dittrich, T; Liu, RZ; Liu, Y; Zhao, Y; Pang, S; An, HY; Ni, CW; Zhou, PW; Han, KL; Fan, FT; Li, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Ruotian; Ren, Zefeng; Liang, Yu; Zhang, Guanhua; Dittrich, Thomas; Liu, Runze; Liu, Yang; Zhao, Yue; Pang, Shan; An, Hongyu; Ni, Chenwei; Zhou, Panwang; Han, Keli; Fan, Fengtao; Li, Can", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Spatiotemporal imaging of charge transfer in photocatalyst particles", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The water-splitting reaction using photocatalyst particles is a promising route for solar fuel production(1-4). Photo-induced charge transfer from a photocatalyst to catalytic surface sites is key in ensuring photocatalytic efficiency(5); however, it is challenging to understand this process, which spans a wide spatiotemporal range from nullometres to micrometres and from femtoseconds to seconds(6-8). Although the steady-state charge distribution on single photocatalyst particles has been mapped by microscopic techniques(9-11), and the charge transfer dynamics in photocatalyst aggregations have been revealed by time-resolved spectroscopy(12,13), spatiotemporally evolving charge transfer processes in single photocatalyst particles cannot be tracked, and their exact mechanism is unknown. Here we perform spatiotemporally resolved surface photovoltage measurements on cuprous oxide photocatalyst particles to map holistic charge transfer processes on the femtosecond to second timescale at the single-particle level. We find that photogenerated electrons are transferred to the catalytic surface quasi-ballistically through inter-facet hot electron transfer on a subpicosecond timescale, whereas photogenerated holes are transferred to a spatially separated surface and stabilized through selective trapping on a microsecond timescale. We demonstrate that these ultrafast-hot-electron-transfer and anisotropic-trapping regimes, which challenge the classical perception of a drift-diffusion model, contribute to the efficient charge separation in photocatalysis and improve photocatalytic performance. We anticipate that our findings will be used to illustrate the universality of other photoelectronic devices and facilitate the rational design of photocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 312, "Times Cited, All Databases": 328, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 13", "Publication Year": 2022, "Volume": 610, "Issue": 7931, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 296, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-022-05183-1", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-05183-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000867324800024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, L; Deng, SQ; Liu, H; Wu, J; Qi, H; Chen, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Liang; Deng, Shiqing; Liu, Hui; Wu, Jie; Qi, He; Chen, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Giant energy-storage density with ultrahigh efficiency in lead-free relaxors via high-entropy design", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Next-generation advanced high/pulsed power capacitors rely heavily on dielectric ceramics with high energy storage performance. However, thus far, the huge challenge of realizing ultrahigh recoverable energy storage density (W-rec) accompanied by ultrahigh efficiency (eta) still existed and has become a key bottleneck restricting the development of dielectric materials in cutting-edge energy storage applications. Here, we propose a high-entropy strategy to design local polymorphic distortion including rhombohedral-orthorhombic-tetragonal-cubic multiphase nulloclusters and random oxygen octahedral tilt, resulting inultra small polar nulloregions, an enhanced breakdown electric field, and delayed polarization saturation. A giant W-rec similar to 10.06 J cm(-3) is realized in lead-free relaxor ferroelectrics, especially with an ultrahigh eta similar to 90.8%, showing breakthrough progress in the comprehensive energy storage performance for lead-free bulk ceramics. This work opens up an effective avenue to design dielectric materials with ultrahigh comprehensive energy storage performance to meet the demanding requirements of advanced energy storage applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 318, "Times Cited, All Databases": 326, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 2", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3089, "DOI": "10.1038/s41467-022-30821-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-30821-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000805202900032", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Pan, D; Yang, G; Abo-Dief, HM; Dong, JW; Su, FM; Liu, CT; Li, YF; Xu, BB; Murugadoss, V; Naik, N; El-Bahy, SM; El-Bahy, ZM; Huang, MA; Guo, ZH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Pan, Duo; Yang, Gui; Abo-Dief, Hala M.; Dong, Jingwen; Su, Fengmei; Liu, Chuntai; Li, Yifan; Xu, Ben Bin; Murugadoss, Vignesh; Naik, Nithesh; El-Bahy, Salah M.; El-Bahy, Zeinhom M.; Huang, Minull; Guo, Zhanhu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Vertically Aligned Silicon Carbide nullowires/ Boron Nitride Cellulose Aerogel Networks Enhanced Thermal Conductivity and Electromagnetic Absorbing of Epoxy Composites", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "With the innovation of microelectronics technology, the heat dissipation problem inside the device will face a severe test. In this work, cellulose aerogel (CA) with highly enhanced thermal conductivity (TC) in vertical planes was successfully obtained by constructing a vertically aligned silicon carbide nullowires (SiC NWs)/boron nitride (BN) network via the ice template-assisted strategy. The unique network structure of SiC NWs connected to BN ensures that the TC of the composite in the vertical direction reaches 2.21 W m(-1) K-1 at a low hybrid filler loading of 16.69 wt%, which was increased by 890% compared to pure epoxy (EP). In addition, relying on unique porous network structure of CA, EP-based composite also showed higher TC than other comparative samples in the horizontal direction. Meanwhile, the composite exhibits good electrically insulating with a volume electrical resistivity about 2.35 x 1011 Omega cm and displays excellent electromagnetic wave absorption performance with a minimum reflection loss of - 21.5 dB and a wide effective absorption bandwidth (< - 10 dB) from 8.8 to 11.6 GHz. Therefore, this work provides a new strategy for manufacturing polymer-based composites with excellent multifunctional performances in microelectronic packaging applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 312, "Times Cited, All Databases": 324, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 118, "DOI": "10.1007/s40820-022-00863-z", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00863-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000789072200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rong, CL; Shen, XJ; Wang, Y; Thomsen, L; Zhao, TW; Li, YB; Lu, XY; Amal, R; Zhao, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rong, Chengli; Shen, Xiangjian; Wang, Yuan; Thomsen, Lars; Zhao, Tingwen; Li, Yibing; Lu, Xunyu; Amal, Rose; Zhao, Chuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Electronic Structure Engineering of Single-Atom Ru Sites via Co-N4 Sites for Bifunctional pH-Universal Water Splitting", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of bifunctional water-splitting electrocatalysts that are efficient and stable over a wide range of pH is of great significance but challenging. Here, an atomically dispersed Ru/Co dual-sites catalyst is reported anchored on N-doped carbon (Ru/Co-N-C) for outstanding oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) in both acidic and alkaline electrolytes. The Ru/Co-N-C catalyst requires the overpotential of only 13 and 23 mV for HER, 232 and 247 mV for OER to deliver a current density of 10 mA cm(geo)(-2) in 0.5 m H2SO4 and 1 m KOH, respectively, outperforming benchmark catalysts Pt/C and RuO2. Theoretical calculations reveal that the introduction of Co-N4 sites into Ru/Co-N-C efficiently modify the electronic structure of Ru by enlarging Ru-O covalency and increasing Ru electron density, which in turn optimize the bonding strength between oxygen/hydrogen intermediate species with Ru sites, thereby enhancing OER and HER performance. Furthermore, the incorporation of Co-N4 sites induces electron redistribution around Ru-N4, thus enhancing corrosion-resistance of Ru/Co-N-C during acid and alkaline electrolysis. The Ru/Co-N-C has been applied in a proton exchange membrane water electrolyzer and steady operation is demonstrated at a high current density of 450 mA cm(geo)(-2) for 330 h.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 307, "Times Cited, All Databases": 312, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2022, "Volume": 34, "Issue": 21, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2110103, "DOI": "10.1002/adma.202110103", "DOI Link": "http://dx.doi.org/10.1002/adma.202110103", "Book DOI": null, "Early Access Date": "APR 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000786440900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, Y; Zhao, Y; Zhou, M; Tan, SJ; Peymanfar, R; Aslibeiki, B; Ji, GB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Yue; Zhao, Yue; Zhou, Ming; Tan, Shujuan; Peymanfar, Reza; Aslibeiki, Bagher; Ji, Guangbin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrabroad Microwave Absorption Ability and Infrared Stealth Property of nullo-Micro CuS@rGO Lightweight Aerogels", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing ultrabroad radar-infrared compatible stealth materials has turned into a research hotspot, which is still a problem to be solved. Herein, the copper sulfide wrapped by reduced graphene oxide to obtain three-dimensional (3D) porous network composite aerogels (CuS@rGO) were synthesized via thermal reduction ways (hydrothermal, ascorbic acid reduction) and freeze-drying strategy. It was discovered that the phase components (rGO and CuS phases) and micro/nullo structure (microporous and nullosheet) were well-modified by modulating the additive amounts of CuS and changing the reduction ways, which resulted in the variation of the pore structure, defects, complex permittivity, microwave absorption, radar cross section (RCS) reduction value and infrared (IR) emissivity. Notably, the obtained CuS@rGO aerogels with a single dielectric loss type can achieve an ultrabroad bandwidth of 8.44 GHz at 2.8 mm with the low filler content of 6 wt% by a hydrothermal method. Besides, the composite aerogel via the ascorbic acid reduction realizes the minimum reflection loss (RLmin) of - 60.3 dB with the lower filler content of 2 wt%. The RCS reduction value can reach 53.3 dB m(2), which effectively reduces the probability of the target being detected by the radar detector. Furthermore, the laminated porous architecture and multicomponent endowed composite aerogels with thermal insulation and IR stealth versatility. Thus, this work offers a facile method to design and develop porous rGO-based composite aerogel absorbers with radar-IR compatible stealth.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 310, "Times Cited, All Databases": 324, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 171, "DOI": "10.1007/s40820-022-00906-5", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00906-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000842159200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhao, W; Yan, PY; Li, BY; Bahri, M; Liu, LJ; Zhou, X; Clowes, R; Browning, ND; Wu, Y; Ward, JW; Cooper, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhao, Wei; Yan, Peiyao; Li, Boyu; Bahri, Mounib; Liu, Lunjie; Zhou, Xiang; Clowes, Rob; Browning, Nigel D.; Wu, Yue; Ward, John W.; Cooper, Andrew, I", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Accelerated Synthesis and Discovery of Covalent Organic Framework Photocatalysts for Hydrogen Peroxide Production", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A high-throughput sonochemical synthesis and testing strategy was developed to discover covalent organic frameworks (COFs) for photocatalysis. In total, 76 conjugated polymers were synthesized, including 60 crystalline COFs of which 18 were previously unreported. These COFs were then screened for photocatalytic hydrogen peroxide (H2O2) production using water and oxygen. One of these COFs, sonoCOF-F2, was found to be an excellent photocatalyst for photocatalytic H2O2 production even in the absence of sacrificial donors. However, after long-term photocatalytic tests (96 h), the imine sonoCOF-F2 transformed into an amide-linked COF with reduced crystallinity and loss of electronic conjugation, decreasing the photocatalytic activity. When benzyl alcohol was introduced to form a two-phase catalytic system, the photostability of sonoCOF-F2 was greatly enhanced, leading to stable H2O2 production for at least 1 week.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 296, "Times Cited, All Databases": 305, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 8", "Publication Year": 2022, "Volume": 144, "Issue": 22, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 9902, "End Page": 9909, "Article Number": null, "DOI": "10.1021/jacs.2c02666", "DOI Link": "http://dx.doi.org/10.1021/jacs.2c02666", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000810004300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qin, Y; Yu, TT; Deng, SH; Zhou, XY; Lin, DM; Zhang, Q; Jin, ZY; Zhang, DF; He, YB; Qiu, HJ; He, LH; Kang, FY; Li, KK; Zhang, TY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qin, Yin; Yu, Tingting; Deng, Sihao; Zhou, Xiao-Ye; Lin, Dongmei; Zhang, Qian; Jin, Zeyu; Zhang, Danfeng; He, Yan-Bing; Qiu, Hua-Jun; He, Lunhua; Kang, Feiyu; Li, Kaikai; Zhang, Tong-Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "RuO2 electronic structure and lattice strain dual engineering for enhanced acidic oxygen evolution reaction performance", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "While water splitting in acid offers higher operational performances than in alkaline conditions, there are few high-activity, acid-stable oxygen evolution electrocatalysts. Here, authors examine electrochemical Li intercalation to improve the activity and stability of RuO2 for acidic water oxidation. Developing highly active and durable electrocatalysts for acidic oxygen evolution reaction remains a great challenge due to the sluggish kinetics of the four-electron transfer reaction and severe catalyst dissolution. Here we report an electrochemical lithium intercalation method to improve both the activity and stability of RuO2 for acidic oxygen evolution reaction. The lithium intercalates into the lattice interstices of RuO2, donates electrons and distorts the local structure. Therefore, the Ru valence state is lowered with formation of stable Li-O-Ru local structure, and the Ru-O covalency is weakened, which suppresses the dissolution of Ru, resulting in greatly enhanced durability. Meanwhile, the inherent lattice strain results in the surface structural distortion of LixRuO2 and activates the dangling O atom near the Ru active site as a proton acceptor, which stabilizes the OOH* and dramatically enhances the activity. This work provides an effective strategy to develop highly efficient catalyst towards water splitting.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 317, "Times Cited, All Databases": 323, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 1", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3784, "DOI": "10.1038/s41467-022-31468-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-31468-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000819790100020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rao, ZY; Tung, PY; Xie, RW; Wei, Y; Zhang, HB; Ferrari, A; Klaver, TPC; Körmann, F; Sukumar, PT; da Silva, AK; Chen, Y; Li, ZM; Ponge, D; Neugebauer, J; Gutfleisch, O; Bauer, S; Raabe, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rao, Ziyuan; Tung, Po-Yen; Xie, Ruiwen; Wei, Ye; Zhang, Hongbin; Ferrari, Alberto; Klaver, T. P. C.; Koermann, Fritz; Sukumar, Prithiv Thoudden; da Silva, Alisson Kwiatkowski; Chen, Yao; Li, Zhiming; Ponge, Dirk; Neugebauer, Joerg; Gutfleisch, Oliver; Bauer, Stefan; Raabe, Dierk", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Machine learning-enabled high-entropy alloy discovery", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-entropy alloys are solid solutions of multiple principal elements that are capable of reaching composition and property regimes inaccessible for dilute materials. Discovering those with valuable properties, however, too often relies on serendipity, because thermodynamic alloy design rules alone often fail in high-dimensional composition spaces. We propose an active learning strategy to accelerate the design of high-entropy Invar alloys in a practically infinite compositional space based on very sparse data. Our approach works as a closed-loop, integrating machine learning with density-functional theory, thermodynamic calculations, and experiments. After processing and characterizing 17 new alloys out of millions of possible compositions, we identified two high-entropy Invar alloys with extremely low thermal expansion coefficients around 2 x 10-6 per degree kelvin at 300 kelvin. We believe this to be a suitable pathway for the fast and automated discovery of high-entropy alloys with optimal thermal, magnetic, and electrical properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 308, "Times Cited, All Databases": 322, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 7", "Publication Year": 2022, "Volume": 378, "Issue": 6615, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 78, "End Page": 84, "Article Number": null, "DOI": "10.1126/science.abo4940", "DOI Link": "http://dx.doi.org/10.1126/science.abo4940", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000909870100058", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mendes, CR; Dilarri, G; Forsan, CF; Sapata, VDR; Lopes, PRM; de Moraes, PB; Montagnolli, RN; Ferreira, H; Bidoia, ED", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mendes, Carolina Rosai; Dilarri, Guilherme; Forsan, Carolina Froes; Ruy Sapata, Vinicius de Moraes; Matos Lopes, Paulo Renato; de Moraes, Peterson Bueno; Montagnolli, Renato Nallin; Ferreira, Henrique; Bidoia, Ederio Dino", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Antibacterial action and target mechanisms of zinc oxide nulloparticles against bacterial pathogens", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Zinc oxide nulloparticles (ZnO NPs) are one of the most widely used nulloparticulate materials due to their antimicrobial properties, but their main mechanism of action (MOA) has not been fully elucidated. This study characterized ZnO NPs by using X-ray diffraction, FT-IR spectroscopy and scanning electron microscopy. Antimicrobial activity of ZnO NPs against the clinically relevant bacteria Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, and the Gram-positive model Bacillus subtilis was evaluated by performing resazurin microtiter assay (REMA) after exposure to the ZnO NPs at concentrations ranging from 0.2 to 1.4 mM. Sensitivity was observed at 0.6 mM for the Gram-negative and 1.0 mM for the Gram-positive cells. Fluorescence microscopy was used to examine the interference of ZnO NPs on the membrane and the cell division apparatus of B. subtilis (amy::pspac-ftsZ-gfpmut1) expressing FtsZ-GFP. The results showed that ZnO NPs did not interfere with the assembly of the divisional Z-ring. However, 70% of the cells exhibited damage in the cytoplasmic membrane after 15 min of exposure to the ZnO NPs. Electrostatic forces, production of Zn2+ ions and the generation of reactive oxygen species were described as possible pathways of the bactericidal action of ZnO. Therefore, understanding the bactericidal MOA of ZnO NPs can potentially help in the construction of predictive models to fight bacterial resistance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 307, "Times Cited, All Databases": 312, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 16", "Publication Year": 2022, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2658, "DOI": "10.1038/s41598-022-06657-y", "DOI Link": "http://dx.doi.org/10.1038/s41598-022-06657-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000757107700007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Peng, LS; Yang, J; Yang, YQ; Qian, FR; Wang, Q; Sun-Waterhouse, D; Shang, L; Zhang, TR; Waterhouse, GIN", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Peng, Lishan; Yang, Jiao; Yang, Yuqi; Qian, Fangren; Wang, Qing; Sun-Waterhouse, Dongxiao; Shang, Lu; Zhang, Tierui; Waterhouse, Geoffrey I. N.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Mesopore-Rich Fe-N-C Catalyst with FeN4-O-NC Single-Atom Sites Delivers Remarkable Oxygen Reduction Reaction Performance in Alkaline Media", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fe-N-C catalysts offer excellent performance for the oxygen reduction reaction (ORR) in alkaline media. With a view toward boosting the intrinsic ORR activity of Fe single-atom sites in Fe-N-C catalysts, fine-tuning the local coordination of the Fe sites to optimize the binding energies of ORR intermediates is imperative. Herein, a porous FeN4-O-NCR electrocatalyst rich in catalytically accessible FeN4-O sites (wherein the Fe single atoms are coordinated to four in-plane nitrogen atoms and one subsurface axial oxygen atom) supported on N-doped carbon nullorods (NCR) is reported. Fe K-edge X-ray absorption spectroscopy (XAS) verifies the presence of FeN4-O active sites in FeN4-O-NCR, while density functional theory calculations reveal that the FeN4-O coordination offers a lower energy and more selective 4-electron/4-proton ORR pathway compared to traditional FeN4 sites. Electrochemical tests validate the outstanding intrinsic activity of FeN4-O-NCR for alkaline ORR, outperforming Pt/C and almost all other M-N-C catalysts reported to date. A primary zinc-air battery constructed using FeN4-O-NCR delivers a peak power density of 214.2 mW cm(-2) at a current density of 334.1 mA cm(-2), highlighting the benefits of optimizing the local coordination of iron single atoms.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 311, "Times Cited, All Databases": 318, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2022, "Volume": 34, "Issue": 29, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2202544, "DOI": "10.1002/adma.202202544", "DOI Link": "http://dx.doi.org/10.1002/adma.202202544", "Book DOI": null, "Early Access Date": "JUN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000809631500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, SY; Luo, T; Li, XQ; Chen, KJ; Fu, JW; Liu, K; Cai, C; Wang, QY; Li, HM; Chen, Y; Ma, C; Zhu, L; Lu, YR; Chan, TS; Zhu, MS; Cortes, E; Liu, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Shanyong; Luo, Tao; Li, Xiaoqing; Chen, Kejun; Fu, Junwei; Liu, Kang; Cai, Chao; Wang, Qiyou; Li, Hongmei; Chen, Yu; Ma, Chao; Zhu, Li; Lu, Ying-Rui; Chan, Ting-Shan; Zhu, Mingshan; Cortes, Emiliano; Liu, Min", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identification of the Highly Active Co-N4 Coordination Motif for Selective Oxygen Reduction to Hydrogen Peroxide", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrosynthesis of hydrogen peroxide (H2O2) through oxygen reduction reaction (ORR) is an environment-friendly and sustainable route for obtaining a fundamental product in the chemical industry. Co-N4 single-atom catalysts (SAC) have sparkled attention for being highly active in both 2e- ORR, leading to H2O2 and 4e- ORR, in which H2O is the main product. However, there is still a lack of fundamental insights into the structure-function relationship between CoN4 and the ORR mechanism over this family of catalysts. Here, by combining theoretical simulation and experiments, we unveil that pyrrole-type CoN4 (Co-N SACDp) is mainly responsible for the 2e- ORR, while pyridine-type CoN4 catalyzes the 4e- ORR. Indeed, Co-N SACDp exhibits a remarkable H2O2 selectivity of 94% and a superb H2O2 yield of 2032 mg for 90 h in a flow cell, outperforming most reported catalysts in acid media. Theoretical analysis and experimental investigations confirm that Co-N SACDp-with weakening O-2/HOO* interaction-boosts the H2O2 production.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 297, "Times Cited, All Databases": 307, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 17", "Publication Year": 2022, "Volume": 144, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 14505, "End Page": 14516, "Article Number": null, "DOI": "10.1021/jacs.2c01194", "DOI Link": "http://dx.doi.org/10.1021/jacs.2c01194", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000860150500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, PT; Yang, H; Tang, C; Wu, Y; Zheng, Y; Cheng, T; Davey, K; Huang, XQ; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Pengtang; Yang, Hao; Tang, Cheng; Wu, Yu; Zheng, Yao; Cheng, Tao; Davey, Kenneth; Huang, Xiaoqing; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boosting electrocatalytic CO2-to-ethanol production via asymmetric C-C coupling", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "It is of high interest to convert CO2 into valuable ethanol product. Here the authors demonstrate the asymmetric C-C coupling triggered on Ag-modified oxide-derived Cu sites can accelerate and steer the reaction pathway for ethanol production with high faradaic efficiency and current density. Electroreduction of carbon dioxide (CO2) into multicarbon products provides possibility of large-scale chemicals production and is therefore of significant research and commercial interest. However, the production efficiency for ethanol (EtOH), a significant chemical feedstock, is impractically low because of limited selectivity, especially under high current operation. Here we report a new silver-modified copper-oxide catalyst (dCu(2)O/Ag-2.3%) that exhibits a significant Faradaic efficiency of 40.8% and energy efficiency of 22.3% for boosted EtOH production. Importantly, it achieves CO2-to-ethanol conversion under high current operation with partial current density of 326.4 mA cm(-2) at -0.87 V vs reversible hydrogen electrode to rank highly significantly amongst reported Cu-based catalysts. Based on in situ spectra studies we show that significantly boosted production results from tailored introduction of Ag to optimize the coordinated number and oxide state of surface Cu sites, in which the *CO adsorption is steered as both atop and bridge configuration to trigger asymmetric C-C coupling for stablization of EtOH intermediates.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 302, "Times Cited, All Databases": 310, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 29", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3754, "DOI": "10.1038/s41467-022-31427-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-31427-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000830675000015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, CL; Hu, H; Yang, MF; Pei, ZY; Zhou, Q; Ren, X; Liu, B; Liu, DW; Zeng, XG; Zhang, GL; Zhang, HB; Liu, JJ; Wang, Q; Deng, XJ; Xiao, CJ; Yao, YG; Xue, DS; Zuo, W; Su, Y; Wen, WB; Ouyang, ZY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Chunlai; Hu, Hao; Yang, Meng-Fei; Pei, Zhao-Yu; Zhou, Qin; Ren, Xin; Liu, Bin; Liu, Dawei; Zeng, Xingguo; Zhang, Guangliang; Zhang, Hongbo; Liu, Jianjun; Wang, Qiong; Deng, Xiangjin; Xiao, Caijin; Yao, Yonggang; Xue, Dingshuai; Zuo, Wei; Su, Yan; Wen, Weibin; Ouyang, Ziyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Characteristics of the lunar samples returned by the Chang'E-5 mission", "Source Title": "NATIONAL SCIENCE REVIEW", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The CE-5 sample is consistent with weathered mare basalts in mineralogy and petrochemistry, and is classified as low-Ti/low-Al/low-K type with lower REE (rare earth element) contents than KREEP (potassium, rare earth element, and phosphorus). This new sample characterized by high FeO and low Mg index could represent a new lunar basalt. Forty-five years after the Apollo and Luna missions returned lunar samples, China's Chang'E-5 (CE-5) mission collected new samples from the mid-latitude region in the northeastern Oceanus Procellarum of the Moon. Our study shows that 95% of CE-5 lunar soil sizes are found to be within the range of 1.40-9.35 mu m, while 95% of the soils by mass are within the size range of 4.84-432.27 mu m. The bulk density, true density and specific surface area of CE-5 soils are 1.2387 g/cm(3), 3.1952 g/cm(3) and 0.56 m(2)/g, respectively. Fragments from the CE-5 regolith are classified into igneous clasts (mostly basalt), agglutinate and glass. A few breccias were also found. The minerals and compositions of CE-5 soils are consistent with mare basalts and can be classified as low-Ti/low-Al/low-K type with lower rare-earth-element contents than materials rich in potassium, rare earth element and phosphorus. CE-5 soils have high FeO and low Mg index, which could represent a new class of basalt.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 278, "Times Cited, All Databases": 308, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 3", "Publication Year": 2022, "Volume": 9, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "nwab188", "DOI": "10.1093/nsr/nwab188", "DOI Link": "http://dx.doi.org/10.1093/nsr/nwab188", "Book DOI": null, "Early Access Date": "FEB 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000753113800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wan, X; Liu, QT; Liu, JY; Liu, SY; Liu, XF; Zheng, LR; Shang, JX; Yu, RH; Shui, JL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wan, Xin; Liu, Qingtao; Liu, Jieyuan; Liu, Shiyuan; Liu, Xiaofang; Zheng, Lirong; Shang, Jiaxiang; Yu, Ronghai; Shui, Jianglan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Iron atom-cluster interactions increase activity and improve durability in Fe-N-C fuel cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Simultaneously increasing the activity and stability of the single-atom active sites of M-N-C catalysts is critical but remains a great challenge. Here, we report an Fe-N-C catalyst with nitrogen-coordinated iron clusters and closely surrounding Fe-N-4 active sites for oxygen reduction reaction in acidic fuel cells. A strong electronic interaction is built between iron clusters and satellite Fe-N-4 due to unblocked electron transfer pathways and very short interacting distances. The iron clusters optimize the adsorption strength of oxygen reduction intermediates on Fe-N-4 and also shorten the bond amplitude of Fe-N-4 with incoherent vibrations. As a result, both the activity and stability of Fe-N-4 sites are increased by about 60% in terms of turnover frequency and demetalation resistance. This work shows the great potential of strong electronic interactions between multiphase metal species for improvements of single-atom catalysts. It is challenging to break the activity-stability trade-off in Fe-N-C fuel cell catalysts. Here, the authors show that interactions between iron atoms and clusters accelerate reaction kinetics and suppress demetalation to improve fuel cell stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 305, "Times Cited, All Databases": 312, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 26", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2963, "DOI": "10.1038/s41467-022-30702-z", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-30702-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000800650200024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hou, YL; Sheng, ZZ; Fu, C; Kong, J; Zhang, XT", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hou, Yinglai; Sheng, Zhizhi; Fu, Chen; Kong, Jie; Zhang, Xuetong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Hygroscopic holey graphene aerogel fibers enable highly efficient moisture capture, heat allocation and microwave absorption", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aerogel fibers have been recognized as the rising star in the fields of thermal insulation and wearable textiles. Yet, the lack of functionalization in aerogel fibers limits their applications. Herein, we report hygroscopic holey graphene aerogel fibers (LiCl@HGAFs) with integrated functionalities of highly efficient moisture capture, heat allocation, and microwave absorption. LiCl@HGAFs realize the water sorption capacity over 4.15 g g(-1), due to the high surface area and high water uptake kinetics. Moreover, the sorbent can be regenerated through both photo-thermal and electro-thermal approaches. Along with the water sorption and desorption, LiCl@HGAFs experience an efficient heat transfer process, with a heat storage capacity of 6.93 kJ g(-1). The coefficient of performance in the heating and cooling mode can reach 1.72 and 0.70, respectively. Notably, with the entrapped water, LiCl@HGAFs exhibit broad microwave absorption with a bandwidth of 9.69 GHz, good impedance matching, and a high attenuation constant of 585. In light of these findings, the multifunctional LiCl@HGAFs open an avenue for applications in water harvest, heat allocation, and microwave absorption. This strategy also suggests the possibility to functionalize aerogel fibers towards even broader applications. Functionalization of aerogel fibers, characterized by high porosity and low thermal conductivity, to obtain multifunctional materials is highly desirable. Here the authors report hygroscopic holey graphene aerogel fibers hosting LiCl salt, enabling moisture capture, heat allocation, and microwave absorption performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 293, "Times Cited, All Databases": 302, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 9", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1227, "DOI": "10.1038/s41467-022-28906-4", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28906-4", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000766759300018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiao, FM; Gao, HQ; Lei, YX; Dai, WB; Liu, MC; Zheng, XY; Cai, ZX; Huang, XB; Wu, HY; Ding, D", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiao, Fuming; Gao, Heqi; Lei, Yunxiang; Dai, Wenbo; Liu, Miaochang; Zheng, Xiaoyan; Cai, Zhengxu; Huang, Xiaobo; Wu, Huayue; Ding, Dan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Guest-host doped strategy for constructing ultralong-lifetime near-infrared organic phosphorescence materials for bioimaging", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic near-infrared room temperature phosphorescence materials have unparalleled advantages in bioimaging due to their excellent penetrability. However, limited by the energy gap law, the near-infrared phosphorescence materials (>650 nm) are very rare, moreover, the phosphorescence lifetimes of these materials are very short. In this work, we have obtained organic room temperature phosphorescence materials with long wavelengths (600/657-681/732 nm) and long lifetimes (102-324 ms) for the first time through the guest-host doped strategy. The guest molecule has sufficient conjugation to reduce the lowest triplet energy level and the host assists the guest in exciton transfer and inhibits the non-radiative transition of guest excitons. These materials exhibit good tissue penetration in bioimaging. Thanks to the characteristic of long lifetime and long wavelength emissive phosphorescence materials, the tumor imaging in living mice with a signal to background ratio value as high as 43 is successfully realized. This work provides a practical solution for the construction of organic phosphorescence materials with both long wavelengths and long lifetimes.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 288, "Times Cited, All Databases": 296, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 10", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 186, "DOI": "10.1038/s41467-021-27914-0", "DOI Link": "http://dx.doi.org/10.1038/s41467-021-27914-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000849942600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qi, Y; Zhang, JW; Kong, Y; Zhao, Y; Chen, SS; Li, D; Liu, W; Chen, YF; Xie, TF; Cui, JY; Li, C; Domen, K; Zhang, FX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qi, Yu; Zhang, Jiangwei; Kong, Yuan; Zhao, Yue; Chen, Shanshan; Li, Deng; Liu, Wei; Chen, Yifan; Xie, Tengfeng; Cui, Junyan; Li, Can; Domen, Kazunari; Zhang, Fuxiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unraveling of cocatalysts photodeposited selectively on facets of BiVO4 to boost solar water splitting", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Artificial photosynthesis offers an integrated means to convert light to fuel, but efficiencies are often low. Here, authors report a Z-scheme system utilizing Ir and FeCoOx co-catalysts to enhance charge separation on BiVO4 facets that achieves high quantum efficiencies for overall water splitting. Bismuth vanadate (BiVO4) has been widely investigated as a photocatalyst or photoanode for solar water splitting, but its activity is hindered by inefficient cocatalysts and limited understanding of the underlying mechanism. Here we demonstrate significantly enhanced water oxidation on the particulate BiVO4 photocatalyst via in situ facet-selective photodeposition of dual-cocatalysts that exist separately as metallic Ir nulloparticles and nullocomposite of FeOOH and CoOOH (denoted as FeCoOx), as revealed by advanced techniques. The mechanism of water oxidation promoted by the dual-cocatalysts is experimentally and theoretically unraveled, and mainly ascribed to the synergistic effect of the spatially separated dual-cocatalysts (Ir, FeCoOx) on both interface charge separation and surface catalysis. Combined with the H-2-evolving photocatalysts, we finally construct a Z-scheme overall water splitting system using [Fe(CN)(6)](3-/4-) as the redox mediator, whose apparent quantum efficiency at 420 nm and solar-to-hydrogen conversion efficiency are optimized to be 12.3% and 0.6%, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 286, "Times Cited, All Databases": 295, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 25", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 484, "DOI": "10.1038/s41467-022-28146-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-28146-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000747410400003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xiao, F; Wang, Q; Xu, GL; Qin, XP; Hwang, IH; Sun, CJ; Liu, M; Hua, W; Wu, HW; Zhu, SQ; Li, JC; Wang, JG; Zhu, YM; Wu, DJ; Wei, ZD; Gu, M; Amine, K; Shao, MH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xiao, Fei; Wang, Qi; Xu, Gui-Liang; Qin, Xueping; Hwang, Inhui; Sun, Cheng-Jun; Liu, Min; Hua, Wei; Wu, Hsi-wen; Zhu, Shangqian; Li, Jin-Cheng; Wang, Jian-Gan; Zhu, Yuanmin; Wu, Duojie; Wei, Zidong; Gu, Meng; Amine, Khalil; Shao, Minhua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Atomically dispersed Pt and Fe sites and Pt-Fe nulloparticles for durable proton exchange membrane fuel cells", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Proton exchange membrane fuel cells convert hydrogen and oxygen into electricity without emissions. The high cost and low durability of Pt-based electrocatalysts for the oxygen reduction reaction hinder their wide application, and the development of non-precious metal electrocatalysts is limited by their low performance. Here we design a hybrid electrocatalyst that consists of atomically dispersed Pt and Fe single atoms and Pt-Fe alloy nulloparticles. Its Pt mass activity is 3.7 times higher than that of commercial Pt/C in a fuel cell. More importantly, the fuel cell with a low Pt loading in the cathode (0.015 mg(P)(t) cm(-2)) shows an excellent durability, with a 97% activity retention after 100,000 cycles and no noticeable current drop at 0.6V for over 200 hours. These results highlight the importance of the synergistic effects among active sites in hybrid electrocatalysts and provide an alternative way to design more active and durable low-Pt electrocatalysts for electrochemical devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 279, "Times Cited, All Databases": 284, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN", "Publication Year": 2022, "Volume": 5, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 503, "End Page": 512, "Article Number": null, "DOI": "10.1038/s41929-022-00796-1", "DOI Link": "http://dx.doi.org/10.1038/s41929-022-00796-1", "Book DOI": null, "Early Access Date": "JUN 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000805042200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Song, LM; Zhang, F; Chen, YQ; Guan, L; Zhu, YQ; Chen, M; Wang, HL; Putra, BR; Zhang, R; Fan, BB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Song, Limeng; Zhang, Fan; Chen, Yongqiang; Guan, Li; Zhu, Yanqiu; Chen, Mao; Wang, Hailong; Putra, Budi Riza; Zhang, Rui; Fan, Bingbing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multifunctional SiC@SiO2 nullofiber Aerogel with Ultrabroadband Electromagnetic Wave Absorption", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Traditional ceramic materials are generally brittle and not flexible with high production costs, which seriously hinders their practical applications. Multifunctional nullofiber ceramic aerogels are highly desirable for applications in extreme environments, however, the integration of multiple functions in their preparation is extremely challenging. To tackle these challenges, we fabricated a multifunctional SiC@SiO2 nullofiber aerogel (SiC@SiO2 NFA) with a three-dimensional (3D) porous cross-linked structure through a simple chemical vapor deposition method and subsequent heat-treatment process. The as-prepared SiC@SiO2 NFA exhibits an ultralow density (similar to 11 mg cm(- 3)), ultra-elastic, fatigue-resistant and refractory performance, high temperature thermal stability, thermal insulation properties, and significant strain-dependent piezoresistive sensing behavior. Furthermore, the SiC@SiO2 NFA shows a superior electromagnetic wave absorption performance with a minimum refection loss (RLmin) value of - 50.36 dB and a maximum effective absorption bandwidth (EAB(max)) of 8.6 GHz. The successful preparation of this multifunctional aerogel material provides a promising prospect for the design and fabrication of the cutting-edge ceramic materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 282, "Times Cited, All Databases": 286, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2022, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 152, "DOI": "10.1007/s40820-022-00905-6", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00905-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000832688000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, Y; Yang, JL; Hou, XY; Li, G; Wang, L; Bai, NN; Cai, MK; Zhao, LY; Wang, Y; Zhang, JM; Chen, K; Wu, X; Yang, CH; Dai, Y; Zhang, ZY; Guo, CF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Yuan; Yang, Junlong; Hou, Xingyu; Li, Gang; Wang, Liu; Bai, Ningning; Cai, Minkun; Zhao, Lingyu; Wang, Yan; Zhang, Jianming; Chen, Ke; Wu, Xiang; Yang, Canhui; Dai, Yuan; Zhang, Zhengyou; Guo, Chuan Fei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly stable flexible pressure sensors with a quasi-homogeneous composition and interlinked interfaces", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "E-skins often have poor interfaces that lead to unstable performances. Here, authors report e-skins with a quasi-homogeneous composition and bonded micro-structured interfaces, through which both the sensitivity and stability of the devices are improved. Electronic skins (e-skins) are devices that can respond to mechanical stimuli and enable robots to perceive their surroundings. A great challenge for existing e-skins is that they may easily fail under extreme mechanical conditions due to their multilayered architecture with mechanical mismatch and weak adhesion between the interlayers. Here we report a flexible pressure sensor with tough interfaces enabled by two strategies: quasi-homogeneous composition that ensures mechanical match of interlayers, and interlinked microconed interface that results in a high interfacial toughness of 390 J center dot m(-2). The tough interface endows the sensor with exceptional signal stability determined by performing 100,000 cycles of rubbing, and fixing the sensor on a car tread and driving 2.6 km on an asphalt road. The topological interlinks can be further extended to soft robot-sensor integration, enabling a seamless interface between the sensor and robot for highly stable sensing performance during manipulation tasks under complicated mechanical conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 274, "Times Cited, All Databases": 282, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 10", "Publication Year": 2022, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1317, "DOI": "10.1038/s41467-022-29093-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-29093-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000767467900015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, X; Ke, MK; Huang, GX; Chen, C; Chen, WX; Liang, K; Qu, YT; Yang, J; Wang, Y; Li, FT; Yu, HQ; Wu, YE", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Xiao; Ke, Ming-Kun; Huang, Gui-Xiang; Chen, Cai; Chen, Wenxing; Liang, Kuang; Qu, Yunteng; Yang, Jia; Wang, Ying; Li, Fengting; Yu, Han-Qing; Wu, Yuen", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Identification of Fenton-like active Cu sites by heteroatom modulation of electronic density", "Source Title": "PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Developing heterogeneous catalysts with atomically dispersed active sites is vital to boost peroxymonosulfate (PMS) activation for Fenton-like activity, but how to controllably adjust the electronic configuration of metal centers to further improve the activation kinetics still remains a great challenge. Herein, we report a systematic investigation into heteroatom-doped engineering for tuning the electronic structure of Cu-N-4 sites by integrating electron-deficient boron (B) or electron-rich phosphorus (P) heteroatoms into carbon substrate for PMS activation. The electron-depleted Cu-N-4/C-B is found to exhibit the most active oxidation capacity among the prepared Cu-N-4 single-atom catalysts, which is at the top rankings of the Cu-based catalysts and is superior to most of the state-of-the-art heterogeneous Fenton-like catalysts. Conversely, the electron-enriched Cu-N-4/C-P induces a decrease in PMS activation. Both experimental results and theoretical simulations unravel that the long-range interaction with B atoms decreases the electronic density of Cu active sites and down-shifts the d-band center, and thereby optimizes the adsorption energy for PMS activation. This study provides an approach to finely control the electronic structure of Cu-N-4 sites at the atomic level and is expected to guide the design of smart Fenton-like catalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 282, "Times Cited, All Databases": 284, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 22", "Publication Year": 2022, "Volume": 119, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "e2119492119", "DOI": "10.1073/pnas.2119492119", "DOI Link": "http://dx.doi.org/10.1073/pnas.2119492119", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000766924200016", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, SS; Sun, Y; Xue, HG; Braunstein, P; Huang, W; Pang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Shasha; Sun, Yan; Xue, Huaiguo; Braunstein, Pierre; Huang, Wei; Pang, Huan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dual-ligand and hard-soft-acid-base strategies to optimize metal-organic framework nullocrystals for stable electrochemical cycling performance", "Source Title": "NATIONAL SCIENCE REVIEW", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Most metal-organic frameworks (MOFs) hardly maintain their physical and chemical properties after exposure to acidic, neutral, or alkaline aqueous solutions, resulting in insufficient stability, therefore limiting their applications. Thus, the design and synthesis of stable size/morphology-controlled MOF nullocrystals is critical but challenging. In this study, dual-ligand and hard-soft-acid-base strategies were used to fabricate a variety of 3D pillared-layer [Ni(thiophene-2,5-dicarboxylate)(4,4'-bipyridine)](n) MOF nullocrystals (1D nullofibers, 2D nullosheets and 3D aggregates) with controllable morphology by varying the concentration of 4,4'-bipyridine and thus controlling the crystal growth direction. Owing to the shorter ion diffusion length, enhanced electron/ion transfer and strong interactions between thiophene-2,5-dicarboxylate and 4,4'-bipyridine, the 2D nullosheets showed much larger specific capacitance than 1D nullofibers and 3D aggregates. A single device with an output voltage as high as 3.0 V and exceptional cycling performance (95% of retention after 5000 cycles at 3 mA cm(-2)) was realized by configuring two aqueous asymmetric supercapacitive devices in series. The excellent cycling property and charge-discharge mechanism are consistent with the hard-soft-acid-base theory.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 284, "Times Cited, All Databases": 295, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 9", "Publication Year": 2022, "Volume": 9, "Issue": 7, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": "nwab197", "DOI": "10.1093/nsr/nwab197", "DOI Link": "http://dx.doi.org/10.1093/nsr/nwab197", "Book DOI": null, "Early Access Date": "AUG 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000837772000003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fu, JH; Fong, PWK; Liu, H; Huang, CS; Lu, XH; Lu, SR; Abdelsamie, M; Kodalle, T; Sutter-Fella, CM; Yang, Y; Li, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fu, Jiehao; Fong, Patrick W. K.; Liu, Heng; Huang, Chieh-Szu; Lu, Xinhui; Lu, Shirong; Abdelsamie, Maged; Kodalle, Tim; Sutter-Fella, Carolin M.; Yang, Yang; Li, Gang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "19.31% binary organic solar cell and low non-radiative recombination enabled by non-monotonic intermediate state transition", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Non-radiative recombination loss suppression is critical for boosting performance of organic solar cells. Here, the authors regulate self-organization of bulk-heterojunction in a non-monotonic manner, and achieve device efficiency over 19% with low non-radiative recombination loss down to 0.168 eV. Non-fullerene acceptors based organic solar cells represent the frontier of the field, owing to both the materials and morphology manipulation innovations. Non-radiative recombination loss suppression and performance boosting are in the center of organic solar cell research. Here, we developed a non-monotonic intermediate state manipulation strategy for state-of-the-art organic solar cells by employing 1,3,5-trichlorobenzene as crystallization regulator, which optimizes the film crystallization process, regulates the self-organization of bulk-heterojunction in a non-monotonic manner, i.e., first enhancing and then relaxing the molecular aggregation. As a result, the excessive aggregation of non-fullerene acceptors is avoided and we have achieved efficient organic solar cells with reduced non-radiative recombination loss. In PM6:BTP-eC9 organic solar cell, our strategy successfully offers a record binary organic solar cell efficiency of 19.31% (18.93% certified) with very low non-radiative recombination loss of 0.190 eV. And lower non-radiative recombination loss of 0.168 eV is further achieved in PM1:BTP-eC9 organic solar cell (19.10% efficiency), giving great promise to future organic solar cell research.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 399, "Times Cited, All Databases": 407, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 30", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-023-37526-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37526-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000961133600031", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, H; Yang, M; Ru, XN; Wang, GS; Yin, S; Peng, FG; Hong, CJ; Qu, MH; Lu, JX; Fang, L; Han, C; Procel, P; Isabella, O; Gao, PQ; Li, ZG; Xu, XX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Hao; Yang, Miao; Ru, Xiaoning; Wang, Genshun; Yin, Shi; Peng, Fuguo; Hong, Chengjian; Qu, Minghao; Lu, Junxiong; Fang, Liang; Han, Can; Procel, Paul; Isabella, Olindo; Gao, Pingqi; Li, Zhenguo; Xu, Xixiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Silicon heterojunction solar cells with up to 26.81% efficiency achieved by electrically optimized nullocrystalline-silicon hole contact layers", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Improvements in the power conversion efficiency of silicon heterojunction solar cells would consolidate their potential for commercialization. Now, Lin et al. demonstrate 26.81% efficiency devices using a p-doped nullocrystalline silicon and low-sheet-resistance transparent conductive oxide contact layer. Silicon heterojunction (SHJ) solar cells have reached high power conversion efficiency owing to their effective passivating contact structures. Improvements in the optoelectronic properties of these contacts can enable higher device efficiency, thus further consolidating the commercial potential of SHJ technology. Here we increase the efficiency of back junction SHJ solar cells with improved back contacts consisting of p-type doped nullocrystalline silicon and a transparent conductive oxide with a low sheet resistance. The electrical properties of the hole-selective contact are analysed and compared with a p-type doped amorphous silicon contact. We demonstrate improvement in the charge carrier transport and a low contact resistivity (<5 m ohm cm(2)). Eventually, we report a series of certified power conversion efficiencies of up to 26.81% and fill factors up to 86.59% on industry-grade silicon wafers (274 cm(2), M6 size).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 347, "Times Cited, All Databases": 357, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 8, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 789, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41560-023-01255-2", "DOI Link": "http://dx.doi.org/10.1038/s41560-023-01255-2", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000984178200002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liang, Z; Zhang, Y; Xu, HF; Chen, WJ; Liu, BY; Zhang, JY; Zhang, H; Wang, ZH; Kang, DH; Zeng, JR; Gao, XY; Wang, QS; Hu, HJ; Zhou, HM; Cai, XB; Tian, XY; Reiss, P; Xu, BM; Kirchartz, T; Xiao, ZG; Dai, SY; Park, NG; Ye, JJ; Pan, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liang, Zheng; Zhang, Yong; Xu, Huifen; Chen, Wenjing; Liu, Boyuan; Zhang, Jiyao; Zhang, Hui; Wang, Zihan; Kang, Dong-Ho; Zeng, Jianrong; Gao, Xingyu; Wang, Qisheng; Hu, Huijie; Zhou, Hongmin; Cai, Xiangbin; Tian, Xingyou; Reiss, Peter; Xu, Baomin; Kirchartz, Thomas; Xiao, Zhengguo; Dai, Songyuan; Park, Nam-Gyu; Ye, Jiajiu; Pan, Xu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Homogenizing out-of-plane cation composition in perovskite solar cells", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite solar cells with the formula FA(1-x)CsxPbI(3), where FA is formamidinium, provide an attractive option for integrating high efficiency, durable stability and compatibility with scaled-up fabrication. Despite the incorporation of Cs cations, which could potentially enable a perfect perovskite lattice(1,2), the compositional inhomogeneity caused by A-site cation segregation is likely to be detrimental to the photovoltaic performance of the solar cells(3,4). Here we visualized the out-of-plane compositional inhomogeneity along the vertical direction across perovskite films and identified the underlying reasons for the inhomogeneity and its potential impact for devices. We devised a strategy using 1-(phenylsulfonyl)pyrrole to homogenize the distribution of cation composition in perovskite films. The resultant p-i-n devices yielded a certified steady-state photon-to-electron conversion efficiency of 25.2% and durable stability.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 415, "Times Cited, All Databases": 427, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 21", "Publication Year": 2023, "Volume": 624, "Issue": 7992, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 557, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-023-06784-0", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-06784-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001169177500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chong, LA; Gao, GP; Wen, JG; Li, HX; Xu, HP; Green, Z; Sugar, JD; Kropf, AJ; Xu, WQ; Lin, XM; Xu, H; Wang, LW; Liu, DJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chong, Lina; Gao, Guoping; Wen, Jianguo; Li, Haixia; Xu, Haiping; Green, Zach; Sugar, Joshua D.; Kropf, A. Jeremy; Xu, Wenqian; Lin, Xiao-Min; Xu, Hui; Wang, Lin-Wang; Liu, Di-Jia", "Book Author Full Names": null, "Group Authors": null, "Article Title": "La- and Mn-doped cobalt spinel oxygen evolution catalyst for proton exchange membrane electrolysis", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Discovery of earth-abundant electrocatalysts to replace iridium for the oxygen evolution reaction (OER) in a proton exchange membrane water electrolyzer (PEMWE) represents a critical step in reducing the cost for green hydrogen production. We report a nullofibrous cobalt spinel catalyst codoped with lanthanum (La) and manganese (Mn) prepared from a zeolitic imidazolate framework embedded in electrospun polymer fiber. The catalyst demonstrated a low overpotential of 353 millivolts at 10 milliamperes per square centimeter and a low degradation for OER over 360 hours in acidic electrolyte. A PEMWE containing this catalyst at the anode demonstrated a current density of 2000 milliamperes per square centimeter at 2.47 volts (Nafion 115 membrane) or 4000 milliamperes per square centimeter at 3.00 volts (Nafion 212 membrane) and low degradation in an accelerated stress test.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 332, "Times Cited, All Databases": 338, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 11", "Publication Year": 2023, "Volume": 380, "Issue": 6645, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 609, "End Page": 616, "Article Number": null, "DOI": "10.1126/science.ade1499", "DOI Link": "http://dx.doi.org/10.1126/science.ade1499", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000999020900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, ZW; Li, YZ; Xu, R; Zhou, WJ; Li, YB; Oyakhire, ST; Wu, YC; Xu, JW; Wang, HS; Yu, ZA; Boyle, DT; Huang, W; Ye, YS; Chen, H; Wan, JY; Bao, ZN; Chiu, W; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Zewen; Li, Yuzhang; Xu, Rong; Zhou, Weijiang; Li, Yanbin; Oyakhire, Solomon T.; Wu, Yecun; Xu, Jinwei; Wang, Hansen; Yu, Zhiao; Boyle, David T.; Huang, William; Ye, Yusheng; Chen, Hao; Wan, Jiayu; Bao, Zhenull; Chiu, Wah; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Capturing the swelling of solid-electrolyte interphase in lithium metal batteries", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although liquid-solid interfaces are foundational in broad areas of science, characterizing this delicate interface remains inherently difficult because of shortcomings in existing tools to access liquid and solid phases simultaneously at the nulloscale. This leads to substantial gaps in our understanding of the structure and chemistry of key interfaces in battery systems. We adopt and modify a thin film vitrification method to preserve the sensitive yet critical interfaces in batteries at native liquid electrolyte environments to enable cryo-electron microscopy and spectroscopy. We report substantial swelling of the solid-electrolyte interphase (SEI) on lithium metal anode in various electrolytes. The swelling behavior is dependent on electrolyte chemistry and is highly correlated to battery performance. Higher degrees of SEI swelling tend to exhibit poor electrochemical cycling.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 267, "Times Cited, All Databases": 289, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 7", "Publication Year": 2022, "Volume": 375, "Issue": 6576, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 66, "End Page": "+", "Article Number": "eabi8703", "DOI": "10.1126/science.abi8703", "DOI Link": "http://dx.doi.org/10.1126/science.abi8703", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000740261400041", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, D; Zhou, CK; Filatov, AS; Cho, WJ; Lagunas, F; Wang, MZ; Vaikuntanathan, S; Liu, C; Klie, RF; Talapin, DV", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Di; Zhou, Chenkun; Filatov, Alexander S.; Cho, Wooje; Lagunas, Francisco; Wang, Mingzhan; Vaikuntanathan, Suriyanarayanull; Liu, Chong; Klie, Robert F.; Talapin, Dmitri V.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct synthesis and chemical vapor deposition of 2D carbide and nitride MXenes", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Two-dimensional transition-metal carbides and nitrides (MXenes) are a large family of materials actively studied for various applications, especially in the field of energy storage. MXenes are commonly synthesized by etching the layered ternary compounds, called MAX phases. We demonstrate a direct synthetic route for scalable and atom-economic synthesis of MXenes, including compounds that have not been synthesized from MAX phases, by the reactions of metals and metal halides with graphite, methane, or nitrogen. The direct synthesis enables chemical vapor deposition growth of MXene carpets and complex spherulite-like morphologies that form through buckling and release of MXene carpet to expose fresh surface for further reaction. The directly synthesized MXenes showed excellent energy storage capacity for lithium-ion intercalation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 343, "Times Cited, All Databases": 360, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 24", "Publication Year": 2023, "Volume": 379, "Issue": 6638, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1242, "End Page": 1247, "Article Number": null, "DOI": "10.1126/science.add9204", "DOI Link": "http://dx.doi.org/10.1126/science.add9204", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000994409800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, CW; Wang, XM; Bi, EB; Jiang, FY; Park, SM; Li, Y; Chen, L; Wang, ZW; Zeng, LW; Chen, H; Liu, YJ; Grice, CR; Abudulimu, A; Chung, JH; Xian, YM; Zhu, T; Lai, HG; Chen, B; Ellingson, RJ; Fu, F; Ginger, DS; Song, ZN; Sargent, EH; Yan, YF", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Chongwen; Wang, Xiaoming; Bi, Enbing; Jiang, Fangyuan; Park, So Min; Li, You; Chen, Lei; Wang, Zaiwei; Zeng, Lewei; Chen, Hao; Liu, Yanjiang; Grice, Corey R.; Abudulimu, Abasi; Chung, Jaehoon; Xian, Yeming; Zhu, Tao; Lai, Huagui; Chen, Bin; Ellingson, Randy J.; Fu, Fan; Ginger, David S.; Song, Zhaoning; Sargent, Edward H.; Yan, Yanfa", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Rational design of Lewis base molecules for stable and efficient inverted perovskite solar cells", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Lewis base molecules that bind undercoordinated lead atoms at interfaces and grain boundaries (GBs) are known to enhance the durability of metal halide perovskite solar cells (PSCs). Using density functional theory calculations, we found that phosphine-containing molecules have the strongest binding energy among members of a library of Lewis base molecules studied herein. Experimentally, we found that the best inverted PSC treated with 1,3-bis(diphenylphosphino)propane (DPPP), a diphosphine Lewis base that passivates, binds, and bridges interfaces and GBs, retained a power conversion efficiency (PCE) slightly higher than its initial PCE of similar to 23% after continuous operation under simulated AM1.5 illumination at the maximum power point and at similar to 40 degrees C for >3500 hours. DPPP-treated devices showed a similar increase in PCE after being kept under open-circuit conditions at 85 degrees C for >1500 hours.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 347, "Times Cited, All Databases": 357, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 17", "Publication Year": 2023, "Volume": 379, "Issue": 6633, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 690, "End Page": 694, "Article Number": null, "DOI": "10.1126/science.ade3970", "DOI Link": "http://dx.doi.org/10.1126/science.ade3970", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001016371000012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, Y; Louisia, S; Yu, S; Jin, JB; Roh, I; Chen, CB; Guzman, MVF; Feijóo, J; Chen, PC; Wang, HS; Pollock, CJ; Huang, X; Shao, YT; Wang, C; Muller, DA; Abruña, HD; Yang, PD", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Yao; Louisia, Sheena; Yu, Sunmoon; Jin, Jianbo; Roh, Inwhan; Chen, Chubai; Fonseca Guzman, Maria V.; Feijoo, Julian; Chen, Peng-Cheng; Wang, Hongsen; Pollock, Christopher J.; Huang, Xin; Shao, Yu-Tsun; Wang, Cheng; Muller, David A.; Abruna, Hector D.; Yang, Peidong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Operando studies reveal active Cu nullograins for CO2 electroreduction", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbon dioxide electroreduction facilitates the sustainable synthesis of fuels and chemicals(1). Although Cu enables CO2-to-multicarbon product (C2+) conversion, the nature of the active sites under operating conditions remains elusive(2). Importantly, identifying active sites of high-performance Cu nullocatalysts necessitates nulloscale, time-resolved operando techniques(3-5). Here, we present a comprehensive investigation of the structural dynamics during the life cycle of Cu nullocatalysts. A 7 nm Cu nulloparticle ensemble evolves into metallic Cu nullograins during electrolysis before complete oxidation to single-crystal Cu2O nullocubes following post-electrolysis air exposure. Operando analytical and four-dimensional electrochemical liquid-cell scanning transmission electron microscopy shows the presence of metallic Cu nullograins under CO2 reduction conditions. Correlated high-energy-resolution time-resolved X-ray spectroscopy suggests that metallic Cu, rich in nullograin boundaries, supports undercoordinated active sites for C-C coupling. Quantitative structure-activity correlation shows that a higher fraction of metallic Cu nullograins leads to higher C2+ selectivity. A 7 nm Cu nulloparticle ensemble, with a unity fraction of active Cu nullograins, exhibits sixfold higher C2+ selectivity than the 18 nm counterpart with one-third of active Cu nullograins. The correlation of multimodal operando techniques serves as a powerful platform to advance our fundamental understanding of the complex structural evolution of nullocatalysts under electrochemical conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 400, "Times Cited, All Databases": 410, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 9", "Publication Year": 2023, "Volume": 614, "Issue": 7947, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 262, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-022-05540-0", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-05540-0", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000938818200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Merchant, A; Batzner, S; Schoenholz, SS; Aykol, M; Cheon, G; Cubuk, ED", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Merchant, Amil; Batzner, Simon; Schoenholz, Samuel S.; Aykol, Muratahan; Cheon, Gowoon; Cubuk, Ekin Dogus", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Scaling deep learning for materials discovery", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Novel functional materials enable fundamental breakthroughs across technological applications from clean energy to information processing1-11. From microchips to batteries and photovoltaics, discovery of inorganic crystals has been bottlenecked by expensive trial-and-error approaches. Concurrently, deep- learning models for language, vision and biology have showcased emergent predictive capabilities with increasing data and computation12-14. Here we show that graph networks trained at scale can reach unprecedented levels of generalization, improving the efficiency of materials discovery by an order of magnitude. Building on 48,000 stable crystals identified in continuing studies15-17, improved efficiency enables the discovery of 2.2 million structures below the current convex hull, many of which escaped previous human chemical intuition. Our work represents an order-of-magnitude expansion in stable materials known to humanity. Stable discoveries that are on the final convex hull will be made available to screen for technological applications, as we demonstrate for layered materials and solid-electrolyte candidates. Of the stable structures, 736 have already been independently experimentally realized. The scale and diversity of hundreds of millions of first-principles calculations also unlock modelling capabilities for downstream applications, leading in particular to highly accurate and robust learned interatomic potentials that can be used in condensed-phase molecular-dynamics simulations and high-fidelity zero-shot prediction of ionic conductivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 372, "Times Cited, All Databases": 397, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 7", "Publication Year": 2023, "Volume": 624, "Issue": 7990, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 80, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-023-06735-9", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-06735-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001169148800004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, S; Wu, JH; Zheng, MT; Jin, X; Shen, ZH; Li, ZH; Wang, YJ; Wang, Q; Wang, XB; Wei, H; Zhang, JW; Wang, P; Zhang, SQ; Yu, LY; Dong, LF; Zhu, QS; Zhang, HG; Lu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Shuo; Wu, Jianghua; Zheng, Mengting; Jin, Xin; Shen, Zihan; Li, Zhonghua; Wang, Yanjun; Wang, Quan; Wang, Xuebin; Wei, Hui; Zhang, Jiangwei; Wang, Peng; Zhang, Shanqing; Yu, Liyan; Dong, Lifeng; Zhu, Qingshan; Zhang, Huigang; Lu, Jun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Fe/Cu diatomic catalysts for electrochemical nitrate reduction to ammonia", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrochemical conversion of nitrate to ammonia offers an efficient approach to reducing nitrate pollutants and a potential technology for low-temperature and low-pressure ammonia synthesis. However, the process is limited by multiple competing reactions and NO3- adsorption on cathode surfaces. Here, we report a Fe/Cu diatomic catalyst on holey nitrogen-doped graphene which exhibits high catalytic activities and selectivity for ammonia production. The catalyst enables a maximum ammonia Faradaic efficiency of 92.51% (-0.3 V(RHE)) and a high NH3 yield rate of 1.08 mmol h(-1) mg(-1) (at - 0.5 V(RHE)). Computational and theoretical analysis reveals that a relatively strong interaction between NO3- and Fe/Cu promotes the adsorption and discharge of NO3- anions. Nitrogen-oxygen bonds are also shown to be weakened due to the existence of hetero-atomic dual sites which lowers the overall reaction barriers. The dual-site and hetero-atom strategy in this work provides a flexible design for further catalyst development and expands the electrocatalytic techniques for nitrate reduction and ammonia synthesis. Nitrate electroreduction to ammonia can decrease pollutants and produce high-value ammonia. Here, the authors design a Fe/Cu diatomic catalyst on nitrogen-doped graphene, which exhibits high catalytic activities of and selectivity for ammonia.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 280, "Times Cited, All Databases": 283, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 19", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3634, "DOI": "10.1038/s41467-023-39366-9", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-39366-9", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001015306500018", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, Z; Sun, XL; Zheng, XP; Li, B; Gao, DP; Zhang, SF; Wu, X; Li, S; Gong, JQ; Luther, JM; Li, ZA; Zhu, ZL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Zhen; Sun, Xianglang; Zheng, Xiaopeng; Li, Bo; Gao, Danpeng; Zhang, Shoufeng; Wu, Xin; Li, Shuai; Gong, Jianqiu; Luther, Joseph M.; Li, Zhong'an; Zhu, Zonglong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Stabilized hole-selective layer for high-performance inverted p-i-n perovskite solar cells", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "P-i-n geometry perovskite solar cells (PSCs) offer simplified fabrication, greater amenability to charge extraction layers, and low-temperature processing over n-i-p counterparts. Self-assembled monolayers (SAMs) can enhance the performance of p-i-n PSCs but ultrathin SAMs can be thermally unstable. We report a thermally robust hole-selective layer comprised of nickel oxide (NiOx) nulloparticle film with a surface-anchored (4-(3,11-dimethoxy-7H-dibenzo[c,g]carbazol-7-yl)butyl)phosphonic acid (MeO-4PADBC) SAM that can improve and stabilize the NiOx/perovskite interface. The energetic alignment and favorable contact and binding between NiOx/MeO-4PADBC and perovskite reduced the voltage deficit of PSCs with various perovskite compositions and led to strong interface toughening effects under thermal stress. The resulting 1.53-electron-volt devices achieved 25.6% certified power conversion efficiency and maintained >90% of their initial efficiency after continuously operating at 65 degrees Celsius for 1200 hours under 1-sun illumination.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 300, "Times Cited, All Databases": 311, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 20", "Publication Year": 2023, "Volume": 382, "Issue": 6668, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 284, "End Page": 289, "Article Number": null, "DOI": "10.1126/science.ade9637", "DOI Link": "http://dx.doi.org/10.1126/science.ade9637", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001138559400027", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hu, HJ; Huang, H; Li, MH; Gao, XX; Yin, L; Qi, RX; Wu, RS; Chen, XJ; Ma, YX; Shi, KR; Li, CH; Maus, TM; Huang, B; Lu, C; Lin, MY; Zhou, S; Lou, ZY; Gu, Y; Chen, YM; Lei, YS; Wang, XY; Wang, RT; Yue, WT; Yang, XY; Bian, YZ; Mu, J; Park, G; Xiang, S; Cai, SQ; Corey, PW; Wang, JS; Xu, S", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hu, Hongjie; Huang, Hao; Li, Mohan; Gao, Xiaoxiang; Yin, Lu; Qi, Ruixiang; Wu, Ray S.; Chen, Xiangjun; Ma, Yuxiang; Shi, Keren; Li, Chenghai; Maus, Timothy M.; Huang, Brady; Lu, Chengchangfeng; Lin, Muyang; Zhou, Sai; Lou, Zhiyuan; Gu, Yue; Chen, Yimu; Lei, Yusheng; Wang, Xinyu; Wang, Ruotao; Yue, Wentong; Yang, Xinyi; Bian, Yizhou; Mu, Jing; Park, Geonho; Xiang, Shu; Cai, Shengqiang; Corey, Paul W.; Wang, Joseph; Xu, Sheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A wearable cardiac ultrasound imager", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Continuous imaging of cardiac functions is highly desirable for the assessment of long-term cardiovascular health, detection of acute cardiac dysfunction and clinical management of critically ill or surgical patients(1-4). However, conventional non-invasive approaches to image the cardiac function cannot provide continuous measurements owing to device bulkiness(5-11), and existing wearable cardiac devices can only capture signals on the skin(12-16). Here we report a wearable ultrasonic device for continuous, real-time and direct cardiac function assessment. We introduce innovations in device design and material fabrication that improve the mechanical coupling between the device and human skin, allowing the left ventricle to be examined from different views during motion. We also develop a deep learning model that automatically extracts the left ventricular volume from the continuous image recording, yielding waveforms of key cardiac performance indices such as stroke volume, cardiac output and ejection fraction. This technology enables dynamic wearable monitoring of cardiac performance with substantially improved accuracy in various environments.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 285, "Times Cited, All Databases": 303, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 26", "Publication Year": 2023, "Volume": 613, "Issue": 7945, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41586-022-05498-z", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-05498-z", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000930959700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, Y; Deng, HC; Sha, XB; Chen, WJ; Wang, RZ; Chen, YH; Wu, D; Chu, JR; Kivshar, YS; Xiao, SM; Qiu, CW", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Yang; Deng, Huachun; Sha, Xinbo; Chen, Weijin; Wang, Ruize; Chen, Yu-Hang; Wu, Dong; Chu, Jiaru; Kivshar, Yuri S. S.; Xiao, Shumin; Qiu, Cheng-Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Observation of intrinsic chiral bound states in the continuum", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photons with spin angular momentum possess intrinsic chirality, which underpins many phenomena including nonlinear optics(1), quantum optics(2), topological photonics(3) and chiroptics(4). Intrinsic chirality is weak in natural materials, and recent theoretical proposals(5-7) aimed to enlarge circular dichroism by resonullt metasurfaces supporting bound states in the continuum that enhance substantially chiral light-matter interactions. Those insightful works resort to three-dimensional sophisticated geometries, which are too challenging to be realized for optical frequencies(8). Therefore, most of the experimental attempts(9-11) showing strong circular dichroism rely on false/extrinsic chirality by using either oblique incidence(9,10) or structural anisotropy(11). Here we report on the experimental realization of true/intrinsic chiral response with resonullt metasurfaces in which the engineered slant geometry breaks both in-plane and out-of-plane symmetries. Our result marks, to our knowledge, the first observation of intrinsic chiral bound states in the continuum with near-unity circular dichroism of 0.93 and a high quality factor exceeding 2,663 for visible frequencies. Our chiral metasurfaces may lead to a plethora of applications in chiral light sources and detectors, chiral sensing, valleytronics and asymmetric photocatalysis.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 286, "Times Cited, All Databases": 303, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 19", "Publication Year": 2023, "Volume": 613, "Issue": 7944, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 474, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-022-05467-6", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-05467-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000955590300008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, GX; Su, ZH; Canil, L; Hughes, D; Aldamasy, MH; Dagar, J; Trofimov, S; Wang, LY; Zuo, WW; Jeronimo-Rendon, JJ; Byranvand, MM; Wang, CY; Zhu, R; Zhang, ZH; Yang, F; Nasti, G; Naydenov, B; Tsoi, WC; Li, Z; Gao, XY; Wang, ZK; Jia, Y; Unger, E; Saliba, M; Li, M; Abate, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Guixiang; Su, Zhenhuang; Canil, Laura; Hughes, Declan; Aldamasy, Mahmoud H.; Dagar, Janardan; Trofimov, Sergei; Wang, Luyao; Zuo, Weiwei; Jeronimo-Rendon, Jose J.; Byranvand, Mahdi Malekshahi; Wang, Chenyue; Zhu, Rui; Zhang, Zuhong; Yang, Feng; Nasti, Giuseppe; Naydenov, Boris; Tsoi, Wing C.; Li, Zhe; Gao, Xingyu; Wang, Zhaokui; Jia, Yu; Unger, Eva; Saliba, Michael; Li, Meng; Abate, Antonio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly efficient p-i-n perovskite solar cells that endure temperature variations", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Daily temperature variations induce phase transitions and lattice strains in halide perovskites, challenging their stability in solar cells. We stabilized the perovskite black phase and improved solar cell performance using the ordered dipolar structure of beta-poly(1,1-difluoroethylene) to control perovskite film crystallization and energy alignment. We demonstrated p-i-n perovskite solar cells with a record power conversion efficiency of 24.6% over 18 square millimeters and 23.1% over 1 square centimeter, which retained 96 and 88% of the efficiency after 1000 hours of 1-sunmaximum power point tracking at 25 degrees and 75 degrees C, respectively. Devices under rapid thermal cycling between -60 degrees and +80 degrees C showed no sign of fatigue, demonstrating the impact of the ordered dipolar structure on the operational stability of perovskite solar cells.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 318, "Times Cited, All Databases": 326, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 27", "Publication Year": 2023, "Volume": 379, "Issue": 6630, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 399, "End Page": 403, "Article Number": null, "DOI": "10.1126/science.add7331", "DOI Link": "http://dx.doi.org/10.1126/science.add7331", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001058669200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, T; Song, Q; Liu, K; Liu, HY; Pan, JJ; Liu, W; Dai, L; Zhang, M; Wang, YX; Si, CL; Du, HS; Zhang, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Ting; Song, Qun; Liu, Kun; Liu, Huayu; Pan, Junjie; Liu, Wei; Dai, Lin; Zhang, Meng; Wang, Yaxuan; Si, Chuanling; Du, Haishun; Zhang, Kai", "Book Author Full Names": null, "Group Authors": null, "Article Title": "nullocellulose-Assisted Construction of Multifunctional MXene-Based Aerogels with Engineering Biomimetic Texture for Pressure Sensor and Compressible Electrode", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Multifunctional architecture with intriguing structural design is highly desired for realizing the promising performances in wearable sensors and flexible energy storage devices. Cellulose nullofiber (CNF) is employed for assisting in building conductive, hyperelastic, and ultralight Ti3C2Tx MXene hybrid aerogels with oriented tracheid-like texture. The biomimetic hybrid aerogels are constructed by a facile bidirectional freezing strategy with CNF, carbon nullotube (CNT), and MXene based on synergistic electrostatic interaction and hydrogen bonding. Entangled CNF and CNT mortars bonded with MXene bricks of the tracheid structure produce good interfacial binding, and superior mechanical strength (up to 80% compressibility and extraordinary fatigue resistance of 1000 cycles at 50% strain). Benefiting from the biomimetic texture, CNF/CNT/MXene aerogel shows ultralow density of 7.48 mg cm(-3) and excellent electrical conductivity (similar to 2400 S m(-1)). Used as pressure sensors, such aerogels exhibit appealing sensitivity performance with the linear sensitivity up to 817.3 kPa(-1), which affords their application in monitoring body surface information and detecting human motion. Furthermore, the aerogels can also act as electrode materials of compressive solid-state supercapacitors that reveal satisfactory electrochemical performance (849.2 mF cm(-2) at 0.8 mA cm(-2)) and superior long cycle compression performance (88% after 10,000 cycles at a compressive strain of 30%).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 274, "Times Cited, All Databases": 279, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 98, "DOI": "10.1007/s40820-023-01073-x", "DOI Link": "http://dx.doi.org/10.1007/s40820-023-01073-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000968816500005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, Z; Zhang, R; Wang, HY; Zhou, SY; Pan, ZY; Huang, YC; Sun, D; Tang, YG; Ji, XB; Amine, K; Shao, MH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Zheng; Zhang, Rui; Wang, Haiyan; Zhou, Siyu; Pan, Zhiyi; Huang, Yuancheng; Sun, Dan; Tang, Yougen; Ji, Xiaobo; Amine, Khalil; Shao, Minhua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Revealing the closed pore formation of waste wood-derived hard carbon for advanced sodium-ion battery", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Although the closed pore structure plays a key role in contributing low-voltage plateau capacity of hard carbon anode for sodium-ion batteries, the formation mechanism of closed pores is still under debate. Here, we employ waste wood-derived hard carbon as a template to systematically establish the formation mechanisms of closed pores and their effect on sodium storage performance. We find that the high crystallinity cellulose in nature wood decomposes to long-range carbon layers as the wall of closed pore, and the amorphous component can hinder the graphitization of carbon layer and induce the crispation of long-range carbon layers. The optimized sample demonstrates a high reversible capacity of 430 mAh g-1 at 20 mA g-1 (plateau capacity of 293 mAh g-1 for the second cycle), as well as good rate and stable cycling performances (85.4% after 400 cycles at 500 mA g-1). Deep insights into the closed pore formation will greatly forward the rational design of hard carbon anode with high capacity. It is essential to investigate the formation mechanism of closed pore, which contributes to low-voltage plateau capacity of hard carbon anode in sodium ion batteries. Herein, the authors explore the impact of wood precursor components and carbonization temperature on closed pore formation in hard carbon for enhanced battery performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 255, "Times Cited, All Databases": 268, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 27", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 6024, "DOI": "10.1038/s41467-023-39637-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-39637-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001095471200017", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhai, PL; Wang, C; Zhao, YY; Zhang, YX; Gao, JF; Sun, LC; Hou, JA", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhai, Panlong; Wang, Chen; Zhao, Yuanyuan; Zhang, Yanxue; Gao, Junfeng; Sun, Licheng; Hou, Jungang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Regulating electronic states of nitride/hydroxide to accelerate kinetics for oxygen evolution at large current density", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rational design efficient transition metal-based electrocatalysts for oxygen evolution reaction (OER) is critical for water splitting. However, industrial water-alkali electrolysis requires large current densities at low overpotentials, always limited by intrinsic activity. Herein, we report hierarchical bimetal nitride/hydroxide (NiMoN/NiFe LDH) array as model catalyst, regulating the electronic states and tracking the relationship of structure-activity. As-activated NiMoN/NiFe LDH exhibits the industrially required current density of 1000 mA cm(-2) at overpotential of 266 mV with 250 h stability for OER. Especially, in-situ electrochemical spectroscopic reveals that heterointerface facilitates dynamic structure evolution to optimize electronic structure. Operando electrochemical impedance spectroscopy implies accelerated OER kinetics and intermediate evolution due to fast charge transport. The OER mechanism is revealed by the combination of theoretical and experimental studies, indicating as-activated NiMoN/NiFe LDH follows lattice oxygen oxidation mechanism with accelerated kinetics. This work paves an avenue to develop efficient catalysts for industrial water electrolysis via tuning electronic states. Rational design of efficient electrocatalysts for oxygen evolution reaction is critical for water-alkali electrolysis. Here, the authors fabricate a NiMoN/NiFe layered double hydroxide and show the accelerated oxygen evolution kinetics are due to the heterointerface.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 266, "Times Cited, All Databases": 270, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 4", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1873, "DOI": "10.1038/s41467-023-37091-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37091-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000983843800002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shao, ZJ; Yin, TY; Jiang, JB; He, Y; Xiang, T; Zhou, SB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shao, Zijian; Yin, Tianyu; Jiang, Jinbo; He, Yang; Xiang, Tao; Zhou, Shaobing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Wound microenvironment self-adaptive hydrogel with efficient angiogenesis for promoting diabetic wound healing", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Neovascularization is critical to improve the diabetic microenvironment, deliver abundant nutrients to the wound and promote wound closure. However, the excess of oxidative stress impedes the healing process. Herein, a self-adaptive multifunctional hydrogel with self-healing property and injectability is fabricated through a boronic ester-based reaction between the phenylboronic acid groups of the 3-carboxyl-4-fluorophenylboronic acid -grafted quaternized chitosan and the hydroxyl groups of the polyvinyl alcohol, in which pro-angiogenic drug of desferrioxamine (DFO) is loaded in the form of gelatin microspheres (DFO@G). The boronic ester bonds of the hydrogel can self-adaptively react with hyperglycemic and hydrogen peroxide to alleviate oxidative stress and release DFO@G in the early phase of wound healing. A sustained release of DFO is then realized by responding to overexpressed matrix metalloproteinases. In a full-thickness diabetic wound model, the DFO@G loaded hydrogel accelerates angiogenesis by upregulating expression of hypoxia-inducible factor-1 and angiogenic growth factors, resulting in collagen deposition and rapid wound closure. This multifunctional hydrogel can not only self-adaptively change the microenvironment to a pro-healing state by decreasing oxidative stress, but also respond to matrix metalloproteinases to release DFO. The self-adaptive multifunctional hydrogel has a potential for treating diabetic wounds.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 296, "Times Cited, All Databases": 299, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 20, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 561, "End Page": 573, "Article Number": null, "DOI": "10.1016/j.bioactmat.2022.06.018", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2022.06.018", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000826897500002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Musaelian, A; Batzner, S; Johansson, A; Sun, LX; Owen, CJ; Kornbluth, M; Kozinsky, B", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Musaelian, Albert; Batzner, Simon; Johansson, Anders; Sun, Lixin; Owen, Cameron J.; Kornbluth, Mordechai; Kozinsky, Boris", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Learning local equivariant representations for large-scale atomistic dynamics", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A simultaneously accurate and computationally efficient parametrization of the potential energy surface of molecules and materials is a long-standing goal in the natural sciences. While atom-centered message passing neural networks (MPNNs) have shown remarkable accuracy, their information propagation has limited the accessible length-scales. Local methods, conversely, scale to large simulations but have suffered from inferior accuracy. This work introduces Allegro, a strictly local equivariant deep neural network interatomic potential architecture that simultaneously exhibits excellent accuracy and scalability. Allegro represents a many-body potential using iterated tensor products of learned equivariant representations without atom-centered message passing. Allegro obtains improvements over state-of-the-art methods on QM9 and revMD17. A single tensor product layer outperforms existing deep MPNNs and transformers on QM9. Furthermore, Allegro displays remarkable generalization to out-of-distribution data. Molecular simulations using Allegro recover structural and kinetic properties of an amorphous electrolyte in excellent agreement with ab-initio simulations. Finally, we demonstrate parallelization with a simulation of 100 million atoms. The paper presents a method that allows scaling machine learning interatomic potentials to extremely large systems, while at the same time retaining the remarkable accuracy and learning efficiency of deep equivariant models. This is obtained with an E(3)- equivariant neural network architecture that combines the high accuracy of equivariant neural networks with the scalability of local methods.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 253, "Times Cited, All Databases": 265, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 3", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 579, "DOI": "10.1038/s41467-023-36329-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36329-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000955633400011", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, YZ; Lu, RH; Tao, XF; Qiu, ZJ; Chen, GB; Yang, J; Zhao, Y; Feng, XL; Müllen, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Yazhou; Lu, Ruihu; Tao, Xiafang; Qiu, Zijie; Chen, Guangbo; Yang, Juan; Zhao, Yan; Feng, Xinliang; Muellen, Klaus", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boosting Oxygen Electrocatalytic Activity of Fe-N-C Catalysts by Phosphorus Incorporation", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Nitrogen-doped graphitic carbon materials hosting single-atom iron (Fe-N-C) are major non-precious metal catalysts for the oxygen reduction reaction (ORR). The nitrogen-coordinated Fe sites are described as the first coordination sphere. As opposed to the good performance in ORR, that in the oxygen evolution reaction (OER) is extremely poor due to the sluggish O-O coupling process, thus hampering the practical applications of rechargeable zinc (Zn)-air batteries. Herein, we succeed in boosting the OER activity of Fe-N-C by additionally incorporating phosphorus atoms into the second coordination sphere, here denoted as P/Fe-N-C. The resulting material exhibits excellent OER activity in 0.1 M KOH with an overpotential as low as 304 mV at a current density of 10 mA cm-2. Even more importantly, they exhibit a remarkably small ORR/OER potential gap of 0.63 V. Theoretical calculations using first-principles density functional theory suggest that the phosphorus enhances the electrocatalytic activity by balancing the *OOH/*O adsorption at the FeN4 sites. When used as an air cathode in a rechargeable Zn-air battery, P/Fe-N-C delivers a charge-discharge performance with a high peak power density of 269 mW cm-2, highlighting its role as the state-of-the-art bifunctional oxygen electrocatalyst.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 264, "Times Cited, All Databases": 267, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2023, "Volume": 145, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 3647, "End Page": 3655, "Article Number": null, "DOI": "10.1021/jacs.2c12933", "DOI Link": "http://dx.doi.org/10.1021/jacs.2c12933", "Book DOI": null, "Early Access Date": "FEB 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000928853600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, W; Dai, YH; Chen, RW; Xu, ZM; Li, JW; Zong, W; Li, HX; Li, Z; Zhang, ZY; Zhu, JX; Guo, F; Gao, X; Du, ZJ; Chen, JT; Wang, TL; He, GJ; Parkin, IP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Wei; Dai, Yuhang; Chen, Ruwei; Xu, Zhenming; Li, Jianwei; Zong, Wei; Li, Huangxu; Li, Zheng; Zhang, Zhenyu; Zhu, Jiexin; Guo, Fei; Gao, Xuan; Du, Zijuan; Chen, Jintao; Wang, Tianlei; He, Guanjie; Parkin, Ivan P.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Highly Reversible Zinc Metal Anode in a Dilute Aqueous Electrolyte Enabled by a pH Buffer Additive", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous zinc-ion batteries have drawn increasing attention due to the intrinsic safety, cost-effectiveness and high energy density. However, parasitic reactions and non-uniform dendrite growth on the Zn anode side impede their application. Herein, a multifunctional additive, ammonium dihydrogen phosphate (NHP), is introduced to regulate uniform zinc deposition and to suppress side reactions. The results show that the NH4+ tends to be preferably absorbed on the Zn surface to form a shielding effect and blocks the direct contact of water with Zn. Moreover, NH4+ and (H2PO4)(-) jointly maintain pH values of the electrode-electrolyte interface. Consequently, the NHP additive enables highly reversible Zn plating/stripping behaviors in Zn//Zn and Zn//Cu cells. Furthermore, the electrochemical performances of Zn//MnO2 full cells and Zn//active carbon (AC) capacitors are improved. This work provides an efficient and general strategy for modifying Zn plating/stripping behaviors and suppressing side reactions in mild aqueous electrolyte.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 263, "Times Cited, All Databases": 267, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 26", "Publication Year": 2023, "Volume": 62, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202212695", "DOI Link": "http://dx.doi.org/10.1002/anie.202212695", "Book DOI": null, "Early Access Date": "DEC 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000894095400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ding, HM; Li, YB; Li, M; Chen, K; Liang, K; Chen, GX; Lu, J; Palisaitis, J; Persson, POA; Eklund, P; Hultman, L; Du, SY; Chai, ZF; Gogotsi, Y; Huang, Q", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ding, Haoming; Li, Youbing; Li, Mian; Chen, Ke; Liang, Kun; Chen, Guoxin; Lu, Jun; Palisaitis, Justinas; Persson, Per O. A.; Eklund, Per; Hultman, Lars; Du, Shiyu; Chai, Zhifang; Gogotsi, Yury; Huang, Qing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Chemical scissor-mediated structural editing of layered transition metal carbides", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Intercalated layered materials offer distinctive properties and serve as precursors for important two-dimensional (2D) materials. However, intercalation of non-van der Waals structures, which can expand the family of 2D materials, is difficult. We report a structural editing protocol for layered carbides (MAX phases) and their 2D derivatives (MXenes). Gap-opening and species-intercalating stages were respectively mediated by chemical scissors and intercalants, which created a large family of MAX phases with unconventional elements and structures, as well as MXenes with versatile terminals. The removal of terminals in MXenes with metal scissors and then the stitching of 2D carbide nullosheets with atom intercalation leads to the reconstruction of MAX phases and a family of metal-intercalated 2D carbides, both of which may drive advances in fields ranging from energy to printed electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 265, "Times Cited, All Databases": 276, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 17", "Publication Year": 2023, "Volume": 379, "Issue": 6637, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1130, "End Page": 1135, "Article Number": null, "DOI": "10.1126/science.add5901", "DOI Link": "http://dx.doi.org/10.1126/science.add5901", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000959028800007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hossain, MK; Toki, GFI; Kuddus, A; Rubel, MHK; Hossain, MM; Bencherif, H; Rahman, MF; Islam, MR; Mushtaq, M", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hossain, M. Khalid; Toki, G. F. Ishraque; Kuddus, Abdul; Rubel, M. H. K.; Hossain, M. M.; Bencherif, H.; Rahman, Md. Ferdous; Islam, Md. Rasidul; Mushtaq, Muhammad", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An extensive study on multiple ETL and HTL layers to design and simulation of high-performance lead-free CsSnCl3-based perovskite solar cells", "Source Title": "SCIENTIFIC REPORTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Cesium tin chloride (CsSnCl3) is a potential and competitive absorber material for lead-free perovskite solar cells (PSCs). The full potential of CsSnCl3 not yet been realized owing to the possible challenges of defect-free device fabrication, non-optimized alignment of the electron transport layer (ETL), hole transport layer (HTL), and the favorable device configuration. In this work, we proposed several CsSnCl3-based solar cell (SC) configurations using one dimensional solar cell capacitance simulator (SCAPS-1D) with different competent ETLs like indium-gallium-zinc-oxide (IGZO), tin-dioxide (SnO2), tungsten disulfide (WS2), ceric dioxide (CeO2), titanium dioxide (TiO2), zinc oxide (ZnO), C-60, PCBM, and HTLs of cuprous oxide (Cu2O), cupric oxide (CuO), nickel oxide (NiO), vanadium oxide (V2O5), copper iodide (CuI), CuSCN, CuSbS2, Spiro MeOTAD, CBTS, CFTS, P3HT, PEDOT:PSS. Simulation results revealed that ZnO, TiO2, IGZO, WS2, PCBM, and C-60 ETLs-based halide perovskites with ITO/ETLs/CsSnCl3/CBTS/Au heterostructure exhibited outstanding photoconversion efficiency retaining nearest photovoltaic parameters values among 96 different configurations. Further, for the six best-performing configurations, the effect of the CsSnCl3 absorber and ETL thickness, series and shunt resistance, working temperature, impact of capacitance, Mott-Schottky, generation and recombination rate, current-voltage properties, and quantum efficiency on performance were assessed. We found that ETLs like TiO2, ZnO, and IGZO, with CBTS HTL can act as outstanding materials for the fabrication of CsSnCl3-based high efficiency (eta >= 22%) heterojunction SCs with ITO/ETL/CsSnCl3/CBTS/Au structure. The simulation results obtained by the SCAPS-1D for the best six CsSnCl3-perovskites SC configurations were compared by the wxAMPS (widget provided analysis of microelectronic and photonic structures) tool for further validation. Furthermore, the structural, optical and electronic properties along with electron charge density, and Fermi surface of the CsSnCl3 perovskite absorber layer were computed and analyzed using first-principle calculations based on density functional theory. Thus, this in-depth simulation paves a constructive research avenue to fabricate cost-effective, high-efficiency, and lead-free CsSnCl3 perovskite-based high-performance SCs for a lead-free green and pollution-free environment.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 262, "Times Cited, All Databases": 261, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 13", "Publication Year": 2023, "Volume": 13, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2521, "DOI": "10.1038/s41598-023-28506-2", "DOI Link": "http://dx.doi.org/10.1038/s41598-023-28506-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000984284300005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Park, SM; Wei, MY; Xu, J; Atapattu, HR; Eickemeyer, FT; Darabi, K; Grater, L; Yang, Y; Liu, C; Teale, S; Chen, B; Chen, H; Wang, TH; Zeng, LW; Maxwell, A; Wang, ZW; Rao, KR; Cai, ZY; Zakeeruddin, SM; Pham, JT; Risko, CM; Amassian, A; Kanatzidis, MG; Graham, KR; Grätzel, M; Sargent, EH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Park, So Min; Wei, Mingyang; Xu, Jian; Atapattu, Harindi R.; Eickemeyer, Felix T.; Darabi, Kasra; Grater, Luke; Yang, Yi; Liu, Cheng; Teale, Sam; Chen, Bin; Chen, Hao; Wang, Tonghui; Zeng, Lewei; Maxwell, Aidan; Wang, Zaiwei; Rao, Keerthan R.; Cai, Zhuoyun; Zakeeruddin, Shaik M.; Pham, Jonathan T.; Risko, Chad M.; Amassian, Aram; Kanatzidis, Mercouri G.; Graham, Kenneth R.; Gratzel, Michael; Sargent, Edward H.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Engineering ligand reactivity enables high-temperature operation of stable perovskite solar cells", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Perovskite solar cells (PSCs) consisting of interfacial two- and three-dimensional heterostructures that incorporate ammonium ligand intercalation have enabled rapid progress toward the goal of uniting performance with stability. However, as the field continues to seek ever-higher durability, additional tools that avoid progressive ligand intercalation are needed to minimize degradation at high temperatures. We used ammonium ligands that are nonreactive with the bulk of perovskites and investigated a library that varies ligand molecular structure systematically. We found that fluorinated aniliniums offer interfacial passivation and simultaneously minimize reactivity with perovskites. Using this approach, we report a certified quasi-steady-state power-conversion efficiency of 24.09% for inverted-structure PSCs. In an encapsulated device operating at 85 degrees C and 50% relative humidity, we document a 1560-hour T-85 at maximum power point under 1-sun illumination.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 247, "Times Cited, All Databases": 253, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 14", "Publication Year": 2023, "Volume": 381, "Issue": 6654, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": 209, "End Page": 215, "Article Number": null, "DOI": "10.1126/science.adi4107", "DOI Link": "http://dx.doi.org/10.1126/science.adi4107", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001058656200008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ji, GJ; Wang, JX; Liang, Z; Jia, K; Ma, J; Zhuang, ZF; Zhou, GM; Cheng, HM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ji, Guanjun; Wang, Junxiong; Liang, Zheng; Jia, Kai; Ma, Jun; Zhuang, Zhaofeng; Zhou, Guangmin; Cheng, Hui-Ming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Direct regeneration of degraded lithium-ion battery cathodes with a multifunctional organic lithium salt", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Sustainable recycle of spent Li ion batteries is an effective strategy to alleviate environmental concerns and support resource conservation. Here, authors report the direct regeneration of LiFePO4 cathode using multifunctional organic lithium salts, leading to high environmental and economic benefits. The recycling of spent lithium-ion batteries is an effective approach to alleviating environmental concerns and promoting resource conservation. LiFePO4 batteries have been widely used in electric vehicles and energy storage stations. Currently, lithium loss, resulting in formation of Fe(III) phase, is mainly responsible for the capacity fade of LiFePO4 cathode. Another factor is poor electrical conductivity that limits its rate capability. Here, we report the use of a multifunctional organic lithium salt (3,4-dihydroxybenzonitrile dilithium) to restore spent LiFePO4 cathode by direct regeneration. The degraded LiFePO4 particles are well coupled with the functional groups of the organic lithium salt, so that lithium fills vacancies and cyano groups create a reductive atmosphere to inhibit Fe(III) phase. At the same time, pyrolysis of the salt produces an amorphous conductive carbon layer that coats the LiFePO4 particles, which improves Li-ion and electron transfer kinetics. The restored LiFePO4 cathode shows good cycling stability and rate performance (a high capacity retention of 88% after 400 cycles at 5 C). This lithium salt can also be used to recover degraded transition metal oxide-based cathodes. A techno-economic analysis suggests that this strategy has higher environmental and economic benefits, compared with the traditional recycling methods.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 241, "Times Cited, All Databases": 251, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 3", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 584, "DOI": "10.1038/s41467-023-36197-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36197-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000955633400015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Szymanski, NJ; Rendy, B; Fei, YX; Kumar, RE; He, TJ; Milsted, D; McDermott, MJ; Gallant, M; Cubuk, ED; Merchant, A; Kim, H; Jain, A; Bartel, CJ; Persson, K; Zeng, Y; Ceder, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Szymanski, Nathan J.; Rendy, Bernardus; Fei, Yuxing; Kumar, Rishi E.; He, Tanjin; Milsted, David; McDermott, Matthew J.; Gallant, Max; Cubuk, Ekin Dogus; Merchant, Amil; Kim, Haegyeom; Jain, Anubhav; Bartel, Christopher J.; Persson, Kristin; Zeng, Yan; Ceder, Gerbrand", "Book Author Full Names": null, "Group Authors": null, "Article Title": "An autonomous laboratory for the accelerated synthesis of novel materials", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "To close the gap between the rates of computational screening and experimental realization of novel materials1,2, we introduce the A-Lab, an autonomous laboratory for the solid-state synthesis of inorganic powders. This platform uses computations, historical data from the literature, machine learning (ML) and active learning to plan and interpret the outcomes of experiments performed using robotics. Over 17 days of continuous operation, the A-Lab realized 41 novel compounds from a set of 58 targets including a variety of oxides and phosphates that were identified using large-scale ab initio phase-stability data from the Materials Project and Google DeepMind. Synthesis recipes were proposed by natural-language models trained on the literature and optimized using an active-learning approach grounded in thermodynamics. Analysis of the failed syntheses provides direct and actionable suggestions to improve current techniques for materials screening and synthesis design. The high success rate demonstrates the effectiveness of artificial-intelligence-driven platforms for autonomous materials discovery and motivates further integration of computations, historical knowledge and robotics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 237, "Times Cited, All Databases": 250, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC 7", "Publication Year": 2023, "Volume": 624, "Issue": 7990, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 86, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-023-06734-w", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-06734-w", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001169148800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, N; Yang, YF; Wang, CX; Wu, QL; Pan, F; Zhang, RA; Liu, JR; Zeng, ZH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Na; Yang, Yunfei; Wang, Changxian; Wu, Qilei; Pan, Fei; Zhang, Runa; Liu, Jiurong; Zeng, Zhihui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrathin Cellulose nullofiber Assisted Ambient-Pressure-Dried, Ultralight, Mechanically Robust, Multifunctional MXene Aerogels", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Ambient-pressure-dried (APD) preparation of transition metal carbide/nitrides (MXene) aerogels is highly desirable yet remains highly challenging. Here, ultrathin, high-strength-to-weight-ratio, renewable cellulose nullofibers (CNFs) are efficiently utilized to assist in the APD preparation of ultralight yet robust, highly conductive, large-area MXene-based aerogels via a facile, energy-efficient, eco-friendly, and scalable freezing-exchanging-drying approach. The strong interactions of large-aspect-ratio CNF and MXene as well as the biomimetic nacre-like microstructure induce high mechanical strength and stability to avoid the structure collapse of aerogels in the APD process. Abundant functional groups of CNFs facilitate the chemical crosslinking of MXene-based aerogels, significantly improving the hydrophobicity, water resistance, and even oxidation stability. The ultrathin, 1D nature of the CNF renders the minimal MXenes' interlayered gaps and numerous heterogeneous interfaces, yielding the excellent conductivity and electromagnetic interference (EMI) shielding performance of aerogels. The synergies of the MXene, CNF, and abundant pores efficiently improve the EMI shielding performance, photothermal conversion, and absorption of viscous crude oil. This work shows great promises of the APD, multifunctional MXene-based aerogels in electromagnetic protection or compatibility, thermal therapy, and oil-water separation applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 243, "Times Cited, All Databases": 247, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 35, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202207969", "DOI Link": "http://dx.doi.org/10.1002/adma.202207969", "Book DOI": null, "Early Access Date": "NOV 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000891050600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cheng, SM; Lou, ZR; Zhang, L; Guo, HT; Wang, ZT; Guo, CF; Fukuda, K; Ma, SH; Wang, GQ; Someya, T; Cheng, HM; Xu, XM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cheng, Simin; Lou, Zirui; Zhang, Lan; Guo, Haotian; Wang, Zitian; Guo, Chuanfei; Fukuda, Kenjiro; Ma, Shaohua; Wang, Guoqing; Someya, Takao; Cheng, Hui-Ming; Xu, Xiaomin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultrathin Hydrogel Films toward Breathable Skin-Integrated Electronics", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "On-skin electronics that offer revolutionary capabilities in personalized diagnosis, therapeutics, and human-machine interfaces require seamless integration between the skin and electronics. A common question remains whether an ideal interface can be introduced to directly bridge thin-film electronics with the soft skin, allowing the skin to breathe freely and the skin-integrated electronics to function stably. Here, an ever-thinnest hydrogel is reported that is compliant to the glyphic lines and subtle minutiae on the skin without forming air gaps, produced by a facile cold-lamination method. The hydrogels exhibit high water-vapor permeability, allowing nearly unimpeded transepidermal water loss and free breathing of the skin underneath. Hydrogel-interfaced flexible (opto)electronics without causing skin irritation or accelerated device performance deterioration are demonstrated. The long-term applicability is recorded for over one week. With combined features of extreme mechanical compliance, high permeability, and biocompatibility, the ultrathin hydrogel interface promotes the general applicability of skin-integrated electronics.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 216, "Times Cited, All Databases": 221, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 35, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202206793", "DOI Link": "http://dx.doi.org/10.1002/adma.202206793", "Book DOI": null, "Early Access Date": "NOV 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000888665600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deng, BW; Zhong, PC; Jun, K; Riebesell, J; Han, K; Bartel, CJ; Ceder, G", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deng, Bowen; Zhong, Peichen; Jun, KyuJung; Riebesell, Janosh; Han, Kevin; Bartel, Christopher J.; Ceder, Gerbrand", "Book Author Full Names": null, "Group Authors": null, "Article Title": "CHGNet as a pretrained universal neural network potential for charge-informed atomistic modelling", "Source Title": "NATURE MACHINE INTELLIGENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Large-scale simulations with complex electron interactions remain one of the greatest challenges for atomistic modelling. Although classical force fields often fail to describe the coupling between electronic states and ionic rearrangements, the more accurate ab initio molecular dynamics suffers from computational complexity that prevents long-time and large-scale simulations, which are essential to study technologically relevant phenomena. Here we present the Crystal Hamiltonian Graph Neural Network (CHGNet), a graph neural network-based machine-learning interatomic potential (MLIP) that models the universal potential energy surface. CHGNet is pretrained on the energies, forces, stresses and magnetic moments from the Materials Project Trajectory Dataset, which consists of over 10 years of density functional theory calculations of more than 1.5 million inorganic structures. The explicit inclusion of magnetic moments enables CHGNet to learn and accurately represent the orbital occupancy of electrons, enhancing its capability to describe both atomic and electronic degrees of freedom. We demonstrate several applications of CHGNet in solid-state materials, including charge-informed molecular dynamics in LixMnO2, the finite temperature phase diagram for LixFePO4 and Li diffusion in garnet conductors. We highlight the significance of charge information for capturing appropriate chemistry and provide insights into ionic systems with additional electronic degrees of freedom that cannot be observed by previous MLIPs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 220, "Times Cited, All Databases": 230, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2023, "Volume": 5, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 1031, "End Page": 1041, "Article Number": null, "DOI": "10.1038/s42256-023-00716-3", "DOI Link": "http://dx.doi.org/10.1038/s42256-023-00716-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Computer Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001085170400007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Jin, HY; Liu, XY; An, PF; Tang, C; Yu, HM; Zhang, QH; Peng, HJ; Gu, L; Zheng, Y; Song, TS; Davey, K; Paik, U; Dong, JC; Qiao, SZ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Jin, Huanyu; Liu, Xinyan; An, Pengfei; Tang, Cheng; Yu, Huimin; Zhang, Qinghua; Peng, Hong-Jie; Gu, Lin; Zheng, Yao; Song, Taeseup; Davey, Kenneth; Paik, Ungyu; Dong, Juncai; Qiao, Shi-Zhang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dynamic rhenium dopant boosts ruthenium oxide for durable oxygen evolution", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Heteroatom-doping is a practical means to boost RuO2 for acidic oxygen evolution reaction (OER). However, a major drawback is conventional dopants have static electron redistribution. Here, we report that Re dopants in Re0.06Ru0.94O2 undergo a dynamic electron accepting-donating that adaptively boosts activity and stability, which is different from conventional dopants with static dopant electron redistribution. We show Re dopants during OER, (1) accept electrons at the on-site potential to activate Ru site, and (2) donate electrons back at large overpotential and prevent Ru dissolution. We confirm via in situ characterizations and first-principle computation that the dynamic electron-interaction between Re and Ru facilitates the adsorbate evolution mechanism and lowers adsorption energies for oxygen intermediates to boost activity and stability of Re0.06Ru0.94O2. We demonstrate a high mass activity of 500 A g(cata.)(-1) (7811 A g(Re-Ru)(-1)) and a high stability number of S-number = 4.0 x 10(6) n(oxygen) n(Ru)(-1) to outperform most electrocatalysts. We conclude that dynamic dopants can be used to boost activity and stability of active sites and therefore guide the design of adaptive electrocatalysts for clean energy conversions. RuO2 is a promising anode catalyst for proton exchange membrane water electrolyzers but suffers from poor catalytic stability. Here the authors present a rhenium-doped RuO2 with a unique dynamic electron accepting-donating that adaptively boosts activity and stability in acidic water oxidation.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 218, "Times Cited, All Databases": 225, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 21", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 354, "DOI": "10.1038/s41467-023-35913-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-35913-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000953220800003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, CY; Xia, JL; Cui, CY; Pollard, TP; Vatamanu, J; Faraone, A; Dura, JA; Tyagi, M; Kattan, A; Thimsen, E; Xu, JJ; Song, WT; Hu, EY; Ji, X; Hou, SY; Zhang, XY; Ding, MS; Hwang, S; Su, D; Ren, Y; Yang, XQ; Wang, H; Borodin, O; Wang, CS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Chongyin; Xia, Jiale; Cui, Chunyu; Pollard, Travis P.; Vatamanu, Jenel; Faraone, Antonio; Dura, Joseph A.; Tyagi, Madhusudan; Kattan, Alex; Thimsen, Elijah; Xu, Jijian; Song, Wentao; Hu, Enyuan; Ji, Xiao; Hou, Singyuk; Zhang, Xiyue; Ding, Michael S. S.; Hwang, Sooyeon; Su, Dong; Ren, Yang; Yang, Xiao-Qing; Wang, Howard; Borodin, Oleg; Wang, Chunsheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "All-temperature zinc batteries with high-entropy aqueous electrolyte", "Source Title": "NATURE SUSTAINABILITY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrification of transportation and rising demand for grid energy storage continue to build momentum around batteries across the globe. However, the supply chain of Li-ion batteries is exposed to the increasing challenges of resourcing essential and scarce materials. Therefore, incentives to develop more sustainable battery chemistries are growing. Here we show an aqueous ZnCl2 electrolyte with introduced LiCl as supporting salt. Once the electrolyte is optimized to Li2ZnCl4.9H(2)O, the assembled Zn-air battery can sustain stable cycling over the course of 800 hours at a current density of 0.4 mA cm-2 between -60 degrees C and +80 degrees C, with 100% Coulombic efficiency for Zn stripping/plating. Even at -60 degrees C, > 80% of room-temperature power density can be retained. Advanced characterization and theoretical calculations reveal a high-entropy solvation structure that is responsible for the excellent performance. The strong acidity allows ZnCl2 to accept donated Cl- ions to form ZnCl42- anions, while water molecules remain within the free solvent network at low salt concentration or coordinate with Li ions. Our work suggests an effective strategy for the rational design of electrolytes that could enable next-generation Zn batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 215, "Times Cited, All Databases": 223, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 6, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 325, "End Page": 335, "Article Number": null, "DOI": "10.1038/s41893-022-01028-x", "DOI Link": "http://dx.doi.org/10.1038/s41893-022-01028-x", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000913832800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wu, D; Guo, CG; Zeng, LH; Ren, XY; Shi, ZF; Wen, L; Chen, Q; Zhang, M; Li, XJ; Shan, CX; Jie, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wu, Di; Guo, Chenguang; Zeng, Longhui; Ren, Xiaoyan; Shi, Zhifeng; Wen, Long; Chen, Qin; Zhang, Meng; Li, Xin Jian; Shan, Chong-Xin; Jie, Jiansheng", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Phase-controlled van der Waals growth of wafer-scale 2D MoTe2 layers for integrated high-sensitivity broadband infrared photodetection", "Source Title": "LIGHT-SCIENCE & APPLICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Being capable of sensing broadband infrared (IR) light is vitally important for wide-ranging applications from fundamental science to industrial purposes. Two-dimensional (2D) topological semimetals are being extensively explored for broadband IR detection due to their gapless electronic structure and the linear energy dispersion relation. However, the low charge separation efficiency, high noise level, and on-chip integration difficulty of these semimetals significantly hinder their further technological applications. Here, we demonstrate a facile thermal-assisted tellurization route for the van der Waals (vdW) growth of wafer-scale phase-controlled 2D MoTe2 layers. Importantly, the type-II Weyl semimetal 1T'-MoTe2 features a unique orthorhombic lattice structure with a broken inversion symmetry, which ensures efficient carrier transportation and thus reduces the carrier recombination. This characteristic is a key merit for the well-designed 1T'-MoTe2/Si vertical Schottky junction photodetector to achieve excellent performance with an ultrabroadband detection range of up to 10.6 mu m and a large room temperature specific detectivity of over 10(8) Jones in the mid-infrared (MIR) range. Moreover, the large-area synthesis of 2D MoTe2 layers enables the demonstration of high-resolution uncooled MIR imaging capability by using an integrated device array. This work provides a new approach to assembling uncooled IR photodetectors based on 2D materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 215, "Times Cited, All Databases": 221, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 2", "Publication Year": 2023, "Volume": 12, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41377-022-01047-5", "DOI Link": "http://dx.doi.org/10.1038/s41377-022-01047-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Optics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000906375800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qiao, LP; Liang, YP; Chen, JY; Huang, Y; Alsareii, SA; Alamri, AM; Harraz, FA; Guo, BL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qiao, Lipeng; Liang, Yongping; Chen, Jueying; Huang, Ying; Alsareii, Saeed A.; Alamri, Abdulrahman Manaa; Harraz, Farid A.; Guo, Baolin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Antibacterial conductive self-healing hydrogel wound dressing with dual dynamic bonds promotes infected wound healing", "Source Title": "BIOACTIVE MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In clinical applications, there is a lack of wound dressings that combine efficient resistance to drug-resistant bacteria with good self-healing properties. In this study, a series of adhesive self-healing conductive antibacte-rial hydrogel dressings based on oxidized sodium alginate-grafted dopamine/carboxymethyl chitosan/Fe3+ (OSD/CMC/Fe hydrogel)/polydopamine-encapsulated poly(thiophene-3-acetic acid) (OSD/CMC/Fe/PA hydro-gel) were prepared for the repair of infected wound. The Schiff base and Fe3+ coordination bonds of the hydrogel structure are dynamic bonds that can be repaired automatically after the hydrogel network is disrupted. Macroscopically, the hydrogel exhibits self-healing properties, allowing the hydrogel dressing to adapt to complex wound surfaces. The OSD/CMC/Fe/PA hydrogel showed good conductivity and photothermal anti-bacterial properties under near-infrared (NIR) light irradiation. In addition, the hydrogels exhibit tunable rheological properties, suitable mechanical properties, antioxidant properties, tissue adhesion properties and hemostatic properties. Furthermore, all hydrogel dressings improved wound healing in the infected full-thickness defect skin wound repair test in mice. The wound size repaired by OSD/CMC/Fe/PA3 hydrogel + NIR was much smaller (12%) than the control group treated with TegadermTM film after 14 days. In conclusion, the hydrogels have high antibacterial efficiency, suitable conductivity, great self-healing properties, good biocompatibility, hemostasis and antioxidant properties, making them promising candidates for wound healing dressings for the treatment of infected skin wounds.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 231, "Times Cited, All Databases": 237, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 30, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 129, "End Page": 141, "Article Number": null, "DOI": "10.1016/j.bioactmat.2023.07.015", "DOI Link": "http://dx.doi.org/10.1016/j.bioactmat.2023.07.015", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Engineering; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001053110100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeng, YH; Xia, ZC; Kang, KF; Zhu, JC; Knueppel, P; Vaswani, C; Watanabe, K; Taniguchi, T; Mak, KF; Shan, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeng, Yihang; Xia, Zhengchao; Kang, Kaifei; Zhu, Jiacheng; Knueppel, Patrick; Vaswani, Chirag; Watanabe, Kenji; Taniguchi, Takashi; Mak, Kin Fai; Shan, Jie", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thermodynamic evidence of fractional Chern insulator in moiré MoTe2", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Chern insulators, which are the lattice analogues of the quantum Hall states, can potentially manifest high-temperature topological orders at zero magnetic field to enable next-generation topological quantum devices(1-3). Until now, integer Chern insulators have been experimentally demonstrated in several systems at zero magnetic field(3-8), whereas fractional Chern insulators have been reported in only graphene-based systems under a finite magnetic field(9,10). The emergence of semiconductor moire materials(11), which support tunable topological flat bands(12,13), provides an opportunity to realize fractional Chern insulators(13-16). Here we report thermodynamic evidence of both integer and fractional Chern insulators at zero magnetic field in small-angle twisted bilayer MoTe2 by combining the local electronic compressibility and magneto-optical measurements. At hole filling factor nu = 1 and 2/3, the system is incompressible and spontaneously breaks time-reversal symmetry. We show that they are integer and fractional Chern insulators, respectively, from the dispersion of the state in the filling factor with an applied magnetic field. We further demonstrate electric-field-tuned topological phase transitions involving the Chern insulators. Our findings pave the way for the demonstration of quantized fractional Hall conductance and anyonic excitation and braiding17 in semiconductor moire materials.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 213, "Times Cited, All Databases": 221, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT 5", "Publication Year": 2023, "Volume": 622, "Issue": 7981, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41586-023-06452-3", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-06452-3", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001078346100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Qin, CC; Wu, XD; Tang, L; Chen, XH; Li, M; Mou, Y; Su, B; Wang, SB; Feng, CY; Liu, JW; Yuan, XZ; Zhao, YL; Wang, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Qin, Chencheng; Wu, Xiaodong; Tang, Lin; Chen, Xiaohong; Li, Miao; Mou, Yi; Su, Bo; Wang, Sibo; Feng, Chengyang; Liu, Jiawei; Yuan, Xingzhong; Zhao, Yanli; Wang, Hou", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Dual donor-acceptor covalent organic frameworks for hydrogen peroxide photosynthesis", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Constructing photocatalytically active and stable covalent organic frameworks containing both oxidative and reductive reaction centers remain a challenge. In this study, benzotrithiophene-based covalent organic frameworks with spatially separated redox centers are rationally designed for the photocatalytic production of hydrogen peroxide from water and oxygen without sacrificial agents. The triazine-containing framework demonstrates high selectivity for H2O2 photogeneration, with a yield rate of 2111 mu Mh(-1) (21.11 mu mol h(-1) and 1407 mu mol g(-1) h(-1)) and a solar-to-chemical conversion efficiency of 0.296%. Codirectional charge transfer and large energetic differences between linkages and linkers are verified in the double donor-acceptor structures of periodic frameworks. The active sites are mainly concentrated on the electron-acceptor fragments near the imine bond, which regulate the electron distribution of adjacent carbon atoms to optimally reduce the Gibbs free energy of O-2* and OOH* intermediates during the formation of H2O2.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 213, "Times Cited, All Databases": 216, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 28", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 5238, "DOI": "10.1038/s41467-023-40991-7", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-40991-7", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001057573200013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kang, X; Yang, FN; Zhang, ZY; Liu, HM; Ge, SY; Hu, SQ; Li, SH; Luo, YT; Yu, QM; Liu, ZB; Wang, Q; Ren, WC; Sun, CH; Cheng, HM; Liu, BL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kang, Xin; Yang, Fengning; Zhang, Zhiyuan; Liu, Heming; Ge, Shiyu; Hu, Shuqi; Li, Shaohai; Luo, Yuting; Yu, Qiangmin; Liu, Zhibo; Wang, Qiang; Ren, Wencai; Sun, Chenghua; Cheng, Hui-Ming; Liu, Bilu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A corrosion-resistant RuMoNi catalyst for efficient and long-lasting seawater oxidation and anion exchange membrane electrolyzer", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Direct seawater electrolysis is promising for sustainable hydrogen production but suffers severe side reactions and corrosion. Here, the authors report a corrosion-resistant electrocatalyst with in situ-formed chloride-ion-repelling cation layer for efficient and long-lasting seawater oxidation. Direct seawater electrolysis is promising for sustainable hydrogen gas (H-2) production. However, the chloride ions in seawater lead to side reactions and corrosion, which result in a low efficiency and poor stability of the electrocatalyst and hinder the use of seawater electrolysis technology. Here we report a corrosion-resistant RuMoNi electrocatalyst, in which the in situ-formed molybdate ions on its surface repel chloride ions. The electrocatalyst works stably for over 3000 h at a high current density of 500 mA cm(-2) in alkaline seawater electrolytes. Using the RuMoNi catalyst in an anion exchange membrane electrolyzer, we report an energy conversion efficiency of 77.9% and a current density of 1000 mA cm(-2) at 1.72 V. The calculated price per gallon of gasoline equivalent (GGE) of the H-2 produced is $ 0.85, which is lower than the 2026 technical target of $ 2.0/GGE set by the United Stated Department of Energy, thus, suggesting practicability of the technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 216, "Times Cited, All Databases": 216, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 17", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3607, "DOI": "10.1038/s41467-023-39386-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-39386-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001009499200009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kuang, PY; Ni, ZR; Zhu, BC; Lin, Y; Yu, JG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kuang, Panyong; Ni, Zhenrui; Zhu, Bicheng; Lin, Yue; Yu, Jiaguo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Modulating the d-Band Center Enables Ultrafine Pt3Fe Alloy nulloparticles for pH-Universal Hydrogen Evolution Reaction", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "By providing dual active sites to synergistically accelerate H2O dissociation and H+ reduction, ordered intermetallic alloys usually show extraordinary performance for pH-universal hydrogen evolution reaction (HER). Herein, activated N-doped mesoporous carbon spheres supported intermetallic Pt3Fe alloys (Pt3Fe/NMCS-A), as a highly-efficient electrocatalyst for pH-universal HER, are reported. The Pt3Fe/NMCS-A exhibits low overpotentials (eta(10)) of 13, 29, and 48 mV to deliver 10 mA cm(-2) in 0.5 m H2SO4, 1.0 m KOH, and 1.0 m phosphate buffered solution (PBS), respectively, as well as robust stability to maintain the overall catalytic performances. Theoretical studies reveal that the strong Pt 5d-Fe 3d orbital electronic interactions negatively shift the d-band center (epsilon(d)) of Pt 5d orbital, resulting in reduced H* adsorption energy of Pt sites and enhanced acidic HER activity. With Pt and Fe acting as co-adsorption sites for H* and *OH intermediates, respectively, a low energy barrier is required for Pt3Fe/NMCS-A to dissociate H2O to afford H* intermediates, which greatly promotes the H* adsorption and H-2 formation in alkaline and neutral conditions. The synthetic strategy is further extended to the synthesis of Pt3Co and Pt3Ni alloys with excellent HER activity in pH-universal electrolytes, demonstrating the great potential of these Pt-based alloys for practical applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 209, "Times Cited, All Databases": 216, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "OCT", "Publication Year": 2023, "Volume": 35, "Issue": 41, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2303030, "DOI": "10.1002/adma.202303030", "DOI Link": "http://dx.doi.org/10.1002/adma.202303030", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001166720600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Sun, X; Qiu, Y; Jiang, B; Chen, ZY; Zhao, CH; Zhou, H; Yang, L; Fan, LS; Zhang, Y; Zhang, NQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Sun, Xun; Qiu, Yue; Jiang, Bo; Chen, Zhaoyu; Zhao, Chenghao; Zhou, Hao; Yang, Li; Fan, Lishuang; Zhang, Yu; Zhang, Naiqing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Isolated Fe-Co heteronuclear diatomic sites as efficient bifunctional catalysts for high-performance lithium-sulfur batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The slow redox kinetics of polysulfides and the difficulties in decomposition of Li2S are two serious obstacles to lithium-sulfur batteries. Here, the authors report an isolated Fe-Co heteronuclear diatomic catalyst to achieve high efficiency bifunctional catalysis for lithium-sulfur batteries. The slow redox kinetics of polysulfides and the difficulties in decomposition of Li2S during the charge and discharge processes are two serious obstacles to the practical application of lithium-sulfur batteries. Herein, we construct the Fe-Co diatomic catalytic materials supported by hollow carbon spheres to achieve high-efficiency catalysis for the conversion of polysulfides and the decomposition of Li2S simultaneously. The Fe atom center is beneficial to accelerate the discharge reaction process, and the Co atom center is favorable for charging process. Theoretical calculations combined with experiments reveal that this excellent bifunctional catalytic activity originates from the diatomic synergy between Fe and Co atom. As a result, the assembled cells exhibit the high rate performance (the discharge specific capacity achieves 688 mAh g(-1) at 5 C) and the excellent cycle stability (the capacity decay rate is 0.018% for 1000 cycles at 1 C).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 205, "Times Cited, All Databases": 207, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 18", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 291, "DOI": "10.1038/s41467-022-35736-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-35736-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001006189100004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, GX; Gong, ZG; Luo, XL; Chen, LH; Shuai, L", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Guangxu; Gong, Zhenggang; Luo, Xiaolin; Chen, Lihui; Shuai, Li", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Bonding wood with uncondensed lignins as adhesives", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Plywood is widely used in construction, such as for flooring and interior walls, as well as in the manufacture of household items such as furniture and cabinets. Such items are made of wood veneers that are bonded together with adhesives such as urea-formaldehyde and phenol-formaldehyde resins1,2. Researchers in academia and industry have long aimed to synthesize lignin-phenol-formaldehyde resin adhesives using biomass-derived lignin, a phenolic polymer that can be used to substitute the petroleum-derived phenol3-6. However, lignin-phenol-formaldehyde resin adhesives are less attractive to plywood manufacturers than urea-formaldehyde and phenol-formaldehyde resins owing to their appearance and cost. Here we report a simple and practical strategy for preparing lignin-based wood adhesives from lignocellulosic biomass. Our strategy involves separation of uncondensed or slightly condensed lignins from biomass followed by direct application of a suspension of the lignin and water as an adhesive on wood veneers. Plywood products with superior performances could be prepared with such lignin adhesives at a wide range of hot-pressing temperatures, enabling the use of these adhesives as promising alternatives to traditional wood adhesives in different market segments. Mechanistic studies indicate that the adhesion mechanism of such lignin adhesives may involve softening of lignin by water, filling of vessels with softened lignin and crosslinking of lignins in adhesives with those in the cell wall. A straightforward strategy for preparing lignin-based wood adhesives from lignocellulosic biomass is described, with the resulting adhesives demonstrating performance attractive for plywood manufacture.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 206, "Times Cited, All Databases": 208, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 21", "Publication Year": 2023, "Volume": 621, "Issue": 7979, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 511, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41586-023-06507-5", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-06507-5", "Book DOI": null, "Early Access Date": "AUG 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001059705300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Cao, QH; Gao, Y; Pu, J; Zhao, X; Wang, YX; Chen, JP; Guan, C", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Cao, Qinghe; Gao, Yong; Pu, Jie; Zhao, Xin; Wang, Yuxuan; Chen, Jipeng; Guan, Cao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Gradient design of imprinted anode for stable Zn-ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Zinc metal anodes suffer from electrolyte corrosion and dendrite growth issues during electrochemical cycling. Here, the authors propose a gradient design to imprint the zinc anode, which both prohibits side reactions and alleviates zinc deposition behaviour. Achieving long-term stable zinc anodes at high currents/capacities remains a great challenge for practical rechargeable zinc-ion batteries. Herein, we report an imprinted gradient zinc electrode that integrates gradient conductivity and hydrophilicity for long-term dendrite-free zinc-ion batteries. The gradient design not only effectively prohibits side reactions between the electrolyte and the zinc anode, but also synergistically optimizes electric field distribution, zinc ion flux and local current density, which induces preferentially deposited zinc in the bottom of the microchannels and suppresses dendrite growth even under high current densities/capacities. As a result, the imprinted gradient zinc anode can be stably cycled for 200 h at a high current density/capacity of 10 mA cm(-2)/10 mAh cm(-2), with a high cumulative capacity of 1000 mAh cm(-2), which outperforms the none-gradient counterparts and bare zinc. The imprinted gradient design can be easily scaled up, and a high-performance large-area pouch cell (4*5 cm(2)) is also demonstrated.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 211, "Times Cited, All Databases": 214, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 6", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1038/s41467-023-36386-3", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36386-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000954587000010", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, SC; Tan, CH; Yan, RP; Zou, XF; Hu, FL; Mi, Y; Yan, C; Zhao, SL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Shucong; Tan, Chunhui; Yan, Ruipeng; Zou, Xifei; Hu, Fei-Long; Mi, Yan; Yan, Cheng; Zhao, Shenlong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Constructing Built-in Electric Field in Heterogeneous nullowire Arrays for Efficient Overall Water Electrolysis", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Efficient bifunctional electrocatalysts for hydrogen and oxygen evolution reactions are key to water electrolysis. Herein, we report a built-in electric field (BEF) strategy to fabricate heterogeneous nickel phosphide-cobalt nullowire arrays grown on carbon fiber paper (Ni2P-CoCH/CFP) with large work function difference (Delta phi) as bifunctional electrocatalysts for overall water splitting. Impressively, Ni2P-CoCH/CFP exhibits a remarkable catalytic activity for hydrogen and oxygen evolution reactions to obtain 10 mA cm(-2), respectively. Moreover, the assembled lab-scale electrolyzer driven by an AAA battery delivers excellent stability after 50 h electrocatalysis with a 100 % faradic efficiency. Computational calculations combining with experiments reveal the interface-induced electric field effect facilitates asymmetrical charge distributions, thereby regulating the adsorption/desorption of the intermediates during reactions. This work offers an avenue to rationally design high-performance heterogeneous electrocatalysts.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 201, "Times Cited, All Databases": 202, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUN 26", "Publication Year": 2023, "Volume": 62, "Issue": 26, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202302795", "DOI Link": "http://dx.doi.org/10.1002/anie.202302795", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000989587300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Huang, W; Chen, JH; Yao, Y; Zheng, D; Ji, XD; Feng, LW; Moore, D; Glavin, NR; Xie, M; Chen, Y; Pankow, RM; Surendran, A; Wang, Z; Xia, Y; Bai, LB; Rivnay, J; Ping, JF; Guo, XG; Cheng, YH; Marks, TJ; Facchetti, A", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Huang, Wei; Chen, Jianhua; Yao, Yao; Zheng, Ding; Ji, Xudong; Feng, Liang-Wen; Moore, David; Glavin, Nicholas R.; Xie, Miao; Chen, Yao; Pankow, Robert M.; Surendran, Abhijith; Wang, Zhi; Xia, Yu; Bai, Libing; Rivnay, Jonathan; Ping, Jianfeng; Guo, Xugang; Cheng, Yuhua; Marks, Tobin J.; Facchetti, Antonio", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Vertical organic electrochemical transistors for complementary circuits", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Organic electrochemical transistors (OECTs) and OECT-based circuitry offer great potential in bioelectronics, wearable electronics and artificial neuromorphic electronics because of their exceptionally low driving voltages (< 1 V), low power consumption (< 1 mu W), high transconductances (> 10 mS) and biocompatibility(1-5). However, the successful realization of critical complementary logic OECTs is currently limited by temporal and/or operational instability, slow redox processes and/or switching, incompatibility with high-density monolithic integration and inferior n-type OECT performance(6-8). Here we demonstrate p- and n-type vertical OECTs with balanced and ultra-high performance by blending redox-active semiconducting polymers with a redox-inactive photocurable and/or photopatternable polymer to form an ion-permeable semiconducting channel, implemented in a simple, scalable vertical architecture that has a dense, impermeable top contact. Footprint current densities exceeding 1 kA cm(-2) at less than +/- 0.7 V, transconductances of 0.2-0.4 S, short transient times of less than 1 ms and ultra-stable switching (> 50,000 cycles) are achieved in, to our knowledge, the first vertically stacked complementary vertical OECT logic circuits. This architecture opens many possibilities for fundamental studies of organic semiconductor redox chemistry and physics in nulloscopically confined spaces, without macroscopic electrolyte contact, as well as wearable and implantable device applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 200, "Times Cited, All Databases": 212, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 19", "Publication Year": 2023, "Volume": 613, "Issue": 7944, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 496, "End Page": 502, "Article Number": null, "DOI": "10.1038/s41586-022-05592-2", "DOI Link": "http://dx.doi.org/10.1038/s41586-022-05592-2", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000922739000002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rao, MY; Tang, H; Wu, JB; Song, WH; Zhang, MX; Yin, WB; Zhuo, Y; Kiani, F; Chen, BJM; Jiang, XQ; Liu, HF; Chen, HY; Midya, R; Ye, F; Jiang, H; Wang, ZR; Wu, MC; Hu, M; Wang, H; Xia, QF; Ge, N; Li, J; Yang, JJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rao, Mingyi; Tang, Hao; Wu, Jiangbin; Song, Wenhao; Zhang, Max; Yin, Wenbo; Zhuo, Ye; Kiani, Fatemeh; Chen, Benjamin; Jiang, Xiangqi; Liu, Hefei; Chen, Hung-Yu; Midya, Rivu; Ye, Fan; Jiang, Hao; Wang, Zhongrui; Wu, Mingche; Hu, Miao; Wang, Han; Xia, Qiangfei; Ge, Ning; Li, Ju; Yang, J. Joshua", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Thousands of conductance levels in memristors integrated on CMOS", "Source Title": "NATURE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Neural networks based on memristive devices(1-3) have the ability to improve throughput and energy efficiency for machine learning(4,5) and artificial intelligence(6), especially in edge applications(7-21). Because training a neural network model from scratch is costly in terms of hardware resources, time and energy, it is impractical to do it individually on billions of memristive neural networks distributed at the edge. A practical approach would be to download the synaptic weights obtained from the cloud training and program them directly into memristors for the commercialization of edge applications. Some post-tuning in memristor conductance could be done afterwards or during applications to adapt to specific situations. Therefore, in neural network applications, memristors require high-precision programmability to guarantee uniform and accurate performance across a large number of memristive networks(22-28). This requires many distinguishable conductance levels on each memristive device, not only laboratory-made devices but also devices fabricated in factories. Analog memristors with many conductance states also benefit other applications, such as neural network training, scientific computing and even `mortal computing'(25,29,30.) Here we report 2,048 conductance levels achieved with memristors in fully integrated chips with 256 x 256 memristor arrays monolithically integrated on complementary metal-oxide-semiconductor (CMOS) circuits in a commercial foundry. We have identified the underlying physics that previously limited the number of conductance levels that could be achieved in memristors and developed electrical operation protocols to avoid such limitations. These results provide insights into the fundamental understanding of the microscopic picture of memristive switching as well as approaches to enable high-precision memristors for various applications.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 204, "Times Cited, All Databases": 216, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 30", "Publication Year": 2023, "Volume": 615, "Issue": 7954, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 823, "End Page": 829, "Article Number": null, "DOI": "10.1038/s41586-023-05759-5", "DOI Link": "http://dx.doi.org/10.1038/s41586-023-05759-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000961772700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YB; Li, Q; Hong, H; Yang, S; Zhang, R; Wang, XQ; Jin, X; Xiong, B; Bai, SC; Zhi, CY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yanbo; Li, Qing; Hong, Hu; Yang, Shuo; Zhang, Rong; Wang, Xiaoqi; Jin, Xu; Xiong, Bo; Bai, Shengchi; Zhi, Chunyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lean-water hydrogel electrolyte for zinc ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Solid polymer electrolytes (SPEs) and hydrogel electrolytes were developed as electrolytes for zinc ion batteries (ZIBs). Hydrogels can retain water molecules and provide high ionic conductivities; however, they contain many free water molecules, inevitably causing side reactions on the zinc anode. SPEs can enhance the stability of anodes, but they typically possess low ionic conductivities and result in high impedance. Here, we develop a lean water hydrogel electrolyte, aiming to balance ion transfer, anode stability, electrochemical stability window and resistance. This hydrogel is equipped with a molecular lubrication mechanism to ensure fast ion transportation. Additionally, this design leads to a widened electrochemical stability window and highly reversible zinc plating/ stripping. The full cell shows excellent cycling stability and capacity retentions at high and low current rates, respectively. Moreover, superior adhesion ability can be achieved, meeting the needs of flexible devices. Excess water in hydrogel-based zinc ion batteries causes side reactions, but reduced water content results in low conductivities. Here, authors develop a lean-water hydrogel based on molecular lubrication mechanism for fast ion transportation, extended stability, and reversible Zinc plating/stripping.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 212, "Times Cited, All Databases": 215, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL 1", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 3890, "DOI": "10.1038/s41467-023-39634-8", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-39634-8", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001022536900008", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yokoyama, T; Nagashima, K; Nakai, I; Young, ED; Abe, Y; Aleon, J; Alexander, CMO; Amari, S; Amelin, Y; Bajo, KI; Bizzarro, M; Bouvier, A; Carlson, RW; Chaussidon, M; Choi, BG; Dauphas, N; Davis, AM; Di Rocco, T; Fujiya, W; Fukai, R; Gautam, I; Haba, MK; Hibiya, Y; Hidaka, H; Homma, H; Hoppe, P; Huss, GR; Ichida, K; Iizuka, T; Ireland, TR; Ishikawa, A; Ito, M; Itoh, S; Kawasaki, N; Kita, NT; Kitajima, K; Kleine, T; Komatani, S; Krot, AN; Liu, MC; Masuda, Y; McKeegan, KD; Morita, M; Motomura, K; Moynier, F; Nguyen, A; Nittler, L; Onose, M; Pack, A; Park, C; Piani, L; Qin, LP; Russell, SS; Sakamoto, N; Schoenbaechler, M; Tafla, L; Tang, HL; Terada, K; Terada, Y; Usui, T; Wada, S; Wadhwa, M; Walker, RJ; Yamashita, K; Yin, QZ; Yoneda, S; Yui, H; Zhang, AC; Connolly, HC Jr; Lauretta, DS; Nakamura, T; Naraoka, H; Noguchi, T; Okazaki, R; Sakamoto, K; Yabuta, H; Abe, M; Arakawa, M; Fujii, A; Hayakawa, M; Hirata, N; Hirata, N; Honda, R; Honda, C; Hosoda, S; Iijima, Y; Ikeda, H; Ishiguro, M; Ishihara, Y; Iwata, T; Kawahara, K; Kikuchi, S; Kitazato, K; Matsumoto, K; Matsuoka, M; Michikami, T; Mimasu, Y; Miura, A; Morota, T; Nakazawa, S; Namiki, N; Noda, H; Noguchi, R; Ogawa, N; Ogawa, K; Okada, T; Okamoto, C; Ono, G; Ozaki, M; Saiki, T; Sakatani, N; Sawada, H; Senshu, H; Shimaki, Y; Shirai, K; Sugita, S; Takei, Y; Takeuchi, H; Tanaka, S; Tatsumi, E; Terui, F; Tsuda, Y; Tsukizaki, R; Wada, K; Watanabe, SI; Yamada, M; Yamada, T; Yamamoto, Y; Yano, H; Yokota, Y; Yoshihara, K; Yoshikawa, M; Yoshikawa, K; Furuya, S; Hatakeda, K; Hayashi, T; Hitomi, Y; Kumagai, K; Miyazaki, A; Nakato, A; Nishimura, M; Soejima, H; Suzuki, A; Yada, T; Yamamoto, D; Yogata, K; Yoshitake, M; Tachibana, S; Yurimoto, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yokoyama, Tetsuya; Nagashima, Kazuhide; Nakai, Izumi; Young, Edward D.; Abe, Yoshinari; Aleon, Jerome; Alexander, Conel M. O'D.; Amari, Sachiko; Amelin, Yuri; Bajo, Ken-ichi; Bizzarro, Martin; Bouvier, Audrey; Carlson, Richard W.; Chaussidon, Marc; Choi, Byeon-Gak; Dauphas, Nicolas; Davis, Andrew M.; Di Rocco, Tommaso; Fujiya, Wataru; Fukai, Ryota; Gautam, Ikshu; Haba, Makiko K.; Hibiya, Yuki; Hidaka, Hiroshi; Homma, Hisashi; Hoppe, Peter; Huss, Gary R.; Ichida, Kiyohiro; Iizuka, Tsuyoshi; Ireland, Trevor R.; Ishikawa, Akira; Ito, Motoo; Itoh, Shoichi; Kawasaki, Noriyuki; Kita, Noriko T.; Kitajima, Kouki; Kleine, Thorsten; Komatani, Shintaro; Krot, Alexander N.; Liu, Ming-Chang; Masuda, Yuki; McKeegan, Kevin D.; Morita, Mayu; Motomura, Kazuko; Moynier, Frederic; Nguyen, Ann; Nittler, Larry; Onose, Morihiko; Pack, Andreas; Park, Changkun; Piani, Laurette; Qin, Liping; Russell, Sara S.; Sakamoto, Naoya; Schoenbaechler, Maria; Tafla, Lauren; Tang, Haolan; Terada, Kentaro; Terada, Yasuko; Usui, Tomohiro; Wada, Sohei; Wadhwa, Meenakshi; Walker, Richard J.; Yamashita, Katsuyuki; Yin, Qing-Zhu; Yoneda, Shigekazu; Yui, Hiroharu; Zhang, Ai-Cheng; Connolly Jr, Harold C.; Lauretta, Dante S.; Nakamura, Tomoki; Naraoka, Hiroshi; Noguchi, Takaaki; Okazaki, Ryuji; Sakamoto, Kanako; Yabuta, Hikaru; Abe, Masanao; Arakawa, Masahiko; Fujii, Atsushi; Hayakawa, Masahiko; Hirata, Naoyuki; Hirata, Naru; Honda, Rie; Honda, Chikatoshi; Hosoda, Satoshi; Iijima, Yu-ichi; Ikeda, Hitoshi; Ishiguro, Masateru; Ishihara, Yoshiaki; Iwata, Takahiro; Kawahara, Kosuke; Kikuchi, Shota; Kitazato, Kohei; Matsumoto, Koji; Matsuoka, Moe; Michikami, Tatsuhiro; Mimasu, Yuya; Miura, Akira; Morota, Tomokatsu; Nakazawa, Satoru; Namiki, Noriyuki; Noda, Hirotomo; Noguchi, Rina; Ogawa, Naoko; Ogawa, Kazunori; Okada, Tatsuaki; Okamoto, Chisato; Ono, Go; Ozaki, Masanobu; Saiki, Takanao; Sakatani, Naoya; Sawada, Hirotaka; Senshu, Hiroki; Shimaki, Yuri; Shirai, Kei; Sugita, Seiji; Takei, Yuto; Takeuchi, Hiroshi; Tanaka, Satoshi; Tatsumi, Eri; Terui, Fuyuto; Tsuda, Yuichi; Tsukizaki, Ryudo; Wada, Koji; Watanabe, Sei-ichiro; Yamada, Manabu; Yamada, Tetsuya; Yamamoto, Yukio; Yano, Hajime; Yokota, Yasuhiro; Yoshihara, Keisuke; Yoshikawa, Makoto; Yoshikawa, Kent; Furuya, Shizuho; Hatakeda, Kentaro; Hayashi, Tasuku; Hitomi, Yuya; Kumagai, Kazuya; Miyazaki, Akiko; Nakato, Aiko; Nishimura, Masahiro; Soejima, Hiromichi; Suzuki, Ayako; Yada, Toru; Yamamoto, Daiki; Yogata, Kasumi; Yoshitake, Miwa; Tachibana, Shogo; Yurimoto, Hisayoshi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Samples returned from the asteroid Ryugu are similar to Ivuna-type carbonaceous meteorites", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Carbonaceous meteorites are thought to be fragments of C-type (carbonaceous) asteroids. Samples of the C-type asteroid (162173) Ryugu were retrieved by the Hayabusa2 spacecraft. We measured the mineralogy and bulk chemical and isotopic compositions of Ryugu samples. The samples are mainly composed of materials similar to those of carbonaceous chondrite meteorites, particularly the CI (Ivuna-type) group. The samples consist predominulltly of minerals formed in aqueous fluid on a parent planetesimal. The primary minerals were altered by fluids at a temperature of 37 degrees +/- 10 degrees C, about 5.2(-0.7)(+0.8) million (statistical) or 5.2(-2.1)(+1.6) million (systematic) years after the formation of the first solids in the Solar System. After aqueous alteration, the Ryugu samples were likely never heated above similar to 100 degrees C. The samples have a chemical composition that more closely resembles that of the Sun's photosphere than other natural samples do.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 208, "Times Cited, All Databases": 211, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 24", "Publication Year": 2023, "Volume": 379, "Issue": 6634, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 786, "End Page": "+", "Article Number": "eabn7850", "DOI": "10.1126/science.abn7850", "DOI Link": "http://dx.doi.org/10.1126/science.abn7850", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000981670800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Mao, ML; Ji, X; Wang, QY; Lin, ZJ; Li, MY; Liu, T; Wang, CL; Hu, YS; Li, H; Huang, XJ; Chen, LQ; Suo, LM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Mao, Minglei; Ji, Xiao; Wang, Qiyu; Lin, Zejing; Li, Meiying; Liu, Tao; Wang, Chengliang; Hu, Yong-Sheng; Li, Hong; Huang, Xuejie; Chen, Liquan; Suo, Liumin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Anion-enrichment interface enables high-voltage anode-free lithium metal batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aggressive chemistry involving Li metal anode (LMA) and high-voltage LiNi0.8Mn0.1Co0.1O2 (NCM811) cathode is deemed as a pragmatic approach to pursue the desperate 400 Wh kg(-1). Yet, their implementation is plagued by low Coulombic efficiency and inferior cycling stability. Herein, we propose an optimally fluorinated linear carboxylic ester (ethyl 3,3,3-trifluoropropanoate, FEP) paired with weakly solvating fluoroethylene carbonate and dissociated lithium salts (LiBF4 and LiDFOB) to prepare a weakly solvating and dissociated electrolyte. An anion-enrichment interface prompts more anions' decomposition in the inner Helmholtz plane and higher reduction potential of anions. Consequently, the anion-derived interface chemistry contributes to the compact and columnar-structure Li deposits with a high CE of 98.7% and stable cycling of 4.6 V NCM811 and LiCoO2 cathode. Accordingly, industrial anode-free pouch cells under harsh testing conditions deliver a high energy of 442.5 Wh kg(-1) with 80% capacity retention after 100 cycles. The implementation of Li metal anode with high-voltage Ni/Co rich cathode is plagued by low coulombic efficiency and inferior cycling stability. Here authors propose an anion-enriched interface to facilitate the columnar-structure of Li deposits to solve this issue.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 190, "Times Cited, All Databases": 197, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 25", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1082, "DOI": "10.1038/s41467-023-36853-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36853-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001002656000019", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Su, JJ; Musgrave, CB; Song, Y; Huang, LB; Liu, Y; Li, G; Xin, YE; Xiong, P; Li, MMJ; Wu, HR; Zhu, MH; Chen, HM; Zhang, JY; Shen, HC; Tang, BZ; Robert, M; Goddard, W ; Ye, RQ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Su, Jianjun; Musgrave, Charles B.; Song, Yun; Huang, Libei; Liu, Yong; Li, Geng; Xin, Yinger; Xiong, Pei; Li, Molly Meng-Jung; Wu, Haoran; Zhu, Minghui; Chen, Hao Ming; Zhang, Jianyu; Shen, Hanchen; Tang, Ben Zhong; Robert, Marc; Goddard, William A., III; Ye, Ruquan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Strain enhances the activity of molecular electrocatalysts via carbon nullotube supports", "Source Title": "NATURE CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Support-induced strain engineering is useful for modulating the properties of two-dimensional materials. However, controlling strain of planar molecules is technically challenging due to their sub-2 nm lateral size. Additionally, the effect of strain on molecular properties remains poorly understood. Here we show that carbon nullotubes (CNTs) are ideal substrates for inducing optimum properties through molecular curvature. In a tandem-flow electrolyser with monodispersed cobalt phthalocyanine (CoPc) on single-walled CNTs (CoPc/SWCNTs) for CO2 reduction, we achieve a methanol partial current density of >90 mA cm(-2) with >60% selectivity, surpassing wide multiwalled CNTs at 16.6%. We report vibronic and X-ray spectroscopies to unravel the distinct local geometries and electronic structures induced by the strong molecule-support interactions. Grand canonical density functional theory confirms that curved CoPc/SWCNTs improve *CO binding to enable subsequent reduction, whereas wide multiwalled CNTs favour CO desorption. Our results show the important role of SWCNTs beyond catalyst dispersion and electron conduction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 195, "Times Cited, All Databases": 200, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP", "Publication Year": 2023, "Volume": 6, "Issue": 9, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 818, "End Page": 828, "Article Number": null, "DOI": "10.1038/s41929-023-01005-3", "DOI Link": "http://dx.doi.org/10.1038/s41929-023-01005-3", "Book DOI": null, "Early Access Date": "AUG 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001048827200001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, ZL; Skripka, A; Dahl, JC; Dun, CC; Urban, JJ; Jaque, D; Schuck, PJ; Cohen, BE; Chan, EM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Zhuolei; Skripka, Artiom; Dahl, Jakob C.; Dun, Chaochao; Urban, Jeffrey J.; Jaque, Daniel; Schuck, P. James; Cohen, Bruce E.; Chan, Emory M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Tuning Phonon Energies in Lanthanide-doped Potassium Lead Halide nullocrystals for Enhanced Nonlinearity and Upconversion", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Optical applications of lanthanide-doped nulloparticles require materials with low phonon energies to minimize nonradiative relaxation and promote nonlinear processes like upconversion. Heavy halide hosts offer low phonon energies but are challenging to synthesize as nullocrystals. Here, we demonstrate the size-controlled synthesis of low-phonon-energy KPb2X5 (X=Cl, Br) nulloparticles and the ability to tune nullocrystal phonon energies as low as 128 cm(-1). KPb2Cl5 nulloparticles are moisture resistant and can be efficiently doped with lighter lanthanides. The low phonon energies of KPb2X5 nulloparticles promote upconversion luminescence from higher lanthanide excited states and enable highly nonlinear, avalanche-like emission from KPb2Cl5 : Nd3+ nulloparticles. The realization of nulloparticles with tunable, ultra-low phonon energies facilitates the discovery of nullomaterials with phonon-dependent properties, precisely engineered for applications in nulloscale imaging, sensing, luminescence thermometry and energy conversion.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 194, "Times Cited, All Databases": 193, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 2", "Publication Year": 2023, "Volume": 62, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202212549", "DOI Link": "http://dx.doi.org/10.1002/anie.202212549", "Book DOI": null, "Early Access Date": "DEC 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000898399100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, MQ; Wu, F; Gong, YT; Li, Y; Li, Y; Feng, X; Li, QJ; Wu, C; Bai, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Mingquan; Wu, Feng; Gong, Yuteng; Li, Yu; Li, Ying; Feng, Xin; Li, Qiaojun; Wu, Chuan; Bai, Ying", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Interfacial-Catalysis-Enabled Layered and Inorganic-Rich SEI on Hard Carbon Anodes in Ester Electrolytes for Sodium-Ion Batteries", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Constructing a homogenous and inorganic-rich solid electrolyte interface (SEI) can efficiently improve the overall sodium-storage performance of hard carbon (HC) anodes. However, the thick and heterogenous SEI derived from conventional ester electrolytes fails to meet the above requirements. Herein, an innovative interfacial catalysis mechanism is proposed to design a favorable SEI in ester electrolytes by reconstructing the surface functionality of HC, of which abundant C(sic)O (carbonyl) bonds are accurately and homogenously implanted. The C(sic)O (carbonyl) bonds act as active centers that controllably catalyze the preferential reduction of salts and directionally guide SEI growth to form a homogenous, layered, and inorganic-rich SEI. Therefore, excessive solvent decomposition is suppressed, and the interfacial Na+ transfer and structural stability of SEI on HC anodes are greatly promoted, contributing to a comprehensive enhancement in sodium-storage performance. The optimal anodes exhibit an outstanding reversible capacity (379.6 mAh g(-1)), an ultrahigh initial Coulombic efficiency (93.2%), a largely improved rate capability, and an extremely stable cycling performance with a capacity decay rate of 0.0018% for 10 000 cycles at 5 A g(-1). This work provides novel insights into smart regulation of interface chemistry to realize high-performance HC anodes for sodium storage.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 185, "Times Cited, All Databases": 191, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JUL", "Publication Year": 2023, "Volume": 35, "Issue": 29, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202300002", "DOI Link": "http://dx.doi.org/10.1002/adma.202300002", "Book DOI": null, "Early Access Date": "MAY 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000995947700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, SJ; Wang, CC; Dong, KX; Zhang, P; Chen, XB; Li, X", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Shijie; Wang, Chunchun; Dong, Kexin; Zhang, Peng; Chen, Xiaobo; Li, Xin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "MIL-101(Fe)/BiOBr S-scheme photocatalyst for promoting photocatalytic abatement of Cr(VI) and enrofloxacin antibiotic: Performance and mechanism", "Source Title": "CHINESE JOURNAL OF CATALYSIS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of highly active, economical, and robust bifunctional photocatalysts is a priority for sustainable photocatalytic water remediation. Inadequately available reactive sites and sluggish interface photocarrier transfer and separation remain significant challenges in the photoreaction progress. In this study, the Fe-containing metal-organic framework (MOF) MIL-101(Fe) was inte-grated with BiOBr microspheres to form a competent S-scheme heterostructure for the photocatalytic mitigation of Cr(VI) and enrofloxacin (ENR) antibiotics. The optimal MIL-101(Fe)/BiOBr ex-hibited the highest photoactivity, with 99.4% of Cr(VI) and 84.4% of ENR eliminated upon visi-ble-light illumination in a single-pollutant system. The photoactivity of MIL-101(Fe)/BiOBr in the decontamination of the Cr(VI)-ENR co-existence system exhibited a substantial enhancement when compared to that in a single system, owing to the improved utilization of electrons and holes resulting from the synergism between Cr(VI), ENR, and the photocatalyst. The enhanced photoactivity is attributed to two aspects: (1) the incorporation of MIL-101(Fe) results in an increased number of available reactive sites and improved solar harvesting properties; and (2) the S-scheme mechanism enables the effective spatial disassociation of photoexcited carriers and optimization of the pho-to-redox capability of the system. Through scavenging experiments, electron spin resonullce characterization, liquid chromatography-tandem mass spectrometry analysis, and T.E.S.T. theoretical estimation, the catalytic mechanism, antibiotic degradation process, and biotoxicities of the de-graded products were analyzed and confirmed. This study provides a viable strategy for building competent MOF-inorganic semiconductor S-scheme photocatalysts with superior photocatalytic decontamination performance.(c) 2023, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 192, "Times Cited, All Databases": 201, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 51, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 101, "End Page": 112, "Article Number": null, "DOI": "10.1016/S1872-2067(23)64479-1", "DOI Link": "http://dx.doi.org/10.1016/S1872-2067(23)64479-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001136853100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Shen, Y; Ren, CJ; Zheng, LR; Xu, XY; Long, R; Zhang, WQ; Yang, Y; Zhang, YC; Yao, YF; Chi, HQ; Wang, JL; Shen, Q; Xiong, YJ; Zou, ZG; Zhou, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Shen, Yan; Ren, Chunjin; Zheng, Lirong; Xu, Xiaoyong; Long, Ran; Zhang, Wenqing; Yang, Yong; Zhang, Yongcai; Yao, Yingfang; Chi, Haoqiang; Wang, Jinlan; Shen, Qing; Xiong, Yujie; Zou, Zhigang; Zhou, Yong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Room-temperature photosynthesis of propane from CO2 with Cu single atoms on vacancy-rich TiO2", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "A photocatalyst for CO2 reduction to C3H8 is prepared by implanting Cu single atoms on vacancy rich TiO2 single layers. Key reaction intermediates, *CHOCO and *CH2OCOCO, are stabilized on the catalyst which promotes C-C bond formation. Photochemical conversion of CO2 into high-value C2+ products is difficult to achieve due to the energetic and mechanistic challenges in forming multiple C-C bonds. Herein, an efficient photocatalyst for the conversion of CO2 into C3H8 is prepared by implanting Cu single atoms on Ti0.91O2 atomically-thin single layers. Cu single atoms promote the formation of neighbouring oxygen vacancies (V(O)s) in Ti0.91O2 matrix. These oxygen vacancies modulate the electronic coupling interaction between Cu atoms and adjacent Ti atoms to form a unique Cu-Ti-V-O unit in Ti0.91O2 matrix. A high electron-based selectivity of 64.8% for C3H8 (product-based selectivity of 32.4%), and 86.2% for total C2+ hydrocarbons (product-based selectivity of 50.2%) are achieved. Theoretical calculations suggest that Cu-Ti-V-O unit may stabilize the key *CHOCO and *CH2OCOCO intermediates and reduce their energy levels, tuning both C-1-C-1 and C-1-C-2 couplings into thermodynamically-favourable exothermal processes. Tandem catalysis mechanism and potential reaction pathway are tentatively proposed for C3H8 formation, involving an overall (20e(-) - 20H(+)) reduction and coupling of three CO2 molecules at room temperature.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 191, "Times Cited, All Databases": 198, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 27", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1117, "DOI": "10.1038/s41467-023-36778-5", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36778-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000942107800020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, MB; Sun, RM; Chang, JX; Dong, JJ; Tian, QS; Wang, HZ; Li, ZH; Yang, PH; Shi, HK; Yang, C; Wu, ZC; Li, RZ; Yang, YG; Wang, AF; Zhang, ST; Wang, FF; Huang, W; Qin, TS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Mubai; Sun, Riming; Chang, Jingxi; Dong, Jingjin; Tian, Qiushuang; Wang, Hongze; Li, Zihao; Yang, Pinghui; Shi, Haokun; Yang, Chao; Wu, Zichao; Li, Renzhi; Yang, Yingguo; Wang, Aifei; Zhang, Shitong; Wang, Fangfang; Huang, Wei; Qin, Tianshi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Orientated crystallization of FA-based perovskite via hydrogen-bonded polymer network for efficient and stable solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Incorporating mixed ion is a frequently used strategy to stabilize black-phase formamidinum lead iodide perovskite for high-efficiency solar cells. However, these devices commonly suffer from photoinduced phase segregation and humidity instability. Herein, we find that the underlying reason is that the mixed halide perovskites generally fail to grow into homogenous and highcrystalline film, due to the multiple pathways of crystal nucleation originating from various intermediate phases in the film-forming process. Therefore, we design a multifunctional fluorinated additive, which restrains the complicated intermediate phases and promotes orientated crystallization of a-phase of perovskite. Furthermore, the additives in-situ polymerize during the perovskite film formation and form a hydrogen-bonded network to stabilize aphase. Remarkably, the polymerized additives endow a strongly hydrophobic effect to the bare perovskite film against liquid water for 5min. The unencapsulated devices achieve 24.10% efficiency and maintain >95% of the initial efficiency for 1000 h under continuous sunlight soaking and for 2000 h at air ambient of similar to 50% humid, respectively.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 191, "Times Cited, All Databases": 195, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 2", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 573, "DOI": "10.1038/s41467-023-36224-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36224-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001076389000015", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, TH; Gao, LL; Lu, J; Ma, C; Du, YC; Wang, PJ; Ding, ZC; Wang, SQ; Xu, P; Liu, DL; Li, HJ; Chang, XM; Fang, JJ; Tian, WM; Yang, YG; Liu, SZ; Zhao, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Tinghuan; Gao, Lili; Lu, Jing; Ma, Chuang; Du, Yachao; Wang, Peijun; Ding, Zicheng; Wang, Shiqiang; Xu, Peng; Liu, Dongle; Li, Haojin; Chang, Xiaoming; Fang, Junjie; Tian, Wenming; Yang, Yingguo; Liu, Shengzhong (Frank); Zhao, Kui", "Book Author Full Names": null, "Group Authors": null, "Article Title": "One-stone-for-two-birds strategy to attain beyond 25% perovskite solar cells", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Even though the perovskite solar cell has been so popular for its skyrocketing power conversion efficiency, its further development is still roadblocked by its overall performance, in particular long-term stability, large-area fabrication and stable module efficiency. In essence, the soft component and ionic-electronic nature of metal halide perovskites usually chaperonage large number of anion vacancy defects that act as recombination centers to decrease both the photovoltaic efficiency and operational stability. Herein, we report a one-stone-for-two-birds strategy in which both anion-fixation and associated undercoordinated-Pb passivation are in situ achieved during crystallization by using a single amidino-based ligand, namely 3-amidinopyridine, for metal-halide perovskite to overcome above challenges. The resultant devices attain a power conversion efficiency as high as 25.3% (certified at 24.8%) with substantially improved stability. Moreover, the device without encapsulation retained 92% of its initial efficiency after 5000 h exposure in ambient and the device with encapsulation retained 95% of its initial efficiency after >500 h working at the maximum power point under continuous light irradiation in ambient. It is expected this one-stone-for-two-birds strategy will benefit large-area fabrication that desires for simplicity. Long-term stability and stable efficiency are essential for large-area fabrication of perovskite solar cells. Here, the authors achieve in situ anion-fixation and undercoordinated-Pb passivation using amidino-based ligand, realizing maximum power conversion efficiency of 25.3% with T95 over 500 h.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 200, "Times Cited, All Databases": 201, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB 15", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 839, "DOI": "10.1038/s41467-023-36229-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-36229-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000940806000012", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lv, HL; Yao, YX; Li, SC; Wu, GL; Zhao, B; Zhou, XD; Dupont, RL; Kara, UI; Zhou, YM; Xi, SB; Liu, B; Che, RC; Zhang, JC; Xu, HB; Adera, S; Wu, RB; Wang, XG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lv, Hualiang; Yao, Yuxing; Li, Shucong; Wu, Guanglei; Zhao, Biao; Zhou, Xiaodi; Dupont, Robert L.; Kara, Ufuoma I.; Zhou, Yimin; Xi, Shibo; Liu, Bo; Che, Renchao; Zhang, Jincang; Xu, Hongbin; Adera, Solomon; Wu, Renbing; Wang, Xiaoguang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Staggered circular nulloporous graphene converts electromagnetic waves into electricity", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The electromagnetic (EM) energy released by electronic devices in the environment is largely wasted and contributes to EM pollution. Here, the authors report the synthesis of staggered circular nulloporous graphene enabling the absorption and conversion of EM waves into electricity via the thermoelectric effect. Harvesting largely ignored and wasted electromagnetic (EM) energy released by electronic devices and converting it into direct current (DC) electricity is an attractive strategy not only to reduce EM pollution but also address the ever-increasing energy crisis. Here we report the synthesis of nulloparticle-templated graphene with monodisperse and staggered circular nullopores enabling an EM-heat-DC conversion pathway. We experimentally and theoretically demonstrate that this staggered nulloporous structure alters graphene's electronic and phononic properties by synergistically manipulating its intralayer nullostructures and interlayer interactions. The staggered circular nulloporous graphene exhibits an anomalous combination of properties, which lead to an efficient absorption and conversion of EM waves into heat and in turn an output of DC electricity through the thermoelectric effect. Overall, our results advance the fundamental understanding of the structure-property relationships of ordered nulloporous graphene, providing an effective strategy to reduce EM pollution and generate electric energy.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 184, "Times Cited, All Databases": 189, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 8", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 1982, "DOI": "10.1038/s41467-023-37436-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-37436-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000980800100009", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, XH; Liu, ZC; Sun, JF; Luo, RH; Xu, K; Si, MY; Kang, J; Yuan, Y; Liu, S; Ahmad, T; Jiang, TL; Chen, N; Wang, MM; Xu, Y; Chuai, M; Zhu, ZX; Peng, Q; Meng, YH; Zhang, K; Wang, WP; Chen, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Xinhua; Liu, Zaichun; Sun, Jifei; Luo, Ruihao; Xu, Kui; Si, Mingyu; Kang, Ju; Yuan, Yuan; Liu, Shuang; Ahmad, Touqeer; Jiang, Taoli; Chen, Na; Wang, Mingming; Xu, Yan; Chuai, Mingyan; Zhu, Zhengxin; Peng, Qia; Meng, Yahan; Zhang, Kai; Wang, Weiping; Chen, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Constructing robust heterostructured interface for anode-free zinc batteries with ultrahigh capacities", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The development of Zn-free anodes to inhibit Zn dendrite formation and modulate high-capacity Zn batteries is highly applauded yet very challenging. Here, we design a robust two-dimensional antimony/antimony-zinc alloy heterostructured interface to regulate Zn plating. Benefiting from the stronger adsorption and homogeneous electric field distribution of the Sb/Sb2Zn3-heterostructured interface in Zn plating, the Zn anode enables an ultrahigh areal capacity of 200 mAh cm(-2) with an overpotential of 112 mV and a Coulombic efficiency of 98.5%. An anode-free Zn-Br-2 battery using the Sb/Sb2Zn3-heterostructured interface@Cu anode shows an attractive energy density of 274 Wh kg(-1) with a practical pouch cell energy density of 62 Wh kg(-1). The scaled-up Zn-Br-2 battery in a capacity of 500 mAh exhibits over 400 stable cycles. Further, the Zn-Br-2 battery module in an energy of 9 Wh (6 V, 1.5 Ah) is integrated with a photovoltaic panel to demonstrate the practical renewable energy storage capabilities. Our superior anode-free Zn batteries enabled by the heterostructured interface enlighten an arena towards large-scale energy storage applications. The development of dendrite-free, Zn-free anodes is challenging. Here, the authors design a two-dimensional antimony/antimony-zinc alloy heterostructured interface to achieve dendrite-free Zn deposition with areal capacity of 200 mAh cm(-2), and energy density of around 270 Wh kg(-1) for anode-free zinc-bromine battery.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 182, "Times Cited, All Databases": 187, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 5", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 76, "DOI": "10.1038/s41467-022-35630-6", "DOI Link": "http://dx.doi.org/10.1038/s41467-022-35630-6", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000940650100013", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Lin, Y; Kang, Q; Liu, YJ; Zhu, YK; Jiang, PK; Mai, YW; Huang, XY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Lin, Ying; Kang, Qi; Liu, Yijie; Zhu, Yingke; Jiang, Pingkai; Mai, Yiu-Wing; Huang, Xingyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Flexible, Highly Thermally Conductive and Electrically Insulating Phase Change Materials for Advanced Thermal Management of 5G Base Stations and Thermoelectric Generators", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Thermal management has become a crucial problem for high-power-density equipment and devices. Phase change materials (PCMs) have great prospects in thermal management applications because of their large capacity of heat storage and isothermal behavior during phase transition. However, low intrinsic thermal conductivity, ease of leakage, and lack of flexibility severely limit their applications. Solving one of these problems often comes at the expense of other performance of the PCMs. In this work, we report core-sheath structured phase change nullocomposites (PCNs) with an aligned and interconnected boron nitride nullosheet network by combining coaxial electrospinning, electrostatic spraying, and hot-pressing. The advanced PCN films exhibit an ultrahigh thermal conductivity of 28.3 W m(-1) K-1 at a low BNNS loading (i.e., 32 wt%), which thereby endows the PCNs with high enthalpy (> 101 J g(-1)), outstanding ductility (> 40%) and improved fire retardancy. Therefore, our core-sheath strategies successfully balance the trade-off between thermal conductivity, flexibility, and phase change enthalpy of PCMs. Further, the PCNs provide powerful cooling solutions on 5G base station chips and thermoelectric generators, displaying promising thermal management applications on high-power-density equipment and thermoelectric conversion devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 179, "Times Cited, All Databases": 190, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 31, "DOI": "10.1007/s40820-022-01003-3", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-01003-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000911314100002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhou, JZ; Xu, X; Wu, HJ; Wang, JL; Lou, LC; Yin, K; Gong, YC; Shi, JJ; Luo, YH; Li, DM; Xin, H; Meng, QB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhou, Jiazheng; Xu, Xiao; Wu, Huijue; Wang, Jinlin; Lou, Licheng; Yin, Kang; Gong, Yuancai; Shi, Jiangjian; Luo, Yanhong; Li, Dongmei; Xin, Hao; Meng, Qingbo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Control of the phase evolution of kesterite by tuning of the selenium partial pressure for solar cells with 13.8% certified efficiency", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The control of the phase evolution during the selenization of kesterite Cu2ZnSn(S,Se)(4) (CZTSSe) is crucial for efficient solar cells. Here, we regulate the phase-evolution kinetics of Ag-alloyed CZTSSe by applying a positive pressure in the reaction chamber at the initial stage of the annealing process. The partial pressure of Se decreases, reducing the collision probability between selenium molecules and the kesterite precursor during the initial formation of the crystals. This results in the precursor transforming into CZTSSe in a single step, without the formation of secondary phases. CZTSSe forms at relatively higher temperature than conventional methods, leading to high-crystallinity kesterite films with fewer defects. We demonstrate solar cells with a total area efficiency of 14.1% and a certified total area efficiency of 13.8%. This work provides insights into the selenization mechanism and phase evolution of kesterite absorbers, enabling efficient solar cells. Secondary phases or multi-step phase formation lead to poorly crystallized and defective kesterite films. Now Zhou et al. convert precursors into kesterite in a single step, using low partial pressure of selenium, and achieve solar cells with 13.8% certified efficiency.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 190, "Times Cited, All Databases": 191, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 8, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 526, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41560-023-01251-6", "DOI Link": "http://dx.doi.org/10.1038/s41560-023-01251-6", "Book DOI": null, "Early Access Date": "APR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000968306600002", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Liu, YF; Liu, SD; Xie, XS; Li, ZC; Wang, PJ; Lu, BA; Liang, SQ; Tang, Y; Zhou, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Liu, Yanfen; Liu, Shude; Xie, Xuesong; Li, Zhicheng; Wang, Pinji; Lu, Bingan; Liang, Shuquan; Tang, Yan; Zhou, Jiang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "A functionalized separator enables dendrite-free Zn anode via metal-polydopamine coordination chemistry", "Source Title": "INFOMAT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Designing a multifunctional separator with abundant ion migration paths is crucial for tuning the ion transport in rocking-chair-type batteries. Herein, a polydopamine-functionalized PVDF (PVDF@PDA) nullofibrous membrane is designed to serve as a separator for aqueous zinc-ion batteries (AZIBs). The functional groups (-OH and -NH-) in PDA facilitate the formation of Zn-O and Zn-N coordination bonds with Zn ions, homogenizing the Zn-ion flux and thus enabling dendrite-free Zn deposition. Moreover, the PVDF@PDA separator effectively inhibits the shuttling of V-species through the formation of V-O coordination bonds. As a result, the Zn/NH4V4O10 battery with the PVDF@PDA separator exhibits enhanced cycling stability (92.3% after 1000 cycles at 5 A g(-1)) and rate capability compared to that using a glass fiber separator. This work provides a new avenue to design functionalized separators for high-performance AZIBs.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 184, "Times Cited, All Databases": 184, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2023, "Volume": 5, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/inf2.12374", "DOI Link": "http://dx.doi.org/10.1002/inf2.12374", "Book DOI": null, "Early Access Date": "OCT 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000863843500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Chen, L; Zhang, WQ; Wang, JF; Li, XJ; Li, Y; Hu, X; Zhao, LH; Wu, Y; He, YM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Chen, Lu; Zhang, Wenqian; Wang, Junfeng; Li, Xiaojing; Li, Yi; Hu, Xin; Zhao, Leihong; Wu, Ying; He, Yiming", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High piezo/photocatalytic efficiency of Ag/Bi5O7I nullocomposite using mechanical and solar energy for N2 fixation and methyl orange degradation", "Source Title": "GREEN ENERGY & ENVIRONMENT", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, Ag/Bi5O7I nullocomposite was prepared and firstly applied in piezo/photocatalytic reduction of N2 to NH3 and methyl orange (MO) degradation. Bi5O7I was synthesized via a hydrothermal-calcination method and shows nullorods morphology. Ag nulloparticles (NPs) were photo deposited on the Bi5O7I nullorods as electron trappers to improve the spatial separation of charge carriers, which was confirmed via XPS, TEM, and electronic chemical analyses. The catalytic test indicates that Bi5O7I presents the piezoelectric-like behavior, while the loading of Ag NPs can strengthen the character. Under ultrasonic vibration, the optimal Ag/Bi5O7I presents high efficiency in MO degra-dation. The degradation rate is determined to be 0.033 min -1, which is 4.7 folds faster than that of Bi5O7I. The Ag/Bi5O7I also presents a high performance in piezocatalytic N2 fixation. The piezocatalytic NH3 generation rate reaches 65.4 mmol L-1 g-1 h-1 with water as a hole scavenger. The addition of methanol can hasten the piezoelectric catalytic reaction. Interestingly, when ultrasonic vibration and light irra-diation simultaneously act on the Ag/Bi5O7I catalyst, higher performance in NH3 generation and MO degradation is observed. However, due to the weak adhesion of Ag NPs, some Ag NPs would fall off from the Bi5O7I surface under long-term ultrasonic vibration, which would greatly reduce the piezoelectric catalytic performance. This result indicates that a strong binding force is required when preparing the piezoelectric composite catalyst. The current work provides new insights for the development of highly efficient catalysts that can use multiple energies.(c) 2021 Institute of Process Engineering, Chinese Academy of Sciences. Publishing services by Elsevier B.V. on behalf of KeAi Commu-nications Co., Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 203, "Times Cited, All Databases": 206, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2023, "Volume": 8, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 283, "End Page": 295, "Article Number": null, "DOI": "10.1016/j.gee.2021.04.009", "DOI Link": "http://dx.doi.org/10.1016/j.gee.2021.04.009", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Energy & Fuels; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000938188100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Fei, CB; Li, NX; Wang, MR; Wang, XM; Gu, HY; Chen, B; Zhang, Z; Ni, ZY; Jiao, HY; Xu, WZ; Shi, ZF; Yan, YF; Huang, JS", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Fei, Chengbin; Li, Nengxu; Wang, Mengru; Wang, Xiaoming; Gu, Hangyu; Chen, Bo; Zhang, Zhao; Ni, Zhenyi; Jiao, Haoyang; Xu, Wenzhan; Shi, Zhifang; Yan, Yanfa; Huang, Jinsong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lead-chelating hole-transport layers for efficient and stable perovskite minimodules", "Source Title": "SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The defective bottom interfaces of perovskites and hole-transport layers (HTLs) limit the performance of p-i-n structure perovskite solar cells. We report that the addition of lead chelation molecules into HTLs can strongly interact with lead(II) ion (Pb2+), resulting in a reduced amorphous region in perovskites near HTLs and a passivated perovskite bottom surface. The minimodule with an aperture area of 26.9 square centimeters has a power conversion efficiency (PCE) of 21.8% (stabilized at 21.1%) that is certified by the National Renewable Energy Laboratory (NREL), which corresponds to a minimal small-cell efficiency of 24.6% (stabilized 24.1%) throughout the module area. Small-area cells and large-area minimodules with lead chelation molecules in HTLs had a light soaking stability of 3010 and 2130 hours, respectively, at an efficiency loss of 10% from the initial value under 1-sun illumination and open-circuit voltage conditions.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 192, "Times Cited, All Databases": 199, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 26", "Publication Year": 2023, "Volume": 380, "Issue": 6647, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 823, "End Page": 829, "Article Number": null, "DOI": "10.1126/science.ade9463", "DOI Link": "http://dx.doi.org/10.1126/science.ade9463", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001001476900004", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, CX; Liu, Y; Jia, ZR; Zhao, WR; Wu, GL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Chenxi; Liu, Yue; Jia, Zirui; Zhao, Wanru; Wu, Guanglei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multicomponent nulloparticles Synergistic One-Dimensional nullofibers as Heterostructure Absorbers for Tunable and Efficient Microwave Absorption", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Application of novel radio technologies and equipment inevitably leads to electromagnetic pollution. One-dimensional polymer-based composite membrane structures have been shown to be an effective strategy to obtain high-performance microwave absorbers. Herein, we reported a one-dimensional N-doped carbon nullofibers material which encapsulated the hollow Co3SnC0.7 nullocubes in the fiber lumen by electrospinning. Space charge stacking formed between nulloparticles can be channeled by longitudinal fibrous structures. The dielectric constant of the fibers is highly related to the carbonization temperature, and the great impedance matching can be achieved by synergetic effect between Co3SnC0.7 and carbon network. At 800 & DEG;C, the necklace-like Co3SnC0.7/CNF with 5% low load achieves an excellent RL value of - 51.2 dB at 2.3 mm and the effective absorption bandwidth of 7.44 GHz with matching thickness of 2.5 mm. The multiple electromagnetic wave (EMW) reflections and interfacial polarization between the fibers and the fibers internal contribute a major effect to attenuating the EMW. These strategies for regulating electromagnetic performance can be expanded to other electromagnetic functional materials which facilitate the development of emerging absorbers.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 173, "Times Cited, All Databases": 184, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 13, "DOI": "10.1007/s40820-022-00986-3", "DOI Link": "http://dx.doi.org/10.1007/s40820-022-00986-3", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000899513300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Rehan, AI; Rasee, AI; Awual, ME; Waliullah, RM; Hossain, MS; Kubra, KT; Salman, MS; Sheikh, MC; Marwani, HM; Khaleque, MA; Islam, A; Awual, MR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Rehan, Ariyan Islam; Rasee, Adiba Islam; Awual, Mrs Eti; Waliullah, R. M.; Hossain, Mohammed Sohrab; Kubra, Khadiza Tul; Salman, Md. Shad; Sheikh, Md. Chanmiya; Marwani, Hadi M.; Khaleque, Md. Abdul; Islam, Aminul; Awual, Md. Rabiul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Improving toxic dye removal and remediation using novel nullocomposite fibrous adsorbent", "Source Title": "COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Materials with regulated nulloscale morphology provide capabilities to remove dangerous pollutants from wastewater, by adsorption. In this study, the chitosan-based composite fibrous adsorbent was fabricated and used as a novel and facile eliminator in the process of removing cationic methyl orange (MO) from the water medium. Different methods were applied to check the properties of the desired composite fibrous adsorbent. The removal value showed that the chitosan-embedded composite fibrous adsorbent has super characteristics and can be removed the organic dye from the water. The influence of pH, time, temperature, eliminator quantity, and MO content was explored. With increasing time and eliminator quantity, the adsorption efficiency increased. The composite fibrous adsorbent with the advantage of its high functionality and combined micro-nullomorphology features, has emerged as a very promising candidate for obtaining versatile and robust adsorbents. This work presents how the tunned synthesis of composite fibrous adsorbent tailored their nulloarchitecture giving rise to adsorption capacities toward cleaning aqueous samples polluted with MO dye. The composite fibrous adsorbent was prepared by the direct immobilization method, with normal aging temperature, in order to study the effect of synthesis conditions on the adsorption properties of MO dye. The solution acidity was exhibited as the key factor, and a suitable pH of 5.50 was selected based on the efficiency. The competing ions were not adversely affected in the dye adsorption as defined by the stable bonding mechanism. The adsorption data were highly fitted with the Langmuir adsorption model with monolayer coverage. The determined maximum adsorption was 175.45 mg/g, which was comparable with the other forms of materials. The adsorbed MO dye elution was evaluated using ethanol and then the composite fibrous adsorbent was ready to use for MO dye adsorption after washing with water without significant loss in its functionality. Therefore, we explored the tunned morphology of composite fibrous adsorbent for obtaining performant adsorbents for the elimination of refractory pollutants in wastewater.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 190, "Times Cited, All Databases": 191, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "SEP 20", "Publication Year": 2023, "Volume": 673, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 131859, "DOI": "10.1016/j.colsurfa.2023.131859", "DOI Link": "http://dx.doi.org/10.1016/j.colsurfa.2023.131859", "Book DOI": null, "Early Access Date": "JUN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001144186400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, YY; Wang, ZJ; Pang, WK; Lie, W; Yuwono, JA; Liang, GM; Liu, SL; D' Angelo, AM; Deng, JJ; Fan, YM; Davey, K; Li, BH; Guo, ZP", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Yanyan; Wang, Zhijie; Pang, Wei Kong; Lie, Wilford; Yuwono, Jodie A.; Liang, Gemeng; Liu, Sailin; D' Angelo, Anita M.; Deng, Jiaojiao; Fan, Yameng; Davey, Kenneth; Li, Baohua; Guo, Zaiping", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Solvent control of water O-H bonds for highly reversible zinc ion batteries", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Aqueous Zn-ion batteries have attracted increasing research interest; however, the development of these batteries has been hindered by several challenges, including dendrite growth, Zn corrosion, cathode material degradation, limited temperature adaptability and electrochemical stability window, which are associated with water activity and the solvation structure of electrolytes. Here we report that water activity is suppressed by increasing the electron density of the water protons through interactions with highly polar dimethylacetamide and trimethyl phosphate molecules. Meanwhile, the Zn corrosion in the hybrid electrolyte is mitigated, and the electrochemical stability window and the operating temperature of the electrolyte are extended. The dimethylacetamide alters the surface energy of Zn, guiding the (002) plane dominated deposition of Zn. Molecular dynamics simulation evidences Zn2+ ions are solvated with fewer water molecules, resulting in lower lattice strain in the NaV3O8 center dot 1.5H(2)O cathode during the insertion of hydrated Zn2+ ions, boosting the lifespan of Zn|| NaV3O8 center dot 1.5H(2)O cell to 3000 cycles. The electrochemical performance of aqueous zinc ion batteries is limited by water activity. Here, the authors propose a hybrid electrolyte that incorporate strongly polar molecules to strengthen the water O-H bonds, thus reduce water activity and improve the electrochemical performance of the batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 182, "Times Cited, All Databases": 184, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 11", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2720, "DOI": "10.1038/s41467-023-38384-x", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38384-x", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000992465700007", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kim, SC; Wang, JY; Xu, R; Zhang, P; Chen, YL; Huang, ZJ; Yang, YF; Yu, Z; Oyakhire, ST; Zhang, WB; Greenburg, LC; Kim, MS; Boyle, DT; Sayavong, P; Ye, YS; Qin, J; Bao, ZA; Cui, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kim, Sang Cheol; Wang, Jingyang; Xu, Rong; Zhang, Pu; Chen, Yuelang; Huang, Zhuojun; Yang, Yufei; Yu, Zhiao; Oyakhire, Solomon T.; Zhang, Wenbo; Greenburg, Louisa C.; Kim, Mun Sek; Boyle, David T.; Sayavong, Philaphon; Ye, Yusheng; Qin, Jian; Bao, Zhenull; Cui, Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-entropy electrolytes for practical lithium metal batteries", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Electrolyte engineering is crucial for improving battery performance, particularly for lithium metal batteries. Recent advances in electrolytes have greatly improved cyclability by enhancing electrochemical stability at the electrode interfaces, but concurrently achieving high ionic conductivity has remained challenging. Here we report an electrolyte design strategy for enhanced lithium metal batteries by increasing the molecular diversity in electrolytes, which essentially leads to high-entropy electrolytes. We find that, in weakly solvating electrolytes, the entropy effect reduces ion clustering while preserving the characteristic anion-rich solvation structures, which is characterized by synchrotron-based X-ray scattering and molecular dynamics simulations. Electrolytes with smaller-sized clusters exhibit a twofold improvement in ionic conductivity compared with conventional weakly solvating electrolytes, enabling stable cycling at high current densities up to 2C (6.2 mA cm(-2)) in anode-free LiNi0.6Mn0.2Co0.2 (NMC622)||Cu pouch cells. The efficacy of the design strategy is verified by performance improvements in three disparate weakly solvating electrolyte systems. Electrolyte engineering has proven an effective approach to enhance the performance of lithium metal batteries. Here the authors propose a strategy by using multiple solvents in weakly solvating electrolytes-dubbed as high-entropy electrolytes-to improve the ionic conductivity while maintaining electrochemical stability, leading to high-performance batteries.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 173, "Times Cited, All Databases": 177, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG", "Publication Year": 2023, "Volume": 8, "Issue": 8, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 814, "End Page": 826, "Article Number": null, "DOI": "10.1038/s41560-023-01280-1", "DOI Link": "http://dx.doi.org/10.1038/s41560-023-01280-1", "Book DOI": null, "Early Access Date": "JUL 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001023405800005", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, DF; Li, MN; Yong, X; Song, HQ; Waterhouse, GIN; Yi, YF; Xue, BJ; Zhang, DL; Liu, BZ; Lu, SY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Dafeng; Li, Mengnull; Yong, Xue; Song, Haoqiang; Waterhouse, Geoffrey I. N.; Yi, Yunfei; Xue, Bingjie; Zhang, Dongliang; Liu, Baozhong; Lu, Siyu", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Construction of Zn-doped RuO2 nullowires for efficient and stable water oxidation in acidic media", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Oxygen evolution reaction catalysts capable of working efficiently in acidic media are highly demanded for the commercialization of proton exchange membrane water electrolysis. Herein, we report a Zn-doped RuO2 nullowire array electrocatalyst with outstanding catalytic performance for the oxygen evolution reaction under acidic conditions. Overpotentials as low as 173, 304, and 373 mV are achieved at 10, 500, and 1000 mA cm(-2), respectively, with robust stability reaching to 1000 h at 10 mA cm(-2). Experimental and theoretical investigations establish a clear synergistic effect of Zn dopants and oxygen vacancies on regulating the binding configurations of oxygenated adsorbates on the active centers, which then enables an alternative Ru-Zn dual-site oxide path of the reaction. Due to the change of reaction pathways, the energy barrier of rate-determining step is reduced, and the over-oxidation of Ru active sites is alleviated. As a result, the catalytic activity and stability are significantly enhanced. Ru-based materials are promising catalysts for oxygen evolution reaction in acidic condition, but their catalytic performance needs to be further improved. Here, the authors report Zn-RuO2 nullowires with a Ru-Zn dual-site oxide reaction pathway with enhanced activity and stability for acidic oxygen evolution reaction.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 178, "Times Cited, All Databases": 181, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY 2", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 2517, "DOI": "10.1038/s41467-023-38213-1", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-38213-1", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000980689000020", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Kumar, P; Kannimuthu, K; Zeraati, AS; Roy, S; Wang, X; Wang, XY; Samanta, S; Miller, KA; Molina, M; Trivedi, D; Abed, J; Mata, AC; Al-Mahayni, H; Baltrusaitis, J; Shimizu, G; Wu, YA; Seifitokaldani, A; Sargent, EH; Ajayan, PM; Hu, JG; Kibria, MG", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Kumar, Pawan; Kannimuthu, Karthick; Zeraati, Ali Shayesteh; Roy, Soumyabrata; Wang, Xiao; Wang, Xiyang; Samanta, Subhajyoti; Miller, Kristen A.; Molina, Maria; Trivedi, Dhwanil; Abed, Jehad; Mata, Astrid Campos; Al-Mahayni, Hasan; Baltrusaitis, Jonas; Shimizu, George; Wu, Yimin A.; Seifitokaldani, Ali; Sargent, Edward H.; Ajayan, Pulickel M.; Hu, Jinguang; Kibria, Md Golam", "Book Author Full Names": null, "Group Authors": null, "Article Title": "High-Density Cobalt Single-Atom Catalysts for Enhanced Oxygen Evolution Reaction", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Single atom catalysts (SACs) possess unique catalytic properties due to low-coordination and unsaturated active sites. However, the demonstrated performance of SACs is limited by low SAC loading, poor metal-support interactions, and nonstable performance. Herein, we report a macromolecule-assisted SAC synthesis approach that enabled us to demonstrate high-density Co single atoms (10.6 wt % Co SAC) in a pyridinic N-rich graphenic network. The highly porous carbon network (surface area of similar to 186 m(2) g(-1)) with increased conjugation and vicinal Co site decoration in Co SACs significantly enhanced the electrocatalytic oxygen evolution reaction (OER) in 1 M KOH (eta(10) at 351 mV; mass activity of 2209 mA mg(Co)(-1) at 1.65 V) with more than 300 h stability. Operando X-ray absorption near-edge structure demonstrates the formation of electron-deficient Co-O coordination intermediates, accelerating OER kinetics. Density functional theory (DFT) calculations reveal the facile electron transfer from cobalt to oxygen speciesaccelerated OER.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 178, "Times Cited, All Databases": 180, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 12", "Publication Year": 2023, "Volume": 145, "Issue": 14, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 8052, "End Page": 8063, "Article Number": null, "DOI": "10.1021/jacs.3c00537", "DOI Link": "http://dx.doi.org/10.1021/jacs.3c00537", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000967668600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, XP; Li, Z; Zhang, Y; Chen, M; Liu, T; Xiao, CX; Gao, DP; Patel, JB; Kuciauskas, D; Magomedov, A; Scheidt, RA; Wang, XM; Harvey, SP; Dai, ZH; Zhang, CL; Morales, D; Pruett, H; Wieliczka, BM; Kirmani, AR; Padture, NP; Graham, KR; Yan, YF; Nazeeruddin, MK; McGehee, MD; Zhu, ZL; Luther, JM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Xiaopeng; Li, Zhen; Zhang, Yi; Chen, Min; Liu, Tuo; Xiao, Chuanxiao; Gao, Danpeng; Patel, Jay B.; Kuciauskas, Darius; Magomedov, Artiom; Scheidt, Rebecca A.; Wang, Xiaoming; Harvey, Steven P.; Dai, Zhenghong; Zhang, Chunlei; Morales, Daniel; Pruett, Henry; Wieliczka, Brian M.; Kirmani, Ahmad R.; Padture, Nitin P.; Graham, Kenneth R.; Yan, Yanfa; Nazeeruddin, Mohammad Khaja; McGehee, Michael D.; Zhu, Zonglong; Luther, Joseph M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Co-deposition of hole-selective contact and absorber for improving the processability of perovskite solar cells", "Source Title": "NATURE ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Simplifying the manufacturing processes of renewable energy technologies is crucial to lowering the barriers to commercialization. In this context, to improve the manufacturability of perovskite solar cells (PSCs), we have developed a one-step solution-coating procedure in which the hole-selective contact and perovskite light absorber spontaneously form, resulting in efficient inverted PSCs. We observed that phosphonic or carboxylic acids, incorporated into perovskite precursor solutions, self-assemble on the indium tin oxide substrate during perovskite film processing. They form a robust self-assembled monolayer as an excellent hole-selective contact while the perovskite crystallizes. Our approach solves wettability issues and simplifies device fabrication, advancing the manufacturability of PSCs. Our PSC devices with positive-intrinsic-negative (p-i-n) geometry show a power conversion efficiency of 24.5% and retain >90% of their initial efficiency after 1,200 h of operating at the maximum power point under continuous illumination. The approach shows good generality as it is compatible with different self-assembled monolayer molecular systems, perovskites, solvents and processing methods. Improving the manufacturability of perovskite solar cells is key to their deployment. Zheng et al. report a one-step deposition of the hole-selective and absorber layers that addresses wettability issues and simplifies the fabrication process.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 178, "Times Cited, All Databases": 183, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAY", "Publication Year": 2023, "Volume": 8, "Issue": 5, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 462, "End Page": "+", "Article Number": null, "DOI": "10.1038/s41560-023-01227-6", "DOI Link": "http://dx.doi.org/10.1038/s41560-023-01227-6", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Energy & Fuels; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000950511100003", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, XW; Yu, X; Zhao, M; Li, ZD; Wang, ZG; Zhai, W", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Xinwei; Yu, Xiang; Zhao, Miao; Li, Zhendong; Wang, Zhonggang; Zhai, Wei", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Multi-Level Bioinspired Microlattice with Broadband Sound-Absorption Capabilities and Deformation-Tolerant Compressive Response", "Source Title": "ADVANCED FUNCTIONAL MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Owing to the omnipresent noise and crash hazards, multifunctional sound-absorbing, and deformation-tolerant materials are highly sought-after for practical engineering design. However, challenges lie with designing such a material. Herein, leveraging the inherent mechanical robustness of the biological cuttlebone, by introducing dissipative pores, a high-strength microlattice is presented which is also sound-absorbing. Its absorption bandwidth and deformation tolerance are further enhanced by introducing another level of bioinspiration, based on geometrical heterogeneities amongst the building cells. A high-fidelity microstructure-based model is developed to predict and optimize properties. Across a broad range of frequencies from 1000 to 6300 Hz, at a low thickness of 21 mm, the optimized microlattice displays a high experimentally measured average absorption coefficient of 0.735 with 68% of the points higher than 0.7. The absorption mechanism attributes to the resonating air frictional loss whilst its broadband characteristics attribute to the multiple resonullce modes working in tandem. The heterogeneous architecture also enables the microlattice to deform with a deformation-tolerant plateau behavior not observed in its uniform counterpart, which thereby leads to a 30% improvement in the specific energy absorption. Overall, this work presents an effective approach to the design of sound and energy-absorbing materials by modifying state-of-the-art bioinspired structures.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 182, "Times Cited, All Databases": 182, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2023, "Volume": 33, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adfm.202210160", "DOI Link": "http://dx.doi.org/10.1002/adfm.202210160", "Book DOI": null, "Early Access Date": "NOV 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000878784800001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xue, TT; Yang, Y; Yu, DY; Wali, Q; Wang, ZY; Cao, XS; Fan, W; Liu, TX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xue, Tiantian; Yang, Yi; Yu, Dingyi; Wali, Qamar; Wang, Zhenyu; Cao, Xuesong; Fan, Wei; Liu, Tianxi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "3D Printed Integrated Gradient-Conductive MXene/CNT/Polyimide Aerogel Frames for Electromagnetic Interference Shielding with Ultra-Low Reflection", "Source Title": "nullO-MICRO LETTERS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Construction of advanced electromagnetic interference (EMI) shielding materials with miniaturized, programmable structure and low reflection are promising but challenging. Herein, an integrated transition-metal carbides/carbon nullotube/polyimide (gradient-conductive MXene/CNT/PI, GCMCP) aerogel frame with hierarchical porous structure and gradient-conductivity has been constructed to achieve EMI shielding with ultra-low reflection. The gradient-conductive structures are obtained by continuous 3D printing of MXene/CNT/poly (amic acid) inks with different CNT contents, where the slightly conductive top layer serves as EM absorption layer and the highly conductive bottom layer as reflection layer. In addition, the hierarchical porous structure could extend the EM dissipation path and dissipate EM by multiple reflections. Consequently, the GCMCP aerogel frames exhibit an excellent average EMI shielding efficiency (68.2 dB) and low reflection (R = 0.23). Furthermore, the GCMCP aerogel frames with miniaturized and programmable structures can be used as EMI shielding gaskets and effectively block wireless power transmission, which shows a prosperous application prospect in defense industry and aerospace.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 166, "Times Cited, All Databases": 180, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "DEC", "Publication Year": 2023, "Volume": 15, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 45, "DOI": "10.1007/s40820-023-01017-5", "DOI Link": "http://dx.doi.org/10.1007/s40820-023-01017-5", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000931727400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zheng, ZL; Zhang, OF; Borgs, C; Chayes, JT; Yaghi, OM", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zheng, Zhiling; Zhang, Oufan; Borgs, Christian; Chayes, Jennifer T.; Yaghi, Omar M.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "ChatGPT Chemistry Assistant for Text Mining and the Prediction of MOF Synthesis", "Source Title": "JOURNAL OF THE AMERICAN CHEMICAL SOCIETY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "We use prompt engineering to guide ChatGPT in the automationoftext mining of metal-organic framework (MOF) synthesis conditionsfrom diverse formats and styles of the scientific literature. Thiseffectively mitigates ChatGPT's tendency to hallucinate information,an issue that previously made the use of large language models (LLMs)in scientific fields challenging. Our approach involves the developmentof a workflow implementing three different processes for text mining,programmed by ChatGPT itself. All of them enable parsing, searching,filtering, classification, summarization, and data unification withdifferent trade-offs among labor, speed, and accuracy. We deploy thissystem to extract 26 257 distinct synthesis parameters pertainingto approximately 800 MOFs sourced from peer-reviewed research articles.This process incorporates our ChemPrompt Engineering strategy to instructChatGPT in text mining, resulting in impressive precision, recall,and F1 scores of 90-99%. Furthermore, with the data set builtby text mining, we constructed a machine-learning model with over87% accuracy in predicting MOF experimental crystallization outcomesand preliminarily identifying important factors in MOF crystallization.We also developed a reliable data-grounded MOF chatbot to answer questionsabout chemical reactions and synthesis procedures. Given that theprocess of using ChatGPT reliably mines and tabulates diverse MOFsynthesis information in a unified format while using only narrativelanguage requiring no coding expertise, we anticipate that our ChatGPTChemistry Assistant will be very useful across various other chemistrysubdisciplines.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 170, "Times Cited, All Databases": 176, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "AUG 7", "Publication Year": 2023, "Volume": 145, "Issue": 32, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 18048, "End Page": 18062, "Article Number": null, "DOI": "10.1021/jacs.3c05819", "DOI Link": "http://dx.doi.org/10.1021/jacs.3c05819", "Book DOI": null, "Early Access Date": "AUG 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001052894400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zeng, JL; Xie, WH; Guo, Y; Zhao, T; Zhou, H; Wang, QY; Li, HD; Guo, ZH; Bin Xu, B; Gu, HB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zeng, Junling; Xie, Wenhao; Guo, Ying; Zhao, Tong; Zhou, Heng; Wang, Qiaoying; Li, Handong; Guo, Zhanhu; Bin Xu, Ben; Gu, Hongbo", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Magnetic field facilitated electrocatalytic degradation of tetracycline in wastewater by magnetic porous carbonized phthalonitrile resin", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Herein, the magnetic field facilitated electrocatalytic degradation of tetracycline is reported for the first time. A magnetic porous carbonized phthalonitrile resin electrocatalyst has been prepared through directly annealing phthalonitrile monomer, polyaniline coated barium ferrite and potassium hydroxide. The tetracycline degradation percentage (DP%) by such electrocatalyst is significantly increased up to 37.42% under magnetic field with the optimal pH value of 5.0 and bias voltage of 1.0 V (vs. SCE). The mechanism of this phenomenon is explained by the spin-selective electron removal process in the reaction between metal-oxygen species and tetracycline on the electrocatalyst. The comparison of degradation pathways for tetracycline with and without magnetic field confirms the improvement of tetracycline DP%. This work opens a new direction for the application of an external magnetic field in the electrocatalytic degradation of antibiotics in wastewater.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 121, "Times Cited, All Databases": 123, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2024, "Volume": 340, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 123225, "DOI": "10.1016/j.apcatb.2023.123225", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2023.123225", "Book DOI": null, "Early Access Date": "AUG 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001069094400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ding, SC; Barr, JA; Lyu, Z; Zhang, FY; Wang, MY; Tieu, P; Li, X; Engelhard, MH; Feng, ZX; Beckman, SP; Pan, XQ; Li, JC; Du, D; Lin, YH", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ding, Shichao; Barr, Jordan Alysia; Lyu, Zhaoyuan; Zhang, Fangyu; Wang, Maoyu; Tieu, Peter; Li, Xin; Engelhard, Mark H.; Feng, Zhenxing; Beckman, Scott P.; Pan, Xiaoqing; Li, Jin-Cheng; Du, Dan; Lin, Yuehe", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Effect of Phosphorus Modulation in Iron Single-Atom Catalysts for Peroxidase Mimicking", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Fe-N-C single-atom catalysts (SACs) exhibit excellent peroxidase (POD)-like catalytic activity, owing to their well-defined isolated iron active sites on the carbon substrate, which effectively mimic the structure of natural peroxidase's active center. To further meet the requirements of diverse biosensing applications, SAC POD-like activity still needs to be continuously enhanced. Herein, a phosphorus (P) heteroatom is introduced to boost the POD-like activity of Fe-N-C SACs. A 1D carbon nullowire (FeNCP/NW) catalyst with enriched Fe-N-4 active sites is designed and synthesized, and P atoms are doped in the carbon matrix to affect the Fe center through long-range interaction. The experimental results show that the P-doping process can boost the POD-like activity more than the non-P-doped one, with excellent selectivity and stability. The mechanism analysis results show that the introduction of P into SAC can greatly enhance POD-like activity initially, but its effect becomes insignificant with increasing amount of P. As a proof of concept, FeNCP/NW is employed in an enzyme cascade platform for highly sensitive colorimetric detection of the neurotransmitter acetylcholine.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 113, "Times Cited, All Databases": 113, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2024, "Volume": 36, "Issue": 10, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202209633", "DOI Link": "http://dx.doi.org/10.1002/adma.202209633", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000948326900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, ML; Lu, YP; Lan, JG; Wang, TM; Zhang, C; Cao, ZQ; Li, TJ; Liaw, PK", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Mingliang; Lu, Yiping; Lan, Jinggang; Wang, Tongmin; Zhang, Chuan; Cao, Zhiqiang; Li, Tingju; Liaw, Peter K.", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Lightweight, ultrastrong and high thermal-stable eutectic high-entropy alloys for elevated-temperature applications", "Source Title": "ACTA MATERIALIA", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Eutectic high-entropy alloys (EHEAs) that combine the advantages of HEAs and eutectic alloys are promising candidates for high-temperature applications. However, currently developed EHEAs still exhibit high densities and low high-temperature strengths, which limit their usage. Here we propose a strategy to design lightweight, strong, and high thermal-stable EHEAs by introducing an extremely stable Heusler-type ordered phase (L21 phase) containing a high-content of low-density elements and constructing a low lattice misfit eutectic-phase interface, which can lead to generate ultrafine and stable lamellar structures and high-density of coherent nulloprecipitates. As a manifestation of this strategy, a novel bulk Al17Ni34Ti17V32 EHEA was designed to consist of L21 and body-centered-cubic (BCC) phases (interlamellar spacing -320 nm) with a lattice misfit only 2.4%. This alloy has one of the lowest densities (-6.2 g/cm3) among all EHEAs reported previously and exhibits much higher high-temperature hardness and specific yield strengths than most reported refractory HEAs (RHEAs), lightweight HEAs (LWHEAs), EHEAs, and conventional superalloys. This work paves the way to develop light EHEAs with excellent high-temperature properties.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 172, "Times Cited, All Databases": 176, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "APR 15", "Publication Year": 2023, "Volume": 248, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 118806, "DOI": "10.1016/j.actamat.2023.118806", "DOI Link": "http://dx.doi.org/10.1016/j.actamat.2023.118806", "Book DOI": null, "Early Access Date": "MAR 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000952487500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Bai, B; Chen, J; Bai, F; Nie, QK; Jia, XX", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Bai, Bing; Chen, Jing; Bai, Fan; Nie, Qingke; Jia, Xiangxin", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Corrosion effect of acid/alkali on cementitious red mud-fly ash materials containing heavy metal residues", "Source Title": "ENVIRONMENTAL TECHNOLOGY & INNOVATION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "High-strength cementitious red mud-fly ash materials (RFMs) were formed from sodium hydroxide and water glass mixed solutions, and their abilities to solidify heavy metal ions (HMs, e. g., copper and cadmium) were assessed. The mechanism for precipitation of the HMs by corrosive acid/alkali solutions was explored via toxicity leaching tests, as well as SEM, XRD, FT-IR and XPS. The results showed that when the added alkaline activator was not fully consumed, the presence of small amounts of HMs consumed the excess alkaline ions to form hydroxide precipitates that filled the pores of the RFM, so the compressive strength of the RFM increased. Otherwise, the presence of excess HMs reduced the compactness of the RFM and eventually resulted in a highly porous structure, leading to weakening of the material. Additionally, small amounts of anhydrite phases were produced in the RFM. In neutral and alkaline environments, the HMs formed precipitates or coordination complexes with hydroxyl groups, and the solidification efficiencies exceeded 99%. In acidic environments, the HMs converted from their original precipitated forms or ion-hydroxide complexes to free cations. As a result, the HMs were more likely to be separated from the RFMs. Moreover, the RFMs were more prone to disaggregation under acidic conditions, which led to destruction of the RFM microstructure and rerelease of the HMs fixed in the microstructure.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 155, "Times Cited, All Databases": 158, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2024, "Volume": 33, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 103485, "DOI": "10.1016/j.eti.2023.103485", "DOI Link": "http://dx.doi.org/10.1016/j.eti.2023.103485", "Book DOI": null, "Early Access Date": "DEC 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Biotechnology & Applied Microbiology; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001145912100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Razaq, R; Din, MMU; Småbråten, DR; Eyupoglu, V; Janakiram, S; Sunde, TO; Allahgoli, N; Rettenwander, D; Deng, LY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Razaq, Rameez; Din, Mir Mehraj Ud; Smabraten, Didrik Rene; Eyupoglu, Volkan; Janakiram, Saravanull; Sunde, Tor Olav; Allahgoli, Nima; Rettenwander, Daniel; Deng, Liyuan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Synergistic Effect of Bimetallic MOF Modified Separator for Long Cycle Life Lithium-Sulfur Batteries", "Source Title": "ADVANCED ENERGY MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Severe polysulfide dissolution and shuttling are the main challenges that plague the long cycle life and capacity retention of lithium-sulfur (Li-S) batteries. To address these challenges, efficient separators are designed and modified with a dual functional bimetallic metal-organic framework (MOF). Flower-shaped bimetallic MOFs (i.e., Fe-ZIF-8) with nullostructured pores are synthesized at 35 degrees C in water by introducing dopant metal sites (Fe), which are then coated on a polypropylene (PP) separator to provide selective channels, thereby effectively inhibiting the migration of lithium polysulfides while allowing homogeneous transport of Li-ions. The active sites of the Fe-ZIF-8 enable electrocatalytic conversion, facilitating the conversion of lithium polysulfides. Moreover, the developed separator can prevent dendrite formation due to the uniform pore size and hence the even Li-ion transport and deposition. A coin cell using a Fe-ZIF-8/PP separator with S-loaded carbon cathode displayed a high cycle life of 1000 cycles with a high initial discharge capacity of 863 mAh g-1 at 0.5 C and a discharge capacity of 746 mAh g-1 at a high rate of 3 C. Promising specific capacity has been documented even under high sulfur loading of 5.0 mg cm-2 and electrolyte to the sulfur ratio (E/S) of 5 mu L mg-1. A multifunctional bimetallic MOF-based separator is designed specifically for lithium-sulfur batteries that can selectively block and convert polysulfides while providing even transport of lithium ions. Remarkably higher catalytic activity is found for the conversion of polysulfides by the Fe-doped MOF (ZIF-8) compared to the parent ZIF-8. Meanwhile, the incorporation of Fe (II) centers into the ZIF framework dramatically improves the specific capacity and rate capability.image", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 145, "Times Cited, All Databases": 145, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2024, "Volume": 14, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/aenm.202302897", "DOI Link": "http://dx.doi.org/10.1002/aenm.202302897", "Book DOI": null, "Early Access Date": "NOV 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Energy & Fuels; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001105691300001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Wang, SJ; Zhang, X; Tang, YX; Hao, SY; Zheng, SA; Qiao, J; Wang, Z; Wu, LL; Liu, JR; Wang, FL", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Wang, Shijie; Zhang, Xue; Tang, Yunxiang; Hao, Shuyan; Zheng, Sinull; Qiao, Jing; Wang, Zhou; Wu, Lili; Liu, Jiurong; Wang, Fenglong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Facile fabrication of biomass chitosan-derived magnetic carbon aerogels as multifunctional and high-efficiency electromagnetic wave absorption materials", "Source Title": "CARBON", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Biomass chitosan-derived porous carbon-based materials take the advantage of light weight, adjustable intrinsic conductivity, and environmental friendliness, attracting more attention in the field of electromagnetic compatibility. However, exploring a facile fabrication method to achieve rational structure design and electrical-magnetic coupling for electromagnetic absorption performance enhancement still remains challenging. Here, a unique honeycomb-like porous cobalt/carbon aerogel is fabricated through the directional freezing-drying and carbonization process, and abundant and even-distributed cobalt particles in-situ grow on the carbon skeletons. The aerogel exhibits an impressive electromagnetic wave absorption performance of a-75.8-dB absorption intensity and a-256.9-dB mm-1 specific reflection loss at a low filling content (10%), as well as an 8.53-GHz effective absorption bandwidth. Besides, the aerogel also demonstrates classy radar stealth and thermal insu-lation performance. The eco-friendly, easily fabricated, and high-performance cobalt/carbon aerogel suggests broad application prospects for electromagnetic compatibility and protection, thermal management, and multifarious electron devices.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 132, "Times Cited, All Databases": 133, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 5", "Publication Year": 2024, "Volume": 216, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 118528, "DOI": "10.1016/j.carbon.2023.118528", "DOI Link": "http://dx.doi.org/10.1016/j.carbon.2023.118528", "Book DOI": null, "Early Access Date": "OCT 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001092870600001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Tang, YQ; Mak, CH; Zhang, J; Jia, GH; Cheng, KC; Song, HS; Yuan, MJ; Zhao, SJ; Kai, JJ; Colmenares, JC; Hsu, HY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Tang, Yunqi; Mak, Chun Hong; Zhang, Jun; Jia, Guohua; Cheng, Kuan-Chen; Song, Haisheng; Yuan, Mingjian; Zhao, Shijun; Kai, Ji-Jung; Colmenares, Juan Carlos; Hsu, Hsien-Yi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Unravelling the Interfacial Dynamics of Bandgap Funneling in Bismuth-Based Halide Perovskites", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "An environmentally friendly mixed-halide perovskite MA(3)Bi(2)Cl(9-)(x)I(x) with a bandgap funnel structure has been developed. However, the dynamic interfacial interactions of bandgap funneling in MA(3)Bi(2)Cl(9-)(x)I(x) perovskites in the photoelectrochemical (PEC) system remain ambiguous. In light of this, single- and mixed-halide lead-free bismuth-based hybrid perovskites-MA(3)Bi(2)Cl(9-)(y)I(y) and MA(3)Bi(2)I(9) (named MBCl-I and MBI)-in the presence and absence of the bandgap funnel structure, respectively, are prepared. Using temperature-dependent transient photoluminescence and electrochemical voltammetric techniques, the photophysical and (photo)electrochemical phenomena of solid-solid and solid-liquid interfaces for MBCl-I and MBI halide perovskites are therefore confirmed. Concerning the mixed-halide hybrid perovskites MBCl-I with a bandgap funnel structure, stronger electronic coupling arising from an enhanced overlap of electronic wavefunctions results in more efficient exciton transport. Besides, MBCl-I's effective diffusion coefficient and electron-transfer rate demonstrate efficient heterogeneous charge transfer at the solid-liquid interface, generating improved photoelectrochemical hydrogen production. Consequently, this combination of photophysical and electrochemical techniques opens up an avenue to explore the intrinsic and interfacial properties of semiconductor materials for elucidating the correlation between material characterization and device performance.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 177, "Times Cited, All Databases": 177, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 12", "Publication Year": 2023, "Volume": 35, "Issue": 2, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202207835", "DOI Link": "http://dx.doi.org/10.1002/adma.202207835", "Book DOI": null, "Early Access Date": "NOV 2022", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000888939100001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Li, XM; Dong, QB; Li, F; Zhu, QH; Tian, QY; Tian, L; Zhu, YY; Pan, B; Padervand, M; Wang, CY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Li, Ximing; Dong, Qibing; Li, Fei; Zhu, Qiuhui; Tian, Qingyun; Tian, Lin; Zhu, Yiyin; Pan, Bao; Padervand, Mohsen; Wang, Chuanyi", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Defective Bi@BiOBr/C microrods derived from Bi-MOF for efficient photocatalytic NO abatement: Directional regulation of interfacial charge transfer via carbon-loading", "Source Title": "APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The implementation of precisely directional electron transfer at the interface of catalysts is still considered a huge challenge. Herein, hierarchical Bi@BiOBr/C microrods derived from a novel Bi-MOF were employed as a model to precisely construct the atomic-level interface electrons transfer channels via carbon-bismuth bonding. The optimized Bi@BiOBr/C with plasmonic Bi and oxygen vacancies exhibited a photocatalytic removal efficiency of 69.5 % for ppb-level atmospheric NO, which is 3.5 times higher than that of pure BiOBr (19.8 %). The enhanced photocatalytic performance is owing to precisely constructed electron transport channels with loaded graphitic carbon as a bridge (i.e., BiOBr -> graphitic carbon -> Bi nulloparticles). Further DFT calculations demonstrated the built-in graphitic carbon reconstructs an Ohmic contact with BiOBr and eliminates the Schottky barrier between BiOBr and Bi nulloparticles, enhancing the photoelectron transfer efficiency. This research represents an exciting case for the modulation of photoelectron transfer at the catalysts interface for air purification.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 71, "Times Cited, All Databases": 72, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN", "Publication Year": 2024, "Volume": 340, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 123238, "DOI": "10.1016/j.apcatb.2023.123238", "DOI Link": "http://dx.doi.org/10.1016/j.apcatb.2023.123238", "Book DOI": null, "Early Access Date": "SEP 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001076231400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhang, X; Su, H; Cui, PX; Cao, YY; Teng, ZY; Zhang, QT; Wang, Y; Feng, YB; Feng, R; Hou, JX; Zhou, XY; Ma, PJ; Hu, HW; Wang, KW; Wang, C; Gan, LY; Zhao, YX; Liu, QH; Zhang, TR; Zheng, K", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhang, Xu; Su, Hui; Cui, Peixin; Cao, Yongyong; Teng, Zhenyuan; Zhang, Qitao; Wang, Yang; Feng, Yibo; Feng, Ran; Hou, Jixiang; Zhou, Xiyuan; Ma, Peijie; Hu, Hanwen; Wang, Kaiwen; Wang, Cong; Gan, Liyong; Zhao, Yunxuan; Liu, Qinghua; Zhang, Tierui; Zheng, Kun", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Developing Ni single-atom sites in carbon nitride for efficient photocatalytic H2O2 production", "Source Title": "NATURE COMMUNICATIONS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Photocatalytic two-electron oxygen reduction to produce high-value hydrogen peroxide (H2O2) is gaining popularity as a promising avenue of research. However, structural evolution mechanisms of catalytically active sites in the entire photosynthetic H2O2 system remains unclear and seriously hinders the development of highly-active and stable H2O2 photocatalysts. Herein, we report a high-loading Ni single-atom photocatalyst for efficient H2O2 synthesis in pure water, achieving an apparent quantum yield of 10.9% at 420nm and a solar-to-chemical conversion efficiency of 0.82%. Importantly, using in situ synchrotron X-ray absorption spectroscopy and Raman spectroscopy we directly observe that initial Ni-N-3 sites dynamically transform into high-valent O-1-Ni-N-2 sites after O-2 adsorption and further evolve to form a key *OOH intermediate before finally forming HOO-Ni-N-2. Theoretical calculations and experiments further reveal that the evolution of the active sites structure reduces the formation energy barrier of *OOH and suppresses the O=O bond dissociation, leading to improved H2O2 production activity and selectivity.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 172, "Times Cited, All Databases": 175, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "NOV 6", "Publication Year": 2023, "Volume": 14, "Issue": 1, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 7115, "DOI": "10.1038/s41467-023-42887-y", "DOI Link": "http://dx.doi.org/10.1038/s41467-023-42887-y", "Book DOI": null, "Early Access Date": null, "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001142811000024", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Awual, E; Salman, MS; Hasan, MM; Hasan, MN; Kubra, KT; Sheikh, MC; Rasee, AI; Rehan, AI; Waliullah, RM; Hossain, MS; Marwani, HM; Asiri, AM; Rahman, MM; Islam, A; Khaleque, MA; Awual, MR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Awual, Eti; Salman, Md Shad; Hasan, Md Munjur; Hasan, Md Nazmul; Kubra, Khadiza Tul; Sheikh, Md Chanmiya; Rasee, Adiba Islam; Rehan, Ariyan Islam; Waliullah, R. M.; Hossain, Mohammed Sohrab; Marwani, Hadi M.; Asiri, Abdullah M.; Rahman, Mohammed M.; Islam, Aminul; Khaleque, Md Abdul; Awual, Md Rabiul", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ligand imprinted composite adsorbent for effective Ni(II) ion monitoring and removal from contaminated water", "Source Title": "JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Heavy metal especially nickel (Ni(II)) is the most pernicious kind of pollution since it is both poisonous and difficult to break down in nature and can cause many human disorders and diseases. The monitoring and removal of Ni(II) ions optically is required to enhance the quality of the water and make it appropriate for drinking as well as other uses around the residence. Therefore, the goal of the current work was to synthesize ligand imprinted composite adsorbent (MCA) and utilize it as an adsorbent to monitor and remove Ni(II) ions from the water. Based on the findings gathered, the MCA that was synthesized had a large particle size with a high surface area even after the ligand impregnation. The MCA was enhanced significantly in color with the contact of Ni(II) ion with limit detection at 0.35 mu g/L. The maximum level of Ni(II) ions was eliminated (99 %) when the pH was adjusted to 5.50. The Langmuir model was also used to study the adsorption equilibrium data and the maximum adsorption capacity was 167.55 mg/g. Additionally, the method can selectively detect and remove Ni(II) even in the presence of diverse metal ions. Overall, the MCA offers an ideal platform for the on-site monitoring and removal of heavy metal ions, especially in resource-limited areas.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 164, "Times Cited, All Databases": 168, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 25", "Publication Year": 2024, "Volume": 131, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 585, "End Page": 592, "Article Number": null, "DOI": "10.1016/j.jiec.2023.10.062", "DOI Link": "http://dx.doi.org/10.1016/j.jiec.2023.10.062", "Book DOI": null, "Early Access Date": "DEC 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001142454000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Zhu, HH; Qin, G; Zhou, W; Li, Y; Zhou, XB", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Zhu, Henghai; Qin, Gang; Zhou, Wei; Li, Yang; Zhou, Xiaobing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Constructing flake-like ternary rare earth Pr3Si2C2 ceramic on SiC whiskers to enhance electromagnetic wave absorption properties", "Source Title": "CERAMICS INTERNATIONAL", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, flaky-like ternary Pr3Si2C2 was successfully coated in SiC whiskers (SiCw) via a molten salt process to augment the electromagnetic wave absorption (EWA) efficiency and expand the application potential of ternary rare earth silicate (RE3Si2C2) materials. Comprehensive investigations into the phase composition, morphological characteristics, EWA capacity, and corresponding mechanisms of the material were conducted. Furthermore, the electric field distribution is simulated and calculated for both vertical and horizontal incidence of the electromagnetic wave (EMW) on the specimens. Results showed that the incorporation of Pr3Si2C2 coating on SiC whiskers induces the development of heterogeneous interfaces and conductive networks, thereby augmenting polarization loss and conductive polarization, correspondingly enhancing the EWA performance of the material. In synergy with excellent attenuation ability and enhanced impedance matching, the Pr3Si2C2/SiCw composite demonstrates superior EWA performance in comparison to pristine SiCw. The minimum reflection loss (RLmin) of Pr3Si2C2/SiCw composites was achieved -48.117 dB accompanied by the effective absorption bandwidth (EAB) of 5.04 GHz at a thin thickness of merely 2.71 mm in the frequency range of 2-18 GHz. This research will serve as a valuable reference for the investigation of ternary rare earth ceramic-based EWA material.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 65, "Times Cited, All Databases": 67, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2024, "Volume": 50, "Issue": 1, "Part Number": "A", "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 134, "End Page": 142, "Article Number": null, "DOI": "10.1016/j.ceramint.2023.10.050", "DOI Link": "http://dx.doi.org/10.1016/j.ceramint.2023.10.050", "Book DOI": null, "Early Access Date": "DEC 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001131768000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Yang, SY; Wang, KL; Chen, Q; Wu, Y", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Yang, Songyu; Wang, Kailin; Chen, Qiao; Wu, Yan", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Enhanced photocatalytic hydrogen production of S-scheme TiO2/g-C3 N 4 heterojunction loaded with single-atom Ni", "Source Title": "JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "S-scheme heterostructure photocatalysts can achieve highly efficient solar energy utilization. Here, singleatom Ni species were deposited onto TiO 2 /g-C 3 N 4 (TCN) composite photocatalyst with an S-scheme heterojunction for highly efficient photocatalytic water splitting to produce hydrogen. Under solar irradiation, it realized the hydrogen production activity of 134 mu mol g -1 h -1 , about 5 times higher than the TCN without atomic Ni. In-situ Kelvin probe force microscopy characterization and the density functional calculation certify that by forming the S-scheme heterojunction, the photo-excited electrons from the TiO 2 combine with the photogenerated holes at the coupled g-C 3 N 4 driven by a built-in electric field. More importantly, the single-atom Ni species stabilized the photogenerated electrons from the g-C 3 N 4 could effectively enhance the charge separation between the holes on the valence band of TiO 2 and electrons at the conduction band of g-C 3 N 4 . Meanwhile, the Ni atoms act as the surface catalytic centers for the water reduction reaction, which greatly improves the reactivity of the photocatalyst. The present work provides a new approach for developing noble metal-free heterojunctions for high-efficiency photocatalysis. (c) 2023 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 82, "Times Cited, All Databases": 83, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 10", "Publication Year": 2024, "Volume": 175, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": 104, "End Page": 114, "Article Number": null, "DOI": "10.1016/j.jmst.2023.07.044", "DOI Link": "http://dx.doi.org/10.1016/j.jmst.2023.07.044", "Book DOI": null, "Early Access Date": "SEP 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Materials Science; Metallurgy & Metallurgical Engineering", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001079213500001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Hui, SC; Zhou, X; Zhang, LM; Wu, HJ", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Hui, Shengchong; Zhou, Xu; Zhang, Limin; Wu, Hongjing", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Constructing Multiphase-Induced Interfacial Polarization to Surpass Defect-Induced Polarization in Multielement Sulfide Absorbers", "Source Title": "ADVANCED SCIENCE", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "The extremely weak heterointerface construction of high-entropy materials (HEM) hinders them being the electromagnetic wave (EMW) absorbers with ideal properties. To address this issue, this study proposes multiphase interfacial engineering and results in a multiphase-induced interfacial polarization loss in multielement sulfides. Through the selection of atoms with diverse reaction activities, the multiphase interfacial components of CuS (1 0 5), Fe0.5Ni0.5S2 (2 1 0), and CuFe2S3 (2 0 0) are constructed to enhance the interfacial polarization loss in multielement Cu-based sulfides. Compared with single-phase high-entropy Zn-based sulfides (ZnFeCoNiCr-S), the multiphase Cu-based sulfides (CuFeCoNiCr-S) possess optimized EMW absorption properties (effective absorption bandwidth (EAB) of 6.70 GHz at 2.00 mm) due to the existence of specific interface of CuS (1 0 5)/CuFe2S3 (2 0 0) with proper EM parameters. Furthermore, single-phase ZnFeCoNiCr-S into FeNi2S4 (3 1 1)/(Zn, Fe)S (1 1 1) heterointerface through 400 degrees C heat-treated is decomposed. The EMW absorption properties are enhanced by strong interfacial polarization (EAB of 4.83 GHz at 1.45 mm). This work reveals the reasons for the limited EMW absorption properties of high-entropy sulfides and proposes multiphase interface engineering to improve charge accumulation and polarization between specific interfaces, leading to the enhanced EMW absorption properties. This work shows that the weak electron exchange effect induced by high conformational entropy adversely affects microwave absorption. Constructing the heterointerfaces with significantly different work functions in multi-element sulfides can effectively enhance the phase interface polarization and eliminate these negative effects. This is expected to serve as a new design guideline for microwave absorbers.image", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 70, "Times Cited, All Databases": 71, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "FEB", "Publication Year": 2024, "Volume": 11, "Issue": 6, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/advs.202307649", "DOI Link": "http://dx.doi.org/10.1002/advs.202307649", "Book DOI": null, "Early Access Date": "DEC 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001113438000001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Ye, RP; Ma, LX; Hong, XL; Reina, TR; Luo, WH; Kang, LQ; Feng, G; Zhang, RB; Fan, MH; Zhang, RG; Liu, J", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Ye, Runping; Ma, Lixuan; Hong, Xiaoling; Reina, Tomas Ramirez; Luo, Wenhao; Kang, Liqun; Feng, Gang; Zhang, Rongbin; Fan, Maohong; Zhang, Riguang; Liu, Jian", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Boosting Low-Temperature CO2 Hydrogenation over Ni-based Catalysts by Tuning Strong Metal-Support Interactions", "Source Title": "ANGEWANDTE CHEMIE-INTERNATIONAL EDITION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Rational design of low-cost and efficient transition-metal catalysts for low-temperature CO2 activation is significant and poses great challenges. Herein, a strategy via regulating the local electron density of active sites is developed to boost CO2 methanation that normally requires >350 degrees C for commercial Ni catalysts. An optimal Ni/ZrO2 catalyst affords an excellent low-temperature performance hitherto, with a CO2 conversion of 84.0 %, CH4 selectivity of 98.6 % even at 230 degrees C and GHSV of 12,000 mL g(-1) h(-1) for 106 h, reflecting one of the best CO2 methanation performance to date on Ni-based catalysts. Combined a series of in situ spectroscopic characterization studies reveal that re-constructing monoclinic-ZrO2 supported Ni species with abundant oxygen vacancies can facilitate CO2 activation, owing to the enhanced local electron density of Ni induced by the strong metal-support interactions. These findings might be of great aid for construction of robust catalysts with an enhanced performance for CO2 emission abatement and beyond.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 89, "Times Cited, All Databases": 89, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 15", "Publication Year": 2024, "Volume": 63, "Issue": 3, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/anie.202317669", "DOI Link": "http://dx.doi.org/10.1002/anie.202317669", "Book DOI": null, "Early Access Date": "DEC 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "Y", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001117638400001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Deng, ZX; Zhang, H; Priimagi, A; Zeng, H", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Deng, Zixuan; Zhang, Hang; Priimagi, Arri; Zeng, Hao", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Light-Fueled Nonreciprocal Self-Oscillators for Fluidic Transportation and Coupling", "Source Title": "ADVANCED MATERIALS", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "Light-fueled self-oscillators based on soft actuating materials have triggered novel designs for small-scale robotic constructs that self-sustain their motion at non-equilibrium states and possess bioinspired autonomy and adaptive functions. However, the motions of most self-oscillators are reciprocal, which hinders their use in sophisticated biomimetic functions such as fluidic transportation. Here, an optically powered soft material strip that can perform nonreciprocal, cilia-like, self-sustained oscillation under water is reported. The actuator is made of planar-aligned liquid crystal elastomer responding to visible light. Two laser beams from orthogonal directions allow for piecewise control over the strip deformation, enabling two self-shadowing effects coupled in one single material to yield nonreciprocal strokes. The nonreciprocity, stroke pattern and handedness are connected to the fluidic pumping efficiency, which can be controlled by the excitation conditions. Autonomous microfluidic pumping in clockwise and anticlockwise directions, translocation of a micro-object by liquid propulsion, and coupling between two oscillating strips through liquid medium interaction are demonstrated. The results offer new concepts for non-equilibrium soft actuators that can perform bio-like functions under water.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 86, "Times Cited, All Databases": 86, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR", "Publication Year": 2024, "Volume": 36, "Issue": 12, "Part Number": null, "Supplement": null, "Special Issue": "SI", "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": null, "DOI": "10.1002/adma.202209683", "DOI Link": "http://dx.doi.org/10.1002/adma.202209683", "Book DOI": null, "Early Access Date": "JAN 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Science & Technology - Other Topics; Materials Science; Physics", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:000906511900001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Xu, MF; Ni, XX; Liu, QW; Chen, CC; Deng, XH; Wang, X; Yu, RR", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Xu, Mingfeng; Ni, Xiangxiang; Liu, Qiwei; Chen, Chengcheng; Deng, Xiaohong; Wang, Xiu; Yu, Rongrong", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Ultra-high pressure improved gelation and digestive properties of Tai Lake whitebait myofibrillar protein", "Source Title": "FOOD CHEMISTRY-X", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "This study investigated the effects of ultra-high pressure (UHP) at different levels on the physicochemical properties, gelling properties, and in vitro digestion characteristics of myofibrillar protein (MP) in Tai Lake whitebait. The alpha-helix gradually unfolded and transformed into beta-sheet as the pressure increased from 0 to 400 MPa. In addition, the elastic modulus (G') and viscous modulus (G) of the 400 MPa-treated MP samples increased by 4.8 and 3.8 times, respectively, compared with the control group. The gel properties of the MP also increased significantly after UHP treatment, e.g., the gel strength increased by a 4.8-fold when the pressure reached 400 Mpa, compared with the control group. The results of in vitro simulated digestion showed that the 400 MPa-treated MP gel samples showed a 1.8-fold increase in digestibility and a 69.6 % decrease in digestible particle size compared with the control group.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 55, "Times Cited, All Databases": 55, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "MAR 30", "Publication Year": 2024, "Volume": 21, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 101061, "DOI": "10.1016/j.fochx.2023.101061", "DOI Link": "http://dx.doi.org/10.1016/j.fochx.2023.101061", "Book DOI": null, "Early Access Date": "DEC 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Chemistry; Food Science & Technology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001137691700001", "Web of Science Record": "View Full Record in Web of Science" }, { "Publication Type": "J", "Authors": "Luo, D; Wu, ZH; Yan, YY; Cao, J; Yang, XL; Zhao, YL; Cao, BY", "Book Authors": null, "Book Editors": null, "Book Group Authors": null, "Author Full Names": "Luo, Ding; Wu, Zihao; Yan, Yuying; Cao, Jin; Yang, Xuelin; Zhao, Yulong; Cao, Bingyang", "Book Author Full Names": null, "Group Authors": null, "Article Title": "Performance investigation and design optimization of a battery thermal management system with thermoelectric coolers and phase change materials", "Source Title": "JOURNAL OF CLEANER PRODUCTION", "Book Series Title": null, "Book Series Subtitle": null, "Language": null, "Document Type": "Article", "Conference Title": null, "Conference Date": null, "Conference Location": null, "Conference Sponsor": null, "Conference Host": null, "Author Keywords": null, "Keywords Plus": null, "Abstract": "In this work, a novel battery thermal management system (BTMS) integrated with thermoelectric coolers (TECs) and phase change materials (PCMs) is developed to ensure the temperature working environment of batteries, where a fin framework is adopted to enhance the heat transfer. By establishing a transient thermal-electric-fluid multi-physics field numerical model, the thermal performance of the BTMS is thoroughly examined in two cases. The findings demonstrate that increasing the TEC input current, fin length, and thickness is beneficial for reducing the maximum temperature and PCM liquid fraction. Nevertheless, although the increase in fin length can lower the temperature difference, the influence of fin thickness and TEC input current on the temperature difference is tiny. Based on the numerical findings, the optimal fin length and thickness of 7 mm and 3 mm are obtained. In this situation, when the TEC input current is 3 A, the maximum temperature, temperature difference, and PCM liquid fraction in Case 1 are 315.10 K, 2.39 K, and 0.002, respectively, and those are respectively 318.24 K, 3.60 K, and 0.181 in Case 2. The configuration of Case 1 outperforms that of Case 2, due to the fewer TECs and greater distance from the battery pack to the TEC within Case 2. When experiencing a higher battery discharge rate, the TEC input current should also be correspondingly increased to ensure the temperature performance of the battery. The relative findings contribute to new insights into battery thermal management.", "Addresses": null, "Affiliations": null, "Reprint Addresses": null, "Email Addresses": null, "Researcher Ids": null, "ORCIDs": null, "Funding Orgs": null, "Funding Name Preferred": null, "Funding Text": null, "Cited References": null, "Cited Reference Count": null, "Times Cited, WoS Core": 60, "Times Cited, All Databases": 61, "180 Day Usage Count": null, "Since 2013 Usage Count": null, "Publisher": null, "Publisher City": null, "Publisher Address": null, "ISSN": null, "eISSN": null, "ISBN": null, "Journal Abbreviation": null, "Journal ISO Abbreviation": null, "Publication Date": "JAN 1", "Publication Year": 2024, "Volume": 434, "Issue": null, "Part Number": null, "Supplement": null, "Special Issue": null, "Meeting Abstract": null, "Start Page": null, "End Page": null, "Article Number": 139834, "DOI": "10.1016/j.jclepro.2023.139834", "DOI Link": "http://dx.doi.org/10.1016/j.jclepro.2023.139834", "Book DOI": null, "Early Access Date": "NOV 2023", "Number of Pages": null, "WoS Categories": null, "Web of Science Index": null, "Research Areas": "Science & Technology - Other Topics; Engineering; Environmental Sciences & Ecology", "IDS Number": null, "Pubmed Id": null, "Open Access Designations": null, "Highly Cited Status": "Y", "Hot Paper Status": "N", "Date of Export": "2025-04-23", "UT (Unique WOS ID)": "WOS:001130014000001", "Web of Science Record": "View Full Record in Web of Science" } ]