commit bccb974250db3498d5f0742624e013a6789b0a74 Author: lzy <949777411@qq.com> Date: Thu May 8 11:32:28 2025 +0800 first commit code diff --git a/code/__pycache__/make_qa_prompts_bp.cpython-311.pyc b/code/__pycache__/make_qa_prompts_bp.cpython-311.pyc new file mode 100644 index 0000000..db70dcf Binary files /dev/null and b/code/__pycache__/make_qa_prompts_bp.cpython-311.pyc differ diff --git a/code/make_qa_bp.log b/code/make_qa_bp.log new file mode 100644 index 0000000..f20c86a --- /dev/null +++ b/code/make_qa_bp.log @@ -0,0 +1,173 @@ +task1文件总数: 209 +过滤后task1文件数: 209 +task2文件总数: 209 +过滤后task2文件数: 209 +[{'id': 1, 'text': 'Dimethyl allylphosphonate is provided as the molecule to enhance the hydrophilicity of the polymer. How would you incorporate this molecule into the plasma-enhanced chemical vapor deposition (PECVD) process to ensure efficient modification of the polymer surface?'}, {'id': 2, 'text': 'Considering dimethyl allylphosphonate, explain how you would optimize the PECVD process parameters, such as plasma power and pulsed versus continuous plasma configuration, to achieve uniform surface modification of the polymer.'}, {'id': 3, 'text': 'After modifying the polymer using dimethyl allylphosphonate, describe how you would confirm that the hydrophilicity of the polymer has been enhanced. Specify the techniques you would use and what evidence you would look for.'}] +[{'id': 1, 'text': 'Describe the role of silicon dioxide (SiO2) in the experimental design for modifying polymers to enhance their hydrophilicity. Why is SiO2 an effective choice in this context?'}, {'id': 2, 'text': 'When applying the silicon dioxide (SiO2) coating to a polymer substrate, why is it necessary to repeat the spray coating and heating processes multiple times? Discuss the potential impact on the surface properties.'}, {'id': 3, 'text': 'Explain how the surface chemistry of silicon dioxide (SiO2) contributes to the hydrophilicity of the modified polymer. In your response, consider the types of functional groups or interactions involved.'}] +[{'id': 1, 'text': "Describe the process for utilizing ethanol as a reaction medium in the synthesis of hydrophilic polymers, specifying the role it plays in modifying the polymer with the molecule 'acryloyloxyethyltrimethylammonium chloride.'"}, {'id': 2, 'text': "What is the purpose of using the molecule 'acryloyloxyethyltrimethylammonium chloride' in the reaction, and how would you confirm the completion of the reaction via FT-IR analysis?"}, {'id': 3, 'text': "Explain how you would incorporate 'acryloyloxyethyltrimethylammonium chloride' into a polymer backbone to introduce hydrophilic properties, and describe the subsequent steps required to prepare the final polymer material."}] +[{'id': 1, 'text': 'How would you incorporate glycerol dimethacrylate into a thermoplastic polymer matrix to enhance its hydrophilicity? Detail the steps for blending it with other components and describe the curing process.'}, {'id': 2, 'text': 'Using bisphenol-A-ethoxylate diacrylate as a hydrophilic acrylate, design an experimental workflow to prepare a coating composition. Specify the types of initiators and surfactants you might use and their respective roles.'}, {'id': 3, 'text': 'When employing poly(ethyleneoxy)methacrylate as a hydrophilic component in polymer synthesis, explain how you would ensure a homogenous mixture with the polymer matrix and achieve proper crosslinking during curing.'}] +[{'id': 1, 'text': 'Using 1,6-hexamethylene diisocyanate biuret, design an experiment to prepare a polymer with enhanced hydrophilicity by reacting it with hydroxyl-containing compounds. Specify the reaction conditions, including temperature, catalysts, and solvents, and explain the chemical mechanism involved.'}, {'id': 2, 'text': 'How would you incorporate poly(ethoxylate-b-caprolactone) monomethacrylate oligomer as a functionalizing agent to create a hydrophilic polymer? Describe the step-by-step process and the expected structural changes to the polymer backbone.'}, {'id': 3, 'text': 'Devise a polymerization protocol utilizing 2-hydroxyethyl methacrylate to introduce hydrophilic functional groups onto a polymer. Discuss how this monomer contributes to the overall hydrophilicity enhancement and outline all necessary materials and conditions for the synthesis.'}] +[{'id': 1, 'text': "Describe how you would use 4,4'-diphenylmethane diisocyanate (MDI) in the preparation of a hydrophilic polymer. Specifically, discuss its role in the reaction and how you would ensure its proper handling and incorporation into the reaction mixture to enhance the polymer's hydrophilicity."}, {'id': 2, 'text': 'Explain how you would monitor the progress of the polymerization reaction involving MDI using Raman spectroscopy. Identify which spectral feature of MDI you would focus on and how you would use this information to determine the conversion of the reaction.'}, {'id': 3, 'text': 'Given the goal of enhancing hydrophilicity, describe how the reaction conditions and stoichiometric ratio of MDI to other components should be optimized to achieve a polymer with functional groups conducive to hydrophilicity. What factors would you consider during your experimental setup?'}] +[{'id': 1, 'text': 'Describe the process by which tannic acid (TA) can act as a crosslinking agent to enhance the hydrophilicity of polyvinyl alcohol (PVA). How does the interaction between these two molecules occur?'}, {'id': 2, 'text': 'When preparing a hydrophilic polymer using tannic acid (TA) and polyvinyl alcohol (PVA), what solvent system would you recommend to achieve good processability and stability of the mixture? Justify your choice.'}, {'id': 3, 'text': 'Explain how the gradual removal of ethanol from a polymer solution containing polyvinyl alcohol (PVA) and tannic acid (TA) might influence the formation of a stable crosslinked structure. What role does hydrogen bond reestablishment play in this process?'}] +[{'id': 1, 'text': "Describe the role of 2-acrylamido-2-methylpropanesulfonic acid (AMPS) when preparing a hydrophilic polymer. How does its incorporation influence the polymer's properties, particularly its hydrophilicity?"}, {'id': 2, 'text': 'Explain how you would use triethoxyvinylsilane (A151) in the synthesis of a hydrophilic polymer. Specify the conditions and steps required for this molecule to effectively contribute to the polymerization process.'}, {'id': 3, 'text': "Consider 3-methacryloxypropyltrimethoxysilane (KH570) as a component in the preparation of a hydrophilic polymer. Discuss the role of KH570 during polymerization and its influence on the final polymer's structure and functionality."}] +[{'id': 1, 'text': "Given the molecule 'methoxy polyethylene glycol acrylate', outline a detailed experimental procedure for its use in forming an amine-terminated intermediate that can be further modified to enhance the hydrophilicity of a polymer material."}, {'id': 2, 'text': "How would you confirm the reaction progress when utilizing 'methoxy polyethylene glycol acrylate' in the first step of the experiment to produce a double-ended secondary amine compound? Specify the analytical technique and the specific characteristic you would monitor."}, {'id': 3, 'text': "After successfully reacting 'methoxy polyethylene glycol acrylate' to prepare an intermediate, propose how you would further modify the intermediate to synthesize a hydrophilic UV-curable resin. Ensure your explanation accounts for temperature control and reaction time."}] +[{'id': 1, 'text': 'Describe the role of N-hydroxymethylacrylamide in the synthesis of hydrophilic polymers and explain how its inclusion in the polymer mixture might contribute to enhancing hydrophilicity.'}, {'id': 2, 'text': 'Design an experimental procedure to incorporate 2-acrylamido-2-methylpropanesulfonic acid into a polymer matrix. Discuss how this molecule specifically improves the hydrophilicity of the resulting material.'}, {'id': 3, 'text': 'How would you optimize the concentration of N,N-dimethylacrylamide in your polymer formulation to balance hydrophilicity and other required properties of the material? Outline your approach and the reasoning behind your decisions.'}] +[{'id': 1, 'text': 'How would you utilize allyl ether sulfate to introduce hydrophilic properties into a polymer during the synthesis process? Please propose a step-by-step experimental scheme.'}, {'id': 2, 'text': 'Explain the role of allyl ether sulfate in enhancing hydrophilicity during the polymer modification process. How does it contribute to the final polymer structure?'}, {'id': 3, 'text': 'Design an experiment using allyl ether sulfate to modify a polymer. Outline the quantities and conditions you would use, specifying the stages where allyl ether sulfate is added.'}] +[{'id': 1, 'text': 'Explain how hexamethyldisilazane (HMDS) can be utilized to modify a polymer surface in order to enhance its hydrophilicity. Provide details on how the molecule interacts with functional groups on the surface.'}, {'id': 2, 'text': 'Design an experimental procedure using HMDS to evaluate how its exposure time affects the contact angle of water on a polymer surface. Include steps for surface cleaning, treatment, and analysis.'}, {'id': 3, 'text': "How would you assess the stability of the hydrophilicity enhancement achieved through HMDS over time? Propose a method, including any metrics or measurements you would use, to monitor changes in the polymer's surface properties."}] +[{'id': 1, 'text': "Describe the role of 2-Acrylamido-2-methyl propane sulfonic acid (AMPS) in the synthesis of a hydrophilic polymer. How would varying its proportion affect the final material's performance?"}, {'id': 2, 'text': 'Explain how you would utilize 3-Trimethoxysilylpropyl methacrylate (TMSMA) in the experiment to improve adhesion of the polymer to a glass substrate. What specific steps would you take to activate the substrate prior to applying the polymer coating?'}, {'id': 3, 'text': 'Outline an experimental approach to determine the impact of different concentrations of ethylene glycol dimethacrylate (EGDMA) on the hydrophilic and mechanical properties of the final polymer material.'}] +[{'id': 1, 'text': 'Given a molecule with the functional group —CO2H, outline the steps you would take to incorporate this molecule into the synthesis of a hydrophilic polyurethane polymer as part of the modification process. Ensure your scheme checks for compatibility with the polyurethane matrix.'}, {'id': 2, 'text': 'A water dispersible polyurethane compound is to be modified using a silicone compound containing —OH groups. How would you determine the appropriate ratio of the silicone compound to the polyurethane compound to ensure uniform dispersion while maintaining film integrity?'}, {'id': 3, 'text': 'Describe the necessary conditions to neutralize acid functionalities in a polymer dispersion preparation using triethylamine, focusing on its role in enhancing hydrophilicity and the subsequent impact on the polymer’s properties. How would you verify the completion of the neutralization reaction?'}] +[{'id': 1, 'text': 'Describe how you would use multifactorial aziridines, such as CX-100, as crosslinking agents during the preparation of a hydrophilic polymer. What role do these crosslinking agents play in improving the hydrophilicity of the polymer material?'}, {'id': 2, 'text': 'In an experiment involving the modification of a polymer to enhance hydrophilicity, how would you incorporate succinic anhydride as a reagent? Discuss the chemical changes and hydrophilic features that result from its use.'}, {'id': 3, 'text': 'Explain the steps you would take to utilize an alicyclic epoxy resin such as ERL-4221 in synthesizing a hydrophilic polymer. What properties of this molecule make it suitable for this purpose?'}] +[{'id': 1, 'text': 'Describe the steps you would take to use sulfonic acid group-containing surfactants to prepare a modified hydrophilic polymer. Include the reaction conditions and catalysts required for the process.'}, {'id': 2, 'text': 'Explain how you would graft glycidyl methacrylate onto a surfactant containing a carboxylic acid group to enhance its hydrophilic properties. Outline the necessary reaction steps and parameters.'}, {'id': 3, 'text': 'When using a catalyst like dibutyltin oxide to prepare a modified surfactant, what precautions must be taken during the reaction, and how does this influence the subsequent polymer hydrophilicity enhancement?'}] +[{'id': 1, 'text': 'Given the molecule 2,4,7,9-tetramethyl-5-decyne-4,7-diol tetraethoxy ether, plan an experimental procedure to modify a polymer in order to enhance its hydrophilicity. Specify the solvents, temperature range, and any catalysts you would use to facilitate the reaction.'}, {'id': 2, 'text': 'When incorporating the molecule 2,4,7,9-tetramethyl-5-decyne-4,7-diol tetraethoxy ether into a reaction to synthesize a hydrophilic polymer, what parameters would you optimize (e.g., molar ratios, reaction time, or catalyst concentration) to achieve a controllable and uniform modification?'}, {'id': 3, 'text': 'Describe the role of 2,4,7,9-tetramethyl-5-decyne-4,7-diol tetraethoxy ether when used in the preparation of hydrophilic polymers. How would you confirm that the resulting polymer has improved hydrophilicity compared to its unmodified counterpart?'}] +[{'id': 1, 'text': 'Explain how zinc chloride (ZnCl2) can be incorporated into an experimental procedure to modify a polymer surface and enhance its hydrophilicity. Provide a detailed schematic of the steps you would propose.'}, {'id': 2, 'text': 'Design an experiment where ZnCl2 is used to functionalize a polymer material. Discuss the potential interactions between ZnCl2 and the polymer that could lead to an improvement in hydrophilicity.'}, {'id': 3, 'text': 'In the preparation of hydrophilic polymers, what factors should be considered when applying ZnCl2 to a substrate? Suggest specific parameters such as concentration, application method, and environmental conditions to achieve optimal results.'}] +[{'id': 1, 'text': 'Describe the steps required to synthesize an anti-fog modifier using octavinyl polyhedral oligomeric silsesquioxane and a polyether containing epoxy propylene and epoxy ethylene chains. Highlight the key reaction conditions you would implement to ensure a successful addition reaction.'}, {'id': 2, 'text': 'What type of catalyst would you select for the addition reaction involving octavinyl polyhedral oligomeric silsesquioxane and why? Specify the appropriate amount of the catalyst to use and explain its significance in the reaction.'}, {'id': 3, 'text': 'After synthesizing the anti-fog modifier with the above molecule, outline how you would integrate it into a water-based polymer resin system to enhance the hydrophilicity of the material. Include considerations for incorporating a crosslinking agent and any additional processing steps.'}] +[{'id': 1, 'text': 'One of the monomers mentioned in the experiment is 2-hydroxyethyl methacrylate. How would you incorporate this molecule into a polymer backbone to enhance the hydrophilicity of the polymer during the reaction process? Detail the specific steps and conditions you would use.'}, {'id': 2, 'text': 'Methacrylic acid is used in the preparation of hydrophilic polymers. How would the carboxylic acid groups in methacrylic acid contribute to the hydrophilic nature of the final polymer, and what strategies can you use to ensure proper polymerization and uniform incorporation of this monomer into the polymer structure?'}, {'id': 3, 'text': "The experimental scheme involves the use of poly(ethoxylate-b-caprolactone) monomethacrylate. How does this molecule's chemical structure aid in increasing the hydrophilicity of the polymer, and what parameters would you optimize to ensure efficient copolymerization and functionalization within the polymer matrix?"}] +[{'id': 1, 'text': 'Describe the steps you would take to synthesize a hydrophilic polymer using 3-isocyanatopropyltrimethoxysilane as a key molecule. Explain how this molecule contributes to the enhanced hydrophilicity of the polymer.'}, {'id': 2, 'text': 'When incorporating silane derivatives containing an epoxy group and polyethylene glycol chains into a polymeric network, what factors would you consider to ensure optimal hydrophilicity? Include how 3-isocyanatopropyltrimethoxysilane can influence these factors.'}, {'id': 3, 'text': 'In the preparation of a hydrophilic polymer, explain how you would confirm that 3-isocyanatopropyltrimethoxysilane has fully reacted within the system. What characterization technique would you use, and what specific signals or data would you look for?'}] +[{'id': 1, 'text': 'Explain how you would incorporate allyl polyether into the synthesis process in order to modify a polymer and enhance its hydrophilicity. Discuss any potential reaction mechanisms involved.'}, {'id': 2, 'text': 'Describe the role of allyl polyether in improving the hydrophilicity of a polymer. How would you ensure that its functional groups are effectively incorporated into the polymer structure?'}, {'id': 3, 'text': 'When using allyl polyether as the key modifier to enhance polymer hydrophilicity, what critical reaction conditions would you consider optimizing, and why are these important for the desired outcome?'}] +[{'id': 1, 'text': 'Explain how the functional molecule pentaerythritol triacrylate (PETA) can be used during the preparation of a polymer to enhance its hydrophilicity. What role does it play in the overall reaction scheme?'}, {'id': 2, 'text': 'Describe the steps you would take to incorporate sulfobetaine methacrylate (SBMA) into a polymer matrix. How does this molecule contribute to the hydrophilicity of the resulting polymer?'}, {'id': 3, 'text': 'Outline an experimental approach for utilizing acrylic acid (AA) in the synthesis of a hydrophilic polymer. What reactions need to occur to ensure the incorporation of this molecule into the polymer structure?'}] +[{'id': 1, 'text': 'Describe the process of incorporating titanium dioxide (TiO2) into a polymer matrix to enhance hydrophilicity. Specify how particle size and concentration may impact the final properties of the polymer.'}, {'id': 2, 'text': 'Explain how sodium alginate (SA) can be utilized in polymer modification to improve hydrophilicity. Discuss the importance of selecting the appropriate mass concentration of SA during the preparation process.'}, {'id': 3, 'text': 'Outline a detailed approach to dissolve polyvinyl alcohol (PVA) in a solvent mixture to prepare a solution that promotes hydrophilic properties in the final polymer. Highlight factors such as temperature and solvent ratios.'}] +[{'id': 1, 'text': 'How would you utilize N-vinylpyrrolidone (NVP) as a monomer in a polymerization process to improve the hydrophilicity of a polymer material? Describe the steps and conditions you would use in the process.'}, {'id': 2, 'text': 'Explain the role of polyvinylpyrrolidone (PVP), specifically when used in combination with other compounds, in creating graft polymerized coatings to enhance hydrophilicity. How would you ensure that PVP becomes effectively entrapped within the polymer matrix?'}, {'id': 3, 'text': 'Design a method to apply a hydrophilic coating onto the surface of a polymer using a combination of 2-hydroxyethyl-methacrylate (HEMA) and a radiation-induced polymerization technique. What parameters would you optimize to achieve a thin and uniform hydrophilic layer?'}] +[{'id': 1, 'text': 'Describe the role of isophorone diisocyanate in the synthesis of a hydrophilic polymer. What precautions should be taken when incorporating this molecule into the reaction to ensure optimal polymer linkages?'}, {'id': 2, 'text': 'When using 4-hydroxybutyl acrylate as a reactant, explain how its inclusion enhances the hydrophilicity of the final polymer. How would you ensure its reaction with other components is complete during the polymerization process?'}, {'id': 3, 'text': 'During free radical polymerization, you need to add IRGACURE 1173 as an initiator. Explain how you would incorporate this molecule in the reaction mixture and why it is critical to the curing process of the polymer network.'}] +[{'id': 1, 'text': 'In an experiment aimed at enhancing polymer hydrophilicity, how would you utilize methylacryloyloxyethyl-N,N-dimethylpropanesulfonate (DMAPS) as a monomer during the synthesis process? Please outline the preparation steps and reaction conditions.'}, {'id': 2, 'text': 'When incorporating 4-vinylpyridine (4-VP) into the synthesis of a hydrophilic polymer, what considerations must you take into account regarding reaction solvents, catalysts, or any auxiliary agents to ensure a successful modification?'}, {'id': 3, 'text': 'During the preparation of a zwitterionic copolymer using acrylamide (AM), describe the steps you would take to ensure proper polymerization and how you would assess the hydrophilicity enhancement achieved in the final product.'}] +[{'id': 1, 'text': 'Describe how you would utilize 2-(dimethylamino)ethyl methacrylate (DMAEMA) in the preparation of hydrophilic polymers using initiated chemical vapor deposition. Focus on the experimental parameters you would adjust to enhance the hydrophilicity of the resulting polymer.'}, {'id': 2, 'text': 'Considering 2-(dimethylamino)ethyl methacrylate (DMAEMA) as one of the monomers, how would you vary its flow rate during initiated chemical vapor deposition to influence the chemical composition of the copolymer for improved hydrophilicity? Justify your reasoning.'}, {'id': 3, 'text': 'If you were to use 2-(dimethylamino)ethyl methacrylate (DMAEMA) to increase the hydrophilic character of the polymer, what other experimental factors, aside from flow rate, would you prioritize during the initiated chemical vapor deposition process? Explain their impact on the hydrophilic properties.'}] +[{'id': 1, 'text': 'Describe the specific role of D(+)-glucose in modifying the polymer to enhance hydrophilicity during the synthesis process. How does its interaction influence the final polymer properties?'}, {'id': 2, 'text': "When preparing hydrophilic polymers, explain how Tollens' reagent interacts with the polymer material during the experimental procedure. What characteristics of this reagent make it suitable for this synthesis?"}, {'id': 3, 'text': 'Discuss how NaOH contributes to the polymer modification process aimed at enhancing hydrophilicity. What considerations must be taken when adding NaOH to the reaction system?'}] +[{'id': 1, 'text': 'How would you identify a commercially available monomer that can be polymerized to create a material with enhanced hydrophilicity using the molecule provided?'}, {'id': 2, 'text': 'Describe the process of using a polymerization reaction template to incorporate the molecule into a polymer structure in order to improve its hydrophilicity. Highlight any considerations specific to this molecule.'}, {'id': 3, 'text': 'What criteria would you use to evaluate the hydrophilicity of the modified polymer after integrating the given molecule into its structure? Propose a method to test this property experimentally.'}] +[{'id': 1, 'text': "How would you incorporate N,N-Dimethylacrylamide (DMAA) as a monomer to improve the hydrophilicity of the polymer during the synthesis process, and what role does this molecule play in the final material's properties?"}, {'id': 2, 'text': 'Describe how you would use a multi-functional isocyanate compound such as hexamethylene diisocyanate to crosslink the polymer and explain its significance in achieving the desired hydrophilic properties.'}, {'id': 3, 'text': 'Explain the importance of introducing a surfactant system that includes both an anionic surfactant and a cationic surfactant in the preparation of the hydrophilic polymer. How would you optimize their proportions to enhance anti-fogging performance?'}] +[{'id': 1, 'text': 'Explain how you would use imidazole, a molecule known to interact with activated double bonds, to modify the structure of a polymer material to enhance its hydrophilicity. Include the type of reaction you would expect to occur and the role of imidazole in this process.'}, {'id': 2, 'text': 'Describe the steps you would take to integrate imidazole into a formulation containing a nucleophilic addition product and an epoxy resin. How would you adjust the formulation to ensure proper functionality and hydrophilicity enhancement?'}, {'id': 3, 'text': "If you were to neutralize a portion of imidazole using an acid during the preparation process, how would this modification potentially influence the hydrophilic properties of the resulting polymer? Provide a detailed rationale based on imidazole's chemical behavior."}] +[{'id': 1, 'text': 'Describe how you would use a functionalized phosphate carbon to enhance the hydrophilicity of a polymer. Specify the steps you would take to incorporate this molecule into the polymer structure.'}, {'id': 2, 'text': 'What experimental parameters, such as temperature and chamber pressure, would you consider critical when utilizing functionalized phosphate carbon to modify the surface properties of a polymer?'}, {'id': 3, 'text': 'Explain the role of functionalized phosphate carbon in improving the hydrophilicity of a polymer and identify any limitations or challenges you might encounter during its application in a modification process.'}] +[{'id': 1, 'text': 'Explain how you would use DNA as a molecule to enhance the hydrophilicity of the polymer material in the experimental scheme, considering its structural and functional properties.'}, {'id': 2, 'text': 'Design a step-by-step procedure to immobilize DNA onto the polymer surface, ensuring that the modification increases the hydrophilic characteristics of the polymer.'}, {'id': 3, 'text': 'Describe the potential challenges you might face when immobilizing DNA onto the polymer and propose strategies to optimize the preparation process for achieving improved hydrophilicity.'}] +[{'id': 1, 'text': 'Describe the steps you would take to incorporate the given molecule into the polymer structure to enhance its hydrophilicity, ensuring you include any required reaction conditions or solvents.'}, {'id': 2, 'text': 'What characterization methods would you use to confirm the successful modification of the polymer with the molecule, and how would these methods demonstrate an increase in hydrophilicity?'}, {'id': 3, 'text': 'Explain how you would optimize the reaction parameters, such as temperature, pH, or catalyst choice, to maximize the efficiency of grafting the molecule onto the polymer while ensuring its hydrophilic properties are retained.'}] +[{'id': 1, 'text': "Describe how the molecule '3-methacryloxypropyltrimethoxysilane (MAPTMS)' can be utilized in a sol-gel process to modify a polymer for enhanced hydrophilicity. Specifically, outline the steps needed to hydrolyze and condense this molecule to create a suitable intermediate for further polymerization."}, {'id': 2, 'text': "Explain how the intermediate derived from 'MAPTMS' can be combined with other functional molecules to form a polymer composite. Include the types of functional groups that need to be present on the secondary molecule to ensure successful attachment and hydrophilic properties."}, {'id': 3, 'text': "Suggest and justify a method for controlling the hydrolyzation and condensation reactions of 'MAPTMS' to achieve optimal thermal and hydrolytic stability in the final hydrophilic polymer material."}] +[{'id': 1, 'text': 'Explain how you would incorporate black phosphorus (BP) sheets into a polymer material to improve its hydrophilicity. Detail the steps needed to prepare the BP sheets and any key parameters to consider during the process.'}, {'id': 2, 'text': 'When preparing a hydrogel using agarose as the polymer matrix, describe how black phosphorus (BP) sheets can be added to the system to enhance the hydrophilicity of the final material. Include the conditions needed for successful dispersion and integration.'}, {'id': 3, 'text': 'Discuss the potential role of black phosphorus (BP) sheets in modifying the water interaction properties of a hydrophilic polymer. Provide a step-by-step experimental outline that demonstrates how you would integrate these sheets into the polymer.'}] +[{'id': 1, 'text': 'Describe how you would utilize a cross-linking molecule to chemically modify a polymer in order to enhance its hydrophilicity. Provide details regarding the reaction conditions and the type of functional groups you would expect to introduce.'}, {'id': 2, 'text': 'Explain how you can design an experiment using a molecule capable of forming dynamic cross-links to prepare a hydrophilic polymer with controllable degradability. What factors would you consider to ensure the stability and functionality of the final material?'}, {'id': 3, 'text': 'Propose a method to integrate a molecule that facilitates physical cross-linking into a polymer structure to improve its hydrophilicity. How would you verify the hydrophilic enhancement of the resulting material experimentally?'}] +[{'id': 1, 'text': 'Describe the role of nano-SiO2 in modifying the polymer material and explain how it improves the hydrophilicity of the resulting polymer film.'}, {'id': 2, 'text': 'How would you incorporate nano-SiO2 into a polymer solution to ensure uniform dispersion and effective integration into the polymer matrix? Detail the steps you would follow.'}, {'id': 3, 'text': 'What considerations are necessary when applying a coating containing nano-SiO2 onto a polymer substrate, and how do these considerations influence the hydrophilic properties of the final material?'}] +[{'id': 1, 'text': 'Describe the steps you would take to use VCN L1-B to modify the surface of a polymer and explain how this modification could enhance the hydrophilicity of the polymer.'}, {'id': 2, 'text': 'If plasma surface cleaning is required before applying the molecule VCN L1-B, explain the role and importance of the plasma cleaning process in ensuring effective hydrophilic modification of the polymer material.'}, {'id': 3, 'text': 'Discuss the curing process after applying VCN L1-B onto the polymer surface. What factors should be optimized to ensure the molecule is properly adhered and contributes to hydrophilicity enhancement?'}] +[{'id': 1, 'text': 'How would you incorporate the diol with polyethylene oxide side chains into the polymer synthesis to enhance hydrophilicity? Describe the reaction steps and the impact of this molecule on the final properties of the polymer.'}, {'id': 2, 'text': 'Design an experiment for preparing a hydrophilic polymer using dimethylolpropionic acid. Explain its purpose in the reaction and how you would ensure it is properly neutralized in the synthesis process.'}, {'id': 3, 'text': 'Outline the process for utilizing a partially blocked tri-functional polyisocyanate in your experimental setup. Discuss its role in achieving a polymer with enhanced hydrophilic properties.'}] +[{'id': 1, 'text': 'Explain how hydroxyethyl acrylate (HEA) can be used to introduce unsaturated bonds into the molecular structure of a polymer and discuss how these bonds can enhance the hydrophilicity of the final material.'}, {'id': 2, 'text': 'When using polyethylene glycol (PEG) as a chain extender in polymer synthesis, describe the steps required to ensure that the resulting polymer exhibits hydrophilic properties. How might you adjust the reaction conditions for optimal results?'}, {'id': 3, 'text': 'Discuss the role of trimethylolpropane diallyl ether (TMPDE) in polymer modification. How would you incorporate this molecule to improve both hydrophilicity and mechanical properties of the polymer material?'}] +[{'id': 1, 'text': 'When using poly(ethylene glycol) (PEG) as a functionalizing molecule to enhance the hydrophilicity of a polymer, what steps would you take to ensure proper attachment onto the polymer matrix? Outline and justify each step in the process.'}, {'id': 2, 'text': 'How can glutaraldehyde, when used in conjunction with PEG, facilitate the functionalization of a polymer to improve its hydrophilicity? Discuss the role of glutaraldehyde in this process.'}, {'id': 3, 'text': "Describe how the pH of the solution containing PEG might influence its ability to functionalize a polymer. What precautions should you take regarding the solution's conditions during this step?"}] +[{'id': 1, 'text': 'Discuss how you would utilize 3,3-Dimethylallyl bromide in the modification of a polymer to enhance its hydrophilicity. Specify any key reaction steps you would include.'}, {'id': 2, 'text': 'Explain the role of β-Lactam DM in polymer synthesis and how its incorporation might influence the hydrophilicity of the final polymer product.'}, {'id': 3, 'text': 'Design an experimental sequence to synthesize a hydrophilic polymer using Dye-NHS ester as an initiator. Justify how this molecule contributes to the hydrophilicity of the resulting polymer without referencing proprietary information.'}] +[{'id': 1, 'text': 'Describe how you would use HAuCl4 (gold chloride) to enhance the hydrophilicity of a polymer in your experimental process. Outline the steps involved and explain its role.'}, {'id': 2, 'text': 'Explain the mechanism by which NaBH4 (sodium borohydride) interacts with HAuCl4 during the preparation process. How does this reaction contribute to the hydrophilicity of the final polymer?'}, {'id': 3, 'text': 'In a synthesis involving the use of HAuCl4 and NaBH4, what additional polymer modification protocols would you recommend to ensure maximum hydrophilicity in the resulting material? Justify your reasoning.'}] +[{'id': 1, 'text': 'Describe a procedure for incorporating hydrophilic bisphenol A-based (meth)acrylate into a polymer matrix to improve the hydrophilicity of the final material. How would you ensure uniform distribution of this molecule within the polymer system?'}, {'id': 2, 'text': 'What role does the reactive ionic liquid play when combined with hydrophilic bisphenol A-based (meth)acrylate in enhancing the hydrophilicity of the polymer? Propose a method to monitor its reaction progress during polymer synthesis.'}, {'id': 3, 'text': 'Suggest a suitable polymerization strategy to cure a hydrophilic bisphenol A-based (meth)acrylate modification of a polymer, ensuring that its hydrophilic properties are preserved. Why would you choose this particular polymerization method?'}] +[{'id': 1, 'text': 'Design a step-by-step experimental scheme for synthesizing a hydrophilic polymer by reacting isophorone diisocyanate (IPDI) with appropriate reagents. Specify reaction conditions, solvents, and the role of IPDI in enhancing hydrophilicity.'}, {'id': 2, 'text': 'Propose a method to incorporate the molecule hydroxyl ethyl acrylate (HEA) into a polymer matrix and describe how its chemical structure contributes to the improvement of hydrophilicity in the final product.'}, {'id': 3, 'text': 'Develop an experimental protocol for modifying a polymer using dodecanol polyoxyethylene ether, and explain the desired hydrophilic behavior expected from this modification. Include reaction conditions and ratios for an optimized synthesis.'}] +[{'id': 1, 'text': 'Explain the role of 3-(trimethoxysilyl)propyl methacrylate (TMSPMA) in the polymerization process to enhance the hydrophilicity of the polymer material.'}, {'id': 2, 'text': 'When using 3-(trimethoxysilyl)propyl methacrylate (TMSPMA), what considerations need to be made to ensure proper bonding with the substrate during the curing process?'}, {'id': 3, 'text': 'Describe how you would utilize 3-(trimethoxysilyl)propyl methacrylate (TMSPMA) to create a polymer solution suitable for application onto a substrate, while maintaining its ability to crosslink during curing.'}] +[{'id': 1, 'text': 'How would you utilize chitosan variants as polycations within the experimental setup to modify a polymer for enhanced hydrophilicity? Specify the buffer conditions required.'}, {'id': 2, 'text': 'Describe the procedure for depositing PAR30 as a polycation during the synthesis of a hydrophilic polymer. What key parameters should you control during this step?'}, {'id': 3, 'text': 'Explain how the molecule PAR30 interacts with polyanions during successive deposition cycles to form a bilayer structure. What techniques would you use to confirm the formation of hydrophilic coatings?'}] +[{'id': 1, 'text': 'Describe how you would incorporate a sulfonic acid type amphoteric surface active agent, derived from alpha-hydroxyalkyldialkylamine reacted with benzyl chloride, into a polymer system to enhance its hydrophilicity. Be specific about the reaction steps and the resulting molecular interactions.'}, {'id': 2, 'text': 'Explain the role of a nonionic surface active agent with the formula R O(C H2C H2O)n, where R is an alkyl group with 10 to 16 carbon atoms, in increasing the hydrophilicity of a polymer. How would you ensure optimal integration of this molecule into the polymer matrix?'}, {'id': 3, 'text': 'Propose a method to incorporate a water-soluble maleic anhydride-vinyl monomer copolymer, such as a maleic anhydride-acetalized vinyl alcohol copolymer, into a polymer modification scheme. How does this specific component contribute to the hydrophilicity of the final polymer material?'}] +[{'id': 1, 'text': 'Explain how methyl methacrylate glycidyl ester (GMA) can be utilized in the synthesis of a hydrophilic polymer. Include in your response the role of cross-linking agents or other components that might be used to enhance hydrophilicity.'}, {'id': 2, 'text': 'Design a procedure for incorporating GMA into a polymer matrix to form a hydrophilic coating. Specify the steps required, including any necessary pre-treatment, reaction parameters, and curing conditions.'}, {'id': 3, 'text': 'Discuss the impact of using GMA as a functional molecule in modifying a polymer’s surface properties. How does the incorporation of GMA enhance the hydrophilicity of the final material?'}] +[{'id': 1, 'text': 'When modifying a polymer material to enhance its hydrophilicity, how would you design a synthesis process involving POSS-Br as an initiator? Describe the steps you would take and the significance of using this molecule in the polymerization process.'}, {'id': 2, 'text': 'Explain how the incorporation of POSS groups could influence the overall hydrophilicity of a polymer material. Specifically, discuss the intended interaction between POSS-Br derivatives and other components during the polymerization.'}, {'id': 3, 'text': 'If you were to use POSS-Br in an ATRP-based reaction, how would you control the polymerization to achieve the desired balance between hydrophilic and hydrophobic properties in the resulting polymer? Include any factors you would consider in your design.'}] +[{'id': 1, 'text': 'Design an experimental procedure to synthesize a hydrophilic polymer by reacting glycidol with a polyfunctional isocyanate resin. Describe the sequence of steps you would follow and indicate how you would ensure the reaction is complete.'}, {'id': 2, 'text': 'Explain how the inclusion of methoxy poly(ethylene glycol) (mPEG) in a stepwise reaction sequence with hexamethylene diisocyanate isocyanurate can contribute to enhancing the hydrophilicity of the resulting polymer. Provide a rationale for your choice of reaction conditions and proportions.'}, {'id': 3, 'text': 'Formulate an aqueous coating preparation using an oligomer synthesized from glycidol and polyfunctional isocyanate resin. Specify how you would disperse the polymer in water and incorporate a curing agent, taking into account a solvent-free system.'}] +[{'id': 1, 'text': 'Describe how you would use polyethylene glycol monomethyl ether (PEGME600) in a preparation scheme to modify a polymer to enhance its hydrophilicity. Specify the key reaction steps and conditions.'}, {'id': 2, 'text': 'Explain the role of pentaerythritol triacrylate (PETA) in the synthesis of hydrophilic polymers. How would you incorporate this molecule to achieve better hydrophilic properties in your polymer?'}, {'id': 3, 'text': 'Discuss how you would utilize isophorone diisocyanate (IPDI) in a reaction to form a hydrophilic polymer. Identify the necessary molar ratios and additional reagents required to optimize this reaction.'}] +[{'id': 1, 'text': 'Explain the role of monomethyl ether polyethylene glycol (mPEG, Mw = 1100) in improving the hydrophilicity of the polymer material and describe how you would modify it using 3-isocyanatopropyl trimethoxysilane.'}, {'id': 2, 'text': 'Design an experimental setup to functionalize silica nanoparticles using mPEG trimethoxysilane. Outline the steps you would take to ensure the nanoparticles are successfully coated and hydrophilic.'}, {'id': 3, 'text': 'Discuss how the inclusion of sulfopropyl acrylate potassium salt in the formulation contributes to hydrophilicity, and propose a method to incorporate it effectively into the polymer coating process.'}] +[{'id': 1, 'text': 'Describe how you would use the Ugi four-component reaction to synthesize a molecule capable of enhancing the hydrophilicity of a polymer. Include the specific roles of each component in the reaction.'}, {'id': 2, 'text': 'Once you have synthesized a molecule via the Ugi four-component reaction, explain the steps you would take to incorporate this molecule into the polymer to achieve the desired increase in hydrophilicity.'}, {'id': 3, 'text': 'How would you evaluate whether the molecule derived from the Ugi four-component reaction enhances the hydrophilicity of the polymer? Specify the experimental methods and parameters you would analyze.'}] +[{'id': 1, 'text': "Describe how you would incorporate polyacrylamide into a polymer modification scheme to enhance the resulting material's hydrophilicity."}, {'id': 2, 'text': 'Explain the role of hydroxyethyl acrylate (HEA) as a monomer in the preparation of hydrophilic polymers and how it can be integrated into the experimental process.'}, {'id': 3, 'text': 'Given that KH-570 can be used to functionalize surfaces, outline how you would use this molecule to improve polymer hydrophilicity in a controlled synthesis reaction.'}] +[{'id': 1, 'text': 'Design an experimental procedure to incorporate γ-glycidoxypropyltrimethoxysilane into a polymer modification process. Explain its role in enhancing the hydrophilicity of the resulting material.'}, {'id': 2, 'text': 'Given that hydrosilicofluoric acid is included as a catalyst in synthesis, describe how you would add this acid to the reaction mixture and hypothesize its impact on the hydrophilic properties of the polymer.'}, {'id': 3, 'text': 'Propose a method to integrate $^{2,2^{\\prime},4,4^{\\prime}}$-tetrahydroxybenzophenone into the polymer preparation process, and discuss its potential influence on both hydrophilicity and weather resistance.'}] +[{'id': 1, 'text': 'Describe how you would utilize zwitterionic polymers to enhance the hydrophilicity of a polymer surface. What steps would you take to ensure these polymers are uniformly integrated into the polymer matrix during synthesis?'}, {'id': 2, 'text': 'When incorporating superhydrophobic particles into a hydrophilic polymer system to enhance functional properties, what key experimental considerations would you address to maintain the overall hydrophilic nature of the final modified polymer?'}, {'id': 3, 'text': 'Polysaccharides are often used to prepare hydrophilic polymer coatings. How would you modify a polymer surface with polysaccharides, and what factors would you evaluate to confirm the improvement in hydrophilicity?'}] +[{'id': 1, 'text': 'Using the Schiff base formation reaction, describe how you would utilize a specific molecule containing an aldehyde group to modify a polymer and enhance its hydrophilicity. Please outline the reactants, reaction conditions, and expected outcomes.'}, {'id': 2, 'text': 'Explain how you would employ a molecule capable of undergoing a Michael addition reaction to chemically crosslink a polymer system. Describe the role of the molecule in forming a hydrophilic network and justify why this method enhances hydrophilicity.'}, {'id': 3, 'text': 'Propose an experimental setup to synthesize a hydrophilic polymer using a molecule that participates in a photoinitiated crosslinking reaction. Detail the light source, reaction time, and any inhibitors or catalysts you might include.'}] +[{'id': 1, 'text': 'Describe the role of DMASi in the experimental preparation scheme for modifying a polymer to enhance its hydrophilicity. How would you ensure proper incorporation of this molecule into the system?'}, {'id': 2, 'text': 'Explain how silica nanoparticles can be functionalized using 1,3-propane sultone during a polymer modification experiment. What steps would you take to ensure this reaction is both effective and complete?'}, {'id': 3, 'text': 'Discuss the method of integrating SBS into the experimental process for preparing a hydrophilic polymer. What conditions are critical to ensure its proper dispersion and interaction within the system?'}] +[{'id': 1, 'text': 'How would you utilize titanium dioxide (TiO2) in the synthesis process to enhance the hydrophilicity of a polymer material?'}, {'id': 2, 'text': 'Describe how the addition of tetraethyl orthosilicate (TEOS) might influence the surface properties of the polymer, and propose a strategy for its effective incorporation into the reaction system.'}, {'id': 3, 'text': 'Explain the role of surfactants, such as sodium dodecyl benzene sulfonate (SDBS), in improving the distribution and stability of TiO2 particles during polymer modification for hydrophilicity enhancement.'}] +[{'id': 1, 'text': 'Describe how d-glucose 6-phosphate monobarium salt (GPS-Ba) can be utilized as a template in the synthesis of a hydrophilic polymer. What is the significance of its interaction with the polymer precursor during the preparation process?'}, {'id': 2, 'text': 'Explain the role that epichlorohydrin plays in the preparation of the hydrophilic polymer. How does it contribute to the final structure and functionality of the polymer?'}, {'id': 3, 'text': 'During the synthesis process, the GPS-Ba template is removed after imprinting. Propose a method to effectively remove this molecule without compromising the polymer’s structural integrity or functionality. Justify your choice of method.'}] +[{'id': 1, 'text': 'How would you utilize glycerol as a key reactant to synthesize a hydrophilic polymer through an esterification reaction? Provide a detailed experimental scheme, including necessary reaction conditions and any precautions you would take during the process.'}, {'id': 2, 'text': 'Describe how you would incorporate methacrylic acid as a functional monomer to modify a polymer and enhance its hydrophilicity. Outline the specific reaction steps and any monitoring methods you would use to ensure the reaction is proceeding as expected.'}, {'id': 3, 'text': 'Using tetrahydrofuran as a solvent, develop an experimental protocol for synthesizing a hydrophilic polymer with functional groups through a co-condensation reaction. Specify the type of functional groups you aim to achieve and their role in enhancing hydrophilicity.'}] +[{'id': 1, 'text': 'How would you incorporate benzophenone into a polymer modification scheme to improve the hydrophilicity of the material? Describe the role benzophenone might play in this experiment.'}, {'id': 2, 'text': 'Design a procedure to uniformly dissolve benzophenone in a solvent mixture prior to its use in preparing a hydrophilic polymer coating. Specify the type of solvents you might choose and their potential effects on the final coating.'}, {'id': 3, 'text': 'Explain how benzophenone might interact with a polymer backbone during or after the polymer modification process and how this could enhance the hydrophilicity of the modified polymer material.'}] +[{'id': 1, 'text': 'How would you incorporate N‑乙烯基‑2‑吡咯烷酮 into a polymerization reaction to improve the hydrophilicity of the resulting polymer? Provide details on the reaction conditions and any other components you would add.'}, {'id': 2, 'text': 'Describe how the presence of 2‑丙烯酰胺‑2‑甲基丙磺酸 in a polymerization process can enhance the hydrophilicity of the resultant polymer material. What is the role of this molecule in the final polymer structure?'}, {'id': 3, 'text': 'What precautions would you take to ensure successful free-radical polymerization when using N,N-二甲基丙烯酸胺 as a monomer in a hydrophilic polymer synthesis? Include considerations for reaction temperature and initiators in your explanation.'}] +[{'id': 1, 'text': 'Design an experiment to incorporate the sodium salt of 5-sulfoisophthalic acid into a copolyester structure. What would be the role of this molecule in enhancing the hydrophilicity of the polymer material, and how would you ensure it is properly integrated during the condensation reaction?'}, {'id': 2, 'text': 'Describe how you would utilize sodium dodecyl benzenesulfonate as a surfactant in a hydrophilic polymer coating formulation. How does this molecule contribute to the dispersion stability and hydrophilicity of the final polymer?'}, {'id': 3, 'text': "Explain the process of incorporating a fluorosurfactant containing fluoroaliphatic oxyethylenes into a water-soluble hydrophilic polymer coating. How does the specific choice of this molecule influence the final coating's wetting tension and hydrophilicity?"}] +[{'id': 1, 'text': 'Given a molecule containing an ether group, design an experimental scheme to modify a polymer via ring-opening polymerization to enhance its hydrophilicity. Outline the steps you would take to ensure accurate identification of reactive sites.'}, {'id': 2, 'text': 'Using a molecule with a primary amine and a carboxylic acid group, propose how you would identify the head and tail atoms and classify the polymerization mechanism to create a hydrophilic polymer. Explain the rationale behind your choices.'}, {'id': 3, 'text': 'Considering a molecule with an alcohol group and a cyanate group, describe how you would determine the nucleophilicity index and identify the most reactive functionality for polymerization. Provide the steps for optimizing the geometry before reaction initiation.'}] +[{'id': 1, 'text': 'How would you utilize acrylamide (AAm) in a polymer synthesis experiment to prepare a hydrophilic polymer? Describe the steps you would take to ensure the monomer is in a purified state before use.'}, {'id': 2, 'text': "Explain how you would incorporate N,N'-methylene bisacrylamide (MBAAm) as a cross-linker in a hydrophilic polymer preparation experiment. What purification steps would you apply to the cross-linker before adding it to the reaction mixture?"}, {'id': 3, 'text': 'Discuss the role of q-ketoglutaric acid (KGA) as a photoinitiator in polymerizing a hydrophilic polymer. How would you ensure its effectiveness in initiating the free-radical solution polymerization process?'}] +[{'id': 1, 'text': 'Explain how the incorporation of glycidyl methacrylate into the polymer structure can enhance its hydrophilicity. Justify your reasoning based on its chemical properties.'}, {'id': 2, 'text': 'Design a polymerization experiment that utilizes glycidyl methacrylate as a monomer to prepare a hydrophilic polymer with functional groups. Specify the polymerization technique you would choose and why.'}, {'id': 3, 'text': 'Describe how you would control the amount of glycidyl methacrylate used in the synthesis to avoid undesired cross-linking effects while maintaining the desired hydrophilic properties.'}] +[{'id': 1, 'text': 'Describe the steps you would take to incorporate a functional group from the provided molecule into the polymer structure to enhance its hydrophilicity. Be specific in identifying reaction conditions and mechanisms.'}, {'id': 2, 'text': 'What analytical methods would you use to confirm that the modification of the polymer with the molecule has successfully increased its hydrophilicity? Provide reasoning behind your chosen techniques.'}, {'id': 3, 'text': 'Propose ways to optimize the reaction between the polymer and the molecule to achieve a high degree of functionalized hydrophilic sites while minimizing side reactions or degradation of the polymer.'}] +[{'id': 1, 'text': 'How can gamma-methacryloxypropyltrimethoxysilane (MPS) be utilized to introduce functional double bonds onto a substrate, and why is this step critical for preparing hydrophilic polymer coatings?'}, {'id': 2, 'text': 'Describe the role of 2-methacrylatoethyl trimethyl ammonium chloride (DMC) in the synthesis of a hydrophilic polyacrylate coating and how its incorporation affects the hydrophilicity of the final material.'}, {'id': 3, 'text': 'Explain how trimethylolpropane triacrylate (TMPTA) acts as a crosslinker in the preparation of the hydrophilic polymer coating and how varying its concentration impacts the final properties of the coating.'}] +[{'id': 1, 'text': 'Describe how you would incorporate polyethylene glycol (PEG 400) into the synthesis process to enhance the hydrophilicity of a polymer. Explain its role within the reaction and why it contributes to improved hydrophilicity.'}, {'id': 2, 'text': 'Trihydroxymethylpropane is to be utilized in the preparation of a hyperbranched resin. Explain how this molecule plays a role in influencing the crosslinking density and how this impacts the overall hydrophilicity of the final polymer material.'}, {'id': 3, 'text': 'In the preparation of Prepolymer 2, hydroxyethyl acrylate is added during synthesis. Explain the purpose of using this molecule, including its functional groups, and how it aids in modifying the polymer to enhance hydrophilicity.'}] +[{'id': 1, 'text': 'Graphene oxide (GO) contains various oxygen-containing functional groups that contribute to its hydrophilic properties. How would you incorporate GO into a polymer matrix to enhance the hydrophilicity of the final polymer material?'}, {'id': 2, 'text': 'When preparing a polymer-based hydrophilic coating using graphene oxide (GO), what steps would you take to ensure uniform dispersion of GO within the polymer matrix?'}, {'id': 3, 'text': 'Describe a method to deposit a graphene oxide (GO)-modified polymer coating on a substrate, ensuring both high hydrophilicity and good mechanical stability of the coating.'}] +[{'id': 1, 'text': "Describe how the molecule '丙二醇单甲醚' (propylene glycol monomethyl ether) could contribute to enhancing the hydrophilicity of a polymer material during the preparation process. Discuss its potential interactions and role in the experiment."}, {'id': 2, 'text': "When using '丙二醇单甲醚' (propylene glycol monomethyl ether) in the modification of a polymer, what considerations should be taken regarding its solubility and compatibility with other components? Outline how this might affect the overall hydrophilicity."}, {'id': 3, 'text': "Propose an experimental approach to uniformly incorporate '丙二醇单甲醚' (propylene glycol monomethyl ether) into a polymer matrix. How would you ensure that the distribution of the molecule maximizes the hydrophilic properties of the material?"}] +[{'id': 1, 'text': 'Describe the role of benzophenone when used as an initiator in the preparation of hydrophilic polymers. How does its interaction with the polymer substrate contribute to the modification process?'}, {'id': 2, 'text': 'Explain how acrylamide (AAm) as a monomer is utilized in this experiment to enhance the hydrophilicity of a polymer surface. What are the key steps to ensure proper polymerization of acrylamide during the modification process?'}, {'id': 3, 'text': 'If Irgacure-2959 is selected as the photoinitiator for this experiment, outline the steps required to utilize this molecule in polymerizing hydrophilic monomers and explain its specific role in initiating the reaction under UV light.'}] +[{'id': 1, 'text': "Describe a detailed reaction scheme to utilize carboxy-functionalized rod-like polySQ to modify a polymer in a way that enhances its hydrophilicity. How would the presence of carboxy groups contribute to the polymer's hydrophilic properties?"}, {'id': 2, 'text': 'Propose a step-by-step approach for incorporating POSS-C into a polymer matrix. Discuss the potential benefits of using POSS-C to improve the hydrophilicity and other properties of the polymer material.'}, {'id': 3, 'text': 'Imagine you are provided with carboxy-functionalized rod-like polySQ and asked to utilize it as a precursor in sol-gel chemistry to create hydrophilic polymer coatings. What experimental conditions (e.g., temperature, solvents) would you optimize and why?'}] +[{'id': 1, 'text': 'Given a specific molecule of your choice that enhances hydrophilicity, propose a mechanism for incorporating it into a polymer material to increase water affinity. What type of functional groups on the polymer backbone would facilitate this modification?'}, {'id': 2, 'text': 'Design an experimental step-by-step procedure to modify a polymer using a molecule that can introduce hydrophilic properties. How would you ensure that the resulting polymer maintains stability in aqueous environments?'}, {'id': 3, 'text': 'What characterization techniques would you use to confirm the successful incorporation of the hydrophilic molecule into the polymer material? Explain how these techniques can provide evidence of enhanced hydrophilicity.'}] +[{'id': 1, 'text': 'Explain the role of lithium hydroxide monohydrate (LiOH*H2O) in the transesterification reaction for enhancing polymer hydrophilicity.'}, {'id': 2, 'text': 'Design an experimental scheme using rape oil as a key reagent to modify a polymer for increased hydrophilicity, and outline all necessary steps and conditions.'}, {'id': 3, 'text': "Discuss how the use of Polyglycerol-3 (as the hydrophilic component) contributes to the final polymer product's hydrophilic properties, and suggest optimizations for the reaction conditions."}] +[{'id': 1, 'text': 'Describe an experimental procedure to synthesize a hydrophilic polymer using trimethylolpropane (tri-hydroxy methyl propane), including details on how to enhance the hydrophilicity of the final polymer product.'}, {'id': 2, 'text': 'How would you use the molecule acrylic acid in a chemical reaction to modify a polymer to increase its hydrophilicity? Specify key reaction conditions and any required catalysts.'}, {'id': 3, 'text': 'Explain how you would carry out a reaction involving propylene oxide to incorporate hydrophilic functional groups into a polymer material. Highlight any critical aspects of temperature and molar ratios that must be controlled.'}] +[{'id': 1, 'text': 'Explain how CHI (chitosan) can be utilized to modify a polymer in order to enhance its hydrophilicity. Include the role of acetic acid in this process.'}, {'id': 2, 'text': 'Describe the steps you would follow to create a layered structure using CMC (carboxymethyl cellulose) and CHI. How does the alternating deposition of these molecules influence the overall hydrophilicity of the polymer?'}, {'id': 3, 'text': 'Silicone oil is mentioned as part of the process to prevent film formation of a photocurable polymer during the synthesis of hydrophilic polymers. Hypothesize why silicone oil might be important and explain how its presence could impact the interaction between PFPE and silica nanoparticles.'}] +[{'id': 1, 'text': 'Explain how you would utilize 2-acrylamido-2-methylpropanesulfonic acid (AMPS) to synthesize an intermediate product for a hydrophilic polymer. Include details of any neutralization steps and justify their role in the reaction.'}, {'id': 2, 'text': 'Describe the reaction conditions (temperature, time, and molar ratios) necessary for reacting linear hydrophilic polyether amine ED2003 with an intermediate to enhance hydrophilicity. What is the significance of using ED2003 in this step?'}, {'id': 3, 'text': 'Outline the process of incorporating 1,6-hexanediol diacrylate (HDDA) and other multifunctional monomers into an intermediate product to achieve a hydrophilic resin. Explain how the multifunctional monomers contribute to the desired anti-fog properties.'}] +[{'id': 1, 'text': "Explain the role of tetraethyl orthosilicate (TEOS) in the preparation of a hydrophilic polymer and describe its expected effect on the polymer's surface properties if used in an experimental setup."}, {'id': 2, 'text': 'Describe the process of forming a sol using a poloxamer such as Pluronic F-127 in the presence of a catalyst. How does this step impact the hydrophilicity of the final polymer material?'}, {'id': 3, 'text': 'Propose a method to optimize the introduction of Si–OH groups on the surface of a polymer coating using tetraethyl orthosilicate (TEOS) and explain how the presence of these groups contributes to hydrophilicity.'}] +[{'id': 1, 'text': "Based on the molecule ethyl hydroxyethyl cellulose, explain how you would utilize it in the preparation of a hydrophilic polymer coating to enhance the polymer's wettability. Include the rationale behind its inclusion in the composition."}, {'id': 2, 'text': 'Colloidal silica nanoparticles are known to contribute to the hydrophilicity of polymer surfaces. Design an experimental step involving these nanoparticles to integrate them effectively into the polymer modification process. Discuss their role in enhancing hydrophilicity.'}, {'id': 3, 'text': 'Surfactants such as Masil SF-19 are often added to polymer coatings to improve their properties. Describe how you would incorporate Masil SF-19 into the experimental scheme to ensure it plays an optimal role in enhancing hydrophilicity.'}] +[{'id': 1, 'text': 'Describe the reaction mechanism and conditions required to synthesize a half-blocked prepolymer using isophorone diisocyanate and 3-methyl-3-hydroxymethyloxetane to introduce terminal -NCO groups. Explain the molar ratio of these two reactants and why this ratio is critical for the reaction.'}, {'id': 2, 'text': 'In a Michael addition reaction, polyethylene glycol diacrylate (PEG400DA) reacts with a diamine to form an intermediate hydrophilic polymer. Outline a detailed experimental procedure for preparing this intermediate, focusing on how the molar ratio of the two reactants influences the hydrophilicity of the intermediate.'}, {'id': 3, 'text': 'The use of sodium ethanesulfonate is essential in modifying intermediates during polymer synthesis to enhance hydrophilicity. Explain how this molecule reacts with acrylate groups in the intermediate polymer at room temperature, and describe the type of functional groups introduced into the final product.'}] +[{'id': 1, 'text': 'In the preparation of a hydrophilic polymer, how would you utilize acrylamide (AAm) to enhance the hydrophilicity of the material? Describe the steps involved in detail.'}, {'id': 2, 'text': 'Poly(2-acrylamido-2-methylpropane sulfonic acid sodium salt) (PNaAMPS) plays a critical role in modifying the polymer for improved hydrophilicity. How would you incorporate PNaAMPS into a polymer matrix, and what parameters would you carefully control during its synthesis?'}, {'id': 3, 'text': 'During the synthesis of a hydrophilic polymer, poly(vinyl acetate) (PVAc) is often used in the preparation process. How would you prepare a substrate layer using PVAc, and why is this step important for enhancing hydrophilicity?'}] +[{'id': 1, 'text': 'Describe how you would utilize isophorone diisocyanate (IPDI) in a reaction with hydroxyethyl acrylate (HEA) to obtain a reactive prepolymer functionalized with isocyanate groups. Specify the mole ratio and key conditions for the reaction.'}, {'id': 2, 'text': 'Explain the role of sodium N-(2-aminoethyl)aminoethanesulfonate in the preparation of hydrophilic polymers and describe how you would react it with a hydrophilic intermediate containing acrylate groups. Include details of the reaction conditions such as temperature, solvent, and mole ratio.'}, {'id': 3, 'text': 'Detail a method for combining an isocyanate-functionalized prepolymer with a hydrophilic intermediate (containing secondary amines) that you have synthesized to produce a light-curable hydrophilic resin. Explain the significance of any reaction parameters you consider critical, including the avoidance of light exposure during the process.'}] +[{'id': 1, 'text': 'Identify an appropriate solvent to dilute the molecule used for polymer modification, ensuring that the dilution does not exceed 30%. Describe how this choice of solvent could impact the hydrophilicity of the final polymer material.'}, {'id': 2, 'text': 'Determine the optimal thickness for the coating layer after the molecule is applied to the polymer. Discuss how variations in this thickness could alter the hydrophilicity and performance of the polymer.'}, {'id': 3, 'text': 'Explain the reasoning behind setting specific temperature and UV curing energy parameters during the molecule application process, and how these factors contribute to achieving enhanced hydrophilicity in the modified polymer.'}] +[{'id': 1, 'text': 'Describe the steps you would take to synthesize 3-(bis(hydroxymethyl)amino)-2-hydroxypropyl methacrylate (D-GMA) and explain why this molecule is significant for enhancing the hydrophilicity of the polymer material.'}, {'id': 2, 'text': 'What role does the molecule 3-(bis(hydroxymethyl)amino)-2-hydroxypropyl methacrylate (D-GMA) play during the copolymerization process, and how might it contribute to the formation of a hydrophilic polymer?'}, {'id': 3, 'text': 'Explain how 3-(bis(hydroxymethyl)amino)-2-hydroxypropyl methacrylate (D-GMA) can be incorporated into a polymer fusion process to enhance hydrophilic properties, and suggest any additional experimental parameters you would consider controlling during this integration.'}] +[{'id': 1, 'text': 'Describe how you would utilize 4-hydroxybutyl acrylate in the preparation of a hydrophilic polymer, and explain its role in the polymer matrix.'}, {'id': 2, 'text': 'Explain the potential impact of incorporating acrylic acid into the polymer composition, and how this might influence the hydrophilicity of the final material.'}, {'id': 3, 'text': 'Propose a polymerization setup using ethylene glycol dimethacrylate as a crosslinking agent, and discuss how the choice of this molecule affects the mechanical and hydrophilic properties of the polymer.'}] +[{'id': 1, 'text': "Describe the steps you would take to utilize isophorone diisocyanate (IPDI) in modifying the polymer, ensuring the polymer's hydrophilicity is enhanced. Please specify the reaction conditions you deem necessary."}, {'id': 2, 'text': "Considering the role of IPDI in the reaction process, how would you select and introduce an appropriate catalyst to optimize the polymer's hydrophilic properties during synthesis?"}, {'id': 3, 'text': 'Explain how you would control the addition of alcohol over time during the synthesis process when IPDI is used as a reactant, and detail how this step contributes to enhancing the hydrophilicity of the polymer material.'}] +[{'id': 1, 'text': 'Describe how you would utilize 3-glycidoxypropyltrimethoxysilane in a procedure to functionalize glass slides before coating a hydrophilic polymer. Specify the purpose of this treatment and how it contributes to enhancing the hydrophilicity of the final polymer material.'}, {'id': 2, 'text': 'Explain the role of acetic acid when mixed with 3-glycidoxypropyltrimethoxysilane in the glass slide preparation process. Why is this molecule crucial for achieving hydrophilicity in the modified polymer?'}, {'id': 3, 'text': 'When using 3-glycidoxypropyltrimethoxysilane, what parameters or controls would you consider critical during the immersion step to maximize the functionality of the glass substrate? How would improper handling of this molecule affect the hydrophilic properties of the polymer?'}] +[{'id': 1, 'text': 'Describe the reaction mechanism between hydroxyl groups in 2-hydroxyethyl acrylate (HEA) and an isocyanate-containing molecule. How would this reaction contribute to the synthesis of a hydrophilic polymer structure?'}, {'id': 2, 'text': 'When integrating polyethylene glycol-based amines (such as ED2003) into a polymer network, what functional group interactions are critical for ensuring the resulting polymer exhibits increased hydrophilicity? Propose experimental conditions to optimize this reaction.'}, {'id': 3, 'text': 'Explain how the use of tris(2-hydroxyethyl)isocyanurate triacrylate (THEICTA) can affect the overall hydrophilicity and mechanical properties of the resulting polymer. Discuss potential advantages and trade-offs in this context.'}] +[{'id': 1, 'text': 'Explain the role of [Fe(CN)6]^{3-/4-} in the polymer modification, and how its inclusion could enhance the hydrophilicity of the final polymer material.'}, {'id': 2, 'text': 'Describe the procedure for incorporating [Fe(CN)6]^{3-/4-} into the polymer matrix and discuss how this step ensures consistent interaction between the molecule and polymer network to improve hydrophilicity.'}, {'id': 3, 'text': "What considerations should you take into account while immersing the polymer in a solution containing [Fe(CN)6]^{3-/4-} to ensure effective modification of the polymer's surface properties?"}] +[{'id': 1, 'text': 'How would you use methyl methacrylate (MMA) to prepare a hydrophilic polymer via in situ radical polymerization, and what specific steps would you take to ensure proper initiation of the polymerization process?'}, {'id': 2, 'text': 'Describe the procedure for purifying the polymer product obtained after using methyl methacrylate (MMA) to modify the polymer. What would be the rationale for choosing specific solvents during the precipitation process?'}, {'id': 3, 'text': 'If methyl methacrylate (MMA) is used as the vinyl monomer in polymer synthesis, what measures should you implement to maximize the hydrophilicity of the resulting polymer material?'}] +[{'id': 1, 'text': "In the synthesis of a hydrophilic polymer, you are provided with glycerol. Explain how this molecule can be utilized to prepare a polymer with enhanced hydrophilicity. Include the role and interaction of glycerol's functional groups in the reaction."}, {'id': 2, 'text': 'You are tasked with utilizing N-(isobutoxy)methylacrylamide in the preparation of a hydrophilic polymer. Describe the chemical reaction mechanism this molecule participates in and its contribution to the overall hydrophilicity of the final polymer.'}, {'id': 3, 'text': 'Assume you are given polyethylene glycol amine and told to perform a reaction involving functionalized acrylamide compounds. Outline the reaction conditions you would use and explain how the resulting product contributes to the hydrophilicity of the polymer material.'}] +[{'id': 1, 'text': 'Explain how you would use hydroxyethyl acrylate (HEA) to modify the terminal molecular chains of a polymer to improve its hydrophilicity. Include a description of its role in the synthesis of the polymer.'}, {'id': 2, 'text': 'Describe the process of incorporating trimethylolpropane diallyl ether (TMPDE) into a polymer matrix to enhance functionality. How does this molecule contribute to the crosslinking of the polymer?'}, {'id': 3, 'text': 'If polyethylene glycol (PEG) is chosen as the polyol component, outline the steps needed to introduce this molecule into the polymer chain. How does the structure of PEG contribute to the hydrophilicity of the final polymer material?'}] +[{'id': 1, 'text': 'Describe how you would utilize diethanolamine in the synthesis of a hydrophilic polymer, considering its structural properties and potential reactivity. How does this molecule contribute to enhancing hydrophilicity?'}, {'id': 2, 'text': 'Explain the role of isophorone diisocyanate in the preparation of hydrophilic polymers. How would you ensure that this molecule reacts fully without compromising the final hydrophilicity of the polymer material?'}, {'id': 3, 'text': "Given that polyethylene glycol monomethyl ether 500 is used in the experiment, outline a detailed procedure for incorporating this molecule into the synthesis process to ensure effective modification of the polymer's hydrophilic properties."}] +[{'id': 1, 'text': 'Describe how you would incorporate 1-propanol into the experimental setup to enhance the hydrophilicity of the polymer material. What role does 1-propanol play in the overall modification process?'}, {'id': 2, 'text': 'Explain how the combination of 1-propanol with water during the solution preparation phase might affect the interactions between the polymer and the added molecule. How is this relevant to increasing the hydrophilicity of the final polymer product?'}, {'id': 3, 'text': 'Consider the drying and curing stages of the polymer modification. How do you think the presence of 1-propanol in the solution influences the final structure and hydrophilicity of the polymer material after curing?'}] +[{'id': 1, 'text': 'Describe how you would use mercaptopropionic acid as a reactant to modify a polymer in an experiment designed to enhance its hydrophilicity. Specify the necessary reaction conditions based on your understanding of hydrophilic polymer synthesis.'}, {'id': 2, 'text': 'Explain how you could incorporate triethanolamine trimethacrylate into an experimental scheme to achieve a POSS-modified polymer with improved hydrophilicity. Outline the role of catalysts in this process.'}, {'id': 3, 'text': 'In the context of modifying a polymer to enhance hydrophilicity, propose a reaction sequence starting with mercaptopropionic acid. Include details of the molar ratios you would choose and justify your choice.'}] +[{'id': 1, 'text': 'Explain how you would use the molecule POSS-Br to initiate an Atom Transfer Radical Polymerization (ATRP) process for enhancing the hydrophilicity of a polymer material. Include any critical preparatory steps you would employ in this synthesis.'}, {'id': 2, 'text': 'Discuss the role of POSS-Br in controlling the polymerization process, and how its presence may influence the overall hydrophilicity of the resulting polymer.'}, {'id': 3, 'text': 'After completing the polymerization process initiated by POSS-Br, describe how you would purify the polymer product to remove any residual catalysts or unwanted byproducts, ensuring a higher hydrophilicity in the final material.'}] +[{'id': 1, 'text': 'Describe the synthetic procedure you would use to prepare a quaternary ammonium salt (14QAS) starting from a tertiary amine and a bromoalkane. Include the reaction conditions and steps required to ensure high product yield.'}, {'id': 2, 'text': 'After obtaining 14QAS, explain how you would incorporate this molecule into a polymer network to enhance the hydrophilicity of the resulting material. Specify any additional components required for the formulation.'}, {'id': 3, 'text': 'If tasked with curing a thin film of polymer containing 14QAS on a glass substrate, describe the process you would follow, including the equipment, light source, and parameters critical to achieving a uniform coating.'}] +[{'id': 1, 'text': 'Explain how you would use POSS-Br to initiate the polymerization process and why it is suitable for this purpose in the synthesis of hydrophilic polymers.'}, {'id': 2, 'text': 'Describe the key experimental steps you would follow to ensure the reaction involving POSS-Br proceeds efficiently under oxygen-free conditions.'}, {'id': 3, 'text': 'After successfully synthesizing a polymer using POSS-Br, how would you ensure the removal of metallic impurities such as copper ions from the final product, and why is this step critical for hydrophilic polymer preparation?'}] +[{'id': 1, 'text': 'The molecule MPEG is mentioned as a component in the experiment involving hydrophilic polymer preparation. Describe a detailed procedure for incorporating MPEG into a polymer synthesis process to enhance its hydrophilicity, ensuring you address monomer proportions and polymerization conditions.'}, {'id': 2, 'text': 'DAROCUR ZLI-3331 is noted as a molecule used in polymer preparation. Explain how you would utilize DAROCUR ZLI-3331 in a photochemical reaction setup to modify the polymer and improve its hydrophilicity. Include details about the preparation conditions and any catalysts required.'}, {'id': 3, 'text': "HEMA is utilized as a monomer in hydrophilic polymer synthesis. Design an experiment that incorporates HEMA into the polymerization process, detailing the other reactants, reaction conditions, and how the resulting polymer's hydrophilicity would be characterized."}] +[{'id': 1, 'text': 'Considering the use of 2-acrylamide-2-methylpropanesulfonic acid (AMPS) as a hydrophilic monomer, describe how you would incorporate it into a polymer matrix to enhance the hydrophilicity of the final material. Specify the steps and conditions you would follow for the modification process.'}, {'id': 2, 'text': 'Explain the role of 2-acrylamide-2-methylpropanesulfonic acid (AMPS) in modifying the hydrophilic properties of the polymer. How would its chemical properties contribute to the overall performance of the modified polymer?'}, {'id': 3, 'text': 'If you were to graft 2-acrylamide-2-methylpropanesulfonic acid (AMPS) onto a polymer substrate, how would you ensure the removal of ungrafted homopolymers during the purification process to isolate the desired hydrophilic polymer? Name the techniques or procedures you would employ.'}] +[{'id': 1, 'text': 'Explain how you would use 2,2,2-trifluoroethanol to prepare a solution of polymers for enhancing the hydrophilicity of a coating. Why is this solvent suitable for the process?'}, {'id': 2, 'text': 'Describe the role of EGDMA in the polymer modification process. How does its addition influence the final hydrophilic properties of the polymer material?'}, {'id': 3, 'text': 'Outline the steps required to incorporate POSS as an initiator in the synthesis of the polymer. How does the inclusion of POSS contribute to the hydrophilicity of the final polymer material?'}] +[{'id': 1, 'text': 'Describe how you would incorporate the molecule HDDA into the preparation of a hydrophilic polymer, and explain its role in the polymer network.'}, {'id': 2, 'text': 'Explain how the molecule I-819 can be used to facilitate the synthesis of a hydrophilic polymer and what its specific function is during the experimental process.'}, {'id': 3, 'text': 'What is the purpose of using the molecule BZSA in the synthesis of hydrophilic polymers? Outline the steps in which it should be introduced and its influence on the final material properties.'}] +[{'id': 1, 'text': "Explain how N-Hydroxyethylacrylamide could be utilized as a monomer in the preparation of hydrophilic polymers and describe the role it plays in modifying the polymer's properties."}, {'id': 2, 'text': 'Design an experimental scheme for polymerization using N-Hydroxyethylacrylamide, specifying the type of initiator you would use, the solvent, and the conditions required to ensure optimal reaction.'}, {'id': 3, 'text': 'After synthesizing a polymer with N-Hydroxyethylacrylamide, propose purification methods that would be effective in isolating the final product while maintaining its hydrophilic properties.'}] +[{'id': 1, 'text': 'Using N-hydroxymethylacrylamide as a monomer, design a step-by-step polymerization process to create a hydrophilic polymer. Include details on the role of this molecule in the crosslinking structure.'}, {'id': 2, 'text': 'Triethanolamine is to be used as a basic compound in the preparation of a hydrophilic polymer. Explain how you would determine the appropriate amount of triethanolamine relative to a sulfonic acid-containing monomer to ensure effective polymer modification.'}, {'id': 3, 'text': 'Describe how the addition of a surfactant during the preparation of a hydrophilic polymer could impact the coating quality when applied to a substrate. What considerations would you make when incorporating the surfactant?'}] +[{'id': 1, 'text': 'How would you utilize Carboxy-Functionalized Polyhedral Oligomeric Silsesquioxane (POSS-C) and vary its molar ratio with another molecule to achieve enhanced hydrophilicity in a polymer, and what would be the significance of these molar ratios?'}, {'id': 2, 'text': 'When using Carboxy-Functionalized Polyhedral Oligomeric Silsesquioxane (POSS-C), explain how changing the number of ethylene glycol (e.g., n=1 to n=6) repeating units could affect the hydrophilicity of the modified polymer.'}, {'id': 3, 'text': 'Describe the steps you would take to apply a polymer coating, synthesized using Carboxy-Functionalized Polyhedral Oligomeric Silsesquioxane (POSS-C), onto a substrate, and discuss how you would evaluate its hydrophilic properties.'}] +[{'id': 1, 'text': 'How would you use the molecule dimethylol propionic acid (DMPA) to prepare a hydrophilic polymer with enhanced water dispersibility and anionic stabilization properties? Describe the steps and the role of this molecule in the synthesis process.'}, {'id': 2, 'text': 'Explain how you could utilize PEG-based modified DVSZN004 (50% coverage and 30 wt%) during the preparation of a polyurethane-based hydrophilic polymer. What specific functional properties would this molecule impart to the final product?'}, {'id': 3, 'text': 'Describe the procedure for incorporating trifunctional aziridine crosslinker PZ-2382 into a polymer matrix to enhance its hydrophilicity and mechanical durability. Include details about curing requirements and performance tests to evaluate the final polymer.'}] +[{'id': 1, 'text': 'How would you modify Tween 20 to ensure its molecular structure improves the hydrophilicity of a polymer matrix during preparation?'}, {'id': 2, 'text': 'Once you have prepared the modified Tween 20, explain how you would integrate it into the polymer system while ensuring uniform dispersion and adherence to the substrate.'}, {'id': 3, 'text': 'Describe the role of Tween 20 in enhancing the hydrophilicity of the final polymer coating and how you would verify its effectiveness experimentally.'}] +[{'id': 1, 'text': 'Describe the role of glycidyl methacrylate (GMA) in the formation of hydrophilic polymers and explain how its chemical properties can be used to crosslink polymer chains.'}, {'id': 2, 'text': 'When synthesizing a hydrophilic polymer system, how would you incorporate 1,3,5-triformylbenzene (TFB) to enhance the stability of the crosslinked network? Outline the specific functional groups this molecule reacts with during the process.'}, {'id': 3, 'text': 'Explain the significance of quaternized ammonium compounds (such as those derived from 2-(dimethylamino)ethyl methacrylate) in enhancing the hydrophilicity of a polymer. How would you ensure proper integration of these compounds into your polymer matrix?'}] +[{'id': 1, 'text': 'Propylene glycol is mentioned as a component in the preparation of hydrophilic polymers. Design an experimental protocol incorporating propylene glycol to enhance the hydrophilicity of a polymer surface. Include details such as concentration, mixing methods, and reaction conditions.'}, {'id': 2, 'text': 'Sodium dodecyl sulfate is a surfactant often used in polymer modification. Explain how you would utilize sodium dodecyl sulfate to improve the hydrophilic properties of a given polymer, and outline the chemical mechanism driving the improvement.'}, {'id': 3, 'text': 'Polyethylene glycol 400 has known hydrophilic properties. Describe how you would integrate polyethylene glycol 400 into a formulation to create a hydrophilic polymer coating and propose a method to test the resulting hydrophilicity.'}] +[{'id': 1, 'text': 'Describe how glycidyl methacrylate (GMA) can be used to modify a polymer to introduce hydrophilic properties. Include the reaction mechanism and the functional groups formed during the process.'}, {'id': 2, 'text': 'Explain how the introduction of hydroxyethylmethacrylate (HEMA) could enhance the hydrophilicity of a polymer coating. What specific properties does HEMA impart to the resulting material?'}, {'id': 3, 'text': "Outline the process of utilizing methacryloxypropyl trimethoxylsilane (KH570) in a condensation reaction to modify a polymer. How does this modification enhance the material's hydrophilicity?"}] +[{'id': 1, 'text': 'Describe the role of polysorbate in modifying a polymer to enhance its hydrophilicity and propose a method for incorporating it into a polyurethane-based prepolymer system.'}, {'id': 2, 'text': 'What factors would you consider when adjusting the molar ratio of polysorbate to diisocyanate monomer in order to optimize the hydrophilicity of the resulting polymer?'}, {'id': 3, 'text': 'Explain the steps you would take to ensure uniform mixing of a polysorbate-modified prepolymer with a reactive diluent and how this would influence the hydrophilicity of the final polymer coating.'}] +[{'id': 1, 'text': 'Explain how you would incorporate the UPy-D400 molecule into a polymer network to improve its hydrophilicity, and describe the role of its functional groups in achieving this.'}, {'id': 2, 'text': 'What steps would you take to ensure effective mixing of UPy-D400 into a polymer formulation, and how would you verify its successful incorporation into the final polymer structure?'}, {'id': 3, 'text': 'Describe how you would optimize the UPy-D400 content within a polymer matrix to balance hydrophilicity with other mechanical or chemical properties of the resulting material.'}] +[{'id': 1, 'text': "Explain how you would incorporate the molecule '甲基丙烯酰氧基丙基三乙氧基硅烷' into a polymer synthesis process to enhance the hydrophilicity of the polymer material. Specify the role of this molecule in the reaction."}, {'id': 2, 'text': "Design an experimental procedure to use '丙烯酰胺基-叔丁基磺酸钾盐' in the preparation of a hydrophilic polymer. Include details on how this molecule contributes to the overall hydrophilicity enhancement."}, {'id': 3, 'text': "Suggest a way to integrate the molecule '甲基丙烯酸缩水甘油酯' into a polymer synthesis process. What functional groups of this molecule could be leveraged to improve the hydrophilicity of the resulting polymer?"}] +[{'id': 1, 'text': 'How would you utilize 1,3,5-triformylbenzene (TFB) as a co-crosslinker to enhance the hydrophilicity of a polymer system during the modification process?'}, {'id': 2, 'text': 'Given that 1,3,5-triformylbenzene (TFB) can react with both amino and hydroxyl groups, detail an experimental approach to incorporate TFB into a polymer coating for hydrophilic surface modification.'}, {'id': 3, 'text': 'Explain the role of 1,3,5-triformylbenzene (TFB) in forming crosslinked polymer networks and how this contributes to improving the hydrophilicity of a polymer coating.'}] +[{'id': 1, 'text': 'Using the molecule polyethylene glycol (PEG), design an experimental procedure to synthesize a PEG-based ammonium salt. Specify the reaction conditions required, including temperature, solvent system, and purification methods to obtain a hydrophilic polymer.'}, {'id': 2, 'text': 'Trifunctional aziridine crosslinkers like PZ-502 can be used to improve anti-fog and hydrophilic properties of polyurethane coatings. Outline a synthesis approach incorporating PZ-502 into a polyurethane dispersion to prepare a hydrophilic polymer. Include the curing steps and any relevant conditions.'}, {'id': 3, 'text': 'Functional silanes are often used to modify silica nanoparticles for improved hydrophilicity. Describe how you would prepare modified silica nanoparticles using functional silanes and incorporate them into a polymer matrix to enhance its hydrophilic properties.'}] +[{'id': 1, 'text': 'Explain the role of 2-acrylamide-2-methylpropane sulfonic acid (AMPS) in enhancing the hydrophilicity of a polymer. How would you ensure its effective integration into the polymer structure during synthesis?'}, {'id': 2, 'text': 'Describe the importance of tetraethylorthosilicate (TEOS) in achieving a hydrophilic polymer film. What specific reaction does TEOS participate in, and how does this contribute to the surface properties of the material?'}, {'id': 3, 'text': '3-(Trimethoxysilyl)propyl-2-methyl-2-methacrylate (MPS) is used in the polymer modification process. Discuss its function within the preparation scheme and why its interaction with TEOS is critical for the desired outcome in terms of hydrophilicity.'}] +[{'id': 1, 'text': 'Describe the procedure for reacting 2-(cyclohexylamino)-ethanesulfonic acid with polyisocyanate under controlled temperature conditions to enhance the hydrophilicity of the polymer. What key parameters require monitoring during the reaction?'}, {'id': 2, 'text': 'Explain how 3-(cyclohexylamino)-propanesulfonic acid can be used as a molecular component to introduce sulfonic acid groups into a polymer. What role does neutralization with a tertiary amine play in this process?'}, {'id': 3, 'text': 'Outline a specific experimental scheme to incorporate 2-aminoethanesulfonic acid (taurine) into a polymer using a polyisocyanate-based approach. Include the ideal environmental conditions and the expected outcome regarding polymer hydrophilicity.'}] +[{'id': 1, 'text': 'Describe how you would incorporate propylene glycol (PG) as a co-solvent in the synthesis of a hydrophilic polymer, and explain its potential effect on surface tension during the process.'}, {'id': 2, 'text': 'In the preparation of a polymer material, how would the addition of dipropylene glycol (DPG) influence the hydrophilicity of the resulting polymer? Outline the steps to incorporate this molecule into the experimental procedure.'}, {'id': 3, 'text': 'Given a molecule like propylene glycol (PG), explain how varying its concentration could impact both the spontaneity of pattern formation on the polymer surface and the resulting hydrophilicity of the material.'}] +[{'id': 1, 'text': 'Describe how you would incorporate a radiation-curable acrylate containing hydrophilic alkylene oxide moieties (characterized by the formula Ω(CH2)Ωn(0-)Σm-, where n is between 1 and 3, and m is between 1 and 10) into a polymer system to enhance its hydrophilicity. Include any relevant steps for curing and network formation in your explanation.'}, {'id': 2, 'text': "Explain the role of the reactive surfactant in the preparation of the hydrophilic polymer when it is introduced in an amount between 0.5 wt% and 4.3 wt%, and describe how it integrates into the polymer's structure during curing."}, {'id': 3, 'text': 'Propose an experimental method to apply a coating containing photoinitiators to a substrate and ensure the formation of a hydrophilic polymer network after exposure to light energy. Include post-curing treatments to achieve optimal hydrophilicity.'}] +[{'id': 1, 'text': 'Describe the steps that you would use to integrate functional groups into a polymer using a molecule designed to enhance hydrophilicity. How would you ensure the functionalization results in optimized wetting behavior?'}, {'id': 2, 'text': 'Explain how you would evaluate the effectiveness of a molecule in reducing condensation and fogging on the surface of the polymer after modifying it. What tests or measurements would you implement to confirm the hydrophilicity enhancement?'}, {'id': 3, 'text': 'Select a specific molecule intended to increase hydrophilicity, and identify the points of attachment or interaction with the polymer. Propose a reaction scheme that uses this molecule in polymer modification to achieve improved anti-fogging properties.'}] +[{'id': 1, 'text': 'Explain how you would incorporate alkylene oxides into the backbone of a polyurethane polymer to enhance its hydrophilicity. Include specific steps in the synthesis process.'}, {'id': 2, 'text': 'Design an experimental scheme to introduce lactones as hydrophilic segments into a polymer material. What techniques and conditions would be optimal for this process?'}, {'id': 3, 'text': 'Describe how you would use lactams to modify a polymer and ensure that hydrophilic segments are covalently bonded to the backbone. What are some potential challenges in this process and how would you address them?'}] +[{'id': 1, 'text': 'How would you incorporate hydroxyethyl methacrylate (HEA) into a copolymer synthesis process to achieve enhanced hydrophilicity in the final polymer material? Specify any variables you would adjust and explain their role in the experiment.'}, {'id': 2, 'text': 'After synthesizing a copolymer containing hydroxyethyl methacrylate (HEA), propose a method to confirm the integration of HEA into the polymer structure. What techniques would you use, and what specific data would you look for?'}, {'id': 3, 'text': 'Describe a strategy to bond copolymers containing hydroxyethyl methacrylate (HEA) onto a substrate surface. Include the steps involved and explain how the bonding method ensures the hydrophilicity enhancement of the coated surface.'}] +[{'id': 1, 'text': 'Explain the role of the molecule REASOAP SR-10 in the synthesis of a hydrophilic polymer. Specifically, discuss how its reactive group contributes to the formation of a hydrophilic network during the curing process.'}, {'id': 2, 'text': 'Describe the steps you would take to incorporate the molecule REASOAP SR-10 into a polymer coating. Highlight how its properties help enhance the hydrophilicity of the resulting material.'}, {'id': 3, 'text': 'When using the molecule REASOAP SR-10 in the preparation of a hydrophilic polymer, explain how you would optimize its concentration to balance hydrophilicity and structural integrity of the polymer. What experimental considerations would you take into account?'}] +[{'id': 1, 'text': 'Explain why poly(ethylene glycol dimethacrylate) (PEGDMA) is used as a cross-linker in the preparation of hydrophilic polymers and how its concentration affects the resulting material properties.'}, {'id': 2, 'text': "Describe the role of 2,2'-azobis(2-methylpropionitrile) (AIBN) in the polymerization process and how the amount of AIBN influences the formation of hydrophilic polymers."}, {'id': 3, 'text': 'Propose a methodology to evaluate the impact of varying the molar ratio of 2-(dimethylamino)ethyl methacrylate (DMAEMA) on the hydrophilicity of the final polymer and justify your approach.'}] +[{'id': 1, 'text': 'Describe how the molecule Tween 20 can be chemically modified and incorporated into a polymer matrix to enhance its hydrophilicity. Include details of any reactions or catalysts that might be required.'}, {'id': 2, 'text': 'What experimental steps would you take to ensure that Tween 20 is covalently bonded within a polymer network, thereby improving the hydrophilic properties of the material?'}, {'id': 3, 'text': "Explain how the addition of Tween 20 to a polymer system might influence the material's transparency and adhesion in the final coating. What considerations should be made during the synthesis process?"}] +[{'id': 1, 'text': "Consider the incorporation of hydroxyethyl methyl acrylate (HEMA) into your experimental scheme. What role does HEMA play in enhancing the hydrophilicity of the polymer, and how might its concentration influence the resulting polymer's properties?"}, {'id': 2, 'text': 'In your synthesis of hydrophilic polymers, if isophorone diisocyanate (IPDI) is used to form a prepolymer, how would you ensure that the functional groups required for increased hydrophilicity are introduced into the polymer structure?'}, {'id': 3, 'text': 'Dimethylol propionic acid (DMPA) is often used to introduce carboxyl groups in a polymer matrix. How would you incorporate DMPA into your experimental procedure to modify the polymer for increased hydrophilicity, ensuring proper compatibility within the reaction system?'}] +[{'id': 1, 'text': 'Given the molecule ethylene glycol, describe how you would identify if it can form polymerizable monomers under the experimental preparation scheme to enhance polymer hydrophilicity.'}, {'id': 2, 'text': 'Using ethylene glycol, propose a step-growth polymerization reaction that would allow the formation of a polymer with enhanced hydrophilicity. Ensure the monomer selection complies with the prerequisites for polymerizable functional groups.'}, {'id': 3, 'text': 'Ethylene glycol contains hydroxyl groups which are hydrophilic. Explain how you would ensure functional group compatibility during polymerization to generate a homopolymer or bipolymer with enhanced hydrophilicity.'}] +[{'id': 1, 'text': "Explain the role of 2-acrylamide-2-methylpropane sulfonic acid (AMPS) in the preparation of hydrophilic polymers and describe how it contributes to the final product's properties."}, {'id': 2, 'text': 'Describe the chemical mechanism by which 3-(trimethoxysilyl)propyl-2-methyl-2-methacrylate (MPS) interacts with other components during polymer modification to enhance hydrophilicity.'}, {'id': 3, 'text': 'When using tetraethylorthosilicate (TEOS) in the experimental process, explain how its role affects the structure and hydrophilicity of the polymer material, and outline a step-by-step approach for incorporating it effectively.'}] +[{'id': 1, 'text': 'Explain the role of 1-bromoheptane in modifying the polymer structure and describe how its incorporation could contribute to enhancing the hydrophilicity of the resulting polymer.'}, {'id': 2, 'text': 'Describe the steps you would take to prepare a dual-cross-linked hydrophilic polymer coating using quaternary ammonium groups. Why do you think these groups are important in modifying the surface properties of the polymer?'}, {'id': 3, 'text': 'During the preparation process, how would you ensure that the quaternary ammonium copolymer is adequately purified after its reaction with 1-bromoheptane, and why is this step critical to the overall success of enhancing hydrophilicity?'}] +[{'id': 1, 'text': 'Using a charged material of your choice, describe how you would prepare a hydrophilic polymer surface modification using a cyclic process to ensure uniform deposition of the material. Detail the steps involved in the adsorption and washing phases.'}, {'id': 2, 'text': 'Explain how you would utilize alternating charged materials in a layer-by-layer (LbL) assembly process to modify a polymer, and discuss how the interaction of these charged materials can enhance the hydrophilicity of the resulting polymer material.'}, {'id': 3, 'text': 'Design an experimental scheme to deposit multiple nanometer-scale layers of charged molecular materials onto a polymer substrate, ensuring each layer enhances the overall hydrophilic properties of the polymer. Outline the control parameters you would use to achieve the desired thickness and hydrophilicity.'}] +[{'id': 1, 'text': 'Identify a suitable solvent to swell the polymer that will allow effective interaction with the provided molecule and explain the criteria you used to select this solvent.'}, {'id': 2, 'text': 'Explain the role of the provided molecule in enhancing the hydrophilicity of the polymer and describe how you would incorporate it into a polymer solution for successful modification.'}, {'id': 3, 'text': "Design an experimental procedure to measure the viscosity of the polymer solution after interacting with the provided molecule and explain how this measurement relates to the effectiveness of enhancing the polymer's hydrophilicity."}] +[{'id': 1, 'text': 'Describe how you would utilize PEG-\\cdotNH2 to modify a polymer and enhance its hydrophilicity. Include the steps you would take to prepare and purify the resulting nanocomposite.'}, {'id': 2, 'text': 'When preparing a hydrophilic polymer using BP and PLGA, explain how you would utilize dichloromethane to dissolve the components and what steps you would take to remove any residual solvent from your material.'}, {'id': 3, 'text': 'Outline the procedure for preparing a BP/Pluronic F127-based hydrophilic polymer composite using freeze drying. Include the critical factors you would consider to ensure strong bonding between the components.'}] +[{'id': 1, 'text': "How can electrostatic interactions between a charged polymer and a nanoparticle be leveraged to assemble a hydrophilic multilayer structure? Describe the steps and specify how you would enhance the polymer's hydrophilicity using this method."}, {'id': 2, 'text': "Design an experimental protocol that uses hydrogen bonding interactions between a hydrophilic polymer and a protein to modify the polymer's surface properties. Detail the role of each material in increasing hydrophilicity."}, {'id': 3, 'text': 'Explain how you would use a host-guest interaction between a suprastructure and a polymer in a layer-by-layer assembly to improve the hydrophilicity of the polymer. Include details about substrate preparation and the number of desired layers.'}] +[{'id': 1, 'text': 'Dimethyl sulfate is used in the experimental preparation scheme to modify the polymer. Explain how the conversion of amine groups to quaternary ammonium groups using dimethyl sulfate contributes to enhancing hydrophilicity in the polymer.'}, {'id': 2, 'text': 'Methyl ethyl ketone (MEK) is included in the reaction alongside dimethyl sulfate. Analyze the role of MEK in the reaction process and how its proper usage might influence the final hydrophilic properties of the polymer.'}, {'id': 3, 'text': "Ethanolamine is one of the starting materials used in polymer modification. Propose how ethanolamine's structure and reactivity play a vital role in introducing hydrophilic functional groups into the polymer material."}] +[{'id': 1, 'text': 'Explain the role of 2-acrylamido-2-methyl propane sulfonic acid (AMPS) in enhancing the hydrophilicity of the polymer during its copolymerization process.'}, {'id': 2, 'text': 'Describe how the isocyanate-containing monomer HIp can be utilized to introduce cross-linkable double bonds and urethane groups into the polymer, and its contribution to the hydrophilicity of the final material.'}, {'id': 3, 'text': 'Outline a step-by-step procedure for ionizing U-PHEMA using KOH-methanol solution, ensuring that the resulting product improves polymer hydrophilicity and is suitable for application as an anti-fog coating.'}] +[{'id': 1, 'text': 'Describe a detailed procedure for synthesizing a hydrophilic polymer using 2-(dimethylamino)ethyl methacrylate (DMAEMA) as a primary monomer through free radical polymerization. Include steps for purification and any post-modification, if applicable.'}, {'id': 2, 'text': 'Explain how partial quaternization using 1-bromoundecane can be employed to modify a polymer synthesized using 2-(dimethylamino)ethyl methacrylate (DMAEMA). What is the significance of this step in enhancing hydrophilicity?'}, {'id': 3, 'text': 'Design an experimental scheme to achieve a balance between hydrophilicity and structural stability for a coating material using a polymer containing 2-(dimethylamino)ethyl methacrylate (DMAEMA). Be specific about the role of hydrophilic functional groups in this process.'}] +[{'id': 1, 'text': 'Describe the steps you would take to incorporate 3-(Trimethoxysilyl) propyl methacrylate (TPM) into a polymer network to enhance the hydrophilicity of the resulting material.'}, {'id': 2, 'text': 'How would you confirm the successful photopolymerization of 3-(Trimethoxysilyl) propyl methacrylate (TPM) in your experiment, and what spectral features would you monitor to ensure this process has occurred?'}, {'id': 3, 'text': 'While preparing a hydrophilic polymer, explain how the hydrolysis and condensation of the siloxane moieties in 3-(Trimethoxysilyl) propyl methacrylate (TPM) contribute to the structural integrity and properties of the final polymer network.'}] +[{'id': 1, 'text': 'Describe a detailed experimental scheme for incorporating TMP(EO)3TA into a polymer matrix to enhance hydrophilicity. Outline the mixing, curing, and thickness measurement steps clearly.'}, {'id': 2, 'text': 'What considerations should be made when using TMP(EO)3TA to achieve uniform dispersion in the polymer material during high-speed mixing? Provide reasoning behind your approach.'}, {'id': 3, 'text': 'Explain how the UV curing process could impact the hydrophilic properties of a polymer modified with TMP(EO)3TA. Include details on how you would monitor or optimize the curing conditions.'}] +[{'id': 1, 'text': 'Discuss how photoinitiators can be utilized to modify the polymer structure in a manner that enhances its hydrophilicity. What specific role do photoinitiators play in initiating reactions during the curing process?'}, {'id': 2, 'text': 'In the context of preparing a hydrophilic polymer, explain the importance of selecting a low viscosity resin for the desired modification. How does the viscosity of the resin impact the effectiveness of the hydrophilic enhancement?'}, {'id': 3, 'text': 'Evaluate the effect of varying photoinitiator concentration on achieving hydrophilicity in the polymer. How would you optimize this parameter to ensure successful hydrophilic modification?'}] +[{'id': 1, 'text': 'Based on your understanding of polymer hydrophilicity enhancement, explain the role of 2-Chloropropionyl chloride in the derivatization process of a polymer and outline the steps you would take to ensure a substitution degree of at least 3.0 while carrying out the reaction.'}, {'id': 2, 'text': 'Describe how you would utilize N-butylimidazole to introduce a cationic functional group into a polymer. Include the reaction conditions you would implement to achieve a homogenous product.'}, {'id': 3, 'text': 'Considering an anion exchange step, such as involving sodium perfluorooctanoate (C8F17COONa), propose a method to prepare a polymer derivative with specific hydrophilic and hydrophobic modifications. Explain how this affects the overall hydrophilicity of the polymer.'}] +[{'id': 1, 'text': 'Explain how you would use N-carboxyethyl chitosan (CEC) as a functional component to enhance the hydrophilicity of a polymer matrix, using a synthesis approach that incorporates crosslinking and functional group integration.'}, {'id': 2, 'text': "Design an experimental protocol to incorporate N-carboxyethyl chitosan (CEC) into a polymer hydrogel system, ensuring the final material has improved hydrophilic properties. Describe the role of CEC in the resulting hydrogel's hydrophilicity."}, {'id': 3, 'text': 'When preparing a hydrophilic polymer using N-carboxyethyl chitosan (CEC), what are the essential steps to ensure the polymer is functionalized appropriately with hydrophilic groups? Include considerations for polymerization and post-processing.'}] +[{'id': 1, 'text': "Using 4,4'-diaminodiphenylmethane as a molecule that can introduce functional groups, propose an experimental scheme to modify a polymer to improve its hydrophilicity. Specifically, describe how this molecule would interact with the polymer and the conditions required for the reaction."}, {'id': 2, 'text': "Choose an appropriate polymer and explain how 3,3'-dichlorodiphenylmethane could be utilized as a modification agent to enhance its hydrophilicity. Include the steps necessary to ensure proper integration of the molecule into the polymer's structure."}, {'id': 3, 'text': 'Design a complete experimental setup using phenolic epoxy as the starting polymer and describe how you would incorporate a functional group using triethanolamine to make the polymer hydrophilic. Include the necessary reactants, solvents, and environmental conditions (e.g., temperature, pH) for the synthesis.'}] +[{'id': 1, 'text': 'Describe the role of polyethylene glycol mono-methacrylate (PEGMA) in the synthesis of a hydrophilic polymer. How would you ensure its effective incorporation into the polymer structure?'}, {'id': 2, 'text': 'Ethanedithiol is provided for the experiment. Propose a mechanism for how it might interact with other components to enhance hydrophilicity, and outline any precautions you would take during its handling or reaction.'}, {'id': 3, 'text': 'How would you utilize pentaerythritol tetrathioglycolate (PTMP) in a polymer modification experiment to enhance hydrophilicity? Elaborate on the steps to ensure a consistent product and high reaction yield.'}] +[{'id': 1, 'text': 'Identify a potential surface modification approach using a molecule generated by PolyTAO to enhance hydrophilicity in a polymer. What key functional groups in the molecule would contribute to greater water affinity?'}, {'id': 2, 'text': 'Design an experimental scheme that incorporates the molecule generated by PolyTAO into the backbone or side chain of the target polymer. How would you ensure the successful integration of this hydrophilic molecule during the synthesis process?'}, {'id': 3, 'text': 'Evaluate the hydrophilicity of the polymer after incorporating the molecule generated by PolyTAO. What experimental methods would you use to validate the improvement in hydrophilicity and water interaction?'}] +[{'id': 1, 'text': "Given the goal of enhancing the hydrophilicity of a polymer, design an experimental scheme to modify the polymer by incorporating a molecule with functional groups, specifically using 'μ_ref' as part of the process. How would you ensure proper equilibrium in the system to successfully integrate this molecule?"}, {'id': 2, 'text': "Describe the steps you would take to calculate the value of λ0 when modifying the polymer with 'μ_ref'. How does solving this boundary value problem contribute to determining the hydrophilic properties of the modified polymer?"}, {'id': 3, 'text': "When using 'μ_ref' to enhance the hydrophilicity of a polymer, explain how you would characterize the mobility tensor in the new reference configuration and ensure accurate representation of the polymer's structural changes."}] +[{'id': 1, 'text': 'Describe how dopamine hydrochloride can be incorporated into a polymer functionalization scheme to enhance hydrophilicity. What role does this molecule play in the modification process?'}, {'id': 2, 'text': 'Explain how the pH conditions during a reaction involving dopamine hydrochloride could influence its incorporation into a polymer and the subsequent hydrophilicity of the modified material.'}, {'id': 3, 'text': 'Propose a purification method to isolate the final product after modifying a polymer with dopamine hydrochloride. How would you ensure the product’s hydrophilicity is preserved during purification?'}] +[{'id': 1, 'text': 'Explain the role of hydrogen peroxide (H2O2) in the preparation of hydrophilic chitosan materials and how its concentration may influence the final properties of the polymer.'}, {'id': 2, 'text': 'Design an experiment to determine the optimal conditions (e.g., temperature, pH, and current density) for using hydrogen peroxide (H2O2) to modify chitosan for enhanced hydrophilicity. Explain your rationale for selecting these conditions.'}, {'id': 3, 'text': 'Describe how the addition of hydrogen peroxide (H2O2) might interact with the electrodeposition process of chitosan and influence the structural parameters such as pore size, porosity, and overall hydrophilicity of the resulting polymer.'}] +[{'id': 1, 'text': 'Describe the role of 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPS) in the synthesis process and explain how its incorporation enhances the hydrophilicity of the resulting polymer.'}, {'id': 2, 'text': 'In the experimental setup involving 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPS), what considerations must be made when selecting the concentration, and how does this influence the polymer structure?'}, {'id': 3, 'text': 'Propose an alternate polymerization setup where 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPS) could successfully achieve enhanced hydrophilicity while addressing any potential challenges in reaction control or material properties.'}] +[{'id': 1, 'text': 'Explain how you would incorporate hydroxyapatite (HAP) nanoparticles into a hydrophilic polymer matrix to enhance the surface characteristics of a polymer. What role does HAP play in achieving the desired hydrophilicity?'}, {'id': 2, 'text': 'Describe the process of modifying a polymer using methacryloyl gelatin (GelMA). Specifically, outline how you would ensure the successful grafting of GelMA onto the polymer surface while maintaining its hydrophilic properties.'}, {'id': 3, 'text': 'Discuss the steps required to prepare methacryloyl chitosan (CSMA) and describe how you would graft it onto the surface of a polymer to enhance its hydrophilicity. Include potential challenges in the process and how you would address them.'}] +[{'id': 1, 'text': 'Explain how tannic acid can be used to enhance the hydrophilicity of a polymer material. Provide a step-by-step experimental outline for using its hydroxyl groups to achieve this modification.'}, {'id': 2, 'text': 'Describe a procedure for functionalizing an inert polymer surface using tannic acid in combination with metal ions. How would this approach improve the hydrophilicity of the polymer?'}, {'id': 3, 'text': 'Propose a method to integrate tannic acid within a polymer matrix to create a hydrophilic coating. How does the utilization of tannic acid contribute to the desired hydrophilic properties?'}] +[{'id': 1, 'text': 'Explain how cyanoacrylate monomers can be utilized to modify a polymer network to enhance its hydrophilicity. Include details about the type of polymerization involved and any necessary considerations during preparation.'}, {'id': 2, 'text': 'Discuss how the diffusion depth of cyanoacrylate monomers within a polymer matrix influences the integrity of the final hydrophilic polymer product. What steps would you include in your experimental design to control this?'}, {'id': 3, 'text': 'Describe the method you would use to ensure complete removal of unreacted cyanoacrylate monomers and initiators from the polymer material during the preparation of hydrophilic polymers. Why is this step critical for the outcome?'}] +[{'id': 1, 'text': 'Explain how you would use photocrosslinkable methacrylic pullulan as a functional molecule to enhance the hydrophilicity of a polymer. Include the relevant steps for its modification and integration.'}, {'id': 2, 'text': 'Describe how you would incorporate photocrosslinkable methacrylic pullulan into a prepolymer solution during 3D printing in order to achieve hydrophilic properties in the resulting polymer material.'}, {'id': 3, 'text': 'Design an experimental scheme for synthesizing a hydrophilic polymer using photocrosslinkable methacrylic pullulan, ensuring the polymer is suitable for applications requiring high water retention. Include the methods for crosslinking and any functional group modifications.'}] +[{'id': 1, 'text': 'Explain the role of methacrylic anhydride (MA) in modifying a polymer to enhance its hydrophilicity. Include the specific steps you would take to incorporate this molecule into the polymer structure.'}, {'id': 2, 'text': 'How would you determine the degree of functionalization (DoF) after functionalizing a polymer with methacrylic anhydride (MA)? Describe this process and the calculations involved.'}, {'id': 3, 'text': 'Describe the procedure for analyzing the crosslinking density of a polymer modified with methacrylic anhydride (MA). Include the method and any key parameters you would measure or calculate.'}] +[{'id': 1, 'text': 'You are tasked with synthesizing poly(ethylene glycol) diacrylate (PEGDA). Based on the molecule provided, describe the procedure to functionalize polyethylene glycol (PEG) with acrylate groups and identify the key reaction steps involved in the acrylation process.'}, {'id': 2, 'text': 'Using gelatin methacryloyl (GelMA) as the selected molecule, outline a method to produce GelMA pre-polymers. In your response, specify how you would control the degree of methacrylation during the synthesis process and why this is important for enhancing hydrophilicity.'}, {'id': 3, 'text': 'Taking methacrylated hyaluronic acid (MeHA) as the reference molecule, design a detailed experimental process to prepare MeHA hydrogels. Include steps for methacrylation, purification, and photopolymerization, and explain how each step contributes to achieving a hydrophilic polymer.'}] +[{'id': 1, 'text': 'Given hydroxyethyl acrylate (HEA), design an experimental procedure to introduce functional hydroxyl groups into a polymer to enhance its hydrophilicity. Be sure to specify reaction conditions and how you would confirm the presence of hydroxyl groups in the resulting polymer.'}, {'id': 2, 'text': "Using diethylene glycol diacrylate (DEGDA) as the chosen molecule, outline the steps for synthesizing a crosslinked polymer network. How would this structure contribute to improved hydrophilicity, and what methods would you use to assess the polymer's water-absorption capacity?"}, {'id': 3, 'text': 'If ethoxy ethoxyethyl acrylate (EOEOEA) is available, suggest an experimental scheme for its utilization in polymer synthesis. Describe how this molecule’s structure can affect the hydrophilicity of the polymer and propose a method to evaluate its water affinity.'}] +[{'id': 1, 'text': 'How would you utilize N,N-dimethylacrylamide (DMAA) in the experimental process to enhance the hydrophilicity of a polymer material? Describe the role of this molecule during polymer preparation.'}, {'id': 2, 'text': 'Design an experimental scheme where N,N-dimethylacrylamide (DMAA) is included to form a hydrophilic coating on a medical-grade polymer surface. Be specific about the steps and conditions required.'}, {'id': 3, 'text': 'Explain the polymerization mechanism of N,N-dimethylacrylamide (DMAA) in the presence of a photoinitiator and ultraviolet light, and how this contributes to the hydrophilicity of the resulting polymer.'}] +[{'id': 1, 'text': 'Discuss the role of benzophenone in the preparation of hydrophilic polymer coatings and explain why it is critical to the modification process.'}, {'id': 2, 'text': 'Describe how you would ensure that N,N-dimethylacrylamide (DMAA) is effectively polymerized onto a polymer surface to enhance hydrophilicity. Include any necessary steps to prepare the surface before polymerization.'}, {'id': 3, 'text': 'Why is it important to use a biocompatible photoinitiator like Irgacure 2959 in hydrophilic polymer synthesis, and how does its use influence the polymerization process?'}] +[{'id': 1, 'text': 'How would you utilize the molecule polydopamine in your experimental design to create an initiation layer that facilitates the synthesis of hydrophilic polymers?'}, {'id': 2, 'text': 'Explain the role of citric acid in the reduction of iron ions during the preparation process, and how this step contributes to enhancing the hydrophilicity of the polymer.'}, {'id': 3, 'text': 'Describe the steps you would take to incorporate a monomer solution into the preparation process, and explain how the reaction is initiated to grow a hydrophilic hydrogel coating.'}] +[{'id': 1, 'text': 'Design an experimental scheme to prepare a hydrophilic polymer coating using acrylamide (AM) as the primary monomer. Ensure you include key steps such as polymerization initiation, cross-linking, and any necessary post-treatment processes.'}, {'id': 2, 'text': 'Explain how methacrylic acid (MAA) can be utilized as a co-monomer in the preparation of a hydrophilic polymer. Discuss its role in enhancing polymer hydrophilicity and how it can be incorporated into the polymer network.'}, {'id': 3, 'text': 'Propose an experimental method to synthesize a hydrogel coating using poly(ethylene glycol) methyl ether methacrylate (OEGMA). Include the type of initiator and cross-linker you would use, as well as the steps for coating application and final processing.'}] +[{'id': 1, 'text': 'Describe the role of polyaniline (PANI) in the preparation of hydrophilic polymers and explain how it contributes to the functionality of the final polymer material.'}, {'id': 2, 'text': 'When using polyaniline (PANI) to modify a polymer matrix, what specific steps would you take to ensure a homogeneous distribution of PANI within the system during polymerization?'}, {'id': 3, 'text': 'Incorporating polyaniline (PANI) into a polymer network involves addressing potential interactions between PANI and the gel matrix. How would you design an experiment to minimize any negative interactions while retaining the hydrophilicity enhancement provided by PANI?'}] +[{'id': 1, 'text': "Explain how the molecule N,N'-methylenebisacrylamide (MBAM) can be utilized as a crosslinker in the preparation of hydrophilic polymers. Include in your answer what role it plays in the polymer network and how its inclusion might enhance hydrophilicity."}, {'id': 2, 'text': 'Describe a step-by-step procedure to include calcium chloride (CaCl2) in the polymerization process to enhance the hydrophilicity of the resulting material. What is the significance of adding this molecule, and how might it interact with other components during synthesis?'}, {'id': 3, 'text': 'Discuss how sodium alginate (SA) could be utilized as the primary material in the synthesis of a hydrophilic polymer. What properties of SA make it suitable for this purpose, and how would you ensure it is effectively incorporated into the polymer network?'}] +[{'id': 1, 'text': "In the synthesis of hydrophilic polymers, explain the role of adipic acid dihydrazide in modifying a polymer's functional groups. How would you ensure it reacts effectively with the polymer backbone?"}, {'id': 2, 'text': 'When using adipic acid dihydrazide to functionalize a polymer, what precautions or steps would you take to achieve a high degree of modification while avoiding side reactions?'}, {'id': 3, 'text': 'Describe how you would verify that adipic acid dihydrazide has been successfully incorporated into a polymer to enhance its hydrophilicity. What specific analytical techniques would you use, and what results would you expect?'}] +[{'id': 1, 'text': 'Describe how you would incorporate TMS-PEG into a polymer matrix to enhance its hydrophilicity. What steps would you take to ensure its uniform dispersion within the polymer material?'}, {'id': 2, 'text': 'Tetrabutylammonium fluoride (TBAF) is commonly used as a catalyst in polymer modification. Explain how you would use TBAF in your synthesis process to enhance the hydrophilicity of a polymer, specifying any precautions necessary to optimize the reaction.'}, {'id': 3, 'text': 'In an experimental setup, how would you systematically vary the concentration of TMS-PEG to study its effect on the hydrophilicity of the modified polymer? Suggest a methodology to evaluate and quantify the change in hydrophilicity across different samples.'}] +[{'id': 1, 'text': 'Describe how you would use a molecule with a low logP value to modify a polymer, ensuring that it enhances the hydrophilicity of the final polymer material.'}, {'id': 2, 'text': 'Explain how the number of hydrogen-bond donors (HBD) and acceptors (HBA) in a molecule could influence its ability to enhance the hydrophilicity of the polymer in your design.'}, {'id': 3, 'text': 'Propose an approach to assess the influence of the topological polar surface area (TPSA) of the chosen molecule on the hydrophilicity of the modified polymer after the experiment.'}] diff --git a/code/make_qa_bp.py b/code/make_qa_bp.py new file mode 100644 index 0000000..ba0f474 --- /dev/null +++ b/code/make_qa_bp.py @@ -0,0 +1,620 @@ +""" +This script generates questions and answers from a given set of CIFs. +It uses the OpenAI API and MySQL for storing and retrieving data. +@author: Yutang Li +""" +import multiprocessing +import os +import re +import json +import random +import time +import tqdm +import glob +import datetime +import sqlite3 +import copy +import multiprocessing +from functools import partial +from openai import OpenAI, APIError # Ensure correct exception class is imported +from mysql.connector import pooling, Error +from make_qa_prompts_bp import FUNC_GROUPS_QUESTION_RPOMPT, FUNC_GROUPS_ANSWER_PROMPT, PROTOCOL_QUESTION_RPOMPT, PROTOCOL_ANSWER_RPOMPT, SELECT_QUESTION_PROMPT + + +# Constants +OPENAI_BASE_URL = "https://vip.apiyi.com/v1" +# OPENAI_BASE_URL = "http://8.218.238.241:17935/v1" +OPENAI_API_KEY = "sk-oYh3Xrhg8oDY2gW02c966f31C84449Ad86F9Cd9dF6E64a8d" +# MODEL_GPT = "gpt-4o-mini" +MODEL_GPT = "chatgpt-4o-latest" +# MINI_MODEL_NAME = "gpt-4o-2024-08-06" +# MAX_MODEL_NAME = "claude-3-5-sonnet-20240620" +# MAX_MODEL_NAME = "gpt-4o-2024-11-20" +# MODEL_GEMINI = "gemini-1.5-flash-002" +MODEL_GEMINI = "gemini-1.5-pro-latest" +MODEL_CLAUDE = "claude-3-5-sonnet-20240620" +# MYSQL_TABLE_NAME = "cif_qa_1104" +# cur_dirname = os.path.dirname(__file__) +# DOC_DIR_NAME = os.path.join(cur_dirname, "qa_source_md") +PROCESS = 32 # Number of parallel processes + +# def record_exists(mp_id, table_name): +# """Check if a mp_id already exists in the table.""" +# db = connection_pool.get_connection() +# cursor = db.cursor() +# query = f"SELECT * FROM {table_name} WHERE mp_id = %s" +# cursor.execute(query, (mp_id,)) +# result = cursor.fetchone() +# cursor.fetchall() # Ensure all results are processed +# cursor.close() +# db.close() +# return result is not None + +# def insert_record(entry, table_name): +# """Insert a record into the MySQL table.""" +# db = None +# cursor = None +# try: +# db = connection_pool.get_connection() +# cursor = db.cursor() + +# insert_query = f""" +# INSERT INTO {table_name} +# (mp_id, question_model, question, answer_model, answer, answer_len) +# VALUES (%s, %s, %s, %s, %s, %s) +# """ +# values = ( +# entry["mp_id"], entry["question_model"], +# entry["question"], entry["answer_model"], entry["answer"], entry["answer_len"], +# ) +# cursor.execute(insert_query, values) +# db.commit() + +# except Error as e: +# print(f"Error: {e}") +# db.rollback() +# finally: +# # Ensure cursor is closed +# if cursor: +# cursor.close() +# # Ensure connection is returned to the pool +# if db: +# db.close() + +def read_cif_txt_file(file_path): + """Read the markdown file and return its content.""" + try: + with open(file_path, 'r', encoding='utf-8') as f: + return f.read() + except Exception as e: + print(f"Error reading file {file_path}: {e}") + return None + +def round_values(data): + """ + 递归地将字典中的所有值保留三位小数 + """ + if isinstance(data, dict): # 如果是字典 + return {key: round_values(value) for key, value in data.items()} + elif isinstance(data, list): # 如果是列表,递归处理每个元素 + return [round_values(item) for item in data] + elif isinstance(data, (int, float)): # 如果是数字,保留三位小数 + return round(data, 3) + else: # 对其他类型,直接返回 + return data + + +def remove_null_values(d): + """ + Recursively remove key-value pairs with null (None) values from a dictionary. + + Args: + d (dict): The dictionary to clean. + + Returns: + dict: A new dictionary without null values. + """ + if not isinstance(d, dict): + raise ValueError("Input must be a dictionary") + _d = copy.deepcopy(d) + + def recursive_remove(d): + cleaned_dict = {} + for key, value in d.items(): + if isinstance(value, dict): + # Recursively clean nested dictionaries + nested_cleaned = recursive_remove(value) + if nested_cleaned: # Only add non-empty dictionaries + cleaned_dict[key] = nested_cleaned + elif value is not None and key != 'version': + cleaned_dict[key] = value + + return cleaned_dict + + clean_dict = recursive_remove(d) + if _d['cbm'] is None and _d['vbm'] is None: + # clean_dict['band_gap'] = None + clean_dict.pop('band_gap') + return clean_dict + + +def get_extra_cif_info(path: str, fields_name: list): + """Extract specific fields from the CIF description.""" + basic_fields = ['formula_pretty', 'formula_anonymous', 'chemsys', 'composition', 'elements', 'symmetry', 'nelements', 'nsites', 'volume', 'density', 'density_atomic'] + energy_electronic_fields = ['formation_energy_per_atom', 'energy_above_hull', 'is_stable', 'efermi', 'cbm', 'vbm', 'band_gap', 'is_gap_direct'] + metal_magentic_fields = ['is_metal', 'is_magnetic', "ordering", 'total_magnetization', 'num_magnetic_sites'] + # metal_magentic_fields = ['is_metal', 'is_magnetic', "ordering", 'total_magnetization', 'total_magnetization_normalized_vol', 'total_magnetization_normalized_formula_units', 'num_magnetic_sites', 'num_unique_magnetic_sites', 'types_of_magnetic_species', "decomposes_to"] + + selected_fields = [] + if fields_name[0] == 'all_fields': + selected_fields = basic_fields + energy_electronic_fields + metal_magentic_fields + # selected_fields = energy_electronic_fields + metal_magentic_fields + else: + for field in fields_name: + selected_fields.extend(locals().get(field, [])) + + with open(path, 'r') as f: + docs = json.load(f) + + new_docs = {} + for field_name in selected_fields: + new_docs[field_name] = docs.get(field_name, '') + + # new_docs['structure'] = {"lattice": docs['structure']['lattice']} + return new_docs + +def extract_json(text): + """Extract JSON content from a block of text using regex.""" + json_pattern = re.compile(r'\\{(?:[^{}]|(?R))*\\}') + matches = json_pattern.search(text) + if matches: + json_str = matches.group(0) + try: + return json.loads(json_str) + except json.JSONDecodeError: + return None + return None + +def extract_and_parse_json(response): + """Extract and parse JSON from a response.""" + json_match = re.search(r'```(?:json)?\s*([\s\S]*?)\s*```', response) + json_str = json_match.group(1) if json_match else response.strip() + json_str = re.sub(r'(\$[^\$]*\$)', lambda m: m.group(1).replace('\\', '\\\\'), json_str) + json_str = json_str.replace('\\"', '"').replace("\\'", "'") + try: + return json.loads(json_str) + except json.JSONDecodeError as e: + print(f"JSON parse error: {e}") + return 'errformat' + + +# 计算输入消息的tokens +# def count_message_tokens(messages, model_name): +# encoding = tiktoken.encoding_for_model(model_name) +# num_tokens = 0 + +# num_tokens += len(encoding.encode(messages)) + +# return num_tokens + + +def generate_func_groups_question(func_groups_info, model_name): + """Generate a question from the source material using OpenAI with stream.""" + try: + # 替换上下文和主题 + instruction = FUNC_GROUPS_QUESTION_RPOMPT.replace("{CONTEXT}", func_groups_info) + + # 创建 OpenAI 客户端 + client = OpenAI(api_key=OPENAI_API_KEY, base_url=OPENAI_BASE_URL) + + # 请求非流式输出 + completion = client.chat.completions.create( + model=model_name, + stream=False, # 关闭流模式 + messages=[ + {"role": "system", "content": "You are a helpful assistant."}, + {"role": "user", "content": instruction} + ], + ) + + response = completion.choices[0].message.content + + # 请求流式输出 + # completion = client.chat.completions.create( + # model=model_name, + # stream=True, # 开启流模式 + # messages=[ + # {"role": "system", "content": "You are a helpful assistant."}, + # {"role": "user", "content": instruction} + # ], + # ) + + # response = "" # 用于累加响应内容 + # # 逐步读取并处理流数据 + # for chunk in completion: + # if chunk.choices[0].delta.content is not None: + # content = chunk.choices[0].delta.content + # response += content + + # 解析为 JSON 响应 + json_response = extract_and_parse_json(response) + if json_response == "errformat": + return 'errformat' + return json_response['questions'] # 返回指令和解析后的响应 + + except APIError as api_error: + print(f"generate_design_question API error: {api_error}") + time.sleep(30) + return 'apierror' + except Exception as e: + print(f"generate_design_question Unexpected error: {e}") + return 'unexpectederror' + + +def generate_protocol_question(protocol_info, model_name): + """Generate a question from the source material using OpenAI with stream.""" + try: + # 替换上下文和主题 + instruction = PROTOCOL_QUESTION_RPOMPT.replace("{CONTEXT}", protocol_info) + + # 创建 OpenAI 客户端 + client = OpenAI(api_key=OPENAI_API_KEY, base_url=OPENAI_BASE_URL) + + completion = client.chat.completions.create( + model=model_name, + stream=False, # 关闭流模式 + messages=[ + {"role": "system", "content": "You are a helpful assistant."}, + {"role": "user", "content": instruction} + ], + ) + + response = completion.choices[0].message.content + + # # 请求流式输出 + # completion = client.chat.completions.create( + # model=model_name, + # stream=True, # 开启流模式 + # messages=[ + # {"role": "system", "content": "You are a helpful assistant."}, + # {"role": "user", "content": instruction} + # ], + # ) + + # response = "" # 用于累加响应内容 + # # 逐步读取并处理流数据 + # for chunk in completion: + # if chunk.choices[0].delta.content is not None: + # content = chunk.choices[0].delta.content + # response += content + + # 解析为 JSON 响应 + json_response = extract_and_parse_json(response) + if json_response == "errformat": + return 'errformat' + return json_response['questions'] # 返回指令和解析后的响应 + + except APIError as api_error: + print(f"generate_design_question API error: {api_error}") + return 'apierror' + except Exception as e: + print(f"generate_design_question Unexpected error: {e}") + return 'unexpectederror' + + +def select_best_question(question_list, answer, model_name): + try: + # 替换上下文和主题 + instruction = SELECT_QUESTION_PROMPT.replace("{ANSWER}", answer).replace("{QUESTIONS}", json.dumps(question_list)) + + # 创建 OpenAI 客户端 + client = OpenAI(api_key=OPENAI_API_KEY, base_url=OPENAI_BASE_URL) + + # 请求非流式输出 + completion = client.chat.completions.create( + model=model_name, + stream=False, # 关闭流模式 + messages=[ + {"role": "system", "content": "You are a helpful assistant."}, + {"role": "user", "content": instruction} + ], + ) + + response = completion.choices[0].message.content + + # 请求流式输出 + # completion = client.chat.completions.create( + # model=model_name, + # stream=True, # 开启流模式 + # messages=[ + # {"role": "system", "content": "You are a helpful assistant."}, + # {"role": "user", "content": instruction} + # ], + # ) + + # response = "" # 用于累加响应内容 + # # 逐步读取并处理流数据 + # for chunk in completion: + # if chunk.choices[0].delta.content is not None: + # content = chunk.choices[0].delta.content + # response += content + + # 解析为 JSON 响应 + json_response = extract_and_parse_json(response) + + return json_response['questions'] # 返回指令和解析后的响应 + + except APIError as api_error: + print(f"select_best_question API error: {api_error}") + time.sleep(30) + return 'apierror' + except Exception as e: + print(f"select_best_question Unexpected error: {e}") + return 'unexpectederror' + + +def generate_func_groups_answer(question, func_groups_info, model_name): + """Generate an answer to a question using OpenAI with stream.""" + try: + instruction = FUNC_GROUPS_ANSWER_PROMPT.replace("{QUESTION}", question).replace("{func_groups_info}", func_groups_info) + client = OpenAI(api_key=OPENAI_API_KEY, base_url=OPENAI_BASE_URL) + + # 使用非流式输出 + completion = client.chat.completions.create( + model=model_name, + stream=False, # 关闭流模式 + messages=[ + {"role": "system", "content": "You are a helpful assistant."}, + {"role": "user", "content": instruction} + ], + ) + + response = completion.choices[0].message.content + + # 使用流式输出 + # completion = client.chat.completions.create( + # model=model_name, + # stream=True, # 开启流模式 + # messages=[{"role": "system", "content": "You are a helpful assistant."}, + # {"role": "user", "content": instruction}], + # ) + + # response = "" # 用于累加响应内容 + # # 逐步读取并处理流数据 + # for chunk in completion: + # if chunk.choices[0].delta.content is not None: + # content = chunk.choices[0].delta.content + # response += content + + return response.replace("placeholder", "").replace("Placeholder", "") + + except APIError as api_error: + print(f"generate_design_answer API error: {api_error}") + time.sleep(30) + return 'apierror' + except Exception as e: + print(f"generate_design_answer Unexpected error: {e}") + return 'unexpectederror' + + +def generate_protocol_answer(question, protocol_info, model_name): + """Generate an answer to a question using OpenAI with stream.""" + try: + instruction = PROTOCOL_ANSWER_RPOMPT.replace("{QUESTION}", question).replace("{context}", protocol_info) + client = OpenAI(api_key=OPENAI_API_KEY, base_url=OPENAI_BASE_URL) + + completion = client.chat.completions.create( + model=model_name, + stream=False, # 关闭流模式 + messages=[ + {"role": "system", "content": "You are a helpful assistant."}, + {"role": "user", "content": instruction} + ], + ) + + response = completion.choices[0].message.content + + # # 使用流式输出 + # completion = client.chat.completions.create( + # model=model_name, + # stream=True, # 开启流模式 + # messages=[{"role": "system", "content": "You are a helpful assistant."}, + # {"role": "user", "content": instruction}], + # ) + + # response = "" # 用于累加响应内容 + # # 逐步读取并处理流数据 + # for chunk in completion: + # if chunk.choices[0].delta.content is not None: + # content = chunk.choices[0].delta.content + # response += content + + return response.replace("placeholder", "").replace("Placeholder", "") + + except APIError as api_error: + print(f"generate_design_answer API error: {api_error}") + return 'apierror' + except Exception as e: + print(f"generate_design_answer Unexpected error: {e}") + return 'unexpectederror' + + +# def generate_func_groups_qa(file_content, sup_content, model_name): +def generate_func_groups_qa(file_content, model_name): + # 1.生成设计的候选问题 + func_groups_info = str(file_content) + # question = generate_question(question_context, MAX_MODEL_NAME) + question = generate_func_groups_question(func_groups_info, model_name) + retry = 0 + while (question=='errformat' or question == 'apierror' or question == 'unexpectederror') and retry < 3: + question = generate_func_groups_question(func_groups_info, model_name) + retry += 1 + # print(question) + + # 2. 设计问答对打分以筛选最好问题 + # score = select_best_question(question, pre_answer, MAX_MODEL_NAME) + score = select_best_question(question, func_groups_info, model_name) + retry = 0 + while (score=='errformat' or score == 'apierror' or score == 'unexpectederror') and retry < 3: + score = select_best_question(question, func_groups_info, model_name) + retry += 1 + score = sorted(score, key=lambda x: x['score'], reverse=True) + q_idx = score[0]['id'] - 1 + # 3. 生成答案 + # pre_answer = generate_func_groups_answer(question[q_idx]['text'], func_groups_info, sup_content, model_name) + pre_answer = generate_func_groups_answer(question[q_idx]['text'], func_groups_info, model_name) + retry = 0 + while (pre_answer=='errformat' or pre_answer == 'apierror' or pre_answer == 'unexpectederror') and retry < 3: + # pre_answer = generate_func_groups_answer(question[q_idx]['text'], func_groups_info, sup_content, model_name) + pre_answer = generate_func_groups_answer(question[q_idx]['text'], func_groups_info, model_name) + retry += 1 + return question[q_idx]['text'], pre_answer + + +def generate_protocol_qa(protocol_info, model_name): + # 1.生成设计的候选问题 + question = generate_protocol_question(protocol_info, model_name) + retry = 0 + while (question=='errformat' or question == 'apierror' or question == 'unexpectederror') and retry < 3: + question = generate_protocol_question(protocol_info, model_name) + retry += 1 + print(question) + # 2. 设计问答对打分以筛选最好问题 + score = select_best_question(question, protocol_info, model_name) + retry = 0 + while (score=='errformat' or score == 'apierror' or score == 'unexpectederror') and retry < 3: + score = select_best_question(question, protocol_info, model_name) + retry += 1 + score = sorted(score, key=lambda x: x['score'], reverse=True) + q_idx = score[0]['id'] - 1 + # 3. 生成答案 + pre_answer = generate_protocol_answer(question[q_idx]['text'], protocol_info, model_name) + retry = 0 + while (pre_answer=='errformat' or pre_answer == 'apierror' or pre_answer == 'unexpectederror') and retry < 3: + pre_answer = generate_protocol_answer(question[q_idx]['text'], protocol_info, model_name) + retry += 1 + return question[q_idx]['text'], pre_answer + + +# Processing function for a single file +def process_file(input_path, task_id): + # print(input_path) + with open(input_path, 'r', encoding='utf-8') as file: + file_content = json.load(file) + # print() + + if task_id == "task-1": + # 获取补充材料 + # with open("../supplementary/NP修饰黑磷/NP修饰黑磷.md", "r", encoding='utf-8') as file: + # n_p_content = file.read() + # with open("../supplementary/Si与S基团调控黑磷稳定性/Si与S基团调控黑磷稳定性.md", "r", encoding='utf-8') as file: + # si_s_content = file.read() + # sup_content = n_p_content + "\n\n" + si_s_content + # model_list = [MODEL_GPT, MODEL_GEMINI, MODEL_CLAUDE] + model = MODEL_GPT + func_goups = file_content["content"] + try: + # 不处理实验方案为空的数据 + if func_goups == {}: + return + # design_question, design_answer = generate_func_groups_qa(file_content, sup_content, model) + design_question, design_answer = generate_func_groups_qa(func_goups, model) + + data = { + "design_question": design_question, + "design_answer": design_answer + } + + output_path = os.path.join(output_task1, os.path.basename(input_path)) + # 将数据写入JSON文件 + with open(output_path, 'w', encoding='utf-8') as file: + json.dump(data, file, ensure_ascii=False, indent=2) + + # output_path = '../task-1/output.txt' + # with open(output_path, 'a') as txt_file: + # txt_file.write(f"{model} task-1问题:\n") + # txt_file.write(design_question+'\n') + # txt_file.write(f"{model} task-1答案:\n") + # txt_file.write(design_answer+'\n\n\n') + + except Exception as e: + print(f"Error processing file: {input_path}") + print(e) + elif task_id == "task-2": + try: + # 选择模型 + model = MODEL_GPT + # model_list = [MODEL_GPT, MODEL_GEMINI, MODEL_CLAUDE] + protocol_info = file_content["protocol"] + # 不处理实验方案为空的数据 + if protocol_info == "": + return + design_question, design_answer = generate_protocol_qa(protocol_info, model) + + data = { + "design_question": design_question, + "design_answer": design_answer + } + + output_path = os.path.join(output_task2, os.path.basename(input_path)) + # 将数据写入JSON文件 + with open(output_path, 'w', encoding='utf-8') as file: + json.dump(data, file, ensure_ascii=False, indent=2) + + # output_path = os.path.join(task2_dir, os.path.basename(input_path).replace('.json', '.txt')) + # with open(output_path, 'a') as txt_file: + # txt_file.write(f"{model} task-2问题:\n") + # txt_file.write(design_question+'\n') + # txt_file.write(f"{model} task-2答案:\n") + # txt_file.write(design_answer+'\n\n\n') + + except Exception as e: + print(f"Error processing file: {input_path}") + print(e) + + +if __name__ == "__main__": + task1_dir = "/home/ubuntu/50T/fsy/wl/" + task2_dir = "/home/ubuntu/50T/fsy/wl/" + + # 获取任务一所提取的信息的路径 + task1_paper_info_jsons_dir = os.path.join(task1_dir, "task1-paper-info") + task1_paper_info_jsons_paths = [os.path.join(task1_paper_info_jsons_dir, path) for path in os.listdir(task1_paper_info_jsons_dir)] + print("task1文件总数:", len(task1_paper_info_jsons_paths)) + # 过滤已处理文件 + output_task1 = os.path.join(task1_dir, "task1-qa") + processed_task1 = [path for path in os.listdir(output_task1)] + task1_paper_info_jsons_paths = [path for path in task1_paper_info_jsons_paths if os.path.basename(path) not in processed_task1] + print("过滤后task1文件数:", len(task1_paper_info_jsons_paths)) + + # 获取任务二所提取的信息的路径 + task2_paper_info_jsons_dir = os.path.join(task2_dir, "task2-paper-info") + task2_paper_info_jsons_paths = [os.path.join(task2_paper_info_jsons_dir, path) for path in os.listdir(task2_paper_info_jsons_dir)] + print("task2文件总数:", len(task2_paper_info_jsons_paths)) + # 过滤已处理文件 + output_task2 = os.path.join(task2_dir, "task2-qa") + processed_task2 = [path for path in os.listdir(output_task2)] + task2_paper_info_jsons_paths = [path for path in task2_paper_info_jsons_paths if os.path.basename(path) not in processed_task2] + print("过滤后task2文件数:", len(task2_paper_info_jsons_paths)) + + # 切换任务一与任务二 + + # process_file_with_params = partial(process_file, task_id = "task-2") + + for path in tqdm.tqdm(task1_paper_info_jsons_paths): + try: + process_file(path, "task-1") + except Exception as e: + print(f"处理 {path} 时出错: {e}") + + # 任务一 + # with multiprocessing.Pool(32) as pool: + # # Use tqdm to track progress + # for _ in tqdm.tqdm(pool.imap_unordered(process_file_with_params, task1_paper_info_jsons_paths), total=len(task1_paper_info_jsons_paths)): + # pass + + # 任务二 + # with multiprocessing.Pool(16) as pool: + # # Use tqdm to track progress + # for _ in tqdm.tqdm(pool.imap_unordered(process_file_with_params, task2_paper_info_jsons_paths), total=len(task2_paper_info_jsons_paths)): + # pass diff --git a/code/make_qa_bp_task1.log b/code/make_qa_bp_task1.log new file mode 100644 index 0000000..5ced71d --- /dev/null +++ b/code/make_qa_bp_task1.log @@ -0,0 +1,565 @@ +task1文件总数: 209 +过滤后task1文件数: 209 +task2文件总数: 209 +过滤后task2文件数: 40 +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/1-s2.0-S0927775719302274-main.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/1-s2.0-S0960852424013415-main.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/10.1002@adfm.201903419.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/10.1002@advs.202000439.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/2003-JP-anti-fog.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/2_UV╖└╬э╥║╩╣╙├╦╡├ў╩щ.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/AI╙├╙┌╙╨╗·-╛█║╧╬я║╧│╔.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/AI╝╝╩ї╘┌╗п╣д╨╨╥╡╔ш╝╞╣д╫ў╓╨╡─╙ж╙├╒╣═√_╜к╥╦╛¤.json +string indices must be integers, not 'str' +JSON parse error: Expecting property name enclosed in double quotes: line 12 column 21 (char 181) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/Advanced Materials - 2024 - Ng - Progress and Opportunities for Machine Learning in Materials and Processes of Additive.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/Application of machine learning in polymer additive manufacturing_ A review.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/CN114829509A╚╒▒╛-╖└╬э═┐▓у╫щ║╧╬ябв╖└╬э═┐─д╝░╖└╬э╓╞╞╖.json +string indices must be integers, not 'str' +JSON parse error: Expecting ',' delimiter: line 14 column 5 (char 740) +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/CN97126279-╙├╙┌╣╠╗п╗╖╤ї╩ў╓м╡─╕─╜°╡─╣╠╗п┤▀╗п╝┴-╔ъ╟ы╣л┐к.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting ',' delimiter: line 14 column 5 (char 846) +JSON parse error: Expecting ',' delimiter: line 14 column 5 (char 790) +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/Hydrophilic and superhydrophilic surfaces and materials.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/IPDI╘┌╛█░▒їе╖┤╙ж╓╨╢╘╤б╘ё╨╘╬┬╢╚бв┤▀╗п╣¤│╠║═╖┤╙ж╢╘╧є╡─╙░╧ь.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/SMiPoly┐╔║╧│╔╛█║╧╬я╨щ─т┐т╡─╔·│╔╩╣╙├╗∙╙┌╣ц╘Є╡─╛█║╧╖┤╙ж.json +string indices must be integers, not 'str' +JSON parse error: Expecting ',' delimiter: line 14 column 5 (char 832) +JSON parse error: Expecting ',' delimiter: line 14 column 5 (char 777) +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/Solvents_-_2015.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/Zhao et al.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/am9b09610_si_001.json +string indices must be integers, not 'str' +JSON parse error: Expecting ',' delimiter: line 14 column 5 (char 881) +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/ap4c00912_si_001.json +string indices must be integers, not 'str' +JSON parse error: Expecting ',' delimiter: line 14 column 5 (char 808) +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/binder2014.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/herkert-et-al-2022-characterization-of-per-and-polyfluorinated-alkyl-substances-present-in-commercial-anti-fog-products.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/martin-audus-2023-emerging-trends-in-machine-learning-a-polymer-perspective.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/s41524-023-01000-z.json +string indices must be integers, not 'str' +JSON parse error: Expecting ',' delimiter: line 14 column 5 (char 770) +JSON parse error: Expecting ',' delimiter: line 14 column 5 (char 784) +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/water drop-surface interactions as the basis for the design of anti-fogging surfaces.json +string indices must be integers, not 'str' +JSON parse error: Expecting ',' delimiter: line 14 column 5 (char 827) +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/└√╙├PubChem╜°╨╨╨щ─т╔╕╤б.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/└√╙├╔ю╢╚╤з╧░╥¤╡╝╡─╥┼┤л╦у╖и╠╜╦ў▓─┴╧╔ш╝╞┐╒╝ф.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/┤є╣ц─г╗п╤з╙я╤╘▒э╩╛▓╢╫╜╖╓╫╙╜с╣╣╙ы╨╘╓╩ zh.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/┤є╣ц─г╗п╤з╙я╤╘▒э╩╛▓╢╫╜╖╓╫╙╜с╣╣╙ы╨╘╓╩.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/┤╙═и╙├╨═╡╜╫и╝╥╨═г║╗п╤з┴ь╙Є┤є╨═╙я╤╘─г╨═╡─╫█╩Ў.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/═и═∙╧┬╥╗┤·╢р╧р┤▀╗п╝┴г║╗·╞ў...╓·┴ж▒э├ц╖┤╙ж╨╘╘д▓тги╙в╬─гй_┴ї╨╛╤╘.json +string indices must be integers, not 'str' +JSON parse error: Expecting ',' delimiter: line 14 column 5 (char 789) +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/║г╤є╗╖╛│╓╟─▄╖└╕п═┐▓уг║╜с╣╣╔ш╝╞╙ы╧ь╙ж╗·╓╞_╦я╙н╧ш.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/╔┘╤∙▒╛SI.json +string indices must be integers, not 'str' +JSON parse error: Expecting ',' delimiter: line 14 column 5 (char 820) +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/╕▀╖╓╫╙▓─┴╧╗∙╥Є╫щ╤╨╛┐╜°╒╣_╙жь│╢∙.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/╖█─й═┐┴╧╛▓╡ч┼ч═┐╡──¤╣╠╣¤│╠╖╓╬Ў╙ы▓╬╩¤╙┼╗п.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/╗∙╙┌├ш╩Ў╖√╠ї╝■╤н╗╖╔ё╛н═°┬ч╡─┤╙═╖╖╓╫╙╔·│╔╓▒╜╙╥¤╡╝.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/╗∙╙┌╗·╞ў╤з╧░╡─╥■╔э═┐┴╧╔ш╝╞╖╜╖и╙ы╤╨╛┐╜°╒╣_┴ї╨ё.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/╘┌╚э╗·╞ў╚╦╓╨╩╡╧╓┤л╕╨╘╦╢п╣ж─▄╡─╚э▓─┴╧║═╫░╓├.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/╙╛╛╡╖└╬э╥й╦о╕─╔╞╩ф╚ы-20191028.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/╚э╨╘║═╥║╠м╖╓╫╙▓─┴╧╡─╗·╞ў╤з╧░.json +string indices must be integers, not 'str' +JSON parse error: Expecting ',' delimiter: line 14 column 5 (char 731) +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/╚╦╣д╓╟─▄+╨┬▓─┴╧╤╨╖вг║┬ї╧Є...╘д▓т╨╘╔ш╝╞б▒║═б░╛л╫╝┤┤╓╞б▒_╣∙╫╙╖╝.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/╚╦╣д╓╟─▄╕и╓·╔ш╝╞╣ж─▄╨╘║═┐╔│╓╨°╛█║╧╬я.json +string indices must be integers, not 'str' +JSON parse error: Expecting ',' delimiter: line 14 column 5 (char 787) +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/╚╦╣д╓╟─▄╕и╓·╨┬╗п╤з╞╖╔ш╝╞╩╙╜╟.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/╚╦╣д╓╟─▄╘┌╗п╤з╣д│╠╓╨╡─╙ж╙├бкбк┤┤╨┬╡─╨┬╞к╒┬ги╙в╬─гй_╚╬╞ф┴·.json +string indices must be integers, not 'str' +JSON parse error: Expecting ',' delimiter: line 14 column 5 (char 785) +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/╛█║╧╬я╡─░┤╨ш─ц╧Є╔ш╝╞╙ыPolyTAO║╧╫ў.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/╤╨╛┐╣д╫ў╨б╜с.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/╥й╬я╖в╧╓╓╨╡─╖╓╫╙╔ш╝╞╔ю╢╚╔·│╔─г╨═╡─╫█╩Ў.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/╦о─¤╜║╗п╤з┤л╕╨.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/╦о─¤╜║╨▐╕┤╣╟╚▒╦Ё.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/╧╚╜°╛█║╧╬я▓─┴╧╡─╗·╞ў╤з╧░╕и╓·╔ш╝╞.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/╩¤╛▌╟¤╢п▓─┴╧╤╨╖в╣ж─▄╨╘═┐┴╧.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/▓у▓у╫╘╫щ╫░ Science ╓╨╬─.json +string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +JSON parse error: Expecting value: line 1 column 1 (char 0) +select_best_question Unexpected error: string indices must be integers, not 'str' +Error processing file: /home/ubuntu/50T/fsy/wl/task1-paper-info/▓у▓у╫╘╫щ╫░ Science.json +string indices must be integers, not 'str' diff --git a/code/make_qa_prompts_bp.py b/code/make_qa_prompts_bp.py new file mode 100644 index 0000000..07acbef --- /dev/null +++ b/code/make_qa_prompts_bp.py @@ -0,0 +1,356 @@ +# QUESTION_RPOMPT = """ +# +# {CONTEXT} +# + + +# FUNC_GROUPS_QUESTION_RPOMPT = """ +# 你是一个材料科学领域的资深教授,你的主要研究领域是亲水性聚合物的制备。 +# 现在你在给我上课,你知道与亲水性聚合物相关的亲水性单体的结构以及其官能团的相关信息如下(用标签标记): +# +# {CONTEXT} +# + +# 你的任务是,根据你已知的亲水性聚合物知识和标记的与亲水性聚合物相关的亲水性单体及其官能团信息设计问题向我提问,以此来考察我对亲水性单体的结构及其对应的官能团相关知识的掌握程度。 +# 你的问题主要考察我以下几个方面的能力: +# 1. 知道与亲水性聚合物相关的单体的结构及其相关的官能团。 +# 2. 根据不同条件、不同要求推荐合适的单体和官能团来实现聚合物的亲水性。 +# 3. 给出正确的合理的官能团以提升聚合物亲水性的作用机制。 + + +# # Output Format +# Generate exactly 3 questions/instructions in the following JSON format: +# ```json +# { +# "questions": [ +# { +# "id": 1, +# "text": "First question/instruction text" +# }, +# { +# "id": 2, +# "text": "Second question/instruction text" +# }, +# { +# "id": 3, +# "text": "Third question/instruction text" +# } +# ] +# } +# ``` + +# 在问题中避免提及我给你提供了信息,只需要提出问题,不需要回答问题。 +# """ + + +FUNC_GROUPS_QUESTION_RPOMPT = """ +You are a senior professor in the field of materials science, with your primary research area focusing on the synthesis of hydrophilic polymers. +Currently, you are lecturing to me on this topic. You know the structural information and functional groups of hydrophilic monomers related to hydrophilic polymers as follows (marked with tags): + +{CONTEXT} + + +Your task is to design questions based on your knowledge of hydrophilic polymers and the hydrophilic monomers and their functional group information marked with , in order to assess my understanding of the structure of hydrophilic monomers and their corresponding functional groups. Your questions should primarily test my abilities in the following areas: +1. Know the structure of monomers related to hydrophilic polymers and their associated functional groups. +2. Recommend suitable monomers and functional groups to achieve polymer hydrophilicity based on different conditions and requirements. +3. Capability to provide correct and reasonable explanations for the mechanisms by which functional groups enhance the hydrophilicity of polymers. + +# Output Format +Generate exactly 3 questions/instructions in the following JSON format: +```json +{ + "questions": [ + { + "id": 1, + "text": "First question/instruction text" + }, + { + "id": 2, + "text": "Second question/instruction text" + }, + { + "id": 3, + "text": "Third question/instruction text" + } + ] +} +``` +Ensure that the questions do not reference any information provided by me; they should only pose questions without providing answers. +""" + + +SELECT_QUESTION_PROMPT = """ +Given the most unique answer, evaluate the following **questions ** and decide which one best matches the answer. The higher the match between the question and the answer, the higher the score. Please rate each question and answer pairing on a scale from **1 to 5**, with 1 being the worst match and 5 being the best match. Then, give a brief reason why the question best matches the answer. + +### # ** Rating Criteria ** : +- **5** : Perfect match - The question is exactly the same as the answer, covering all the key information for the answer. +- **4** : High match - The question and answer are mostly consistent, and basically cover the core content of the answer. +- **3** : Medium match - The question partially agrees with the answer, but does not match exactly, or the answer does not fully cover the requirements of the question. +- **2** : Low match - There is a gap between the question and the answer, and more details may be needed to match. +- **1** : Very low match - the question has little to do with the answer, or the answer does not match the question at all. + +### Note that you should also include in your evaluation criteria whether the question is asked about the recommended functional group. If so, the score should be higher, if not, the score should be lower. + +### ** Inputs: ** +1. ** unique answer **: +{ANSWER} +2. **questions **: +{QUESTIONS} + +### ** Output format: ** +- Score how well each question matches the answer in the following JSON format: +```json +{ + "questions": [ + { + "id": 1, + "score": xxxx, + }, + { + "id": 2, + "score": xxxx, + }, + { + "id": 3, + "score": xxxx, + }, + ... + ] +} +``` +""" + + +# FUNC_GROUPS_ANSWER_PROMPT = """ +# 你是一个材料科学领域的资深教授,你的主要研究领域是亲水性聚合物的制备。 +# 现在你在给我上课,你知道亲水性聚合物的单体结构以及其官能团的相关信息如下(用标签标记): +# +# {func_groups_info} +# + +# 介于你出色的知识和丰富的实践经验,你是整个学院最为专业的教授。 +# 你总能在课堂上科学、正确、逻辑严密地回答学生提出的关于如何亲水性聚合物的单体结构以及其亲水性相关的官能团的问题。 +# 同时你在回答问题时还倾向于满足以下要求使得你的学生能够更好的掌握相关知识并在实验室进行成功的实践: +# 1. 分析问题并总结问题要点。 +# 2. 推荐合适的官能团,同时给出详细科学的官能团提升水的相互作用的作用机制。 +# 3. 你在推荐官能团的时候习惯以类似(Phosphino Groups (-PR2))的结构进行推荐并详细说明。 +# 4. 你还习惯在回答的最后给出表格形式的官能团推荐总结,通过多维度对比的方式提升我对不同官能团的理解。 + +# 现在,请你根据以上要求回答我的问题。我的问题是: +# {QUESTION} + +# Let's thinking step by step: +# """ + + +# FUNC_GROUPS_ANSWER_PROMPT = """ +# 你是一个材料科学领域的资深教授,你的主要研究领域是黑磷稳定性以及黑磷表面修饰。 +# 现在你在给我上课,你知道黑磷稳定性的表面修饰可以使用如下官能团(用标签标记)。 +# +# {func_groups_info} +# +# 除了标记中的内容之外,你自己在实验中还总结出了以下知识(用标记)。 +# +# {sup_content} +# + +# 介于你出色的知识和丰富的实践经验,你是整个学院最为专业的教授。 +# 你总能在课堂上科学、正确、逻辑严密的回答学生和我关于利用不同官能图进行黑磷表面修饰以提高黑磷稳定性相关的问题。 +# 同时你在回答问题时还倾向于满足以下要求使得我能够更好的掌握相关知识并在实验室进行成功的实践: +# 1. 分析问题并总结问题要点。 +# 2. 推荐合适的官能团,同时给出详细科学的官能团提升黑磷稳定性的作用机制。 +# 3. 你在推荐官能团的时候习惯以类似(Phosphino Groups (-PR2))的结构进行推荐并详细说明。 + +# 但由于你的个人经验中常用的官能团如下: +# 1. -SiR3 silyl group 硅烷基 +# 2. -PR2 phosphino group 磷基 +# 3. -SH thiol 巯基 +# 4. C=S 碳硫双键 +# 5. -NH2 amine group 胺基 +# 6. C=NH imine group 亚胺基 +# 7. -OH hydroxyl group 羟基 +# 8. C=O carbonyl group 羰基 +# 因此你在回答问题的时候总是倾向于将这些内容跟放在靠前面的位置,并对他们进行额外的说明(包括你的个人的专业的实践经验)。 +# 中的内容是你在实验中总结出来的,体现了你对黑磷表面修饰的理解,因此从中获取的官能团应该放在最前面。 +# 你还习惯在回答的最后给出表格形式的官能团推荐总结,通过多维度对比的方式提升我对不同官能团的理解。 + +# ### 注意,所有推荐的官能团一起给出即可,无需按照来源分类。但是可以将官能团与化学修饰物分类开,方便我学习理解。 +# 现在,请你根据以上要求回答我的问题。我的问题是: +# {QUESTION} + +# Let's thinking step by step: +# """ + + +# FUNC_GROUPS_ANSWER_PROMPT = """ +# ```python +# You are a senior professor in the field of materials science, with a primary research focus on the stability of black phosphorus and surface modification of black phosphorus. +# Right now, you are teaching me, and you know that surface modifications for enhancing the stability of black phosphorus can utilize the following functional groups (marked with tags). +# +# {func_groups_info} +# +# In addition to the content marked with , you have also summarized the following knowledge from your experiments (marked with tags). +# +# {sup_content} +# +# Given your outstanding knowledge and rich practical experience, you are the most professional professor in the entire college. +# You are always able to answer questions from students and me about using different functional groups for surface modification of black phosphorus to enhance its stability in a scientific, correct, and logically rigorous manner during class. +# At the same time, when answering questions, you tend to meet the following requirements so that I can better grasp the related knowledge and achieve successful practice in the laboratory: +# 1. Analyze the problem and summarize the key points. +# 2. Recommend suitable functional groups while providing a detailed scientific explanation of the mechanisms by which these functional groups enhance the stability of black phosphorus. +# 3. When recommending functional groups, you typically use a structure similar to (Phosphino Groups (-PR2)) and provide a detailed explanation. +# However, due to your personal experience, the commonly used functional groups are as follows: +# 1. -SiR3 silyl group +# 2. -PR2 phosphino group +# 3. -SH thiol +# 4. C=S carbon-sulfur double bond +# 5. -NH2 amine group +# 6. C=NH imine group +# 7. -OH hydroxyl group +# 8. C=O carbonyl group +# Therefore, when answering questions, you always tend to place these components towards the front and provide additional explanations (including your personal professional practical experiences). +# The content in reflects your understanding of the surface modification of black phosphorus and should therefore have the functional groups derived from it placed at the forefront. +# You also have a habit of providing a tabular summary of the recommended functional groups at the end of your answers to enhance my understanding of different functional groups through multi-dimensional comparisons. +# ### Note that all recommended functional groups should be presented together without categorization by source. However, you can categorize functional groups and chemical modifiers separately for ease of learning and understanding. +# Now, please answer my question based on the above requirements. My question is: +# {QUESTION} +# Let's think step by step: +# ``` +# """ + + +FUNC_GROUPS_ANSWER_PROMPT = """ +You are a seasoned professor in the field of materials science, with a primary research focus on the preparation of hydrophilic polymers. +Currently, you are lecturing to me, and you know the monomer structures of hydrophilic polymers and the relevant information about their functional groups as follows (marked with tags): + +{func_groups_info} + + +Given your outstanding knowledge and extensive practical experience, you are the most specialized professor in the entire college. +You always provide scientific, accurate, and logically rigorous answers to questions from students and me about the monomer structures of hydrophilic polymers and the hydrophilicity-related functional groups. +Additionally, when answering questions, you tend to meet the following requirements to help me better understand the relevant knowledge and successfully practice it in the laboratory: +1. Analyze the question and summarize the key points. +2. Recommend suitable functional groups while providing a detailed and scientific explanation of how these groups enhance water interactions. +3. When recommending functional groups, you habitually use a format like (Phosphino Groups (-PR2)) and provide detailed explanations. +4. You also habitually conclude your answers with a tabular summary of recommended functional groups, using multidimensional comparisons to deepen my understanding of the different functional groups. + +Now, please answer my question according to the above requirements. My question is: +{QUESTION} + +Let's thinking step by step: +""" + + +# PROTOCOL_QUESTION_RPOMPT = """ +# 你是一个材料科学领域的资深教授,你的主要研究领域是亲水性聚合物的制备。 +# 现在你正在考察你的学生,你的学生需要根据你提供的分子设计一个亲水性聚合物的实验制备方案,从而提升聚合物的亲水性。你这里正好有某种分子用于亲水性聚合物的实验制备方案,制备方案(用标签标记)如下: +# +# {CONTEXT} +# + +# 你的任务是根据你已知的亲水性聚合物知识和标记中的实验制备方案设计问题向你的学生提问,你提出的问题的核心是如何利用某种分子(来自于)进行亲水性聚合物的实验,以此来考察他们是否知道如何进行制备亲水性聚合物以及掌握程度。 + +# 你提出的问题需要注意以下要求: +# 1. 问题应该仅仅围绕实验制备方案,而且这次实验的目的是为了提高聚合物的亲水性。从而让你的学生可以更好地理解你的问题。 +# 2. 你需要从中提取出具体的某种分子,并在问题中指出这种分子,从而让你的学生不会盲目地解答你的问题。 +# 3. 你的学生并不知道的存在,因此你的问题中除了具体分子以外,不应提及的其他内容。 + +# # Output Format +# Generate exactly 3 questions/instructions in the following JSON format: +# ```json +# { +# "questions": [ +# { +# "id": 1, +# "text": "First question/instruction text" +# }, +# { +# "id": 2, +# "text": "Second question/instruction text" +# }, +# { +# "id": 3, +# "text": "Third question/instruction text" +# } +# ] +# } +# ``` +# 在问题中避免提及我给你提供了信息,只需要提出问题,不需要回答问题。 +# """ + + +PROTOCOL_QUESTION_RPOMPT = """ +You are a seasoned professor in the field of materials science, with a primary research focus on the preparation of hydrophilic polymers. +Currently, you are assessing your student, who needs to design an experimental preparation scheme for modifying a polymer using a molecule you have provided, in order to enhance the hydrophilicity of the polymer material. You have an experimental preparation scheme for modifying the polymer using a specific molecule (marked using tags), which is as follows: + +{CONTEXT} + + +Your task is to design questions for your student based on your knowledge of hydrophilic polymer preparation and the experimental preparation scheme marked within the tag. The core of your questions should be about how to utilize a certain molecule (derived from ) in the experiment to prepare a hydrophilic polymer, in order to assess whether the student understands how to carry out the synthesis of hydrophilic polymers and to what extent they have mastered it. + +Your questions should adhere to the following requirements: +1. The questions should solely revolve around the experimental preparation scheme, and the purpose of this experiment is to enhance the hydrophilicity of the polymer, enabling your student to better understand your questions. +2. You need to extract a specific molecule from the and mention this molecule in your question, ensuring that your student does not answer the question blindly. +3. Your student is unaware of the existence of the , therefore, apart from the specific molecule, your question should not refer to any other content from the . + +# Output Format +Generate exactly 3 questions/instructions in the following JSON format: +```json +{ + "questions": [ + { + "id": 1, + "text": "First question/instruction text" + }, + { + "id": 2, + "text": "Second question/instruction text" + }, + { + "id": 3, + "text": "Third question/instruction text" + } + ] +} +``` +Ensure that the questions do not reference any information provided by me; they should only pose questions without providing answers. +""" + + +# PROTOCOL_ANSWER_RPOMPT = """ +# 你是一个材料科学领域的资深教授,你的主要研究领域是亲水性聚合物的制备。 +# 现在你正在解答你的学生提出的问题,你需要根据你的学生提供的分子设计一个亲水性聚合物的实验制备方案,从而提升聚合物的亲水性。你这里正好有你学生说的亲水性聚合物的实验制备方案,制备方案(用标签标记)如下: +# +# {CONTEXT} +# + +# 介于你出色的知识和丰富的实践经验,你是整个学院最为专业的教授。 +# 你总能在课堂上科学、正确、逻辑严密地回答学生提出的关于如何制备亲水性聚合物实验的问题。 +# 同时你在回答问题时还倾向于满足以下要求使得你的学生能够更好的掌握相关知识并在实验室进行成功的实践: +# 1. 分析问题并总结问题要点。 +# 2. 详细、系统地解答这个问题,你的回答不仅要覆盖合成过程的每个步骤,而且需要深入阐述每个步骤的反应条件、试剂配比、摩尔量等细节。这样有助于你的学生更好地在实验室中成功地完成该实验。 + +# 现在,请你根据以上要求回答我的问题。我的问题是: +# {QUESTION} + +# Let's thinking step by step: +# """ + +PROTOCOL_ANSWER_RPOMPT = """ +You are a seasoned professor in the field of materials science, with a primary research focus on the preparation of hydrophilic polymers. +Currently, You are now answering a question posed by your student. Based on the molecule provided by your student, you need to design an experimental preparation scheme for a hydrophilic polymer, in order to enhance the hydrophilicity of the polymer. You happen to have the experimental preparation scheme for the hydrophilic polymer mentioned by your student, marked with tags as follows: + +{CONTEXT} + + +Given your outstanding knowledge and extensive practical experience, you are the most specialized professor in the entire college. +You always provide scientific, accurate, and logically rigorous answers to students' questions regarding the preparation of experiments for hydrophilic polymer synthesis during lectures. +Additionally, when answering questions, you tend to meet the following requirements to help students better grasp the relevant knowledge and successfully practice it in the laboratory: +1. Analyze the question and summarize the key points. +2. Answer this question in detail and systematically, covering every step of the synthesis process while delving into the details of reaction conditions, reagent ratios, molar quantities, etc., for each step. This aids your students in successfully completing the experiment in the lab. + +Now, please answer my question according to the above requirements. My question is: +{QUESTION} + +Let's thinking step by step: +""" \ No newline at end of file diff --git a/code/merge_qa2jsonl.py b/code/merge_qa2jsonl.py new file mode 100644 index 0000000..5f7e606 --- /dev/null +++ b/code/merge_qa2jsonl.py @@ -0,0 +1,71 @@ +# import os +# import json +# import random + +# # 设定目录路径 +# directory_path = '/home/ubuntu/50T/fsy/wl/task1/task1-qa' # 替换为你的目录 +# output_file_1 = '/home/ubuntu/50T/fsy/wl/task1/task1_train_dataset_new.jsonl' # 输出的第一个 jsonl 文件名 +# output_file_2 = '/home/ubuntu/50T/fsy/wl/task1/task1_val_dataset_new.jsonl' # 输出的第二个 jsonl 文件名 + +# # 获取目录下所有 JSON 文件 +# json_files = [f for f in os.listdir(directory_path) if f.endswith('.json')] +# random.shuffle(json_files) # 打乱文件顺序 + +# # 随机选择 30 个文件 +# num_random_files = 30 +# if len(json_files) < num_random_files: +# num_random_files = len(json_files) + +# random_files = json_files[:num_random_files] +# remaining_files = json_files[num_random_files:] + +# # 保存到 jsonl 文件 +# def save_to_jsonl(file_list, output_file): +# with open(output_file, 'w', encoding='utf-8') as f: +# for json_file in file_list: +# with open(os.path.join(directory_path, json_file), 'r', encoding='utf-8') as json_f: +# data = json.load(json_f) +# data_done = {"messages": [{"role": "system", "content": "You are a seasoned professor in the field of materials science, with primary research focusing on the monomer synthesis of hydrophilic polymers."}, {"role": "user", "content": data["design_question"]}, {"role": "assistant", "content": data["design_answer"]}]} +# # data_done = {"system":"You are a seasoned professor in the field of materials science, with primary research focusing on the monomer synthesis of hydrophilic polymers.", "conversation":[{"prompt":data["design_question"],"response":data["design_answer"]}]} +# f.write(json.dumps(data_done) + '\n') + +# # 将文件保存到对应的 jsonl 文件 +# save_to_jsonl(remaining_files, output_file_1) +# save_to_jsonl(random_files, output_file_2) + +# print(f'已将 {len(remaining_files)} 个文件保存到 {output_file_1}') +# print(f'已将 {len(random_files)} 个文件保存到 {output_file_2}') + + +import json +import random + +# 假设这是你的两个输入 JSONL 文件 +input_file_1 = '/home/ubuntu/50T/fsy/wl/task1_val_dataset_new.jsonl' # 第一个 JSONL 文件名 +input_file_2 = '/home/ubuntu/50T/fsy/wl/task2_val_dataset_new.jsonl' # 第二个 JSONL 文件名 +output_file = '/home/ubuntu/50T/fsy/wl/val_dataset.jsonl' # 合并后输出的 JSONL 文件名 + +# 读取 JSONL 文件并存储到列表中 +def read_jsonl(file_name): + data = [] + with open(file_name, 'r', encoding='utf-8') as f: + for line in f: + data.append(json.loads(line)) + return data + +# 读取两个 JSONL 文件 +data1 = read_jsonl(input_file_1) +data2 = read_jsonl(input_file_2) + +# 合并数据 +merged_data = data1 + data2 + +# 随机打乱合并后的数据 +random.shuffle(merged_data) + +# 将打乱后的数据写入新的 JSONL 文件 +with open(output_file, 'w', encoding='utf-8') as f: + for entry in merged_data: + f.write(json.dumps(entry) + '\n') + +print(f'已将 {len(merged_data)} 条记录合并并打乱,保存到 {output_file}') \ No newline at end of file diff --git a/code/task1.log b/code/task1.log new file mode 100644 index 0000000..e9cd353 --- /dev/null +++ b/code/task1.log @@ -0,0 +1,12863 @@ +chunks文件数量: 209 +过滤后chunks文件数量: 209 +{ + "content": "The text discusses phosphonic acid and sulfonic acid as functional groups used in hydrophilic polymers, where phosphonic acid groups enhance hydrophilicity by being amphoteric and exhibiting a high degree of auto-dissociation, leading to a hydrogen-bonding network that enables proton conductivity independent of humidity and temperature." +} +{ + "content": "" +} +{ + "content": "The text does not provide information about the monomer structures or the functional groups that enhance the hydrophilicity of the polymers." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include 2-acrylamido-2-methylpropanesulfonic acid (AMPS), which contains a sulfonic acid functional group that enhances hydrophilicity through strong hydration due to ion-dipole interactions with water molecules, and triethoxyvinylsilane (A151), which contributes hydrophobic characteristics while forming stable covalent bonds with the substrate, thereby improving coating adhesion and interfacial interactions." +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include poly (vinyl alcohol) (PVA), triethoxyvinylsilane, 3-methacryloxypropyltrimethoxysilane, and 2-acrylamide-2-methylpropane sulfonic acid (AMPS), which contain functional groups such as hydroxyl groups in PVA and sulfonic acid groups in AMPS that enhance hydrophilicity by increasing hydrogen bonding and ionic interactions with water molecules." +} +{ + "content": "The hydrophilic polymers synthesized in this study included PVA (polyvinyl alcohol) and AMPS (2-acrylamido-2-methylpropane sulfonic acid), where the hydroxyl groups in PVA and the sulfonic acid groups in AMPS enhance the hydrophilicity of the polymers by increasing their ability to interact with water through hydrogen bonding and ionic interactions, respectively." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The monomers used include 2-acrylamido-2-methyl propane sulfonic acid (AMPS), which has sulfonic acid functional groups that enhance the hydrophilicity of the resulting polymer by promoting hydrogen bonding and ionic interactions with water, thus facilitating increased water absorption and retention.", +} +{ + "content": "" +} +{ + "content": "2-Acrylamido-2-methyl propane sulfonic acid (AMPS) contains sulfonic acid functional groups that enhance hydrophilicity by attracting water molecules through ion-dipole interactions, while the use of ethylene glycol dimethacrylate (EGDMA) contributes additional hydrophilic properties due to its ether groups, which also improve water solubility and interaction.", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include AMPS (2-acrylamido-2-methylpropanesulfonic acid) and MMA (methyl methacrylate), where the sulfonic acid group in AMPS enhances hydrophilicity due to its ability to form hydrogen bonds with water, increasing interactions through strong ionic and dipole-dipole interactions.", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The hydrophilic monomer AMPS contains functional groups that enhance the hydrophilicity of the polymer, which interact with water through hydrogen bonding and ionic interactions, while the presence of hydroxyl groups generated by air plasma treatment further promotes interfacial interactions with TMSMA, another constituent of the polymer.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing the hydrophilic polymers include polyvinyl alcohol (PVA) and sodium alginate (SA), which possess functional groups such as hydroxyl (-OH) in PVA and carboxyl (-COOH) in SA that enhance the hydrophilicity of the resulting polymers by promoting strong hydrogen bonding and ionic interactions with water, facilitating better water retention and spreading." +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "The polymers were synthesized using PVA and SA, which contain hydroxyl (-OH) and carboxylic acid (-COOH) functional groups, respectively; these functional groups enhance hydrophilicity by forming hydrogen bonds with water, thus increasing the water affinity of the resulting polymers." +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include 2-(dimethylamino)ethyl methacrylate (DMAEMA), which contains a dimethylamino functional group that enhances hydrophilicity through increased hydrogen bonding and ionic interactions with water.", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include 2-(dimethylamino)ethyl methacrylate (DMAEMA) and hexafluorobutyl acrylate (HFBA), where the amino (-NH) and carboxylic acid (-COOH) functional groups of DMAEMA enhance hydrophilicity through hydrogen bonding and electrostatic interactions with water, while HFBA contributes to hydrophilicity due to its ability to interact with water molecules.", +} +{ + "content": "The synthesis of hydrophilic polymers involves functional groups such as carboxylic acids from HFBA and amino groups from DMAEMA, which enhance hydrophilicity by enabling strong hydrogen bonding and electrostatic interactions with water molecules.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include poly(vinyl alcohol) (PVA) containing numerous hydroxyl groups (-OH), as well as poly(acrylic acid) (PAA) with carboxylic acid (-COOH) groups, both of which enhance the hydrophilicity of the corresponding polymers by enabling strong hydrogen bonding and increasing affinity for water molecules, thus promoting better intermolecular interactions with water and improving the antifogging properties.", +} +{ + "content": "" +} +{ + "content": "The monomer used for synthesizing hydrophilic polymers is Poly(vinyl alcohol) (PVA), which contains hydroxyl (–OH) functional groups that enhance the hydrophilicity of the polymers by increasing their ability to form hydrogen bonds with water, thereby facilitating better interactions and dispersion in aqueous environments." +} +{ + "content": "The hydrophilic polymers synthesized in the excerpt utilize polyvinyl alcohol (PVA) and silica (SiO2) as the primary monomer components, where the hydroxyl functional groups in PVA enhance hydrophilicity by forming hydrogen bonds with water molecules, thus increasing water interactions." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves using monomers such as polyethylene glycols (PEG), which contain hydroxyl groups that enhance hydrophilicity by forming hydrogen bonds with water, and hydroxyethyl acrylate (HEA), which provides additional hydroxyl groups that also interact favorably with water, facilitating hydration and improving the overall hydrophilic properties of the resulting polymers." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers in the anti-fogging agent composition include sulfonic acid type amphoteric surface active agents and nonionic surface active agents, where the sulfonic acid functional group enhances hydrophilicity by providing ionic interactions with water, leading to improved solubility and adsorption on surfaces, especially when combined with inorganic salts or acetates that exhibit a salting-in phenomenon, dramatically increasing interactions with water." +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers includes monomers such as maleic anhydride and vinyl alcohol, which possess functional groups that enhance hydrophilicity through increased water interaction, as these polar functional groups can form hydrogen bonds with water molecules, thereby improving the polymer's affinity for water." +} +{ + "content": "" +} +{ + "content": "The hydrophilic polymers are synthesized using monomers that contain sulfonic acid functional groups, which enhance hydrophilicity by increasing the polymer's ability to interact with water through charge interactions and hydrogen bonding." +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include polyether polyol and polyalkylene oxide, which contain functional groups that enhance hydrophilicity through water absorption and improved wetting properties, allowing for interaction with water by reducing the contact angle and increasing moisture retention.", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include polyacrylic and polyvinyl alcohol, which possess functional groups that enhance hydrophilicity through their capacity for hydrogen bonding with water molecules, thereby improving water absorption and surface interactions." +} +{ + "content": "The functional groups that enhance the hydrophilicity of the corresponding polymers include hydroxyl groups from hydrolyzed alkoxyl groups and carboxyl, carbonyl, amino, vinyl, and epoxy groups introduced via compounds such as vinyltrichlorosilane and polyacrylic acid; these functional groups enhance interactions with water by forming hydrogen bonds and increasing the overall polarity of the polymer, leading to improved water affinity." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers in the anti-fogging coating material include hydrosilicofluoric acid, epoxy group-containing silane coupling agents such as gamma-glycidoxypropyltrimethoxysilane, and the polyacrylic ester and polyvinyl alcohol, which contain functional groups like hydroxyl groups and sulfonic acid groups that enhance hydrophilicity by forming hydrogen bonds and ionic interactions with water, facilitating moisture adsorption on the polymer surface." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include polyvinyl alcohol with a saponification degree of about 82% and a 20 mol% saponified product of polymethyl acrylate, where the polyvinyl alcohol enhances hydrophilicity through hydroxyl (-OH) functional groups and the saponified polymethyl acrylate contributes hydrophilicity via carboxylic acid (-COOH) groups, both of which enhance interactions with water by forming hydrogen bonds and increasing the affinity for water molecules." +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as polyvinyl alcohol, which contains hydroxyl functional groups that enhance hydrophilicity by forming hydrogen bonds with water, and polyacrylic acid, which possesses carboxylic acid groups that enhance interactions with water through ionization and hydrogen bonding.", +} +{ + "content": "The synthesis of hydrophilic polymers includes the use of monomers such as polymethylacrylate and polyvinyl alcohol, which contain functional groups like hydroxyl (-OH) and carboxyl (-COOH), enhancing hydrophilicity through strong hydrogen bonding and polar interactions with water molecules, thereby increasing water absorption and wettability.", +} +{ + "content": "Hydrophilic polymers are synthesized using monomers such as polyacrylic acid and polyvinyl alcohol, which include functional groups like hydroxyl groups and sulfonic acid groups; these functional groups enhance interactions with water by forming hydrogen bonds and increasing solubility in aqueous environments." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The hydrophilic polymers are synthesized using monomers that include functional groups such as sulfonate groups and hydroxyl groups, which enhance hydrophilicity by increasing water affinity and solubility; for example, the sodium salt of 5-sulfoisophthalic acid improves water interactions through ionic hydration and dipole interactions, while ethylene glycol provides hydrogen bonding capabilities with water.", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The synthesis of hydrophilic polymers involves using sulfomonomers, such as 5-sulfoisophthalic acid, which contain sulfonate groups that enhance hydrophilicity by promoting ionic interactions with water, and copolymerizable glycols with 2 to 11 carbon atoms that contribute to the overall hydrophilic character of the polymer.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The monomer structures used for synthesizing hydrophilic polymers include polyglycerol comprising at least two glycerol units and natural oils which contain triglycerides of aliphatic monocarboxylic acids; functional groups such as hydroxyl groups in polyglycerols and fatty acids enhance the hydrophilicity of the corresponding polymers by forming strong hydrogen bonds with water molecules, thereby increasing water affinity and reducing the surface tension of the polymer.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The water-soluble organic polymer ethyl hydroxyethyl cellulose contains hydroxyl functional groups that enhance hydrophilicity by interacting with water molecules, allowing for reduced fogging and increased transparency.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The hydrophilic polymers synthesized include acrylic monomers, a sulfonic acid group, and functionalities such as hydroxyl (OH), amino (NH2), carboxyl (COOH), ester (COOR), amide (NHCOR), and sulfonic (HSO3) groups, which enhance hydrophilicity through strong and stable binding interactions with water molecules due to electrostatically induced hydration interactions and favorable water droplet spreading." +} +{ + "content": "" +} +{ + "content": "The hydrophilic polymers were synthesized using monomers like hydroxyethyl methacrylate (HEMA) and 2-acrylamide-2-methylpropanesulfonic acid (AMPS), which contain functional groups such as hydroxyl (-OH) and sulfonic acid (-SO3H) that enhance hydrophilicity through strong hydrogen bonding and ionic interactions with water, respectively." +} +{ + "content": "The synthesized monomer, 3-(bis(hydroxymethyl)amino)-2-hydroxypropyl methacrylate (D-GMA), contains functional groups such as hydroxymethyl and amino, which enhance the hydrophilicity of the corresponding polymers by interacting favorably with water molecules through hydrogen bonding and dipolar interactions." +} +{ + "content": "The hydrophilic monomers used for synthesizing hydrophilic polymers include D-GMA, sulfonic acid quaternary ammonium salt (AMPS), and hydroxyethyl methacrylate (HEMA), which possess functional groups such as hydroxy (-OH) from HEMA and sulfonate (-SO3) from AMPS that enhance interactions with water through hydrogen bonding and ionic interactions, respectively." +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves functional groups such as sulfonated resins and non-ionic surfactants containing hydroxyl reactive groups, which enhance the hydrophilicity of the polymers by increasing their water absorption and improving interactions with water, leading to better anti-fog properties.", +} +{ + "content": "The hydrophilic polymers synthesized include polyurethane segments characterized by urethane groups containing carbonyl groups that enhance hydrophilicity, as well as acrylic polymers incorporating functional groups such as carboxylates from acrylic acid and dimethylol propionic acid, which enhance interactions with water through ionic and hydrogen bonding.", +} +{ + "content": "The text excerpt does not provide specific information about the monomer structures or functional groups that enhance the hydrophilicity of the corresponding polymers." +} +{ + "content": "The synthesis of hydrophilic polymers utilizes monomers such as fatty alcohols with hydroxyl groups, including dodecyl alcohol, cetyl alcohol, and oleyl alcohol, which enhance hydrophilicity through their ability to form hydrogen bonds with water, thus increasing solubility and interaction; additionally, polyethoxylated and polypropoxylated fatty alcohols contain multiple ethylene oxide or propylene oxide repeat units, contributing to improved water affinity and minimizing surfactant leaching due to increased hydrophilic segments.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include 2-[Methoxy(polyethyleneoxy)propyl] which contains ether functional groups that enhance hydrophilicity by forming hydrogen bonds with water, and trimethoxysilane which can also interact with water due to its silanol groups.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesis involves PEG-based dicarboxylic acid ammonium salts, which possess functional groups such as carboxylic acids and ammonium that enhance the hydrophilicity of the polymers due to their ability to form hydrogen bonds and ionic interactions with water." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The hydrophilicity of the synthesized polymers is enhanced by the presence of functional groups in the hydrophilic aziridine crosslinkers, which improve interactions with water due to the ability of these groups to form hydrogen bonds with water molecules." +} +{ + "content": "The synthesis involved monomers such as PEG-modified DVSZN004, which contains ether functional groups that enhance hydrophilicity by increasing hydrogen bonding capacity with water molecules, thereby improving water interactions and promoting wettability." +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The hydrophilic polymers are synthesized using monomers such as poly(ethylene glycol) which contains hydroxyl functional groups that enhance the hydrophilicity of the resulting polymers, facilitating strong interactions with water through hydrogen bonding.", +} +{ + "content": "", +} +{ + "content": "PZ-2382 includes functional groups that enhance the hydrophilicity of the polymers, while PEG-based modified DVSZN004 provides additional hydrophilic properties due to its ethylene glycol units, which facilitate interactions with water through hydrogen bonding.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesis involved PEG-based modified DVSZN004, which contains functional groups such as hydroxyl groups that enhance the hydrophilicity of the corresponding polymers by forming strong hydrogen bonds with water molecules, leading to improved water interaction.", +} +{ + "content": "" +} +{ + "content": "The synthesis involves monomers such as PEG-based modified DVSZN004, which contains ether functional groups that enhance hydrophilicity through their ability to form hydrogen bonds with water, leading to improved interactions and solubility in aqueous environments." +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include PEG-modified DVSZN004, which contains polyethylene glycol (PEG) as a functional group that enhances hydrophilicity, and water, which enhances interactions with water due to its polar nature and ability to form hydrogen bonds." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The synthesis of hydrophilic polymers involved the use of PZ-2382, which contains hydrophilic aziridine crosslinkers, enhancing hydrophilicity due to their ability to form hydrogen bonds with water molecules, thereby increasing interactions with water and improving the overall performance of the coated films.", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as diols or diamines reacted with di-carboxylic acid esters, which upon sulfonation or quaternization enhance hydrophilicity; these functional groups increase interactions with water by incorporating hydrophilic characteristics directly into the polymer backbone, rather than as pendant groups, allowing for better water absorption and reducing interfacial tension." +} +{ + "content": "The monomers used in synthesizing hydrophilic polymers include acrylic acid and methacrylic acid, which contain carboxylic acid functional groups that enhance hydrophilicity by allowing for hydrogen bonding with water molecules.", +} +{ + "content": "Monomers used for synthesizing hydrophilic polymers include diols such as ethylene glycol and neopentyl glycol, which possess hydroxyl functional groups that enhance hydrophilicity by forming hydrogen bonds with water, and carboxylic acids like dimethylol propionic acid (DMPA), which contains carboxylate ions that provide ionic character, stabilize aqueous dispersions, and act as internal emulsifiers.", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include hydrophilic additives with functional groups such as acid or salt of a polyalkylene oxide, which enhance hydrophilicity through the presence of ethylene oxide and propylene oxide repeat units that facilitate interactions with water through hydrogen bonding and increased solubility.", +} +{ + "content": "" +} +{ + "content": "Functional groups such as ethoxy groups in ethoxylated trimethylpropane triacrylate and the hydroxyl groups in poly(ethylene glycol) monomethacrylate enhance the hydrophilicity of polymers by increasing their ability to form hydrogen bonds with water, thus improving interactions with water." +} +{ + "content": "The text excerpt does not provide specific monomer structures or detailed information about functional groups that enhance the hydrophilicity of the corresponding polymers." +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as polyethylene glycol (PEG), which possesses hydroxyl (-OH) functional groups that enhance hydrophilicity by forming hydrogen bonds with water, thereby improving interactions with aqueous environments." +} +{ + "content": "The synthesis of hydrophilic polymers involved the use of monomers such as tri-functional aziridine crosslinkers and PEG-based diacid, which contain functional groups such as carboxylic acid and amine groups, enhancing hydrophilicity through their ability to form hydrogen bonds with water molecules.", +} +{ + "content": "", +} +{ + "content": "The synthesis involved monomers such as 900-DA and PZ-2382, which contain functional groups that enhance hydrophilicity through increased hydrogen bonding and dipole interactions with water." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The hydrophilic polymers were synthesized using monomers such as aziridine (PZ-2382 and PZ-502) which possess functional groups that enhance hydrophilicity through their ability to form hydrogen bonds with water, thus increasing interactions with water and contributing to the excellent anti-fog performance of the coatings." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The monomer structures used for synthesizing hydrophilic polymers include polyalkylene oxide backbones terminating with acid or salt groups, which enhance hydrophilicity through the presence of carboxylate functional groups that strongly interact with water due to their ability to form hydrogen bonds and ionic interactions." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "The hydrophilic polymer of the anti-fog layer can include polyvinyl alcohol, polyvinyl acetal, polyvinyl acetate, polyvinylpyrrolidone, polyethylene oxide, polyacrylamide, polyester, polyurethane, cellulose acetate, hydroxyethyl cellulose, hydroxymethyl cellulose, or gelatin, with hydrophilic segments such as alkylene oxides, lactones, lactams, or combinations thereof, and these functional groups enhance interactions with water through hydrogen bonding, promoting solubility and increased water affinity." +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The hydrophilic polymer comprises a polymer having a polyurethane backbone and hydrophilic segments covalently bonded to the polyurethane backbone, with the hydrophilic segments including alkylene oxides, lactones, lactams, and combinations thereof, enhancing interactions with water through their polar functional groups, which promote hydrogen bonding and water solubility." +} +{ + "content": "The hydrophilic polymer in the transparent composite comprises a polyurethane backbone with hydrophilic segments that include alkylene oxides, lactones, lactams, or combinations thereof, which enhance interactions with water through the presence of polar functional groups capable of forming hydrogen bonds.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The hydrophilic polymer network is composed of poly(vinyl alcohol) (PVA), which contains hydroxyl functional groups that enhance hydrophilicity through hydrogen bonding with water molecules, thereby promoting water absorption and preventing fog formation." +} +{ + "content": "The hydrophilic polymer is synthesized using PVA, which contains abundant hydrophilic hydroxyl groups that facilitate the quick spreading and sucking of condensed water, enhancing its interactions with water through hydrogen bonding.", +} +{ + "content": "The extracted text does not provide specific information regarding the monomer structures or the functional groups that enhance the hydrophilicity of the corresponding polymers." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "The functional groups of -CH2 and -CH3 in the PDMS surface not only enhance hydrophobicity dramatically but also decrease water adhesion performance." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The monomer structures used for synthesizing hydrophilic polymers include vinyl monomers with N-hydroxymethyl or N-alkoxy hydroxymethyl (monomer A1), vinyl monomers with sulfonic acid groups (monomer A2), and alkyl (meth)acrylate monomers (monomer A3), where the functional groups such as N-hydroxymethyl and sulfonic acid groups enhance hydrophilicity by increasing water interactions through hydrogen bonding and ionic interactions, respectively." +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "The hydrophilic polymer part of the block copolymer or graft copolymer is formed from monomers that possess hydroxymethyl, N-hydroxymethyl ether, or hydroxyl functional groups, which enhance hydrophilicity through the ability to form hydrogen bonds with water, thereby improving water interaction and adhesion properties." +} +{ + "content": "The hydrophilic polymers are synthesized using monomers such as N-hydroxymethyl or N-alkoxymethyl vinyl monomers (monomer A1) which contain functional groups that facilitate crosslinking and enhance hydrophilicity, sulfonic acid group-containing vinyl monomers (monomer A2) that improve the hydrophilicity of the copolymer and suppress fogging phenomena by having both neutralized and unneutralized sulfonic groups, and alkyl acrylate monomers (monomer A3) that contribute to adhesion and heat resistance, with the alkaline compound used in the formulation neutralizing some of the sulfonic groups in monomer A2 to increase the overall hydrophilicity; these functional groups enhance interactions with water by providing increased polar character and enabling hydrogen bonding with water molecules, which is vital for improving the copolymer's adhesion and resistance to fogging phenomena in high humidity environments." +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers with functional groups such as carboxylic acid esters, which enhance hydrophilicity by providing polar interactions with water, thus increasing the polymer's affinity for water.", +} +{ + "content": "", +} +{ + "content": "The text describes the use of polyether polyols containing sulfonic functional groups, which enhance the hydrophilicity of polyurethane polymers by allowing the sulfonic groups to react into the polyurethane main chain, thus improving water interactions without providing a clear separation between hydrophilic and hydrophobic segments, ultimately enhancing the water absorption and maintaining antifog properties.", +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers with functional groups such as hydroxyl (-OH) and carboxyl (-COOH) that enhance hydrophilicity; these groups increase interactions with water through hydrogen bonding, thus resulting in improved water absorption and stability of the resulting polymers." +} +{ + "content": "The information provided does not include specific details about the functional groups in the monomers used for synthesizing hydrophilic polymers or explanations of how these functional groups enhance interactions with water." +} +{ + "content": "The hydrophilic polymers were synthesized using monomers such as 2-[甲氧基(聚氧乙烯)丙基]三甲氧基硅烷, PEG单甲醚, and ammonia salts based on PEG, with functional groups like hydroxyl (-OH), ether (-O-), and amine (-NH) that enhance hydrophilicity by increasing the polymer's ability to interact with water through hydrogen bonding and dipole-dipole interactions." +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include N,N-dimethylaminoethyl methacrylate, which contains dimethylamino groups that enhance hydrophilicity through strong hydrogen bonding with water, and 1,3-propyl sulfonic acid lactone, which improves water interaction via its sulfonic acid group that increases ionic interactions with water molecules." +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The hydrophilic polymers synthesized from monomers such as acrylamide (AM), 2-acrylamido-2-methylpropane sulfonic acid (AMPS), and dimethyl diallyl ammonium chloride (DMDAAC) contain functional groups like sulfonic acid and ammonium groups that enhance hydrophilicity by promoting strong interactions with water through hydration and ionization, which increases their water retention and resistance to salt and temperature variations." +} +{ + "content": "The hydrophilic polymers synthesized in the method comprise methacryloxyethyl-N,N-dimethylpropanesulfonate and 4-vinylpyridine with functional groups such as sulfonate and quaternary ammonium, which enhance hydrophilicity through increased ionic interactions and hydrogen bonding with water." +} +{ + "content": "The synthesized hydrophilic polymers include methyl methacrylate-derived DMAPS (dimethylaminopropyl sulfonate) which features functional groups such as sulfonate that enhance hydrophilicity through strong ionic interactions with water, and VPPS (vinylpyridine propanesulfonate) which contains pyridinium and sulfonate groups that improve water affinity by facilitating hydrogen bonding with water molecules." +} +{ + "content": "The copolymer (A) is composed of monomers (A-1), (A-2), and (A-3), where (A-1) enhances hydrophilicity through hydroxyl (OH) functional groups, as the NCO/OH ratio in the multifunctional isocyanate compound (B) is maintained between 0.1 and 1.5, and these hydroxyl groups interact with water via hydrogen bonding.", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "The monomer structures used for synthesizing hydrophilic polymers include a water-soluble vinyl-type monomer (monomer A) and a vinyl-type monomer with hydroxyl groups (monomer C), where the hydroxyl groups enhance hydrophilicity by promoting hydrogen bonding with water, thereby increasing water interactions." +} +{ + "content": "Monomer structures used for synthesizing hydrophilic polymers include N,N-dimethylacryl amide (A-1), butyl acrylate (A-2), and 2-hydroxyethyl acrylate (A-3), with functional groups such as hydroxyl groups (-OH) from A-3 enhancing hydrophilicity by allowing stronger hydrogen bonding with water molecules, thereby increasing interaction and affinity for water." +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "活性功能型硅倍半氧烷中含有乙烯基、烯丙基、(甲基)丙烯酸酯基、氨基、环氧基、脂环族环氧基和羧基等功能基团,这些功能基团通过提供化学和生物活性位点,增强聚合物与水的相互作用,从而提高材料的亲水性。", +} +{ + "content": "The monomers used for synthesizing the hydrophilic polymers include siloxane-polyurethane, which contains hydroxyl (OH) groups and hydrolysable functional groups, all enhancing hydrophilicity by forming hydrogen bonds and facilitating interactions with water." +} +{ + "content": "The hydrophilic polymers synthesized in the process include functional groups such as hydroxyl (-OH) groups from hydroxyethyl acrylate (HEA) and silanol (Si-OH) groups from silsesquioxane, which enhance hydrophilicity by forming hydrogen bonds with water molecules, thus improving interaction and affinity with water." +} +{ + "content": "The mentioned hydrophilic polymer, methyl acrylate oxypropyl trimethoxysilane (MAPTMS), enhances its hydrophilicity through hydroxyl (-OH) and methoxy (-OCH3) functional groups, which increase interactions with water by forming hydrogen bonds and improving water absorption, allowing for better water solubility and compatibility in the final produced polymers." +} +{ + "content": "The hydrophilic polymers are synthesized using monomers that contain functional groups such as hydroxyl, amino, and epoxy groups, which enhance hydrophilicity by establishing strong hydrogen bonds with water molecules, facilitating greater water retention and interaction." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as methacrylic acid or methacrylic acid/styrene copolymers that contain carboxyl groups which enhance hydrophilicity by increasing the surface tension of the coating, thereby promoting water spreading on the surface, while organic binders that include epoxy, amine, and hydroxyl groups also contribute to improved interactions with water through crosslinking with carboxyl groups to enhance the hardness and adhesion of the coating.", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include 1,4-dioxane, which contributes to hydrophilicity due to its ether functional groups that enhance interactions with water, and sulfonic acid groups in the polyacrylic acid which increase hydrogen bonding capabilities with water molecules.", +} +{ + "content": "", +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as hydrophilic acrylic resins, which contain functional groups like hydroxyl groups from polyoxyethylene fatty alcohols, enhancing hydrophilicity by forming hydrogen bonds with water molecules, thus promoting water interaction.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The text discusses the introduction of functional groups that enhance hydrophilicity in polymers, specifically hydrogen-bond-forming groups such as carboxyl, amino, thiol, and hydroxyl groups, as well as ionic groups like carboxylate, sulfonate, ammonium, and phosphate, which improve water interactions by allowing water vapor to condensate and spread uniformly across the material surface, forming a homogeneous water film that mitigates light scattering and fogging effects." +} +{ + "content": "The synthesized hydrophilic polymers utilize monomers such as acrylic esters, specifically containing hydroxyl groups like hydroxyethyl methacrylate (HEMA) and hydroxyethyl acrylate (HEA), along with hydrophilic alkyl polyethylene ether (AEO) to enhance hydrophilicity, where the hydroxyl groups contribute to improved water interactions through hydrogen bonding and increased surface energy, allowing water to spread easily on the polymer surface and preventing fogging." +} +{ + "content": "Monomers used for synthesizing hydrophilic polymers include hydroxyethyl acrylate (HEA) and hydroxyethyl methacrylate (HEMA), which contain hydroxyl functional groups that enhance hydrophilicity by providing strong hydrogen bonding interactions with water molecules, resulting in improved water affinity and solubility." +} +{ + "content": "" +} +{ + "content": "The hydrophilic polymers are synthesized using monomers such as acrylate compounds which include functional groups like hydroxyl (-OH) from hydroxyethyl acrylate, and carboxyl (-COOH) from acrylic acid, enhancing hydrophilicity through hydrogen bonding and allowing increased interactions with water.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include light curing hydrophilic resins, light curing hydrophilic small molecules, and light curing hydrophilic salts such as PEG diacrylate (PEG400DA, PEG600DA, PEG1000DA), acrylic acid, hydroxyethyl acrylate, and ammonium salts like DNS-86 and 2-acrylamido-2-methylpropanesulfonic acid (AMPS), which enhance the polymers' hydrophilicity through the presence of hydroxyl and ionic functional groups that promote hydrogen bonding and electrostatic interactions with water." +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers with functional groups such as hydroxyl groups from PEG400DA, PEG600DA, and PEG1000DA, as well as the carboxyl groups in acrylic acid and hydroxyethyl acrylate, which enhance the polymers' hydrophilicity by increasing their ability to form hydrogen bonds and interact with water molecules." +} +{ + "content": "", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include hydroxyl-containing acrylate monomers such as hydroxyethyl methacrylate (HEMA), hydroxyethyl acrylate (HEA), hydroxypropyl acrylate (HPA), and 4-hydroxybutyl acrylate (4HBA), where the hydroxyl (-OH) functional groups enhance hydrophilicity by forming hydrogen bonds with water, thus increasing interactions with water." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves the use of functional groups such as sulfonic acid groups in sulfonic acid-containing hydrophilic monomers (AMPS) which enhance the hydrophilicity of the polymers by increasing their interaction with water through polar interactions and hydrogen bonding capabilities.", +} +{ + "content": "The synthesis of hydrophilic polymers utilizes monomers with hydroxyl groups (-OH) from hydroxyacrylate monomers, which enhance hydrophilicity by increasing hydrogen bonding interactions with water, and these functional groups also improve the interactions with water by facilitating water absorption and providing a water-attracting environment within the polymer structure." +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as diethanolamine and polyethylene glycol monoether, which contain functional groups like hydroxyl groups (-OH) that enhance hydrophilicity by forming hydrogen bonds with water, increasing water absorption and interaction.", +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as methyl methacrylate (MMA), acrylic acid (AA), styrene (St), and hydroxyethyl acrylate (HEA), where the presence of functional groups like hydroxyl (-OH) groups in HEA enhances hydrophilicity by promoting hydrogen bonding with water, thus improving water interactions and solubility.", +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "The synthesis of hydrophilic polymers involves using monomers with functional groups such as esters and ethers that enhance hydrophilicity by promoting wettability and allowing water to spread across their surfaces, thereby improving the interaction with water." +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as methyl methacrylate (MMA), acrylic acid (AA), styrene (St), and hydroxyethyl acrylate (HEA), which contain functional groups like -COOH and -OH that enhance hydrophilicity by increasing hydrogen bonding and dipole-dipole interactions with water." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include hydroxyethyl methacrylate and glycidyl methacrylate, which feature hydroxyl (-OH) and ether (-O-) functional groups that enhance hydrophilicity through their ability to form hydrogen bonds with water, resulting in improved interactions and water absorption." +} +{ + "content": "The synthesis of hydrophilic polymers utilizes monomers such as acrylic acid or its derivatives and acrylamide, which incorporate functional groups like carboxylic acids and amides that enhance hydrophilicity through strong hydrogen bonding and polar interactions with water molecules." +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves using monomers such as acrylic acid (AA), methacrylic acid (MAA), and acrylamide (AM), whose carboxyl and amino functional groups enhance hydrophilicity by increasing hydrogen bonding and ionic interactions with water, thus improving compatibility with hydrophilic resins." +} +{ + "content": "The text excerpts describe the use of functional groups such as acrylic acid and acrylamide in the synthesis of hydrophilic polymers, where the carboxylic acid group (-COOH) in acrylic acid and the amide group (-CONH2) in acrylamide enhance the hydrophilicity of the corresponding polymers due to their ability to form hydrogen bonds with water molecules, facilitating increased water interaction and absorption." +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The hydrophilic polymers are synthesized using various monomers, including A1 (N-vinyl-2-pyrrolidone), which acts as a primary hydrophilic monomer; A2, a vinyl monomer with hydroxy functional groups that enhance hydrophilicity; A4, another vinyl monomer with hydrophilic functional groups that effectively improve the hydrophilicity of the copolymer; and A5, a vinyl monomer with sulfonic acid groups that react with a basic compound to form salts, contributing to enhanced water interactions due to the presence of ionic species and hydroxyl groups that establish hydrogen bonds with water, thereby improving the overall affinity of the polymer for water." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The hydrophilic polymers are synthesized from monomers including N-vinyl-2-pyrrolidone, vinyl monomers with hydroxyl functional groups, vinyl monomers with sulfonic acid groups, and vinyl monomers with other hydrophilic functional groups, wherein the hydroxyl and sulfonic acid groups enhance hydrophilicity through their ability to form hydrogen bonds and react with water, promoting better interactions and improving water absorption and retention in the polymer matrix." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers in the study include N-vinyl-2-pyrrolidone (NVP), hydroxyethyl acrylate (HEA), methyl methacrylate (MMA), N,N-dimethylacrylamide (DMAA), and 2-acrylamido-2-methylpropane sulfonic acid (AMPS), with functional groups such as hydroxyl groups in HEA and sulfonic groups in AMPS enhancing hydrophilicity by forming hydrogen bonds with water, thereby increasing water affinity and interaction.", +} +{ + "content": "The hydrophilic polymers are synthesized using hydroxyl acrylate monomers which contain hydroxyl functional groups that enhance hydrophilicity by forming hydrogen bonds with water, improving hydration and interaction with aqueous environments." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The hydrophilic polymers used in anti-fog coatings contain hydrophilic functional groups that enhance water interactions, as these groups facilitate better absorption and adhesion of water molecules, thereby improving the durability and effectiveness of the anti-fog properties." +} +{ + "content": "The synthesis of hydrophilic polymers includes monomers with functional groups such as hydroxyl (-OH) groups and hydrophilic chain segments, which enhance hydrophilicity and improve interactions with water by forming hydrogen bonds and increasing the availability of polar sites for water interaction." +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as polyethyleneglycol (PEG) which features hydroxyl groups (-OH) that enhance the hydrophilicity of the polymer, leading to improved interactions with water through hydrogen bonding, as well as acrylic monomers that contain ester groups which also contribute to the water affinity due to their polar nature." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The hydrophilic polymer is synthesized using a photopolymerizable monomer with a backbone structure of ethoxylated trimethylolpropane triacrylate containing 10 to 15 ethylene glycol units, which have functional groups that enhance hydrophilicity through their interactions with water due to their ability to form hydrogen bonds and increase solubility in aqueous environments." +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as ethoxylated trimethylolpropane triacrylate, which contains functional groups like ether and ester linkages that enhance the hydrophilicity of the corresponding polymers, promoting interactions with water through increased wettability and penetration ability due to the presence of polyethylene glycol segments in the polymer chains." +} +{ + "content": "The hydrophilic polymers are synthesized using monomers such as hydroxyl ethyl acrylate (HEA) and polyether amine (ED2003), which contain functional groups like hydroxyl (-OH) that enhance hydrophilicity by forming hydrogen bonds with water molecules, thereby increasing the interaction with water.", +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as tri(hydroxymethyl)propane, epoxy propane, acrylic acid, and hydroxyl ethyl acrylate, wherein functional groups like hydroxyl (-OH) and carboxyl (-COOH) enhance hydrophilicity by increasing the ability of the polymers to interact with water molecules through hydrogen bonding and ionic interactions." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include PEG (EO)n, bisphenol A(EO)n diacrylate, trimethylolpropane(EO)n triacrylate, acrylic manner, and N,N-dimethylacrylamide, with the functional groups enhancing hydrophilicity primarily being the long polyethylene glycol (EO) chain segments, which increase interactions with water through hydrogen bonding and improved wettability.", +} +{ + "content": "The hydrophilic polymers synthesized in this invention utilize functional groups such as sulfonate and acrylate esters, which enhance hydrophilicity through ionic interactions and hydrogen bonding with water molecules, respectively." +} +{ + "content": "The synthesis of hydrophilic polymers utilizes monomers such as 2-acrylamide-2-methylpropane sulfonic acid (AMPS) and N,N-dimethylacrylamide, which contain functional groups like sulfonic acid and amide that enhance the hydrophilicity of the polymers by enabling strong hydrogen bonding and ionic interactions with water, thus increasing the water affinity of the resulting polymer matrix." +} +{ + "content": "The synthesized hydrophilic polymer includes monomer structures such as diisocyanates and hydroxyl-functionalized oxazolidinones, where the hydroxyl (-OH) functional groups enhance hydrophilicity by forming strong hydrogen bonds with water, thus improving water interactions.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The hydrophilic polymer is synthesized using a fully hydrophilic main chain from a binary polyether amine and polyethylene glycol diacrylate, incorporating functional groups such as hydroxyl (-OH) from the oxazolidinone and acrylate moieties that enhance hydrophilicity through strong hydrogen bonding and affinity for water, ensuring a persistent low water contact angle of less than 10 degrees." +} +{ + "content": "The hydrophilic polymers are synthesized using monomers such as polyethylene glycol diacrylate (PEGDA) and polyetheramines which contain functional groups such as hydroxymethyl and sulfonic acid that enhance hydrophilicity by forming hydrogen bonds with water molecules, thereby increasing water affinity and interaction." +} +{ + "content": "" +} +{ + "content": "The hydrophilic polymers are synthesized using monomers such as polyether amines and polyethylene glycol diacrylate, which contain functional groups like hydroxyl (-OH) and isocyanate (-NCO), enhancing hydrophilicity through hydrogen bonding and increased interactions with water, while the hydrophobic side chains derived from isocyanate reactions with hydroxy acrylates provide structure and stability to the polymer.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers includes the use of hydrophilic groups which enhance water interactions, although specific functional groups are not detailed in the excerpt." +} +{ + "content": "The hydrophilic polymers are synthesized from monomers that include hydroxyl acrylates, which contain hydroxyl functional groups that enhance hydrophilicity by forming hydrogen bonds with water, and amino sulfonate salts, which also contribute to hydrophilic properties via ionic interactions with water." +} +{ + "content": "The hydrophilic polymers were synthesized using monomers such as hydroxyethyl acrylate, hydroxypropyl acrylate, and hydroxybutyl acrylate, which contain functional groups like hydroxyl (-OH) that enhance hydrophilicity by forming hydrogen bonds with water molecules, thereby increasing the polymers' affinity for water.", +} +{ + "content": "The monomer used for synthesizing the hydrophilic polymer includes ureido groups, which enhance hydrophilicity due to their hydrogen bonding capabilities with water, as well as poly(ethylene oxide) ether segments that increase the polymer's affinity for water through increased surface hydration and decreased surface tension." +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "The text mentions that hydrophilic polymers are often synthesized from low-adhesion oligomers such as polyethyleneglycol acrylate or polyurethane acrylate, which contain functional groups that may improve hydrophilicity; however, these oligomers typically lack rich functional groups, leading to poor adhesion.", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include urea groups and polyethylene glycol ether, which enhance hydrophilicity through functional groups that provide better wetting properties and facilitate interactions with water, ultimately improving adhesion to substrates by utilizing low surface tension and permeability to swell in substrates." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include tri(2-hydroxyethyl) isocyanurate triacrylate (THEICTA) and hydroxyethyl acrylate (HEA), which contain functional groups such as hydroxyl (-OH) that enhance the hydrophilicity of the corresponding polymers by facilitating hydrogen bonding and increasing interactions with water." +} +{ + "content": "", +} +{ + "content": "The hydrophilic polymers synthesized include multi-functional alcohols A such as isosorbide, Tween 20, Tween 60, Tween 80, glycerol, glycerol polyether-18, and glycerol polyether-26, which possess hydroxyl groups that enhance hydrophilicity by forming hydrogen bonds with water, and multi-functional alcohols B, which contain hydroxyl groups as well, mixed with N-isobutoxy and/or N-n-butoxy methacrylamide compounds that also contribute to enhancing interactions with water through hydrogen bonding.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers utilizes monomers such as polyols A and B, which contain hydroxyl functional groups, and N-(isobutoxy) methacrylamide or N-(butoxy) methacrylamide, containing ether and alkoxy groups that enhance hydrophilicity by facilitating hydrogen bonding and increased interaction with water." +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as multi-functional alcohols and isocyanates, where hydroxyl groups and ether linkages in polyether amines enhance hydrophilicity by forming hydrogen bonds with water molecules, thereby improving interactions with water." +} +{ + "content": "", +} +{ + "content": "The hydrophilic cyclic siloxane used to synthesize hydrophilic polymers includes hydroxyl and epoxy functional groups, which enhance hydrophilicity by forming hydrogen bonds with water molecules, thereby improving the interactions with water.", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include hydrophilic cyclic siloxane, which contains hydrophilic functional groups that enhance hydrophilicity and prevent fogging, and epoxy groups that can interact with curing agents; these functional groups enhance interactions with water by facilitating hydrogen bonding and hydrophilic interactions, allowing for effective moisture retention and surface wetting." +} +{ + "content": "The hydrophilic cyclic siloxane polymers are synthesized using monomers such as diethanolamine and poly(ethylene glycol) monomethyl ethers, which contain hydroxyl (-OH) and ether (–O–) functional groups that enhance hydrophilicity by forming strong hydrogen bonds with water molecules, thus increasing water affinity and facilitating interactions with water." +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include mercaptoacetic acid, which features a thiol functional group that can form hydrogen bonds with water to enhance hydrophilicity, and ethoxylated trimethylolpropane triacrylate, which contains ether groups that increase polarity and improve interactions with water." +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as ethoxylated trimethylolpropane triacrylate and mercaptopropionic acid, which contain functional groups like ether, ester, and epoxy groups that enhance hydrophilicity by promoting stronger interactions with water through the formation of hydrogen bonds and facilitating the expansion of a water film on the polymer surface." +} +{ + "content": "The synthesis of hydrophilic polymers involves the use of monomers such as thiopropionic acid and ethoxylated trimethylolpropane triacrylate, which contain functional groups like thiol (-SH) and hydroxyl (-OH) that enhance hydrophilicity through strong hydrogen bonding and polar interactions with water." +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The hydrophilic polymers were synthesized using monomers such as acrylamide (AM) and 2-acrylamido-2-methylpropane sulfonic acid (AMPS), both of which contain functional groups like amide and sulfonic acid that enhance the hydrophilicity of the polymers by increasing their ability to interact with water through hydrogen bonding and ionic interactions with water molecules." +} +{ + "content": "The monomers used for synthesizing the hydrophilic polymers include acrylamide (AM), 2-acrylamido-2-methylpropane sulfonic acid (AMPS), N-vinyl pyrrolidone (NVP), and N,N-dimethylacrylamide (DMAM), where functional groups such as amide in AM, sulfonic acid in AMPS, and the lactam in NVP enhance the polymers' hydrophilicity by facilitating hydrogen bonding and ionic interactions with water, leading to improved water affinity and solubility.", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include 2-acrylamido-2-methylpropane sulfonic acid (AMPS), acrylamide (AM), N-vinyl pyrrolidone (NVP), and N,N-dimethylacrylamide (DMAM), with functional groups such as hydroxyl (O-H), amide (C=O, N-H), and sulfonic (O-S) groups that enhance hydrophilicity through hydrogen bonding and ionic interactions with water molecules." +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include vinyl monomers with N-hydroxymethyl or N-alkoxyhydroxymethyl groups as well as vinyl monomers with sulfonic groups, which enhance the hydrophilicity of the polymers through the presence of hydrophilic functional groups that interact with water via hydrogen bonding and ionic interactions." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers that have functional groups such as N-hydroxymethyl, N-hydroxymethyl ether, and hydroxyl, which enhance hydrophilicity by increasing interactions with water through hydrogen bonding." +} +{ + "content": "The hydrophilic polymers are synthesized using monomers that include vinyl monomers with N-hydroxymethyl or N-alkoxymethylol groups (monomer A1), vinyl monomers with sulfonic acid groups (monomer A2), and alkyl acrylate monomers (monomer A3), where the presence of N-hydroxymethyl or N-alkoxymethylol functional groups enhances polymer crosslinking, and sulfonic acid groups improve the hydrophilicity and heat resistance of the copolymer, facilitating interactions with water through ion-dipole and hydrogen bonding mechanisms." +} +{ + "content": "Monomers used in the synthesis of hydrophilic polymers include A1: vinyl monomers with N-hydroxymethyl or N-alkoxy hydroxymethyl groups, which induce crosslinking and enhance hydrophilicity; A2: vinyl monomers featuring sulfonic acid groups, which improve the polymer's hydrophilicity and suppress fogging phenomena in high humidity; and A3: alkyl ester monomers of (meth)acrylic acid, which improve adhesion and heat resistance of the film, with the sulfonic acid groups in A2 maintaining some acidity to catalyze reactions while also contributing to the overall hydrophilicity of the copolymer." +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves the use of hydroxyl acrylic acid esters, which contain hydroxyl functional groups that enhance hydrophilicity by forming hydrogen bonds with water, and polythorate, which further increases hydrophilic interactions due to its polar functional groups.", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include hydroxy acrylates and sorbitan esters, where functional groups such as hydroxyl (-OH), carboxyl (-COOH), amino (-NH2), thiol (-SH), and ionic groups like carboxylate, sulfonate, ammonium, and phosphate enhance the hydrophilicity by enabling hydrogen bonding with water, which allows for water condensation to spread uniformly on the surface, thereby forming a continuous water film and reducing light scattering caused by small water droplets." +} +{ + "content": "", +} +{ + "content": "The synthesis of hydrophilic polymers involves using monomers such as polyether polyols, methacrylic acid hydroxyl esters, and polysorbates, where functional groups like hydroxyl groups enhance hydrophilicity by forming hydrogen bonds with water molecules, promoting better water absorption and wettability.", +} +{ + "content": "" +} +{ + "content": "The hydrophilic polymers synthesized from the copolymer (i) include monomer structures with functional groups such as hydroxyl groups and ether groups, which enhance hydrophilicity by increasing hydrogen bonding interactions with water and improving water affinity." +} +{ + "content": "The hydrophilic polymers synthesized include sulfonic acid copolymers and amino resins, where the sulfonic acid functional groups enhance hydrophilicity by providing strong ionic interactions with water, while amino groups form hydrogen bonds with water molecules, thus increasing the polymer's affinity for water." +} +{ + "content": "" +} +{ + "content": "Monomers used for synthesizing hydrophilic polymers include epoxy-functionalized unsaturated monomers, sulfonic acid-functionalized unsaturated monomers, hydroxyl-functionalized unsaturated monomers, and hydrolyzable silane-functionalized unsaturated monomers, wherein functional groups such as sulfonic acid and hydroxyl groups enhance hydrophilicity by promoting strong hydrogen bonding and ionic interactions with water, thereby increasing the material's affinity for water and its ability to absorb moisture." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include copolymers that have sulfonic groups and epoxy groups, or silane groups, which enhance the hydrophilicity by increasing the electrostatic interactions and hydrogen bonding with water molecules." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include compounds with sulfonic acid groups, such as allyl sulfonic acid derivatives, which enhance the hydrophilicity of the resulting polymers by introducing polar groups that can interact favorably with water through hydrogen bonding and ion-dipole interactions." +} +{ + "content": "Monomers used for synthesizing hydrophilic polymers include ATBS (acrylamide-based sulfonic acid), GMA (glycidyl methacrylate), and KBE-503 (a type of acrylic polymer), with functional groups such as sulfonate (SO3-) in ATBS and hydroxyl groups in GMA, which enhance the hydrophilicity of the polymers by increasing their capacity to interact with water through hydrogen bonding and ionic interactions." +} +{ + "content": "", +} +{ + "content": "The synthesis of the hydrophilic polymer involves the use of acrylic compounds containing trimethyl ammonium groups and polyethylene glycol diamine, which enhance hydrophilicity through the presence of quaternary ammonium structures that facilitate strong interactions with water due to their ionic nature and ability to form hydrogen bonds." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves introducing functional groups such as carboxyl, amino, thiol, hydroxyl, ionic groups like carboxylate, sulfonate, quaternary ammonium, phosphate, and ethoxy units, which enhance hydrophilicity by enabling hydrogen bonding and ionic interactions with water, leading to the formation of a uniform water film that prevents the scattering of light and achieves anti-fog properties." +} +{ + "content": "The synthesis of the hydrophilic polymer involves monomers such as di-functional polyether amines and multi-functional acrylates, with ethoxy units serving as hydrophilic functional groups that enhance water interactions by facilitating hydrogen bonding and increasing water absorption, leading to improved hydrophilicity and fog-repellent properties of the resultant polymer.", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include ethoxylated trimethylolpropane triacrylate (EO35mol) with a hydroxyl functional group and ethoxylated pentaerythritol tetraacrylate (EO120mol), both of which enhance hydrophilicity due to the presence of ether (–O–) linkages and hydroxyl (–OH) groups that can form hydrogen bonds with water, thus enhancing interactions with water." +} +{ + "content": "", +} +{ + "content": "The hydrophilic polymers are synthesized using monomers such as methoxy poly(ethylene glycol) acrylate, which contains polyethylene glycol units that enhance hydrophilicity due to their hydrophilic ether functional groups capable of forming hydrogen bonds with water, and multifunctional acrylate monomers featuring ethoxy units, which further improve water interactions by increasing the polymer's ability to absorb moisture.", +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers with functional groups such as carboxyl, amine, thiol, hydroxyl, and ionic groups like carboxylate, sulfonate, ammonium, and phosphate, which enhance hydrophilicity by forming hydrogen bonds with water, allowing water vapor to condense and spread uniformly over surfaces, thereby eliminating the scattering of light caused by small water droplets." +} +{ + "content": "The synthesis of hydrophilic polymers involves using monomers such as methoxy poly(ethylene glycol) acrylate with polyethylene glycol units of high molecular weight (at least 400) and multi-functional acrylates containing ethoxy units, which enhance hydrophilicity due to their ability to form strong hydrogen bonds with water, thus improving water interactions and contributing to superior anti-fog performance and water resistance of the resulting polymer.", +} +{ + "content": "The hydrophilic polymers in the synthesis include monomers such as methoxy polyethylene glycol acrylates and ethoxy polyfunctional acrylates which contain functional groups such as ether groups (-O-) that enhance hydrophilicity by promoting hydrogen bonding and dipole-dipole interactions with water molecules." +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers with functional groups such as sulfonate, hydroxyl, and carboxyl groups, which enhance water interactions; the sulfonate groups in particular enhance hydrophilicity by creating ionic interactions with water, while hydroxyl groups promote hydrogen bonding, and carboxyl groups increase solubility and further facilitate interactions with water." +} +{ + "content": "" +} +{ + "content": "The text does not provide any specific information regarding the monomer structures, functional groups that enhance hydrophilicity, or explanations of how these functional groups improve interactions with water." +} +{ + "content": "The hydrophilic organic polymer antifog coatings contain polar hydrophilic functional groups such as hydroxyl and carboxyl groups that enhance hydrophilicity by improving the wettability of the substrate surface, allowing water droplets to spread quickly and uniformly, thus lowering the static water contact angle.", +} +{ + "content": "The monomers used in synthesizing the hydrophilic polymers include sulfonate-containing polyacrylate, which enhances hydrophilicity due to the presence of sulfonate groups that serve as strong hydrophilic groups facilitating dispersion in water, and hydroxyl groups that can react with isocyanate groups, contributing to the water resistance and durability of the resulting coating.", +} +{ + "content": "The hydrophilic polymers synthesized incorporate monomers such as methacrylic acid, hydroxyethyl methacrylate, sodium 2-acrylamido-2-methylpropanesulfonate, and others, which contain functional groups such as sulfonic acid and carboxylic acid, enhancing hydrophilicity through strong ionic interactions and hydrogen bonding with water." +} +{ + "content": "Monomers used for synthesizing hydrophilic polymers include methacrylic acid butyl ester, methacrylic acid methyl ester, isooctyl acrylate, hydroxypropyl methacrylate, and vinyl sulfonate, where functional groups such as sulfonate groups enhance hydrophilicity by increasing the ionic and polar interactions with water, allowing for better water retention and improved interaction with polar solvents." +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves a double-structured polyether siloxane containing multiple hydrophobic linkages and two hydrophilic linkages, which enhance interactions with water through functional groups such as hydrophilic links that interact favorably with water molecules.", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The copolymer contains multiple hydrophobic linkages and two hydrophilic linkages, which enhance interactions with water by providing sites for hydrogen bonding and facilitating water retention.", +} +{ + "content": "The hydrophilic polymers synthesized in the examples utilize monomers such as 2,4,7,9-四甲基-5-癸炔-4,7-二醇四乙氧基醚 and its derivatives, which contain hydroxyl (-OH) groups that enhance their hydrophilicity by forming hydrogen bonds with water molecules, thus increasing interactions with water.", +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves using monomers with functional groups such as epoxy propane and epoxy ethane chains that enhance interactions with water by providing low surface energy, hydrophilicity, and wettability.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The text mentions hydrophilic acrylates or their copolymers as monomers used for synthesizing hydrophilic polymers, where the functional groups in these acrylates enhance hydrophilicity through their ability to absorb moisture from the air, contributing to anti-fog properties.", +} +{ + "content": "The monomers used in the synthesis of hydrophilic polymers include star-shaped organic silicone compounds, which feature functional groups such as epoxy propane chains and ethylene oxide chains that enhance the hydrophilicity of the polymers by improving their wettability and interaction with water through the formation of micro-physical structures that facilitate water retention.", +} +{ + "content": "", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include octavinyl polyhedral silsesquioxane and a polyether containing epoxy propylene and epoxy ethylene chains, which enhance the hydrophilicity of the polymers through the presence of hydroxyl groups and ether linkages that interact with water via hydrogen bonding and dipole-dipole interactions." +} +{ + "content": "The monomer structures used for synthesizing hydrophilic polymers include silane derivatives having polyethylene glycol chains and epoxy groups, where the polyethylene glycol chain enhances hydrophilicity due to its ability to form hydrogen bonds with water, and the epoxy group can react with water, further increasing interaction and compatibility with aqueous environments." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The monomer structures used for synthesizing hydrophilic polymers include silane derivatives with polyethylene glycol chains and silane derivatives with epoxy groups, where the polyethylene glycol chains contribute to hydrophilicity through their hydrophilic ether groups, enhancing interactions with water by increasing solubility and promoting hydrogen bonding.", +} +{ + "content": "The synthesis of hydrophilic polymers includes monomers such as silane derivatives that contain polyethylene glycol (PEG) chains and epoxy groups, where the PEG chains enhance hydrophilicity due to their high affinity for water, facilitating the formation of water films on surfaces, while epoxy groups can promote cross-linking among the silicate structures, thus improving the overall film strength and hydrophilic properties." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves the use of hydrophilic bisphenol A-type (meth)acrylate, which contains functional groups that enhance hydrophilicity and improve interactions with water." +} +{ + "content": "The synthesis of hydrophilic polymers involves the use of monomers such as hydrophilic bisphenol A type (meth)acrylate, which has functional groups like hydroxyl groups, and (meth)acrylate groups that enhance hydrophilicity by allowing the polymer to disperse or dissolve in water without phase separation, thereby improving water interactions and contact angle reduction.", +} +{ + "content": "The synthesis of hydrophilic polymers utilizes monomers such as hydrophilic Bisphenol A-type (meth)acrylate and reactive nonionic surfactants, which feature functional groups that enhance hydrophilicity through their ability to interact favorably with water molecules due to hydrogen bonding and dipole interactions." +} +{ + "content": "" +} +{ + "content": "The text excerpt mentions a hydroxylated polyalkylene oxide chain as a key component in the synthesis of hydrophilic polymers, with the hydroxyl functional groups enhancing the hydrophilicity of the corresponding polymers by promoting hydrogen bonding and interactions with water." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include hydroxyl functional polymers and glycidyl carbamate, which feature hydroxyl and epoxy functional groups respectively; these functional groups enhance hydrophilicity by increasing the ability of the polymers to form hydrogen bonds with water, thereby improving their interactions with moisture." +} +{ + "content": "The text excerpt does not provide specific information regarding the monomer structures or the functional groups that enhance the hydrophilicity of the corresponding polymers." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include polyfunctional oligomers with epoxy urethane functional groups and polyalkylene oxide chains, where the epoxy urethane functional groups and polyalkylene oxide enhance the hydrophilicity by providing polar functional groups that interact favorably with water through hydrogen bonding and dipole-dipole interactions, improving the water dispersibility of the resulting polymers." +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers with functional groups such as epoxy urethane functional groups and polyalkylene oxide chains, particularly ethylene oxide, which enhance hydrophilicity by increasing interactions with water due to their ability to form hydrogen bonds and provide a polar backbone that attracts water molecules." +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing the hydrophilic polymers include methoxy poly(ethylene glycol) (mPEG), which contains hydroxyl functional groups that enhance hydrophilicity through hydrogen bonding with water, and glycidol, which also possesses hydroxyl groups that promote similar interactions, thereby improving the water retention and dispersibility of the resulting polymers.", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The synthesis of hydrophilic polymers includes monomers such as methoxy poly(ethylene glycol), which contains ether functional groups that enhance hydrophilicity by promoting hydrogen bonding and increasing solubility in water, as well as polyfunctional isocyanate resins derived from isocyanurate or biuret compounds that contribute to the overall hydrophilicity through their reactive functional groups, enabling better interaction with water molecules." +} +{ + "content": "", +} +{ + "content": "The text mentions that the hydrophilic polymers can include polyalkylene oxides such as ethylene oxide, propylene oxide, and ethylene propylene oxide, which contain hydroxyl groups that enhance their hydrophilicity by forming strong hydrogen bonds with water molecules." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The monomer structures used for synthesizing hydrophilic polymers include primary amines and carboxylic acids in polyamides, aliphatic alcohols and carboxylic acids in polyesters, ether groups in polyethers, and alcohol groups with cyanate groups in polyurethanes, where the presence of functional groups such as amides, carboxylic acids, and alcohols enhances the hydrophilicity by providing sites for hydrogen bonding and ionic interactions with water." +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as glycidyl monomers and N-vinyl lactams, where functional groups such as glycidyl and the lactam ring enhance hydrophilicity by providing polar regions that facilitate hydrogen bonding and other interactions with water." +} +{ + "content": "The synthesized hydrophilic polymers use monomers such as glycidyl acrylate and glycidyl methacrylate, which contain epoxide functional groups, N-vinyl pyrrolidone that contains a lactam functional group, and acrylic acid as an unsaturated carboxylic acid; these functional groups enhance hydrophilicity by providing polar sites that facilitate hydrogen bonding and increased water absorption.", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include glycidyl and lactam monomers, where the glycidyl group introduces a latent functional group for potential cross-linking and enhances adhesion through reaction with hydroxyl groups on substrates or complexation with nitrogen of the lactam, while the lactam is used primarily for increasing adhesion to vinyl films and painted surfaces.", +} +{ + "content": "The monomer mixture for synthesizing the hydrophilic polymers included methyl acrylate, glycidyl methacrylate, N-vinyl pyrrolidone, and acrylic acid, where functional groups such as carboxylic acid from acrylic acid, amide from N-vinyl pyrrolidone, and hydroxyl groups from glycidyl methacrylate enhance hydrophilicity by increasing the ability of the polymers to form hydrogen bonds with water molecules." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include acrylic acid, which contains carboxylic acid functional groups that enhance hydrophilicity, allowing for increased hydrogen bonding with water, and N-vinyl caprolactam, which introduces polar amide groups that also promote interactions with water through dipole interactions.", +} +{ + "content": "" +} +{ + "content": "The monomers used to synthesize the hydrophilic polymers include acrylic acid, which contains a carboxylic acid functional group that enhances hydrophilicity by allowing for hydrogen bonding with water molecules, as well as N-vinyl pyrrolidone, which possesses a lactam functional group that increases water interactions through dipole-dipole interactions and hydrogen bonding.", +} +{ + "content": "", +} +{ + "content": "Graphene oxide (GO) contains various oxygen-containing functional groups such as epoxy, hydroxyl, and carbonyl groups that enhance its hydrophilicity by increasing interactions with water through hydrogen bonding and polar interactions." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as polyethylene glycols and polyols with hydroxyl or amino groups that enhance hydrophilicity through their ability to form hydrogen bonds with water molecules.", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include ethylenically unsaturated monomers with pendent hydrophilic poly(alkylene oxide) groups and additional functional groups like hydroxy, amino, and carboxyl, which enhance hydrophilicity through hydrogen bonding and interactions with water.", +} +{ + "content": "Monomers such as 2-hydroxyethyl methacrylate (HEMA) and polyethylene glycol methyl ether methacrylate (MPEG) contain functional groups like hydroxyl (-OH) and ether (C-O-C) groups, which enhance the hydrophilicity of the corresponding polymers by promoting hydrogen bonding and dipole-dipole interactions with water." +} +{ + "content": "The hydrophilic copolymers were synthesized using monomers such as MPEG, HEMA, DMACM, and NVA, which contain functional groups like hydroxyl (-OH) and amide (-C(O)NH-) that enhance hydrophilicity by increasing hydrogen bonding and dipole interactions with water." +} +{ + "content": "The synthesized hydrophilic copolymer includes MPEG, which has methoxy (–OCH3) functional groups that enhance the hydrophilicity of the polymer by increasing its ability to interact with water through hydrogen bonding." +} +{ + "content": "The monomers used for synthesizing the hydrophilic copolymer include MPEG and HEMA, where HEMA contains a hydroxyl group that enhances hydrophilicity by forming hydrogen bonds with water molecules, thus increasing the polymer's affinity for water." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The hydrophilic copolymers synthesized in the described example utilize monomers such as MPEG and VDM, which contain functional groups that enhance hydrophilicity, thereby facilitating greater interactions with water due to their ability to form hydrogen bonds and increase solubility.", +} +{ + "content": "The synthesis of hydrophilic polymers in the preparatory examples involves the use of HEMA, which contains hydroxyl functional groups that enhance hydrophilicity by forming hydrogen bonds with water, thereby improving interactions with the solvent.", +} +{ + "content": "The synthesis of the hydrophilic copolymer utilized monomers such as MPEG and HEMA, where the hydroxyl (-OH) groups in HEMA enhance hydrophilicity by forming hydrogen bonds with water, leading to improved water absorption and interaction." +} +{ + "content": "" +} +{ + "content": "The hydrophilic polymers are synthesized using monomers that contain pendent, hydrophilic poly(alkylene oxide) groups, which enhance hydrophilicity through increased interaction with water due to their ability to form hydrogen bonds and their high water affinity." +} +{ + "content": "The hydrophilic polymers synthesized for antifog coatings utilize functional groups such as hydroxyl groups present in poly(ethylene glycol) (PEG) and surface-active agents like Tween 20, which enhance hydrophilicity by promoting strong hydrogen bonding interactions with water molecules, thereby allowing water droplets to spread and form a continuous film rather than bead up." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include 2-hydroxyethyl methacrylate (2-HEMA), which contains a hydroxyl functional group that enhances hydrophilicity by forming hydrogen bonds with water molecules, significantly increasing water interactions through strong dipole-dipole interactions.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The text excerpt does not provide specific information regarding the monomer structures used for synthesizing hydrophilic polymers, the functional groups that enhance the hydrophilicity of corresponding polymers, or explanations of how these functional groups enhance interactions with water.", +} +{ + "content": "Minor amount of hydroxyethylmethacrylate, which contains a hydroxyl functional group that enhances hydrophilicity, was added to promote adherence property, as hydroxyl groups can form hydrogen bonds with water, thereby increasing interactions with water." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The monomers used in synthesizing hydrophilic polymers included glycidyl methacrylate (GMA), hydroxyethyl methacrylate (HEMA), and methacrylic acid (MHMA), with functional groups such as hydroxyl and carboxylic acid enhancing hydrophilicity by promoting hydrogen bonding and ionic interactions with water." +} +{ + "content": "The synthesis of the hydrophilic polymer MATSi involves the use of monomers such as KH570, which contains functional groups that enhance hydrophilicity by promoting interactions with water through hydrogen bonding.", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The presence of hydroxyl groups resulting from the reaction of epoxy groups with methacrylate enhances the hydrophilicity of the corresponding polymers by increasing their capacity to form hydrogen bonds with water, thereby facilitating better interactions with the solvent." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as one or more radiation-curable acrylates containing reactive hydrophilic alkoxylated groups, enhancing hydrophilicity through functional groups like alkyl ether structures, which promote water interactions by increasing adsorption and compatibility with water molecules." +} +{ + "content": "The hydrophilic polymers are synthesized using one or more radiation-curable acrylates that contain hydrophilic alkoxy group regions which enhance interactions with water due to the presence of one or more hydrophilic alkoxy groups of the formula (CH2)nO- where n is between 1 and 3 and m is between 1 and 10." +} +{ + "content": "The hydrophilic polymers are synthesized using acrylates that contain one or more hydrophilic alkoxylation groups, specifically with the structure (CH2)nO-m, where n can be between 1 and 3, and m can range from 1 to 10, which enhance hydrophilicity and allow for interaction with water by increasing the surface energy of the cured coating, facilitating water spread instead of droplet formation." +} +{ + "content": "The synthesis of hydrophilic polymers can include monomers such as ethoxylated dimethacrylate and ethoxylated trimethylolpropane triacrylate, which contain functional groups like hydroxyl and ether that enhance hydrophilicity by promoting hydrogen bonding and dipole interactions with water molecules." +} +{ + "content": "The polymers synthesized in the examples include functional groups such as hydroxyl groups (-OH) and ether groups (-O-) from monomers like SR9035, 3-EGA, and various acrylates, which enhance hydrophilicity by forming hydrogen bonds with water molecules, thereby increasing the polymers' ability to interact with moisture and maintain a hydrophilic surface." +} +{ + "content": "", +} +{ + "content": "The hydrophilic network includes one or more radiation-curable acrylates containing hydrophilic alkoxy groups that enhance hydrophilicity through their ability to establish hydrogen bonds and dipole-dipole interactions with water, with the alkoxy groups represented by the formula -(CH2)nO- where n is an integer between 1 and 3." +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as acrylates that contain hydrophilic alkoxy groups, represented by the formula –(CH2)nO– with n ranging from 1 to 3 and m from 1 to 10, which enhance the hydrophilicity through increased water interaction via hydrogen bonding and the ability to form stable aqueous surfaces.", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include ethoxylated dimethacrylates and ethoxylated trimethylolpropane triacrylate, which enhance hydrophilicity due to the presence of ethylene oxide units that facilitate hydrogen bonding and increase affinity for water." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers for anti-fog coatings involves using monomers such as UV curable hydrophilic acrylate polymers that contain functional groups like sulfonic acid and ammonium salts, which enhance hydrophilicity by promoting strong ionic interactions and hydrogen bonding with water molecules." +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include ethanolamine, which contains amino and hydroxyl functional groups that enhance hydrophilicity through hydrogen bonding with water, and SY-40M (glycidyl ether of C12 and C14 alcohol), which likely possesses ether linkages contributing to increased water affinity." +} +{ + "content": "The monomer structures used for synthesizing hydrophilic polymers include ethanolamine, which contains hydroxyl (-OH) functional groups, and alkyl glycidyl ether, which enhances hydrophilicity through its ether linkages; these functional groups facilitate hydrogen bonding with water, thereby increasing interactions and solubility in aqueous environments." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include ammonium salt (AS), which contains functional groups such as -NH, contributing to enhanced hydrophilicity by forming hydrogen bonds with water molecules, and acrylate groups that allow for polymeric cross-linking, further improving interaction and swelling in the presence of water." +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "Hydrophilic polymers are synthesized using monomers that contain functional groups such as hydroxyl groups (-OH), amino groups (-NH2), carboxyl groups (COOH), and sulfonic groups (-SO3H), which enhance their hydrophilicity by strongly interacting with water molecules and having a high capacity to absorb water." +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include 2-hydroxyethyl methacrylate (HEMA) and 2-acrylamido-2-methyl propane sulfonic acid (AMPS), which contain hydroxyl and sulfonic acid functional groups, respectively; these functional groups enhance hydrophilicity by promoting hydrogen bonding and ionic interactions with water molecules." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include HEMA and AMPS, with functional groups such as sulfo groups and hydroxyl groups that enhance hydrophilicity by promoting hydrogen bonding and ion-dipole interactions with water." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The hydrophilic components used in the synthesis of antifog coatings include hydroxy groups and alkoxy groups, which enhance the polymer's interactions with water by increasing hydrogen bonding capabilities and improving solubility in aqueous environments." +} +{ + "content": "The hydrophilic polymers are synthesized using acrylate or methacrylate monomers that can include functional groups such as hydroxyl (O), which enhances hydrophilicity by promoting hydrogen bonding and interactions with water, as well as substituents that can include linear or cycloalkyl, divalent aromatic, or heterocyclic groups, influencing the degree of water affinity based on their structure and polarity." +} +{ + "content": "The monomer structures used for synthesizing hydrophilic polymers include poly(ethyleneoxy)methacrylate, poly(ethyleneoxy)acrylate, poly(ethyleneoxy)monomethylether acrylate, poly(ethyleneoxy)monomethylether methacrylate, pentaerythritol triacrylate, glycerol dimethacrylate, glycerol diacrylate, bisphenol-A-glycerol tetraacrylate, bisphenol-A-glycerol diacrylate, and bisphenol-A-ethyleneoxy diacrylate, which feature functional groups such as hydroxy (-OH), alkoxy (-O-R), and ether links that enhance the hydrophilicity of the polymers by promoting strong hydrogen bonding and dipole-dipole interactions with water molecules." +} +{ + "content": "The hydrophilic component of the antifog composition includes a hydrophilic acrylate, which may contain functional groups such as hydroxy groups, alkoxy groups, and poly(ethylene oxide) segments that enhance the hydrophilicity of the corresponding polymers by increasing the polymer's ability to interact with water through hydrogen bonding and dipole-dipole interactions." +} +{ + "content": "The text mentions monomer structures such as glycerol dimethacrylate, glycerol diacrylate, bisphenol-A-glycerol tetraacrylate, bisphenol-A-glycerol diacrylate, and bisphenol-A-ethyleneoxy diacrylate, which include functional groups like hydroxyl and ether groups that enhance hydrophilicity by increasing interactions with water through hydrogen bonding and dipole-dipole interactions." +} +{ + "content": "The hydrophilic monomers include functional groups such as hydroxy groups and alkoxy groups, which enhance the hydrophilicity of the resulting polymers by increasing their ability to interact with water through hydrogen bonding and dipole-dipole interactions." +} +{ + "content": "The hydrophilic monomers used for synthesizing hydrophilic polymers include glycerol dimethacrylate, bisphenol A glycerolate diacrylate, and poly(ethyleneoxy) methacrylate, which contain functional groups such as ether and hydroxyl groups that enhance the hydrophilicity of the polymers by forming hydrogen bonds with water, thereby increasing their ability to interact with and absorb water." +} +{ + "content": "" +} +{ + "content": "The hydrophilic functional groups in the formulations include glycerol dimethacrylate and various surfactants such as PEG monolaurate, BRIJ O20, P2393, Igepal CO720, and Tween 20, which enhance the hydrophilicity of the corresponding polymers by increasing their interactions with water through the formation of hydrogen bonds and improving wettability.", +} +{ + "content": "The synthesis of hydrophilic polymers utilized monomers such as Bisphenol-A-ethoxylate diacrylate, glycerol dimethacrylate, and various hydrophilic multifunctional (meth)acrylates, which bear functional groups like ethylene glycol units, hydroxyl groups, and alkoxy groups that enhance hydrophilicity by increasing hydrogen bonding and dipole interactions with water." +} +{ + "content": "The synthesis of hydrophilic polymers incorporates monomers such as acrylates and methacrylates with functional groups like hydroxy and alkoxy, which enhance hydrophilicity by forming hydrogen bonds with water molecules." +} +{ + "content": "The text does not provide specific information about monomer structures or functional groups that enhance the hydrophilicity of corresponding polymers." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include silicone compounds with hydrophilic functional groups like —CO2H, —OH, —NH, oxyethylene segments, —SH, ester, urethane, and isocyanate groups, which enhance the polymers' hydrophilicity by providing sites for interaction with water through hydrogen bonding and lowering the surface energy of the aqueous dispersion." +} +{ + "content": "The synthesis of hydrophilic polymers often involves monomers containing functional groups such as hydroxyl groups from polyether polyols and carboxylic acid functionalities from compounds like dimethylol propionic acid, which enhance hydrophilicity by forming hydrogen bonds with water, thus increasing interactions and solubility in aqueous environments." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include N-vinylpyrrolidone (NVP) and 2-hydroxyethyl-methacrylate (HEMA), where functional groups such as the pyrrolidone in NVP and the hydroxyl group in HEMA enhance hydrophilicity by increasing hydrogen bonding and dipole interactions with water." +} +{ + "content": "Monomers such as PVP, PHEMA, NVP, and HEMA contain functional groups like hydroxyl (-OH), amide (-C(O)NH-), and carboxylic acid (-COOH) that enhance the hydrophilicity of the corresponding polymers by forming hydrogen bonds and ionic interactions with water molecules, thereby increasing their affinity for water." +} +{ + "content": "The monomer structures used for synthesizing hydrophilic polymers include polyvinylpyrrolidone (PVP) and N-vinylpyrrolidone (NVP), which contain functional groups such as pyrrolidone that enhance hydrophilicity by enabling strong hydrogen bonding interactions with water.", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include acrylic acid, methacrylic acid, and other ethylenically unsaturated carboxylic acids, which contain functional groups such as carboxylates and amines that enhance hydrophilicity by increasing hydrogen bonding and ionic interactions with water.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The hydrophilic polymers synthesized in this coating composition are derived from a polyurethane having ethylenically unsaturated functional groups and include an isocyanate-reactive surfactant, which enhances hydrophilicity by chemically bonding within the polymeric network, thus improving water interaction through increased surface wettability." +} +{ + "content": "The synthesis of hydrophilic polymers involves the use of isocyanate-reactive components having ethylenically unsaturated functional groups, such as hydrophilic alkoxylated acrylates, which enhance hydrophilicity and contribute to permanent anti-fog properties by providing crosslinkable acrylate functionality that allows for better interactions with water through hydrogen bonding and polar interactions." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers includes ethylenically unsaturated functional groups such as reactive vinyl groups, reactive acrylate groups, reactive methacrylate groups, and reactive allyl groups, which enhance interactions with water due to their ability to form hydrogen bonds and increase polarity, thereby improving hydrophilicity." +} +{ + "content": "The polyols used for synthesizing hydrophilic polymers include diols and triols with main chain segments of polyethylene oxide and polypropylene oxide, containing functional groups such as ethylene glycol, propylene glycol, and polyethylene oxide, which enhance the hydrophilicity of the polymers by increasing their ability to form hydrogen bonds with water molecules." +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include hydroxyl groups, thiol groups, amine groups, and ethylenically unsaturated functional groups like acrylates, which enhance the hydrophilicity of the polymers by increasing their capacity to form hydrogen bonds with water molecules, thereby improving their interaction with water." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involved the use of monomers such as trimethylolethane, ethylene glycol, and polyethylene glycol, all of which contain hydroxyl functional groups that enhance hydrophilicity by forming strong hydrogen bonds with water, thereby improving the interaction of the polymer with water." +} +{ + "content": "The synthesis involves functional groups like the hydroxyl group from 4-hydroxybutyl acrylate that enhance the hydrophilicity of the resulting polymers by forming strong hydrogen bonds with water, thus improving water interaction and absorption." +} +{ + "content": "The synthesis of hydrophilic polymers involves the use of monomers such as ethylene glycol, which contains hydroxyl (-OH) groups that enhance hydrophilicity by forming hydrogen bonds with water molecules, and 4-hydroxybutyl acrylate, which also has hydroxyl groups contributing to water interaction through similar hydrogen bonding mechanisms." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include acrylic acid and polyethyleneglycol diglycidyl ether, with functional groups such as carboxyl (-COOH) in acrylic acid and ether (-O-) in polyethyleneglycol enhancing hydrophilicity by promoting hydrogen bonding and dipole-dipole interactions with water molecules." +} +{ + "content": "" +} +{ + "content": "The isocyanate-reactive component having ethylenically unsaturated functional groups comprises an isocyanate-reactive alkoxylated acrylate, which includes hydroxyl groups that enhance hydrophilicity by promoting hydrogen bonding interactions with water." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The monomer structures used for synthesizing hydrophilic polymers include diols with polyethylene oxide side chain segments, dihydroxy-carboxylic acids, and polyols with main chain segments of polyethylene oxide or polypropylene oxide, where the presence of hydroxyl and carboxylic functional groups on these monomers enhances hydrophilicity by promoting hydrogen bonding and ionic interactions with water." +} +{ + "content": "The third polyol component used for synthesizing hydrophilic polymers includes a diol with polyethylene oxide side chain segments that enhances hydrophilicity through the presence of ether functional groups, which increase interactions with water by forming hydrogen bonds." +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves using monomers like hydrophilic polyols which contain functional groups such as hydroxyl groups that enhance polymer hydrophilicity by forming hydrogen bonds with water, improving interactions that lead to better dispersibility and anti-fogging properties of the resulting polyurethane coating.", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include polyols such as diols and triols with main chain segments of polyethylene oxide or polypropylene oxide, which enhance hydrophilicity through hydroxyl functional groups that promote strong interactions with water via hydrogen bonding.", +} +{ + "content": "", +} +{ + "content": "The text excerpt does not provide specific details about the monomer structures or the functional groups that enhance the hydrophilicity of the corresponding polymers." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include polyethylene glycol (PEG) and polyethylene oxide (PEO), both of which possess hydroxyl functional groups that enhance hydrophilicity by forming hydrogen bonds with water molecules, thus increasing water interaction and solubility in the resulting polymers." +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers with functional groups such as polyethylene oxide side chains and neutralized amines, which enhance hydrophilicity by promoting stronger interactions with water through hydrogen bonding and ionic interactions, respectively." +} +{ + "content": "The synthesis of hydrophilic polymers involves the use of dimethylolpropionic acid, which contains carboxylic acid functional groups that enhance hydrophilicity by increasing the polymer’s interaction with water through hydrogen bonding and ionic interactions, and polyethylene oxide side chains, which provide additional hydrophilicity due to the ether functional groups that facilitate the formation of hydrogen bonds with water molecules." +} +{ + "content": "The monomers used for synthesizing the hydrophilic polymers include trimethylolpropane and dimethylolpropionic acid, where the hydroxyl groups in trimethylolpropane and the carboxylic acid group in dimethylolpropionic acid enhance the hydrophilicity of the polymers by promoting intermolecular hydrogen bonding and ionic interactions with water." +} +{ + "content": "The polyurethane used in the synthesis of hydrophilic polymers contains polyethylene oxide side chains and main chains, which enhance hydrophilicity due to their ether functional groups that increase hydrogen bonding and interactions with water." +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as dimethylolpropionic acid and polyethylene oxide, which contain carboxylic acid and ether functional groups respectively, enhancing their hydrophilicity by enabling hydrogen bonding and increasing interactions with water." +} +{ + "content": "The hydrophilic properties of the synthesized polyurethane are attributed to the presence of polyethylene oxide side chains and main chains, which contain hydroxyl and ether functional groups that enhance interactions with water through hydrogen bonding and increased solubility.", +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing the hydrophilic polymers include polyethylene oxide side chains and main chains, which contain ether functional groups that enhance the hydrophilicity of the resulting polyurethane by forming hydrogen bonds with water molecules, thereby increasing water affinity and solubility.", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include polyethylene oxide side chains and main chains, which contain ether functional groups that enhance hydrophilicity by increasing the polymer's interactions with water through hydrogen bonding and enhanced solubility." +} +{ + "content": "" +} +{ + "content": "The synthesized hydrophilic polymers include polyethylene oxide side chains and main chains, which enhance hydrophilicity through their ether functional groups that interact favorably with water via hydrogen bonding and dipole-dipole interactions." +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers includes monomers with polyethylene oxide side chains and main chains, which contain hydroxyl and ether functional groups that enhance hydrophilicity through increased hydrogen bonding and dipole-dipole interactions with water." +} +{ + "content": "The synthesis of the hydrophilic polyurethane involves monomers such as polyethylene oxide side chains, which possess functional groups that enhance hydrophilicity through their ability to form hydrogen bonds and increase water solubility, thereby enhancing interactions with water.", +} +{ + "content": "The polyurethane synthesized includes polyethylene oxide side chains, which contain functional groups that enhance hydrophilicity through increased interactions with water due to the ether linkages within the polyethylene oxide structure, allowing for improved water solubility and dispersion.", +} +{ + "content": "The polyurethane mixture includes polyethylene oxide side chains, which contain hydrophilic functional groups that enhance the hydrophilicity of the polymers by increasing their affinity for water through hydrogen bonding and solvation interactions.", +} +{ + "content": "The hydrophilic properties of the synthesized polyurethane are enhanced by the presence of functional groups such as the polyethylene oxide side chains and neutralized amine groups, which facilitate interactions with water through hydrogen bonding and ionic interactions, respectively." +} +{ + "content": "The polyurethane used for synthesis includes polyethylene oxide side chains, which possess hydrophilic functional groups that enhance interactions with water by promoting hydrogen bonding and increasing water affinity, thereby increasing the overall hydrophilicity of the resulting polymer." +} +{ + "content": "", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include alkyl betaine with unbranched alkyl groups having about 8 to 18 carbon atoms, quaternary ammonium surfactants with 2 hydrophilic isocyanate-reactive functional groups such as hydroxyethyl and hydrophobic chains with at least 18 carbon atoms; these functional groups enhance hydrophilicity by providing ionic interactions with water, facilitating increased solubility and water absorption." +} +{ + "content": "Super-hydrophilic coatings have a very low contact angle, less than 5 degrees, indicating that they contain functional groups that enhance hydrophilicity, allowing water condensed on these surfaces to spread out quickly without the need for surfactants to be extracted, unlike Type II coatings which rely on surfactants to lower surface energy.", +} +{ + "content": "" +} +{ + "content": "The monomer used for synthesizing hydrophilic polymers is monomethyl ether polyethylene glycol (mPEG), which contains ether functional groups that enhance hydrophilicity by providing polar sites that facilitate interactions with water through hydrogen bonding.", +} +{ + "content": "The text describes the use of monomers such as mPEG triethoxysilane, 3-(trimethoxysilyl)propyl acrylate, and 3-(trimethoxysilyl)propyl methacrylate, which contain hydrophilic functional groups such as ethylene glycol units and methacrylate groups that enhance interactions with water by promoting hydrogen bonding and increasing water solubility." +} +{ + "content": "The synthesis of hydrophilic polymers involved using monomers such as polyethylene glycol diacrylate and sulfopropyl acrylate potassium salt, where functional groups like the ether groups in polyethylene glycol and the sulfonate groups in sulfopropyl acrylate enhance hydrophilicity by forming strong hydrogen bonds with water molecules, thereby increasing interactions with water." +} +{ + "content": "" +} +{ + "content": "A variety of polymers like surface-active, zwitterionic, polysaccharides, and hydrophilic polymers such as polyethylene glycol, which contain functional groups that enhance their hydrophilicity, are used to synthesize functional polymer coatings and brushes, with these functional groups improving interactions with water by providing polar regions that can hydrogen bond with water molecules." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The hydrophilic monomers used for synthesizing super-hydrophilic polymers include acrylic acid, poly(ethylene glycol) monomethacrylate, and 2-(methacryloyloxy) ethyl phosphorycholine, which enhance hydrophilicity through functional groups such as carboxylic acid (-COOH) in acrylic acid and ethylene glycol units (-O-), enabling strong hydrogen bonding and dipole interactions with water, thereby promoting water absorption and spreading.", +} +{ + "content": "" +} +{ + "content": "The monomer 2-Methacrylatoethyl trimethyl ammonium chloride contains a quaternary ammonium group that enhances the hydrophilicity of corresponding polymers due to its positive charge, which facilitates strong ionic interactions with water." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "Hydrophilic polymers can be synthesized using monomers such as acrylamide (AAm), acrylic acid (AA), N,N-dimethylacrylamide (DMAA), N-vinylpyrrolidone (VP), and hydroxyethyl methacrylate (HEMA), which contain functional groups like –COOH, –NH2, and –OH that enhance hydrophilicity through hydrogen bonding and ionic interactions with water, thereby facilitating water absorption and improving antifouling properties.", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include acrylic acid, acrylamide, N,N-dimethylacrylamide, N-vinylpyrrolidone, and hydroxyethyl methacrylate, which contain functional groups such as carboxylic (-COOH) and hydroxyl (-OH) that enhance hydrophilicity by enabling hydrogen bonding with water molecules, thus increasing the interaction and affinity of the polymers with water." +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include Chitosan (CHI), which contains amino (-NH2) and hydroxyl (-OH) functional groups, and Carboxymethyl cellulose (CMC), which has carboxyl (-COOH) and hydroxyl (-OH) groups; these functional groups enhance hydrophilicity by increasing hydrogen bonding capacity and enabling strong interactions with water molecules, contributing to the overall water affinity of the resulting polymers." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include acrylamide (AAm) and poly(2-acrylamide-2-methylpropane sulfonic acid sodium salt) (PNaAMPS), where functional groups such as amide and sulfonic acid enhance hydrophilicity through strong interactions with water molecules via hydrogen bonding and ionic interactions, respectively." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include 2-Acrylamide-2-methylpropane sulfonic acid sodium salt (NaAMPS) and Acrylamide (AAm), where the sulfonic acid group in NaAMPS and the amide group in AAm enhance the hydrophilicity of the corresponding polymers by promoting strong interactions with water through hydrogen bonding and ionic interactions, leading to increased water absorption and improved swelling properties." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include polyvinyl alcohol (PVA) and 3-(Trimethoxysilyl) propyl methacrylate (TPM), where functional groups such as hydroxyl (-OH) in PVA and methoxy (-OCH3) in TPM enhance hydrophilicity by increasing hydrogen bonding interactions with water molecules, facilitating water absorption and retention in the polymer matrix." +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as PVP (polyvinylpyrrolidone), which contains the pyrrolidone functional group that enhances hydrophilicity through strong hydrogen bonding interactions with water, and PETRA (polymer of ethylene glycol and trimethylolpropane), which consists of acrylate functional groups that, when crosslinked, also improve the interaction with water." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The hydrophilic polymers were synthesized using monomers such as 2-(Dimethylamino) ethyl methacrylate (DMAEMA), which contains a dimethylamino group that enhances hydrophilicity through strong hydrogen bonding with water, and 2-(Methacryloyloxy) ethyl dimethyl-(3-sulfopropyl)ammonium hydroxide (SBMA), which has a zwitterionic nature due to the presence of a sulfonic acid group, thereby increasing interactions with water molecules through ionic interactions and dipole interactions.", +} +{ + "content": "N-Hydroxyethylacrylamide contains a hydroxyl (-OH) functional group that enhances hydrophilicity by forming hydrogen bonds with water, while quaternary ammonium groups can increase solubility in water due to their charged nature, allowing for stronger ionic interactions with water molecules." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers, such as 2-(Dimethylamino)ethyl methacrylate (DMAEMA), N-(2-hydroxyethyl) acrylamide (HEAA), and 2-Aminoethyl methacrylate hydrochloride (AEMA), contain functional groups like amino (-NH2), hydroxyl (-OH), and quaternary ammonium groups, which enhance the hydrophilicity of the corresponding polymers by promoting hydrogen bonding and ionic interactions with water molecules." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include carboxylic acid groups (COOH) and hydroxyl groups (OH), which enhance hydrophilicity by forming hydrogen bonds with water, thereby increasing the interaction with the solvent and improving the polymer's affinity for water." +} +{ + "content": "The synthesis of hydrophilic polymers involves using monomers such as N-(2-hydroxyethyl)acrylamide (HEAA), which contains hydroxyl groups that enhance hydrophilicity and provide strong resistance to bacterial attachment, and glycidyl methacrylate (GMA), where the presence of these hydroxyl groups improves hydration and hemocompatibility, thereby facilitating interactions with water through hydrogen bonding.", +} +{ + "content": "The QAC monomer, derived from the quaternization of 2-(dimethylamino)ethyl methacrylate, contains a quaternary ammonium functional group that enhances the hydrophilicity of the polymer by facilitating ionic interactions with water, while the N-hydroxyethylacrylamide (HEAA) monomer possesses a hydroxyl group that increases hydrophilicity through hydrogen bonding with water molecules." +} +{ + "content": "" +} +{ + "content": "The hydrophilic polymers were synthesized using monomers such as N-(2-hydroxyethyl)acrylamide (HEAA) which contains hydroxyl groups that enhance hydrophilicity, improving hydration and resistance to bacterial adhesion, while poly(acrylic acid) and zwitterionic peptides, which feature functional groups that interact favorably with water, also contribute to the superhydrophilicity of the resulting materials by forming strong hydrogen bonds with water molecules." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include QAC, which contains quaternary ammonium functional groups that enhance hydrophilicity through electrostatic interactions with water, and N-hydroxyethylacrylamide (HEAA), which has hydroxyl groups that form hydrogen bonds with water, thereby improving water affinity." +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The synthesis of hydrophilic polymers utilizes monomers containing functional groups such as carboxyl groups and sulfuric acid groups, which enhance hydrophilicity by allowing for ionic interactions and increasing solubility in water, leading to improved dispersibility in aqueous systems." +} +{ + "content": "The monomers 2-(cyclohexylamino)-ethanesulfonic acid and 3-(cyclohexylamino)-propanesulfonic acid contain sulfonic acid functional groups, which enhance the hydrophilicity of the corresponding polymers by providing strong ionic interactions with water molecules, thereby increasing their solubility and compatibility in aqueous environments.", +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as 2-(cyclohexylamino)-ethanesulfonic acid and 3-(cyclohexylamino)-propanesulfonic acid, which contain sulfonate groups that enhance hydrophilicity through strong ionic interactions with water, leading to increased water dispersibility and improved formulation processes." +} +{ + "content": "The synthesis of hydrophilic polymers utilizes monomers such as 2-(cyclohexylamino)-ethanesulfonic acid (CHES) and 3-(cyclohexylamino)-propanesulfonic acid (CAPS), which contain sulfonic acid functional groups that enhance hydrophilicity through their ability to form strong ionic bonds and hydrogen bonds with water molecules, leading to increased interaction with water." +} +{ + "content": "The synthesized hydrophilic polymers utilize sulfonate groups and ethylene oxide units, which enhance their hydrophilicity by increasing the interaction with water through increased ionic and hydrogen bonding capabilities.", +} +{ + "content": "" +} +{ + "content": "Monomers such as 3-(cyclohexylamino)-propanesulfonic acid (CAPS) and 2-(cyclohexylamino)-ethanesulfonic acid (CHES) contain sulfonate groups, which enhance the hydrophilicity of the resulting polymers by introducing polar sulfonic acid functional groups that facilitate strong hydrogen bonding and ionic interactions with water molecules." +} +{ + "content": "The monomer used in the synthesis of hydrophilic polymers is 2-methylaminoethanesulfonic acid (methyltaurine), which contains a sulfonic acid functional group that enhances hydrophilicity by promoting strong ionic interactions with water." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include 2-(cyclohexylamino)-ethanesulfonic acid and 3-(cyclohexylamino)-propanesulfonic acid, which possess sulfonate groups that enhance hydrophilicity by promoting strong ionic interactions with water molecules through hydrogen bonding and electrostatic interactions." +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The monomer structures used for synthesizing hydrophilic polymers include hydroxyethyl methacrylate (HEA), which contains a hydroxyl functional group that enhances hydrophilicity through hydrogen bonding interactions with water, facilitating strong intermolecular interactions with the water molecules." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The copolymers were synthesized from HEA (hydroxyethyl acrylate), which contains a hydroxyl functional group that enhances hydrophilicity through hydrogen bonding with water, and 4-BP acrylate, which contributes to the overall polymer structure, while MMA (methyl methacrylate) is less hydrophilic and does not significantly enhance water interactions." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "The hydrophilic monomer used in the synthesis of the copolymers is hydroxyethyl acrylate (HEA), which contains hydroxyl (-OH) functional groups that enhance hydrophilicity by increasing water adsorption capability due to their ability to form hydrogen bonds with water molecules." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include 2-(dimethylamino)ethyl methacrylate (DMAEMA), N-vinylpyrrolidone (NVP), and methyl methacrylate (MMA), which contain functional groups such as dimethylamino and carbonyl groups that enhance hydrophilicity by facilitating hydrogen bonding and dipole interactions with water, leading to improved water absorption and antifogging properties in the resulting polymers." +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include DMAEMA, N-vinylpyrrolidone, and EGDMA, where functional groups such as amines and carbonyls enhance the hydrophilicity by promoting hydrogen bonding with water molecules." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include DMAEMA, which contains a quaternary ammonium group enhancing hydrophilicity, and NVP, which has a pyrrolidinone ring that contributes to increased water interaction, making the resulting terpolymer more hydrophilic due to the presence of polar functional groups that interact favorably with water molecules.", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing the hydrophilic polymers include DMAEMA and NVP, where the NVP monomer contains a functional group that enhances hydrophilicity, improving water interactions due to its polar nature that facilitates hydrogen bonding with water molecules." +} +{ + "content": "The monomer structures used for synthesizing hydrophilic polymers include poly(ethylene glycol) (PEG) and surface active agents like Tween 20, which possess functional groups such as hydroxyl groups (-OH) that enhance hydrophilicity by promoting interactions with water through hydrogen bonding.", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include 2-hydroxyethyl methacrylate (2-HEMA) possessing a hydroxyl functional group that enhances hydrophilicity by forming hydrogen bonds with water, and sorbitan monolaurate (Tween 20) which contains multiple hydroxyl groups that also promote strong interactions with water through hydrogen bonding." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include 2-acrylamide-2-methylpropane sulfonic acid (AMPS), which has a sulfonic acid functional group enhancing hydrophilicity, and the hydroxyl groups from 3-(trimethoxysilyl)propyl-2-methyl-2-methacrylate (MPS) and tetraethylorthosilicate (TEOS), with hydroxyl groups providing strong hydrogen bonding interactions with water, allowing water to penetrate and swell the film.", +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include 2-Acrylamido-2-methylpropane sulfonic acid (AMPS) and acrylic acid (AA), which contain sulfonic acid and carboxylic acid functional groups, respectively, that enhance hydrophilicity by increasing hydrogen bonding and ionic interactions with water." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers included acrylic acid (AA), 2-hydroxyethyl acrylate (HEA), and 2-acrylamido-2-methylpropanesulfonic acid (AMPS), which contain functional groups such as carboxylic acid (from AA), hydroxyl (from HEA), and sulfonic acid (from AMPS) that enhance the hydrophilicity of the corresponding polymers by facilitating strong hydrogen bonding and ionic interactions with water molecules." +} +{ + "content": "The hydrophilic polymers were synthesized using monomers such as acrylic acid (AA), hydroxyethyl acrylate (HEA), 2-acrylamido-2-methylpropane sulfonic acid (AMPS), methacryloxyethyltrimethyl ammonium chloride (MPS), and trimethylolpropane triacrylate (15EO-TMPTA), which contain functional groups such as carboxyl (-COOH), hydroxyl (-OH), sulfonic (-SO3H), and quaternary ammonium groups that enhance hydrophilicity by increasing hydrogen bonding and ionic interactions with water.", +} +{ + "content": "" +} +{ + "content": "The text discusses the use of acid functional monomers such as acrylic acid or methacrylic acid in photoresists, which enhance hydrophilicity through their carboxylic acid groups that facilitate hydrogen bonding and ionic interactions with water, thereby increasing the water solubility and dispersibility of the resulting polymers." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include those with one or more functional groups that enhance hydrophilicity by increasing interactions with water through mechanisms such as swelling or dissolving in water at normal temperatures." +} +{ + "content": "Monomers or oligomers with free hydroxyl (-OH), carboxyl (-COOH), ester (-COO-R), and aminyl (-NH2 or -NHR) functional groups enhance hydrophilicity by increasing the ability of the resulting polymers to interact with water through hydrogen bonding and ionic interactions.", +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers with functional groups such as isocyanates, alkyleneoxy groups, aryleneoxy groups, and base cleavable groups like esters and carbonates, which enhance hydrophilicity by increasing interactions with water through hydrogen bonding and creating a hydrophilic polymer backbone.", +} +{ + "content": "Monomers used for synthesizing hydrophilic polymers include acrylic anhydride, methacrylic anhydride, and (meth)acrylate end groups, containing functional groups such as carboxylic acids, sulfonic acids, phosphonic acids, and phenols that enhance hydrophilicity by forming hydrogen bonds and ionic interactions with water, thereby increasing water solubility and compatibility of the polymers." +} +{ + "content": "The text mentions the use of hydroxyl, carboxyl, and aminyl functional groups that enhance the hydrophilicity of the corresponding polymers, and these functional groups increase interactions with water by forming hydrogen bonds and ionic interactions, contributing to solubility in alkaline solutions." +} +{ + "content": "The monomer structures used for synthesizing hydrophilic polymers include methacrylic acid, which has a carboxylic acid functional group that enhances hydrophilicity, and methyl methacrylate, which is less hydrophilic, but when functionalized with polypropoxylated hydroxypropylmethacrylate moieties, introduces additional hydroxyl groups that increase the interaction with water through hydrogen bonding.", +} +{ + "content": "The synthesis involved polypropoxylated hydroxypropylmethacrylate, which contains hydroxyl functional groups that enhance hydrophilicity by forming hydrogen bonds with water molecules, thus improving water interaction and absorption." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include 2-hydroxyethyl methacrylate, which features a hydroxyl functional group, and methacrylic acid, which contains a carboxylic acid functional group, both of which enhance the hydrophilicity of the corresponding polymers by increasing the ability to form hydrogen bonds with water molecules, thereby improving interactions with water." +} +{ + "content": "The hydroxyl groups of the 2-hydroxyethyl methacrylate moiety enhance the hydrophilicity of the corresponding polymer by increasing hydrogen bonding interactions with water, while the isocyanate groups of the isophorone diisocyanate contribute to the formation of functionalized pendent groups that further improve water interaction." +} +{ + "content": "The synthesis involves monomers such as polyalkoxylated hydroxyalkyl (meth)acrylate and hydroxyalkyl (meth)acrylate, which contain functional groups like hydroxyl, carboxyl, and amino groups, enhancing hydrophilicity through hydrogen bonding and polar interactions with water." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include acrylic acid, which contains carboxyl groups that enhance hydrophilicity by facilitating hydrogen bonding with water, and hydroxybutyl imidazole, which has hydroxyl groups that improve interactions with water through similar hydrogen bonding.", +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "The synthesis involved the use of poly(ethoxylate-b-caprolactone) monomethacrylate oligomer, which contains ethoxylate groups that enhance the hydrophilicity of the resulting polymer through the formation of hydrogen bonds with water, thereby fostering better solubility and interaction with the aqueous environment." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include 2-hydroxyethyl methacrylate and methacrylic acid, which possess hydroxyl (-OH) and carboxylic acid (-COOH) functional groups, respectively, enhancing the hydrophilicity of the corresponding polymers through hydrogen bonding and ionic interactions with water molecules.", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include hydroxyalkyl (meth)acrylate, hydroxy polyalkyleneoxide (meth)acrylate, (meth)acrylic acid, and hydroxy poly opened-ring lactone polyalkylene oxide (meth)acrylate, which contain functional groups such as hydroxy and carboxyl that enhance hydrophilicity by forming hydrogen bonds with water molecules, thereby increasing water absorption and interaction." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include hydroxyalkyl (meth)acrylates, hydroxy polyalkylene oxide (meth)acrylates, (meth)acrylic acid, substituted ethylene monomers, and nitrogen-containing compounds, with functional groups such as hydroxyl groups and carboxyl groups enhancing the hydrophilicity of the polymers by providing sites for hydrogen bonding and ionic interactions with water, thus increasing their solubility in aqueous environments." +} +{ + "content": "", +} +{ + "content": "The monomers used for synthesizing the hydrophilic polymers include methacrylic acid, which contains a carboxylic acid functional group that enhances hydrophilicity through hydrogen bonding with water, and poly(ethoxylate-b-caprolactone) monomethacrylate, which has ethoxy groups that increase affinity for water, facilitating interactions through dipole-dipole interactions and enhancing solubility in aqueous environments." +} +{ + "content": "" +} +{ + "content": "The copolymer synthesized from methacrylic acid, methyl methacrylate, and 2-hydroxyethyl methacrylate includes functional groups such as carboxylic acid (from methacrylic acid) and hydroxyl groups (from 2-hydroxyethyl methacrylate), which enhance its hydrophilicity by promoting hydrogen bonding and ionic interactions with water, thus enhancing its interactions with water." +} +{ + "content": "" +} +{ + "content": "The copolymer synthesized contains methacrylic acid with carboxyl groups, which enhance hydrophilicity, as well as poly(ethoxylated) monomethacrylate with ethoxy groups, both of which improve interactions with water through hydrogen bonding and increased solubility.", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include methacrylic acid, which contains carboxylic acid functional groups, and 2-hydroxyethyl methacrylate, which has hydroxyl functional groups; these functional groups enhance hydrophilicity by increasing the ability of the polymer to interact with water through hydrogen bonding and ionic interactions." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers included methacrylic acid with carboxylic acid functional groups, methyl methacrylate, and poly(ethoxylated) monomethacrylate, where the carboxylic acid groups in methacrylic acid enhance hydrophilicity through increased hydrogen bonding with water, while poly(ethoxylated) monomethacrylate contains ethylene glycol units that further improve water interactions via their hydrophilic ether linkages." +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as 2-hydroxyethyl methacrylate and methacrylic acid which contain hydroxyl (-OH) and carboxylic acid (-COOH) functional groups, respectively, that enhance hydrophilicity by forming hydrogen bonds with water molecules, thus facilitating better water interactions.", +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include hydroxyl alkyl (meth)acrylate, hydroxy polyalkylene oxide (meth)acrylate, and (meth)acrylic acid, where functional groups such as hydroxyl and carboxylic acid enhance hydrophilicity by forming hydrogen bonds with water molecules, increasing water solubility and interaction.", +} +{ + "content": "The monomer structures used for synthesizing hydrophilic polymers include phosphate groups, which enhance hydrophilicity through their polar nature that promotes interactions with water, thereby increasing the affinity of the polymers for hydration and improving their overall water interaction.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "Monomers used for synthesizing hydrophilic polymers include poly(vinyl alcohol) (PVA) and poly(acrylic acid) (PAA), which contain hydroxyl (-OH) and carboxyl (-COOH) functional groups, respectively; these functional groups enhance hydrophilicity by engaging in hydrogen bonding with water, thereby increasing the affinity of the polymers for moisture and improving water retention." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include poly(dimethylaminoethyl methacrylate) (PDMAEMA) and poly(sulfobetaine methacrylate) (PSBMA), where PDMAEMA enhances interactions with water through hydrogen-bond and electrostatic interactions due to its amine functional groups, and PSBMA improves hydrophilicity through its zwitterionic nature, which allows it to regulate water interactions and may lower the freezing point of water." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include 2-(dimethylamino)ethyl methacrylate (DMAEMA) and sulfobetaine methacrylate (SBMA), where the zwitterionic functional groups in SBMA enhance interactions with water through stronger hydrogen bonding compared to other polymers like PEG." +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include poly(ethylene glycol) (PEG), polyacrylic acid, polyvinylpyrrolidone, and hydroxethylmethacrylate (HEMA), with functional groups such as hydroxyl and quaternary ammonium groups enhancing hydrophilicity by increasing the polar character and enabling hydrogen bonding interactions with water molecules, thus facilitating the formation of a continuous water film and reducing fogging.", +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as sulfobetaine methacrylate (SBMA) and 2-hydroxyethyl methacrylate (HEMA), which contain functional groups like sulfonate and hydroxy groups that enhance hydrophilicity by promoting hydrogen bonding and ion-dipole interactions with water.", +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include polyethylene glycol, poly(vinyl alcohol), polyvinyl acetate, and polyvinylpyrrolidone, which contain functional groups that enhance hydrophilicity, such as hydroxyl (-OH) or ether (-O-) groups, allowing for strong interactions with water through hydrogen bonding and increased surface wettability." +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as polyvinylpyrrolidone (PVP) which contains a pyrrolidone group that enhances hydrophilicity through its ability to form hydrogen bonds with water, thereby increasing interactions and affinity for moisture.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The hydrophilic polymers synthesized for antifog hard coatings incorporate functional groups such as hydroxy, carboxy, ammonium, and sulfo groups, which enhance the hydrophilicity through increased polarity and the ability to form hydrogen bonds with water, promoting better interactions and a continuous water layer on surfaces.", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include tetraethylene glycol (OEG), which contains hydroxy functional groups, and carboxy-functionalized rod-like polySQ that includes carboxylic acid functional groups; these functional groups enhance hydrophilicity by promoting hydrogen bonding and electrostatic interactions with water molecules." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The functional groups Si–O–Si and Si–OH present on the surface of mesoporous silica coatings enhance hydrophilicity by providing high surface energy and facilitating interactions with water through hydrogen bonding, leading to superamphiphilic properties.", +} +{ + "content": "" +} +{ + "content": "The UV-curable PUA is prepared using 4-hydroxybutyl acrylate, which contains a hydroxyl functional group that enhances hydrophilicity through hydrogen bonding interactions with water, and acrylic acid, which has a carboxyl functional group facilitating ionic interactions with water." +} +{ + "content": "The synthesis of hydrophilic polymers involves vinyl monomers such as N-vinylpyrrolidone (NVP), which contains a lactam functional group that enhances hydrophilicity through strong hydrogen bonding interactions with water molecules, consequently improving water absorption and polymer swelling properties." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include 1-vinyl-2-pyrrolidone (NVP), which contains a lactam functional group that enhances hydrophilicity by forming hydrogen bonds with water, and thus improving interaction with water.", +} +{ + "content": "Hydrophilic polysaccharides such as chitosan, alginate, hyaluronic acid, and carboxymethyl cellulose contain functional groups that enhance hydrophilicity through their ability to form hydrogen bonds with water, thus increasing interactions with water and leading to long-lasting antifog coatings." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesis involved Dimethylaminoethyl methacrylate (DMAEMA), which contains a dimethylamino group that enhances the hydrophilicity of the corresponding polymer by increasing interactions with water through hydrogen bonding and ionic interactions.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The monomer used for synthesizing the hydrophilic polymer 14QAS includes dimethylaminoethyl methacrylate (DMAEMA), which possesses functional groups such as the dimethylamino group (-N+(CH3)2) and the methacrylate group (-C(=O)O-), enhancing hydrophilicity through ionic and polar interactions with water molecules, allowing for increased water solubility and hydration." +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include 4-Hydroxybutyl acrylate (HBA), acrylic acid, and poly(ethylene glycol) methyl ether acrylate (PEGA), with functional groups such as hydroxyl (-OH) in HBA and carboxylic acid (-COOH) in acrylic acid that enhance hydrophilicity by forming hydrogen bonds and ion-dipole interactions with water molecules, leading to increased polymer-water interactions." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The hydrophilicity of the polymers synthesized in the study is enhanced by incorporating amino-terminated urea-pyrimidinone monomers (UPy-D400), which contain functional groups capable of forming quadruple hydrogen bonds that interact with water through self-association and directional binding." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The hydrophilic monomer 2-acrylamide-2-methylpropane sulfonic acid (AMPS) enhances the hydrophilicity of the film through the introduction of sulfonic acid functional groups, while hydroxyl groups from 3-(trimethoxysilyl)propyl-2-methyl-2-methacrylate (MPS) and tetraethylorthosilicate (TEOS) further increase interactions with water by allowing water to penetrate and swell the film, contributing to hydrophilicity and mechanical properties.", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include acrylic acid (AA), 2-hydroxyethyl acrylate (HEA), and 2-acrylamido-2-methylpropane sulfonic acid (AMPS), which feature carboxylic acid, hydroxyl, and sulfonic acid functional groups respectively, enhancing hydrophilicity by increasing water interactions through hydrogen bonding and ionic interactions." +} +{ + "content": "The hydrophilic polymers are synthesized using monomers that contain functional groups such as carboxylic acid (from AA), hydroxyl (from HEA), and sulfonate (from AMPS), which enhance the polymers' hydrophilicity by providing polar interactions and increasing water affinity through hydrogen bonding and ionic interactions.", +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include propylene glycol (PG) and dipropylene glycol (DPG), which contain hydroxyl functional groups that enhance hydrophilicity by forming hydrogen bonds with water, thus increasing water interactions and promoting better solubility in aqueous environments." +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include dimethylol propionic acid (DMPA) and hydroxyethyl methyl acrylate (HEMA), where the carboxyl group in DMPA enhances hydrophilicity, promoting interactions with water through hydrogen bonding and ionic interactions, and the hydroxyl group in HEMA improves water affinity due to its ability to form hydrogen bonds with water molecules." +} +{ + "content": "" +} +{ + "content": "The functional groups in the monomers, such as the hydroxyl group in hydroxyethyl methyl acrylate (HEMA) and the carboxylic acid group in dimethylpropionic acid (DMPA), enhance the hydrophilicity of the corresponding polymers by allowing for strong hydrogen bonding and ionic interactions with water, thereby facilitating water absorption and retention." +} +{ + "content": "The synthesis of hydrophilic polymers involved monomers with functional groups such as carboxyl groups from DMPA and hydroxyl groups from HEMA, which enhance hydrophilicity by promoting hydrogen bonding and ionic interactions with water." +} +{ + "content": "The text does not provide specific information about the monomer structures used for synthesizing hydrophilic polymers or details about the functional groups that enhance hydrophilicity.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers includes the use of monomers with functional groups such as hydrophilic quaternary ammonium groups, which enhance hydrophilicity by enabling better interactions with water through hydrogen bonding and ionic interactions.", +} +{ + "content": "The monomers used for synthesizing the hydrophilic polymers include 2-(Dimethylamino)ethyl methacrylate (DMAEMA) and acrylic acid (AA), both of which contain functional groups such as amino groups (-N(CH3)2) in DMAEMA and carboxylic acid groups (-COOH) in AA that enhance hydrophilicity by creating strong hydrogen bonding interactions with water molecules, thereby increasing the affinity of the resulting polymers for water." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The text mentions monomers used to synthesize hydrophilic polymers such as PLGA, PU, PEG, PDA, PPy, PVA, and PANI, which contain functional groups that enhance hydrophilicity through mechanisms like hydrogen bonding and electrostatic interactions, thus improving interactions with water." +} +{ + "content": "Hydrophilic functionalized PEG, specifically PEG-NH2, enhances the hydrophilicity of corresponding polymers through its amino functional group, which can form hydrogen bonds with water molecules, thus improving water interactions and solubility, while other hydrophilic polymers like PLL and PDDA contribute similar effects by enhancing dispersity in water and passing the lone-pair electrons of phosphorus to facilitate interactions with water." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The hydrophilic polymers used in the synthesis of BP/polymers include PVA (polyvinyl alcohol) and Pluronic F127, both of which contain hydroxyl functional groups that enhance the hydrophilicity of the resulting polymers, as these functional groups facilitate strong hydrogen bonding and increase interactions with water." +} +{ + "content": "" +} +{ + "content": "Hydrophilic polymers are synthesized using monomers that include poly(ethylene glycol) (PEG) segments and poly(2-(dimethylamino)ethyl methacrylate) (DMAEMA) with methacrylate, where functional groups like ether (-O-) in PEG enhance hydrophilicity by forming hydrogen bonds with water, and amino (-NH-) in DMAEMA promotes ionic interactions with water; these interactions help in rapidly absorbing water from the surrounding, preventing the formation of discrete water droplets." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include 2-(dimethylamino)ethyl methacrylate (DMAEMA), which contains a dimethylamino group that enhances hydrophilicity through strong hydrogen bonding with water, while ethylene glycol dimethacrylate (EGDMA) contributes to hydrophilicity through its ether oxygen atoms that also facilitate interactions with water.", +} +{ + "content": "" +} +{ + "content": "The text mentions that hydrophilic polymers can be synthesized using monomers such as TPGDA, NPG(PO)2DA, TMPTA, and others, which contain functional groups like polyether, polyol, and acrylate that enhance hydrophilicity through hydrogen bonding and ionic interactions with water." +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The monomers used in synthesizing hydrophilic polymers, particularly cellulose, are composed of repeating beta-D-glucopyranose units connected by covalent linkages between hydroxyl groups on C4 and C1 carbon atoms, and these monomers contain a high number of hydroxyl functional groups (three per anhydroglucose unit) that enhance the hydrophilicity, as hydroxyl groups are known for their affinity towards water due to their ability to form hydrogen bonds with water molecules.", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The hydroxyl groups (-OH) present on each glucose unit of the cellulose chain enhance the hydrophilicity of the corresponding polymers by forming hydrogen bonds with water, which facilitates strong interactions and increases water affinity." +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as cellulose derivatives, where functional groups like carboxymethyl, hydroxyl, and ether groups enhance the hydrophilicity of the polymers by increasing their ability to interact with water through hydrogen bonding and dipole interactions." +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "The text discusses imidazole-type PILs synthesized through in situ photopolymerization that utilize functional groups such as cationic units and anions, which enhance hydrophilicity by improving interactions with water through ionic interactions and favorable surface properties, contributing to the antimicrobial activity of the resulting polymers.", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "The synthesis involved the use of cellulose derivatives with multi-hydroxyl functional groups that enhance hydrophilicity by increasing hydrogen bonding interactions with water.", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "The functional groups that enhance the hydrophilicity of the corresponding polymers include hydroxyl groups from cellulose, which can be modified to form cellulose esters or ethers; these modifications improve the interactions with water by increasing solubility and reducing the use of organic solvents in applications such as coatings, adhesives, and biologically relevant materials." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic cellulose derivatives involves the functional groups of 2-chloro propionic acid ester and imidazolium ions, which enhance the hydrophilicity of the polymers through strong ionic interactions and hydrogen bonding with water molecules.", +} +{ + "content": "The synthesis involves cellulose 2-chloropropionate, which contains functional groups that enhance hydrophilicity, such as ester groups that interact with water through hydrogen bonding, thereby improving water absorption and overall hydrophilic properties of the resulting polymer.", +} +{ + "content": "" +} +{ + "content": "The synthesis of cationic cellulose derivatives involves the use of 2-chloropropionic acid ester as a monomer, which contains functional groups such as halides that can enhance the hydrophilicity of the resulting polymers by facilitating interaction with water through hydrogen bonding and ionic interactions.", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "The hydrophilic properties of the synthesized cellulose-based gas separation membranes are enhanced by the incorporation of cationic structures, such as 1-butyl imidazolium cation, which facilitates strong electrostatic interactions with various free ionic liquids, allowing for better water interactions and improved CO2 permeability.", +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "The synthesis involves the use of 1-butyl-imidazolium chloride and 1-butyl-3-trimethylammonium bis(trifluoromethanesulfonyl)imide salts, which contain functional groups such as imidazolium and ammonium that enhance hydrophilicity by facilitating ionic interactions and hydrogen bonding with water molecules." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "In the synthesis of hydrophilic polymers, the introduction of hydroxyl groups from cellulose enhances hydrophilicity by allowing for multiple interactions with water, while the 1-butylimidazolium group in CA-BimCl forms new peaks in NMR and FTIR, indicating its hydrophilic character due to the imidazole ring's ability to interact with water through hydrogen bonding." +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves introducing hydrophilic cationic groups onto cellulose, which contains multiple hydroxyl groups that enhance hydrophilicity, and the balance between hydrophilic and hydrophobic groups can be adjusted to modulate interfacial water, thus improving interactions with water and enabling the material to perform well in anti-fog and anti-ice applications." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves incorporating functional groups such as -NH in cellulose 1-butyl-3-methylimidazolium chloride (Cellulose-BimCl) and anionic groups from perfluorooctanoate in cellulose 1-butyl-3-methylimidazolium perfluorooctanoate (Cellulose-BimPFO), which enhance the hydrophilicity of the polymers by increasing their ability to form hydrogen bonds and ionic interactions with water." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The hydrophilic polymers synthesized include CA-CI, which enhances hydrophilicity through the introduction of the chloroacetyl group, and CA-BimCl and CA-BimX, where the presence of the imidazolium functional group and metal chlorides contribute to increased water interactions due to their polar nature.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesized hydrophilic polymer CA-BimCl incorporates 2-chloropropionic acid ester and imidazolium groups, where the hydroxyl groups of cellulose and the imidazole's nitrogen enhance the hydrophilicity through strong hydrogen bonding interactions with water.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers included PBA (polybutylene adipate), which contains hydroxyl functional groups that enhance hydrophilicity, and BDO (1,4-butanediol), which also has hydroxyl groups; these functional groups enhance interactions with water by forming hydrogen bonds, thereby increasing the polymer's affinity for water." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The functional groups identified in the synthesis of hydrophilic polymers include isocyanates, hydroxyls, and urethanes, where hydroxyl and urethane groups enhance hydrophilicity through hydrogen bonding and increased polarity, resulting in improved interactions with water." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The text does not provide specific information about the monomer structures used for synthesizing hydrophilic polymers, nor does it detail the functional groups that enhance hydrophilicity or explain how these functional groups enhance interactions with water." +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include acrylic acid (AA) and 2-hydroxyethyl methacrylate (HEMA), both of which contain functional groups such as carboxylic acid and hydroxyl groups respectively, enhancing hydrophilicity by facilitating hydrogen bonding and dipole-dipole interactions with water." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesized hydrophilic polymers included acrylate monomers such as acrylic acid (AA), hydroxyethyl methacrylate (HEMA), and sulfobetaine methacrylate (SBMA), which contain functional groups like carboxylic acid (-COOH), hydroxyl (-OH), and quaternary ammonium (-N^+(CH_3)_2CH_2CH_2SO_3^-) that enhance hydrophilicity by increasing water affinity and promoting hydrogen bonding or ionic interactions with water molecules." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The hydrophilic polymers were synthesized using the monomers acrylic acid (AA), 2-hydroxyethyl methacrylate (HEMA), and sulfobetaine methacrylate (SBMA), which contain functional groups such as carboxylic acid (-COOH), hydroxyl (-OH), and sulfonium groups that enhance hydrophilicity through their ability to form hydrogen bonds with water molecules, thereby increasing water affinity and improving interactions with the surrounding aqueous environment." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include alginate, carrageenans (λ, κ, and ι), chitosan, chondroitin sulfate, dextran, fucoidan, heparin, and poly(styrene sulfonate), which contain functional groups such as carboxyl, sulfate, and sulfonate groups that enhance hydrophilicity by increasing interactions with water through hydrogen bonding and ionic interactions." +} +{ + "content": "The text discusses peptide-based hydrogels emphasizing that the introduction of different chemical groups (other than carboxylic acids) can enhance the self-assembly properties and therefore improve hydrophilicity through interactions with water." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} 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functional groups like hydroxyl and carbonyl that interact favorably with water molecules, thereby increasing their affinity for water." +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include glycerol esters and pentaerythritol esters, which contain hydroxyl and carboxyl functional groups that enhance the hydrophilicity of the polymers by promoting strong hydrogen bonding and interactions with water." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves acrylate monomers, such as acrylic acid, which possess functional groups that enhance hydrophilicity through the presence of hydroxyl (–OH) groups that can form hydrogen bonds with water, thereby increasing water interactions." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include polyols and polyacids, which feature functional groups such as -OH (hydroxyl) and -COOH (carboxyl), enhancing hydrophilicity through their ability to form strong hydrogen bonds with water molecules, thereby increasing the water interaction capacity of the resulting polymers.", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as polyols, which contain hydroxyl (-OH) functional groups that enhance hydrophilicity by forming hydrogen bonds with water molecules, thereby improving water interaction and solubility." +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The text discusses the use of pentaerythritol, which contains four primary hydroxyl groups that enhance the hydrophilicity of resulting polymers through increased polarity and solubility in water, leading to improved interactions with water molecules.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The monomer structures used for synthesizing hydrophilic polymers include methacrylic acid-2-hydroxyethyl (HEMA) and hydroxyl-terminated siloxane, where the hydroxyl (–OH) and carboxyl (–COOH) functional groups enhance the hydrophilicity of the corresponding polymers by forming hydrogen bonds with water, facilitating interaction and water absorption.", +} +{ + "content": "The monomer structures for synthesizing hydrophilic polymers include acrylate double bonds and allyl double bonds, which enhance hydrophilicity through functional groups that interact favorably with water, promoting hydrogen bonding and increasing the ability to absorb moisture." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The aldehyde functional group, characterized by a carbonyl group where the carbon is connected to a hydrogen atom and a hydrocarbon group, enhances hydrophilicity due to the oxygen atom in the carbonyl group being able to form hydrogen bonds with water, allowing low carbon chain aldehydes like formaldehyde and acetaldehyde to be miscible with water, although solubility diminishes with increasing carbon chain length." +} +{ + "content": "The functional groups that enhance the hydrophilicity of phenolic compounds are the hydroxyl groups directly connected to the aromatic rings, which improve interactions with water through hydrogen bonding capabilities." +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "The phenolic monomers used for synthesizing hydrophilic polymers contain hydroxyl (-OH) groups and aromatic rings that enhance hydrophilicity due to the ability of oxygen atoms in -OH groups to engage in hydrogen bonding with water molecules, thus increasing the interaction between the polymer and water." +} +{ + "content": "", +} +{ + "content": "The monomer structures used for synthesizing hydrophilic polymers include o,o'-dihydroxy diphenylmethane, which contains hydroxyl groups that enhance hydrophilicity by forming hydrogen bonds and increasing water interactions." +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves amino compounds containing the amino functional group (-NH2) which enhances hydrophilicity and promotes interactions with water due to the ability of amino groups to form hydrogen bonds, and the use of aldehydes such as formaldehyde, which contains hydroxymethyl functional groups (-CH2OH) that also contribute to hydrogen bonding, further enhancing water affinity." +} +{ + "content": "", +} +{ + "content": "The text describes hydrophilic polymers synthesized using monomers such as urea, which contains an amine functional group (-NH2) that enhances hydrophilicity by forming hydrogen bonds with water, and melamine, which also contains multiple amine groups that improve water interactions and solubility.", +} +{ + "content": "The synthesis of hydrophilic polymers utilizes alcohols such as methanol, ethanol, isopropanol, and butanol, which possess hydroxyl (-OH) functional groups that enhance hydrophilicity by forming hydrogen bonds with water molecules, thereby improving their solubility in aqueous environments." +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include urea, which contains a carbonyl group that enhances hydrophilicity through its polar oxygen atom, providing good adhesion to substrates and increasing layer adhesion in coatings.", +} +{ + "content": "" +} +{ + "content": "The hydrophilic polymers mentioned in the text involve various amino resins synthesized from monomers with hydroxymethyl groups, which enhance water solubility through hydrogen bonding and dipole-dipole interactions with water molecules, thereby increasing their interaction with water and improving their hydrophilicity." +} +{ + "content": "The hydrophilic polymers discussed in the text are synthesized using monomers such as formaldehyde and methanol, which contain hydroxymethyl and methoxy functional groups that enhance the hydrophilicity of the resulting polymers by forming hydrogen bonds with water molecules, thereby improving water interaction and solubility.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The amino resin structures contain functional groups such as hydroxymethyl and carboxyl groups, which enhance the hydrophilicity of the polymers through their ability to form hydrogen bonds with water, while the hydroxymethyl and ureido groups promote crosslinking and catalyze reactions that improve water interaction.", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The text excerpt includes information about monomers such as acrylic acid butyl ester and hydroxypropyl ester, which possess functional groups like carboxylic acids and hydroxyl groups that enhance the hydrophilicity of the corresponding polymers by forming hydrogen bonds with water, thereby increasing interactions." +} +{ + "content": "The polyester resin synthesized from polyols and polyacids contains hydroxyl and carboxyl groups that enhance hydrophilicity by providing sites for hydrogen bonding with water molecules, thus increasing the affinity of the polymers for water." +} +{ + "content": "The hydrophilic polymers synthesized from acrylic resins contain hydroxyl and carboxyl functional groups, which enhance interactions with water by increasing hydrogen bonding capability and polarity, leading to improved water affinity." +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as hydroxylpropyl acrylate, which contains hydroxy functional groups that enhance hydrophilicity by promoting hydrogen bonding and van der Waals interactions with water.", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The hydrophilic polymers are synthesized using polyols that contain hydroxyl (–OH) functional groups, which enhance the hydrophilicity of the polymers by increasing their ability to interact with water due to the polar nature of the hydroxyl groups, allowing for hydrogen bonding with water molecules." +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "The text mentions that the functional groups such as hydroxyl and carboxyl groups enhance the hydrophilicity of the corresponding polymers synthesized through esterification and condensation reactions.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The commonly used hydrophilic polymers include saturated polyester resins that contain hydroxyl functional groups which enhance hydrophilicity, as these hydroxyl groups can form hydrogen bonds with water molecules, increasing the polymer's affinity for water." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves acrylate or methacrylate monomers, which contain functional groups such as acrylic acid and ester groups that enhance hydrophilicity by increasing the number of hydrogen bonds and dipole interactions with water molecules.", +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers utilizes monomers like acrylic acids and methacrylic acids which contain functional groups such as hydroxyl, carboxyl, epoxy, and amino that enhance hydrophilicity and improve water interactions by increasing polarity and promoting hydrogen bonding with water molecules." +} +{ + "content": "The text does not provide any specific information about the structures of monomers used for synthesizing hydrophilic polymers, the functional groups that enhance hydrophilicity of the corresponding polymers, or explanations of how these functional groups enhance interactions with water." +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "The text does not provide specific monomer structures used for synthesizing hydrophilic polymers; however, it mentions that the introduction of functional groups such as hydroxyl groups and carboxyl groups enhances the hydrophilicity of acrylic resins, with the hydroxyl groups providing crosslinking sites for film formation and the carboxyl groups increasing polarity, which together improve interactions with water by enabling hydrogen bonding and enhancing solubility." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include 2-hydroxyethyl methacrylate and 2-hydroxypropyl methacrylate, both containing hydroxyl functional groups that enhance hydrophilicity by forming hydrogen bonds with water molecules, thereby increasing the interaction between the polymer and water." +} +{ + "content": "The synthesis of hydrophilic polymers involves using monomers such as acrylic acid, methacrylic acid, and hydroxypropyl acrylate, which contain functional groups like carboxyl groups (-COOH) and hydroxyl groups (-OH), that enhance hydrophilicity by forming hydrogen bonds with water, thereby improving water absorption and interaction." +} +{ + "content": "The synthesis involves using acrylic acid and hydroxypropyl methacrylate, both of which contain hydroxyl functional groups that enhance the hydrophilicity of the resulting polymers by promoting strong hydrogen bonding with water molecules." +} +{ + "content": "" +} +{ + "content": "The hydrophilic polymers are synthesized using monomers containing functional groups such as carboxyl groups, sulfonic groups, ether linkages, and hydroxyl groups, which enhance hydrophilicity by providing hydrophilic groups and water solubility, thereby increasing interactions with water.", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include acrylic acid, which contains carboxyl groups that enhance the hydrophilicity of the polymers; these carboxyl groups increase interactions with water through their ability to form hydrogen bonds and salts in aqueous solutions." +} +{ + "content": "The synthesis of hydrophilic polymers employed monomers such as acrylic acid, methacrylic acid and their esters, where functional groups like carboxylic acid (-COOH) in acrylic acid enhance hydrophilicity by forming hydrogen bonds with water molecules, thus increasing their interactions with water." +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "Hydrophilic polymers can be synthesized using monomers such as methacrylic acid, maleic acid, fumaric acid, and acrylic amide, which contain functional groups like hydroxyl, carboxyl, and amide groups that enhance hydrophilicity by forming hydrogen bonds with water molecules." +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as acrylic acid (AA) and ethyl acrylate (EA), which contain functional groups like carboxylic acid (-COOH) in AA that enhance hydrophilicity through strong hydrogen bonding with water, leading to increased water solubility and better interaction with aqueous environments." +} +{ + "content": "" +} +{ + "content": "The monomers used in synthesizing hydrophilic polymers include acrylic acid, methacrylic acid, vinyl acetate, and various acrylic esters, where the carboxyl (-COOH) and hydroxyl (-OH) functional groups in these monomers enhance the hydrophilicity by establishing strong hydrogen bonding and ionic interactions with water molecules, promoting better water retention and swelling of the resulting polymers." +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include acrylate monomers such as hydroxyethyl acrylate and butyl acrylate, which contain hydroxyl (-OH) and carboxyl (-COOH) functional groups that enhance hydrophilicity by increasing hydrogen bonding interactions with water molecules." +} +{ + "content": "The text mentions the use of acrylic acid and hydroxyethyl acrylate as monomers in the synthesis of hydrophilic polymers, where the carboxylic acid group in acrylic acid and the hydroxyl group in hydroxyethyl acrylate enhance hydrophilicity by increasing hydrogen bonding and dipole-dipole interactions with water." +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers with functional groups such as carboxyl (-COOH) and hydroxyl (-OH), which enhance the hydrophilicity of the polymers by creating strong polar interactions with water through hydrogen bonding and ionic interactions, facilitating improved water absorption and interaction.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "双酚A和环氧氯丙烷是用于合成环氧树脂的二官能度化合物,其中双酚A的苯酚羟基功能团与水具有强烈的氢键作用,而环氧氯丙烷的环氧基团则具有亲核特性,能够与水分子形成强相互作用,从而提高聚合物的亲水性。", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include bisphenol A and bisphenol F, with functional groups such as hydroxyl (-OH) in the bisphenols enhancing the hydrophilicity of the polymers through the formation of hydrogen bonds with water molecules, which increases water retention and solubility in the resulting hydrogels." +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "The amidoamines used for synthesizing hydrophilic polymers contain amide and amino functional groups, which enhance hydrophilicity by providing active hydrogen atoms that facilitate interactions with water and improve wetting properties." +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "The monomer structures used for synthesizing hydrophilic polymers include phenolic hydroxyl groups and tertiary amines, which enhance hydrophilicity by promoting interactions with water due to their ability to hydrogen bond and increase polarity." +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesis involves monomers such as ethylenediamine and diglycidyl ether that introduce amine (-NH2) and hydroxyl (-OH) functional groups, which enhance the hydrophilicity of the resulting polymers by forming hydrogen bonds with water and increasing their affinity for moisture." +} +{ + "content": "The synthesis of hydrophilic polymers involves the use of functional groups such as amide and hydroxyl groups, which enhance hydrophilicity by providing polar sites that enable strong interactions with water molecules, thereby improving adhesion and water replacement capabilities." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers includes the use of bisphenol A and formaldehyde, which enhance hydrophilicity due to hydroxyl (–OH) groups that promote hydrogen bonding interactions with water, increasing water affinity and thus improving the polymer’s interaction with aqueous environments." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The text mentions the presence of amino groups in the water-soluble amine curing agent EH-1 and hydroxyl groups that promote the curing reaction after solidification, with phenyl alcohol helping in film formation and enhancing the toughness of the paint film.", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The stable functional groups in hydrophilic polymers like polyurethanes include urethane linkages, which can form hydrogen bonds that enhance the polymer's interactions with water by allowing for reversible bond formation that facilitates mechanical flexibility and water retention." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers incorporates monomers such as tri-hydroxymethyl propane (TMP) which features hydroxyl functional groups that enhance hydrophilicity through the formation of hydrogen bonds with water, promoting better water interactions and reducing surface tension.", +} +{ + "content": "", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include hydroxyethyl methacrylate (HEMA), hydroxypropyl methacrylate (HPMA), hydroxyethyl acrylate (HEA), and hydroxypropyl acrylate (HPA), all of which feature hydroxyl functional groups; these hydroxyl groups enhance hydrophilicity by facilitating strong hydrogen bonding interactions with water molecules, increasing solubility and interaction with the aqueous environment." +} +{ + "content": "The text does not provide specific information about the monomer structures or functional groups that enhance the hydrophilicity of the polymers.", +} +{ + "content": "The hydrophilic polymers are synthesized from monomers containing hydroxyl (-OH) functional groups, which enhance their hydrophilicity by forming hydrogen bonds with water molecules, thereby increasing their interaction and solubility with water.", +} +{ + "content": "" +} +{ + "content": "The functional groups enhancing the hydrophilicity of the corresponding polymers include hydroxyl groups, which are capable of forming hydrogen bonds with water, thereby improving the interaction of the polymers with water.", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The text does not provide information regarding the monomer structures or functional groups that enhance the hydrophilicity of hydrophilic polymers." +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers containing functional groups such as isocyanate (–NCO) and amine (–NH2), where the presence of –NH2 enhances hydrophilicity through increased water interaction due to hydrogen bonding capabilities, thus improving the polymer's affinity for water." +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include hexamethylene diisocyanate (HDI), isophorone diisocyanate (IPDI), and xylene diisocyanate (XDI), which feature functional groups such as isocyanate (-NCO) that enhance hydrophilicity by promoting strong hydrogen bonding and polar interactions with water molecules, thereby improving the polymers' affinity for water." +} +{ + "content": "", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include polyoxypropylene polyols such as PPG, poly-tetrahydrofuran, and polycaprolactone, which feature functional groups like hydroxyl groups that enhance hydrophilicity by providing active hydrogen bonds capable of forming strong hydrogen bonds with water, thus improving water interactions and solubility.", +} +{ + "content": "The monomer structures mentioned include primary amines, specifically diaminodiphenylmethane (MOCA), which contains amino groups (-NH2) that enhance the hydrophilicity of the corresponding polymers by participating in reactions with isocyanate end groups (-NCO) to form carbamate or urea structures, thereby increasing the hydrogen bonding interactions with water through the presence of active hydrogen atoms.", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include DETDA, which has amino and hydroxyl functional groups enhancing hydrophilicity, providing increased interaction with water through hydrogen bonding, and DMTDA, which contains thioether groups that may enhance solubility and interaction with water; IPDA, with its amine functionality promotes water solubility and favorable interaction in hydrophilic environments." +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "The SPUA materials incorporate urethane groups characterized by a C=O moiety that enhances hydrophilicity, improving interactions with water due to the ability of these carbonyl groups to form hydrogen bonds.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + 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water absorption capacity of the polymers." +} +{ + "content": "", +} +{ + "content": "Monomers used for synthesizing hydrophilic polymers include acrylic hydroxyl esters and silanes with hydroxyl groups, which introduce functional groups such as hydroxyl and acrylate, thereby enhancing hydrophilicity through the formation of hydrogen bonds with water molecules.", +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include methyl methacrylate (MMA), butyl acrylate (BA), acrylic acid (AA), and siloxane monomers, where acrylic acid contains a carboxylic acid functional group that enhances hydrophilicity through its ability to form hydrogen bonds with water molecules, thereby increasing water uptake and interaction." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "The monomers used for 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+{ + "content": "The monomer 三羟甲基丙烷三缩水甘油醚 contains three hydroxyl groups and three epoxy groups, which enhance the hydrophilicity of the corresponding polymers by increasing their ability to interact with water through hydrogen bonding and polar interactions." +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "丙烯酸羟乙酯(HEA)、丙烯酸羟丙酯(HPA)、甲基丙烯酸羟乙酯(HEMA)和甲基丙烯酸羟丙酯(HPMA)具有羟基功能组,这些羟基通过形成氢键与水分子相互作用,从而增强了聚合物的亲水性并提高了对极性基材的附着力。" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include glycidyl methacrylate (GMA) with an epoxy group that enhances water interaction through increased adhesion, isobornyl methacrylate (IBOA) which has low viscosity and low skin irritation, tetrahydrofuran acrylate (THFFA) containing a polar tetrahydrofuran ring that improves adhesion, and phenoxyethyl acrylate (POEA) which, due to its high reactivity and low skin irritation, facilitates better interactions with water.", +} +{ + "content": "", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include diethylen glycol diacrylate (DEGDA) and triethylen glycol diacrylate (TEGDA), which possess functional groups such as hydroxyl (-OH) that enhance hydrophilicity by interacting with water molecules through hydrogen bonding, thus facilitating greater compatibility with water.", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The text mentions that PETA contains hydroxyl groups which enhance adhesion, potentially improving the interactions with water due to the hydrophilic nature of the hydroxyl functional groups." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + 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it describe the functional groups that enhance hydrophilicity or their interactions with water." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include acrylamide (AM) and acrylic acid (AA), both of which contain functional groups such as amide and carboxylic acid respectively, which enhance hydrophilicity through their ability to form hydrogen bonds with water, thereby increasing the interaction with water molecules.", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include acrylamide (AM), acrylic acid (AA), hydroxyl ethyl methacrylate (HEMA), and succinic acid (SA), which contain functional groups such as carboxylic groups from AA and SA, hydroxyl groups from HEMA and PVA, and amide groups from AM and PAM that enhance the hydrophilicity of the resulting polymers; these functional groups enhance interactions with water through hydrogen bonding and ion-dipole interactions, facilitating increased water uptake and retention.", +} +{ + "content": "The synthesis of hydrophilic polymers involves the use of monomers such as polyacrylic acid (PAA) and polyacrylamide (PAM), which contain carboxylic acid and amide functional groups, respectively, that enhance their hydrophilicity by allowing for strong hydrogen bonding and electrostatic interactions with water molecules." +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers with functional groups such as hydroxyl (-OH) in polyvinyl alcohol (PVA) and amide (-C(=O)NH-) in polyacrylamide (PAAm), which enhance the hydrophilicity of corresponding polymers by promoting hydrogen bonding interactions with water molecules, thereby improving the solubility and water retention of the hydrogels." +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include polyvinyl alcohol (PVA), which contains hydroxyl functional groups, and acrylamide (AAm), which also has amide groups; these functional groups enhance the hydrophilicity of the polymers by increasing their ability to form hydrogen bonds with water molecules, thereby improving interactions with water." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers such as polyacrylamide-alginate double network hydrogel involves functional groups from polar group-containing epoxies that enhance hydrophilicity through increased interactions with water due to their ability to form hydrogen bonds and facilitate the diffusion and reorganization of polymer chains in an aqueous environment." +} +{ + "content": "Monomers such as sodium alginate, acrylamide, and gelatin contain functional groups like hydroxyl (-OH) and amine (-NH2), which enhance the hydrophilicity of the corresponding polymers by forming hydrogen bonds with water molecules, thus increasing their interactions with water." +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic 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environmental changes like temperature and pH." +} +{ + "content": "Monomers used for synthesizing hydrophilic polymers include oligo(ethylene glycol) methyl ether methacrylate (OEGMA), di(ethylene glycol) methyl ether methacrylate (M(EO)2MA), acrylic acid (AA), thioglycolic acid (TGA), and N,N-dimethylaminoethyl methacrylate (DMAEMA), with functional groups such as hydroxyl (-OH), carboxylic acid (-COOH), and amine (-NH2) enhancing the hydrophilicity of the polymers, as these polar functional groups increase hydrogen bonding and ionic interactions with water molecules, thereby promoting better affinity and solubility in aqueous environments." +} +{ + "content": "Monomers used for synthesizing hydrophilic polymers include TMS-PEG and MeTAcSi, whose functional groups such as –OH and –O– in PEG promote strong hydrogen bonding and ionic interactions with water, enhancing hydrophilicity through increased affinity for water molecules." +} +{ + "content": "" +} +{ + "content": "" +} +{ + 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overall performance in oil-water separation applications." +} +{ + "content": "The monomer structures used for synthesizing hydrophilic polymers include poly(vinyl alcohol) (PVA) and plant-derived polyphenol TA, with functional groups such as hydroxyl (-OH) on PVA and phenolic groups in TA that enhance the hydrophilicity of the polymers through strong hydrogen bonding interactions with water." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include Polyvinyl Alcohol (PVA) and Tannic Acid (TA), wherein the hydroxyl groups (-OH) in PVA and the multiple phenolic hydroxyl groups in TA enhance the hydrophilicity of the resulting polymers by facilitating hydrogen bonding with water molecules.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + 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from sodium borate, which facilitate strong hydrogen bonding and enhance interactions with water by providing sites for hydrogen bonding and increasing water affinity." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "The synthesis involves PVA, which contains hydroxyl functional groups that enhance hydrophilicity through hydrogen bonding with water, as well as agarose, which has hydroxyl groups that similarly improve water interactions." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + 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interactions with water." +} +{ + "content": "The synthesis involves the use of PEGMA, which contains ether functional groups that enhance hydrophilicity through hydrogen bonding interactions with water, and PTMP, which supports the polymer structure without specifying its functional groups but contributes to the overall polymer properties." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include PEGDMA, which contains ether groups that enhance hydrophilicity, and POSS-SH6-PEGMA, which has thiol and methacrylate functional groups, both of which improve water interactions through hydrogen bonding and increased surface wettability.", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": 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polymer's affinity for moisture." +} +{ + "content": "The monomer chitosan, an amino-polysaccharide, contains functional groups such as amine and hydroxyl groups which enhance the hydrophilicity of the corresponding polymers by enabling hydrogen bonding and electrostatic interactions with water.", +} +{ + "content": "The monomer structure used for synthesizing hydrophilic polymers is chitosan, which contains functional groups such as amino (-NH2) and hydroxyl (-OH) groups that enhance the hydrophilicity of the corresponding polymers by facilitating hydrogen bonding and ionic interactions with water." +} +{ + "content": "The monomer used for synthesizing hydrophilic polymers in this study is 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPS), which contains a sulfonic acid functional group that enhances hydrophilicity by increasing electrostatic interactions with water, thereby promoting the retention of a water layer at the interface for low frictional coefficients.", +} +{ + "content": "", +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as methacrylated gelatin (GelMA), polyacrylamide (PAAM), and methacrylated chitosan (CSMA), which possess functional groups like methacrylate that enhance hydrophilicity through hydrogen bonding and polar interactions with water, thereby allowing these polymers to interact favorably with moisture and promote biological activities such as osteogenesis and angiogenesis." +} +{ + "content": "The hydrophilic polymers used for synthesizing hydrophilic polymers in this study include methacryloyl gelatin (GelMA), polyacrylamide (PAAM), polyethylene glycol diacrylate (PEGDA), and methacryloyl chitosan (CSMA), with functional groups such as -OH, -COOH, and -NH2 that enhance hydrophilicity by enabling strong hydrogen bonding and ionic interactions with water, thereby facilitating improved water absorption and interaction within the polymer network." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "The hydrophilic polymers are synthesized from natural monomers like chitosan, gelatin, and hyaluronic acid, which contain functional groups such as amino (-NH2), hydroxyl (-OH), and carboxyl (-COOH) that enhance hydrophilicity by promoting strong hydrogen bonding and ionic interactions with water molecules." +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves functional groups like sulfonate groups from sulfonation treatment, methodologies employing methacrylated gelatin and polyethylene glycol diacrylate, and pH-responsive chitosan, which enhance hydrophilicity and promote interactions with water by increasing the network's ability to absorb moisture and offering a conducive environment for cellular activities necessary for bone healing." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves using monomers like methacrylated gelatin (GelMA) which contains functional groups such as RGD sequences that promote cell adhesion and proliferation, and through surface sulfonation, hydroxyl and carboxyl groups can be introduced, enhancing the material's interactions with water by increasing the overall polar surface area and enabling hydrogen bonding with water molecules." +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The hydrophilic polymer methyl acrylated gelatin (GelMA) is synthesized using the monomer methacrylic anhydride, which contains functional groups that enhance hydrophilicity, such as carboxyl and hydroxyl groups, which enable stronger interactions with water through hydrogen bonding and ionic interactions.", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include GelMA and AM, which possess functional groups that enhance the hydrophilicity of the corresponding polymers by interacting favorably with water through hydrogen bonding and ionic interactions.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The monomer used for synthesizing hydrophilic polymers is Gelatin methacryloyl (GelMA), which contains functional groups such as C=O and N-H that enhance hydrophilicity by forming hydrogen bonds with water molecules.", +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include oxidized graphene (GO) with oxygen-containing functional groups such as -COOH, -OH, and -O- that enhance hydrophilicity by promoting water interactions through hydrogen bonding and ionic interactions.", 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"", +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as methyl acrylate-acrylic acid copolymers, which contain functional groups like carboxylic acids that enhance hydrophilicity by forming hydrogen bonds with water, thereby increasing water absorption and interaction.", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesis of HAP@Mg-GA MOF nanoparticles involves the use of gallic acid, which contains the -COO- functional group that enhances hydrophilicity through electrostatic interactions with water.", +} +{ + "content": "The monomer used for synthesizing the hydrophilic polymer methylacryloylated chitosan (CSMA) is maleic anhydride, which enhances the hydrophilicity of the polymer through the presence of functional groups such as carboxyl and hydroxyl groups that interact favorably with water, facilitating hydrogen bonding and dipole-dipole interactions.", +} +{ + "content": "" +} +{ + "content": "The monomer structures used for synthesizing hydrophilic polymers include CSMA (甲基丙烯酰化壳聚糖) which contains functional groups that enhance hydrophilicity through its hydroxyl and amine groups, promoting strong interactions with water via hydrogen bonding.", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The text discusses the presence of amine groups (-NH2) and catechol functional groups in polydopamine and their significant role in enhancing hydrophilicity through strong molecular bonding and interactions with water, emphasizing that amine groups displace hydrated salts and facilitate the formation of robust non-covalent interactions such as hydrogen bonding, coordination bonding, and cation-π interactions, which ultimately contribute to the material independence and versatile surface modifications of polydopamine coatings." +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "Tannic acid contains abundant hydroxyl groups that enhance its hydrophilicity by allowing for hydrogen bonding with water, while catechin derivatives, although poorly water-soluble, can form complexes with hydrophilic polymers like poly(ethylene glycol), increasing their effective interaction with water.", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include acrylic acid, poly(acrylic acid), poly(ethylene glycol), poly(2-hydroxyethyl methacrylate), and poly(carboxybetaine), which possess functional groups such as hydroxyl, carboxyl, and amine groups that enhance the hydrophilicity of the corresponding polymers by increasing hydrogen bonding and ionic interactions with water." +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "Monomers used for synthesizing hydrophilic polymers include hyaluronic acid, which contains carboxylic acid and hydroxyl functional groups, and poly(ethylene glycol) and poly(acrylamide), both of which feature hydroxyl and amide groups; these functional groups enhance interactions with water by promoting hydrogen bonding and increasing the polymer's capacity to retain moisture." +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "Methacrylic anhydride and acryloyl chloride are used to introduce functional groups that enhance the hydrophilicity of polymers like gelatin methacryloyl, hyaluronic acid methacryloyl, and chitosan methacryloyl, which possess unsaturated double bonds that facilitate interactions with water through hydrogen bonding and dipole-dipole interactions." +} +{ + "content": "" +} +{ + "content": "The text excerpt discusses monomers involved in the synthesis of hydrophilic polymers, specifically mentioning amino groups (-NH2) which enhance the hydrophilicity of the corresponding polymers by increasing the interaction with water due to their ability to form hydrogen bonds.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include poly(ethylene glycol) diacrylate (PEGDA), gelatin methacryloyl (GelMA), and methacrylated hyaluronic acid (MeHA), which contain functional groups such as acrylates and methacrylates that enhance hydrophilicity by promoting strong hydrogen bonding and electrostatic interactions with water molecules." +} +{ + "content": "" +} +{ + "content": "The hydrophilic polymer PEGDA is synthesized from PEG, which contains terminal hydroxyl groups that enhance its hydrophilicity, as these hydroxyl groups facilitate hydrogen bonding with water molecules, thus increasing the polymer's interaction with water.", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers such as PEGDA include PEG diol featuring hydroxyl (-OH) functional groups and acryloyl chloride, which enhance the hydrophilicity of the resulting polymers by promoting hydrogen bonding and dipole interactions with water molecules.", +} +{ + "content": "" +} +{ + "content": "The monomer used for synthesizing hydrophilic polymers in the GelMA hydrogel is gelatin, which enhances hydrophilicity through its RGD sequences, while the methacrylic anhydride functional group introduced during methacrylation improves the degradation rate and mechanical strength of the resulting polymer, thus facilitating water interactions." +} +{ + "content": "The synthesis of GelMA involves methacryloyl groups substituted onto the hydroxyl and amine functional groups of gelatin, which enhance hydrophilicity; these groups provide sites for hydrogen bonding with water molecules, increasing the polymer's interaction with water." +} +{ + "content": "", +} +{ + "content": "The monomer used for synthesizing hydrophilic polymers in this context is hyaluronic acid (HA), which contains functional groups such as the N-acetyl group and carboxyl groups that enhance hydrophilicity by promoting hydrogen bonding and electrostatic interactions with water." +} +{ + "content": "The synthesis of MeHA involves methacryloyl groups substitution on the hydroxyl and reactive amine groups of HA, which enhance the hydrophilicity of the corresponding polymers due to the presence of polar functional groups that interact favorably with water through hydrogen bonding." +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers, including poly(ethylene glycol) diacrylate (PEGDA), gelatin methacryloyl (GelMA), and methacrylated hyaluronic acid (MeHA), contain functional groups that enhance hydrophilicity, which enables improved interactions with water through hydrogen bonding and other polar interactions due to the presence of hydroxyl and carboxyl groups in their structures." +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "The synthesis of hydrophilic polymers involves the use of monomers such as (meth)acrylic acid and hydroxy esters, which contain functional groups such as carboxylic acid (-COOH) and hydroxyl (-OH) that enhance the hydrophilicity of the corresponding polymers by increasing their ability to form hydrogen bonds with water molecules." +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include (meth)acrylic acid esters and (meth)acrylic hydroxyl esters, which contain hydroxyl groups that enhance hydrophilicity by increasing hydrogen bonding interactions with water, thus improving water solubility and interaction.", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include acrylic esters, specifically ethoxyethyl acrylate (EOEOEA), which contains multiple ether functional groups that enhance hydrophilicity by increasing the polymer's ability to interact with water through hydrogen bonding and dipole-dipole interactions." +} +{ + "content": "丙烯酸羟乙酯(HEA)、丙烯酸羟丙酯(HPA)、甲基丙烯酸羟乙酯(HEMA)和甲基丙烯酸羟丙酯(HPMA)均含有羟基,这些羟基能够形成氢键,从而增强聚合物与水的相互作用,并提高其对极性基材的附着力。", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include glycidyl methacrylate (GMA) with an epoxy group that enhances adhesion and contributes to hydrophilicity, isobornyl methacrylate (IBOA) which, while expensive, has a low viscosity and low skin irritation but lacks notable hydrophilic functional groups, tetrahydrofuran methacrylate (THFA) containing a polar tetrahydrofuran ring that increases adhesion and hydrophilicity, and phenoxyethyl acrylate (POEA, 2-PEA) which has a high reactivity and a low skin irritation but possesses a phenolic odor; the polar functional groups in THFA and GMA enhance interactions with water by increasing the polymer's ability to form hydrogen bonds and improve its overall hydrophilicity." +} +{ + "content": "The text excerpt mentions N-乙烯基吡咯烷酮 (NVP) as a water-soluble monomer, which enhances hydrophilicity due to its amide group that forms hydrogen bonds with water molecules, thus improving interactions with water." +} +{ + "content": "", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include diethylene glycol diacrylate (DEGDA), triethylene glycol diacrylate (TEGDA), and a series of polyethylene glycol diacrylates (PEGDA), where functional groups such as ether (–O–) and hydroxyl (–OH) enhance the hydrophilicity of the corresponding polymers by promoting hydrogen bonding and favorable interactions with water, thus increasing their flexibility and biocompatibility." +} +{ + "content": "", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include 1,4-butanediol diacrylate (BDDA), 1,6-hexanediol diacrylate (HDDA), neopentyl glycol diacrylate (NPGDA), and phthalate diethylene glycol diacrylate (PDDA), and their functional groups such as hydroxyl (-OH) and ether (-O-) enhance hydrophilicity by allowing for strong hydrogen bonding and dipole-dipole interactions with water, thus improving water solubility and interaction.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves using diols such as ethylene glycol and polypropylene glycol, and diacids like maleic acid and its anhydride, where the presence of hydroxyl and carboxylic acid functional groups enhances hydrophilicity by promoting hydrogen bonding and ionic interactions with water." +} +{ + "content": "", +} +{ + "content": "The synthesis of hydrophilic polymers utilizes monomers such as acrylic acid, which possesses carboxylic acid functional groups that enhance hydrophilicity through the ability to form hydrogen bonds with water, increasing the polymer's affinity for moisture." +} +{ + "content": "The synthesis of hydrophilic polymers involves using long chain diols, primarily polyether diols such as polyethylene glycol and polypropylene glycol, which contain ether linkages that contribute to their lower cohesive energy and enhanced flexibility, thereby improving the flexibility and hydrophilicity of the resultant urethane acrylate; furthermore, the hydroxyl groups (-OH) in hydroxy acrylates such as hydroxyethyl acrylate (HEA) and hydroxypropyl acrylate (HPA) interact favorably with water due to their polar nature, resulting in enhanced water affinity and solubility." +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "The synthesis of polyester acrylates (PEA), a common oligomer, involves the use of monomers such as diacids and diols which contain carboxyl (-COOH) groups as functional groups that enhance hydrophilicity by promoting hydrogen bonding with water, thereby increasing the polymers' interaction with water." +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polyether acrylates include poly(ethylene glycol) and poly(propylene glycol), which possess hydroxyl functional groups that enhance hydrophilicity by facilitating hydrogen bonding with water molecules." +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as acrylic acid and hydroxyethyl acrylate, where functional groups like carboxyl groups in acrylic acid enhance hydrophilicity by forming hydrogen bonds with water, while hydroxyl groups in hydroxyethyl acrylate improve water interaction through their ability to form hydrogen bonds, both promoting water compatibility in the resulting polymers." +} +{ + "content": "The functional groups that enhance the hydrophilicity of the corresponding polymers include acrylate groups derived from acrylic hydroxyl esters, which improve interactions with water by providing polar character that facilitates hydrogen bonding with water molecules." +} +{ + "content": "The synthesis involves the use of epoxidized soybean oil acrylate, which contains epoxy functional groups, and acrylic acid that provides carboxyl functional groups; both functional groups enhance the hydrophilicity of the resulting polymers by facilitating hydrogen bonding interactions with water due to their polar nature." +} +{ + "content": "The synthesis of hydrophilic polymers includes using dicarboxylic acid, specifically adipic acid, which contains carboxyl (-COOH) functional groups that enhance hydrophilicity through the formation of hydrogen bonds with water, and maleic anhydride, which also has carboxylic groups contributing to the increased water affinity." +} +{ + "content": "The synthesis of hydrophilic polymers involves the use of monomers such as acrylic acid and maleic anhydride which possess functional groups like carboxyl (-COOH) that enhance hydrophilicity by forming hydrogen bonds with water, thereby increasing water affinity and solubility.", +} +{ + "content": "", +} +{ + "content": "Monomers used for synthesizing hydrophilic polymers include hydroxyl ethyl acrylate (HEA), which possesses hydroxyl functional groups that enhance hydrophilicity by forming hydrogen bonds with water, enabling better solubility and interaction with water molecules." +} +{ + "content": "The monomer structures used for synthesizing hydrophilic polymers include hydroxyl groups in hydroxy-terminated polyesters and carboxylic acid groups in acrylic acids, which enhance the hydrophilicity of the polymers due to their ability to form strong hydrogen bonds with water molecules, thereby increasing water interactions." +} +{ + "content": "The text does not provide any information regarding monomer structures or functional groups that enhance the hydrophilicity of the corresponding polymers." +} +{ + "content": "The synthesis involves triethylene glycol diacrylate and a mixture of hydrosilicones, which contain functional groups such as hydroxyl (-OH) and siloxane (-Si-O-Si-) that enhance hydrophilicity by forming strong hydrogen bonds and promoting water interaction through their ability to attract and stabilize water molecules." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include methacryloxypropyl trimethoxysilane, hydroxyethyl acrylate, and acrylate modified polysiloxane, which contain functional groups such as hydroxyl (-OH) and methoxy (-OCH3) that enhance hydrophilicity by increasing the polymer's ability to interact with water through hydrogen bonding and dipole-dipole interactions." +} +{ + "content": "The synthesized hydrophilic polymer, PSUA, incorporates functional groups such as epoxy groups and carboxylic acid groups, which enhance hydrophilicity by forming strong hydrogen bonds with water molecules, therefore improving water affinity and interaction.", +} +{ + "content": "The synthesis of hydrophilic polymers involves functional groups such as hydroxyl (-OH) and carboxyl (-COOH) groups which enhance hydrophilicity by forming hydrogen bonds with water, thereby increasing water affinity and solubility in the resulting polymers." +} +{ + "content": "The synthesized hydrophilic polymers contain functional groups such as carboxyl groups from methacrylic acid, which enhance hydrophilicity through hydrogen bonding interactions with water, as well as hydroxyl groups from hydroxyethyl acrylate, which further improve water affinity due to their ability to form hydrogen bonds with water molecules." +} +{ + "content": "The text describes various hydrophilic polymers synthesized using monomers that contain functional groups such as carboxyl groups and hydroxyl groups, which enhance the hydrophilicity of the corresponding polymers by increasing their polar characteristics and enabling stronger hydrogen bonding or ionic interactions with water." +} +{ + "content": "The text mentions functional groups such as carboxyl groups in the synthesized polymers, which enhance hydrophilicity by forming hydrogen bonds with water, resulting in improved water interactions within the hydrophilic 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hydrophilic polymers include 2-hydroxy-1,4-dimethylthiocarbamate, which contains a hydroxyl group that enhances hydrophilicity by forming hydrogen bonds with water, and 3-chloro-2-hydroxypropyl trimethyl ammonium chloride, which has quaternary ammonium groups that enhance interactions with water through ionic interactions and electrostatic attractions." +} +{ + "content": "The synthesized hydrophilic polymers incorporate functional groups such as sulfonate (-SO3Na) and hydroxyl (-OH) groups, which enhance hydrophilicity by increasing the polarity of the polymer chains and improving the interaction with water through hydrogen bonding and ion-dipole interactions." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include 2-hydroxy-1,4-dimethylthioketone sodium salt and 3-chloro-2-hydroxypropyl sulfonate, which contain hydroxyl (-OH) and sulfonate (-SO3Na) functional groups that enhance hydrophilicity, as these groups can form hydrogen bonds with water and increase ionic interactions, leading to improved water solubility and interaction with hydrophilic environments." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The hydrophilicity of the polymers can be enhanced by functional groups such as carboxyl (-COOH) and hydroxyl (-OH) groups, which promote interactions with water through the formation of hydrogen bonds and chemical bonds with metal surfaces, thus increasing adhesion.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": 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+ "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include multi-functional acrylates such as PETA, TMPTA, and TPGDA, which contain functional groups that enhance hydrophilicity through their ability to form hydrogen bonds with water.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include HEMA, which contains hydroxyl functional groups that enhance the hydrophilicity of the polymer by forming hydrogen bonds with water, thereby increasing water absorption and interaction." +} +{ + "content": "" +} +{ + "content": "The text excerpt includes HEMA (2-hydroxyethyl methacrylate) as a monomer used for synthesizing hydrophilic polymers, which contains a hydroxyl (-OH) functional group that enhances the hydrophilicity of the 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these groups increase interactions with water by facilitating hydrogen bonding and reducing the contact angle, as evidenced by a decrease to below 40 degrees after the water gel coating application." +} +{ + "content": "The hydrophilic polymers are synthesized using N,N-dimethylacrylamide, which contains amide functional groups that enhance hydrophilicity by providing polar sites for hydrogen bonding with water molecules, thereby improving water interactions.", +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers in this study involved the monomer N,N-dimethylacrylamide (DMAA), which contains amide functional groups that enhance the hydrophilicity of the corresponding polymers, as these amide groups can form hydrogen bonds with water molecules, promoting interactions with water and resulting in a reduced contact angle of the coated surface from above 80 degrees to under 40 degrees after application of a thin hydrogel layer.", +} +{ + "content": "The synthesis of hydrophilic polymers involves the use of N,N-dimethylacrylamide, which contains amide functional groups that enhance the hydrophilicity of the resulting polymers by forming hydrogen bonds with water molecules, thus increasing their affinity for water." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesized hydrophilic polymers include acrylic ester monomers, nitrogen-containing vinyl monomers, and modified surfactants containing sulfonic, sulfuric, or carboxylic functional groups, which enhance hydrophilicity through increased hydrogen bonding and ionic interactions with water, thereby improving water interaction and retention." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as acrylate monomers and nitrogen-containing vinyl monomers, where functional groups like sulfonic, sulfuric, and carboxylic acids enhance hydrophilicity by increasing water interactions through ionic and polar interactions, thereby improving the polymers' ability to maintain low contact angles with water vapor.", +} +{ + "content": "The hydrophilic polymers described in the synthesis involve monomers containing functional groups such as sulfonic acid, sulfuric acid, carboxylic acid, and nitrogen-containing vinyl groups that enhance hydrophilicity through increased interactions with water via hydrogen bonding and ionic interactions, promoting improved water affinity and solubility." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include allyl polyether, tetraethylorthosilicate, and octamethylcyclotetrasiloxane, where the ether groups in allyl polyether and the ethoxy groups in tetraethylorthosilicate enhance hydrophilicity through increased water interaction and the ability to form hydrogen bonds with water molecules." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The monomers used in synthesizing hydrophilic polymers include partially acetylated poly(vinyl alcohol) (PVAAc), which has hydroxyl (-OH) groups that enhance hydrophilicity, and anhydrous D(+)-glucose, which also contains multiple hydroxyl groups; these functional groups enhance interactions with water by forming hydrogen bonds that increase water solubility and affinity.", +} +{ + "content": "", +} +{ + "content": "The synthesis of hydrophilic polymers involved the use of D(+)-glucose, which contains alcohol functional groups that enhance the hydrophilicity of the polymers by allowing for strong hydrogen bonding interactions with water due to the presence of hydroxyl (-OH) groups.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The polymer chains in hydrogels are enriched with functional groups such as amine, acylamino, carboxy, and hydroxy, which enhance hydrophilicity by increasing interactions with water through hydrogen bonding and ionic interactions.", +} +{ + "content": "" +} +{ + "content": "The monomer acrylamide possesses a functional amide group, while acrylic acid contains a carboxylic acid group, both of which enhance the hydrophilicity of the resulting polymers by increasing hydrogen bonding interactions with water, thereby enhancing water absorption and retention in the hydrogels.", +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include acrylamide (AAm), N-isopropylacrylamide (NIPAm), and acrylic acid (AAc), where the -C(O)OH group in acrylic acid enhances the hydrophilicity of the polymers by providing strong hydrogen bonding interactions with water, while the amide groups in acrylamide and N-isopropylacrylamide facilitate dipole-dipole interactions and hydrogen bonding with water, thereby improving the overall affinity of the polymers for moisture." +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers that contain functional groups capable of forming covalent bonds in chemical hydrogels, which enhances the hydrophilicity of the resulting polymers.", +} +{ + "content": "", +} +{ + "content": "The text does not provide specific information about the monomer structures or the functional groups that enhance the hydrophilicity of the corresponding polymers." +} +{ + "content": "The hydrophilic polymer synthesized is poly(allylamine hydrochloride) (PAH), which contains amino groups that enhance hydrophilicity through hydrogen bonding with water molecules, thus facilitating diffusion and detection of polar glucose molecules through the hydrogel.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The hydrophilic polymers were synthesized using poly(allylamine hydrochloride) (PAH) which contains primary amine functional groups that enhance hydrophilicity through hydrogen bonding and ionic interactions with water.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The monomer acrylamide (AAm) contains an amide functional group that enhances the hydrophilicity of the corresponding polymer by promoting strong hydrogen bonding with water molecules, leading to increased water interactions." +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The hydrophilic polymer is synthesized using acrylamide as the matrix, and the presence of functional groups such as the amide group in acrylamide enhances the polymer's hydrophilicity by allowing strong hydrogen bonding with water molecules." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include acrylamide, gelatin, and N,N'-methylene bisacrylamide, with functional groups such as amide (-CONH2) and hydroxyl (-OH) that enhance the hydrophilicity of the corresponding polymers by forming hydrogen bonds with water, thereby increasing affinity and interaction with the solvent." +} +{ + "content": "The synthesized hydrophilic polymers include 2-(Dimethylamino) ethyl methacrylate (DMAEMA) which contains a dimethylamino group that enhances hydrophilicity through hydrogen bonding with water, and 2-(Methacryloyloxy) ethyl dimethyl-(3-sulfopropyl) ammonium hydroxide (SBMA), which has a sulfonate group that increases hydrophilicity due to its ionic charge enabling stronger interactions with water molecules." +} +{ + "content": "" +} +{ + "content": "The polydimethylsiloxane (PDMS)-poly(ethylene glycol) (PEG) copolymer and zwitterionic poly(sulfobetaine methacrylate) (PSBMA) used in amphiphilic coatings enhance hydrophilicity through their water-absorbing PEG chains and zwitterionic components, which facilitate strong electrostatic and hydrogen-bond interactions with water, thereby promoting water absorption and forming a lubricating aqueous layer that improves antifogging and anti-icing performances." +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include DMAEMA and SBMA, where the functional groups such as the zwitterionic moiety in SBMA and the ammonium groups in PDMAEMA enhance the hydrophilicity by enabling stronger hydrogen bonding with water molecules compared to other surfaces like PEG." +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include polyvinylpyrrolidone (PVP), polyethylene glycol (PEG), and lauryl ether, which contain functional groups such as hydroxyl and ether groups that enhance hydrophilicity by increasing hydrogen bonding and ionic interactions with water.", +} +{ + "content": "" +} +{ + "content": "Hydrophilic materials used for antifog include those containing a large number of hydrophilic groups, which enhance water interactions by attracting water molecules, allowing droplets on the material surface to rapidly spread and form a continuous water film, thereby reducing light diffusion." +} +{ + "content": "" +} +{ + "content": "The monomers used for synthesizing hydrophilic polymers include ethanol, propylene glycol, polyoxyethylene lauryl ether, sodium dodecyl sulfate, polyethylene glycol 400, and acrylic acid, which feature functional groups such as hydroxyl (-OH) and ether (-O-) that enhance the hydrophilicity of the polymers by increasing their ability to form hydrogen bonds with water, thereby improving water interactions.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "The text does not provide relevant information regarding the monomer structures or functional groups used for synthesizing hydrophilic polymers." +} +{ + "content": "" +} +{ + "content": "The hydrophilic polymers are synthesized using anhydrous ethanol, propylene glycol, lauryl alcohol polyethylene ether, sodium dodecyl sulfate, and polyethylene glycol 400, with functional groups such as hydroxyl groups and ether linkages that enhance hydrophilicity by creating hydrogen bonds with water molecules, thus improving water interaction." +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The synthesis of hydrophilic polymers involves monomers such as polyethylene glycol, which contains ether groups that enhance hydrophilicity by facilitating hydrogen bonding and dipole interactions with water." +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "", +} +{ + "content": "The synthesis involves the use of functional groups from polyacrylic acid, polyethylene glycol, and various nanoscale metal oxides such as zinc oxide, titanium dioxide, and silica, which enhance the hydrophilicity of the polymers due to their ability to form hydrogen bonds and interact favorably with water molecules." +} +{ + "content": "" +} +{ + "content": "The hydrophilic substances mentioned include anionic surfactants with carboxyl and sulfate functional groups, cationic surfactants containing amino and quaternary ammonium groups, and nonionic surfactants with ether and carboxylester groups that enhance interactions with water by attracting water molecules, making solid surfaces easily wettable and forming a water film that reduces light scattering to achieve anti-fogging effects." +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "The text mentions the use of acrylic acid as a monomer, which contains carboxyl functional groups that enhance hydrophilicity through hydrogen bonding interactions with water, promoting water uptake and swelling in the resulting polymers." +} +{ + "content": "" +} +{ + "content": "The hydrophilic polymers are synthesized using monomers that contain functional groups such as -OH, -COOH, and -NH2 which enhance their hydrophilicity by promoting strong interactions with water molecules, leading to a reduction in the interfacial tension between the solid and liquid, and allowing water to spread and form a thin film rather than discrete droplets on the surface." +} +{ + "content": "The text discusses monomers with various hydrophilic functional groups such as carboxylic acids, sulfates, amino groups, amines, hydroxyls, amides, and ether linkages, which enhance the hydrophilicity of polymers by promoting strong polar interactions with water, thereby effectively reducing surface tension and improving water absorption.", +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} +{ + "content": "" +} diff --git a/code/task1.py b/code/task1.py new file mode 100644 index 0000000..628f839 --- /dev/null +++ b/code/task1.py @@ -0,0 +1,257 @@ +from openai import OpenAI +from pathlib import Path +import os +import re +import json +import glob +import tqdm +from multiprocessing import Pool +from functools import partial +from collections import Counter + +API_KEY = "sk-oYh3Xrhg8oDY2gW02c966f31C84449Ad86F9Cd9dF6E64a8d" +BASE_URL = "https://vip.apiyi.com/v1" +MODEL_GPT = "gpt-4o-mini" + +# 确保输出为标准json格式字符串 +def comfirm_json_string_gpt(json_string): + client = OpenAI(api_key=API_KEY, base_url=BASE_URL) + + prompt = f""" + You will read a , please fix this string into a string that can be parsed by json.loads. + + Note: + 1. No descriptive text is required. + 2. Don't use markdown syntax. + + The : {json_string} + """ + + response = client.chat.completions.create( + model=MODEL_GPT, + messages=[ + {"role": "system", "content": "You are an assistant who is proficient in material synthesis."}, + {"role": "user", "content": prompt} + ] + ) + + return response.choices[0].message.content + +# 确保输出为标准json格式字符串 +def comfirm_json_string(json_string): + json_string = re.sub(r'[“”]', '"', json_string) + json_string = re.sub(r'\\', r'\\\\', json_string) + json_string = re.sub(r'\\"', r'\"', json_string) + json_string = json_string.replace("\n", "").replace("\r", "") + # 去掉 Markdown 的语法包裹 + if json_string.startswith("```json"): + json_string = json_string.strip("`json\n") + json_string = json_string.strip('`\n') + + return json_string + +# 文本分割 +def split_by_heading(markdown_text, heading_level='#'): + # `heading_level` could be '#', '##', '###', etc. + pattern = r'(?=\n{})'.format(re.escape(heading_level)) + + # 使用正则表达式进行切割,以包含标题的内容 + split_texts = re.split(pattern, markdown_text) + + # 去除空白的块 + return [block.strip() for block in split_texts if block.strip()] + +# 文本段分类 +def segment_classification(text_split): + client = OpenAI(api_key=API_KEY, base_url=BASE_URL) + + prompt = f""" + You will read a text segment about hydrophilic polymers. Please analyze which part of a paper this segment belongs to and give your classification result. The categories you can only choose are as follows: + 1. Abstract + 2. Introduction + 3. Materials and methods + 4. Results and discussion + 5. Conclusions + 6. References + + Please output the result using the following format: + Category: Abstract/Introduction/Materials and methods/Results and discussion/Conclusions/References + + Text segment as follows: {text_split} + """ + + response = client.chat.completions.create( + model=MODEL_GPT, + messages=[ + {"role": "system", "content": "You are an expert in interdisciplinary research across fields such as materials chemistry, polymer science, biomaterials engineering, and interface and surface science."}, + {"role": "user", "content": prompt} + ] + ) + + return response.choices[0].message.content + +# 处理单个md文件 +def process_file(md_path, output_dir): + chunks = [] + with open(md_path, 'r', encoding='utf-8') as file: + md_content = file.read() + + # 将文本按heading分割 + content_splits = split_by_heading(md_content) + + id = 0 + for content_split in content_splits: + id += 1 + chunk = {} + result = segment_classification(content_split) + chunk["id"] = id + chunk["chunk"] = content_split + chunk["category"] = result[9:] + chunks.append(chunk) + + output_path = os.path.join(output_dir, os.path.basename(md_path).replace('.md', '.json')) + with open(output_path, 'w', encoding='utf-8') as json_file: + json.dump(chunks, json_file, ensure_ascii=False, indent=4) + +# 获取已经处理过的md +def chunk_done(json_dir): + jsons = os.listdir(json_dir) + json_names = [json_name.replace('.json', '') for json_name in jsons] + return json_names + +# 将文本段分割分类并保存为json +def md_segment(): + md_paths = glob.glob("/home/ubuntu/50T/fsy/wl/articles/mds/**/*.md", recursive=True) + print("md文件数量:", len(md_paths)) + # 过滤已经过处理的文件 + output_dir = "/home/ubuntu/50T/fsy/wl/task1-chunks" + json_names = chunk_done(output_dir) + md_paths = [md_path for md_path in md_paths if os.path.basename(md_path).replace(".md", "") not in json_names] + print("过滤后md文件数量:", len(md_paths)) + + for path in tqdm.tqdm(md_paths): + try: + process_file(path, output_dir) + except Exception as e: + print(f"处理 {path} 时出错: {e}") + + # # 设置多进程池 + # pool = Pool(processes=32) + + # process_func = partial(process_file, output_dir=output_dir) + + # # imap_unordered 将逐步从 md_paths 传给 process_func 进行并行处理 + # for _ in tqdm.tqdm(pool.imap_unordered(process_func, md_paths), total=len(md_paths)): + # pass + + # pool.close() + # pool.join() + +# 提取分子做亲水性聚合物的单体结构及其有助于亲水性的相应官能团 +def get_function_groups(text): + client = OpenAI(api_key=API_KEY, base_url=BASE_URL) + + prompt = f""" + You will read a text excerpt about the synthesis of hydrophilic polymers. Please extract all information regarding the monomer structures used for synthesizing hydrophilic polymers, including: + 1. Information about the functional groups that enhance the hydrophilicity of the corresponding polymers. + 2. Explanations of how these functional groups enhance interactions with water. + + Note: + 1. The information you extract must come from the text excerpt(example not included), and fabrication of information is strictly prohibited. + 2. Don't use markdown syntax. + 3. If no relevant information is extracted, return the format with the "content" field left empty. + + Please output the result using the following format: + {{ + "content": "a single complete sentence containing all the required information", + }} + + The text except: {text} + """ + + response = client.chat.completions.create( + model=MODEL_GPT, + messages=[ + {"role": "system", "content": "You are an expert in developing hydrophilic polymers for applications such as biomedical hydrogels or water filtration membranes."}, + # {"role": "system", "content": "You are an expert in researching surface modification of black phosphorus."}, + {"role": "user", "content": prompt} + ] + ) + + return response.choices[0].message.content + +# 提取实验方案 +def extract_info(chunks_path): + with open(chunks_path, 'r', encoding='utf-8') as file: + chunks = json.load(file) + + protocol_dict = {"content" : ""} # 存放最终输出 + for chunk in chunks: + chunk_text = chunk['chunk'] + category = chunk['category'] + try: + # 提取分子做亲水性聚合物的单体结构及其有助于亲水性的相应官能团 + if category == ' Introduction' or category == ' Materials and methods' or category == 'Results and discussion': + intermediate_result = get_function_groups(chunk_text) + print(intermediate_result) + intermediate_result = comfirm_json_string(intermediate_result) + try: + result_protocol = json.loads(intermediate_result) + except json.JSONDecodeError as e: + # 修复json字符串(gpt) + escaped_protocol = comfirm_json_string_gpt(intermediate_result) + try: + result_protocol = json.loads(escaped_protocol) + except Exception as e: + print(e) + print(escaped_protocol) + return + if result_protocol["content"] == "": + continue + if isinstance(result_protocol, dict): + protocol_dict["content"] += result_protocol["content"] + else: + print("result_content不是一个字典") + print(result_protocol) + return + except Exception as e: + print(e) + return + + output_path = os.path.join(output_dir, os.path.basename(chunks_path)) + with open(output_path, 'w') as json_file: + json.dump(protocol_dict, json_file, ensure_ascii=False, indent=4) + +if __name__ == '__main__': + chunks_dir = "/home/ubuntu/50T/fsy/wl/task1-chunks" + paths = [os.path.join(chunks_dir, path) for path in os.listdir(chunks_dir)] + print("chunks文件数量:", len(paths)) + + # 过滤已处理的文件 + output_dir = "/home/ubuntu/50T/fsy/wl/task1-paper-info" + proccessed_files = [path for path in os.listdir(output_dir)] + paths = [path for path in paths if os.path.basename(path) not in proccessed_files] + print("过滤后chunks文件数量:", len(paths)) + + # step1 + # md_segment() + + # step2 + for path in tqdm.tqdm(paths): + try: + extract_info(path) + except Exception as e: + print(f"处理 {path} 时出错: {e}") + + + # 设置多进程池 + # pool = Pool(processes=32) + + # process_func = partial(extract_info) + + # # imap_unordered 将逐步从 md_paths 传给 process_func 进行并行处理 + # for _ in tqdm.tqdm(pool.imap_unordered(process_func, paths), total=len(paths)): + # pass + + # pool.close() + # pool.join() diff --git a/code/task2.py b/code/task2.py new file mode 100644 index 0000000..27bf103 --- /dev/null +++ b/code/task2.py @@ -0,0 +1,250 @@ +from openai import OpenAI +from pathlib import Path +import os +import re +import json +import glob +import tqdm +from multiprocessing import Pool +from functools import partial +from collections import Counter + +API_KEY = "sk-oYh3Xrhg8oDY2gW02c966f31C84449Ad86F9Cd9dF6E64a8d" +BASE_URL = "https://vip.apiyi.com/v1" +MODEL_GPT = "gpt-4o-mini" + +# 确保输出为标准json格式字符串 +def comfirm_json_string_gpt(json_string): + client = OpenAI(api_key=API_KEY, base_url=BASE_URL) + + prompt = f""" + You will read a , please fix this string into a string that can be parsed by json.loads. + + Note: + 1. No descriptive text is required. + 2. Don't use markdown syntax. + + The : {json_string} + """ + + response = client.chat.completions.create( + model=MODEL_GPT, + messages=[ + {"role": "system", "content": "You are an assistant who is proficient in material synthesis."}, + {"role": "user", "content": prompt} + ] + ) + + return response.choices[0].message.content + +# 确保输出为标准json格式字符串 +def comfirm_json_string(json_string): + json_string = re.sub(r'[“”]', '"', json_string) + json_string = re.sub(r'\\', r'\\\\', json_string) + json_string = re.sub(r'\\"', r'\"', json_string) + json_string = json_string.replace("\n", "").replace("\r", "") + # 去掉 Markdown 的语法包裹 + if json_string.startswith("```json"): + json_string = json_string.strip("`json\n") + json_string = json_string.strip('`\n') + + return json_string + +# 文本分割 +def split_by_heading(markdown_text, heading_level='#'): + # `heading_level` could be '#', '##', '###', etc. + pattern = r'(?=\n{})'.format(re.escape(heading_level)) + + # 使用正则表达式进行切割,以包含标题的内容 + split_texts = re.split(pattern, markdown_text) + + # 去除空白的块 + return [block.strip() for block in split_texts if block.strip()] + +# 文本段分类 +def segment_classification(text_split): + client = OpenAI(api_key=API_KEY, base_url=BASE_URL) + + prompt = f""" + You will read a text segment about hydrophilic polymers. Please analyze which part of a paper this segment belongs to and give your classification result. The categories you can only choose are as follows: + 1. Abstract + 2. Introduction + 3. Materials and methods + 4. Results and discussion + 5. Conclusions + 6. References + + Please output the result using the following format: + Category: Abstract/Introduction/Materials and methods/Results and discussion/Conclusions/References + + Text segment as follows: {text_split} + """ + + response = client.chat.completions.create( + model=MODEL_GPT, + messages=[ + {"role": "system", "content": "You are an expert in interdisciplinary research involving materials chemistry, surface and interface science, and the functionalization of nanomaterials."}, + {"role": "user", "content": prompt} + ] + ) + + return response.choices[0].message.content + +# 处理单个md文件 +def process_file(md_path, output_dir): + chunks = [] + with open(md_path, 'r', encoding='utf-8') as file: + md_content = file.read() + + # 将文本按heading分割 + content_splits = split_by_heading(md_content) + + id = 0 + for content_split in content_splits: + id += 1 + chunk = {} + result = segment_classification(content_split) + chunk["id"] = id + chunk["chunk"] = content_split + chunk["category"] = result[9:] + chunks.append(chunk) + + output_path = os.path.join(output_dir, os.path.basename(md_path).replace('.md', '.json')) + with open(output_path, 'w', encoding='utf-8') as json_file: + json.dump(chunks, json_file, ensure_ascii=False, indent=4) + +# 获取已经处理过的md +def chunk_done(json_dir): + jsons = os.listdir(json_dir) + json_names = [json_name.replace('.json', '') for json_name in jsons] + return json_names + +# 将文本段分割分类并保存为json +def md_segment(): + md_paths = glob.glob("/home/ubuntu/50T/fsy/wl/articles/mds/**/*.md", recursive=True) + print("md文件数量:", len(md_paths)) + # 过滤已经过处理的文件 + output_dir = "/home/ubuntu/50T/fsy/wl/task2-chunks" + json_names = chunk_done(output_dir) + md_paths = [md_path for md_path in md_paths if os.path.basename(md_path).replace(".md", "") not in json_names] + print("过滤后md文件数量:", len(md_paths)) + + for path in tqdm.tqdm(md_paths): + try: + process_file(path, output_dir) + except Exception as e: + print(f"处理 {path} 时出错: {e}") + + # 设置多进程池 + # pool = Pool(processes=32) + + # process_func = partial(process_file, output_dir=output_dir) + + # # imap_unordered 将逐步从 md_paths 传给 process_func 进行并行处理 + # for _ in tqdm.tqdm(pool.imap_unordered(process_func, md_paths), total=len(md_paths)): + # pass + + # pool.close() + # pool.join() + +# 提取合成方案 +def get_protocol(text): + client = OpenAI(api_key=API_KEY, base_url=BASE_URL) + + prompt = f""" + You will read a text excerpt from an article on hydrophilic polymer synthesis. Please extract the specific experimental protocol for synthesis of hydrophilic polymers with functional groups. + + Note: + 1. The information you extract must come from the text excerpt(example not included), and fabrication of information is strictly prohibited. + 2. Don't use markdown syntax. + + Please output the result using the following format: + {{ + "protocol": "" + }} + + The text except: {text} + """ + + response = client.chat.completions.create( + model=MODEL_GPT, + messages=[ + {"role": "system", "content": "You are an expert in developing hydrophilic polymers for applications such as biomedical hydrogels or water filtration membranes."}, + # {"role": "system", "content": "You are an expert in researching surface modification of black phosphorus."}, + {"role": "user", "content": prompt} + ] + ) + + return response.choices[0].message.content + +# 提取实验方案 +def extract_info(chunks_path): + with open(chunks_path, 'r', encoding='utf-8') as file: + chunks = json.load(file) + + protocol_dict = {"protocol" : ""} # 存放最终输出 + for chunk in chunks: + chunk_text = chunk['chunk'] + category = chunk['category'] + try: + # 提取分子做亲水性聚合物合成的具体实验步骤 + if category == ' Introduction' or category == ' Materials and methods': + intermediate_result = get_protocol(chunk_text) + intermediate_result = comfirm_json_string(intermediate_result) + try: + result_protocol = json.loads(intermediate_result) + except json.JSONDecodeError as e: + # 修复json字符串(gpt) + escaped_protocol = comfirm_json_string_gpt(intermediate_result) + try: + result_protocol = json.loads(escaped_protocol) + except Exception as e: + print(e) + print(escaped_protocol) + return + if result_protocol == "": + continue + if isinstance(result_protocol, dict): + protocol_dict["protocol"] += result_protocol["protocol"] + else: + print("result_protocol不是一个字典") + print(result_protocol) + return + except Exception as e: + print(e) + return + + output_path = os.path.join(output_dir, os.path.basename(chunks_path)) + with open(output_path, 'w') as json_file: + json.dump(protocol_dict, json_file, ensure_ascii=False, indent=4) + +if __name__ == '__main__': + chunks_dir = "/home/ubuntu/50T/fsy/wl/task2-chunks" + paths = [os.path.join(chunks_dir, path) for path in os.listdir(chunks_dir)] + print("chunks文件数量:", len(paths)) + + # 过滤已处理的文件 + output_dir = "/home/ubuntu/50T/fsy/wl/task2-paper-info" + proccessed_files = [path for path in os.listdir(output_dir)] + paths = [path for path in paths if os.path.basename(path) not in proccessed_files] + print("过滤后chunks文件数量:", len(paths)) + + # md_segment() + + for path in tqdm.tqdm(paths): + try: + extract_info(path) + except Exception as e: + print(f"处理 {path} 时出错: {e}") + + # # 设置多进程池 + # pool = Pool(processes=32) + + # process_func = partial(extract_info) + + # # imap_unordered 将逐步从 md_paths 传给 process_func 进行并行处理 + # for _ in tqdm.tqdm(pool.imap_unordered(process_func, paths), total=len(paths)): + # pass + + # pool.close() + # pool.join()